CA2120813A1 - Process for producing polyolefins and polyolefin catalyst - Google Patents
Process for producing polyolefins and polyolefin catalystInfo
- Publication number
- CA2120813A1 CA2120813A1 CA002120813A CA2120813A CA2120813A1 CA 2120813 A1 CA2120813 A1 CA 2120813A1 CA 002120813 A CA002120813 A CA 002120813A CA 2120813 A CA2120813 A CA 2120813A CA 2120813 A1 CA2120813 A1 CA 2120813A1
- Authority
- CA
- Canada
- Prior art keywords
- metallocenes
- transition metal
- polyolefin catalyst
- producing polyolefins
- cyclopentadienyls
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63904—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with another component of C08F4/62
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Abstract
The present invention provides a process for preparing polyolefins having a multimodal or at least bimodal molecular weight distribution by contacting in a reaction mixture under polymerization conditions at least one olefin and a catalyst system comprising a supported catalyst-component comprising an alumoxane and at least two metallocenes containing the same transition metal and selected from mono, di, and tri-cyclopentadienyls and substituted cyclopentadienyls of a transition metal and wherein at least one of the metallocenes is bridged and at least one of the metallocenes is unbridged.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP93870064A EP0619325B1 (en) | 1993-04-07 | 1993-04-07 | Process for preparing polyolefin catalysts |
EP93870064.8 | 1993-04-07 | ||
US08/224,604 US5719241A (en) | 1993-04-07 | 1994-04-07 | Process for producing polyolefins and polyolefin catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2120813A1 true CA2120813A1 (en) | 1994-10-08 |
CA2120813C CA2120813C (en) | 2006-07-25 |
Family
ID=26134956
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002120813A Expired - Fee Related CA2120813C (en) | 1993-04-07 | 1994-04-07 | Process for producing polyolefins and polyolefin catalyst |
Country Status (10)
Country | Link |
---|---|
US (2) | US5719241A (en) |
EP (1) | EP0619325B1 (en) |
JP (1) | JP4049403B2 (en) |
AT (1) | ATE204884T1 (en) |
CA (1) | CA2120813C (en) |
DE (1) | DE69330674T2 (en) |
DK (1) | DK0619325T3 (en) |
ES (1) | ES2163404T3 (en) |
HU (1) | HU220239B (en) |
PT (1) | PT619325E (en) |
Families Citing this family (102)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2181413A1 (en) * | 1995-07-18 | 1998-01-18 | Edwar S. Shamshoum | Process for the syndiotactic propagation of olefins |
US6166153A (en) * | 1995-07-18 | 2000-12-26 | Fina Technology, Inc. | Process for the syndiotactic propagation of olefins |
DE69633436T3 (en) † | 1995-07-24 | 2016-06-16 | Mitsui Chemicals, Inc. | Ethylene copolymer composition |
FR2746672B1 (en) | 1996-04-02 | 1998-04-24 | Atochem Elf Sa | CATALYTIC COMPONENT AND ITS USE IN OLEFIN POLYMERIZATION |
AU2411797A (en) * | 1996-05-03 | 1997-11-26 | Dsm N.V. | A process for making polyolefins having broad molecular weight distributions |
US6759499B1 (en) * | 1996-07-16 | 2004-07-06 | Exxonmobil Chemical Patents Inc. | Olefin polymerization process with alkyl-substituted metallocenes |
US6583227B2 (en) * | 1996-09-04 | 2003-06-24 | Exxonmobil Chemical Patents Inc. | Propylene polymers for films |
US5847059A (en) * | 1996-12-20 | 1998-12-08 | Fina Technology, Inc. | Catalyst yield from supported metallocene catalysts |
US6180736B1 (en) | 1996-12-20 | 2001-01-30 | Exxon Chemical Patents Inc | High activity metallocene polymerization process |
US5965477A (en) * | 1997-02-21 | 1999-10-12 | Council Of Scientific & Industrial Research | Process for the preparation of supported metallocene catalyst |
GB9712663D0 (en) * | 1997-06-16 | 1997-08-20 | Borealis As | Process |
US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
US6268447B1 (en) | 1998-12-18 | 2001-07-31 | Univation Technologies, L.L.C. | Olefin polymerization catalyst |
US6677265B1 (en) | 1997-12-08 | 2004-01-13 | Albemarle Corporation | Process of producing self-supported catalysts |
ES2198098T3 (en) | 1998-03-09 | 2004-01-16 | Basell Poliolefine Italia S.P.A. | MULTIETAPE PROCEDURE FOR POLYMERIZATION OF OLEFINS. |
US6245868B1 (en) | 1998-05-29 | 2001-06-12 | Univation Technologies | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
US6303719B1 (en) | 1998-12-18 | 2001-10-16 | Univation Technologies | Olefin polymerization catalyst system |
EP1144465A2 (en) * | 1998-12-18 | 2001-10-17 | Univation Technologies LLC | Olefin polymerization catalyst system, polymerization process and polymer therefrom |
KR100438130B1 (en) * | 1998-12-18 | 2004-07-02 | 유니베이션 테크놀로지즈, 엘엘씨 | Olefin Polymerization Catalyst System, Polymerization Process and Polymer Therefrom |
US20010047065A1 (en) * | 1999-06-03 | 2001-11-29 | Sun-Chueh Kao | Method for preparing a supported catalyst system and its use in a polymerization process |
US6482905B1 (en) | 1999-08-16 | 2002-11-19 | Phillips Petroleum Company | Unsymmetric unbridged bis-indenyl metallocenes and their use |
DE19940151A1 (en) * | 1999-08-24 | 2001-03-01 | Targor Gmbh | Supported catalyst systems, process for their preparation and process for the preparation of poly-1-alkenes with bimodal or multimodal molecular mass distribution |
US6395666B1 (en) * | 1999-09-29 | 2002-05-28 | Phillips Petroleum Company | Organometal catalyst compositions |
TW526209B (en) * | 1999-10-21 | 2003-04-01 | Asahi Chemical Ind | Method for producing an olefin homopolymer or an olefin copolymer |
EP1242476B1 (en) * | 1999-10-22 | 2007-05-02 | Univation Technologies LLC | Start up methods for multiple catalyst systems |
CN1217733C (en) | 1999-12-16 | 2005-09-07 | 菲利浦石油公司 | Organometal compound catalyst |
US6384161B1 (en) * | 1999-12-30 | 2002-05-07 | Phillips Petroleum Company | Method and catalyst system for producing polyolefins with broadened molecular weight distributions |
US7041617B2 (en) | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
EP1138604A1 (en) * | 2000-03-30 | 2001-10-04 | Fina Research S.A. | Glossy plastic containers |
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JP2001316415A (en) * | 2000-05-10 | 2001-11-13 | Tosoh Corp | Catalyst for olefin polymerization and method for manufacturing olefinic polymer using the same |
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US6605675B2 (en) | 2000-12-04 | 2003-08-12 | Univation Technologies, Llc | Polymerization process |
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CN110655597A (en) * | 2019-10-09 | 2020-01-07 | 营口风光新材料股份有限公司 | MgCl2Preparation method and application of metallocene catalyst loaded on silica gel carrier |
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US4935474A (en) * | 1983-06-06 | 1990-06-19 | Exxon Research & Engineering Company | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
US4897455A (en) * | 1985-06-21 | 1990-01-30 | Exxon Chemical Patents Inc. | Polymerization process |
US4752597A (en) * | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
US4659685A (en) * | 1986-03-17 | 1987-04-21 | The Dow Chemical Company | Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound |
US4658078A (en) * | 1986-08-15 | 1987-04-14 | Shell Oil Company | Vinylidene olefin process |
JPH0742301B2 (en) * | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | Particulate aluminoxane, its manufacturing method and its use |
US5064797A (en) * | 1987-04-03 | 1991-11-12 | Phillips Petroleum Company | Process for producing polyolefins and polyolefin catalysts |
IT1237398B (en) * | 1989-01-31 | 1993-06-01 | Ausimont Srl | CATALYSTS FOR THE POLYMERIZATION OF OLEFINE. |
JP2566829B2 (en) * | 1989-08-03 | 1996-12-25 | 日本石油株式会社 | Method for producing polyolefin |
MY141000A (en) * | 1990-04-18 | 2010-02-12 | Mitsui Chemicals Inc | Process for the preparation of an ethylene copolymer and an olefin polymer, and catalysts for olefin polymerization |
US5087788A (en) * | 1991-03-04 | 1992-02-11 | Ethyl Corporation | Preparation of high purity vinylindene olefin |
DE69226564T3 (en) * | 1991-05-20 | 2004-04-08 | Mitsui Chemicals, Inc. | Catalyst and process for olefin polymerization |
DE69219206T2 (en) * | 1991-05-31 | 1997-08-28 | Mitsui Petrochemical Ind | Solid catalyst component, catalyst and process for olefin polymerization |
US5281679A (en) * | 1991-11-07 | 1994-01-25 | Exxon Chemical Patents Inc. | Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof |
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1993
- 1993-04-07 ES ES93870064T patent/ES2163404T3/en not_active Expired - Lifetime
- 1993-04-07 AT AT93870064T patent/ATE204884T1/en not_active IP Right Cessation
- 1993-04-07 DE DE69330674T patent/DE69330674T2/en not_active Expired - Lifetime
- 1993-04-07 PT PT93870064T patent/PT619325E/en unknown
- 1993-04-07 EP EP93870064A patent/EP0619325B1/en not_active Expired - Lifetime
- 1993-04-07 DK DK93870064T patent/DK0619325T3/en active
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1994
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- 1994-04-07 HU HU9400991A patent/HU220239B/en not_active IP Right Cessation
- 1994-04-07 US US08/224,604 patent/US5719241A/en not_active Expired - Lifetime
- 1994-04-07 CA CA002120813A patent/CA2120813C/en not_active Expired - Fee Related
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1995
- 1995-06-02 US US08/459,526 patent/US6541413B1/en not_active Expired - Lifetime
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EP0619325B1 (en) | 2001-08-29 |
ATE204884T1 (en) | 2001-09-15 |
PT619325E (en) | 2002-02-28 |
HU9400991D0 (en) | 1994-06-28 |
DE69330674T2 (en) | 2002-07-04 |
DK0619325T3 (en) | 2001-12-03 |
JPH06322014A (en) | 1994-11-22 |
DE69330674D1 (en) | 2001-10-04 |
JP4049403B2 (en) | 2008-02-20 |
US6541413B1 (en) | 2003-04-01 |
US5719241A (en) | 1998-02-17 |
CA2120813C (en) | 2006-07-25 |
HUT67821A (en) | 1995-05-29 |
EP0619325A1 (en) | 1994-10-12 |
HU220239B (en) | 2001-11-28 |
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