CA2094392A1 - Mass spectrometer-based continuous emissions monitoring system for hazardous waste stack gas measurements - Google Patents

Mass spectrometer-based continuous emissions monitoring system for hazardous waste stack gas measurements

Info

Publication number
CA2094392A1
CA2094392A1 CA 2094392 CA2094392A CA2094392A1 CA 2094392 A1 CA2094392 A1 CA 2094392A1 CA 2094392 CA2094392 CA 2094392 CA 2094392 A CA2094392 A CA 2094392A CA 2094392 A1 CA2094392 A1 CA 2094392A1
Authority
CA
Canada
Prior art keywords
mass spectrometer
monitoring system
hazardous waste
stack gas
exhaust gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA 2094392
Other languages
French (fr)
Other versions
CA2094392C (en
Inventor
Candace D. Bartman
James H. Renfroe Jr.
Henry L. Robards Jr.
Erin M. Connolly
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Marine Shale Processors Inc
Original Assignee
Candace D. Bartman
James H. Renfroe Jr.
Henry L. Robards Jr.
Erin M. Connolly
Marine Shale Processors, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Candace D. Bartman, James H. Renfroe Jr., Henry L. Robards Jr., Erin M. Connolly, Marine Shale Processors, Inc. filed Critical Candace D. Bartman
Publication of CA2094392A1 publication Critical patent/CA2094392A1/en
Application granted granted Critical
Publication of CA2094392C publication Critical patent/CA2094392C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/44—Sample treatment involving radiation, e.g. heat
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/2247—Sampling from a flowing stream of gas
    • G01N1/2258—Sampling from a flowing stream of gas in a stack or chimney
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/24—Suction devices
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00—Sampling; Preparing specimens for investigation
    • G01N1/02—Devices for withdrawing samples
    • G01N1/22—Devices for withdrawing samples in the gaseous state
    • G01N1/2247—Sampling from a flowing stream of gas
    • G01N1/2258—Sampling from a flowing stream of gas in a stack or chimney
    • G01N2001/2261—Sampling from a flowing stream of gas in a stack or chimney preventing condensation (heating lines)

Abstract

A continuous emissions monitoring system for exhaust gas emissions containing HCl comprising a sampling subsystem with a sample probe in the effluent collecting effluent that is transmitted through heated conduits to filtering means and pump means to a mass spectrometer. The sampling subsystem is maintained at a temperature no less than about 190 °C and the flow rate through the system is greater than about 10 liters per minute. The process for continuous monitoring of exhaust emissions containing HCl extracts an exhaust gas sample and maintains the temperature and physical state of the exhaust gas throughout transport of the sample from the exhaust effluent to a mass spectrometer.
CA002094392A 1990-10-22 1991-10-16 Mass spectrometer-based continuous emissions monitoring system for hazardous waste stack gas measurements Expired - Fee Related CA2094392C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US60129990A 1990-10-22 1990-10-22
US601,299 1990-10-22
PCT/US1991/007449 WO1992007242A1 (en) 1990-10-22 1991-10-16 A mass spectrometer-based continuous emissions monitoring system for hazardous waste stack gas measurements

Publications (2)

Publication Number Publication Date
CA2094392A1 true CA2094392A1 (en) 1992-04-23
CA2094392C CA2094392C (en) 2000-09-19

Family

ID=24406987

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002094392A Expired - Fee Related CA2094392C (en) 1990-10-22 1991-10-16 Mass spectrometer-based continuous emissions monitoring system for hazardous waste stack gas measurements

Country Status (17)

Country Link
US (1) US5415025A (en)
EP (1) EP0554327A1 (en)
JP (1) JPH06504614A (en)
AU (1) AU660951B2 (en)
BR (1) BR9107030A (en)
CA (1) CA2094392C (en)
FI (1) FI931773A (en)
IE (1) IE913688A1 (en)
IL (1) IL99771A0 (en)
LT (1) LTIP409A (en)
LV (1) LV10811A (en)
MX (1) MX9101697A (en)
PL (1) PL169569B1 (en)
RU (1) RU2074389C1 (en)
WO (1) WO1992007242A1 (en)
YU (1) YU46955B (en)
ZA (1) ZA918375B (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
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DE19523599A1 (en) * 1995-06-30 1997-01-02 Ruhrgas Ag Mass flow rate determination of emitted component in engine exhaust gases
DE19631002C2 (en) * 1996-08-01 1998-07-16 Testo Gmbh & Co Sample gas hose for a gas analysis device
US6487920B1 (en) 1997-01-30 2002-12-03 Trustees Of Tufts College Situ soil sampling probe system with heated transfer line
US6293161B1 (en) * 1998-05-12 2001-09-25 Honda Giken Kogyo Kabushiki Kaisha Exhaust gas sampling apparatus
US6021678A (en) * 1998-05-27 2000-02-08 Kennecott Utah Copper Corporation Apparatus for transporting emissions from a stack
US5979220A (en) * 1998-06-30 1999-11-09 Siemens Westinghouse Power Corporation In-situ sensors for gas turbines
JP3876554B2 (en) * 1998-11-25 2007-01-31 株式会社日立製作所 Method and apparatus for monitoring chemical substance and combustion furnace using the same
US6212937B1 (en) 1999-01-26 2001-04-10 Consumers Energy Company Stack gas emissions monitoring system
US7029920B2 (en) * 2001-10-31 2006-04-18 General Electric Company Method and system for monitoring combustion source emissions
US20030221708A1 (en) * 2002-06-04 2003-12-04 Chun-Hao Ly Method of cleaning a semiconductor process chamber
US20080115594A1 (en) * 2006-11-16 2008-05-22 Mangan, Inc. High temperature enclosure system for flare gas sampling
FR2910966B1 (en) * 2006-12-28 2009-04-17 Commissariat Energie Atomique COUPLED MEASURING DEVICE FOR GLOBAL AND CONTINUOUS TRACKING OF TARESTS PRESENT IN A GASEOUS FLOW
FR2910967B1 (en) * 2006-12-28 2009-04-03 Commissariat Energie Atomique DEVICE AND METHOD FOR CONTINUOUSLY MEASURING TARGET CONCENTRATION IN A GASEOUS FLOW
US9086398B1 (en) * 2014-01-21 2015-07-21 Caterpillar Inc. Engine exhaust gas sampling for mass spectrometer real time oil consumption measurement
CN106987792A (en) * 2017-06-07 2017-07-28 上海颐柏热处理设备有限公司 A kind of acetylene carburizing furnace under normal pressure
CN107478777A (en) * 2017-08-10 2017-12-15 安徽省碧水电子技术有限公司 A kind of CEMS backflush units decompression protection system
CN107807165A (en) * 2017-11-29 2018-03-16 安徽中烟工业有限责任公司 A kind of experimental provision for monitoring smoker's suction and exhalation gaseous phase of main stream smoke of cigarette chemical composition oral cavity residual efficiency on-line
CN111111392B (en) * 2019-12-30 2021-08-31 杭州电子科技大学 Online automatic control method for SO2 concentration during blowback of CEMS table of power plant

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3718434A (en) * 1972-01-13 1973-02-27 R Pierce Apparatus and method for detecting gaseous contaminants
US3848548A (en) * 1973-11-27 1974-11-19 Hercules Inc Incineration process for disposal of waste propellant and explosives
US4073619A (en) * 1974-10-28 1978-02-14 British Steel Corporation Sampling gas for analysis
US3960500A (en) * 1975-01-09 1976-06-01 Bailey Meter Company Gas sampling analyzing system
GB1496887A (en) * 1975-06-12 1978-01-05 British Petroleum Co Chimney
US4094187A (en) * 1977-07-22 1978-06-13 Champion International Corporation Stack gas analyzing system with calibrating/sampling feature
US4578986A (en) * 1984-07-06 1986-04-01 Champion International Corporation Gas analyzer for dry/dusty kilns
DE8421369U1 (en) * 1984-07-17 1987-08-06 Bernath, Tibor, Dipl.-Ing., 3000 Hannover, De
FR2578325B1 (en) * 1985-03-04 1987-03-20 Siderurgie Fse Inst Rech GAS SAMPLING AND CONDITIONING LINE FOR ITS ANALYSIS.
US4856352A (en) * 1988-08-23 1989-08-15 The Babcock & Wilcox Company Gas sampling system for reactive gas-solid mixtures
US4974455A (en) * 1989-08-29 1990-12-04 Lear Siegler Measurement Controls Corporation Dilution extractive probe
US4974453A (en) * 1989-10-19 1990-12-04 United States Department Of Energy Method and apparatus for nitrogen oxide determination
JP4149672B2 (en) * 1998-07-06 2008-09-10 ザ・グッドイヤー・タイヤ・アンド・ラバー・カンパニー Improved sidewall with insert structure for run-flat tires

Also Published As

Publication number Publication date
PL169569B1 (en) 1996-08-30
LV10811A (en) 1995-08-20
CA2094392C (en) 2000-09-19
IE913688A1 (en) 1992-04-22
ZA918375B (en) 1993-03-31
RU2074389C1 (en) 1997-02-27
FI931773A0 (en) 1993-04-20
BR9107030A (en) 1993-08-17
FI931773A (en) 1993-04-20
WO1992007242A1 (en) 1992-04-30
AU8841791A (en) 1992-05-20
US5415025A (en) 1995-05-16
AU660951B2 (en) 1995-07-13
YU46955B (en) 1994-06-24
IL99771A0 (en) 1992-08-18
YU168691A (en) 1994-01-20
JPH06504614A (en) 1994-05-26
EP0554327A1 (en) 1993-08-11
MX9101697A (en) 1992-06-05
LTIP409A (en) 1994-10-25

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