CA2038099C - Clear antiperspirant stick - Google Patents

Clear antiperspirant stick Download PDF

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Publication number
CA2038099C
CA2038099C CA002038099A CA2038099A CA2038099C CA 2038099 C CA2038099 C CA 2038099C CA 002038099 A CA002038099 A CA 002038099A CA 2038099 A CA2038099 A CA 2038099A CA 2038099 C CA2038099 C CA 2038099C
Authority
CA
Canada
Prior art keywords
composition
emollient
amount
stabilizing compound
amino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002038099A
Other languages
French (fr)
Other versions
CA2038099A1 (en
Inventor
Chung T. Shin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Signal Investment and Management Co
Original Assignee
Signal Investment and Management Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Signal Investment and Management Co filed Critical Signal Investment and Management Co
Publication of CA2038099A1 publication Critical patent/CA2038099A1/en
Application granted granted Critical
Publication of CA2038099C publication Critical patent/CA2038099C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/0229—Sticks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/26—Optical properties
    • A61K2800/262—Transparent; Translucent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A61K2800/31—Anhydrous

Abstract

The invention provides stable, substantially anhydrous, transparent, gelled, antiperspirant sticks which are substantially free of lower monohydroxy alcohols, contain dibenzylmonsorbitol acetal as a gelling agent and are stabilized by the presence of a weakly basic, organic, nitrogen containing, stabilizing compound soluble in the composition employed to produce the stick.

Claims (10)

1. A stable, substantially anhydrous, transparent, gelled, antiperspirant composition substantially free of lower monohydroxy alcohol comprising by weight, based on total weight of the composition;
a. an antiperspirant amount of an acidic antiperspirant soluble in the composition, b. from about 25% to about 90% of a dihydric alcohol solvent containing from 3 to 6 carbon atoms, c. an amount of dibenzylmonosorbitol acetal sufficient to gel the composition, d. 0 to 20% of N-methyl-2-pyrrolidone, e. 0 to 30% of an emollient, and f. from about 0.5% to about 20% of a weakly basic organic nitrogen containing stabilizing compound which is soluble in the composition and has a pKb of from about 3.4 to 13.9, the amount of the stabilizing compound present being sufficient to render the composition stable.
2. A composition as in claim 1, wherein the stabilizing compound is selected from the group consisting of urea, imidazole, 2-amino-2-hydroxymethyl-1,3-propanediol, 2-amino-2-methyl-1-propanol and N,N-tetrakis-2-hydroxypropyl-ethylene diamine.
3. A composition as in claim 2, wherein the stabilizing compound is 2-amino-2-hydroxymethyl-1,3-propane diol, and such compound is present in an amount of from about 0.5% to about 2%.
4. A composition as in claim 2, wherein the emollient is represented by the formulae wherein R is hydrogen or a straight or branched hydrocarbon group containing from 1 to 18 carbon atoms, x and y are integers which are independently from about 2 to about 25.
5. A composition as in claim 4, wherein x is from about 2 to about 5, and y is from about 2 to about 20.
6. A composition of claim 4, wherein the value of is less than or equal to 0.5.
7. A composition of claim 4, wherein R is a branched hydrocarbon group.
8. A composition of claim 4, wherein R is isostearyl.
9. A composition of claim 1, containing from about 3% to about 20% of the emollient.
10. A composition of claim 1 containing from about 3% to about 20% of an emollient selected from the group consisting of isosteareth 2, PPG-3-isosteareth-9 and PEG-7-glyceryl cocoate.
CA002038099A 1990-04-04 1991-03-12 Clear antiperspirant stick Expired - Fee Related CA2038099C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US50449490A 1990-04-04 1990-04-04
US504,494 1990-04-04

Publications (2)

Publication Number Publication Date
CA2038099A1 CA2038099A1 (en) 1991-10-05
CA2038099C true CA2038099C (en) 2002-01-15

Family

ID=24006510

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002038099A Expired - Fee Related CA2038099C (en) 1990-04-04 1991-03-12 Clear antiperspirant stick

Country Status (10)

Country Link
US (1) US5405605A (en)
EP (1) EP0451002B1 (en)
JP (1) JP3072602B2 (en)
AU (1) AU634643B2 (en)
CA (1) CA2038099C (en)
DE (1) DE69112249T2 (en)
GR (1) GR3018114T3 (en)
NZ (1) NZ237585A (en)
TW (1) TW198687B (en)
ZA (1) ZA911953B (en)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU1990492A (en) * 1991-05-06 1992-12-21 Procter & Gamble Company, The Acid stable gel stick antiperspirant compositions and process for making them
US5270034A (en) * 1992-04-14 1993-12-14 Cheng Guang Yu Translucent antiperspirant stick composition
DE4229707A1 (en) * 1992-09-05 1994-03-10 Beiersdorf Ag Germicide drug combinations
GB2280111B (en) * 1993-07-16 1997-05-07 Union Camp Corp Clear gel antiperpirant compositions
US5490979A (en) * 1994-01-07 1996-02-13 The Mennen Company Clear antiperspirant stick gelled with dibenzylidene sorbitol and containing a guanidine compound as gel stabilizer, and process of making same
US5610199A (en) * 1994-03-22 1997-03-11 Estee Lauder Inc. Solid lipophilic composition and process for its preparation
US5725846A (en) * 1995-03-02 1998-03-10 The Gillette Company Clear antiperspirant stick containing dibenzylidene alditol and hydroxyalkyl cellulose
NZ305082A (en) * 1995-03-02 1999-10-28 Gillette Co A clear antiperspirant stick containing dibenzylidene alditol
US5709852A (en) * 1995-12-05 1998-01-20 Basf Corporation Ethylene oxide/propylene oxide/ethylene oxide (EO/PO/EO) triblock copolymer carrier blends
US5723135A (en) * 1996-02-06 1998-03-03 The Gillette Company One-phase process for making a clear antiperspirant stick containing dibenzylidene alditol
US5939055A (en) * 1996-02-29 1999-08-17 The Gillette Company Clear antiperspirant stick containing dibenzylidene alditol
DE19707309B4 (en) * 1997-02-11 2004-08-12 Lancaster Group Gmbh Solid cosmetic compositions based on solidified oils
US5827813A (en) * 1997-02-28 1998-10-27 Procter & Gamble Company Detergent compositions having color care agents
US5804547A (en) * 1997-02-28 1998-09-08 The Procter & Gamble Company Dryer-activated laundry additive compositions with color care agents
US5874396A (en) * 1997-02-28 1999-02-23 The Procter & Gamble Company Rinse added laundry additive compositions having color care agents
US5964691A (en) * 1997-08-01 1999-10-12 Milliken & Company Composition useful for gelled cosmetic stick
US5858336A (en) * 1997-10-10 1999-01-12 Avon Products, Inc. Clear stick deodorant
US5871720A (en) * 1997-11-20 1999-02-16 Colgate-Palmolive Company Cosmetic compositions with DBS and functionalized silicones
US6180125B1 (en) 2000-02-18 2001-01-30 Colgate-Palmolive Company Low tack cosmetic composition sticks
US6358499B2 (en) 2000-02-18 2002-03-19 Colgate-Palmolive Company Deodorant with small particle zinc oxide
US6338841B1 (en) 2001-07-19 2002-01-15 Colgate-Palmolive Company Antiperspirant product with dibenzylidene sorbitol and elastomer in dimethicone
CN1966090B (en) * 2005-11-18 2012-09-05 花王株式会社 Deodorant compositions
JP5038656B2 (en) * 2005-11-18 2012-10-03 花王株式会社 Deodorant composition
JP5038632B2 (en) * 2006-02-08 2012-10-03 花王株式会社 Deodorant composition
JP5139639B2 (en) * 2006-03-03 2013-02-06 花王株式会社 Deodorant composition
JP5139645B2 (en) * 2006-05-08 2013-02-06 花王株式会社 Deodorant composition
JP5197968B2 (en) * 2007-02-07 2013-05-15 花王株式会社 Deodorant composition
CN102933196B (en) * 2010-06-09 2016-04-13 花王株式会社 Cosmetic composition
US8668918B2 (en) 2011-09-01 2014-03-11 Milliken & Company Bisurea gelling agents and compositions
CN109288720A (en) * 2017-07-24 2019-02-01 刘崇庆 Deodorant compositions and preparation method thereof

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US3420932A (en) * 1966-12-20 1969-01-07 Armour Pharma Methods of making alcohol soluble complexes of aluminum and preparations employing the complexes
US3630896A (en) * 1968-07-12 1971-12-28 Hideto Oka Agricultural chemical composition in solid or jelly form
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US4108977A (en) * 1975-03-12 1978-08-22 Colgate-Palmolive Company Method of producing improved antiperspirant composition
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Also Published As

Publication number Publication date
JP3072602B2 (en) 2000-07-31
TW198687B (en) 1993-01-21
GR3018114T3 (en) 1996-02-29
ZA911953B (en) 1991-11-27
DE69112249T2 (en) 1996-01-25
US5405605A (en) 1995-04-11
EP0451002A2 (en) 1991-10-09
NZ237585A (en) 1993-04-28
DE69112249D1 (en) 1995-09-28
AU634643B2 (en) 1993-02-25
EP0451002B1 (en) 1995-08-23
EP0451002A3 (en) 1992-08-26
CA2038099A1 (en) 1991-10-05
JPH0597641A (en) 1993-04-20
AU7403591A (en) 1991-10-10

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