CA2145569A1 - Polymer mixture and films prepared therefrom - Google Patents

Polymer mixture and films prepared therefrom

Info

Publication number
CA2145569A1
CA2145569A1 CA002145569A CA2145569A CA2145569A1 CA 2145569 A1 CA2145569 A1 CA 2145569A1 CA 002145569 A CA002145569 A CA 002145569A CA 2145569 A CA2145569 A CA 2145569A CA 2145569 A1 CA2145569 A1 CA 2145569A1
Authority
CA
Canada
Prior art keywords
polyamide
polymer mixture
blocks
prepared therefrom
vinylacetate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002145569A
Other languages
French (fr)
Other versions
CA2145569C (en
Inventor
Roland Steenblock
Norbert Kock
Detlef Fiedler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Produktions und Vertriebs GmbH and Co oHG
Original Assignee
Elf Atochem Deutschland GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Elf Atochem Deutschland GmbH filed Critical Elf Atochem Deutschland GmbH
Publication of CA2145569A1 publication Critical patent/CA2145569A1/en
Application granted granted Critical
Publication of CA2145569C publication Critical patent/CA2145569C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
    • C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C08L31/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/12—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/12—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31725—Of polyamide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31725—Of polyamide
    • Y10T428/31739—Nylon type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2164—Coating or impregnation specified as water repellent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2164—Coating or impregnation specified as water repellent
    • Y10T442/2197—Nitrogen containing

Abstract

The invention relates to a polymer mixture which contains (A) 50 to 85 wt.% of a polyether block amide consisting of 30 to 60 wt.% of polyamide-12, polyamide-11 and/or polyamide-12,12 blocks and 70 to 40 wt.% of polyethylene glycol blocks, (B) 10 to 40 wt.% of a polyether block amide consisting of 65 to 85 wt.% of polyamide-12, polyamide-11 and/or polyamide-12,12 blocks and 35 to 15 wt.% of polyethylene glycol blocks, and (C) 5 to 40 wt.% of a poly(ethylene-co-vinylacetate-g-maleic anhydride) polymer consisting of 75 to 95 wt.% of ethylene, 5 to 25 wt.% of vinylacetate and 0.1 to 2 wt.% of malefic anhydride, wherein the data relating to wt.% for the constituents (A), (B) and (C) are with reference to the total amount of polymer mixture. The invention also relates to films produced from this polymer mixture and the use of these films to produce waterproof, water vapour permeable, wind resistant textile composite materials, dressing materials and hygiene items.
CA002145569A 1994-03-29 1995-03-27 Polymer mixture and films prepared therefrom Expired - Fee Related CA2145569C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4410921.0 1994-03-29
DE4410921A DE4410921C2 (en) 1994-03-29 1994-03-29 Polymer blend and its use

Publications (2)

Publication Number Publication Date
CA2145569A1 true CA2145569A1 (en) 1995-09-30
CA2145569C CA2145569C (en) 2007-03-06

Family

ID=6514176

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002145569A Expired - Fee Related CA2145569C (en) 1994-03-29 1995-03-27 Polymer mixture and films prepared therefrom

Country Status (13)

Country Link
US (2) US5614588A (en)
EP (1) EP0675167B1 (en)
JP (1) JP3563146B2 (en)
KR (1) KR100289165B1 (en)
CN (1) CN1111267A (en)
AT (1) ATE175705T1 (en)
AU (1) AU1506195A (en)
CA (1) CA2145569C (en)
DE (2) DE4410921C2 (en)
DK (1) DK0675167T3 (en)
ES (1) ES2129687T3 (en)
TW (1) TW362108B (en)
ZA (1) ZA952129B (en)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE29619194U1 (en) * 1996-11-05 1997-02-27 Rein Plastik Kg Foil for the production of disposable protective clothing
FR2755970B1 (en) * 1996-11-19 1998-12-18 Atochem Elf Sa MATERIAL COMPRISING A POLYAMIDE, A POLYAMIDE AND POLYETHER BLOCK POLYMER AND A FUNCTIONALIZED POLYOLEFIN, FILM AND OBJECT OBTAINED THEREFROM
JPH10168298A (en) 1996-12-10 1998-06-23 Elf Atochem Japan Kk Thermoplastic resin composition and molded product
US5900471A (en) * 1997-04-03 1999-05-04 Alliedsignal Inc. Films of blended nylon resins and laminates therefrom
NL1009935C2 (en) * 1998-08-24 2000-02-25 Hyplast Nv Film with controllable gas and steam permeability for packaging comprises block copolymer containing polyolefin and polyether
US6357278B1 (en) * 1999-08-09 2002-03-19 General Electric Company Polymer coatings for chemical sensors
BR0102116B1 (en) 2000-05-10 2010-09-21 component for a breathing circuit member.
US7559324B2 (en) 2000-06-21 2009-07-14 Fisher & Paykel Healthcare Limited Conduit with heated wick
FR2812647B1 (en) 2000-08-04 2003-02-21 Atofina WATERPROOFING FILM
DE10125207A1 (en) * 2001-05-18 2002-11-21 Kalle Gmbh & Co Kg Smoke permeable nutrient material skin based on polyamide modified with glycols and containing a bubble former, useful in the production of smoked sausages
US6753369B2 (en) * 2001-10-16 2004-06-22 Buckman Laboratories International, Inc. Leather waterproofing formulation and leather goods waterproofed therewith
US7166656B2 (en) * 2001-11-13 2007-01-23 Eastman Kodak Company Smectite clay intercalated with polyether block polyamide copolymer
AU2003244171B2 (en) 2002-09-09 2007-11-15 Fisher & Paykel Healthcare Limited Limb for Breathing Circuit
EP1591471A4 (en) * 2003-02-04 2007-07-25 Toray Industries Moisture-permeable waterproof film, composite material, and processes for producing these
DE10323417B3 (en) 2003-05-23 2004-09-16 Kuhne Anlagenbau Gmbh Flat or tubular sheath or film, useful for the packaging of smokeable sausage and meat products, comprises polyamide, polyvinyl alcohol and polyether block amide and is formed by blow molding
AU2004202274B2 (en) 2003-05-30 2006-10-26 Fisher & Paykel Healthcare Limited Breathing Assistance Apparatus
FR2858624B1 (en) * 2003-08-08 2005-09-09 Rhodia Engineering Plastics Sa ELECTROSTATIC COMPOSITION BASED ON POLYAMIDE MATRIX
AU2004203870B2 (en) 2003-09-17 2011-03-03 Fisher & Paykel Healthcare Limited Breathable Respiratory Mask
US7344767B2 (en) * 2004-07-26 2008-03-18 Serena Giori Self-cooling beverage container with permeable wall
JP5075349B2 (en) * 2006-04-25 2012-11-21 グンゼ株式会社 Antistatic fiber structure
EP2024479B2 (en) * 2006-05-31 2015-02-25 The Procter & Gamble Company Cleaning compositions with amphiphilic graft polymers based on polyalkylene oxides and vinyl esters
DE102008038375A1 (en) 2008-08-19 2010-02-25 Epurex Films Gmbh & Co. Kg Composite material, useful for laminating porous substrates e.g. synthetic foam materials, comprises a low softening layer made from thermoplastic copolyester elastomer and a high softening layer made of thermoplastic polyurethane
SE532941C2 (en) 2008-09-15 2010-05-18 Phasein Ab Gas sampling line for breathing gases
AU2010247771A1 (en) * 2009-05-11 2011-11-24 Invista Technologies S.A. R.L. Nylon carpet fibers having bleach resistance
EP3909631A1 (en) 2009-12-22 2021-11-17 Fisher & Paykel Healthcare Limited Components for medical circuits
FR2992652B1 (en) * 2012-06-27 2014-06-20 Arkema France USE OF A THERMOPLASTIC STARCH ALLOY AND TPE FOR THE MANUFACTURE OF A ULTRA-FINE IMPER-BREATHABLE ADHESIVE FILM.
WO2014142679A1 (en) 2013-03-15 2014-09-18 Fisher & Paykel Healthcare Limited Drying expiratory limb with tailored temperature profile and multi-lumen configuration
CA3093754A1 (en) 2013-03-15 2014-09-18 Fisher & Paykel Healthcare Limited Components for medical circuits
FR3011550B1 (en) * 2013-10-07 2016-11-18 Arkema France POLYAMIDE BLOCK COPOLYMER AND POLYETHER BLOCK
DE102013016583A1 (en) * 2013-10-08 2015-04-09 Infiana Germany Gmbh & Co. Kg Film with adjustable water vapor permeability
KR102345704B1 (en) * 2013-11-26 2021-12-30 에이지씨 가부시키가이샤 Water- and oil-repellent composition, article and process for producing article
JP2017071765A (en) * 2015-10-06 2017-04-13 三洋化成工業株式会社 Moisture permeable waterproof material
FR3098816B1 (en) * 2019-07-15 2021-10-22 Arkema France Polyamide rigid block copolymers and flexible blocks comprising polyethylene glycol
CN111117215A (en) * 2020-01-02 2020-05-08 李宁（中国）体育用品有限公司 Thermoplastic elastomer foamed shoe material and preparation method thereof
CN111303593B (en) * 2020-03-23 2022-04-12 江苏科奕莱新材料科技有限公司 Thermoplastic polymer composition for waterproof moisture-permeable film
FR3108912B1 (en) 2020-04-07 2023-06-30 Arkema France Composition of polymers for waterproof-breathable films
FR3108911B1 (en) 2020-04-07 2023-06-30 Arkema France Composition of polymers for waterproof-breathable films

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2273021B1 (en) * 1974-05-31 1977-03-11 Ato Chimie
FR2401947A1 (en) * 1977-09-02 1979-03-30 Ato Chimie PROCESS FOR THE PREPARATION OF POLYETHER-ESTER-AMIDES USABLE SEQUENCES, AMONG OTHERS, AS MOLDING, EXTRUDING OR SPINNING PRODUCTS
DE2935631A1 (en) * 1979-09-04 1981-04-16 Plate Bonn Gmbh, 5300 Bonn MULTILAYER PLASTIC FILM, METHOD FOR THE PRODUCTION AND USE THEREOF
US4707528A (en) * 1984-07-30 1987-11-17 Toyoda Gosei Co., Ltd. Polyamide resin composition
US5024792A (en) * 1986-10-14 1991-06-18 W. R. Grace & Co.-Conn. Antistatic thermoplastic/polyamide-polyether compositions and antistatic polymeric films made therefrom
FR2639644A1 (en) * 1988-11-25 1990-06-01 Atochem THERMOPLASTIC ELASTOMERIC FILM PERMEABLE TO WATER VAPOR BASED ON POLYETHERESTERAMIDE, PROCESS FOR PRODUCING THE SAME AND ARTICLES COMPRISING SUCH FILM
DE3902019C2 (en) * 1989-01-25 1996-09-19 Atochem Elf Deutschland Thermoplastic composition for the production of molding compounds
CH677674A5 (en) * 1989-03-30 1991-06-14 Inventa Ag
US5348804A (en) * 1990-06-01 1994-09-20 Salomon S.A. Ski structure obtained from a polyamide based thermoplastic elastomer and grafted copolyolefin based film adapted for adhesion
ATE156172T1 (en) * 1990-06-01 1997-08-15 Atochem Elf Sa COMPOSITIONS OF THERMOPLASTIC ELASTOMERS BASED ON POLYAMIDES AND MODIFIED POLYOLEFINS, MOLDED OR EXTRUDED BODY, FILMS AND COMPOSITE MATERIALS MADE THEREOF
US5369179A (en) * 1990-09-07 1994-11-29 W. R. Grace & Co.-Conn. Inherently antistatic thermoplastic polyamide-polyether films
NZ239723A (en) * 1990-09-18 1993-06-25 Chicopee Blends comprising a hydrophilic block poly (ether-co-amide) and a hydrophobic polymer
GB9023188D0 (en) * 1990-10-24 1990-12-05 Bicc Plc Polymer compositions
AU671617B2 (en) * 1992-03-13 1996-09-05 Mcneil-Ppc, Inc. Bicomponent polymeric films containing block poly(ether-co-amides)
US5356709A (en) * 1992-05-14 1994-10-18 Baxter International, Inc. Non-PVC coextruded medical grade port tubing

Also Published As

Publication number Publication date
DE4410921C2 (en) 1996-12-19
DE59504772D1 (en) 1999-02-25
EP0675167B1 (en) 1999-01-13
ZA952129B (en) 1995-12-14
KR950032463A (en) 1995-12-20
DE4410921A1 (en) 1995-10-05
ES2129687T3 (en) 1999-06-16
JPH0812884A (en) 1996-01-16
CA2145569C (en) 2007-03-06
CN1111267A (en) 1995-11-08
TW362108B (en) 1999-06-21
US5614588A (en) 1997-03-25
AU1506195A (en) 1995-10-05
EP0675167A1 (en) 1995-10-04
US5703161A (en) 1997-12-30
KR100289165B1 (en) 2001-05-02
ATE175705T1 (en) 1999-01-15
DK0675167T3 (en) 1999-09-06
JP3563146B2 (en) 2004-09-08

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Legal Events

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