CA2051937A1 - High performance tire treads and tires - Google Patents
High performance tire treads and tiresInfo
- Publication number
- CA2051937A1 CA2051937A1 CA002051937A CA2051937A CA2051937A1 CA 2051937 A1 CA2051937 A1 CA 2051937A1 CA 002051937 A CA002051937 A CA 002051937A CA 2051937 A CA2051937 A CA 2051937A CA 2051937 A1 CA2051937 A1 CA 2051937A1
- Authority
- CA
- Canada
- Prior art keywords
- alkyne
- molecular weight
- conjugated diene
- tires
- mole ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Abstract
High-performance tires comprising treads made of elastomer compositions comprising (A) ultra high molecular weight copolymer compositions of 1,3-conjugated dienes and aromatic vinyl compounds having a weight average molecular weight of greater than about 1,000,000; (B) extender oil; and (C) carbon black are described. The ultra high molecular weight copolymer compositions which are also characterised as having an intrinsic viscosity in tetrahydrofuran of at least about 4.0 may be obtained by a process which comprises polymerizing a 1,3-conjugated diene and a vinyl aromatic compound in a hydrocarbon solvent in the presence of a trimetalated 1-alkyne catalyst which comprises the reaction product of a 1-alkyne containing at least 4 carbon atoms, an organo metallic compound R~M and a 1,3-conjugated diene wherein R~
is a hydrocarbyl group, M is an alkali metal, the mole ratio of R~M to 1-alkyne is about 3:1 and the mole ratio of conjugated diene to 1-alkyne is from about 2:1 to about 30:1.
is a hydrocarbyl group, M is an alkali metal, the mole ratio of R~M to 1-alkyne is about 3:1 and the mole ratio of conjugated diene to 1-alkyne is from about 2:1 to about 30:1.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US586,065 | 1990-09-21 | ||
US07/586,065 US5272203A (en) | 1990-09-21 | 1990-09-21 | High performance tire treads and tires |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2051937A1 true CA2051937A1 (en) | 1992-03-22 |
CA2051937C CA2051937C (en) | 2005-08-09 |
Family
ID=24344167
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002051937A Expired - Lifetime CA2051937C (en) | 1990-09-21 | 1991-09-20 | High performance tire treads and tires |
Country Status (6)
Country | Link |
---|---|
US (1) | US5272203A (en) |
EP (1) | EP0476640B1 (en) |
JP (1) | JP3157216B2 (en) |
CA (1) | CA2051937C (en) |
DE (1) | DE69128862T2 (en) |
ES (1) | ES2111549T3 (en) |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0502728B1 (en) * | 1991-03-05 | 1996-08-14 | Bridgestone Corporation | Pneumatic tires |
MY115289A (en) * | 1992-08-27 | 2003-05-31 | Cabot Corp | Carbon blacks containing epdm compositions having either a high gloss or a textured matte finish |
JP3378313B2 (en) * | 1993-09-10 | 2003-02-17 | 株式会社ブリヂストン | Rubber composition |
US5508336A (en) * | 1993-12-29 | 1996-04-16 | Bridgestone Corporation | Rubber composition |
DE4400996C2 (en) * | 1994-01-14 | 1997-04-24 | Uniroyal Englebert Gmbh | Tire tread |
US5750615A (en) * | 1996-11-26 | 1998-05-12 | The Goodyear Tire & Rubber Company | Use of fullerene carbon in curable rubber compounds |
US5730910A (en) * | 1997-01-03 | 1998-03-24 | Bridgestone/Firestone, Inc. | Method for preparing polymetalated compositions |
JPH11116736A (en) * | 1997-10-13 | 1999-04-27 | Bridgestone Corp | Rubber composition and pneumatic tire made of the same |
KR100290438B1 (en) | 1998-12-19 | 2001-10-26 | 박찬구 | Manufacturing Method of Double-Ended Modified Random Copolymer |
JP5738179B2 (en) | 2008-04-14 | 2015-06-17 | 株式会社ブリヂストン | Method for recovering rubber from natural rubber latex |
KR101044070B1 (en) | 2008-09-23 | 2011-06-27 | 주식회사 엘지화학 | Bifunctional organolithium initiator and conjugated dienes polymerized from the same |
JP5513338B2 (en) * | 2010-09-24 | 2014-06-04 | 株式会社ブリヂストン | Butadiene polymer, process for producing the same, rubber composition and tire |
JP5281109B2 (en) * | 2011-04-05 | 2013-09-04 | 住友ゴム工業株式会社 | Rubber composition for cap tread and studless tire |
RU2630489C2 (en) | 2012-03-06 | 2017-09-11 | Бриджстоун Корпорейшн | Method of distribution of rubbers from plants not potentially presented by geves |
JP2013185059A (en) * | 2012-03-07 | 2013-09-19 | Bridgestone Corp | Polymer and producing method thereof, rubber composition containing the polymer, and tire having the rubber composition |
RU2017140651A (en) | 2012-05-16 | 2019-02-12 | Бриджстоун Корпорейшн | COMPOSITIONS CONTAINING CLEANED RUBBER RECEIVED FROM A NON-GEWAI, AND RELATED CLEANING METHODS |
US10471473B2 (en) | 2012-06-18 | 2019-11-12 | Bridgestone Corporation | Systems and methods for the management of waste associated with processing guayule shrubs to extract rubber |
ES2740752T3 (en) | 2012-06-18 | 2020-02-06 | Bridgestone Corp | Method for solvent extraction from bagasse |
ES2633958T3 (en) | 2012-06-18 | 2017-09-26 | Bridgestone Corporation | Methods to increase the removable rubber content of plant material other than hevea |
ITMI20121495A1 (en) * | 2012-09-07 | 2014-03-08 | Versalis Spa | PROCEDURE FOR THE PREPARATION OF DIENIC POLYMERS OR OF VINYLARENE-DIENE STATISTICAL COPOLYMERS |
US9567457B2 (en) | 2013-09-11 | 2017-02-14 | Bridgestone Corporation | Processes for the removal of rubber from TKS plant matter |
IT201600131325A1 (en) * | 2016-12-27 | 2018-06-27 | Pirelli | Elastomeric compositions comprising natural Guayule gums for tire and tire components which comprise them |
JP6926881B2 (en) * | 2017-09-21 | 2021-08-25 | 住友ゴム工業株式会社 | Rubber composition for tread and tires |
US10775105B2 (en) | 2018-11-19 | 2020-09-15 | Bridgestone Corporation | Methods for the desolventization of bagasse |
CN113174116B (en) * | 2021-06-15 | 2022-07-01 | 河北金威新型建筑材料有限公司 | Flexible foam rubber-plastic heat-insulating material |
Family Cites Families (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL114097C (en) * | 1950-11-20 | |||
US3135716A (en) * | 1958-11-06 | 1964-06-02 | Phillips Petroleum Co | Process for preparing terminally reactive polymers |
US3157604A (en) * | 1960-10-24 | 1964-11-17 | Phillips Petroleum Co | Polymerization initiators |
US3193590A (en) * | 1961-08-10 | 1965-07-06 | Phillips Petroleum Co | Method of preparing organolithium polymerization initiators |
US3159587A (en) * | 1961-08-21 | 1964-12-01 | Phillips Petroleum Co | Organopolylithium polymerization initiators and their preparation |
US3296150A (en) * | 1962-08-27 | 1967-01-03 | Phillips Petroleum Co | Organopolylithium polymerization initiators and their preparation |
US3303225A (en) * | 1962-12-26 | 1967-02-07 | Phillips Petroleum Co | Production of polymetallated 1-acetylenes |
US3438957A (en) * | 1964-11-09 | 1969-04-15 | Phillips Petroleum Co | Metalated acetylenic polymers and their preparation |
US3640899A (en) * | 1969-01-30 | 1972-02-08 | Phillips Petroleum Co | Reaction product of hydrocarbylmonolithium and 1 3-butadiene as polymerization initiator |
US3784637A (en) * | 1969-01-30 | 1974-01-08 | Phillips Petroleum Co | Multifunctional polymerization initiators from vinylsilanes or vinylphosphines and organomonolithium compounds |
US3787510A (en) * | 1969-02-03 | 1974-01-22 | Phillips Petroleum Co | Multifunctional polymerization initiators |
US3644322A (en) * | 1969-02-03 | 1972-02-22 | Phillips Petroleum Co | Polymerization of conjugated dienes and monovinyl aromatic compounds with multifunctional polymerization initiators |
US3668263A (en) * | 1970-01-19 | 1972-06-06 | Lithium Corp | Organolithium polymerization initiators and use thereof in polymerization processes |
US3725368A (en) * | 1970-01-19 | 1973-04-03 | Lithium Corp | Preparation of polymers |
US3769267A (en) * | 1971-02-16 | 1973-10-30 | Firestone Tire & Rubber Co | Process for polymerization of conjugated dienes |
US4028484A (en) * | 1971-10-29 | 1977-06-07 | Morton Avery A | Alfin polymerized rubber |
US3954894A (en) * | 1973-05-18 | 1976-05-04 | Lithium Corporation Of America | Organotrilithium polymerization initiators |
JPS5223380B2 (en) * | 1973-09-12 | 1977-06-23 | ||
US3903168A (en) * | 1973-11-23 | 1975-09-02 | Du Pont | Stable anionic polymerization initiator |
JPS533791B2 (en) * | 1974-05-15 | 1978-02-09 | ||
US3984387A (en) * | 1974-08-07 | 1976-10-05 | The Dow Chemical Company | Preparation of linear α-olefin polymers having ultra high molecular weight |
US4189555A (en) * | 1974-12-23 | 1980-02-19 | Compagnie Generale Des Etablissements Michelin | Continuous solution polymerization process |
US3975453A (en) * | 1975-02-24 | 1976-08-17 | Foote Mineral Company | Process for preparing butynyllithium |
US4201848A (en) * | 1976-01-01 | 1980-05-06 | Japan Synthetic Rubber Co., Ltd. | Process for preparing polymers having high molecular weight |
US4196154A (en) * | 1977-10-11 | 1980-04-01 | The Dow Chemical Company | Soluble multifunctional lithium containing initiator |
JPS5527337A (en) * | 1978-08-18 | 1980-02-27 | Asahi Chem Ind Co Ltd | Isoprene-butadiene copolymer rubber having improved processability |
US4339397A (en) * | 1979-11-26 | 1982-07-13 | Shin-Etsu Chemical Co., Ltd. | Method for the preparation of a sodium salt of 1-alkyne compound |
US4497748A (en) * | 1981-07-13 | 1985-02-05 | The General Tire & Rubber Company | Preparation of lithium initiator for the preparation of star polymers |
CA1196139A (en) * | 1982-02-26 | 1985-10-29 | Hiroshi Furukawa | Elastomer composition |
US4399078A (en) * | 1982-03-15 | 1983-08-16 | Lithium Corporation Of America | Hydrocarbon solvent solutions of complexes of N-butyllithium and ethyllithium |
US4859748A (en) * | 1982-04-02 | 1989-08-22 | The Dow Chemical Company | Process for anionic polymerization in a continuous stirred tank reactor |
JPS59102602A (en) * | 1982-12-01 | 1984-06-13 | Bridgestone Corp | Pneumatic radial tire |
US4429091A (en) * | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators |
JPS60215403A (en) * | 1984-04-10 | 1985-10-28 | Bridgestone Corp | Low fuel consumption tire with all weather performance |
DE3580213D1 (en) * | 1984-07-18 | 1990-11-29 | Bridgestone Corp | RUBBER BLOCK FOR RUNNINGS. |
JPH0662727B2 (en) * | 1984-08-27 | 1994-08-17 | 日本合成ゴム株式会社 | Rubber composition |
JPS61203145A (en) * | 1985-03-05 | 1986-09-09 | Bridgestone Corp | Rubber composition for tire tread |
JPS6236437A (en) * | 1985-08-12 | 1987-02-17 | Bridgestone Corp | Tire tread rubber composition |
JPS6296545A (en) * | 1985-10-23 | 1987-05-06 | Yokohama Rubber Co Ltd:The | Rubber composition for tire tread |
DE3772476D1 (en) * | 1986-01-10 | 1991-10-02 | Asahi Chemical Ind | RUBBER-LIKE POLYMERS FOR TIRE PATHS, A METHOD FOR THE PRODUCTION THEREOF, AND COMPOSITIONS THAT CONTAIN THESE POLYMERS. |
JPH06104760B2 (en) * | 1986-10-17 | 1994-12-21 | 日本合成ゴム株式会社 | Rubber composition |
JPS63118343A (en) * | 1986-11-07 | 1988-05-23 | Japan Synthetic Rubber Co Ltd | Conjugated diene rubber composition |
JPH0653833B2 (en) * | 1987-01-13 | 1994-07-20 | 横浜ゴム株式会社 | Rubber composition for tire tread |
DE3711920A1 (en) * | 1987-04-08 | 1988-10-27 | Basf Ag | METHOD FOR PRODUCING MULTIFUNCTIONAL INITIATORS FOR ANIONIC POLYMERIZATION, OLIGOMERS MULTIFUNCTIONAL INITIATORS, USE OF THE POLYMER RECEIVED FOR PRODUCING OPTIONALLY FUNCTIONALIZED POLYMERS AND ALSO PREPARATIONS |
US4871794A (en) * | 1987-06-30 | 1989-10-03 | Bridgestone Corporation | Pneumatic tires |
-
1990
- 1990-09-21 US US07/586,065 patent/US5272203A/en not_active Expired - Lifetime
-
1991
- 1991-09-19 DE DE69128862T patent/DE69128862T2/en not_active Expired - Lifetime
- 1991-09-19 EP EP91115926A patent/EP0476640B1/en not_active Expired - Lifetime
- 1991-09-19 ES ES91115926T patent/ES2111549T3/en not_active Expired - Lifetime
- 1991-09-20 JP JP26861091A patent/JP3157216B2/en not_active Expired - Fee Related
- 1991-09-20 CA CA002051937A patent/CA2051937C/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0476640A1 (en) | 1992-03-25 |
EP0476640B1 (en) | 1998-02-04 |
CA2051937C (en) | 2005-08-09 |
JP3157216B2 (en) | 2001-04-16 |
ES2111549T3 (en) | 1998-03-16 |
US5272203A (en) | 1993-12-21 |
JPH04252242A (en) | 1992-09-08 |
DE69128862D1 (en) | 1998-03-12 |
DE69128862T2 (en) | 1998-05-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed | ||
MKEC | Expiry (correction) |
Effective date: 20121202 |