CA2149618A1 - Spray polyurea elastomers containing organic carbonates to improve processing characteristics - Google Patents

Spray polyurea elastomers containing organic carbonates to improve processing characteristics

Info

Publication number
CA2149618A1
CA2149618A1 CA002149618A CA2149618A CA2149618A1 CA 2149618 A1 CA2149618 A1 CA 2149618A1 CA 002149618 A CA002149618 A CA 002149618A CA 2149618 A CA2149618 A CA 2149618A CA 2149618 A1 CA2149618 A1 CA 2149618A1
Authority
CA
Canada
Prior art keywords
component
carbonate
polyurea elastomers
spray polyurea
containing organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002149618A
Other languages
French (fr)
Other versions
CA2149618C (en
Inventor
Dudley Joseph Ii Primeaux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Petrochemical LLC
Original Assignee
Dudley Joseph Ii Primeaux
Huntsman Corporation
Huntsman Petrochemical Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dudley Joseph Ii Primeaux, Huntsman Corporation, Huntsman Petrochemical Corporation filed Critical Dudley Joseph Ii Primeaux
Publication of CA2149618A1 publication Critical patent/CA2149618A1/en
Application granted granted Critical
Publication of CA2149618C publication Critical patent/CA2149618C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/109—Esters; Ether-esters of carbonic acid, e.g. R-O-C(=O)-O-R
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/156—Heterocyclic compounds having oxygen in the ring having two oxygen atoms in the ring
    • C08K5/1565—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2150/00—Compositions for coatings
    • C08G2150/50—Compositions for coatings applied by spraying at least two streams of reaction components

Abstract

Spray polyurea elastomers are disclosed made from an (A) component and a (B) component, where the (A) component has a quasi-prepolymer made from an isocyanate and an active hydrogen-containing material, such as a polyoxyalkylenepolyamine. The (B) component includes an amine resin, such as an amine-terminated polyoxyalkylene polyol which may be the same or different from the polyoxyalkylene polyamine of the quasi-prepolymer. The viscosity of the (A) component is reduced by the inclusion of an organic, alkylene carbonate, such as ethylene carbonate, propylene carbonate, butylene carbonate, dimethyl carbonate, and the like.
The alkylene carbonate also serves as a compatibilizer between between the two components, thus giving an improved mix of the system.
CA002149618A 1994-06-01 1995-05-17 Spray polyurea elastomers containing organic carbonates to improve processing characteristics Expired - Fee Related CA2149618C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/252,031 US5442034A (en) 1994-06-01 1994-06-01 Spray polyurea elastomers containing organic carbonates to improve processing characteristics
US08/252,031 1994-06-01
EP95109286A EP0748827B1 (en) 1994-06-01 1995-06-16 Spray polyurea elastomers

Publications (2)

Publication Number Publication Date
CA2149618A1 true CA2149618A1 (en) 1995-12-02
CA2149618C CA2149618C (en) 2008-11-25

Family

ID=26138671

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002149618A Expired - Fee Related CA2149618C (en) 1994-06-01 1995-05-17 Spray polyurea elastomers containing organic carbonates to improve processing characteristics

Country Status (3)

Country Link
US (1) US5442034A (en)
EP (1) EP0748827B1 (en)
CA (1) CA2149618C (en)

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5700846A (en) * 1994-06-15 1997-12-23 Huntsman Petrochemical Corporation Polyurea foam made from a partially aminated polyether polyamine
US5731397A (en) * 1996-04-16 1998-03-24 Huntman Petrochemical Corporation Polyurea spray railcar lining systems
US6399736B1 (en) * 1997-03-11 2002-06-04 Huntsman Petrochemical Corporation Method of preparing spray elastomer systems
US6013755A (en) * 1997-03-11 2000-01-11 Huntsman Petrochemical Corporation Method of preparing an aliphatic polyurea spray elastomer system
US5962618A (en) * 1997-04-16 1999-10-05 Huntsman Petrochemical Corporation Polyurea spray railcar lining systems
US5759695A (en) * 1997-06-05 1998-06-02 Huntsman Petrochemical Corporation Polyurea elastomer systems with improved adhesion to substrates
USRE40088E1 (en) 1997-06-13 2008-02-19 3M Innovative Properties Company Liquid pavement marking compositions
EP0988333B1 (en) * 1997-06-13 2006-03-15 Minnesota Mining And Manufacturing Company Liquid pavement marking compositions
KR100246009B1 (en) * 1997-12-26 2000-04-01 이은택 Spray polyurea elastomer containing alkylolamine
CA2335348A1 (en) 1998-06-18 1999-12-23 Daniel W. Irvine Method for damping noise, vibration and harshness of a substrate and composition therefor
US6437059B1 (en) 1999-02-11 2002-08-20 Reichhold, Inc. Composition of epoxy, urethane polyacrylate and polyamine
US6369189B1 (en) 1999-12-07 2002-04-09 Reichhold, Inc. Hindered amine adducts for polyurea systems
US6635737B1 (en) 2000-05-26 2003-10-21 Williamette Valley Company Polymers derived from low unsaturation polyamines
US6605126B1 (en) 2000-06-02 2003-08-12 Milliken & Co. Low-viscosity polymeric colorants exhibiting high color strength characteristics
US6525108B2 (en) 2000-06-02 2003-02-25 Milliken & Company Scorch inhibiting compositions for polyurethane foams
US6541532B1 (en) 2000-06-02 2003-04-01 Milliken & Company Scorch inhibiting compositions for polyurethane foams
US6395797B2 (en) 2000-06-02 2002-05-28 Milliken & Company Reduction of color degradation of triphenylmethane polymeric colorants within polyurethane foams
US6294590B1 (en) 2000-06-02 2001-09-25 Milliken & Company Reduction of color degradation of triphenylmethane polymeric colorants within polyurethane foams
US6607591B1 (en) 2000-06-02 2003-08-19 Milliken & Company Low-viscosity nonaqueous liquid pigment dispersions and methods of utilizing such compositions
US20030013835A1 (en) * 2001-04-25 2003-01-16 Anastasios Zahariadis 100% polyurea elastomeric system, process for producing and use thereof
US7001948B2 (en) * 2001-05-16 2006-02-21 American Polymer Corporation Polyurea coating compositions
US7097734B2 (en) 2001-05-16 2006-08-29 Hill David A System and method for forming wood products
ES2288553T3 (en) * 2001-06-15 2008-01-16 Huntsman Petrochemical Corporation SYNERGIC AMINE CHAIN EXTENSORS IN ELASTOMEROS IN POLYUREA SPRAYING.
US7378483B2 (en) * 2002-08-27 2008-05-27 Acushnet Company Compositions for golf equipment
US20070270240A1 (en) * 2002-09-09 2007-11-22 Reactamine Technology, Llc Pure polyurea and method for making same
US7427424B2 (en) * 2003-08-07 2008-09-23 Hill David A Systems and methods of bonding materials
US20070173348A1 (en) * 2004-06-02 2007-07-26 Acushnet Company Compositions for Golf Equipment
US7342056B2 (en) * 2004-06-17 2008-03-11 3M Innovative Properties Company Pavement marking comprising modified isocyanate
US20060068198A1 (en) * 2004-09-02 2006-03-30 Bratys Dan M Composite films and process for making the same
US7387819B2 (en) * 2005-01-10 2008-06-17 Ppg Industries Ohio, Inc. Method and apparatus for repairing bed-liner coatings
EP1913047A1 (en) * 2005-07-07 2008-04-23 Huntsman International Llc Spray polyurea system, process for producing and use thereof
US7753616B2 (en) * 2006-12-21 2010-07-13 Greer Robert F System, method and composition for adhering preformed thermoplastic traffic control signage to pavement
US20080176040A1 (en) * 2007-01-22 2008-07-24 Patrick Ilfrey Dwelling exterior thermal protection
US20080173728A1 (en) * 2007-01-22 2008-07-24 Patrick Ilfrey High-solids, reactive components spray application systems
US8313809B2 (en) * 2007-12-11 2012-11-20 Patrick Ilfrey Same-day coatings and processes
US8168299B1 (en) 2008-03-05 2012-05-01 Dct Holdings, Llc Polymeric coating and lining system
CN101544818A (en) * 2008-03-26 2009-09-30 拜耳材料科技贸易(上海)有限公司 Isocyanate-terminated prepolymer and preparation method and application thereof
KR101541188B1 (en) * 2008-11-06 2015-08-03 삼성전자주식회사 Composition for polyurethane foam and polyurethane foam prepared therefrom
US20110132782A1 (en) 2009-12-07 2011-06-09 Patrick Ilfrey Article and method for reactive mixtures
EP2365011A1 (en) * 2010-03-02 2011-09-14 Sika Technology AG Amino group terminated toughener and its use in epoxy resin based compositions
WO2011143179A2 (en) 2010-05-12 2011-11-17 3M Innovative Properties Company Method of reinforcing irregular structures
US8691929B2 (en) 2010-11-18 2014-04-08 Ppg Industries Ohio, Inc. Curable compositions that form a polyurea demonstrating elongation properties over a large temperature range
US9487662B1 (en) * 2014-01-21 2016-11-08 Nanotech Industries, Inc. Radiation-curable biobased flooring compositions with nonreactive additives
DE102015108232A1 (en) 2015-05-26 2016-12-01 Franken Systems Gmbh Process for the moisture-resistant primer of mineral substrates
DE102015110841A1 (en) 2015-07-06 2017-01-12 Franken Systems Gmbh Use of a reactive system for building waterproofing and structural waterproofing
US11822117B2 (en) * 2019-10-08 2023-11-21 Corning Incorporated Primary coating compositions with improved microbending performance
CN111363120A (en) * 2020-04-24 2020-07-03 长沙盾甲新材料科技有限公司 High-strength spraying polyurethane material containing reactive flame retardant and preparation method thereof
GB2604129A (en) * 2021-02-25 2022-08-31 John Foster Richard Compositions for forming polyureas, methods of forming polyureas and kits for forming polyureas
CN115806652A (en) * 2022-12-14 2023-03-17 合肥安利聚氨酯新材料有限公司 Low-carbon environment-friendly polyurethane resin and preparation method thereof

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE595337A (en) 1957-09-25
US4154716A (en) * 1972-04-24 1979-05-15 The Dow Chemical Company Fluid rapid-setting urethane compositions
US4000105A (en) * 1973-01-29 1976-12-28 The Dow Chemical Company Solid, rapid-setting, rigid polyurethanes
US3883466A (en) * 1973-05-07 1975-05-13 Dow Chemical Co Rapid setting polyurethanes from diols and polyisocyanates prepared in the presence of an organic carbonate
US4530941A (en) * 1983-01-26 1985-07-23 The Dow Chemical Company Reaction injection molded polyurethanes employing high molecular weight polyols
US4748192A (en) * 1986-03-24 1988-05-31 Urylon Development, Inc. Aliphatic polyurethane sprayable coating compositions and method of preparation
US4709002A (en) * 1986-06-05 1987-11-24 Atlantic Richfield Company Method for the preparation of rigid non-cellular reaction injection molded thermoset polyisocyanurate compositions
US4705814A (en) 1986-11-06 1987-11-10 Texaco Inc. Reaction product of polyoxyalkylene polyamine and an aliphatic isocyanate
US4731427A (en) * 1987-04-01 1988-03-15 Arco Chemical Company Method for the preparation of rigid reaction injection molded thermoset polyurethane modified polyisocyanurate compositions
US5028635A (en) * 1988-06-28 1991-07-02 Mobay Corporation Polyurea-cyclic carbonate RIM systems having improved flow properties
EP0350644A1 (en) * 1988-06-28 1990-01-17 Miles Inc. Polyurea rin sytems having improved flow properties
DE3825320A1 (en) * 1988-07-26 1990-02-01 Bayer Ag METHOD FOR PRODUCING COMPRESSED MATERIALS
GB8822790D0 (en) * 1988-09-28 1988-11-02 Ici Plc Novel polyisocyanate composition
US4883854A (en) * 1988-09-30 1989-11-28 Medtronic, Inc. Hydroxyl functional monomers
US5171818A (en) * 1990-03-23 1992-12-15 Bruce Wilson Sprayable aliphatic polyurea-polyurethane coating compositions and methods
US5082917A (en) * 1990-05-29 1992-01-21 Texaco Chemical Co. Piperazine derivatives as chain extenders in polyurea elastomer systems and method making same
US5162388A (en) * 1991-06-04 1992-11-10 Texaco Chemical Company Aliphatic polyurea elastomers
CA2057335A1 (en) * 1991-08-26 1993-02-27 Dudley J. Ii Primeaux Quasi-prepolymers of aliphatic diisocyanates and polyoxyalkylene polyamine mixtures useful for making polyurea elastomers
US5218005A (en) * 1991-10-16 1993-06-08 Texaco Chemical Company Polyurea elastomers made using polyamine/carbonyl adducts as chain extenders
US5175231A (en) * 1992-04-17 1992-12-29 Fiber-Cote Corporation Urethane oligomers and polyurethanes
FR3098292B1 (en) 2019-07-04 2021-07-23 Cta Int Telescoped ammunition including a shell

Also Published As

Publication number Publication date
US5442034A (en) 1995-08-15
CA2149618C (en) 2008-11-25
EP0748827B1 (en) 2000-03-15
EP0748827A1 (en) 1996-12-18

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