CA2015489A1 - Process for producing and use of maleic acid (co-) polymer salt improved in biodegradability - Google Patents

Process for producing and use of maleic acid (co-) polymer salt improved in biodegradability

Info

Publication number
CA2015489A1
CA2015489A1 CA2015489A CA2015489A CA2015489A1 CA 2015489 A1 CA2015489 A1 CA 2015489A1 CA 2015489 A CA2015489 A CA 2015489A CA 2015489 A CA2015489 A CA 2015489A CA 2015489 A1 CA2015489 A1 CA 2015489A1
Authority
CA
Canada
Prior art keywords
maleic acid
biodegradability
specially defined
polymer salt
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2015489A
Other languages
French (fr)
Other versions
CA2015489C (en
Inventor
Shigeru Yamaguchi
Tokihiro Yokoi
Shorbu Shioji
Yoshio Irie
Teruaki Fujiwara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Shokubai Co Ltd
Original Assignee
Nippon Shokubai Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Shokubai Co Ltd filed Critical Nippon Shokubai Co Ltd
Publication of CA2015489A1 publication Critical patent/CA2015489A1/en
Application granted granted Critical
Publication of CA2015489C publication Critical patent/CA2015489C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/14Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/02Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid

Abstract

A specially defined amount of hydrogen peroxide is used as a polymerization catalyzer and, under a condition of that a specially defined amount and a specially defined kind of a polyvalent metal ion and a specially defined amount of an alkaline substance exist, only maleic acid or a monomer component composed of maleic acid and the other water-soluble unsaturated monomer in a specially defined proportion is polymerized in water, whereby a maleic acid ( co-)polymer salt improved in biodegradability is produced.
The maleic acid (co-)polymer salt obtained is superior in biodegradability and little in amount of a residual monomer and useful as a detergent builder and a scale inhibitor etc.
CA002015489A 1989-04-28 1990-04-26 Process for producing and use of maleic acid (co-) polymer salt improved in biodegradability Expired - Fee Related CA2015489C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP10720089 1989-04-28
JP1-107200 1989-04-28

Publications (2)

Publication Number Publication Date
CA2015489A1 true CA2015489A1 (en) 1990-10-28
CA2015489C CA2015489C (en) 1996-11-19

Family

ID=14453022

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002015489A Expired - Fee Related CA2015489C (en) 1989-04-28 1990-04-26 Process for producing and use of maleic acid (co-) polymer salt improved in biodegradability

Country Status (6)

Country Link
US (1) US5064563A (en)
EP (1) EP0396303B1 (en)
JP (1) JPH0627136B2 (en)
CA (1) CA2015489C (en)
DE (1) DE69015424T2 (en)
ES (1) ES2069004T3 (en)

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Also Published As

Publication number Publication date
EP0396303A2 (en) 1990-11-07
DE69015424T2 (en) 1995-08-17
EP0396303B1 (en) 1994-12-28
JPH0372502A (en) 1991-03-27
JPH0627136B2 (en) 1994-04-13
DE69015424D1 (en) 1995-02-09
ES2069004T3 (en) 1995-05-01
EP0396303A3 (en) 1991-04-24
CA2015489C (en) 1996-11-19
US5064563A (en) 1991-11-12

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