CA2069687A1 - Tobacco smoking article with electrochemical heat source - Google Patents

Abstract

ABSTRACT

A tobacco smoking article with an electro-chemical heat source is disclosed. The non-combustion heat source includes at least two metallic agents capable of interacting electrochemically with one another, such as magnesium and iron or nickel. The metallic agents may be provided in a variety of forms, including a frozen melt, a bimetallic foil, wire of a first metal wrapped around strands of a different metal, and a mechanical alloy. The metallic agents may be in the form of a powder filling a straw, or small particles extruded with a binder or pressed to form a rod. The powder filled straw or rod may be placed in a heat chamber surrounded by tobacco. An electrolyte solution contacts the metallic agents in the heat chamber to initiate the electrochemical interaction, generating heat which in turn volatilizes the nicotine and flavor materials in the tobacco.
Processes for producing flavor substances from tobacco are also disclosed. The processes involve heating tobacco during a first staged heating to a first toasting temperature to drive off volatile materials; increasing the toasting temperature during a second staged heating to a second toasting temperature and separately collecting, as flavor substances, at least portions of the volatile materials driven off at the first and second toasting temperatures. Prefer-ably, the moisture content of the tobacco is reduced without removing volatile flavor components, such as by freeze drying the tobacco, and then heating the dried tobacco.

Description

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~ SMOKING ARTICLE
- WITH ELECTROCHEMICAL
HEAT SOURCE

BACKGROUND OF THE INVENTION
The present invention relates to cigarettes ~` and other smoking articles such as cigars, pipes, and the like, and in particular, to smoking articles which employ a relatively low temperature heat source to heat tobacco to produce a tobacco flavor or tobacco-flavored aerosol. The invention also relates to processes for extracting flavor substances from tobacco; and to : . ~
smoking articles made, at least in part, with extracted ~:~ tobacco flavor substances. Further, the present ~: 15 invention relates to methods of forming electrochemical heat sources, and in particular to electrochemical heat sources to heat tobacco to produce a tobacco flavor or ~` tobacco^flavored aerosol.
Preferred smoking articles of the invention ~r; 20 are capable of providing the user with the pleasures of smoking (e.g., smoking taste, feel, satisfaction, and !, the like), without burning tobacco or any other material, without producing sidestream smoke or odor, and without producing cQmbustion products such as carbon monoxide. As used herein, the term ~smoking article" includes cigarettes, cigars, pipes, and the like, which use to~acco in various forms.

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2a~687 Many smoking articles have been proposed through the years as improvements upon, or alternatives to, smoking products which burn tobacco.
- Many tobacco substitute smoking materials have been proposed, and a substantial listing of such materials can be found in U.S. Pat. No. 4,079,742 to Rainer et al. Tobacco substitute smoking materials having the tradenames Cytrel and NSM were introduced in Europe during the 1970's as partial tobacco replace-ments, but did not realize any long-term commercial success.
Numerous references have proposed smoking articles which generate ~lavored vapor and/or visible aerosol. Most of such articles have employed a combustible fuel source to provide an aerosol and/or to heat an aerosol forming substance. See, for example, the background art cited in U.S. Pat. No. 4,714,082 to Banerjee et al.
However, despite decades of interest and effort, no one had successfully developed a smoking article which provided the sensations associated with cigarette or pipe smoking, without delivering considerable quantities of incomplete co~bustion and pyrolysis products.
Recently, however, in U.S. Pat. Nos.
4,7~8,151 to Shelar, 4,714,082 to Banerjee et al., ; 4,756,318 to Clearman et al. and 4,793,365 to Sensabaugh et al., there are described smoking articles which are capable of providing the sensations associ-ated with cigarette and pipe smoking, without burning tobacco or delivering considerable quantities of incom-plete combustion products. ~uch articles rely on the combustion of a fuel element ~or heat generation, resulting in the production o~ some combustion products.

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; Over the years, there have been proposed numerous smoking products which utilize various forms of energy to vaporize or heat tobacco, or attempt to provide the sensations of cigarette or pipe smoking ` 5 wi~hout burning any substance. For example, U.S. Pat.
~`~ No. 2,104,266 to McCormick proposed an article having a pipe bowl or cigarette holder which included an electrical resistance coil. Prior to use of the article, the pipe bowl was filled with tobacco or the holder was fitted with a cigarette. Current was then passed through the resistance coil. Heat produced by ~ the resistance coil was transmitted to the tobacco in `~ the bowl or holder, resulting in the volatilization of various ingredients from the tobacco.
U.S. Pat. No. 3,258,015 and Australian Patent No. 276,250 to Ellis et al. proposed, among other embodiments, a ~moking article having cut or shredded tobacco mixed with a pyrophorous material such as finely divided aluminum hydride, boron hydride, calcium oxide or fully activated molecular sieve~. In U8P, the pyrophorous material generates heat which reportedly -~ heated the tobacco to a temperature between 200C and ~00C to cau~e the tobacco to relea~e volatilizable materials. Ellis et al. also proposed a ~moking article including cut or shredded tobacco separated from a ~ealed pyrophorous material such as finely divided metallic particles. In use, the metallic par~icles were exposed to air to generate heàt which reportedly heated the tobacco to a temperature between 200C and 400C to release aerosol forming material~
from the tobacco.
PCT Publication No. WO 86/02528 to Nilsson et al. proposed an article similar to that described by McCormick. Nilsson et al. proposed an article for releasing volatiles from a tobacco material which had 913/77C:3 :

2 ~ 7 been treated with an aqueous solution of sodium carbonate. The article resembled a cigarette holder and reportedly included a battery operated heating coil to heat an untipped cigarette inserted therein. Air drawn through the device reportedly was subjected to elevated temperatures below the combustion temperature of tobacco and reportedly liberated tobacco flavors from the treated tobacco contained therein. Nilsson et al. also proposed an alternate source of heat whereby - 10 two liquids were mixed to produce heat.
Despite many years of interest and effort, none of the foregoing non-combustion articles has ever realized any significant commercial success, and it is believed that none has ever been widely marketed.
Moreover, it i8 believed that none of the foregoing non-combustion articles is capable of adequately providing the user with many of the pleasures of cigarette or pipe smoking.
In addition, natural tobacco flavors are important for the taste, aroma and acceptance of smoking products, including substitute smoking materials. Thus, the search for natural tobacco flavor additives (or flavor substances) is a continuing task.
For instance, U.S. Patent No. 3,424,171 describes a process for the production of a non-tobacco smokable product having a tobacco taste. Tobacco i8 subjected to a moderate (i.e., below scorching) heat treatment, i.e., at from about 175 to 200C (or about 350-400F), to drive off aromatic component~ These components are trapped on ad~orbent charcoal, and removed from the charcoal by solvent extraction. The smokable product disclosed is vegetable matter, treated with the mixture of tobacco aromatic components and the solvent.

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Similarly, U.S. Patent No. 4,150,677 describes a process for the treatment of tobacco which comprises the steps of~ contacting tobacco which contains relatively high quantities of desirable flavorants with a stream of non-reactive gas, under conditions whereby the tobacco is heated in a - temperature range from about 140 to about 180C;
(2) condensing the volatile constituents of the resulting gaseous stream; and (3) collecting said 1~ condensate. The condensate may be used subsequently to flavor a smoking material in order to enhance the organoleptic properties of its smoke.
British Patent No. 1,383,029 describes a method for obtaining tobacco aroma ~ubstances which comprises an extraction treatment wherein the components of the tobacco that are soluble in a suitable ~olvent are extracted and the residue obtained after removing the ~olvent i8 aubjected to heat treatment at a temperature from 30~ to 260C.
Similarly, U.S. Patent No. 3,316,919 describes a process for improving the taste of smoking tobacco that entail~ adding a powder of freeze dried aqueous tobacco extract to tobacco cut filler in amounts ranging from about 5 to 10~ by weight.
U.S. Patents Nos. 5,038,802 to White et al.
and 5,016,654 to Bernasek et al. disclose extraction proce~ses which heat tobacco and then pass an inert atmosphere through the heating chamber to collect ~ volatiles from the tobacco. The volatiles are then - 30 fractionated in downstream operations, which include liquid sorbents, cold temperature traps and filtera.
While these proce~e~ have produced flavor ~ubstances acceptable for use in many smoking articles, they ha~e either not been suitable for some ~moking articles, such as those that u~e a heat source that 913/77C:5 .

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generates a low temperature in ~he substrate to which they are applied, or they have not been applied to such substrates in a fashion that permits an optimum release therefrom.
Thus, it would be desirable to provide processes for producing better flavor substances from tobacco and smoking articles which utilize extracted tobacco flavors in a manner so as to obtain an optimum release of the flavor substances from the smoking article. It would also be desirable to provide a smoking article which can provide many of the pleasures of cigarette or pipe smoking, which does not burn tobacco or other material, and which does not produce any combustion products.
SUMMARY OF THE INVENTION
The present invention relates to cigarettes and other smoking articles which normally employ a non-combustion heat sourcè for heating tobacco to provide a tobacco flavor and other pleasures of smoking to the user thereof. Preferred tobacco smoking articles of the present invention produce controlled amounts of volatilized tobacco flavors and other substances which do not volatilize to any significant degree under ambient conditions, and such volatilized substances can be provided throughout each puff, for at least 6 to 10 puffs, the normal number of puffs for a typical cigarette.
More particularly, the present invention relates to cigarettes and other tobacco smoking articles having a heat source which generates heat in a controlled manner as a result of one or more electro-chemical interactions between the components thereof.
In one aspect, the tobacco, which can be in a processed form, is positioned physically separate from, and in a 913/77C:6 ,:

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heat exchange relationship with, the heat source. By "physically separate" it is meant that the tobacco used for providing flavor is not mixed with, or is not a part of, the heat source.
The heat source includes at least two metallic agents which are capable of interacting electrochemically with one another. The metallic agents can be provided within the smoking article in a variety of ways. For example, the metallic agents and an undissociated electrolyte can be mixed within the smoking article, and interactions therebetween can be initiated upon the introduction of a solvent for the electrolyte. Alternatively, the metallic agents can be provided within the smoking article, and interactions therebetween can be initiated upon the introduction of an electrolyte solution.
A preferred heat source is a mixture of solid components which provide the desired heat delivery upon in`teraction of certain components thereof with a liquid solvent, such as water. For example, a solid mixture of granular magnesium and iron particles, granular potassium chloride crystals, and finely divided cellu-lose can be contacted with li~uid water to generate heat. Heat i9 generated by the exothermic hydroxyla-tion of magnesium; and the rate of hydroxylation of the magnesium i9 accelerated in a controlled manner by the electrochemical interaction between magne~ium and iron, which interaction is initiated when the potassium chloride electrolyte dissociates upon contact with the liquid water. m e cellulose is employed as a di~pers-ing agent to space the components of the heat source, as well as to act as a reservoir for the electrolyte and solvent, and hence control the rate of the exothermic hydrox~lation reaction. Preferred heat ; 35 sources also include, or are used with electrolytes ,':
913/77C:7 which include, an oxidizing agent in an amount suffi-cient to oxidize reaction products of ~he hydroxylation reaction, and hence generate a further amount of heat and water. An example of a suitable oxidizing agent is sodium nitrate.
Preferred heat sources generate relatively ... .
large amounts of heat to rapidly heat at least a portion of the tobacco to a temperature suf~icient to volatilize flavorful components from the tobacco. For example, preferred smoking articles employ a heat - source capable of heating at least a portion of the tobacco to ahove about 70C within about 30 seconds from the time that the heat source i9 activated.
Preferred smoking articles employ heat sources which avoid excessive heating of the tobacco and maintain the tobacco within a desired temperature range for about 4 to about 8 minutes or longer. For the preferred smoking article3, the heat source thereof heat~ the tobacco contained therein to a temperature range between about 70C and about 180C, more preferably between about 85C and about 120C, during the useful life of the ~moking article.
The tobacco can be processed or otherwise ; treated so that the flavorful components thereof readily volatilize at those temperatures experienced during use. In addition, the tobacco can contain or carry a wide range of added flavor~ and aerosol forming substances which volatilize at tho3e temperatures experienced during use. For example, depending upon the temperature generated by the heat source, the smoking article can yield, in addition to the flavorful volatile components of the tobacco, a flavor such as menthol, and/or a viæible aerosol provided by an aerosol forming substance (e.g., propylene glycol, glycerin).
913/77C:8 " ' ' - ' ~' -2~J~

To use the smoking article of the invention, the smoker initiates the interactions between the components of the heat source, and heat is generated.
The interaction of the components of the heat source provides sufficient heat to heat the tobacco, and tobacco flavors and other flavoring substances are volatilized from the tobacco. When the smoker draws on the smoking article, the volatilized substances pass through the smoking article and into the mouth of the smoker. As such, the smoker is provided with many of the flavors and other pleasures associated with ' cigarette smoking without burning any materials.
It has also been discovered that better flavor release can be obtained from smoking articles that incorporate extracted tobacco flavor substances ! applied to a substrate if the substances are separately extracted and are then applied separately to a plurality of individual segments of the substrate.
Thus one aspect of the present in~ention is a smoking ar~icle comprising separately extracted tobacco flavor substances applied to a plurality of individual ; segments of a carrier within the smoking article.
Improved processes for producing flavor substances from tobacco have also been discovered.
Thus another aspect of the present invention involves ,~ heating tobacco during a first staged heating to a first toasting temperature to drive off volatile materials; increasing the toasting temperature during a ~econd staged heating to a second toasting temperature - 30 and separately collecting, as flavor substances, at least portions of the volatile materials driven off at the first and ~econd toasting temperatures~
Another aspect of the present invention involves reducing the moisture content of the tobacco without removing volatile fla~or components, such as by . .
-, 913/77C:9 ., ., ~, ,~, :
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. ~ - ~ ' ' :' 2 ~ 3 7 freeze drying the tobacco, and then heating the dried tobacco at a toasting temperature to drive off volatile materials, at least a portion of which are then collected.
In another aspect of the present invention, tobacco is heated in a flowing gas stream at a toasting temperature to drive off volatile materials, and at least portions of the volatile materials are separately collected as flavor substances as the gas stream passes sequentially through a moderate temperature trap, a - cold temperature trap and a filter capable of collecting submicron sized particles.
Flavor 3ubstances produced by these various processes of the invention have been found to provide better flavor than previously known extracted flavor æubstances when employed in tobacco smoking articles, particularly those in which the carrier to which they are applied is heated to a low temperature, ~uch as :.
between about 80C and about 200C. Al~o, it has been found that when separately extracted flavor substances are applied to individual segments of a carrier in a smoking article, the substances are released in a more ; optimum fashion, developing a more desirable flavor.
These and other advantage~ of the present invention, as well as the invention it~elf, will be .: best understood in view of the accompanying drawing~
and detailed description of the invention which follows .
','' BRIEF DESCRIPTION OF THE DRAWINGS
.' FIG. 1 is a longitudinal, sectional view of a cigarette of a first preferred embodiment of the present invention;
FI~. 2 is a prospective, exploded view of a cigarette similar to the cigarette shown in FIG. 1;
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2~ it~7 FIG. 3 is a schematic representation of one embodiment of metallic agents capable of interacting electrochemically with one another for use in the cigarettes of FIGS. 1 and 2;
FIG. 4 is a block diagram outlining s~veral alternative methods of producing electrochemical agents for use in the cigarette of FIGS. 1 and 2;
. FIGS. 5, 5a and 5b are schematic representations of another embodiment of a heat source for the cigarette of FIG. 2;
! FIG. 6 is a schematic repre~entation of another embodiment of metallic agents capable of interacting .: electrochemically with one another;
. FIG. 7 is an enlarged elevational view of another embodiment of a heat source for the cigarette of FIG. 1;
; FIGS. 8 and 9 are schematic representations of two : alternative methods of initiating an electrochemicalreaction in the cigarettes of FIGS. 1 and 2;
. 20 FIG. 10 is a schematic representation of another embodiment of a heat source for the cigarette of FIG. 2;
FIG. 11 is a schematic representation of a system for extracting and collecting tobacco flavors;
FIG. 1~ is a graph showing the temperature with : respect to time produced by a heat source used in the present invention;
FIG. 13 is a prospective, exploded view of a .- preferred embodiment of a cigarette of the pre~ent invention; and FIG. 14 is a longitudinal, sectional view of the .'. cigarette of FIG. 13 showing the heat source partially ;~ inserted into the heat chamber.
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DETAILED DESCRIPTION OF PREF'ERRED EMBODIMENTS
Unless specified otherwise, all percentages used herein are percentages by weight.
Referring to FIG. 1, cigarette 9 has an elongated, essentially cylindrical rod shape. The cigarette includes a roll or charge of tobacco 11 wrapped in a generally tubular outer wrap 13 such as cigarette paper, thereby forming a tobacco rod 15. An example of a suitable outer wrap is calcium carbonate and flax fiber cigarette paper a~ailable as Reference No. 719 from Kimberly-Clark Corp. The roll of tobacco 11 may be a blend of tobaccos in cut filler form as shown, or may be in the form of rolled tobacco sheet.
In addition, the preferred tobacco is cased and top dressed with flavoring agents. Within the roll of tobacco filler is positioned a heat chamber 20 having an open end 22 near the air inlet region 25 of the -~ cigarette, and a sealed end 28 toward the mouth end 33 of the tobacco rod 15. The heat chamber 20 can be manufactured from a heat conductive material (e.g., aluminum), a plastic material (e.g., mylar), or any material which i~ heat resistant up to the temperature generated by the heat source. The heat chamber is preferably a good heat conductor, with a low heat capacity. Preferably the heat chamber is light weight, ,!' water impervious, and strong enough so that it does not rupture, even when wet. Even some coated papers may be - used to construct the heat chamber 20. When the heat chamber 2Q i8 manufactured from an electrically conductive material (e.g., aluminum), it i8 preferred that the inner portion of the heat chamber 20 be ;~! composed of an electrically insulative material if no other electrical insulation i9 used in the system.
Within the heat chamber 20 i8 positioned a heat source 35 (discussed in detail hereinafter). In 913/77C:12 :

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the embodiment shown, the heat source 35 is maintained in place within the heat chamber 20 by a plug 38, such t as moisture impermeable, plasticized cellulose acetate tow having a thin surface coating of a low melting ` 5 point paraffin wax, or a resilient open cell foam material covered with a thin coating of paraffin wax.
As such, there is provided a moisture barrier for storage, as well as a material having an air permeable character when the heat source 35 generates heat. The resulting tobacco rod 15 has the heat source 35 embed-ded therein, but such that the tobacco and heat source 35 are physically separate from one another. The tobacco rod 15 has a length which can vary, but gener-ally has a length of about 5 mm to about 90 mm, prefer-ably about 40 mm to about 80 mm, and more preferably , about 55 mm to about 75 mm; and a circumference of about 22 mm to about 30 mm, preferably about 24 mm to abou~ 27 mm.
Filter~element 43 i9 axially aligned with, - 20 and positioned in an end-to-end relationship with the ' tobacco rod 15. Since there are no combustion products, the filter element 43 performs primarily as a mouth piece~ The filter element 43 may be a cellulose acetate tube or may include a filter material 45, such :~ 25 as a gathered or pleated polypropylene web, or the like, and an outer wrapper 47, such as a paper plug wrap. Highly preferred filter element~ 43 exhibit ~o, or relatively low, filtration efficiencies. Normally, the circumference of the filter element 43 i9 similar to that of the tobacco rod 15, and the length ranges from about 10 mm to about 35 mm. A repre~entative filter element 43 can be provided as de~cribed in U.S.
Pat. No. 4,807,809 to Pryor et al. The filter el~ment 43 and tobacco rod 15 are held together using tipping P~ 35 paper 50. Normally, tipping paper 50 has adhesive 913/77C:13 ::

2 Q ~ 7 applied to the inner face thereof, and circumscribes the filter element 43 and an adjacent region of the tobacco rod 15.
The cigarette 9 could also be configured to have the tobacco in the center and the heat source surrounding it, a~ shown in FIGS. 2 and 2A of U.S.
Patent No. 4,938,236.
The cigarette 59 ~hown in PIG. 2 i~ essenti-ally like cigarette 9, and identical parts are numbered identically. The main difference i8 that the heat source 60 of the cigarette 59 includes an outer wrap 64 surrounding the metallic agents 62. Heat source 60 will be discuased in more detail below. FIG. 2 shows how the heat source 60 fits into heat chamber 20.
lS Heat source~ of the ~moking articles of the present in~ention generate heat in the desired amount and at the desired rate a~ a result of one or more electroch~;cal interaction6 between compone~ts thereof, and not as a re~ult of combu~tion of com-ponents of the heat source. As used herein, the term "combu~tion~ relate~ to the oxidation of a sub~tance ~o yield heat and oxides of carbon. See, Baker, Prog.
En~r. Combust. Sci., Vol. 7, pp. 135-153 (1981). In addition, preferred non-co~bustion heat source~ of the present invention generate heat without the nece3sity of the pre~ence of a~y ga~eous or environmental oxygen (i.e., in the absence of atmospheric oxygen).
Preferred heat source~ generate heat rapidly upon initiatio~ of the electrochemical interaction of the components thereof. As such, heat is generated to warm the tobacco to a degree sufficient to volatilize an appropriate amount ~f flavorful components of the tobacco rapidly after the smoker has initiated use of the cigarette. Rapid heat generation also a~ures that ~ufficient volatilized tobacco flavor is provided 913/77C:14 2 ~ $ .~ 7 during the early puffs. Typically, heat sources of the present invention include sufficient amounts of com-ponents which interact to heat at least a portion of the tobacco to a temperature in excess of 70C, more preferably in excess of 80C, within about 60 seconds, more preferably within about 30 ~econds, from the time that the smoker has initiated use of the cigarette.
Preferred heat sources generate heat so that the tobacco is heated to within a desired temperature range during the useful life of the cigarette. For example, although it is desirable for the heat source to heat at least a portion of the tobacco to a tempera-ture in excess of 70C very rapidly when use of the cigarette is initiated, it is also desirable that the tobacco experience a temperature of less than about 180C, preferably less than about 150C, during the typical life of the cigarette. Thus, once the heat source achieves ~ufficient rapid heat generation to heat the tobacco to the desired minimum temperature, the heat source then generates heat sufficient to main-tain the tobacco within a relatively narrow and well controlled temperature range for the remainder of the heat generation period. Thi~ temperature range is preferably maintained for at least 4 minutes, more preferably 8 minutes, and most preferably longer.
Typical temperature ranges for the life of the cigarette are between about 70C and about 180C, more preferably between about 85C and a~out 120C, for moat cigarettes of the present invention. Control of the maximum temperature exhibited by the heat source is desired in order to avoid thermal degradation and/or exce~sive, premature volatilization of the flavorful components of the tobacco and added flavor component~
that may be carried by the tobacco.

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The heat source may come in a variety of configurations. In each instance, the heat source includes at least two metallic agents which can interact electrochemically. The individual metallic agents can be pure metals, metal alloys, or other metallic compounds.
The metallic agents may be simply a mixture of powders. However, preferred configurations of the metallic agents include mechanically bonded metals (sometimes referred to as mechanical alloys), frozen melts of the metallic agents, bimetallic foils and electrically connected wires. With respect to mechanical alloys, frozen melts, and sometimes even with bimetallic foils, the mechanical agents generally are formed into small particles that are later com-pressed or extruded, or packed in a tube, to form the heat source 35 or 60.
Each of the preferred heat source configura-tions uses one of the metallic agents as an anode in an electrochemical interaction and another metallic agent as a cathode. For thi~ to happen, the metallic agents must be in electrical contact with one another. Each of the configurations also uses an electrolyte. In some embodiments, the electrical contact between the metallic agents could be through the electrolyte. A
preferred anode material i8 magnesium, which reacts with water to form magnesium hydroxide (Mg(OH)2) and hydrogen ga~, and generates large amount~ of heat.
Other metallic agents ha~ing high standard oxidation potentials (such as lithium) may also ~erve as the anode material, but are less preferred from a cost and safety ~tandpoint.
The second metallic agent acts as a cathode to speed up the reaction of the anode material. The cathode may be any metallic agent having a lower 913/77C:16 ~ ~ ~ c~ 6 $ 1~

standard oxidation potential than the anode material.
The cathode is not consumed in the electrochemical interaction, but serves as a site for electrons given up by the corroding anode to neutralize positively charged ions in the electrolyte.
Some preferred metallic agents for use in the heat sources of the present invention include iron, copper, nickel, palladium, silver, gold, platinum, carbon, cobalt, magnesium, aluminum, lithium, Fe203, Fe3O4, Mg2Ni, MgNi2, Mg2Ca, MgCa2, MgCo2, and combinations thereof. For example, platinum may be dispersed on carbon and this dispersion used as a cathode material.
A frozen melt 70 is shown schematically in FIG. 3. The melt is prepared by heating the metallic agents until both are melted, and then cooling the melt until it is solid. With some metallic agents, the frozen melt will constitute a multiphase alloy, such as when two metallic agents are not very soluble with one another. Also, in preferred frozen melts, one metallic agent is provided in a concentration such that it precipitates as large crystalline grains 72 in the matrix of smaller eutectic solids 74. FIG. 3 shows an enlarged section of the eutectic matrix 74 depicting crystallites of the individual metallic agents. In preferred embodiments, the grains 72 will be more predominant than shown in FIG. 3, making up the majority of the frozen melt.
One suitable system for forming such a frozen melt is magnesium and nickel. In concentrations of less than about 11.3 atomic percent nickel, as the melt cools, magnesium will precipitate out, raising the "
nickel concentrate of the remaining liquid. At about 11.3 atomic percent nickel, further cooling results in a eutectic of magnesium crystallites and Mg2Ni crystal-lites. For this ~ystem, the grains 72 shown in FIG. 3 913/77C:17 : ~ , : . ' ' 2~5g~ :

would be magnesium and the matrix 74 would be Mg2Ni and magnesium crystallites. The size of the grains 72 would depend on the amount of magnesium present in the original melt and the cooling conditions.
Other cathode materials that are preferred for forming a frozen melt with magnesium include iron, copper, and cobalt, although gold, silver, palladium, or platinum may also be used. Of course other cathode materials besides magnesium may be used. Any metallic agents that can be melted together, or physically mixed together while melted, may be used, though some systems that do not form solutions may be hard to work with.
It is not necessary for the system to form a eutectic.
Also, it i~ preferable to use melts that are pre-dominantly the metallic agent which will serve as the anode in the electrochemical interaction, such as magnesium in the magnesium-nickel system, since the cathode is not consumed. A preferred frozen melt can be made from 96~ magnesium and 4~ nickel, resulting in a solid comprising 85% magnesium grains and 15~ of a eutectic of MgNi2 and magnesium crystallites.
The frozen melt is preferably formed into small particles to increase the surface area. FIG. 4 shows two preferred methods for forming small particles and the heat source. The metallic agents are first melted to form a li~uid melt. In the case of magnesium-nickel melt~, the melt temperature is about 800C The melt can then either be cast into ingots and milled to small particles, or the molten alloy may be atomized, with individual droplets cooling to form the frozen melt 70 represented by FIG. 3. The atomizing step can be performed by a variety of standard metallurgical processes for forming small spherical particles from a molten melt. In the preferred large scale process, the magnesium alloy is sprayed into an 913/77C:18 -`: :

2~687 inert atmosphere (argon) in a large vessel which permits the droplets to freeze before contacting the side of the vessel. The size of the particles can be controlled by atomization conditions. A second process, know as rotating electrode powder preparation, i9 a smaller scale process suitable for laboratory production of powder. In this process, an electrode is fabricated from the desired alloy and the electrode is placed in a rotating chuck within an enclosed chamber.
The chamber is purged with argon and evacuated by mechanical pumping. Electrical sparks are generated between the electrode and an electrical ground. The sparks melt the alloy at a local pOiIlt and the droplet of molten metal is spun from the surface by centrifugal force. The droplet cools during its trajectory and is collected. The preferred particle si~e of the frozen melt particles is in the range of 50-400 microns, most preferably 100-300 microns.
FIG. 7 shows yet another embodiment of the metallic agents used to form heat source 35 or 60. In this embodiment, small particles 102 of a "mechanical alloy" are prepared by mechanically bonding or cold welding together small particles of the separate metallic agent. Preferably, the area of contact of the metallic agents is very high. The metallic agent that will serve as the anode is the most predominant in particles 102 and forms the background 104 of the particle. The metallic agent that will serve as the cathode i~ present as distinct specks 106 in the background 104.
Preferably, the anode material 104 is magnesium and the cathode specks 106 comprise iron.
This type of material can be purchased from Dymatron Inc., 2085 Fallon Road, Lexington, Ky. 40504. The powder is reportedly made by ball-milling coarse 913/77C:19 :

2 ~ 8 7 magnesium powder with very fine iron powder in a vibrating mill. The powder blend used is 10% iron and 90~ magnesium. Steel balls (0.25-inch diameter) are added to the powder blend, and the blend and the balls are reportedly vibrated for a period of about 15 minutes. U.S. Patent Nos. 4,017,414 and 4,264,362 disclose processes for making such magnesium-iron mechanical alloys.
Preferably the mechanical alloy is screened to obtain desired particle sizes before it is used in the present invention. It has been found that in materials procured from Dymatron, Inc., only abou~ half of the iron powder is embedded in the surface of the magnesium, the rest remains as fine iron powder. The powder as received from Dymatron also has a very broad particle size distribution. The powder is preferably sized on a standard screener using screen sizes of 16, 30, 40, 50, ~0, 140 mesh. The portion that passes through the 50-mesh screen and stays on the 80-mesh screen is generally used, as it produces heat sources with the longest life at temperatures above 100C. If a faster heating rate is desired, 10 or 20~ of the total powder used may be a finer cut of powder (through 80-mesh screen, on the 140-mesh screen). The iron content of these cut powders are generally 6-7~. The unbound iron passes through the 140-mesh screen and is collected on the pan.
After particles of the proper size of either the frozen melt or the mechanical alloy are obtained, they may be used to create a heat source 35 or 60. One method of forming a heat source i8 to extrude the par-ticles of frozen melt with a binder into an extruded rod, which is then severed into the proper length to form a heat source 35. Cylindrical, square, annular and even star-shaped extrusions may be formed. A
913/77C:20 2 ~ 7 binder such as sodium carboxymethyl cellulose (CMC) may be used to extrude the metallic agent~. A level of about 6~ binder in the extrudate has been found to hold the metallic agents into the proper shape.
Extrusion is complicated by the fact that water typically used in extruding powders will initiate the electrochemical interaction of the heat source particles. A preferred extrusion process uses low amounts of de,onized water, and several other pre-cautions to limit this problem. First, all of the ingredients and e~uipment are preferabl~ cooled prior to the extrusion process. Second, it has been found that a ~mall amount of heptane may be used to coat the powder particles prior to mixing the powder with CMC
and water for the extrusion. Third, the extruder parts are preferably made of brass to reduce the po~sibility of sparking, and the equipment should be grounded.
Preferably the CMC is first mixed with deionized water to form a gel. A preferred ratio is 12 parts water to 1 part CMC. The powder/heptane ratio is preferably 20:1. The CMC gel and treated powder are preFerably chilled before mixing. A Sigma blade mixer built to allow cooling with a liquid during mixing, such as the small Sigma blade mixer sold by C. W.
Braybender Inst~uments Company, South Hakensak, N.J., has been found to give good results. The treated powder is preferably added to the pLe-chilled (about 4C) mixer first and the CMC gel is slowly added and worked into the powder, using a 910w blade speed, preferably about 8 RPM. The temperature should be monitored during the mixing, which may take up to an hour or more. Normally the temperature will rise a few degrees. If the temperature increases 15-20C, the product should be emptied from the mixer, since the temperature rise indicates an excessive reaction is 913/77C:21 2~QG~

taking place and the mix will not be usable, and continued mixing may be dangerous.
The extruder should also be prechilled, and the mixed material charged to the extruder with a minimum of handling. The forming die will vary depend-ing on the size of the heat source being made. For 60 mm heat sources, a 0.130 inch die has been found appropriate, while 55 mm heat sources have been made with a 0.136 inch die. The extruder may be as simple as a tube and plunger. For example, a FORNEY compres-sion tester has been used to supply extrusion pressure for a ram in a one inch diameter tube.
Pr~ferably the die will be pointing down so that the extrudate can be caught on a plastic sheet taped onto a conveyor belt and removed in a horizontal position. The belt speed and extrusion speed should be controlled to obtain good results. Pressure in the extruder will preferably be increased in small incre-ments, as over pressurizing may cause separation of the powder and CMC gel. A ram speed of about 0.3 to 0.5 inches per minute, with a load of about 70 pounds, has been found useful for an extrusion tube having an inside diameter of one inch.
After the extrudate i8 extruded out on the conveyor belt, it should be allowed to partially dr~
before it i9 handled. After about 30 minutes of drying, the extrudate can be cut into ~trips about 24 inches long and put onto drying racks. The strips ~hould be allowed to dry at room temperature overnight, and may be cut to size the following morning. The cut rods ~y then be heated to 60C in a vacuum oven (preferably explo~ion-proof) overnight to remove the heptane. The dried rods are then ready for assembly into smoking articles.

913/77C:22 2 Q ~ 7 The metallic agents may also be pressed into desired shapes. Two methods of pressing are contem-plated, die pressing and isostatic pressing. Die pressing magnesium-based heat source particles is dif-ficult because of the tendency of magnesium to smearand reduce the porosity on the surface of the rod. To make a successful rod it is preferable to press the rod in a horizontal position. The die should be designed to release the part without any stripping action, which causes galling. A preferred die cavity is 0.090 inches wide and 3 inches long. The depth may be varied as necessary to produce a part of a desired weight and thickness. However, difficulties in filling such a long narrow c~vity uniformly have been found to produce variable densities within the rod.
It is believed that isostatic pressing would produce parts of uniform density without galling and with uniform density.
The material may need to have a binder or extender added to produce a heat source with a proper rate of reaction. Also, the porosity (or void fraction) and pore size may be varied to help control the rate of reaction. Polysulfone, a high temperature plastic from Amoco, and CMC are possible binders.
Magnesium and, less preferable because of its weight, aluminum, may be used a~ extenders. The porosity is primarily controlled by the pressure used. The pore size is primarily controlled by the particle size.
An additional extender i8 NaCl. The NaCl may be used to provide porosity, as it will dissolve to form an electrolyte when the pres~ed rod is contacted by water. However, rods produced with NaCl may be hygroscopic, and may therefore need to be stored in controlled humidity environments.

913/77C:~3 ~ . ~
.
. ~ ~

2 ~ 7 A preferred material for making pressed rods comprises an intimate mixture of 48~ magnesium (-325 mesh), 32~ of a -30 mesh, +40 mesh cut of mechanically bonded magnesium and iron from Dymatron, Inc., and 20 NaCl ground to a small particle size. A preferred pressure for pressing such a mixture is 14,800 psi.
Another method of using the particles of metallic agents is to fill a preformed straw or tube with the particles to form a heat source 60, with the wall of the straw forming the outer wrap 64. The straw may be plagtic, metal or even paper. Of course, the particles need to be secured in the straw so that they do not fall out prior to use.
One preferred embodiment of such a preformed straw 76 is shown in FIG. 10. The powder 75 is contained in a plastic straw 77 having small holes 78 formed in the sides for migration of the electrolyte.
The ends 79 of the straw 77 are sealed.
FIG. 5 illustrates another configuration of a heat source formed from a bimetallic foil 80. The bimetallic foil 80 is formed with the metallic agent that will be corroded (the anode) forming a first or primary layer 82. A second metallic agent (the cathode) is applied in a thin film to the first layer to form a second layer 84. This thin, ~econd layer 84 may preferably be formed by sputter coating. A pre-ferred bimetallic foil 80 comprise~ a magnesium primary - layer 82 about 4 mils thick, and a sputter coated iron second layer 84 about 0.1 micron thick. The bond between the first and second layers 82 and 84 can be formed in other ways, so long as the first and second layers 82 and 84 are in electrical contact with one another.
The bimetallic foil 80 may be formed into a heat source in ~everal ways. A preferred method is to 913/77C:24 ~ .

2~6~6~7 roll the foil 80 into a roll 88. When this method is used, an absorbent material such as tissue paper 86 may be rolled interspaced with the foil 80 as shown in FIG. 5a. The absorbent paper then helps to convey water into the inside layers of the foil for use in the electrochemical interaction. As shown in FIG. 5b, the roll 88 may then be inserted into a heat chamber 20.
Alternatively, the foil 80 can be chopped into fine shreds and either extruded with a binder, pressed into a rod or used to fill a straw, just as with the par-ticle~ of frozen melt or mechanical alloy discu~sed above.
Yet another possible configuration of the heat ource 35 i8 depicted in FIG. 6. In this embodi-ment, the anode material i~ formed into strands 92 and the cathode material is formed into a fine wire 94.
The wire 94 can then be wrapped around the strands 92 to put the wire 94 in close proximity to the strands 92.
In this embodiment, the wire 94 must be in electrical contact with strands 92. Since the strand~ 92 will corrode during the electrochemical interaction, it is preferably to protect at least one area of the electrical contact from interaction 80 that the electrical contact i8 not lost. One ~imple method to do this i8 to crimp the wire 94 and strand~ 92 together at one end and coat the crimped end with a protective coating material impervious to the electrolyte used in the electrochemical interaction~. The diameter of the Btrand8 i8 important to obtain a ~ufficient surface area. In this embodiment, the strands 92 are prefer-ably magnesium and the wire 94 is preferably iron.
When magnesium is used to form the strands 92, each ~-strand is preferably O.2 inches in diameter. The wire 94 need only be thick enollgh ~o provide physical 3S integrity, since the wire does not corrode. However, 913/77C:25 .

2 ~ 7 the surface area of the strands 92 and wire 94 are preferably approximately equal. In the preferred embodiment of FIG. 6, the iron wire 94 is 0.001 inches in diameter. The embodiment of FIG. 6 may preferably be constructed by twisting the strands 92 together before wrapping them with wire 94.
Normally, each heat source comprises about 100 mg to about 400 mg of metallic agents. For heat sources which include a mixture of magnesium and iron, the amount of magnesium relative to iron within each heat source ranges from about 100:1 to about 4:1, most preferably 50:1 to 16:1. Other metallic agents would use similar ratios.
The electrolyte can vary. Preferred electrolytes are the strong electrolytes. Examples o~
preferred electrolytes include potassium chloride, sodium chloride, and calcium chloride. The electrolyte can be provided in a dry state with the metallic agents and formed into the heat source, or can be supplied as a saline solution to initiate the electrochemical interaction. When the electrolyte is mixed with the metallic agents, each heat source will normally com-prise about 5 mg to about 150 mg electrolyte. Alterna-tively, when the electrolyte is provided with water in a saline solution, the electrolyte will preferably be di~solved at a :Level of about 1~ to about 20~ of the solution.
A solvent for the electrolyte is employed to dis~ociate the electrolyte (if present in the heat source), and hence initiate the electrochemical inter-action between the metallic agents. The preferred solvent i9 water. The pH of the water can vary, but typically i8 about 6 or less. Contact of water with the component3 of the heat ~ource can be achieved in a variety of ways. For example, a~ depicted in FIG. 8, 913/77C:26 2~&~7 the heat source 35 can be present in a heat chamber 20 in a dry state. Water can then be in~ected into the heat source from a hand-held and hand-operated pump 110 when activation of the heat source 35 is desired.
Preferably, the plug 38 (FIG. 1) used in such a config-uration will provide a port for injecting the water.
Alternatively, as depicted in FIG. 9, liquid water can be contained in a container inside the heat chamber 20 but separate from the heat source, such as a rupturable capsule 120. The capsule can be formed by the walls of the heat chamber 20 and the end 28 thereof and a frangible seal 122 which is ruptured when contact of the water with the heat source 60 is desired. The frangible seal 122 may preferably be made of wax or grease.
In either embodiment, water can be supplied to the portion of the heat source distant from the source of the water by using a porous wick. The absorbent material 86 interspaced in the bimetallic foil roll 88 serves this function. The outer wrap 64 on heat source 60 may also provide this wicking action to the metallic agents 62 inside. Normally, each heat source is contacted with about 0.25 ml to about 0.6 ml water, most pre~erably about 0.45 ml. As noted above, the water in the pump 110 or capsule 120 may contain the salt to be used as the electrolyte if the electro-lyte is not present in the heat source initially.
Preferred heat sources or solutions applied thereto include an oxidizing agent, such as calcium nitxate, sodium nitrate or sodium nitrite. For example, for preferred heat sources containing magnesium, hydrogen gas, which results upon the hydroxylation of magnesium, can be exothermically oxidized by a suitable oxidizing agent. Normally, each heat source or solution applied thereto comprises up to 913/77C:27 2~6~

about 150 mg oxidizing agent. The oxidizing agent can be encapsulated within a polymeric material (e.g., microencapsulated using known techniques) in order to minimize contact thereof with the metallic agents (e.g., magnesium) until the desired time. For example, encapsulated oxidizing agent can increase the shelf life of the heat source; and the form of the encapsulating material then is altered to release the oxidizing agent upon experiencing heat during use of the heat source.
Unless the particles of metallic agents by their size and shape provide physical spacing, the heat source preferably includes a dispersing agent to provide a physical spacing of the metallic agents.
Preferred dispersing agents are eæsentially inert with respect to the electrolyte and the metallic agents.
Preferably, the dispersing agent has a normally solid form in order to (i) maintain the metallic agents in a spaced apart relationship, and (ii) act as a reservoir for the electrolyte solution. Even where a disper~ing agent is not needed for spacing, it may be used as a water retention aid.
Examples of normally solid dispersing agents or water retention aids are porous materials including inorganic materials such as granular alumina and silica; celite; carbonaceous materials such as finely ground graphite, activated carbons and powdered charcoal; organic materials such as wood pulp and other cellulosic materials; and the like. Generally, the normally solid dispersing agent ranges from a fine powder to a coarse grain or fibrous size. The particle size of the dispersing agent can affect the rate of interaction of the heat generating components, and therefore the temperature and longevity of the inter-action. Although less preferred, crystalline compounds 913/77C:28 2 ~ 3 ~

having chemically bound water molecules can be employed as dispersin~ agents to provide a source of water for heat generation. Examples of such compounds include potassium aluminum doderahydrate, cupric sulfate penta-hydrate, and the like. Normally, each preferred heatsource comprises up to about 150 mg normally solid dispersing agent.
The electrolyte or heat source preferably includes an acid. The acid provides hydrogen ions, which are capable of enhancing the rate of the electro-chemical reaction. Also, the acid is used to maintain the pH of the system below the point where the oxidiz-ing anode reaction is impeded. For example, when the anode comprises magnesium, the system will become more basic as the reaction proceeds. However, at a pH of about 11.5, the Mg~OH)2 forms a passive coating pre-venting further contact between the electrolyte solu-tion and unreacted magnesium. The acid may be present in the form of a solution with the electrolyte, pro-vided on a solid support, or mixed with the electrolytesolution to form a slurry. The solid and slurry may be preferable as the acid may then dissolve over time and provide a constant stream of hydrogen ions. The acid may preferably be malic acid. Other acids, such as citric and lactic acid may also be used. The acid chosen must not react with the electrolyte. Also, the acid should not be toxic, or produce unpleasant fumes or odors. Also, the acid may have an effect on the overall reaction rate, and ~hould thus be chosen accordingly.
Although not preferred, the heat source or the solution applied thereto may also include a phase change or heat exchanging material. Examples of such materials are sugars such as dextrose, sucrose, and the like, which change from a solid to a liquid and back 913/77C:29 ~ 2o6~687 again within the temperature range achieved by the heat source during use. Other phase change agents include selected waxes or mixtures of waxes. Such materials absorb heat as the interactant components interact exo-thermically so that the maximum temperature exhibitedby the heat source is controlled. In particular, the sugars undergo a phase change from solid to liquid upon application of heat thereto, and heat is absorbed.
However, after the exothermic chemical interaction of the interactive components is nearly complete and the generation of heat thereby decreases, the heat absorbed by the phase change material can be released (i.e., the phase change material changes from a liquid to a solid) thereby extending the useful life of the heat source.
Phase change materials such as waxes, which have a viscous liquid ~orm when heated, can act as dispersing agents also. About 150 mg of phase change material may be used with each heat source.
The electrolyte solution may include a boiling modifier such as glycerin ~o prevent the water from vaporizing at temperatures experienced by the heat source. Other boiling modifiers include triethylene glycol and 1-3-propane diol. Also, the outerwrap 64 of the heat source may act as a surface on which steam generated by the electrochemical interaction can condense.
The relative amounts of the various com-ponents of the heat source can vary, and often is dependent upon factors such as the minimum and maximum temperature desired, the time period over which heat generation is desired, and the like. An example of a suitable heat source includes about 200 mg magnesium metal particles, about 50 mg iron metal particles, about 50 mg crystalline potassium chloride, about 100 mg crystalline sodium nitrate and about 100 mg gl3/77C:30 :` :

2~6~7 cellulose particles; which are in turn contacted with about 0~2 ml liquid water. A more preferred heat source include~ O.4-0.5 gram~ extruded or pressed metallic agents, comprising 6~ CMC and 94~ alloy, which is 6~ iron and 94~ magnesium. This is preferably contacted by O.45 ml of an electrolyte solution con-taining 20S NaCl, 10~ Ca(NO3~ 2~ 5~ glycerin and 1~ malic acid.

To control the rate of the electrochemical interaction, the anode material, particularly magnesium, may be pretreated. For example, it has been found that some mechanical alloys from Dymatron, Inc.
reacted very quickly but cooled off sooner than desired. It was discovered that if additional electrolytes were added to the~e previou~ly reacted powders, they would heat up again, though not a~
quickly as at first, and maintain a high temperature for a longer time. A mixture of pretreated and untreated powder~ was thus prepared and found to have good initiation characterietic~ and maintained high temperatures for ~ufficient durations. A preferred pretreating process involves contacting the particles with a limited amount of acid solution and allowing the reaction to heat up and drive off the water, thus te~minating the reaction. One particularly preferred pretreating process uses 0.34 ml of 12 N HCl acid diluted with 54.67 ml of water and 100 grams of mechanical alloy from Dymatron, Inc. screened to remove particle~ passing through a 28 US mesh screen. After reacting with the acid, the pretreated particles are preferably dried under a vacuum at 120C for 2~ hour~.
Cigarettes of the pxesent invention incorporate some form of tobacco. The form of the tobacco can vary, and more than one form of tobacco can 913/77C:31 ' ::

206~6~7 be incorporated into a particular smoking article. The type of tobacco can vary, and includes flue-cured, Burley, Maryland and Oriental tobaccos, the rare and specialty tobaccos, as well as blends thereof.
Any form of tobacco may be used herein. For example, tobacco cut filler (e.g., strands or shreds of tobacco filler having widths of about 1/15 inch to about l/4G inch, and lengths of about 1/4 inch to about 3 inches). Tobacco cut filler can be provided in the form of tobacco laminae, volume e~panded or puffed tobacco laminae, processed tobacco stems including cut-rolled or cut-puffed stems, or reconstituted tobacco material. Processed tobaccos, such as those described in U.S. Patent No. 5,025,812 to Fagg et al., and IJ.S.
Patent No. 5,065,775, can also be employed.
Although the roll or charge of tobacco can be employed as cut filler, other fonns of tobacco are preferred. One particularly preferred form of tobacco useful herein is tobacco paper. For example, a web of tobacco paper available as P2831-189-A~-6215 from Kimberly-r:lark Corp. may be used.
Another form of tobacco useful herein i9 finely divided tobacco material. Such a form of tobacco includes tobacco dust and finely divided tobacco laminae. Typically, finely divided tobacco material i5 carried by a substrate.
Another fonn of tobacco useful herein is tobacco extract. Tobacco extracts typically are pro-vided by extracting a tobacco material using a solvent such as water, carbon dioxide, sulfur hexafluroide, a h~drocarbon such as hexane or ethanol, a halocarbon such as a co~nercially available Freon, as well as other organic and inorganic solvents. Tobacco extracts can include spray dried tobacco extracts, freeze dried tobacco extracts, tobacco aroma oils, tobacco essences, 913/77C:32 20~8~

and other tobacco extracts. Methods for providing suitable tobacco extracts are set forth in U.S. Patent Nos. 4,506,682 to Mueller and 4,986,286 to Roberts et al.; European Patent Publication Nos. 326,370 and 338,831; U.S. Applications Serial No. 536,250 filed June 11, 1990; Serial No. 452,175 filed December 18, 1989; and Serial No. 680,207 filed April 4, 1991.
Also useful are flavorful tobacco composi-tions such as those described in ~.S. Patent No. 5,016,654 to Bernasek et al. Extruded tobacco materials (made by processes such as those described in U.S. Patent No. 4,821,749 to Toft et al.) can also be used.
When tobacco extracts are employed, such extracts normally are carried by a substrate such as tobacco materials (e.g. reconstituted tobacco and tobacco laminae). Reconstituted tobacco material can be provided using ca~t sheet techniques; papermaking techniques, such as described in U.S. Patent Nos. 4,962,774 to Thomasson et al. and 4,987,906 to Young et al. Reconstituted tobacco materials may include fillers, such as calcium carbonate, carbon and alumina. Processed tobaccos, such as tobaccos treated with sodium bicarbonate or potassium carbonate, which readily release the flavorful component~ thereof upon the application of heat thereto are particularly desir-able. Normally, the weight of the tobacco within the cigarette ranges from about 0.2 g to about 1 g.
To help release the volitile tobacco flavors, it is preferable to apply tobacco extracts and flavors on an alkaline porous material. One example of a preferred alkaline porous material in the form o$
reconstituted tobacco sheets is made as follows. APC
carbon (Calgon Corporation, Pennsylvania) is deactivated to a temperature appropriate for the flavor ~13/77C:33 -20~87 to be released, generally in the range of 1800C to 2500C, for two hours under nitrogen. The heat-treated carbon i9 then pulverized and sieved. Preferably the powder that passes through a 100 US mesh screen is collected and used.
Next, fibrillated tobacco is preferably mixed with 5 to 20% by weight of thermally deactivated APC
carbon powder and 10 to 20~ by weight of well refined wood pulp and 300 ml of water, blended for one minute at high speed in a household-type Os~erizer blender.
The mixture may then be poured into an 8" by 8" mold having a 100 me~h (US) screen and containing 3 liters of water. The slurry may be gravity drained and the resulting sheet tran~ferred to a conventional flat bed dryer, preset at 150~, and dried until the moisture content is below 2~.
Similar sheets may be made with powdered alpha alumina, zeolite, graphi~e carbon or precipitated calcium carbonate. Tobacco sheets containing either alumina, deactivated carbon or calcium carbonate have been found to release a significantly higher amount of volitizable tobacco flavors than tobacco or tobacco sheets not containing fillers.
Flavoring agents such as menthol, vanillin, cocoa, licorice, cinnamic aldehyde, and the like; as well as tobacco flavor modifiers such as levulinic acid, can be employed in the present invention. Such flavoring agents can be carried by the tobacco or positioned within the smoking article (e.g., on a separate ~ubstrate located in a heat exchange relation-ship with the heat source~ or within the filter). If desired, substances which vaporize and yield visible aerosols can be incorporated into the smoking article in a heat exchange relationship with the heat source.

913/77C:34 ........ .

: ~
: ; , .: ~ : ~ .

; ~ ::: : :
::

2 ~ 7 For example, an effective amount of propylene glycol can be carried by the tobacco.
Tobacco smoke flavor substances particularly useful in the present invention are derived by the "toastingl' of natural tobacco, e.g., Burley, Flue Cured, Turkish, Latakia, Maryland, etc. types of tobacco, or blends thereof. In preferred embodiments, the types of tobacco are extracted separately, though some types may be blended together, such as Flue Cured and Turkish.
As used herein, the term lltoa tingll refers to the process of heating tobacco in a suitable container, preferably under an inert atmosphere, within a temperature range sufficiently high to drive-off volatiles, without excessively charring or burning the tobacco. Generally, this temperature range has been found to be between about 100C and about 350C at atmospheric pressure.
There are several unique aspects of the present invention which relate to processe~ for producing flavor sub~tances from tobacco. Briefly, they are (1) using a multi-staged heating operation and separately collected flavoring substances during each stage, (2) reducing the moisture content of the tobaccG, without removing volatile flavor components, prior to heating the tobacco to extract the flavor components and t3) separately collecting, as flavor ~ubstance~, at least portions of volatile materials produced when tobacco i~ toasted in a flowing gas stream by pa~sing the gas stream sequentially through a moderate temperature trap, a cold temperature trap and a filter capable of collecting submicron sized particles. ~ach of these aspects may be used independently or in combination of any two aspects, but 913/77C:35 ' ' ' ' -: ' ., ' .

2 ~ 7 in the preferred embodiment of the invention they are used together.
FIG. 11 depicts an apparatus that may be used to practice the processes of the present invention.
The apparatus of FIG. 11 depicts laboratory scale equipment. It is understood that other equipment could be used, and that the process could be scaled up to use larger sized equipment for commercial applications.
The apparatus of FIG. 11 includes a round bottom flask 132 with a heating mantle 134 controlled by a powerstat 136. A thermocouple 139 and temperature recorder 138 monitor and record the temperature in the flask 132.
Nitrogen or ano~her inert carrier gas is supplied from a tank 140 equipped with a flow meter 142. The nitrogen enters the flask 132 through a glass tube 144 and exits through a side arm adapter. Fiberglass insulation 150 insulates the outlet to the round bottom flask 132. The collection system includes two collection flasks ~146 and 148) with exit tubes, each containing a liquid sorbent 149, such as propylene glycol, in the bottom of each flask. The carrier gas, containing the extracted flavors, is bubbled sequentially through the sorbent 149 in each flask.
Flask 146 is a moderate te~perature trap. Flask 148 is cooled and acts as a cold temperature trap. A
filter 152 on the exit tube of collection flask 148 traps any uncollected extracts.
In the process of the present invention, the tobacco used for the extraction will preferably first have its moisture content reduced without removing volatile flavor components. It is believed that moisture in the tobacco negatively interacts with flavor components during the extraction process.
Preferably the moisture content will be reduced to less 913/77C:36 2~&8~

than about 4~, and more preferably to less than about 1~ .
The preferred water reduction method is freeze drying the tobacco. Freeze drying the tobacco will generally be at a pressure below about 100 millitorr and at a temperature less than about 0C.
Most preferably the freeze drying will be carried at less than about 10 millitorr and less than about -5C.
Another contemplated method of reducing the tobacco moisture content is the use of a strong desiccant, such as calcium sulfate. Using this method, a sufficient amount of the desiccant and the tobacco are placed in a tightly closed container for a sufficient time period for the moisture in the tobacco to be drawn from the tobacco to the desired degree of dryness.
In a preferred embodiment, the tobacco is toasted at atmospheric pressure, but higher or lower pressures may be used. When the toasting is conducted at lower pressures, lower temperatures are effective for driving off the desired volatile materials. Those having ordinary skill in the art to which this invention pertains, with benefit of the present disclosure, will readily be able to determine appropriate temperatures for subatmospheric and super-atmospheric pres3ures.
In the preferred process, the tobacco is heated to at least two different toasting temperatures, preferably in a staged manner, with the volatiles released at each temperature being separately collected. With a two-staged heating, the difference between the first and second toasting temperatures will preferably differ by at least about 50C. When atmospheric pressures are used for a two-staged heating, the first toasting temperature will preferably be between about 100C and about 225C, and the second ~13/77C:37 2 ~ 8 ~

toasting temperature will preferably be between about 225C and about 350C. More preferably the first toasting temperature will be between about 200C and about 216C and the second toasting temperature will be between about 270C and about 325C. Optimum temperatures will vary depending on the tobacco used.
Preferably the carrier gas flow is initiated early in the heating process, possibly as soon a~
heating begins. This way volat-les are remo~ed from the heating chamber, cooled and collected as soon as they are released. It is believed that this prevents undesirable reactions that might otherwise occur between flavor substances and other tobacco components at elevated temperatures. An important part of this aspect of the invention is separately collecting the flavor substances given off at the different stages of heating. Thus the collection flasks are preferably changed when heating to the second toasting temperature is initiated. The time at which the tobacco is held at each stage may vary, depending on the tobacco, temperature, carrier gas flow rates and flavor desired.
One way to judge whether collection at a given temperature will produce additional flavor substances i9 to view whether aerosols are still exiting the 2S second flask 148. When no further substances are being collected at the first toasting temperature, the collection flas}cs should be changed and the tobacco heated to the higher second toasting temperature.
Preferably the heating is carried out 810wly so that portions of the tobacco closer to the heat source are not heated to a temperature much higher than the tobacco furthest from the heat source. Since the tobacco acts as an insulator, if the heating is performed too ~uickly, the tobacco next to the wall of flask 132 can char before the tobacco in the center is 913/77C:38 .

2~6~

heated. More rapid heating may be possible if the tobacco is agitated or other more uniform heat transfer methods are utilized. Preferably non~ of the tobacco will be heated to a temperature of more than about 20C
above the temperature of other tobacco in the flask 132. This also assures that none of the tobacco reaches a temperature of more than about 20C above the first toasting temperature during the first staged heating and about 20C above the second toasting temperature during the second staged heating. Thus all of the flavor substances collected in the separate collections will be from tobacco heated to the same general temperature range.
Preferably the flavor substances will be separately collected by passing the flowing gas stream seq~entially through 1) a moderate temperature trap, 2) a cold temperature trap, and 3) a filter capable of collecting submicron sized aerosol particles. In the preferred embodiments, either one, or most preferably both, of the moderate and cold temperature traps comprise a sorbent through which the gas stream passes.
Suitable sorbents are known and available to the skilled artisan, and include solids such as carbon (activated or unactivated), alumina, alpha alumina, tobacco, diatomaceous earth, clays and the like.
Suitable liquid sorbents include those materials typically used in the manufacture of cigarettes, including humectants, such as glycerin and propylene glycol. Other liquid ~orbent media useful herein include triacetin, ve~etable oils, e.g., sunflower, corn, peanut, etc. Especially preferred solid sorbent media are sintered alpha alumina and activated carbon.
An especially preferred liquid sorbent medium i~
propylene glycol. ~iquid sorbents have the advantage that the flavor compositions can be easily applied to a 913/77C:39 `.

.

2Q~87 substrate used in the smoking article while still dissolved in the sorbents. With solid sorbents, the flavor substances may be extracted with a liquid solvent that is then applied to a substrate, or the solid sorbents with the flavor substance thereon may be incorporated into the substrate, or otherwise incorporated into the smoking article.
When the process is carried out at atmospheric pressure, the moderate temperature trap will preferably cool the gas stream to a temperature below about 50C, and most preferably to a temperature of between about 20C and about 40C, and the cold temperature trap will cool the gas stream to a temperature below about 10C, and most preferably to a temperature between about 5C and about 0C. Suitable moderate temperature traps can thus be held at room temperature and suitable cold temperature traps can be operated at about 0C by using an ice bath.
A suitable filter 152 will remove submicron sized aerosol particles that are not removed by the traps 146 and 148. A Cambridge filter has been used satisfactorily. Under atmospheric pressure operating conditions, the filter 152 will preferably be maintained at a temperature below about 40C, and can be operated at room temperature. The flavor substance collected on the filter may be eluded with any suitable solvent, such as propylene glycol.
The inert gas used as the carrier gas may be any gas which does not have a detrimental effect on the gaseous products evolved from the heated tobacco. Such gases include nitrogen, argon a~d the like. The inert atmosphere is employed as a carrier gas, at a sufficient ~weep velocity to force the volatile components from flask 132, through the moderate and cold temperature traps 146 and 148 and filter 152.
913/77C:40 2`'~

In the following examples, extractions were carried out generally using the apparatus depicted in FIG. 11. The flask 132 was a 250 ml round bottom flask. Nitrogen was supplied at a rate of 1 liter/minute from tank 140. Each collection flask 146 and 148 was a 125 ml flask. Flask 146 was maintained at room temperature, and flask 148 wa~ maintained at an ice bath temperature. The filter 152 was used for Examples 5, 6 and 7. Other differences in the extraction apparatus, if they existed, are noted in the description of the examples.

Example 1 A sample o~ Flue Cured tobacco that had been freeze dried to remove moisture was distilled using the apparatus of FIG. 11 except that instead of a filter 152, the outlet of flask 148 was connected to a trap cooled by dry ice and containing glass beads. Flasks 146 and 148 both included 15 g of propylene glycol and a frit placed on the end of the inlet tubes. The powerstat 136 was set up to operate the heating mantel 134 at 250C. However, when heat was applied, it was obvious that the bottom of the flask 132 was getting too hot. The current to the heating mantel 134 was limited to keep the temperature in the flask 132 at 260C. The system was operated at 260C for 1 1/2 hours, at which time the frit in flask 146 stopped up and had to be cleaned out. After the frit was cleaned out the system operated another 30 minutes before it stopped up. A ~ine aerosol was noticed escaping from the dry ice trap and the dry ice trap did not increase in weight. The materials in flasks 146 and 148 were separately collected and labeled (respecti~ely Samples 1-1 and 1-2).

913/77C:41 2~$~8~

Example 2 A sample of freeze dried Burley tobacco was distilled in the apparatus of FIG. 11 except that no ice-bath temperature trap (flask 148) or filter 152 were used. Flask 146 contained 20 g of propylene glycol. The voltage to the heating mantle 134 was increased over a 2 hour period until 216C was obtained. This temperature was continued for 3 hours and the material from flask 146 was collected (Sample 2-1), though the distillation of Burley tobacco did not give much color to the propylene glycol at this temperature. The effluent from the exit of flask 146 had a nicotine - Nn~ aroma and was basic to pH paper.
The system was shut off, flask 132 was stoppered and allowed to cool over night. The next day 20 g of fresh propylene glycol was placed in flask 146 and the heating mantel 134 turned on. The second heating stage took about 2.5 hours to reach a temperature o~ 325C, and distillation was continued for 3 hours thereafter.
The material from flask 146 was again collected (Sample 2-2). It had a golden color and an earthy, nicotine-like aroma.

Example 3 A sample of freeze dried Flue Cured tobacco was distilled using the apparatus of FIG. 11 modified as described in Example 1, except that a frit was only used in flask 148 and 20 g of propylene glycol were used in flask 146. The temperature was raised in a first stage heating over a period of 2 hours to 216C
and remained at this temperature for about 4 hours.
Approximately 1.5 hours after the 216C temperature was reached the frit in flask 148 had enough back pressure to cause the system to leak, requiring the frit to be cleaned up so that the run could be completed.
913/77C:4~

-: .
~ , 2~fi~ 7 Samples were taken from the traps. The room temperature trap (flask 146) had a weight gain of 2.42 g (Sample 3-1). The ice-bath trap (flask 148) had a weight gain of 1.23 g (Sample 3-2). The dry ice trap had only a 20 mg weight gain. At this temperature very little aroma escaped the dry ice trap exit. Sample 3-1 was amber colored a~d had a Flue Cured-like aroma.
Sample 3-2 was light yellow and had a green hay-grass note. Equal parts of Samples 2-1, 2-2, 3-1 and 3-2 were mixed together to use as a combination flavor (Sample 3-C).

Example 4 Forty-five grams of freeze-dried Flue Cured tobacco was heat treated in the round bottom flask 132 as shown in FIG. 11, with 20 g of propylene glycol in each flask 146 and 148. The freeze drying was at 5-10 millitorr overnight at -8C, reducing the moisture content to less than 1~. Heat was applied to the flask 132 in a staged manner that reached -~212C in 2-3/5 hours. After approximately five hours at this temperature, samples were pulled from collection flasks 146 and 148 and labeled (Samples 4-1 and 4-2). Another 20 g of propylene glycol was then put into each collection flask. The temperature was then increased to ~270C in 1/2 hours. Samples were then again removed from flasks 146 and 148 (Samples 4-3 and 4-4).
Ten grams of each Sample 4-1, 4-~, 4-3 and 4-4 were mixed to yield 40 grams of Flue Cured flavor (Sample 4-C).

Example 5 Forty-five grams of freeze-dried Turkish tobacco was placed in the flask 134 and processed in the same manner as Example 4, except a double Cambridge 913/77C:43 -2~6~6~

filter was placed at the exit 152 of flask 148. In previous experiments, aerosol was observed at this exit. The Cambridge filter pads entrapped this material. The temperature increase at the thermocouple was staged to reach 216C + 2 o~er 4.5 hours and held for 4 hours. The propylene glycol was removed from flasks 146 and 148 ~Samples 5-1 and 5-2) and the temperature was increased. Fresh propylene glycol was added to clean collection flasks and the temperature was increased to 275C ~ 5 in 1.25 hours. The Cambridge filter pads from the filters were extracted with 15 g propylene glycol (Sample 5-3) at the same time as the fresh propylene glycol was added to flasks 146 and 148. Approximately .75g of material was collected on the pads. The 275C temperature was maintained for ~3.5 hours. At this time the propylene glycol from flasks 146 and 148 was again collected (Samples 5-4 and 5-5). Only 20 mg of material was collected on the Cambridge pads for the second phase of the run, which was probably due to a build up of solid material between flask 146 and flask 148. This solid material was washed into flask 148 (Sample 5-5). Ten grams each of Samples 5-1, 5-2, 5-4 and 5-5, and 5 grams of Sample 5-3 were combined to yield 45 grams of combined Turkish flavor ~Sample 5-C).

Example 6 Forty-five grams of freeze dried Latakia tobacco were placed in the distillation system shown in FIG. 11 with 20 g of propylene glycol in each of flasks 146 and 148. The system was heated to 200C in ~4.5 hours and remained above 200C for ~3.5 hours. A large amount of oil-like material collected in the flask 146.
The propylene glycol was therefore changed in the middle of the low temperature run. At the end of the 913/77C:44 2 ~ ~ r~ ~ ~ 7 3.5 hours, samples were collected from both flasks 146 and 148, and the temperature was slowly increased over a period of about ~1.0 hour to 270-275C. Flask 132 then remained at this temperature for 3 hours and 45 minutes. Again, the propylene glycol in flask 146 was changed in the middle of the high temperature run. A
Cambridge filter was initially placed on the exit of flask 148 and replaced at the end of the low temperature heating. Material was eluted from the Cambridge filter (.78 g) that collected during low temperature heating with about 7.0 g propylene glycol.
The filter used during the high temperature heating was also eluted with about 7.0 g propylene glycol. The following samples were thus collected in this 15 extraction run.
Trap Sample Description Retort Temperature & Time 6-1 Flask 146 Initial heating and 210C
for 2 hours 6-2 Flask 146 210C between hours 2 and 6-3 Flask 148 Initial heating and 210C
for ~4 hours 6-4 Cambridge Filter Initial heating and 210C
for ~4 hours 6-5 Flask 146 Second stage heating and 275C for -2 hours 6-6 Flask 146 275C between hours 2 and 3.5 6-7 Flask 148 Second stage heating and 275C for ~3.5 hours 6-8Cambridge Filter Second stage heating and 275C for ~3.5 hours 913/77C:45 - .

2 Q ~ 7 A combination flavor (Sample 6-C) was made from 10 grams each of Samples 6-1, 6-3, 6-5 and 6-7 and 1 gram each of Samples 6-4 and 6-8.

Example 7 Forty-five grams of freeze-dried Burley tobacco was distilled using ~he apparatus of FIG. 11 with 20 g of propylene glycol in each of flasks 146 and 148. A Cambridge filter was used on the exit of flask 148. The system was staged to about 250C over a 3.5 hour period and continued at that temperature for about 3.5 hour~. Samples were collected from the flasks 146 (Sample 7-1) and 148 (Sample 7-2) and eluted from the Cambridge pad (Sample 7 3). The flask 132 was cooled and sealed for storage over the weekend. The flask 132 was thereafter put back into the distillation system of FIG. 1 with 20 g of fresh propylene glycol in each flask 146 and 148 and the system was staged to about 320C over a 3.5 hour period. The distillation was continued at this temperature for about 3.5 hours.
Samples were again collected from the flasks 146 (Sample 7-4) and 148 (Sample 7-5) and eluted from the Cambridge pad (Sample 7-6~. A combination flavor (Sample 7-C) was made by mixing 10 grams each of Samples 7-1, 7-2, 7-4 and 7-5 and 1 gram each of Samples 7-3 and 7-6.
The flavor sub~tances of ~he present invention are particularly advantageous because they are capable of providing a good tobacco smoke taste to cigarettes and other smoking articlee. The flavor substances of the present invention may be u~ed in a variety of ways. For example, they may be added to conventional cigarettes or other smoking article~ as a top dres~ing or in any other convenient mode selected by the manufacturer.
913/77C:46 ' ,.

2 P~ 3 7 The flavor substances of the present invention may be added to various elements within the smoking article, such as tobacco, a substrate in a heat exchange relationship with a heat source, an aerosol generating means, and/or the mouthpiece end component, or any other place that it will contribute smoke flavors as the smoking article is used. Preferably, the flavor substances are added to a relatively cool region of the article, i.e., away from the heat source, e.g., in the mouthend piece. Alternatively, the heat source will preferably heat the region to which the flavor substances have been applied to a relatively low temperature.
Another important discovery associated with the present invention is that the release of smoke flavors from a smoking article to which they have been applied is dependant on how those flavors are applied.
As more fully described hereafter, it was discovered that when the flavors from two or more types of tobaccos were mixed, applied to a substrate (in this case a reconstituted tobacco sheet) and the tobacco sheet heated, the flavors were not released very well.
However, when the mixture of samples from the same tobacco (such as Sample 5-C) were applied to a reconstituted tobacco sheet, the flavor released much better. This was found to be true even if several different tobacco sheets carrying sample mixtures from different tobaccos were used in seg~ents in the same cigarette. Not wishing to be bound by theory, it is contemplated that in a mixture of flavors from different tobaccos, the vapor pressure of the various flavors are reduced, preventing the flavor~ from releasing as well as when they are present by themselves. Also, it is believed that there may be 913/77C:47 . .

v , 2 ~ 7 acid-base reactions when flavor substances from two different types of tobacco are mixed.
As such, flavor substances extracted by processes of the present invention are preferably located on separate segments of a carrier, such as sheets of reconstructed tobacco. They may also be placed separately on a carrier in the cigarette and the filter element of the mou~hpiece end of the cigarette.
The discovery that separately collected flavor substances may have better release characteristic~ when used on separate segments or areas within a smoking article has application to flavor substances in addition to those produced by the processes of the present invention. Hence, flavor substances produced or extracted in other ways may preferably be used by applying separately extracted tobacco flavor substances to a plurality of individual ~egments o~ a carrier within a smoking article.
Preferably, the carrier will comprise three or more segments so that several flavor substances can be utilized in the same smoking article.
Preferred smoking articles of the present invention have a long shelf life. That is, during di~tribution and storage incident to commercial product~, neither the flavor nor the heat source will lose their potency over time. Finally, when the product is ready for use, the smoker initiates exothermic interaction of the heat source 35 or 60 and the heat source generates heat. Heat which results acts to warm the tobacco which is positioned in close proximity to the heat source so as to be in a heat exchange relationship therewith. The heat so supplied to the tobacco acts to volatilize flavorful components of the tobacco as well a~ flavorful c~mponents carried by the tobacco. The volatilized materials then are 913/77C:48 :' :
.

2~&,~7 drawn to the mouth-end region of the cigarette and into the smoker's mouth. As such, the smoker is provided with many of the flavors and other pleasures associated with cigarette smoking without burning any matexials.
The heat source provides sufficient heat to volatilize flavorful components of the tobacco while maintaining the temperature of the tobacco within the desired temperature range. When heat generation is complete, the tobacco begins to cool and volatilization of flavorful components thereof decreases. The cigarette then is discarded or otherwise disposed of.
The following product examples are provided in order to further illustrate various embodiment~ of the invention but should not be construed as limiting the scope thereof.

Example 8 A heat source is prepared as follows:
About 5 g of magne~ium powder having a particle size of -40 to ~80 US mesh and about 5 g of iron powder having a particle size of -325 US mesh are ball milled at low speed under ni~rogen atmosphere for about 30 minutes. The resulting mixture of magnesium and iron i8 sieved through a 200 US mesh ~creen, and about 6.1 g of +200 US mesh particle~ are collected.
The particles which are collected comprise about 5 parts magnesium and about 1 part iron. Then, about 300 mg of the collected particles are mixed with about 90 mg of crystalline potassium chloride and about 100 mg of finely powdered wood pulp. The wood pulp has a particle size of about 200 US mesh. The re~ulting solid mixture i~ pressed under 33,000 p.s.i. using a Carver Laboratory Press to a cylindrical pellet ha~ing a diameter of about 7.6 mm and a thic~less of about 10 mm.

913/77C:49 :

:.:

2 ~ 7 The pellet is placed into an uninsulated glass tube having one closed end. The tube has a length of about 76 mm and an inner diameter of about 12 mm. Into the tube is charged 0.25 ml water. The heat source generates heat, and reaches 70C in about 2 minutes and 95C in about 4 minutes. The heat ~ource then continues to generate heat at a temperature between about 85C and about 95C for about 30 minutes.

Example 9 A heat source i8 prepared as follows:
About 200 mg of magnesium powder having a particle ~ize of -40 to +80 US mesh is mixed thoroughly with about 50 mg of iron powder having a particle size of -325 US mesh. The resulting solid mixture is pressed under 33,000 p.s.i. using a Carver Laboratory Press to provide a pellet in the form of a cylindrical tube having a length of about 3.2 mm and an outer diameter of abou~ 7.6 mm, and an axial passageway of about 2.4 mm diameter.
The pellet is placed into the glass tube described in Example 8. Into the tube is charged 0.2 ml of a solution of 1 part potacsium chloride and 4 parts water. The heat source reaches 100C in about 0.5 minutes. The heat source continues to generate heat at a temperature between about 95C and about 105C fcr about 8.5 minutes.

Example 1~
A heat source is prepared a~ follows:
About 200 mg of magnesium powder having a particle ~ize of -40 to +80 US mesh is mixed thoroughly with about 50 mg of iron powder having a particle size of -325 US me~h and about 100 mg wood pulp having a particle size of about 200 US mesh. The resulting g13/77C:50 , , -, :, .
-2 ~ 7 solid mixture is pressed under 33,000 p.s.i. using a Carver Laboratory Press to provide a pellet in the form of a cylindrical pellet having a length of about 3.8 mm and a diameter of about 7.6 mm.
The pellet is placed into the glass tube described in Example 8. Into the tube is charged 0.2 ml of a solution of 1 part potassium chloride and 4 parts water. The heat source reaches 100C in about 0.5 minutes. The heat source continues to generate heat, maintaining a temperature above 70C for about 4 minutes. men, about 0.2 ml of a solution of 1 part sodium nitra~e and 1 part water is charged into the tube. The heat source generates more heat, and reaches a temperature of 130C in about 5 minutes. The heat source then maintains a temperature of above 100C for an additional 4.5 minutes.

Example 11 ` Magnesium wire having a diameter of 0.032 inches (0.081 cm) was cut into five strands, each about 1.97 inches (5 cm) in length, and twisted to~ether.
The twisted ~trands weighed 0.226 ~rams and had a calculated surface area of 6.38 cm2. An iron wire having a diameter of 0.001 inches (0.003 cm), a length of 39.37 inches (100 cm), a calculated surface area of 0.80 cm2, and weighing 0.004 grams was wrapped tightly around the twisted magnesium strands.
The wire assembly was placed in a plastic tube approximately 4 mm in diameter and 600 microliters of electrolyte containing 20~ NaCl, 10~ calcium nitrate, 5~ glycerin, 1~ malic acid, and 64~ water were added. Thermocouples were inserted to monitor tempera-ture. The temperature of the assembly increased very rapidly to 95C (less than 2 minutes) and maintained temperatures greater than 70C for ten minutes.
913/77C:51 2 ~

Example 12 A melt of 96~ magnesium and 4~ nickel was prepared and cast into ingots. Theoretically the ingots contained 85~ magnesium grains and 15~ of a eutectic of magnesium and Mg2Ni. An ingot was machined into fine filings. To achieve a suitable bulk density (about 0.5 g/cm3), the filin~s were milled for one hour using 3/8-inch diameter steel balls. The resultant product, irregular flat platelets, was screened to a -50 to +80 US mesh size. These particles were then extruded with 6% sodium carboxymethyl cellulose into a rod 3.5 mm in diameter. A 60 mm length of the rod, weighing 0.36 grams, was wrapped in two layers of 60 x 70 mm tissue papers and inserted into a mylar tube with an inside diameter of 0.203 inches and a sealed bottom.
A 6 mm long plug was used to seal the top of the tube.
An electrolyte was prepared with 20~ NaCl, 5~ glycerin, 10~ calcium nitrate and 1~ malic acid dissolved in water. Exactly 0.45 cc of electrolyte were injected into the bottom of the tube. For temperature measurement~, the assembly was insulated with three wraps of laboratory-grade paper towel. The temperature inside the tube reached 100C in about 30 seconds and maintained a temperature of over 100C for more than 7 minutes. The maximum temperature reached was about 110C.

Example 13 Heat sources were extruded generall~ using the extrusion process and equipment described earlier.
2.7g of CMC (Aqualon) were blended with 33 grams of deionized water in a small jar and placed on rotating rollers for several hours. The resulting gel was stored in a refrigerator to improve its shelf-life and to pre-cool it. 40.3~ of magnesium/iron mechanical 913/77C:52 alloy from Dymatron, Inc., screened to a particle size that passed through a 50 US mesh screen but was retained on a 80 US mesh screen, were placed in a small jar with 2g of heptane. The jar was placed on rotary rollers for at least 15 minutes and then stored in the refrigerator.
A Braybender Sigma blade mixer was pre-cooled to 4C using ice water. The powder was added to the pre-chilled mixer, and CMC gel was worked into the powder by slowly adding the CMC gel. After the sample was mixed, extruded and dried, the CMC constituted 6 of the final extrudate.
Six centimeter lengths of the extrudate were wrapped with 6 X 7 cm two-ply Kleenex facial tissue paper and held with Elmer's glue. A reaction chamber was prepared from a 7-cm segment of mylar tube (O.D.
.208 inches) sealed at one end and containing .45 ml of aqueous electrolyte solution. The electrolyte solution contained 20~ sodium chloride, 10~ calcium nitrate, 5~
glycerine and 1% malic acid. Reaction was initiated by inserting the wrapped heat source in the reac~ion chamber. Temperatures were measured by placing thermo-couples between the chamber wall and the heat source at about 15 mm and 35 mm from the bottom. The assembl~
was insulated with three wraps of laboratory grade paper towel. The heat profiles generated are shown in FIG. 12. A ~100 C temperature was achieved in one minute. The temperature of the heat source remained above 95C for at least 7 min. Temperatures over 100C
have been achieved in less than 30 seconds in this example by (a) incorporating 20 - 30 mg of -100 US mesh mechanical alloy powder placed along the length of the extruded rod and wrapped with the tissue described above, (b) using finer particles of mechanical alloy in 913/77C:53 2 ~

the extrusion, or (c) increasing the malic acid con-centration to 2~.

Example 14 Magnesium/iron alloy from Dymatron, Inc. was screened to pass through a 50 US mesh screen, but be retained on an 80 US mesh screen. The powder was about 6~ iron. This material was then pretreated with acid using the process described earlier. Some of the same particle size powder that was not pretreated, the pretreated powder and Celatom FW-60 (Aldrich Chemical Company, Inc., Wisconsin) were mixed in the ratio of 8:8:7 by weight. A fuel rod like that shown in FIG. 10 was made in the following manner. A mylar tube with an external diameter of .208 inches was cut into 8 cm segments and one end was sealed by flame. The tube was perforated with four rows o~ 18-mil holes 5 mm apart.
The tube was filled with about 500 mg of the powder/pretreated powder/Celatom mixture and the open end heat sealed, thus forming a perforated capsule ~bout 6 cm long. Another 7 cm long mylar tube with an outer diameter of .212 inches with one end heat sealed was used to form a reaction chamber. This chamber contained 0.5 ml of an a~ueous electrolyte solution sontaining 20~ sodium chloride, 10% calcium nitrate and 5~ glycerine. The exothermic reaction was initiated by inserting the perfora~ed capsule in the reaction chamber. Temperature was mea3ured by inserting a thermocouple between the two chambers at about 15 mm from the bottom. For temperature measurements, the assembly was insulated with three wraps of paper towel.
Following initiation, the temperature reached about 95C in less than 30 seconds and stayed at or above lOGC for 7 minutes.

913/77C:54 20~6~7 Examplç 15 A pressed rod was made generally using the procedure described earlier. Sodium chloride was ground with a mortar and pestle to a fine powder. 4.8g of -325 US mesh magnesium powder from Morton Thiokol, Inc. was mixed with 3.2g of -30 to ~40 US mesh magnesium/iron powder from Dymatron, Inc. in a small plastic beaker. 2g of the powdered ~odium chloride was then mixed with the metal powders. Precsure for pressing was supplied by a Forney compres~ion tester.
A 4,000 pound load waa applied, generating 14,800 psi in the die, producing a pressed rod 0.09 x 0.136 x 3 inches, which was cut into 4 cm segments weighing about 0.5g each. A te t rod was wrapped in two layers of Kleenex tissue, each 2 x 2 inches and inserted into a .203" I.D. mylar tube. Thermocouples were attached to the tube, which was then wrapped with an insulating sleeve of Kleenex tissue. An electrolyte, 0.5 ml, containing 20~ NaCl, 5% Ca(No3) 2~ 5~ glycerine and 70 water was injected into the bottom of the mylar tube.
This test was repeated two more time~. All samples reached a temperature of 90C within at lea~t one minute and maintained a temperature at, or above, 90C
for 11 minutes.
Example 16 The presently preferred embodiment of a cigarette of the present invention i~ shown in FIGS. 13 and 14 and was constructed as follows. FIG. 13 i8 an exploded view, and FIG. 14 is a view showing the heat source partially inserted into the heat chamber.
The heat source 160 consists of a 6.0 cm length of extruded rod 162 having a diameter of .125 inches and a weight of about .37g, made in accordance with Example 13, placed end to end with a cellulose 913/77C:55 '' ' :
' ' ' ~

- : ;

2 ~ 3 ~
\

fiber rod 164 (EF203032/82 available from Baumgartner, Lausanne-Crissier, Switzerland) 4.40 mm in diameter and 8.00 mm in length and held in place by wrapping the arrangement in an outerwrap 166 made of a two-ply segment of a Kleenex facial tissue 60 X 75 mm. The outer edge of the tissue is very lightly glued.
A mylar tube (J.L. Clark Manufacturing Co., Maryland) 0.208" in diameter and 3.4" in length with one end sealed with heat serves as the heat or reaction chamber 168 where the exothermic electro-chemical reaction takes place. This heat chamber 168 should be inspected after heat sealing to assure that the bottom portion did not shrink, which would interfere with its capacity and further assembly. This tube contains .45 ml of electrolyte solution 170, containing 20~
sodium chloride, 10~ calcium nitrate, 5% glycerine and 2~ malic acid, sealed in the bottom behind a grease seal 172. The grease seal 172 i9 applied using a syringe loaded with grease. A first layer about 0.01 inches thick is applied just above the liquid level in the tube 168. A second layer of the same thickness is applied about 6mm above the liquid.
Reconstituted tobacco sheets (P2831- 189-AA - 6215, Kimberly-Clark Corporation, GA) consisting of 20.7~ precipitated calcium carbonate, 20~ wood pulp and 59.3~ tobacco are cut into 60 X 70 mm segments and rolled into a 7 cm tube with an internal diameter of .208n. Various flavoring materials and humectants are applied to the rod and equilibra~ed overnight. Levuli-nic or other acids are applied to similar tobacco rods made with reconstituted sheets not containing calcium carbonate. The flavored tobacco tubes are cut into either 7 or 10 mm segments. Various segment~ from different tubes may then be used as segments 174-180 in the cigarette of the preferred embodiment. The 913/77C:56 2 a ~ 7 segments 174-180 are placed on mylar tube 168 containing the electrolyte 170. It is important to note that the delivery of taste and flavor depends on, besides many other factors, the sequence in which the segments 174-180 are placed. In the preferred embodiment, the flavors applied to the segments 174-180 are as follows:
Segment No. Flavor 174 Sample 2-2 (Burley) 175 Sample 6-1 (Latakia) 176 Nicotine 177 Sample 2-2 (Burley) 178 Sample 6-1 (Latakia) 179 Sample 5-3 (Turkish) 180 Menthol The flavors were used at a level of 10 mg of a flavor sample on a 10 mm segment. The nicotin used 2.5 mg nicotine on a 7 mm segment. The menthol was used at a llevel of 1.43mg on a 10mm segment.

The heat chamber 168 and the flavored tobacco segments 174-180 are inserted into another mylar tube 182, 100 mm long and .298" O.D. Collars 184 are fabricated from reconstituted tobacco sheet (P831-189-AA5116, Kimberly-Clark corporation, GA) by rolling a ~egment of 20.5 X 6 cm to form a tube with a .293"
O.D., .208" I.D~ and 6.0 cm length. This tube is cut into 5 mm collars and held in place in the end of tube 182 with Elmer's glue.
The collar 184 at the end of the outer tube 182 serves to hold the heat chamber 168 in place. To the mouth end of the tube 182 is inserted a segment of COD filter 186, one end of which is cut at a 60 degree angle. The COD filter 186 is 13 mm long on the short 913/77C:57 : ~:

2 ~ 7 - 5~ -side and has a passage hole 4.5 mm in diameter through the center.
The outer tube 182 is wrapped with a ~006"
thick polystyrene insulating material 188 (Astro Valcour Inc., N.Y.) 49 X 100 mm in dimension forming several layers, only one of which is shown. This is then overwrapped with cigarette paper 190 and tipping paper 192 (respectively P2831-77 and AR~704 from Kimberly-Clark Corporation, GA). The initiating end of the cigarette has a series of 5 air intake holes 194, equally spaced 72 degrees apart and 7 mm from the end, made with a 23 gauge B-D syringe needle. The collar 184 seals the front of the cigarette 90 that air that flows past the tobacco segments 174-180 may only enter through holes 194. The small amount of steam or other gases created by the reaction pass out the initiating end of the cigarette and are thus diverted away from the air intake holes 194.
The cigarette is activated by inserting the heat source 160 through collar 184 and into the heat chamber 168, forcing electrolyte 170 to flow along outerwrap 166 and into the extruded rod 162. When fully inserted, the end of heat source 160 will be flush with the end of the heat chamber 168 and collar 184. About 30 seconds after initiation, taste and flavor components are delivered to the mouth of the smoker upon puffing. If it i8 desired that the cigarette generate an aroma when activated, a drop of tobacco flavor extract may be added to the fiber rod 164 or end of heat source 160. Under normal puffing conditions the cigarette will deliver the flavor and taste components for at least 7 minutes. After this period the rate of delivery decreases.
Several advantages are obtained with preferred embodiments of the invention. The particle 913/77C:58 ~ , 2 ~ 7 sizes of the atomized or milled frozen melts, or shreds of bimetallic foil, can be used to adjust surface areas and hence control the speed of the reaction. Likewlse, pressing and extruding conditions may be varied to change the porosity of the heat source to optimize electrolyte penetration and thus the reaction rate.
Alternatively, where the particles of metallic agents are packed into a straw, a water retention aid such as celite mixed with the powders keeps the water from vaporizing and escaping from the heat chamber.
The bimetallic foil geometry assures good electrical contact between the two metallic agents, even when the exposed surface of the anode corrodes.
Also, this embodiment enables the ratio of the surface area to the total mass of the anode to be de~igned over a wide range of values simply by controlling the thickness of the anode. Limiting ranges of thickness are dictated by the ability to manufacture and process the bimetallic element.
The wire model (FIG. 6) presents the oppor-tunity to control the rate of reaction by controlling the flow of electrons between the wire 94 and strands 92. For example, if the wire 94 and strands 92 are isolated electrically 80 that they only have one point of electrical contact, a resistor may be used as a means for controlling the rate of electrical current between the wire 94 and strands 92 to thereby control the rate of the electrochemical interaction.
Because the cigarette of the pre~ent invention may be made to look like a conventional cigarette, it may inadvertently be attempted to be lit with a match, cigarette lighter or other flame.
Therefore, the heat source preferably should not be combustible, or at least be ~elf extinguishing if inadvertently contacted by a flame. One advantage of 913/77C:59 ~ '' ~ ...

2 ~ 7 the pressed-rod heat sources is that they are compact enough that they have good heat transfer properties.
As a result, if the end of the rod is contacted by a flame, the tightly compacted particles conduct the heat away, preventing the end from reaching a combustion temperature.
It should be appreciated that the structures and methods of the present invention are capable of being incorporated in the form of a variety of embodi-ments, only a few of which have been illustrated anddescribed above. The invention may be embodied in other forms without departing from its spirit or essential characteristics. For example, even though the systems described herein use only two metallic agents, the heat sources may be made using more than two metallic agent~ that electrochemically interact.
Thus, the described embodiments are to be considered in all respects only as illustrative and not restrictive, and the scope of the invention is, therefore, indicated by the appended claims rather than by the foregoing description. All changes which come within the meaning and range of equivalency of the claims are to be embraced within their scope.

913/77C:60

Claims (20)

1. A smoking article comprising:
a) a flavor material; and b) a non-combustion heat source for heating the flavor material comprising at least two metallic agents capable of interacting electrochemically with one another wherein the at least two metallic agents are in the form of frozen melt of at least two metals.

2. A smoking article comprising:
a) a flavor material; and b) a non-combustion heat source for heating the flavor material comprising at least two metallic agents capable of interacting electrochemically with one another wherein the at least two metallic agents comprise two metals in the form of a bimetallic foil.

3. A smoking article comprising:
a) a flavor material; and b) a non-combustion heat source for heating the flavor material comprising at least two metallic agents capable of interacting electrochemically with one another wherein the at least two metallic agents comprise a first metal in the form of a wire in close proximity and in electrical contact with a second metal.

4. The smoking article of any one of claims 1 to 3 wherein the flavor material comprises tobacco.

5. The smoking article of any one of claims 1 to 3 wherein the flavor material comprises tobacco, and wherein the two metallic agents are selected from the group consisting of iron, copper, nickel, palladium, silver, gold, platinum, carbon, cobalt, magnesium, aluminum, lithium, Fe2O3, Fe3O4, Mg2Ni, MgNi2, Mg2Ca, MgCO2, and combinations thereof.

6. The smoking article of any one of claims 1 to 3 wherein the flavor material comprises tobacco, and wherein the tobacco is treated to reduce the temperature at which nicotine and flavors in the tobacco will volatilize.

7. The smoking article of any one of Claims 1 to 3 further comprising a filter on one end thereof and an initiating end opposite the filter, and wherein the flavor material is contained within an outer tube having air intake holes near the initiating end and a collar sealing the initiating end such that any steam or gases from the heat chamber exit out the initiating end and are directed away from the air intake holes.

8. A method of heating tobacco in a smoking article comprising:
a) providing a non-combustion heat source comprising at least two metallic agents capable of interacting electrochemically with one another in a heat-transferrable relationship with the tobacco, wherein the at least two metallic agents are in the form of i) a frozen melt of at least two metals, ii) two metals in the form of a bimetallic foil or iii) a first metal in the form of a wire in close proximity and in electrical contact with a second metal;

b) initiating the electrochemical interaction.

9. The method of Claim 8 wherein the heat source reaches a temperature of at least 70°C within 30 seconds of initiating the electrochemical reaction.

10. The method of any one of Claims 8 to 9 wherein the heat source maintains a temperature of at least 85°C for at least 7 minutes.

11. A process for producing flavor substances from tobacco comprising:
(a) heating tobacco during a first staged heating to a first toasting temperature to drive off volatile materials;
(b) increasing said toasting temperature during a second staged heating to a second toasting temperature; and (c) separately collecting, as flavor substances, at least portions of said volatile materials driven off at said first and second toasting temperatures.

12. A process for producing a flavor substance from tobacco comprising:
(a) reducing the moisture content of the tobacco without removing volatile flavor components;
(b) heating the dried tobacco at a toasting temperature to drive off volatile materials; and (c) collecting, as a flavor substance, at least a portion of the volatile materials.

13. A process for producing flavor substances from tobacco comprising:

(a) heating tobacco in a flowing gas stream at a toasting temperature to drive off volatile materials; and (b) separately collecting, as flavor substances, a portion of the volatile materials that are removed from said flowing gas stream as it passes sequentially through (i) a moderate temperature trap;
(ii) a cold temperature trap; and (iii) a filter capable of collecting submicron sized aerosol particles.

14. A method of forming an electrochemical heat source comprising the steps of:
a) providing particles comprising at least two metallic agents in electrical contact with one another;
b) extruding the particles into an extruded rod and c) dividing said rod to form an individual heat source.

15. A method of forming an electrochemical heat source containing magnesium comprising the steps of:
a) providing particles comprising magnesium and at least one other metallic agent in electrical contact with the magnesium;
b) mixing a binder with deionized water to form a gel;
c) cooling the particles and gel;
d) mixing the cooled particles and cooled gel;
e) extruding the mixture of particles and gel into an extruded rod; and f) dividing said rod to form an individual heat source.

16. A method of forming an electrochemical heat source comprising the steps of:
a) providing a first metallic agent in the form of one or more strands;
b) providing a second metallic agent in the form of a wire, the second metallic agent being capable of reacting electrochemically with the first metallic agent to produce heat;
c) wrapping the wire around the one or more strands; and d) forming a non-corrodible electrical contact between the wire and the one or more strands.

17. A method of forming an electrochemical heat source comprising the steps of:
a) providing two metallic agents in the form of foil having layers of the metallic agents in electrical contact with one another, the two metallic agents being capable of reacting electrochemically with one another to produce heat; and b) rolling the foil into a roll.

18. An electrochemical heat source comprising:
a) a rod-shaped member comprising particles of at least two metallic agents in electrical contact with one another capable of interacting electrochemically with one another to product heat; and b) an electrolyte absorbent material surrounding the rod-shaped member.

19. An electrochemical heat source comprising:

a) a roll of a bimetallic foil, the bimetallic foil comprising layers of metallic agents capable of interacting electrochemically with one another to produce heat; and b) an electrolyte absorbent material interspaced between layers of the bimetallic foil in the roll.

20. An electrochemical heat source comprising:
a) strands of a first metallic agent;
b) a wire of a second metallic agent wrapped around the strands, the first and second metallic agents being capable of interacting electrochemically with one another to produce heat; and c) an electrical contact between he wire and the strands, the contact being protected from corrosion.