CA2067286A1 - Hydrides of lithiated nickel dioxide and secondary cells prepared therefrom - Google Patents

Hydrides of lithiated nickel dioxide and secondary cells prepared therefrom

Info

Publication number
CA2067286A1
CA2067286A1 CA2067286A CA2067286A CA2067286A1 CA 2067286 A1 CA2067286 A1 CA 2067286A1 CA 2067286 A CA2067286 A CA 2067286A CA 2067286 A CA2067286 A CA 2067286A CA 2067286 A1 CA2067286 A1 CA 2067286A1
Authority
CA
Canada
Prior art keywords
hydrides
disclosed
nickel
secondary cells
prepared therefrom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2067286A
Other languages
French (fr)
Other versions
CA2067286C (en
Inventor
Ulrich Von Sacken
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Moli Energy Canada Ltd
Original Assignee
NEC Moli Energy Canada Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Moli Energy Canada Ltd filed Critical NEC Moli Energy Canada Ltd
Publication of CA2067286A1 publication Critical patent/CA2067286A1/en
Application granted granted Critical
Publication of CA2067286C publication Critical patent/CA2067286C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
    • C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
    • C01B6/246—Hydrides containing at least two metals; Addition complexes thereof also containing non-metals other than hydrogen
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

Hydrides of lithiated nickel dioxide are disclosed, prepared by providing a substantially homogeneous dry intermediate mixture of a starting material containing a nickel compound selected from nickel oxide, nickel hydroxide and mixtures thereof, and optionally including one or more oxides or hydroxides of a transition metal selected from cobalt, iron, chromium, titanium, manganese and vanadium, together with about a 25% stoichiometric excess of lithium hydroxide. The mixture is heat-treated at a temperature above about 600°C in an atmosphere having a partial pressure of water vapor greater than about two torr.
Electrochemical cells are also disclosed, incorporating the disclosed hydrides as a cathode-active material.
CA002067286A 1992-01-30 1992-04-27 Hydrides of lithiated nickel dioxide and secondary cells prepared therefrom Expired - Fee Related CA2067286C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/828,772 US5180574A (en) 1990-07-23 1992-01-30 Hydrides of lithiated nickel dioxide and secondary cells prepared therefrom
US07/828,772 1992-01-30

Publications (2)

Publication Number Publication Date
CA2067286A1 true CA2067286A1 (en) 1993-07-31
CA2067286C CA2067286C (en) 1998-02-03

Family

ID=25252708

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002067286A Expired - Fee Related CA2067286C (en) 1992-01-30 1992-04-27 Hydrides of lithiated nickel dioxide and secondary cells prepared therefrom

Country Status (6)

Country Link
US (1) US5180574A (en)
EP (1) EP0554649B1 (en)
JP (2) JP3419800B2 (en)
AT (1) ATE152292T1 (en)
CA (1) CA2067286C (en)
DE (1) DE69219304T2 (en)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5264201A (en) * 1990-07-23 1993-11-23 Her Majesty The Queen In Right Of The Province Of British Columbia Lithiated nickel dioxide and secondary cells prepared therefrom
CA2110097C (en) * 1992-11-30 2002-07-09 Soichiro Kawakami Secondary battery
DE69411637T2 (en) * 1993-04-28 1998-11-05 Fuji Photo Film Co Ltd Accumulator with non-aqueous electrolyte
EP0653797B1 (en) * 1993-05-31 1999-02-24 Hitachi Maxell, Ltd. Lithium secondary cell containing organic electrolyte, active material for positive electrode of lithium secondary cell, and method for manufacturing the active material
JPH07130367A (en) * 1993-10-29 1995-05-19 Sony Corp Manufacture of positive active material for lithium secondary battery
DE69512182T2 (en) * 1994-11-22 2000-04-06 Sumitomo Chemical Co Cathode for lithium secondary battery and process for its manufacture
DE19520874A1 (en) * 1994-12-15 1996-06-20 Basf Magnetics Gmbh Spinels containing lithium and manganese (III / IV)
JP3329124B2 (en) * 1995-03-03 2002-09-30 松下電器産業株式会社 Manufacturing method of positive electrode active material for non-aqueous electrolyte secondary battery
US5591548A (en) * 1995-06-05 1997-01-07 Motorola, Inc. Electrode materials for rechargeable electrochemical cells and method of making same
US5955051A (en) * 1996-08-02 1999-09-21 Westaim Technologies Inc. Synthesis of lithium nickel cobalt dioxide
JPH10106566A (en) * 1996-09-24 1998-04-24 Japan Storage Battery Co Ltd Manufacture of positive electrode active material for lithium secondary battery
CN1164002C (en) * 1996-11-08 2004-08-25 日本电池株式会社 Lithium battery
CN1185666A (en) * 1996-11-18 1998-06-24 日本电池株式会社 Positive pole-plate for lithium cell and lithium cell thereof
US5766797A (en) * 1996-11-27 1998-06-16 Medtronic, Inc. Electrolyte for LI/SVO batteries
US6017656A (en) * 1996-11-27 2000-01-25 Medtronic, Inc. Electrolyte for electrochemical cells having cathodes containing silver vanadium oxide
US6277521B1 (en) 1997-05-15 2001-08-21 Fmc Corporation Lithium metal oxide containing multiple dopants and method of preparing same
WO1998054772A1 (en) 1997-05-27 1998-12-03 Tdk Corporation Method of producing an electrode for non-aqueous electrolytic cells
US6112448A (en) * 1997-06-30 2000-09-05 Gray; Robert Firearm forearm sling and method of use of same
EP0938148B1 (en) * 1997-07-15 2008-05-07 Sony Corporation Non-aqueous electrolyte secondary cell
CA2320155C (en) * 1998-02-09 2006-07-25 H.C. Starck Gmbh & Co. Kg Process for preparing lithium transition metallates
TW416166B (en) 1998-03-13 2000-12-21 Toshiba Battery Manufacturing method of anode active material of alkaline battery, the anode using the active material, and manufacturing method of alkaline battery using the anode
JP3524762B2 (en) * 1998-03-19 2004-05-10 三洋電機株式会社 Lithium secondary battery
US6045950A (en) * 1998-06-26 2000-04-04 Duracell Inc. Solvent for electrolytic solutions
US6267943B1 (en) 1998-10-15 2001-07-31 Fmc Corporation Lithium manganese oxide spinel compound and method of preparing same
KR100578862B1 (en) * 1998-10-30 2006-08-18 삼성에스디아이 주식회사 Pole plate manufacturing method for lithium ion battery
AU1720000A (en) 1998-11-13 2000-06-05 Fmc Corporation Layered lithium metal oxides free of localized cubic spinel-like structural phases and methods of making same
EP1135334B1 (en) 1998-11-20 2002-10-09 Fmc Corporation Multiple doped lithium manganese oxide compounds and methods of preparing same
KR100307160B1 (en) * 1999-03-06 2001-09-26 김순택 A positive active material for a lithium secondary battery and a method of preparing the same
DE60002505T2 (en) 1999-12-10 2004-03-25 Fmc Corp. LITHIUM COBALTOXIDES AND PRODUCTION METHOD
US6350543B2 (en) 1999-12-29 2002-02-26 Kimberly-Clark Worldwide, Inc. Manganese-rich quaternary metal oxide materials as cathodes for lithium-ion and lithium-ion polymer batteries
JP4963777B2 (en) * 2001-08-24 2012-06-27 ソニー株式会社 battery
FR2846648B1 (en) 2002-10-31 2005-01-28 Centre Nat Rech Scient STORAGE OF HYDROGEN IN SOLID COMPOSITIONS BASED ON MIXED OXIDES.
JPWO2006123531A1 (en) * 2005-04-28 2008-12-25 株式会社ジーエス・ユアサコーポレーション Method for producing positive electrode using proton-containing nickel-based transition metal oxide
JP2007134218A (en) * 2005-11-11 2007-05-31 Kansai Electric Power Co Inc:The Nonaqueous electrolyte secondary battery
JP5003030B2 (en) * 2006-06-27 2012-08-15 株式会社Ｇｓユアサ Cathode active material for nonaqueous electrolyte secondary battery, method for producing the same, and nonaqueous electrolyte secondary battery including the same
JP4765895B2 (en) * 2006-10-30 2011-09-07 株式会社Ｇｓユアサ Non-aqueous electrolyte battery
JP5316512B2 (en) * 2010-10-29 2013-10-16 株式会社豊田中央研究所 Garnet-type ion conductive oxide and method for producing the same
US8703336B2 (en) 2012-03-21 2014-04-22 The Gillette Company Metal-doped nickel oxide active materials
US9028564B2 (en) 2012-03-21 2015-05-12 The Gillette Company Methods of making metal-doped nickel oxide active materials
US9570741B2 (en) 2012-03-21 2017-02-14 Duracell U.S. Operations, Inc. Metal-doped nickel oxide active materials
JP5892048B2 (en) * 2012-11-20 2016-03-23 住友金属鉱山株式会社 Coated nickel hydroxide powder for positive electrode active material of alkaline secondary battery and method for producing the same
JP5842794B2 (en) * 2012-11-20 2016-01-13 住友金属鉱山株式会社 Coated nickel hydroxide powder for positive electrode active material of alkaline secondary battery and method for producing the same

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0017400B1 (en) * 1979-04-05 1984-05-30 United Kingdom Atomic Energy Authority Electrochemical cell and method of making ion conductors for said cell
US4567031A (en) * 1983-12-27 1986-01-28 Combustion Engineering, Inc. Process for preparing mixed metal oxides
CA1245280A (en) * 1984-06-15 1988-11-22 Balaraman Mani Active material and cathode for electrochemical cells
US4770960A (en) * 1986-04-30 1988-09-13 Sony Corporation Organic electrolyte cell
JPH0687419B2 (en) * 1986-07-10 1994-11-02 日本電池株式会社 Method for producing positive electrode active material for non-aqueous electrolyte battery
JP2668678B2 (en) * 1986-11-08 1997-10-27 旭化成工業株式会社 Rechargeable battery
US4980080A (en) * 1988-06-09 1990-12-25 Societe Anonyme Dite: Saft Process of making a cathode material for a secondary battery including a lithium anode and application of said material
US5264201A (en) * 1990-07-23 1993-11-23 Her Majesty The Queen In Right Of The Province Of British Columbia Lithiated nickel dioxide and secondary cells prepared therefrom

Also Published As

Publication number Publication date
JP2002179426A (en) 2002-06-26
ATE152292T1 (en) 1997-05-15
CA2067286C (en) 1998-02-03
EP0554649B1 (en) 1997-04-23
DE69219304D1 (en) 1997-05-28
JPH0668878A (en) 1994-03-11
EP0554649A1 (en) 1993-08-11
DE69219304T2 (en) 1997-08-14
JP3419800B2 (en) 2003-06-23
US5180574A (en) 1993-01-19

Similar Documents

Publication Publication Date Title
CA2067286A1 (en) Hydrides of lithiated nickel dioxide and secondary cells prepared therefrom
CA2038631A1 (en) Lithiated nickel dioxide and secondary cells prepared therefrom
CA2365562A1 (en) Nonaqueous electrolyte secondary battery
TW377338B (en) Cathode materials for lithium-ion secondary cells
HK1063381A1 (en) Improved cathode compositions for lithium-ion batteries
EP1347524A4 (en) Positive electrode active material and nonaqueous electrolyte secondary cell
EP0918041A4 (en) Lithium/nickel/cobalt composite oxide, process for preparing the same, and cathode active material for rechargeable battery
CA2055305A1 (en) Nonaqueous electrolyte secondary battery
CA2369030A1 (en) Positive electrode active material and lithium ion secondary battery
EP1117145A4 (en) Nonaqueous electrolyte secondary cell
EP0849817A3 (en) Positive active material for lithium battery having the same, and method for producing the same
KR100304432B1 (en) Manganese-containing nickel hydroxide for manufacturing secondary batteries
WO2003063273A3 (en) Stabilized electrochemical cell active material
CA2271516A1 (en) Method for making lithiated manganese oxide
CA2032530A1 (en) Air assisted alkaline cells
DE59601058D1 (en) ELECTROCHEMICAL LITHIUM SECONDARY ELEMENT
CA2162216A1 (en) Manganese(iii)-doped nickel (ii) hydroxide powders
EP1107338A3 (en) Lithium manganese compound oxide and non-aqueous electrolyte secondary battery
AU1739200A (en) Multiple doped lithium manganese oxide compounds and methods of preparing same
EP1052710A4 (en) Non-aqueous electrolyte secondary cell
JPH07320784A (en) Nonaqeous electrolytic lithium secondary battery
Thirunakaran et al. Electrochemical behaviour of LiM y Mn 2− y O 4 (M= Cu, Cr; 0≤ y≤ 0.4)
AU1938797A (en) Gallium doped lithium manganese oxide spinels (ligaxmn2-xo4) as active cathode material for lithium or lithium-ion rechargeable batteries with improved cycling performance
Xia et al. Studies on the Li Mn O spinel system (obtained from melt-impregnation method) as positive electrodes for 4 V lithium batteries. Part III. Characterization of capacity and rechargeability
CA2298095A1 (en) Lithium secondary battery

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed