CA1316603C - Optical recording medium and manufacturing method thereof - Google Patents
Optical recording medium and manufacturing method thereofInfo
- Publication number
- CA1316603C CA1316603C CA 590987 CA590987A CA1316603C CA 1316603 C CA1316603 C CA 1316603C CA 590987 CA590987 CA 590987 CA 590987 A CA590987 A CA 590987A CA 1316603 C CA1316603 C CA 1316603C
- Authority
- CA
- Canada
- Prior art keywords
- recording medium
- optical recording
- sides
- protrusions
- center substrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- 239000000463 material Substances 0.000 claims description 13
- 238000001746 injection moulding Methods 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 9
- 238000001125 extrusion Methods 0.000 claims description 8
- 239000004431 polycarbonate resin Substances 0.000 claims description 5
- 229920005668 polycarbonate resin Polymers 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 229920003002 synthetic resin Polymers 0.000 claims description 3
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- 238000000034 method Methods 0.000 abstract description 11
- 238000004299 exfoliation Methods 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 abstract description 2
- 239000004417 polycarbonate Substances 0.000 description 35
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 206010040844 Skin exfoliation Diseases 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
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- 229920000647 polyepoxide Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000009993 protective function Effects 0.000 description 1
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Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B11/00—Recording on or reproducing from the same record carrier wherein for these two operations the methods are covered by different main groups of groups G11B3/00 - G11B7/00 or by different subgroups of group G11B9/00; Record carriers therefor
- G11B11/10—Recording on or reproducing from the same record carrier wherein for these two operations the methods are covered by different main groups of groups G11B3/00 - G11B7/00 or by different subgroups of group G11B9/00; Record carriers therefor using recording by magnetic means or other means for magnetisation or demagnetisation of a record carrier, e.g. light induced spin magnetisation; Demagnetisation by thermal or stress means in the presence or not of an orienting magnetic field
- G11B11/105—Recording on or reproducing from the same record carrier wherein for these two operations the methods are covered by different main groups of groups G11B3/00 - G11B7/00 or by different subgroups of group G11B9/00; Record carriers therefor using recording by magnetic means or other means for magnetisation or demagnetisation of a record carrier, e.g. light induced spin magnetisation; Demagnetisation by thermal or stress means in the presence or not of an orienting magnetic field using a beam of light or a magnetic field for recording by change of magnetisation and a beam of light for reproducing, i.e. magneto-optical, e.g. light-induced thermomagnetic recording, spin magnetisation recording, Kerr or Faraday effect reproducing
- G11B11/10582—Record carriers characterised by the selection of the material or by the structure or form
- G11B11/10584—Record carriers characterised by the selection of the material or by the structure or form characterised by the form, e.g. comprising mechanical protection elements
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/26—Apparatus or processes specially adapted for the manufacture of record carriers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/146—Laser beam
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23—Sheet including cover or casing
- Y10T428/239—Complete cover or casing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
- Y10T428/24521—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness with component conforming to contour of nonplanar surface
- Y10T428/24529—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness with component conforming to contour of nonplanar surface and conforming component on an opposite nonplanar surface
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
Abstract
ABSTRACT OF THE DISCLOSURE
A novel optical recording medium and a method for manufacture thereof is disclosed, the optical recording medium, which is used as an optical disc or optical card et cetera for optically recording, reproducing, erasing and the like of information, comprising a center substrate having formed on at least either of both sides thereof recesses and/or protrusions, recording films formed on both sides thereof and transparent protective plates stuck to these recording films respectively, and featuring special arrangements to ensure against warping of the substrates constituting the optical recording medium and also against exfoliation of substrates or the like even when the optical recording medium is subjected to sudden changes in temperature as well as to allow placing emphasis on optical performance and protective effect in selecting the transparent protective plate regardless of the ease of forming recesses and/or protrusions such as grooves to thereby enable a marked improvement in its performance such as carrier-to-noise ratio and isotropy.
A novel optical recording medium and a method for manufacture thereof is disclosed, the optical recording medium, which is used as an optical disc or optical card et cetera for optically recording, reproducing, erasing and the like of information, comprising a center substrate having formed on at least either of both sides thereof recesses and/or protrusions, recording films formed on both sides thereof and transparent protective plates stuck to these recording films respectively, and featuring special arrangements to ensure against warping of the substrates constituting the optical recording medium and also against exfoliation of substrates or the like even when the optical recording medium is subjected to sudden changes in temperature as well as to allow placing emphasis on optical performance and protective effect in selecting the transparent protective plate regardless of the ease of forming recesses and/or protrusions such as grooves to thereby enable a marked improvement in its performance such as carrier-to-noise ratio and isotropy.
Description
131~60~
OPTICAL RECORDING MEDIUM AND MANUFACTURING METHOD THEREOF
FIELD OF THE INVENTION
The present invention relates to an optical recording medium such as an optical disk, optical card or the like for optical recording, reproducing, erasing et cetera of information, and the manufacturing method thereof.
BACKGROUND OF THE INVENTION
A common method of manufacturing an optical recording medium for recording, reproducing, erasing et cetera on both sides thereof comprises, as shown in Fig. 4(a), the steps of first forming recesses and/or protrusions 2... such as grooves and pits on one side of a transparent substrate 1 and then integrally forming a recording film 3 to cover these recesses and/or protrusions, as shown in Fig. 4(b) to thus form an optical recording substrate 4. Thereafter, as shown in Fig. 4(c), an optical recording substrate 4' is 13166~3 formed in a like way and with their recording films 3, 3' opposed to each other, the optical recording substrates 4, 4' are bonded to each other by the use of an adhesive 5, for instance, an ultraviolet ray hardening resin.
The aforementioned substrates 1, 1' are, however, required to allow transmission of light for recording, reproducing and erasing information and since the recesses/
protrusions 2..., 2'... have to be formed, there are various conditions or requirements for such substrates 1, 1'.
For instance, they are required to be (1) transparent, (2) optically isotropic and, in particular, small in bire-fringence, (3) flat with little indication of warping or waviness and (4) easy to form the recesses and/or protru-sions. Furthermore, various requirements are made for the substrates 1, 1' also relating to the recording films 3, 3':
for instance, they are required to have a high heat resistance if the method of forming the recording films 3, 3' requires heating, and if the films 3, 3' are required to be moisture-proof, they are required to have a low moisture permeability and low water absorption.
Recently, therefore, study has been made of the possi-bility of using as the aforementioned substrates 1, 1' those of polycarbonate resin made by injection molding(hereinafter called "PC substrate").
Even the aforementioned PC substrate made by injection 13166~3 molding tends to be high in birefringence and, when the recording film 3 is formed thereon to make it the optical recording substrate 4, it tends to warp with the side covered with the recording film 3 convex, as shown in Fig.
5. This phenomenon of the optical recording substrate 4 warping with the side covered with the recording film 3 convex is due to the difference in thermal expansion coefficient between the recording film 3 and the PC
substrate 1 and, if the temperature is raised at the time of forming the recording film 3, the dimensions of the PC
substrate 1 becomes smaller than that of the recording film 3.
Also, when an optical recording medium is made by bond-ing together the optical recording substrates 4, 4', such an optical recording medium is constantly subject to some degree of stress. When the optical recording medium so prepared is subjected to sudden changes in temperature, exfoliation of recording film 3 from substrate 1, or of each substrate 1, 1' takes place in the optical recording medium, this affecting the reliability of the optical recording medium.
SUMMARY OF THE INVENTION
It is a primary object of the present invention to provide a highly reliable optical recording medium, substrates forming it being safe from warping and even when 1~16~03 the optical recording medium as such is subjected to sudden changes in temperature or the like, there is no risk of exfoliation of a recording film et cetera, and manufacturing method thereof.
Another object of the present invention is to provide a kind of optical recording medium which can be manufactured with emphasis on the optical quality or performance required of a transparent protective plate as well as its protective effect, the carrier-to-noise ratio and optical isotropy, in particular, and manufacturing method thereof.
In order to accomplish the aforementioned objects, the present invention relates to an optical recording medium, comprising a center substrate, of whose both sides at least either has recesses and/or protrusions formed therein, recording films formed on both sides thereof and transparent protective plates stuck to these recording films res-pectively.
The aforementioned center substrate may possibly be an injection-molded sheet of polycarbonate (hereinafter called "PC") resin. It may also be a synthetic resin sheet formed by casting.
Meanwhile, the aforementioned transparent protective plate may possibly be an extrusion-molded sheet of PC resin. It may as well be made of glass.
Further, the aforementioned center substrate and trans-~ 3 ~ 3 parent protective plate may be formed of materials similarin thermal expansion coefficient.
Further still, the aforementioned center substrate is an injection-molded PC resin sheet, while the transparent protective plate may be a PC sheet molded by extrusion.
The method of manufacturing the aforementioned optical recording medium comprises the steps of first preparing the center substrate with recesses and/or protrusions formed at least on one side and, after forming the recording films on both sides, sticking the transparent protective plate to the recording films respectively.
As the method of forming recesses and/or protrusions on the center substrate in the manufacturing process of the aforementioned optical recording medium, it is also possible to form recesses and/or protrusions on both sides of the center substrate simultaneously by the use of a pair of stampers attached to the die, at the time the center substrate is formed by injection molding.
Also, for forming recesses and/or protrusions on the center substrate in the process of manufacturing the aforementioned optical recording medium a method of first sheeting the material by extrusion molding and then placing it between a pair of stampers attached to the dies and pressing from both sides to thereby forming recesses and/or protrusions simultaneously is available.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1(a) is a vertically-sectioned front view of the ce!nter substrate of an optical recording medium having formed on both sides thereof recesses and/or protrusions such as grooves.
Fig. 1(b) is another vertically-sectioned front view of the center substrate of the optical recording medium having formed recording films on both sides thereof.
Fig. 1(c) is still another vertically-sectioned front view of the center substrate of the optical recording medium with recording films formed on both sides thereof and transparent protective layers are stuck to the recording films with each one layer of transparent adhesive there-between.
Fig. 2 is a diagram showing the relationship between the length of optical recording bit and the carrier-to-noise ratio for the optical recording medium when as the transparent protective plate (1) glass base plate is used, (2) extrusion-molded PC (polycarbonate) plate is used, and (3) injection-molded PC plate is used respectively.
Fig. 3 is another diagram showing the relationship between the rotation angle of the transparent protective plate and the difference in refractive index in the direction along the plate and the direction vertical thereto when as the transparent protective plate (1) extrusion-131~603 molded PC plate is used and (2) injection-molded PC plate is used respectively.
Fig. 4(a) is a vertically-sectioned front view of the substrate of a conventional optical recording medium with recesses and/or protrusions such as grooves formed on one side thereof.
Fig. 4(b) is another vertically-sectioned front view of the substrate of the same conventional optical recording medium with a recording film formed on the side with recesses and/or protrusions.
Fig. 4(c) is still another vertically-sectioned front view showing two stuck-together substrates of the conventio-nal optical recording medium, each substrate having formed thereon a recording film.
Fig. 5 is a vertically-sectioned front view showing the warped substrate of the optical recording medium.
DESCRIPTION OF THE EMBODIMENTS
A preferred embodiment of the present invention is described below with reference being made to Figs. 1 through 3.
In the optical recording medium of the present inven-tion, as shown in Fig. 1(c), a center substrate 11 has formed on both sides thereof recesses and/or protrusions 12... such as grooves and pits and recording films 13, 13 are formed integrally to cover these recesses and/or 13166~3 protrusions 12... . On the recording films 13, 13 there are formed transparent adhesive layers 14, 14 and transparent protective plates 15, 15 are securely bonded thereby.
The process of manufacturing the optical recording medium described above comprises the steps of first forming recesses and/or protrusions 12... , as shown in Fig. 1~a), and then forming the recording films 13, 13 by spattering et cetera as shown in Fig. 1(b).
As recording films 13, 13, magneto-optical recording medium films formed as a laminate of 4 layers, namely Al/AlN/(Gdo~6 Tb 0~4 ) 0,28 Fe 0~2/AlN, et cetera is available Of course, this means no limitation, and besides GdTbFe type as such, magneto-optical recording medium in film form made of some other material or even recording medium film of phase change type using Te ~type utilizing crystalline-amorphous phase change) is available.
Then, a transparent adhesive is applied on the afore-mentioned recording films 13, 13 for formation of adhesive layers 14, 14, and the transparent protective plates 15, 15 are securely bonded thereby. As the aforementioned adhesive is applied an ultraviolet ray curing resin or the like.
According to the aforementioned composition, the recording films 13, 13 are formed on both sides of the center substrate 11, hence with the recording films 13, 13 formed on the center substrate 11 warping of the center 131g6~3 substrate 11 can be prevented.
Since the recording films 13, 13 are equal or closely similar in thermal expansion coefficient, they are deemed equal in dimensional change due to changes in te~perature.
Hence, even if the dimensions of these recording films 13, 13 should be different from those of the above center substrate 11, the force resulting from this difference in dimensions acts on the center substrate 11 from both sides thereof at equal magnitudes. If forces of equal magnitudes act on both sides of the center substrate 11, these forces are offset, this resulting in no warping of the aforementioned center substrate 11.
As to the aforementioned transparent preventive plates 15, 15, there is no necessity of forming the recesses and/or protrusions 12..., it is, therefore, not necessary to take the ease of formation of recesses and/or protrusions into consideration. Hence, the range of materials to choose from, is that much increased, this enabling selection of materials with emphasis on optical performance and protective function required of the transparent protective plate 15.
Although in this embodiment, the recesses and/or protrusions 12... are formed on both sides of the center substrate 11, formation of the aforementioned recesses and/or protrusions 12... can be made by means of a pair of i316603 stampers attached to the die/s, in case the center substrate 11 is a polycarbonate (hereinafter called "PC") substrate macle by injection molding.
This way, the trouble of doing center alignment of grooves each time can be dispensed with when 2 sheets of optical recording substrate are bonded together~ That is, by doing position adjustment of the aforementioned stamper in advance, center alignment of grooves formed on both sides of the center substrate is easily feasible and, moreover, if this- center alignment of grooves is done once, reproduced center substrate 11 with grooves is bound to have the identical groove center.
Thus, if the groove's centers can be aligned on both sides, the equilibrium error possibly occurring when the optical recording medium is set on the player and rotated can be easily eliminated or minimized.
By the way, it is not always necessary that the afore-mentioned center substrate 11 must be transparent, and as its material can be used, besides the aforementioned PC
substrate, also ABS resin, melamine resin, glass, ceramics et cetera. As to the method of preparing the center substrate 11, extrusion molding, casting et cetera are applicable in addition to injection molding, and the epoxy resin plate or acrylic resin plate molded by the casting method are well usable as materials of the center substrate 131~603 The signal quality of the optical recording medium, for in!;tance, the relationship between the recording bit length and the carrier-to-noise ratio was measured using as the aforementioned transparent protective plates 15, 15 (1) glass plate, (2) extrusion-molded PC plate and (3) injection-molded PC plate, and the result was as shown in Fig. 2.
According to the measured data, the optical recording medium using an extrusion-molded PC plate was comparable with that using glass plate in carrier-to-noise ratio, and the former turned out to be extremely suited as material of transparent protective plate 15. Meanwhile, the optical recording medium using injection-molded PC plate was lower in carrier-to-noise ratio than that with glass plate, the former not necessarily suitable as the transparent protective plate 15.
There is a difference between an extrusion-molded PC
plate and an injection-molded counterpart also in a difference in refractive index in the direction along the plate and the direction vertical thereto (hereinafter called "vertical birefringence"), as shown in Fig. 3. That is, an extrusion-molded PC plate is smaller in vertical birefringence, and superior in optical isotropy to an injection molded counterpart. With glass plate birefrin-131~3 gence was practically noticeable.
Further, there is also a difference between anextrusion-molded and injection-molded PC plates ln the ease of forming the recesses and/or protrusions 12... , this being attributable to the difference in the method of manufacture. And in this respect an injection-molded PC
plate is superior, that is, easier for formation thereof than an extrusion-molded counterpart.
For the reasons as described above, an ideal optical recording medium is obtainable by using an injection-molded PC plate as the center substrate 11 in which the recesses and/or protrusions are formed and by using an extrusion-molded PC plate as the transparent protective plate 15, 15 which is required to be superior in optical isotropy. This also contributes to the desired reduction in inside stress of the optical recording medium for an extrusion-molded PC
plate and an injection-molded counterpart are similar in thermal expansion coefficient.
Needless to say, the aforementioned center substrate 11 need not necessarily be an injection-molded PC plate, and an extrusion-molded counterpart may be used instead. In order to form the recesses andtor protrusions 12... in an extrusion-molded PC plate the PC plate is placed between a pair of patterned dies and then pressed inward from both sides. When the temperature is kept at approximately 100C, the aforementioned recesses and/or protrusions 12... such as grooves can well be transferred onto the plate.
The optical recording medium of the present invention need not necessarily be disk-shaped, and may be formed as a card or the like as well.
As described above, the present invention relates to an optical recordinq medium comprising a center substrate with recesses and/or protrusions formed on at least either of its both sides and recording films formed on both sides of the center substrate, transparent protective plates stuck to the recording films respectively.
The aforementioned center substrate may possibly be of PC resin made by injection molding.
This center substrate may also be of a synthetic resin made by cast molding.
The aforementioned transparent protective plate may possibly be of PC resin made by extrusion molding.
This transparent protective plate may also be of glass.
Further, the aforementioned center substrate and trans-parent protective plate may possibly be made of materials similar in thermal expansion coefficient.
Further still, it is also possible to have the afore-mentioned center substrate made of PC resin by injection molding, while using a extrusion-molded PC resin as the aforementioned transparent protective plate.
13l66o3 The method for manufacture of the aforementioned optical recording medium comprises the steps of first making the center substrate having formed recesses and/or protrusions on at least either of both sides thereof, then forming the recording films on both sides of the center substrate and thereafter sticking the transparent protective plates to the recording films respectively.
In the aforementioned process for manufacture of the optical recordi-ng substrate the recesses and/or protrusions may possibly be formed on both sides of the center substrate by means of a pair of stampers attached to the die in the course of injection molding.
In the aforementioned manufacturing process the recesses and/or protrusions may also be formed on both sides of the center substrate by first by preparing a material plate by extrusion molding, then placing it between a pair of dies and pressing inward from both sides.
This way, it is possible to obtain a highly reliable optical recording medium, which is prevented from warping of the substrates constituting the optical recording medium, and thus safe from exfoliation of the recording film or the like, even when the optical recording medium is subjected to sudden changes in temperature or the like.
Further, in selecting the trans?arent protective plate, emphasis may be placed on the optical performance and pro-.
,,, ,.-.~ . . .
-13~03 tective effect required of a transparent protective plate re~ardless of the ease of forming recesses and/or protrusions such as grooves, hence a marked improvement in carrier-to-noise ratio, isotropy and the like can well be hoped for.
Further still, the relative positional precision of the recesses and/or protrusions formed on both sides of the center substrate can be easily improved.
OPTICAL RECORDING MEDIUM AND MANUFACTURING METHOD THEREOF
FIELD OF THE INVENTION
The present invention relates to an optical recording medium such as an optical disk, optical card or the like for optical recording, reproducing, erasing et cetera of information, and the manufacturing method thereof.
BACKGROUND OF THE INVENTION
A common method of manufacturing an optical recording medium for recording, reproducing, erasing et cetera on both sides thereof comprises, as shown in Fig. 4(a), the steps of first forming recesses and/or protrusions 2... such as grooves and pits on one side of a transparent substrate 1 and then integrally forming a recording film 3 to cover these recesses and/or protrusions, as shown in Fig. 4(b) to thus form an optical recording substrate 4. Thereafter, as shown in Fig. 4(c), an optical recording substrate 4' is 13166~3 formed in a like way and with their recording films 3, 3' opposed to each other, the optical recording substrates 4, 4' are bonded to each other by the use of an adhesive 5, for instance, an ultraviolet ray hardening resin.
The aforementioned substrates 1, 1' are, however, required to allow transmission of light for recording, reproducing and erasing information and since the recesses/
protrusions 2..., 2'... have to be formed, there are various conditions or requirements for such substrates 1, 1'.
For instance, they are required to be (1) transparent, (2) optically isotropic and, in particular, small in bire-fringence, (3) flat with little indication of warping or waviness and (4) easy to form the recesses and/or protru-sions. Furthermore, various requirements are made for the substrates 1, 1' also relating to the recording films 3, 3':
for instance, they are required to have a high heat resistance if the method of forming the recording films 3, 3' requires heating, and if the films 3, 3' are required to be moisture-proof, they are required to have a low moisture permeability and low water absorption.
Recently, therefore, study has been made of the possi-bility of using as the aforementioned substrates 1, 1' those of polycarbonate resin made by injection molding(hereinafter called "PC substrate").
Even the aforementioned PC substrate made by injection 13166~3 molding tends to be high in birefringence and, when the recording film 3 is formed thereon to make it the optical recording substrate 4, it tends to warp with the side covered with the recording film 3 convex, as shown in Fig.
5. This phenomenon of the optical recording substrate 4 warping with the side covered with the recording film 3 convex is due to the difference in thermal expansion coefficient between the recording film 3 and the PC
substrate 1 and, if the temperature is raised at the time of forming the recording film 3, the dimensions of the PC
substrate 1 becomes smaller than that of the recording film 3.
Also, when an optical recording medium is made by bond-ing together the optical recording substrates 4, 4', such an optical recording medium is constantly subject to some degree of stress. When the optical recording medium so prepared is subjected to sudden changes in temperature, exfoliation of recording film 3 from substrate 1, or of each substrate 1, 1' takes place in the optical recording medium, this affecting the reliability of the optical recording medium.
SUMMARY OF THE INVENTION
It is a primary object of the present invention to provide a highly reliable optical recording medium, substrates forming it being safe from warping and even when 1~16~03 the optical recording medium as such is subjected to sudden changes in temperature or the like, there is no risk of exfoliation of a recording film et cetera, and manufacturing method thereof.
Another object of the present invention is to provide a kind of optical recording medium which can be manufactured with emphasis on the optical quality or performance required of a transparent protective plate as well as its protective effect, the carrier-to-noise ratio and optical isotropy, in particular, and manufacturing method thereof.
In order to accomplish the aforementioned objects, the present invention relates to an optical recording medium, comprising a center substrate, of whose both sides at least either has recesses and/or protrusions formed therein, recording films formed on both sides thereof and transparent protective plates stuck to these recording films res-pectively.
The aforementioned center substrate may possibly be an injection-molded sheet of polycarbonate (hereinafter called "PC") resin. It may also be a synthetic resin sheet formed by casting.
Meanwhile, the aforementioned transparent protective plate may possibly be an extrusion-molded sheet of PC resin. It may as well be made of glass.
Further, the aforementioned center substrate and trans-~ 3 ~ 3 parent protective plate may be formed of materials similarin thermal expansion coefficient.
Further still, the aforementioned center substrate is an injection-molded PC resin sheet, while the transparent protective plate may be a PC sheet molded by extrusion.
The method of manufacturing the aforementioned optical recording medium comprises the steps of first preparing the center substrate with recesses and/or protrusions formed at least on one side and, after forming the recording films on both sides, sticking the transparent protective plate to the recording films respectively.
As the method of forming recesses and/or protrusions on the center substrate in the manufacturing process of the aforementioned optical recording medium, it is also possible to form recesses and/or protrusions on both sides of the center substrate simultaneously by the use of a pair of stampers attached to the die, at the time the center substrate is formed by injection molding.
Also, for forming recesses and/or protrusions on the center substrate in the process of manufacturing the aforementioned optical recording medium a method of first sheeting the material by extrusion molding and then placing it between a pair of stampers attached to the dies and pressing from both sides to thereby forming recesses and/or protrusions simultaneously is available.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1(a) is a vertically-sectioned front view of the ce!nter substrate of an optical recording medium having formed on both sides thereof recesses and/or protrusions such as grooves.
Fig. 1(b) is another vertically-sectioned front view of the center substrate of the optical recording medium having formed recording films on both sides thereof.
Fig. 1(c) is still another vertically-sectioned front view of the center substrate of the optical recording medium with recording films formed on both sides thereof and transparent protective layers are stuck to the recording films with each one layer of transparent adhesive there-between.
Fig. 2 is a diagram showing the relationship between the length of optical recording bit and the carrier-to-noise ratio for the optical recording medium when as the transparent protective plate (1) glass base plate is used, (2) extrusion-molded PC (polycarbonate) plate is used, and (3) injection-molded PC plate is used respectively.
Fig. 3 is another diagram showing the relationship between the rotation angle of the transparent protective plate and the difference in refractive index in the direction along the plate and the direction vertical thereto when as the transparent protective plate (1) extrusion-131~603 molded PC plate is used and (2) injection-molded PC plate is used respectively.
Fig. 4(a) is a vertically-sectioned front view of the substrate of a conventional optical recording medium with recesses and/or protrusions such as grooves formed on one side thereof.
Fig. 4(b) is another vertically-sectioned front view of the substrate of the same conventional optical recording medium with a recording film formed on the side with recesses and/or protrusions.
Fig. 4(c) is still another vertically-sectioned front view showing two stuck-together substrates of the conventio-nal optical recording medium, each substrate having formed thereon a recording film.
Fig. 5 is a vertically-sectioned front view showing the warped substrate of the optical recording medium.
DESCRIPTION OF THE EMBODIMENTS
A preferred embodiment of the present invention is described below with reference being made to Figs. 1 through 3.
In the optical recording medium of the present inven-tion, as shown in Fig. 1(c), a center substrate 11 has formed on both sides thereof recesses and/or protrusions 12... such as grooves and pits and recording films 13, 13 are formed integrally to cover these recesses and/or 13166~3 protrusions 12... . On the recording films 13, 13 there are formed transparent adhesive layers 14, 14 and transparent protective plates 15, 15 are securely bonded thereby.
The process of manufacturing the optical recording medium described above comprises the steps of first forming recesses and/or protrusions 12... , as shown in Fig. 1~a), and then forming the recording films 13, 13 by spattering et cetera as shown in Fig. 1(b).
As recording films 13, 13, magneto-optical recording medium films formed as a laminate of 4 layers, namely Al/AlN/(Gdo~6 Tb 0~4 ) 0,28 Fe 0~2/AlN, et cetera is available Of course, this means no limitation, and besides GdTbFe type as such, magneto-optical recording medium in film form made of some other material or even recording medium film of phase change type using Te ~type utilizing crystalline-amorphous phase change) is available.
Then, a transparent adhesive is applied on the afore-mentioned recording films 13, 13 for formation of adhesive layers 14, 14, and the transparent protective plates 15, 15 are securely bonded thereby. As the aforementioned adhesive is applied an ultraviolet ray curing resin or the like.
According to the aforementioned composition, the recording films 13, 13 are formed on both sides of the center substrate 11, hence with the recording films 13, 13 formed on the center substrate 11 warping of the center 131g6~3 substrate 11 can be prevented.
Since the recording films 13, 13 are equal or closely similar in thermal expansion coefficient, they are deemed equal in dimensional change due to changes in te~perature.
Hence, even if the dimensions of these recording films 13, 13 should be different from those of the above center substrate 11, the force resulting from this difference in dimensions acts on the center substrate 11 from both sides thereof at equal magnitudes. If forces of equal magnitudes act on both sides of the center substrate 11, these forces are offset, this resulting in no warping of the aforementioned center substrate 11.
As to the aforementioned transparent preventive plates 15, 15, there is no necessity of forming the recesses and/or protrusions 12..., it is, therefore, not necessary to take the ease of formation of recesses and/or protrusions into consideration. Hence, the range of materials to choose from, is that much increased, this enabling selection of materials with emphasis on optical performance and protective function required of the transparent protective plate 15.
Although in this embodiment, the recesses and/or protrusions 12... are formed on both sides of the center substrate 11, formation of the aforementioned recesses and/or protrusions 12... can be made by means of a pair of i316603 stampers attached to the die/s, in case the center substrate 11 is a polycarbonate (hereinafter called "PC") substrate macle by injection molding.
This way, the trouble of doing center alignment of grooves each time can be dispensed with when 2 sheets of optical recording substrate are bonded together~ That is, by doing position adjustment of the aforementioned stamper in advance, center alignment of grooves formed on both sides of the center substrate is easily feasible and, moreover, if this- center alignment of grooves is done once, reproduced center substrate 11 with grooves is bound to have the identical groove center.
Thus, if the groove's centers can be aligned on both sides, the equilibrium error possibly occurring when the optical recording medium is set on the player and rotated can be easily eliminated or minimized.
By the way, it is not always necessary that the afore-mentioned center substrate 11 must be transparent, and as its material can be used, besides the aforementioned PC
substrate, also ABS resin, melamine resin, glass, ceramics et cetera. As to the method of preparing the center substrate 11, extrusion molding, casting et cetera are applicable in addition to injection molding, and the epoxy resin plate or acrylic resin plate molded by the casting method are well usable as materials of the center substrate 131~603 The signal quality of the optical recording medium, for in!;tance, the relationship between the recording bit length and the carrier-to-noise ratio was measured using as the aforementioned transparent protective plates 15, 15 (1) glass plate, (2) extrusion-molded PC plate and (3) injection-molded PC plate, and the result was as shown in Fig. 2.
According to the measured data, the optical recording medium using an extrusion-molded PC plate was comparable with that using glass plate in carrier-to-noise ratio, and the former turned out to be extremely suited as material of transparent protective plate 15. Meanwhile, the optical recording medium using injection-molded PC plate was lower in carrier-to-noise ratio than that with glass plate, the former not necessarily suitable as the transparent protective plate 15.
There is a difference between an extrusion-molded PC
plate and an injection-molded counterpart also in a difference in refractive index in the direction along the plate and the direction vertical thereto (hereinafter called "vertical birefringence"), as shown in Fig. 3. That is, an extrusion-molded PC plate is smaller in vertical birefringence, and superior in optical isotropy to an injection molded counterpart. With glass plate birefrin-131~3 gence was practically noticeable.
Further, there is also a difference between anextrusion-molded and injection-molded PC plates ln the ease of forming the recesses and/or protrusions 12... , this being attributable to the difference in the method of manufacture. And in this respect an injection-molded PC
plate is superior, that is, easier for formation thereof than an extrusion-molded counterpart.
For the reasons as described above, an ideal optical recording medium is obtainable by using an injection-molded PC plate as the center substrate 11 in which the recesses and/or protrusions are formed and by using an extrusion-molded PC plate as the transparent protective plate 15, 15 which is required to be superior in optical isotropy. This also contributes to the desired reduction in inside stress of the optical recording medium for an extrusion-molded PC
plate and an injection-molded counterpart are similar in thermal expansion coefficient.
Needless to say, the aforementioned center substrate 11 need not necessarily be an injection-molded PC plate, and an extrusion-molded counterpart may be used instead. In order to form the recesses andtor protrusions 12... in an extrusion-molded PC plate the PC plate is placed between a pair of patterned dies and then pressed inward from both sides. When the temperature is kept at approximately 100C, the aforementioned recesses and/or protrusions 12... such as grooves can well be transferred onto the plate.
The optical recording medium of the present invention need not necessarily be disk-shaped, and may be formed as a card or the like as well.
As described above, the present invention relates to an optical recordinq medium comprising a center substrate with recesses and/or protrusions formed on at least either of its both sides and recording films formed on both sides of the center substrate, transparent protective plates stuck to the recording films respectively.
The aforementioned center substrate may possibly be of PC resin made by injection molding.
This center substrate may also be of a synthetic resin made by cast molding.
The aforementioned transparent protective plate may possibly be of PC resin made by extrusion molding.
This transparent protective plate may also be of glass.
Further, the aforementioned center substrate and trans-parent protective plate may possibly be made of materials similar in thermal expansion coefficient.
Further still, it is also possible to have the afore-mentioned center substrate made of PC resin by injection molding, while using a extrusion-molded PC resin as the aforementioned transparent protective plate.
13l66o3 The method for manufacture of the aforementioned optical recording medium comprises the steps of first making the center substrate having formed recesses and/or protrusions on at least either of both sides thereof, then forming the recording films on both sides of the center substrate and thereafter sticking the transparent protective plates to the recording films respectively.
In the aforementioned process for manufacture of the optical recordi-ng substrate the recesses and/or protrusions may possibly be formed on both sides of the center substrate by means of a pair of stampers attached to the die in the course of injection molding.
In the aforementioned manufacturing process the recesses and/or protrusions may also be formed on both sides of the center substrate by first by preparing a material plate by extrusion molding, then placing it between a pair of dies and pressing inward from both sides.
This way, it is possible to obtain a highly reliable optical recording medium, which is prevented from warping of the substrates constituting the optical recording medium, and thus safe from exfoliation of the recording film or the like, even when the optical recording medium is subjected to sudden changes in temperature or the like.
Further, in selecting the trans?arent protective plate, emphasis may be placed on the optical performance and pro-.
,,, ,.-.~ . . .
-13~03 tective effect required of a transparent protective plate re~ardless of the ease of forming recesses and/or protrusions such as grooves, hence a marked improvement in carrier-to-noise ratio, isotropy and the like can well be hoped for.
Further still, the relative positional precision of the recesses and/or protrusions formed on both sides of the center substrate can be easily improved.
Claims (10)
1. An optical recording medium, comprising a center substrate, of whose both sides at least either has recesses and/or-protrusions formed therein, recording films formed on both sides thereof and transparent protective plates stuck to these recording films respectively.
2. An optical recording medium according to claim 1, wherein said center substrate is of polycarbonate resin formed by injection molding.
3. An optical recording medium according to claim 1, wherein said center substrate is of a synthetic resin formed by cast molding.
4. An optical recording medium according to claim 1, wherein said transparent protective plate is of polycarbonate resin formed by extrusion molding.
5. An optical recording medium according to claim 1, wherein said transparent protective plate is made of glass.
6. An optical recording medium according to claim 1, wherein said center substrate and said transparent protective plate are made of materials similar in thermal expansion coefficient.
7. An optical recording medium according to claim 6, wherein said center substrate is of polycarbonate resin formed by injection molding, while said transparent pro-tective plate is of polycarbonate resin formed by extrusion molding.
8. A method of manufacturing an optical recording medium comprising the steps of first preparing a center substrate with recesses and/or protrusions formed at least on one side thereof, then forming recording films on both sides of said substrate and thereafter sticking transpa-rent, protective plates to said recording films respectively
9. A method of manufacturing an optical recording medium according to claim 8, wherein said center substrate is made by injection molding and in the course of said injection molding recesses and/or protrusions are formed by means of a pair of stampers attached to the die on both sides of said center substrate simultaneously.
10. A method of manufacturing an optical recording medium according to claim 8, wherein a material is first formed as a plate by extrusion molding and placing this material plate between a pair of dies and pressing inward from both sides to thereby form said recesses and/or protrusions on both sides of said center substrate simultaneously.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3212388A JP2680591B2 (en) | 1988-02-15 | 1988-02-15 | Method for manufacturing optical memory device |
| JP63-32123 | 1988-02-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1316603C true CA1316603C (en) | 1993-04-20 |
Family
ID=12350107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 590987 Expired - Lifetime CA1316603C (en) | 1988-02-15 | 1989-02-14 | Optical recording medium and manufacturing method thereof |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5059473A (en) |
| EP (1) | EP0329425B1 (en) |
| JP (1) | JP2680591B2 (en) |
| CA (1) | CA1316603C (en) |
| DE (1) | DE68914490T2 (en) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04149834A (en) * | 1990-10-12 | 1992-05-22 | Pioneer Electron Corp | Phase transition type optical information recording medium |
| US5202880A (en) * | 1992-03-06 | 1993-04-13 | Digital Equipment Corporation | Double-sided magneto-optical media for a multi-disk storage device |
| US5470627A (en) * | 1992-03-06 | 1995-11-28 | Quantum Corporation | Double-sided optical media for a disk storage device |
| US5467327A (en) * | 1993-12-22 | 1995-11-14 | Jamail; Randall | Method of masking data on a storage medium |
| US5471443A (en) * | 1993-12-22 | 1995-11-28 | Randall Jamail | Method of selectively concealing magneto-optical compact disk data for playback upon demand |
| US5808974A (en) * | 1993-12-22 | 1998-09-15 | Jamail; Randall H. | Method of masking data on a storage medium using a directory |
| US5488597A (en) * | 1994-04-19 | 1996-01-30 | Alan G. Chen | Multilayer optical memory with means for recording and reading information |
| DE69520920T2 (en) * | 1994-10-03 | 2001-09-27 | Matsushita Electric Ind Co Ltd | Optical information medium, as well as unit and method for its production |
| USRE39412E1 (en) | 1995-02-15 | 2006-11-28 | Matsushita Electric Industrial Co., Ltd. | Optical information medium, and method and apparatus for fabricating the same |
| US6676791B1 (en) * | 1995-03-24 | 2004-01-13 | Jvc Victor Company Of Japan, Ltd. | Multilayered optical information-recording media and process for manufacture thereof |
| JP3351164B2 (en) * | 1995-03-24 | 2002-11-25 | 日本ビクター株式会社 | Method for manufacturing optical information recording medium |
| US5764619A (en) | 1995-04-07 | 1998-06-09 | Matsushita Electric Industrial Co., Ltd. | Optical recording medium having two separate recording layers |
| JPH09180251A (en) * | 1995-12-22 | 1997-07-11 | Pioneer Electron Corp | Disk substrate, metal mold for molding the same, and optical disk |
| JPH113541A (en) * | 1997-06-11 | 1999-01-06 | Sony Corp | Optical disk and manufacture thereof |
| US5922430A (en) * | 1998-04-02 | 1999-07-13 | Biddlecome; Robert L. | Compact disk protector |
| JPH11296904A (en) * | 1998-04-03 | 1999-10-29 | Toshiba Corp | Information recording medium and manufacture of resin substrate used for the same |
| EP1166264A1 (en) | 1999-02-12 | 2002-01-02 | General Electric Company | Data storage media |
| TW559800B (en) * | 2001-11-27 | 2003-11-01 | Ind Tech Res Inst | Manufacturing method for multi-layer information storage medium |
| TWI297493B (en) * | 2002-09-09 | 2008-06-01 | Ind Tech Res Inst | Double-sided high-density information storage medium |
| TWI233936B (en) * | 2003-11-07 | 2005-06-11 | Ind Tech Res Inst | Polymer material applied to be signal recording layer of multi-layer information storage medium |
| US20050238145A1 (en) * | 2004-04-22 | 2005-10-27 | Sbc Knowledge Ventures, L.P. | User interface for "how to use" application of automated self service call center |
| JP2005332480A (en) * | 2004-05-19 | 2005-12-02 | Fuji Photo Film Co Ltd | Optical information recording carrier |
| US20060177622A1 (en) * | 2005-02-08 | 2006-08-10 | Wu-Hsuan Ho | Structure of double-side optical storage medium |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2306496A1 (en) * | 1975-04-02 | 1976-10-29 | Thomson Brandt | Optical recording disc mfr. - uses vacuum deposition of metallised layer onto thin thermoplastics sheet |
| US4179532A (en) * | 1976-04-09 | 1979-12-18 | Polygram Gmbh | Process for producing a disc-shaped information carrier which has information in the form of a beam-reflecting structure |
| US4268369A (en) * | 1977-07-18 | 1981-05-19 | Ampex Corporation | Process of making silicon dioxide films for use as wear resistant coatings in video and digital magnetic recording |
| US4363844A (en) * | 1980-09-22 | 1982-12-14 | Lewis Terry W | Metallized information carrying discs |
| US4544443A (en) * | 1983-05-13 | 1985-10-01 | Shap Kabushiki Kaisha | Method for manufacturing an optical memory element |
| JPS60155424A (en) * | 1984-01-26 | 1985-08-15 | Daicel Chem Ind Ltd | Large diameter optical disc substrate made of polycarbonate and its preparation |
| DE3583754D1 (en) * | 1984-03-16 | 1991-09-19 | Sharp Kk | METHOD FOR PRODUCING AN OPTICAL STORAGE ELEMENT. |
| EP0166614A3 (en) * | 1984-06-29 | 1987-12-23 | Minnesota Mining And Manufacturing Company | Encoated optical recording medium |
| JPS6124039A (en) * | 1984-07-12 | 1986-02-01 | Pioneer Electronic Corp | Information recording disc and its manufacture |
| NL8402681A (en) * | 1984-09-03 | 1986-04-01 | Philips Nv | OPTICALLY READABLE INFORMATION DISC AND METHOD FOR MANUFACTURING IT. |
| JPS62185264A (en) * | 1986-02-12 | 1987-08-13 | Fuji Photo Film Co Ltd | Information recording medium |
| JPS6429530U (en) * | 1987-08-14 | 1989-02-22 |
-
1988
- 1988-02-15 JP JP3212388A patent/JP2680591B2/en not_active Expired - Lifetime
-
1989
- 1989-02-09 US US07/308,018 patent/US5059473A/en not_active Expired - Lifetime
- 1989-02-14 CA CA 590987 patent/CA1316603C/en not_active Expired - Lifetime
- 1989-02-15 EP EP19890301463 patent/EP0329425B1/en not_active Expired - Lifetime
- 1989-02-15 DE DE1989614490 patent/DE68914490T2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5059473A (en) | 1991-10-22 |
| DE68914490D1 (en) | 1994-05-19 |
| JPH01208742A (en) | 1989-08-22 |
| DE68914490T2 (en) | 1994-11-24 |
| EP0329425A3 (en) | 1990-10-10 |
| EP0329425A2 (en) | 1989-08-23 |
| JP2680591B2 (en) | 1997-11-19 |
| EP0329425B1 (en) | 1994-04-13 |
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