CA1185936A - Dispenser for pasty substances - Google Patents

Dispenser for pasty substances

Info

Publication number
CA1185936A
CA1185936A CA000389630A CA389630A CA1185936A CA 1185936 A CA1185936 A CA 1185936A CA 000389630 A CA000389630 A CA 000389630A CA 389630 A CA389630 A CA 389630A CA 1185936 A CA1185936 A CA 1185936A
Authority
CA
Canada
Prior art keywords
tubule
bellows
headpiece
housing
dispenser according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000389630A
Other languages
French (fr)
Inventor
Werner Sieverding
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bramlage GmbH
Original Assignee
Bramlage GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bramlage GmbH filed Critical Bramlage GmbH
Application granted granted Critical
Publication of CA1185936A publication Critical patent/CA1185936A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents
    • B65D83/0005Containers or packages provided with a piston or with a movable bottom or partition having approximately the same section as the container
    • B65D83/0033Containers or packages provided with a piston or with a movable bottom or partition having approximately the same section as the container the piston being a follower-piston and the dispensing means comprising a hand-operated pressure-device at the opposite part of the container

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Ignition Installations For Internal Combustion Engines (AREA)

Abstract

ABSTRACT OF THE DISCLOSURE

The specification relates to a dispenser for pasty substances with a housing having a piston displaceable only in discharge direction and an outer operating handle which is formed at a headpiece, compressible in a bellows-like manner in direction of the piston.
The headpiece has a dispenser-outlet opening. The dispenser is characterized in that a tubule, immersed with its inner open end in every position of the bellows in the pasty substance, proceeds inwardly from the dispenser-outlet opening.

Description

~L185~

Dispenser for Pasty Substances The invention relates to a dispenser for pasty substances wi-th a housing having a piston displaceable only in a discharge direction and an outer operating handle which is fo~med at a headpiece, compressible in a bellows-like manner :Ln the clirection of the piston, the headpiece having a dispenser-o~tlet openiny at the outer end of a tubule, the inner end section o e which is immersed in the pasty substance on -the entire length projecting inwardly beyond the bellows~like headpiece.

.

Besides slide valves, it is known to use lip-like or ball valves (German AS 1,210,149). There, the piston is drawn by the vacuum which forms in the housing with each restoring action of the headpiece bellows, over the rilling column in the direction of the headpiece. In order not to lose this function by entry of air leakage via the dispenser-outlet opening, a valve is mounted in the latter which momentarily closes the opening again upon the dropping oE overpressure (pressure above atmospheric pressure).
The coordination of a corresponding dispensing valve is too expensive for a mass produced arkicle as, for example, a toothpaste-dispenser package. Moreover, operating breakdowns are to be expected since the headpiece bellows, which i5 formed from correspondingly softened material and thus considerably variable in shape, does not exclude shifting of the spring. Since, ultimately, the outlet valve is suddenly opened by a predetermined overpressure threshold, undesirable spray effects and, in any event, inexactly proportionable discharging amounts can result. Finally, there is also the disadvantage of a considerable expenditure for assembling and components. The spring closing the lips must be inserted from the inside. Since they are located in the region of the considerable deformable bellows the spring can lose its hold.
~,~
, ~ . ,, -- 1 `,3 ,~,~

ll1~S~3~

It is the objec-t of the inventlon to crea~e a dispen~er o this type, with a structure which is techni.cally simpl~r ~o manufacture and more advantayeous to use, in such a way that the noted discharge valve can be eliminated.

This object is solved by a tubule, immersed, with an inner always open mouth end being completely free, in every posi-tion of the bellows, in the pasty subs-tance, extending inw~rdly Erom -the dispenser-outlet opening.

As a result of such a design a dispenser of thls type is created which is satisfactory without any separate valve, however, still allowing an exactly proportionable, convenient to operate dispensing. The valve function, still attainable surprisingly with use of the inertia of the pasty substance, is also more advantageous in that an overpressure (pressure above atmospheric) for opening the valve, no longer has to first be produced, which overpressure always causes a more or less sudden, inadequately controllable discharging of the contents. In a structurally simple manner with the present invention, a tubule extends from the clispenser-outlet opening which tubule remains immersed in the pasty substance with its inner open mouth end in every position of the bellows with the inner always open, mouth end of the tubule being completely exposed communicating with the pasty substance in the housing. The factors such as -tubule cross-section, length and viscosity of the pasty substance are adjusted or balanced in such a way that the retraction of the piston occurs first, that is, before the pasty substance remaining in the tubule, which as a plug obstructs the tubule from communication with the outside air, can equalize the resulting vacuum with ai-r. The structural design of the dispenser i5 also considerably simplified. Such a tubule can be attached directly to or formed in one-piece on the headpiece. A
separate construction is, however, recommended when substances of
- 2 -5~73~;

differiny viscosity and other charac~.e.r:i.st:Lc-i are .inv~lved, so tha.t by keeping the basic structure, comprisinCJ the housiny, clamp-locked piston and headpiece, it is then equipped, as required, with the cross-sectionally adapted tubule. A
formation, practically itself bringing about the operationally correct usage, exists when the tubule extends inclined at an acute-angle relative to the longi.tudinal axis of the tubular housing. This, above all, brings a desired, exact alignment of the tubule with respect to the discharge posi.tion as, for example, for the bristles part of a toothbrush. ~hereby, the inner open end of-the correspondingly coordinated tubule extends into the area of the longitudinal center axis of the housing, that is, into a central area which is convenient or favorable for pressing. If, finally, the bellows and its folding zone are formed in such a way that the tubule tilts, during bellows operation, in an approximately coaxial position relative to the longi.tudinal center axis of the housing, then the considerable operational advantage results that the dispensing-sided tubule end practically retracts from the projecting paste-extrusion.
~his facilitates the applicatio~ of this paste extrusion, which can also be.exactly followed visually, onto the toothbrush.

With the above and other ob,ects and advantages in view, the present invention will become more clearly understood in connection with the detailed description of a preferred embodiment, when considered with the accompanying drawings, of which:

Fig~ 1 shows a dispenser formed in accordance with the invention, in side view;

Fig. 2 is a base view thereof; and -~.3:~

~3S9311~

Fig. 3 is a longitu(llnal sec~ion throuyh the dispen~er wi-th closure cap indicated in d~sh-dotted lines.

The long cylindrical housing l contains a piston 2. Its peripheral edge lips ~' run alony the cylindrical inner side of housing wall l'. The housiny l is open at the bot-tom.

The piston 2 is only displaceable in the c1ischarginy direction (arrow x). On its wide surface, facing the assembly-~ided open end of the housing, it carries a so~cal].ed clamp module 3 in the shape of a star, made of spring steel, having substan~ially radially directed prongs 3'. Its diameter circumscribing khe prongs in the free non-inserted position is larger than the open diameter of the housing, whereby the prong ends blockingly hook-in as inclined support feet on the inner housing wall opposite to the direction of the arrow x preventing the piston 2 from moving down.

The dispensing-side closure of the housing l -forms an operating or actuation handle mounted opposite the standing base 4 of the same. It is a headpiece 5, compressible in a bellows-like manner in the direction of the piston 2, always returning spontaneously straightening again into its initial position~ The headpiece 5 is attached to the slightly narrowed neck 6 of the housing l~ By means of a ring-groove connection in cooperation wi-th the restoring force of the material forming the headpiece 5, there i5 provided a usable durable fastening.

The headpiece 5 forms a cross~sectionally narrowed dispenser outlet opening ~. A tubule 7 projects into the interior of the dome-like shaped headpiece 5 from the opening ~. The tubule is made of relatively stiff material and is held by a protrusion extending and formed from the headpiece cover 5' and pointing diagonally upward. The tubule is seated therein in a clamp ~S~3~i mounting, hu-t can, however, lf re~uired, be conrlected -to the headpiece by glue or even welding.

Equally possib]e is a one piece formatlon of the tubule 7 with the headpiece 5~

The tubule 7 is inclined at an acute-angle to the lonyltudinal axis y-y of the tubular or cylindrical housincJ 1. ~n this manner it projects with ;ts outer open end 7', forming the outlet ~, almost into the area o~ an extendiny cas:iny level of the housing 1. The inner open end 7" extends into the vicinity o~ the longitudinal center axis y-y, that is, into the center of the axially symmetric housing. It ends about level with the upper edge 6' of the neck and penetrates, as seen in Fig. 3, with this inner open end 7" into the pasty substance M, which comes up to under the dome shaped cover 5' of the headpiece 5, that is, the pasty substance also entirely surrounds the tubule~ Moreover, a portion of the tubule 7 is always filled with the pasty substance. The angle of inclination alpha of the tubule 7 relative to the axis y-y is approximately 30.

The zone forming the bellows B of the headpiece 5 is obtained by a horizontal flat-V-shaped constriction E. This constriction extends over half the cross-sectional width of the headpiece 5 which tapers frustoconically upward in its basic form. The furrow of the bellows is indicated with the numeral 9 and illustrated in Fig, 3 with a dashed line.

The acute-angled coordination of the tubule 7 in the section of the headpiece 5, opposite the constriction E, is such that the tubule 7 tips, by the bellows operation, so as to orient itself in a coaxial or approximately coaxial or spacial parallel position relative to the longitudinal center axis y-y of the housing 1. In this manner the outer open end 7' o~ the tubule 7 ~`~'?

~1~5~336 moves away from its usual position near the edge. The open end 7' can also be shaped in a more beak-shaped curv~d form in such a way that the opening ~ is perpendicular to the axis y-y.

The headpiece 5 is encased by a cap 10 shown partially in dot-dashed lines in Fig. 3. The inner corner of the cap cover is -tapered corresponding to the front surface posltion of the tubule, so that with the tapered cap 10 in position the tubule opening is tightly sealed. The cap 10 is held xictionally or locked in position by a complementary shaping of the parts at a peripheral bead in the fastening area of the same between the lower headpiece edge and the neck 6 of the housing 1.

The manner of operation of the described dispenser is as follows:
After removal of cap 10, the headpiece S is pressed downwardly in the direction of the piston 2 in the area forming the bellows B, which area is grooved like a tire or otherwise roughened on the upper side. The piston 2 is supported by the clamp module 3, so that ik cannot move or deviate downwardly. The pasty substance M
is pressed, while passing through the tubule 7, in direction of the opening ~ and finally discharges from the open end 7'. If the headpiece 5 is now released, vacuum pressure develops in the housing interior. The flexible headpiece 5, returning to its initial position, retracts or pulls the piston up in the direction of the arro~ x over the contents column. This resetting is completed before the substance still remaining in the tubule as a plug can reach the inner open end 7". Decisive thereby is that the tubule 7, in cross-section and length, with adjustment to the viscosity of the pasty substance and the resultant slow velocity, forms a corresponding resistance which bridges the occurring vacuum.

The ratio of the open tubule cross-section to the tubule length is approximately 1:5.

` '{" ~
. . .~

~L185~

Pressure ratios in the D~
_ _ , (h~draulic system) Explanation of symbols: ~

= coefficient of friction for flowing mediums;
= tubule l.enyth;
d = open tubule width;
R = Reynolds' Nurnber -R ~ 2000 (laminar) R ~ 3000 (turbulent);
V = average velocity of substance ~ = density of substance The table of pressure ratios in the dispenser is reproduced on the following page.

~ L~l35~6 r ~

"~ u (a--~
" r ~ aJ
a ~1 ~n (I) Q
Q ~ ~
~ U.~J
U) ~ ~ ~, P~
P~
.1 .
U~
a) u ~1 , ,q .
,,~J
~ __ ~ o ~
~ ~1 U~ ~ X
~ h à ~ ,~ ~ ~
~ F. ~ P~ X
r ~ u P~ c~ ~ c u~ ~ 11 11 O ~ l ~1 h ~; O _P~ P~/
O U t: 0~1 0 h ~: O r~ ~ ~1 :~ ~rl ~ U
u) ~1 U a.) h h h ~ J
~1 ~ h u) U~ IJ u) t)~ h O
P~ ,~ C) U R a) C) t ~rl ,L~ I F u~
O O P~ rl O C
rl Q ~ 0 la c ~ I
E~ ~ r, IJ u~ I
r~ 1--h O t~l O r ~ n ~> I
l L~
U. ~I) ~I r~l ~ IXN r~l I X

~j h r-l td X ~ ¦1~ P~

r~ rJ X . ~ _ O ~,~0 ~ ,C O ~ 11 ~ ¦ ~ .
U ~ rJ J~ O ~ t~ .
rl ~ C~l ~1 R~

. - 8 - .

"
.. . . . ...... ... ~ .. ..... . .

Claims (15)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. A dispenser in combination with and adapted for particular pasty substances comprising a tubular housing containing a particular pasty substance and defining a longitudinal axis, a piston mounted in said housing displaceably only in one direction constituting a discharging direction, a headpiece mounted on said housing, formed as a bellows and having an outer operating handle which is formed at said headpiece, the latter having a folding-bellows cover being compressible in a bellows-like manner in a direction of the piston, the headpiece having an interior wall including an interior side of said cover, a tubule is arranged in said cover and extends inclined at an acute-angle relative to the longitudinal axis of the tubular housing through said headpiece defining an inner section therein which over its entire length projects inwardly inside the bellows into the housing and terminates at an innermost end, said tubule has a dispenser-outlet opening at an outer end of the tubule and extends inwardly therefrom to said innermost end, the latter being formed with an inner open mouth end formed so as to be always completely openly exposed penetrating in and communicating the tubule with said pasty substance in said housing and headpiece in every position of the bellows, said tubule constituting the exclusive means of the dispenser for communicating the interior of said housing with the outside, .

said. particular pasty substance completely fills the interior of said housing above said piston and above said innermost end of said tubule, surrounding said inner section of said tubule, to said interior wall of said headpiece and extends continuously through the always communicating openly exposed inner open mouth end into said tubule through said entire length of said inner section forming a pasty substance plug continuously connected to said pasty substance in said housing and headpiece, said inner section of said tubule and said inner open mouth end penetrating substantially deeply into the pasty substance in the interior of said housing and headpiece, said tubule, said piston and said housing being formed relative the particular pasty substance such that resistance against displacement in said one direction of the piston in said housing is smaller than resistance against displacement of the particular pasty substance in the tubule when said bellows is released after being compressed.
2. The dispenser according to claim 1, wherein said inner open mouth end is approximately at the longitudinal axis of the houding.
3. The dispenser according to claims 1 or 2, wherein said folding-bellows cover is formed such that upon bellows operation during the compressing of said folding bellows cover, the tubule tips substantially into a coaxially position relative to the longitudinal axis of the housing with said dispenser-outlet opening and said inner open mouth substantially coaxially to said longitudinal axis.
4. The dispenser according to claim 1, wherein said tubule is formed such that the piston retracts upon the release of the bellows before the pasty substance in the tubule can reach the inner open mouth end.
5. The dispenser according to claim 1, wherein said tubule is made of a substantially stiff material.
6. The dispenser according to claim 1, wherein said headpiece has a zone formed by a horizontal flat V-shaped constriction extending over substantially half of the cross-sectional width of said headpiece forming the bellows, the headpiece tapering upwardly frustoconically in a normal position.
7. The dispenser according to claim 1, wherein with slow release of the bellows ?V2/2 (64?1/Vd2 + 1) is at least equal to .DELTA.Ppf +.DELTA.Ppa + .DELTA.Psf + .DELTA.Psa where ? is the density of the pasty substance, V is the average velocity of the pasty substance, ? is the viscosity of the pasty substance, 1 (first occurrence) is the length of the tuhule, d is the inner open width of the tubule, .DELTA.Ppf is the pressure increment due to piston friction, .DELTA.Ppa is the pressure increment due to piston acceleration, .DELTA.Psf is the pressure increment due to friction of the pasty substance, and .DELTA.PSa is the pressure increment due to acceleration of the pasty substance.
8. The dispenser according to claim 1, wherein said tubule is non-displaceable relative to said headpiece.
9. The dispenser according to claim 1, wherein said inner section of the tubule projects beyond the bellows with said innermost end thereof.
10. The dispenser according to claim 1, wherein said tubule has a substantially linear axis.
11. The dispenser according to claim 10, wherein said tubule has a substantially uniform cross-section.
12. The dispenser according to claim 1, wherein said folding-bellows cover has a highest surface constituting pressing surface extending from and substantially on one side of said tubule in a direction substantially away from the direction of extension of said tubule towards said outer end of the tubule.
13. The dispenser according to claim 12, wherein said tubule is mounted in said folding-bellows cover at a position spaced away from the longitudinal axis of said tubular housing in substantially the same direction as the direction of extension of said tubule towards said outer end of the tubule extends away from said longitudinal axis, whereby said longitudinal axis intersects said pressing surface and the latter surrounds and extends beyond said longitudinal axis.
14. The dispenser according to claim 13, wherein said tubule projects above said folding-bellows cover to said outer end of the tubule, said outer end being located substantially above a side of said tubular housing.
15. The dispenser according to claim 1, wherein said acute angle is substantially 45°.
CA000389630A 1980-11-08 1981-11-06 Dispenser for pasty substances Expired CA1185936A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3042285.6 1980-11-08
DE19803042285 DE3042285A1 (en) 1980-11-08 1980-11-08 MEASURE DONOR FOR PASTOESE

Publications (1)

Publication Number Publication Date
CA1185936A true CA1185936A (en) 1985-04-23

Family

ID=6116361

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000389630A Expired CA1185936A (en) 1980-11-08 1981-11-06 Dispenser for pasty substances

Country Status (6)

Country Link
US (1) US4474313A (en)
EP (1) EP0051790B1 (en)
JP (1) JPS6050670B2 (en)
AT (1) ATE9312T1 (en)
CA (1) CA1185936A (en)
DE (2) DE3042285A1 (en)

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Publication number Priority date Publication date Assignee Title
DE3222492A1 (en) * 1982-06-15 1983-12-15 Joachim 8405 Donaustauf Czech DISPENSER FOR PASTOESE PRODUCTS
US4640442A (en) * 1983-10-31 1987-02-03 The Procter & Gamble Company Dispensing package and follower deivce
US4533069A (en) * 1983-10-31 1985-08-06 The Procter & Gamble Company Pump-type dispenser
EP0144879B1 (en) * 1983-12-02 1988-10-12 Bramlage GmbH Dispenser for pasty materials, especially a dispenser for toothpaste
DE3416999A1 (en) * 1984-05-09 1985-11-14 Bramlage Gmbh, 2842 Lohne MEASURE DONOR FOR PASTOESE
DE3438579A1 (en) * 1984-10-20 1986-04-30 Bramlage Gmbh, 2842 Lohne MEASURE DONOR FOR PASTOESE
ATE71048T1 (en) * 1985-11-06 1992-01-15 Future Patents Dev Fpd DISPENSER FOR PASTOESE MASS.
DE3781830D1 (en) * 1986-05-31 1992-10-29 Pohl Gmbh & Co Kg DISPENSER FOR PORTIONED SINGLE OUTPUT OF PASTE OR THE LIKE.
EP0422698A3 (en) * 1986-05-31 1991-07-17 Pohl Gmbh & Co. Kg Dispenser
GB8617350D0 (en) * 1986-07-16 1986-08-20 Metal Box Plc Pump chamber dispenser
US4749108A (en) * 1986-12-19 1988-06-07 The Procter & Gamble Company Bimodal storage and dispensing package including self-sealing dispensing valve to provide automatic shut-off and leak-resistant inverted storage
GB2204099B (en) * 1987-04-29 1991-04-24 Metal Box Plc Pump chamber dispenser
BR8807067A (en) * 1987-05-20 1989-10-17 Colgate Palmolive Co DISTRIBUTOR OF MATERIALS IN PUMP FORM AND PUMP DIAPHRAGM
DE3803229A1 (en) * 1988-02-04 1989-08-17 Alfred Von Schuckmann DISPENSER FOR PORTIONED ISSUE OF PASTOESER MASS
US4858785A (en) * 1988-04-04 1989-08-22 Package Research Corporation Multiple fluid dispenser
US5016783A (en) * 1988-04-26 1991-05-21 Anchor Hocking Corporation Pump dispenser package
US4938393A (en) * 1988-06-02 1990-07-03 The Procter & Gamble Company Bimodal storage and dispensing package for fluent material
US4927058A (en) * 1988-07-20 1990-05-22 Colgate-Palmolive Company Package for a flowable material susceptible to flavor loss
US5346324A (en) * 1991-09-19 1994-09-13 Youti Kuo Dentifrice dispensing toothbrush with replaceable cartridge
US5253787A (en) * 1992-08-03 1993-10-19 Package Research Corporation Fluid dispenser with tiltable dispensing nozzle and sealing membrane
IT1256628B (en) * 1992-12-04 1995-12-12 DISPENSER OF FLUID SUBSTANCES, WITH DEFORMABLE HEAD
DE20115432U1 (en) * 2001-09-19 2003-02-27 Sulzer Chemtech Ag Winterthur Cartridge with piston lock
DE20315111U1 (en) * 2003-09-30 2005-02-10 Wilden Ag follower piston
WO2010012814A1 (en) * 2008-08-01 2010-02-04 Boehringer Ingelheim International Gmbh Package in the form of a bottle comprising a cushioning means disposed therein
US8668119B2 (en) * 2009-09-03 2014-03-11 James Wheeler Container for viscous comestibles
AT508350B1 (en) * 2009-09-28 2011-01-15 Rene Ing Mag Habinger TOOTHBRUSH
KR200459835Y1 (en) * 2009-12-11 2012-04-20 (주)아모레퍼시픽 Cosmetic container
US20130134188A1 (en) * 2010-05-28 2013-05-30 Yoshino Kogyosho Co., Ltd. Cartridge-type dispenser
DE102011102524A1 (en) * 2011-05-26 2012-11-29 Krallmann Kunststoffverarbeitung Gmbh donor
DE202015006514U1 (en) 2015-09-15 2015-12-03 Kegham Armen Polish dispenser for a polishing machine
FR3081113B1 (en) * 2018-05-18 2020-05-29 Albea Le Treport PISTON FOR TANK OF A DISPENSER OF A FLUID PRODUCT WITHOUT AIR INTAKE

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US2679337A (en) * 1950-12-04 1954-05-25 Ralph T Leach Combined closure and dispenser
US2789337A (en) * 1953-07-02 1957-04-23 Rocwall Company Inside corner structure for prefabricated forms for composition walls
US3088636A (en) * 1959-12-08 1963-05-07 Walter B Spatz Dispensers for fluent masses
DE1210149B (en) * 1963-08-08 1966-02-03 Walter Bates Spatz Container for liquid or viscous cosmetics and the like Like. With a dispensing valve
US3870200A (en) * 1973-05-14 1975-03-11 Spatz Corp Valveless dispenser for fluent masses
US4087024A (en) * 1976-02-27 1978-05-02 Graber-Rogg, Inc. Fluid dispenser
AT364089B (en) * 1980-03-10 1981-09-25 Blendax Werke Schneider Co CONTAINER FOR VISCOSE MASSES

Also Published As

Publication number Publication date
US4474313A (en) 1984-10-02
JPS57114465A (en) 1982-07-16
DE3166068D1 (en) 1984-10-18
EP0051790B1 (en) 1984-09-12
DE3042285A1 (en) 1982-06-09
JPS6050670B2 (en) 1985-11-09
EP0051790A1 (en) 1982-05-19
ATE9312T1 (en) 1984-09-15

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