CA2040537C - Colored retroreflective sheeting and method for making same - Google Patents
Colored retroreflective sheeting and method for making sameInfo
- Publication number
- CA2040537C CA2040537C CA002040537A CA2040537A CA2040537C CA 2040537 C CA2040537 C CA 2040537C CA 002040537 A CA002040537 A CA 002040537A CA 2040537 A CA2040537 A CA 2040537A CA 2040537 C CA2040537 C CA 2040537C
- Authority
- CA
- Canada
- Prior art keywords
- microprisms
- coating
- face
- accordance
- retroreflective
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00605—Production of reflex reflectors
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/10—Decorating textiles by treatment with, or fixation of, a particulate material, e.g. mica, glass beads
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
Abstract
A retroreflective material providing a visual coloration includes a body member with microprisms on its rear surface.
Some of the microprisms have a retroreflective interface and the remainder have a colored non-reflective coating thereon.
As a result, light rays entering the front face which impinge upon the prisms with the retroreflective interface are redirected so that they exit the material in a parallel path.
Light rays which travel to the color coated prisms are refracted from those prisms and impart a visual coloration to the material in daylight and ambient light.
Some of the microprisms have a retroreflective interface and the remainder have a colored non-reflective coating thereon.
As a result, light rays entering the front face which impinge upon the prisms with the retroreflective interface are redirected so that they exit the material in a parallel path.
Light rays which travel to the color coated prisms are refracted from those prisms and impart a visual coloration to the material in daylight and ambient light.
Description
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The present invention relates to retroreflective sheeting employing microprism formations to retroreflect the light rays impinging thereon, and, more particularly, to a method for producing such retroreflective sheet material which provides a bright coloration in daylight and ambient light and which is also highly retroreflective when exposed to light beams at night.
Retroreflective sheet material is widely employed for a variety of safety and decorative purposes, and is particularly useful when the need for night time visibility i8 significant under conditions of low ambient light. In retroreflective materials, the light rays impinging upon the front surface are reflected back towards the source of the illumination in a substantially parallel path. In situations where headlights or search lights on boats and aircraft are the only source of illumination, this ability to retroreflect the bulk of the rays falling thereon is especially significant for warning signs, delineators and the like.
Minnesota Mining and Manufacturing Corporation has manufactured retroreflective sheeting utilizing minute glass beads embedded in a matrix of synthetic resin to provide such retroreflection, and these materials have been sold under the trademark SCOTCHLITE. Illustrative of such materials is Bergeson et al United States Letters Patent 4,637,950 granted January 20, 1987.
Applicant's assignee, Reflexite Corporation, has been marketing under the trademark REFLEXITE, reflective sheeting employing microprisms formations to produce such retroreflection. Illustrative of such materials is Rowland .
~ ~ United States Letters Patent 3,689,346 granted September 5, - 1972.
~ -2-- - - - - - -In Martin United States Patent No. 4,801,193 granted January 31, 198g, there is described in detail a process for producing grid patterns of metallized and unmetallized pri~ms, and the use of adhesive spacing to provide an air backing about prisms.
Among the applications for such retroreflective materials are reflective tapes and patches for clothing of firemen, reflective vests and belts, bands for posts and barrels, traffic cone collars, highway signs, warning reflectors, and i 10 the like.
It is desirable for some applications that the retroreflective sheeting exhibit a bright coloration in daylight and ambient light, such as the red and yellow/green used for warning and emergency. In Rowland United States Letters Patent No. 3,830,682 granted August 20, 1974, a metameric dye is included so that the sheet material fluoresces in one color in daylight and retroreflects in a second coloration when exposed to headlights and other directional light sources at night.
The use of a metallized aluminum coating on the prism ., . ~ , surfaces tends to produce a grey coloration to the observer in ambient light or daylight conditions. In some applications, ~ this grey appearance is considered aesthetically undesirable, - and coloration would be desirable.
'~ It is an object of the present invention to provide a novel retroreflective sheeting using microprism formations which exhibits a bright coloration in daylight and high -::
retroreflectivity at night when exposed to directional light sources.
It is also an object of the present invention to provide ;;
such a colored retroreflective sheet material which may be : ;J . ,r' 5 ~ ~ ~
readily fabricated and which is durable and resistant to the elements.
Another object of the present invention is to provide novel methods for fabricating such retroreflective sheet material which are relatively simple and relatively economical, and which produce long-lived materials.
It has now been found that the foregoing and related objects and advantages may be readily attained in a retroreflective material which has a body member of transparent synthetic resin with a first planar face and a second face with closely spaced microprisms thereover.
Suitable means provides a reflective interface for the microprism in a pattern over the expanse of the second face, and a colored non-reflective coating is disposed on the surfaces of the microprisms between those in the pattern. The microprisms with the reflective interface Comprise 40-85 percent of the total surface area of the second face so that light rays impinging on the first planar face and thereafter directed upon the reflective interfaces of the microprisms are retroreflected thereby in the direction from which they came.
Those impinging upon the coated microprisms are refracted therefrom with the coloration of the coating in daylight and also in diffuse light.
In one embodiment, the body member has a reflective metallic layer on the uncoated microprisms to provide the reflective interface, and this may include a deposit of protective material on the metallic layer. The colored coating may extend over the deposit. In another embodiment, the uncoated microprisms have an air interface about substantially their entire surface.
Generally, there is a backing member disposed over the , coated and uncoated microprisms, and the material of the coating has adhesive properties so that the backing member i8 adhered thereto. The coating may extend to a distance above the microprisms and provide a spacer for the backing member to position it above the uncoated microprisms, and thereby provide an air interface thereabout.
In one method for making a colored retroreflective -~1 material, a retroreflective body member is provided which has ~' 10 a planar first face and a second face with closely spaced microprisms thereover. A reflective aeposit is formed on the surface of the microprisms in a pattern extending over the v second face and covering 40-85 percent of the total area of ~, the second face. On the surface of the microprisms not within the pattern is provided a coating of colored non-reflective material, whereby the light rays impinging upon the first face and thereafter impinging upon the inner surface of the microprisms with the reflective deposit are retroreflected thereby and the light rays impinging upon the inner surface of the microprisms with the colored coating are refracted therefrom with the coloration thereof in daylight and diffuse light.
In another embodiment of the method, the second face is initially metallized to produce a metallic deposit on all of the microprisms and a layer of protective material is provided thereon in the pattern, after which the metallized deposit is stripped in the areas without the protective material. The coating step thereafter follows to produce a coating over the entire second face. The stripping of the deposit may be effected by a solvent for the metallic deposit to which the protective material is substantially inert.
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Desirably, the protective material i8 applied in a grid pattern. The material of the coating may be of adheeive nature, and a backing member may be bonded thereto. The body member and backing member may be fabricated from synthetic resin to provide a retroreflective material which i6 relatively flexible.
In another embodiment, there is applied to the microprisms in a pattern a colored non-reflective coating material to a depth above the height of the microprisms, and this pattern covers 15-65 percent of the total surface of the second face. A backing member is applied to the second face over the coating material, and it is spaced by the coating material to provide an air interface about the microprisms not within the pattern of the coating. The colored non-reflective material is of adhesive nature and the backing member is bonded thereto. Degirably, the coating i8 applied in a grid pattern, and the body member and backing member are fabricated from synthetic resin and provide a retroreflective material which is relatively flexible.
Figure 1 i8 a partially diagrammatic illustration of an early step in one embodiment of a process for forming a retroreflective material embodying the present invention;
Figure 2 is a similar illustration of a subsequent step in the process in which microprism formations have been formed ::
- -~ thereon and are being cured in a mold by exposure to radiation;
Figure 3 i9 a similar illustration of a subsequent etep ~; in which a reflective metallic deposit has been formed on all - -the microprism for~ations;
Figure 4 i9 a similar illustration wherein a protective '-~ coating has been formed on the deposit in a pattern;
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Figure 5 is a similar illustration in which the material of Figure 4 is shown in contact with a solvent for the ~.;
unprotected metallic deposit;
Figure 6 is a similar illustration showing the material . with the metallic deposit removed in the areas not protected : by the coating;
Figure 7 is a similar illustration showing a colored adhesive coating material deposited over the entire surface of the sheet material and a fabric layer adhered thereto Figure 8 is a similar illustration showing the removal of the carrier sheeting Figure 9 is a fragmentary plan view of a grid pattern of the protective coating on the microprism face as formed in ~----- Figure 4;
Figure 10 is a diagrammatic view of the finished sheet material showing the path of light rays impinging upon the front face; and ~ ~ . . ~ , Figure 11 is a fragmentary cross sectional view of another embodiment of the retroreflective material of the present invention.
Turning first to Figure 1, therein a thin flexible sheet material body member 10 is being temporarily laminated to a - relatively thick carrier sheet 12 by an adhesive layer 14 which preferentially adheres to the carrier sheet 12. In this step, the thick carrier sheet 12 has been precoated with the : ~ . adhesive 14 and is passed through the nip of a pair of laminating rollers 16, 18 with the body member 10.
In the next step (not shown), the lower or opposite surface of the body member 10 is provided with a thin tie coat - 20 of synthetic resin. As seen in Figure 2, this coated ~ .
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laminate is then pressed against the surface of a mold 22 with closely spaced microprism recesses 24 in which is deposited a fluid synthetic resin composition. m e assembly is exposed to ultraviolet rays from the lamps 28 to cure the fluid resin composition to form microprism formations 26 on the surface of body member 10.
In the illustrated embodiment of the process, the sheet material is stripped from the surface of the mold 22 and i9 then vacuum metallized or otherwise treated to form a reflective metallic deposit 30 on the surface of the microprism formations 26, as seen in Figure 3.
In the next step, and as seen in Figures 4 and 9, a coating 32 of a protective material is applied in a grid pattern over the metallic deposit 30 on the microprisms 26.
In Figure 5, the coated surface is shown as being exposed to a solvent 34 for the metallic deposit 30 which removes the - ~ deposit in the unprotected areas. This leaves the reflective metallic deposit 30 only in those areas underlying the protective coating 32 as seen in Figure 6.
In Figure 7, the laminate is shown as bonded to a flexible fabric 36 by a coating 38 of colored adhesive disposed over the entire surface of the microprism face.
m u8, this coating 38 is in direct contact with those microprisms 26 which do not have the metallic deposit 30 and protective coating 32.
In Figure 8, the carrier 12 and its adhesive bonding layers 14 are shown as being stripped from the fabric ' supported microprism material.
-~ As seen in Figure 10, those light rays 40a impingins uponl the front face 42 of the retroreflective material which pass .,, ~ . 1~
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through the body member 10 and tie coat 20 into the microprisms 26 with the metallic deposit 30 impinge upon the retroreflective interface and are redirected from the surfaces of the microprisms 26 in a sub~tantially parallel path. Those light rays 40b impinging upon the front face 42 which enter the microprisms 26 having their surfaces in direct contact with the colored adhesive 38 are refracted at that interface and are scattered at different angles thereby and provide a visual coloration to the retroreflective material in ambient light or daylight which is that of the colored adhesive 38.
In Figure 11, another embodiment of the present invention is illu~trated and in which an air interface is employed for the retroreflection. The colored adhesive 38 is applied in a grid pattern to a height above the prisms 26 and the fabric 36 ~' is thereby spaced above the tips of the prisms to provide a ~- ~ retroreflective air interface about the prisms 26.
~ As previously indicated, the microprisms are closely ; spaced and can be described as cube corner formations.
Details concerning the structure and operation of such ~-~
microprisms may be found in Rowland United States Letters Patent 3,684,348 granted August 15, 1972. m ese microprisms ~;~
or cube corner formations may have a side edge dimension of up~
to 0.025 inch, but the preferred structure~ use edge ~ dimensions of not more than 0.010 inch, and most deslrably on - the order of 0.004-0.008 inch. ~, e body member of the sheeting will generally have a ; ;~
' - thicknesc on the order of 0.0001-0.030 inch and preferably -- - about 0.0002-0.0004 inch when a highly flexible laminate is to - ~ ~ be formed and, depending upon the method of fabrication, the - resins, and other characteristics desired for the - ~i :~ :
~ retroreflective sheeting. ~
- : .
_g_ ~ ~, , ,~ , r~ t The microprism sheeting may be formed by casting prisms ~-~
upon a film surface functioning as the ~ody, or by embos~ing a preformed sheeting, or by casting both body and prisms concurrently. Generally, the resins employed for the -microprism sheeting are cross linked thermoplastic ~ ~
formulations, and desirably these resins provide flexibility, ; -light stability, and good weathering characteristics. In some ---. , instances, the front face of the retroreflective sheeting may be provided with a protective coating such as by application 10 Of a lacquer or other coating material. Suitable resins for the retroreflective sheeting include vinyl chloride polymers, polyesters, polycarbonates, methyl methacrylate polymers, ~ .
polyurethanes and acrylated urethanes.
To protect the relatively thin body member during processing, the relatively thick carrier temporarily bonded thereto will generally have a thickness of 0.005-0.008 inch.
The adhesive used to effect the bonding therebetween preferentially adheres to the carrier and is conveniently a ~ilicone adhesive applied to a thickness of about 0.00025-0.0005 inch. When ultraviolet curing of the resin in the prisms is employed, the adhesive must be transparent to , 3 the light rays. Although various resins may be employed for the carrier, polyesters and particularly polyethylene ;~r~,r terepthalate are desirably employed because of their toughness and relative resistance to processing conditions. As with the t~ 5r adhesive, the carrier should be transparent to the ultraviolet ~ i radiation used to effect curing. Moreover, the surface of the carrier may be treated to enhance the preferential adhesion of ''''''~J
the adhesive to the surface of the carrier. ~ , A particularly advantageous method for making 6uch retroreflective sheeting is described and claimed in Rowland ~. ''''~
,' .~ '" t,., ~, ,','-', United States Letter Patent No. 3,689,346 granted September 5, 1972 in which the cube corner formations are cast in a -~
cooperatively configured mold and are bonded to sheeting which is applied thereover to provide a composite structure in which the cube corner formations project from the one surface of the sheeting.
Another method for fabricating such microprism sheeting s is shown in Rowland United States Patent No. 4,244,683 granted -- ~
January 13, 1981 in which the cube corner formations are ~ ;
produced by embossing a length of sheeting in suitable embossing apparatus with precisely formed molds in a manner which avoids entrapment of air.
The latter method has been used for forming sheeting of acrylic and polycarbonate resins while the former method has proven highly advantageous for forming retroreflective sheeting from polyvinyl chloride resins and, more recently, polyester body members with prisms of various resin formulations including acrylated epoxy oligomers. Although the carrier concept of the present invention is useful in both types of operation, it is particularly beneficial in producing -~ sheeting using thin polyester and like films which, while strong, might be damaged during the processing steps prior to ; its being supported by the flexible backing. :
-~ It is customary to provide a backing sheet behind the microprisms so as to protect them and to provide a smooth surface for application of the structure to support surfaces.
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To effect lamination of such a backing sheet to the ;~
retroreflective sheeting, adhesives and ultrasonic welding .,~J'.~' have generally been employed. ' As is known, the reflective interface for the prisms may -be provlded by a reflective ~o~ting or by ~n air int-r~ace.
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In the preferred embodiment of the present invention, a reflective coating is provided upon the surfaces of at least-some of the microprisms, and such reflective coatings have most commonly been vacuum metallized aluminum deposits, although metallic lacquers and other specular coating materials have also been used.
In one embodiment, the vacuum metallized prism surface is printed in a coating apparatus with a grid-like pattern of a protective coating material a~ indicated by the numeral 32 in Figures 4 and 9. In this grid pattern, there i8 a composite of underlying metal deposit 30 and overlying coating material 32. The coating material may be an adhesive, or a lacquer, or any other readily applied coating material which is essentially inert to the intended solvent bath.
The coated surface is subjected to treatment in a bath 34 of a solvent for the deposited metal, as shown by the numeral 32 in Figure 5. This bath i~ conveniently a mild caustic solution which will dissolve an aluminum deposit. The portion of the metal coating 30 which is not protected by the second coating material 32 is removed by the solvent in this step so as to leave the prisms 30 within the areas bounded by the grid free from any coating.
In the preferred process in which the metal deposit is to be removed in those areas where it is not protected, the solvent conveniently comprises a solution of alkali metal hydroxide or other alkaline solution which will dissolve the aluminum. In the instance of coatings other than metals, solutions with which the material will react or in which it will dissolve, are employed.
The colored coating material may be a colored lacquer -~ applied to the surface of the sheeting, a colored adhesive, or : :
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any other colored deposit which will coat the prism surfaces.
Conveniently, a colored adhesive is employed since this will enable bonding of the backing material thereto.
Another process for producing a grid pattern of metallized and unmetallized prisms involves applying a soluble resin to the prism surface in a grid pattern and then -:: :
metallizing the entire surface. The entire prism surface may then be subjected to the action of an agitated detergent - ~ solution to dissolve the soluble resin and thereby remove the aluminum deposit thereover. This leaves those prisms free -- from any coating, while there remains a metallic deposit on the ~urface of the other prisms.
~-In either of the techniques, the result is that some of ~-~ the microprisms are coated with the reflective deposit, and the remaining prisms are free from any coating.
,: :
~ m e colored coating is then applied over the entire prism - ~ surface and directly coats the unmetallized prisms.
-;~ m ereafter, the backing material is applied.
.-~ - - .
~- In the alternate embodiment, a colored adhesive is applied in a pattern to the prism surface and to a depth greater than the height of the prisms. When the backing element is laminated thereto, it is spaced from the prisms by ::
the adhesive and this provides an air interface about the - uncoated prisms.
m e backing sheet may be a woven or laid fabric, or a --~ flexible, durable polymeric material. Suitable resins include polyethylene, polypropylene, polyurethanes, acrylated ~;- polyurethanes and ethylene/vinyl acetate copolymers.
. "
; Polyester and urethane fabrics may be employed as well as -- those of natural fibers such as cotton. Flame retardants may ' ~ """'. "'~, .:
.... .
The present invention relates to retroreflective sheeting employing microprism formations to retroreflect the light rays impinging thereon, and, more particularly, to a method for producing such retroreflective sheet material which provides a bright coloration in daylight and ambient light and which is also highly retroreflective when exposed to light beams at night.
Retroreflective sheet material is widely employed for a variety of safety and decorative purposes, and is particularly useful when the need for night time visibility i8 significant under conditions of low ambient light. In retroreflective materials, the light rays impinging upon the front surface are reflected back towards the source of the illumination in a substantially parallel path. In situations where headlights or search lights on boats and aircraft are the only source of illumination, this ability to retroreflect the bulk of the rays falling thereon is especially significant for warning signs, delineators and the like.
Minnesota Mining and Manufacturing Corporation has manufactured retroreflective sheeting utilizing minute glass beads embedded in a matrix of synthetic resin to provide such retroreflection, and these materials have been sold under the trademark SCOTCHLITE. Illustrative of such materials is Bergeson et al United States Letters Patent 4,637,950 granted January 20, 1987.
Applicant's assignee, Reflexite Corporation, has been marketing under the trademark REFLEXITE, reflective sheeting employing microprisms formations to produce such retroreflection. Illustrative of such materials is Rowland .
~ ~ United States Letters Patent 3,689,346 granted September 5, - 1972.
~ -2-- - - - - - -In Martin United States Patent No. 4,801,193 granted January 31, 198g, there is described in detail a process for producing grid patterns of metallized and unmetallized pri~ms, and the use of adhesive spacing to provide an air backing about prisms.
Among the applications for such retroreflective materials are reflective tapes and patches for clothing of firemen, reflective vests and belts, bands for posts and barrels, traffic cone collars, highway signs, warning reflectors, and i 10 the like.
It is desirable for some applications that the retroreflective sheeting exhibit a bright coloration in daylight and ambient light, such as the red and yellow/green used for warning and emergency. In Rowland United States Letters Patent No. 3,830,682 granted August 20, 1974, a metameric dye is included so that the sheet material fluoresces in one color in daylight and retroreflects in a second coloration when exposed to headlights and other directional light sources at night.
The use of a metallized aluminum coating on the prism ., . ~ , surfaces tends to produce a grey coloration to the observer in ambient light or daylight conditions. In some applications, ~ this grey appearance is considered aesthetically undesirable, - and coloration would be desirable.
'~ It is an object of the present invention to provide a novel retroreflective sheeting using microprism formations which exhibits a bright coloration in daylight and high -::
retroreflectivity at night when exposed to directional light sources.
It is also an object of the present invention to provide ;;
such a colored retroreflective sheet material which may be : ;J . ,r' 5 ~ ~ ~
readily fabricated and which is durable and resistant to the elements.
Another object of the present invention is to provide novel methods for fabricating such retroreflective sheet material which are relatively simple and relatively economical, and which produce long-lived materials.
It has now been found that the foregoing and related objects and advantages may be readily attained in a retroreflective material which has a body member of transparent synthetic resin with a first planar face and a second face with closely spaced microprisms thereover.
Suitable means provides a reflective interface for the microprism in a pattern over the expanse of the second face, and a colored non-reflective coating is disposed on the surfaces of the microprisms between those in the pattern. The microprisms with the reflective interface Comprise 40-85 percent of the total surface area of the second face so that light rays impinging on the first planar face and thereafter directed upon the reflective interfaces of the microprisms are retroreflected thereby in the direction from which they came.
Those impinging upon the coated microprisms are refracted therefrom with the coloration of the coating in daylight and also in diffuse light.
In one embodiment, the body member has a reflective metallic layer on the uncoated microprisms to provide the reflective interface, and this may include a deposit of protective material on the metallic layer. The colored coating may extend over the deposit. In another embodiment, the uncoated microprisms have an air interface about substantially their entire surface.
Generally, there is a backing member disposed over the , coated and uncoated microprisms, and the material of the coating has adhesive properties so that the backing member i8 adhered thereto. The coating may extend to a distance above the microprisms and provide a spacer for the backing member to position it above the uncoated microprisms, and thereby provide an air interface thereabout.
In one method for making a colored retroreflective -~1 material, a retroreflective body member is provided which has ~' 10 a planar first face and a second face with closely spaced microprisms thereover. A reflective aeposit is formed on the surface of the microprisms in a pattern extending over the v second face and covering 40-85 percent of the total area of ~, the second face. On the surface of the microprisms not within the pattern is provided a coating of colored non-reflective material, whereby the light rays impinging upon the first face and thereafter impinging upon the inner surface of the microprisms with the reflective deposit are retroreflected thereby and the light rays impinging upon the inner surface of the microprisms with the colored coating are refracted therefrom with the coloration thereof in daylight and diffuse light.
In another embodiment of the method, the second face is initially metallized to produce a metallic deposit on all of the microprisms and a layer of protective material is provided thereon in the pattern, after which the metallized deposit is stripped in the areas without the protective material. The coating step thereafter follows to produce a coating over the entire second face. The stripping of the deposit may be effected by a solvent for the metallic deposit to which the protective material is substantially inert.
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Desirably, the protective material i8 applied in a grid pattern. The material of the coating may be of adheeive nature, and a backing member may be bonded thereto. The body member and backing member may be fabricated from synthetic resin to provide a retroreflective material which i6 relatively flexible.
In another embodiment, there is applied to the microprisms in a pattern a colored non-reflective coating material to a depth above the height of the microprisms, and this pattern covers 15-65 percent of the total surface of the second face. A backing member is applied to the second face over the coating material, and it is spaced by the coating material to provide an air interface about the microprisms not within the pattern of the coating. The colored non-reflective material is of adhesive nature and the backing member is bonded thereto. Degirably, the coating i8 applied in a grid pattern, and the body member and backing member are fabricated from synthetic resin and provide a retroreflective material which is relatively flexible.
Figure 1 i8 a partially diagrammatic illustration of an early step in one embodiment of a process for forming a retroreflective material embodying the present invention;
Figure 2 is a similar illustration of a subsequent step in the process in which microprism formations have been formed ::
- -~ thereon and are being cured in a mold by exposure to radiation;
Figure 3 i9 a similar illustration of a subsequent etep ~; in which a reflective metallic deposit has been formed on all - -the microprism for~ations;
Figure 4 i9 a similar illustration wherein a protective '-~ coating has been formed on the deposit in a pattern;
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Figure 5 is a similar illustration in which the material of Figure 4 is shown in contact with a solvent for the ~.;
unprotected metallic deposit;
Figure 6 is a similar illustration showing the material . with the metallic deposit removed in the areas not protected : by the coating;
Figure 7 is a similar illustration showing a colored adhesive coating material deposited over the entire surface of the sheet material and a fabric layer adhered thereto Figure 8 is a similar illustration showing the removal of the carrier sheeting Figure 9 is a fragmentary plan view of a grid pattern of the protective coating on the microprism face as formed in ~----- Figure 4;
Figure 10 is a diagrammatic view of the finished sheet material showing the path of light rays impinging upon the front face; and ~ ~ . . ~ , Figure 11 is a fragmentary cross sectional view of another embodiment of the retroreflective material of the present invention.
Turning first to Figure 1, therein a thin flexible sheet material body member 10 is being temporarily laminated to a - relatively thick carrier sheet 12 by an adhesive layer 14 which preferentially adheres to the carrier sheet 12. In this step, the thick carrier sheet 12 has been precoated with the : ~ . adhesive 14 and is passed through the nip of a pair of laminating rollers 16, 18 with the body member 10.
In the next step (not shown), the lower or opposite surface of the body member 10 is provided with a thin tie coat - 20 of synthetic resin. As seen in Figure 2, this coated ~ .
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laminate is then pressed against the surface of a mold 22 with closely spaced microprism recesses 24 in which is deposited a fluid synthetic resin composition. m e assembly is exposed to ultraviolet rays from the lamps 28 to cure the fluid resin composition to form microprism formations 26 on the surface of body member 10.
In the illustrated embodiment of the process, the sheet material is stripped from the surface of the mold 22 and i9 then vacuum metallized or otherwise treated to form a reflective metallic deposit 30 on the surface of the microprism formations 26, as seen in Figure 3.
In the next step, and as seen in Figures 4 and 9, a coating 32 of a protective material is applied in a grid pattern over the metallic deposit 30 on the microprisms 26.
In Figure 5, the coated surface is shown as being exposed to a solvent 34 for the metallic deposit 30 which removes the - ~ deposit in the unprotected areas. This leaves the reflective metallic deposit 30 only in those areas underlying the protective coating 32 as seen in Figure 6.
In Figure 7, the laminate is shown as bonded to a flexible fabric 36 by a coating 38 of colored adhesive disposed over the entire surface of the microprism face.
m u8, this coating 38 is in direct contact with those microprisms 26 which do not have the metallic deposit 30 and protective coating 32.
In Figure 8, the carrier 12 and its adhesive bonding layers 14 are shown as being stripped from the fabric ' supported microprism material.
-~ As seen in Figure 10, those light rays 40a impingins uponl the front face 42 of the retroreflective material which pass .,, ~ . 1~
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through the body member 10 and tie coat 20 into the microprisms 26 with the metallic deposit 30 impinge upon the retroreflective interface and are redirected from the surfaces of the microprisms 26 in a sub~tantially parallel path. Those light rays 40b impinging upon the front face 42 which enter the microprisms 26 having their surfaces in direct contact with the colored adhesive 38 are refracted at that interface and are scattered at different angles thereby and provide a visual coloration to the retroreflective material in ambient light or daylight which is that of the colored adhesive 38.
In Figure 11, another embodiment of the present invention is illu~trated and in which an air interface is employed for the retroreflection. The colored adhesive 38 is applied in a grid pattern to a height above the prisms 26 and the fabric 36 ~' is thereby spaced above the tips of the prisms to provide a ~- ~ retroreflective air interface about the prisms 26.
~ As previously indicated, the microprisms are closely ; spaced and can be described as cube corner formations.
Details concerning the structure and operation of such ~-~
microprisms may be found in Rowland United States Letters Patent 3,684,348 granted August 15, 1972. m ese microprisms ~;~
or cube corner formations may have a side edge dimension of up~
to 0.025 inch, but the preferred structure~ use edge ~ dimensions of not more than 0.010 inch, and most deslrably on - the order of 0.004-0.008 inch. ~, e body member of the sheeting will generally have a ; ;~
' - thicknesc on the order of 0.0001-0.030 inch and preferably -- - about 0.0002-0.0004 inch when a highly flexible laminate is to - ~ ~ be formed and, depending upon the method of fabrication, the - resins, and other characteristics desired for the - ~i :~ :
~ retroreflective sheeting. ~
- : .
_g_ ~ ~, , ,~ , r~ t The microprism sheeting may be formed by casting prisms ~-~
upon a film surface functioning as the ~ody, or by embos~ing a preformed sheeting, or by casting both body and prisms concurrently. Generally, the resins employed for the -microprism sheeting are cross linked thermoplastic ~ ~
formulations, and desirably these resins provide flexibility, ; -light stability, and good weathering characteristics. In some ---. , instances, the front face of the retroreflective sheeting may be provided with a protective coating such as by application 10 Of a lacquer or other coating material. Suitable resins for the retroreflective sheeting include vinyl chloride polymers, polyesters, polycarbonates, methyl methacrylate polymers, ~ .
polyurethanes and acrylated urethanes.
To protect the relatively thin body member during processing, the relatively thick carrier temporarily bonded thereto will generally have a thickness of 0.005-0.008 inch.
The adhesive used to effect the bonding therebetween preferentially adheres to the carrier and is conveniently a ~ilicone adhesive applied to a thickness of about 0.00025-0.0005 inch. When ultraviolet curing of the resin in the prisms is employed, the adhesive must be transparent to , 3 the light rays. Although various resins may be employed for the carrier, polyesters and particularly polyethylene ;~r~,r terepthalate are desirably employed because of their toughness and relative resistance to processing conditions. As with the t~ 5r adhesive, the carrier should be transparent to the ultraviolet ~ i radiation used to effect curing. Moreover, the surface of the carrier may be treated to enhance the preferential adhesion of ''''''~J
the adhesive to the surface of the carrier. ~ , A particularly advantageous method for making 6uch retroreflective sheeting is described and claimed in Rowland ~. ''''~
,' .~ '" t,., ~, ,','-', United States Letter Patent No. 3,689,346 granted September 5, 1972 in which the cube corner formations are cast in a -~
cooperatively configured mold and are bonded to sheeting which is applied thereover to provide a composite structure in which the cube corner formations project from the one surface of the sheeting.
Another method for fabricating such microprism sheeting s is shown in Rowland United States Patent No. 4,244,683 granted -- ~
January 13, 1981 in which the cube corner formations are ~ ;
produced by embossing a length of sheeting in suitable embossing apparatus with precisely formed molds in a manner which avoids entrapment of air.
The latter method has been used for forming sheeting of acrylic and polycarbonate resins while the former method has proven highly advantageous for forming retroreflective sheeting from polyvinyl chloride resins and, more recently, polyester body members with prisms of various resin formulations including acrylated epoxy oligomers. Although the carrier concept of the present invention is useful in both types of operation, it is particularly beneficial in producing -~ sheeting using thin polyester and like films which, while strong, might be damaged during the processing steps prior to ; its being supported by the flexible backing. :
-~ It is customary to provide a backing sheet behind the microprisms so as to protect them and to provide a smooth surface for application of the structure to support surfaces.
:~: .~;
To effect lamination of such a backing sheet to the ;~
retroreflective sheeting, adhesives and ultrasonic welding .,~J'.~' have generally been employed. ' As is known, the reflective interface for the prisms may -be provlded by a reflective ~o~ting or by ~n air int-r~ace.
~: ' ,.. ~, -~ ~0~3~
In the preferred embodiment of the present invention, a reflective coating is provided upon the surfaces of at least-some of the microprisms, and such reflective coatings have most commonly been vacuum metallized aluminum deposits, although metallic lacquers and other specular coating materials have also been used.
In one embodiment, the vacuum metallized prism surface is printed in a coating apparatus with a grid-like pattern of a protective coating material a~ indicated by the numeral 32 in Figures 4 and 9. In this grid pattern, there i8 a composite of underlying metal deposit 30 and overlying coating material 32. The coating material may be an adhesive, or a lacquer, or any other readily applied coating material which is essentially inert to the intended solvent bath.
The coated surface is subjected to treatment in a bath 34 of a solvent for the deposited metal, as shown by the numeral 32 in Figure 5. This bath i~ conveniently a mild caustic solution which will dissolve an aluminum deposit. The portion of the metal coating 30 which is not protected by the second coating material 32 is removed by the solvent in this step so as to leave the prisms 30 within the areas bounded by the grid free from any coating.
In the preferred process in which the metal deposit is to be removed in those areas where it is not protected, the solvent conveniently comprises a solution of alkali metal hydroxide or other alkaline solution which will dissolve the aluminum. In the instance of coatings other than metals, solutions with which the material will react or in which it will dissolve, are employed.
The colored coating material may be a colored lacquer -~ applied to the surface of the sheeting, a colored adhesive, or : :
~ 3 ,.,, ~.
,......
any other colored deposit which will coat the prism surfaces.
Conveniently, a colored adhesive is employed since this will enable bonding of the backing material thereto.
Another process for producing a grid pattern of metallized and unmetallized prisms involves applying a soluble resin to the prism surface in a grid pattern and then -:: :
metallizing the entire surface. The entire prism surface may then be subjected to the action of an agitated detergent - ~ solution to dissolve the soluble resin and thereby remove the aluminum deposit thereover. This leaves those prisms free -- from any coating, while there remains a metallic deposit on the ~urface of the other prisms.
~-In either of the techniques, the result is that some of ~-~ the microprisms are coated with the reflective deposit, and the remaining prisms are free from any coating.
,: :
~ m e colored coating is then applied over the entire prism - ~ surface and directly coats the unmetallized prisms.
-;~ m ereafter, the backing material is applied.
.-~ - - .
~- In the alternate embodiment, a colored adhesive is applied in a pattern to the prism surface and to a depth greater than the height of the prisms. When the backing element is laminated thereto, it is spaced from the prisms by ::
the adhesive and this provides an air interface about the - uncoated prisms.
m e backing sheet may be a woven or laid fabric, or a --~ flexible, durable polymeric material. Suitable resins include polyethylene, polypropylene, polyurethanes, acrylated ~;- polyurethanes and ethylene/vinyl acetate copolymers.
. "
; Polyester and urethane fabrics may be employed as well as -- those of natural fibers such as cotton. Flame retardants may ' ~ """'. "'~, .:
.... .
2 ~ 7 be incorporated in the adhesives as well as in the fabric or resin backing to impart flame retardance to the retroreflective material.
Although other metals may be used to provide a specular metal deposit including silver, rhodium, copper, tin, zinc, ~: ;
- ; and palladium, the preferred and most economical processes ' utilize aluminum vacuum deposition. Other deposition --~ techniques include electroless plating, electroplating, ion deposition and sputter coating.
The protective coating material is desirably a pressure - sensitive adhesive which will not be unduly affected in the ~' solvent treating step, and it may be the same adhesive as - ~ employed as the means for bonding the backing member.
Preferred adhesives include rubber based systems such as ~ ~ isobutylene in a solvent carrier and acrylic-based adhesives -~~ and silicones in solvent systems. Other adhesives may also be - employed, and water based systems may also be used although sometimes requiring drying time before further processing.
Specific examples of suitable adhesive systems are a rubber based, resin modified adhesive sold by B.F. Goodrich under the - designation A1569-B, a latex rubber-based adhesive sold by : -~-- Emhart Industries, Bostik Division, under the designation ~: ;, : ----~ --; 8786X and a latex rubber-based system sold by B.F. GoodriCh '~ under the designation 26171, and a pressure sensitive silicone - resin adhesive in a solvent sold by Dow under the designation QZ-7406.
Whether using solvent-based or water based systems, the ;~ coating may require drying before further processing. If so, heating may be utilized to accelerate the proces~.
~ The step of adhering the backing to the retroreflective A.~' sheeting may simply involve passing the adhesively coated ~ - -14-retroreflective sheeting through the nip of a pair of rolls together with the backing material to apply the necessary pressure to effect adhesion. If a heat activatable adhesive is employed, the retroreflective sheeting may be subjected to preheating prior to passage through the rolls, or the rolls may be heated to achieve the necessary activation. However, it is also practicable to employ ultrasonic welding and other techniques to bond the backing material to the retroreflective sheeting by the material of the backing material itself when it is thermoplastic.
To provide a coloration to the retroreflective light at - ~ night, a dye may be incorporated in the resin used to form the - ~ - body member, or the tie coat, or even the prisms. As an alternative to a dye and as an effective necessity in some ~- resin systems, the coloration may be provided as a finelydivided pigment which is well dispersed however, some loss in retroreflectivety will occur as the result of refraction by pigment particles which are directly in the path of light rayg .
; ~ 20 Illustrative of the present invention is the following example.
EXAMPLE ONE
~ Utilizing the method generally illustrated in Rowland United States Patent No. 3,689,346, microprisms having a height of 0.0028 inch and a spacing of about 0.006 inch on center are cast upon a polyester film having a thickness of ~.
0.0005 inch, and coated with a tie coat of a solution of ' ~ polyester resin. The thin polyester film is temporarily bonded to a carrier of surface treated polyester film having a : ~
thickness of 0.002 inch by a silicone adhesive. The resin '"~d_~
- ) ~ Q ~
employed casting for the prisms is an acrylated epoxy oligomer modified with monofunctional and trifunctional acrylic ~,,i, , monomers and containing a cross linking catalyst.
-~ The retroreflective sheeting is vacuum metallized with - aluminum to a thickness in excess of 240 Angstroms. The metallized sheeting i5 then imprinted by a modified gravure roll with a grid pattern of a pressure sensitive, ever-tacky isobutylene rubber based adhesive. m e grid has a spacing of 1/4 inch between lines and the lines have a thickness of approximately 0.04 inch.
Following printing of the grid pattern, the sheeting i8 passed through a 1.0 M. solution of sodium hydroxide for a period of 10-30 seconds during which the unprotected aluminum deposit is removed. m e sheeting is then passed through a : ::
water bath to rinse the surface, and thence through a dryer.
The sheeting is coated with a red pigmented silicone adhesive containing a bromine flame retardant to a thickness of about 0.004 inch or about 0.0015 inch above the tops of the prisms.
m e coated sheet material is then passed through the nip of laminating rollers together with a woven cotten fabric treated with a flame retardant and having a thickness of about 0.006 inch to effect the lamination thereto. Thereafter, the carrier and its adhesive are stripped from the retroreflective ~heeting.
Upon visual inspection, the retroreflective material is flexible and may be conformed easily to clothing and the like.
It may be readily sewn to fabric and adhesively bonded to various substrates. m e sheet material exhibits a red coloration in daylight. When exposed to a beam of directional incandescent light, it retroreflects brightly in a white/grey coloration.
Thus, it can be seen from the foregoing detailed specification and the attached drawings that the retroreflective sheeting of the present invention exhibits a bright coloration in daylight and high retroreflectivity when exposed to directional light sources at night. m e material may be readily fabricated, is relatively durable, and may be made substantially resistant to the elements to which it may be exposed. By incorporating dyes and extremely fine particle pigments into the material, the retroreflected light may also be provided with coloration at night.
:
:
, ,;~,. . .
.,~ , .
,~ . ,, ~-. -':
, . . .
, : ,. I
Although other metals may be used to provide a specular metal deposit including silver, rhodium, copper, tin, zinc, ~: ;
- ; and palladium, the preferred and most economical processes ' utilize aluminum vacuum deposition. Other deposition --~ techniques include electroless plating, electroplating, ion deposition and sputter coating.
The protective coating material is desirably a pressure - sensitive adhesive which will not be unduly affected in the ~' solvent treating step, and it may be the same adhesive as - ~ employed as the means for bonding the backing member.
Preferred adhesives include rubber based systems such as ~ ~ isobutylene in a solvent carrier and acrylic-based adhesives -~~ and silicones in solvent systems. Other adhesives may also be - employed, and water based systems may also be used although sometimes requiring drying time before further processing.
Specific examples of suitable adhesive systems are a rubber based, resin modified adhesive sold by B.F. Goodrich under the - designation A1569-B, a latex rubber-based adhesive sold by : -~-- Emhart Industries, Bostik Division, under the designation ~: ;, : ----~ --; 8786X and a latex rubber-based system sold by B.F. GoodriCh '~ under the designation 26171, and a pressure sensitive silicone - resin adhesive in a solvent sold by Dow under the designation QZ-7406.
Whether using solvent-based or water based systems, the ;~ coating may require drying before further processing. If so, heating may be utilized to accelerate the proces~.
~ The step of adhering the backing to the retroreflective A.~' sheeting may simply involve passing the adhesively coated ~ - -14-retroreflective sheeting through the nip of a pair of rolls together with the backing material to apply the necessary pressure to effect adhesion. If a heat activatable adhesive is employed, the retroreflective sheeting may be subjected to preheating prior to passage through the rolls, or the rolls may be heated to achieve the necessary activation. However, it is also practicable to employ ultrasonic welding and other techniques to bond the backing material to the retroreflective sheeting by the material of the backing material itself when it is thermoplastic.
To provide a coloration to the retroreflective light at - ~ night, a dye may be incorporated in the resin used to form the - ~ - body member, or the tie coat, or even the prisms. As an alternative to a dye and as an effective necessity in some ~- resin systems, the coloration may be provided as a finelydivided pigment which is well dispersed however, some loss in retroreflectivety will occur as the result of refraction by pigment particles which are directly in the path of light rayg .
; ~ 20 Illustrative of the present invention is the following example.
EXAMPLE ONE
~ Utilizing the method generally illustrated in Rowland United States Patent No. 3,689,346, microprisms having a height of 0.0028 inch and a spacing of about 0.006 inch on center are cast upon a polyester film having a thickness of ~.
0.0005 inch, and coated with a tie coat of a solution of ' ~ polyester resin. The thin polyester film is temporarily bonded to a carrier of surface treated polyester film having a : ~
thickness of 0.002 inch by a silicone adhesive. The resin '"~d_~
- ) ~ Q ~
employed casting for the prisms is an acrylated epoxy oligomer modified with monofunctional and trifunctional acrylic ~,,i, , monomers and containing a cross linking catalyst.
-~ The retroreflective sheeting is vacuum metallized with - aluminum to a thickness in excess of 240 Angstroms. The metallized sheeting i5 then imprinted by a modified gravure roll with a grid pattern of a pressure sensitive, ever-tacky isobutylene rubber based adhesive. m e grid has a spacing of 1/4 inch between lines and the lines have a thickness of approximately 0.04 inch.
Following printing of the grid pattern, the sheeting i8 passed through a 1.0 M. solution of sodium hydroxide for a period of 10-30 seconds during which the unprotected aluminum deposit is removed. m e sheeting is then passed through a : ::
water bath to rinse the surface, and thence through a dryer.
The sheeting is coated with a red pigmented silicone adhesive containing a bromine flame retardant to a thickness of about 0.004 inch or about 0.0015 inch above the tops of the prisms.
m e coated sheet material is then passed through the nip of laminating rollers together with a woven cotten fabric treated with a flame retardant and having a thickness of about 0.006 inch to effect the lamination thereto. Thereafter, the carrier and its adhesive are stripped from the retroreflective ~heeting.
Upon visual inspection, the retroreflective material is flexible and may be conformed easily to clothing and the like.
It may be readily sewn to fabric and adhesively bonded to various substrates. m e sheet material exhibits a red coloration in daylight. When exposed to a beam of directional incandescent light, it retroreflects brightly in a white/grey coloration.
Thus, it can be seen from the foregoing detailed specification and the attached drawings that the retroreflective sheeting of the present invention exhibits a bright coloration in daylight and high retroreflectivity when exposed to directional light sources at night. m e material may be readily fabricated, is relatively durable, and may be made substantially resistant to the elements to which it may be exposed. By incorporating dyes and extremely fine particle pigments into the material, the retroreflected light may also be provided with coloration at night.
:
:
, ,;~,. . .
.,~ , .
,~ . ,, ~-. -':
, . . .
, : ,. I
Claims (20)
1. A retroreflective material, comprising:
a) a body member of transparent synthetic resin having a first planar face and a second face with closely spaced microprisms thereover, each microprism of said microprisms having a surface;
b) means providing a reflective interface for said microprisms in a pattern over an expanse of said second face;
and c) a colored non-reflective coating on each surface of each of said microprisms between those in said pattern, said microprisms with said reflective interface comprising 40-85 percent of the total surface area of said second face, whereby light rays impinging on said first planar face and thereafter impinging upon said reflective interfaces of said microprisms are retroreflected thereby in a direction from which they came and those impinging on said colored non-reflective coating on said surfaces of said microprisms are refracted therefrom with coloration thereof in daylight and in diffuse light.
a) a body member of transparent synthetic resin having a first planar face and a second face with closely spaced microprisms thereover, each microprism of said microprisms having a surface;
b) means providing a reflective interface for said microprisms in a pattern over an expanse of said second face;
and c) a colored non-reflective coating on each surface of each of said microprisms between those in said pattern, said microprisms with said reflective interface comprising 40-85 percent of the total surface area of said second face, whereby light rays impinging on said first planar face and thereafter impinging upon said reflective interfaces of said microprisms are retroreflected thereby in a direction from which they came and those impinging on said colored non-reflective coating on said surfaces of said microprisms are refracted therefrom with coloration thereof in daylight and in diffuse light.
2. The retroreflective material in accordance with claim 1, wherein said body member has a reflective metallic layer on a portion of said microprisms to provide said reflective interface.
3. The retroreflective material in accordance with claim 2, wherein there is a deposit of protective material on said metallic layer.
4. The retroreflective material in accordance with claim 3, wherein said coating extends over said deposit.
5. The retroreflective material in accordance with any one of claims 1 through 4, wherein a portion of said microprisms has an air interface about substantially its entire surface.
6. The retroreflective material in accordance with any one of claims 1 through 5, wherein there is included a backing member disposed over said microprisms.
7. The retroreflective material in accordance with claim 6, wherein said material of said coating has adhesive properties and said backing member is adhered thereto.
8. The retroreflective material in accordance with any one of claims 1 through 7, wherein a portion of said microprisms have an air interface about substantially their entire surface, and wherein there is a backing member disposed over said microprisms.
9. The retroreflective material in accordance with claim 8, wherein said material of said coating has adhesive properties and said backing member is adhered thereto.
10. The retroreflective material in accordance with an one of claims 8 and 9, wherein said coating extends to a distance above said microprisms and provides a spacer for said backing member to position said backing member above the portion of said microprisms, and thereby maintain said air interface.
11. A method for making a colored retroreflective material, comprising the steps of:
a) providing a retroreflective body member with a planar first face and a second face with closely spaced microprisms thereover each microprism of said microprisms having a surface;
b) forming a reflective deposit on each surface of each of said microprisms in a pattern extending over said second face and covering 40-85 percent of a total area of said second face; and c) providing, on each surface of each of said microprisms not within said pattern, a coating of colored non-reflective material, whereby light rays impinging upon said first face and thereafter impinging upon an inner surface of said microprisms with said reflective deposit are retroreflected thereby and light rays impinging upon said inner surface of said microprisms with said colored coating are refracted therefrom with said coloration thereof in daylight and diffuse light.
a) providing a retroreflective body member with a planar first face and a second face with closely spaced microprisms thereover each microprism of said microprisms having a surface;
b) forming a reflective deposit on each surface of each of said microprisms in a pattern extending over said second face and covering 40-85 percent of a total area of said second face; and c) providing, on each surface of each of said microprisms not within said pattern, a coating of colored non-reflective material, whereby light rays impinging upon said first face and thereafter impinging upon an inner surface of said microprisms with said reflective deposit are retroreflected thereby and light rays impinging upon said inner surface of said microprisms with said colored coating are refracted therefrom with said coloration thereof in daylight and diffuse light.
12. The method in accordance with claim 11, wherein said second face is initially metallized to produce a metallic deposit on said microprisms and a layer of protective material is provided thereon in said pattern and wherein said metallized deposit is stripped in areas without said protective material, and including a coating step thereafter to produce a coating over said entire second face entirely.
13. The method in accordance with claim 12, wherein said stripping is effected by a solvent for said metallic deposit to which said protective material is substantially inert.
14. The method in accordance with any one of claims 12 or 13, wherein said protective material is applied in a grid pattern.
15. The method in accordance with any one of claims 11 through 14, wherein said material of said coating is of adhesive nature and a backing member is bonded thereto.
16. The method in accordance with claim 15, wherein said body member and said backing member are fabricated from synthetic resin and provide a retroreflective material which is flexible.
17. A method for making a colored retroreflective material, comprising the steps of:
a) providing a retroreflective body member with a planar first face and a second face with closely spaced microprisms thereover;
b) applying to said microprisms, in a pattern, a colored non-reflective coating material said coating being deposited to a depth above the height of said microprisms, said pattern covering 15-65 percent of the total surface of said second face; and c) applying a backing member to said second face over said coating material, said backing member being spaced by said coating material to provide an air interface about said microprisms not within said pattern, whereby light rays impinging upon said first face of said body member and thereafter impinging upon said microprisms with said air interface are retroreflected thereby and light rays impinging said microprisms with said coating material thereon are refracted therefrom with said coloration thereof in daylight and diffuse light.
a) providing a retroreflective body member with a planar first face and a second face with closely spaced microprisms thereover;
b) applying to said microprisms, in a pattern, a colored non-reflective coating material said coating being deposited to a depth above the height of said microprisms, said pattern covering 15-65 percent of the total surface of said second face; and c) applying a backing member to said second face over said coating material, said backing member being spaced by said coating material to provide an air interface about said microprisms not within said pattern, whereby light rays impinging upon said first face of said body member and thereafter impinging upon said microprisms with said air interface are retroreflected thereby and light rays impinging said microprisms with said coating material thereon are refracted therefrom with said coloration thereof in daylight and diffuse light.
18. The method in accordance with claim 17, wherein said colored nonreflective material is of adhesive nature and said backing member is bonded thereto.
19. The method in accordance with claim 17 or claim 18, wherein said coating is applied in a grid pattern.
20. The method in accordance with any one of claims 17 through 19, wherein said body member and said backing member are fabricated from synthetic resin and provide a retroreflective material which is flexible.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/525,241 | 1990-05-16 | ||
| US07/525,241 US5229882A (en) | 1990-05-16 | 1990-05-16 | Colored retroreflective sheeting and method of making same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2040537A1 CA2040537A1 (en) | 1991-11-17 |
| CA2040537C true CA2040537C (en) | 1999-07-20 |
Family
ID=24092486
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002040537A Expired - Fee Related CA2040537C (en) | 1990-05-16 | 1991-04-16 | Colored retroreflective sheeting and method for making same |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5229882A (en) |
| JP (1) | JP2617630B2 (en) |
| CA (1) | CA2040537C (en) |
| DE (1) | DE4115823A1 (en) |
| FR (1) | FR2662267B1 (en) |
| GB (1) | GB2245194B (en) |
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-
1990
- 1990-05-16 US US07/525,241 patent/US5229882A/en not_active Expired - Lifetime
-
1991
- 1991-04-16 CA CA002040537A patent/CA2040537C/en not_active Expired - Fee Related
- 1991-05-15 FR FR9105887A patent/FR2662267B1/en not_active Expired - Fee Related
- 1991-05-15 DE DE4115823A patent/DE4115823A1/en not_active Ceased
- 1991-05-15 JP JP3110383A patent/JP2617630B2/en not_active Expired - Fee Related
- 1991-05-16 GB GB9110656A patent/GB2245194B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH06342102A (en) | 1994-12-13 |
| FR2662267A1 (en) | 1991-11-22 |
| GB2245194B (en) | 1994-03-30 |
| US5229882A (en) | 1993-07-20 |
| FR2662267B1 (en) | 1993-07-30 |
| JP2617630B2 (en) | 1997-06-04 |
| GB2245194A (en) | 1992-01-02 |
| CA2040537A1 (en) | 1991-11-17 |
| GB9110656D0 (en) | 1991-07-03 |
| DE4115823A1 (en) | 1991-11-21 |
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| Date | Code | Title | Description |
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| EEER | Examination request | ||
| MKLA | Lapsed |