CA2156722A1 - Fluorine-containing polymers and preparation and use thereof - Google Patents

Fluorine-containing polymers and preparation and use thereof

Info

Publication number
CA2156722A1
CA2156722A1 CA002156722A CA2156722A CA2156722A1 CA 2156722 A1 CA2156722 A1 CA 2156722A1 CA 002156722 A CA002156722 A CA 002156722A CA 2156722 A CA2156722 A CA 2156722A CA 2156722 A1 CA2156722 A1 CA 2156722A1
Authority
CA
Canada
Prior art keywords
fluoroalkyl
disulfinates
fluoropolymers
fluorine
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002156722A
Other languages
French (fr)
Other versions
CA2156722C (en
Inventor
Werner M. Grootaert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining And Manufacturing Company
Werner M. Grootaert
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining And Manufacturing Company, Werner M. Grootaert filed Critical Minnesota Mining And Manufacturing Company
Publication of CA2156722A1 publication Critical patent/CA2156722A1/en
Application granted granted Critical
Publication of CA2156722C publication Critical patent/CA2156722C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine

Abstract

Fluoroalkyl sulfinates were synthesized and used as a source of fluoroalkyl radicals in aqueous emulsion polymerization. The resulting polymers contained a high level of perfluoroalkyl end groups. When fluoroalkyl disulfinates were utilized, the fluoroalkyl moiety and was incorporated in the polymer backbone. These disulfinates act as monomers, yielding fluoropolymers with specific micro structural fragments derived from the parent perfluoro disulfinate. Novel fluoropolymers can thus be prepared.
CA002156722A 1993-03-23 1994-01-24 Fluorine-containing polymers and preparation and use thereof Expired - Fee Related CA2156722C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/036,073 US5285002A (en) 1993-03-23 1993-03-23 Fluorine-containing polymers and preparation and use thereof
US08/036073 1993-03-23
PCT/US1994/000833 WO1994021697A1 (en) 1993-03-23 1994-01-24 Fluorine-containing polymers and preparation and use thereof

Publications (2)

Publication Number Publication Date
CA2156722A1 true CA2156722A1 (en) 1994-09-29
CA2156722C CA2156722C (en) 2005-03-29

Family

ID=21886467

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002156722A Expired - Fee Related CA2156722C (en) 1993-03-23 1994-01-24 Fluorine-containing polymers and preparation and use thereof

Country Status (9)

Country Link
US (2) US5285002A (en)
EP (1) EP0690880B1 (en)
JP (1) JP3457317B2 (en)
CN (1) CN1041206C (en)
AU (1) AU6094594A (en)
CA (1) CA2156722C (en)
DE (1) DE69405859T2 (en)
RU (1) RU2131888C1 (en)
WO (1) WO1994021697A1 (en)

Families Citing this family (185)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5623038A (en) * 1994-12-14 1997-04-22 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation thereof
IT1272861B (en) * 1995-01-04 1997-07-01 Ausimont Spa COPOLYMERS OF ETHYLENE WITH TETRAFLUOROETHYLENE AND / OR CHLOROTRIFLUOROETHYLENE, WITH IMPROVED MECHANICAL PROPERTIES AT HIGH TEMPERATURES
IT1273608B (en) 1995-04-28 1997-07-08 Ausimont Spa FLUOROELASTOMERS SUBSTANTIALLY FREE OF POLAR TERMINALS AND RELATED PREPARATION PROCESS
DE19516967A1 (en) * 1995-05-12 1996-11-14 Basf Ag Process for the preparation of polymers of vinylic monomers with a narrow molecular weight distribution by controlled radical polymerization
US5639837A (en) * 1996-06-04 1997-06-17 E. I. Du Pont De Nemours And Company Process for making fluoropolymers
DE69610099T2 (en) * 1995-06-30 2001-05-10 Du Pont METHOD FOR PRODUCING FLUOR-CONTAINING POLYMERS
IT1277445B1 (en) * 1995-08-04 1997-11-10 Ausimont Spa VULCANIZABLE COMPOSITIONS OF FLUOROELASTOMERS CONTAINING BROMO
US5710217A (en) * 1995-09-15 1998-01-20 Minnesota Mining And Manufacturing Company Extrudable thermoplastic hydrocarbon compositions
US5734085A (en) * 1995-12-21 1998-03-31 Minnesota Mining And Manufacturing Company Fluorinated phosphonium salts
US5922425A (en) * 1996-05-28 1999-07-13 Minnesota Mining And Manufacturing Company Multi-layer compositions and articles comprising fluorine-containing polymer
US5733981A (en) * 1996-08-26 1998-03-31 Minnesota Mining And Manufacturing Company Aqueous dehydrofluorination method
US6114452A (en) * 1996-11-25 2000-09-05 E. I. Du Pont De Nemours And Company Perfluoroelastomer composition having excellent heat stability
US5874523A (en) * 1996-11-25 1999-02-23 E. I. Du Pont De Nemours And Company Sulfonated perfluoroelastomer composition having improved processability
US5936060A (en) * 1996-11-25 1999-08-10 E. I. Du Pont De Nemours And Company Perfluoroelastomer composition having improved processability
US6413630B1 (en) 1997-05-15 2002-07-02 3M Innovative Properties Company Decorative film
DE19740633A1 (en) * 1997-09-16 1999-03-18 Bayer Ag Production of low-viscosity fluoro-rubber
US6462228B1 (en) 1997-12-22 2002-10-08 3M Innovative Properties Company Process for preparation of fluorinated sulfinates
EP1068248A1 (en) * 1998-03-23 2001-01-17 Dyneon Llc Perfluoroelastomer compositions
EP1194462A1 (en) 1999-07-02 2002-04-10 Dyneon LLC Fluoroelastomer compositions and articles made therefrom
US6593416B2 (en) 2000-02-01 2003-07-15 3M Innovative Properties Company Fluoropolymers
US6720360B1 (en) * 2000-02-01 2004-04-13 3M Innovative Properties Company Ultra-clean fluoropolymers
IT1318488B1 (en) * 2000-04-21 2003-08-25 Ausimont Spa FLUOROVINYLETERS AND POLYMERS THAT CAN BE OBTAINED.
US7534845B2 (en) 2000-04-21 2009-05-19 Solvay Solexis S.P.A. Fluorovinyl ethers and polymers obtainable therefrom
IT1318487B1 (en) * 2000-04-21 2003-08-25 Ausimont Spa FLUORO-ELASTOMERS.
IT1318596B1 (en) * 2000-06-23 2003-08-27 Ausimont Spa THERMOPROCESSABLE TFE COPOLYMERS.
AU2001292633A1 (en) 2000-09-18 2002-04-02 3M Innovative Properties Company Imidate-containing fluoropolymer compositions
US6657012B2 (en) 2000-09-18 2003-12-02 3M Innovative Properties Company Metal amine complex containing fluoropolymer compositions
US6730760B2 (en) 2001-01-31 2004-05-04 3M Innovative Properties Company Perfluoroelastomers having a low glass transition temperature and method of making them
US6890995B2 (en) * 2001-01-31 2005-05-10 3M Innovative Properties Company Fluoropolymer compositions
US7125941B2 (en) * 2001-03-26 2006-10-24 3M Innovative Properties Company Aqueous emulsion polymerization process for producing fluoropolymers
US6844388B2 (en) 2001-04-12 2005-01-18 3M Innovative Properties Company Fluoropolymer compositions containing a nitrogen cure site monomer
US6803425B2 (en) 2001-04-12 2004-10-12 3M Innovative Properties Company Fluoropolymers having pendant imidate structures
US6794457B2 (en) 2001-04-30 2004-09-21 3M Innovative Properties Company Fluoropolymer curing system containing a nitrogen cure site monomer
US6753087B2 (en) 2001-05-21 2004-06-22 3M Innovative Properties Company Fluoropolymer bonding
US6630047B2 (en) * 2001-05-21 2003-10-07 3M Innovative Properties Company Fluoropolymer bonding composition and method
US7485371B2 (en) * 2004-04-16 2009-02-03 3M Innovative Properties Company Bonding compositions
US6685793B2 (en) 2001-05-21 2004-02-03 3M Innovative Properties Company Fluoropolymer bonding composition and method
US7045571B2 (en) * 2001-05-21 2006-05-16 3M Innovative Properties Company Emulsion polymerization of fluorinated monomers
US20050208308A1 (en) * 2001-05-21 2005-09-22 3M Innovative Properties Company Bonding compositions
US6545109B2 (en) 2001-06-29 2003-04-08 3M Innovative Properties Company Imide salts as emulsifiers for the polymerization of fluoroolefins
US7279522B2 (en) * 2001-09-05 2007-10-09 3M Innovative Properties Company Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant
US7291369B2 (en) 2001-10-03 2007-11-06 3M Innovative Properties Company Multi-layer articles including a fluoroelastomer layer and a barrier layer and method of making the same
US6916871B2 (en) * 2001-10-31 2005-07-12 3M Innovative Properties Company Composition and method for making a fluoroelastomer
US6844030B2 (en) 2001-12-14 2005-01-18 3M Innovative Properties Company Process for modifying a polymeric surface
US6752894B2 (en) 2001-12-14 2004-06-22 3M Innovative Properties Company Process for modifying a polymeric surface
ITMI20020598A1 (en) * 2002-03-22 2003-09-22 Ausimont Spa VULCANIZABLE FLUOROELASTOMERS
US20030198770A1 (en) * 2002-04-18 2003-10-23 3M Innovative Properties Company Composite fluoropolymer-perfluoropolymer assembly
US7569275B2 (en) 2002-04-18 2009-08-04 3M Innovative Properties Company Fluoropolymer articles
US6849314B2 (en) * 2002-04-18 2005-02-01 3M Innovative Properties Company Fluoropolymer blends and multilayer articles
US6759129B2 (en) 2002-04-18 2004-07-06 3M Innovative Properties Company Adhesion and bonding of multi-layer articles including a fluoropolymer layer
US6812310B2 (en) * 2002-06-21 2004-11-02 3M Innovative Properties Company Process for producing fluoropolymers having a reduced amount of polar end groups
US6803435B2 (en) 2002-07-18 2004-10-12 3M Innovative Properties Company Curable fluoropolymers containing bromine groups having improved compression set
ATE494312T1 (en) * 2002-07-29 2011-01-15 3M Innovative Properties Co FLUORELASTOMER AND METHOD FOR THE PRODUCTION THEREOF
CN1671757A (en) * 2002-07-29 2005-09-21 3M创新有限公司 Ultraclean fluoroelastomer suitable for use in the manufacturing of electronic components
DE60327452D1 (en) * 2002-10-31 2009-06-10 3M Innovative Properties Co EMULSIFY-FREE AQUEOUS EMULSION POLYMERIZATION METHOD FOR THE PRODUCTION OF FLUORIZED OLEFIN AND OLEFINIC HYDROCARBON COPOLYMERS
EP1576020B1 (en) * 2002-12-23 2011-01-26 3M Innovative Properties Company Fluoroplastic polymers having nitrogen-containing cure sites
US20040126708A1 (en) * 2002-12-31 2004-07-01 3M Innovative Properties Company Method for modifying the surface of a polymeric substrate
US6734254B1 (en) 2003-01-13 2004-05-11 3M Innovative Properties Company Co-curable blends featuring bromine-and iodine-containing fluoroplastic polymers
EP1441014A1 (en) * 2003-01-22 2004-07-28 3M Innovative Properties Company Aqueous fluoropolymer dispersion comprising a melt processible fluoropolymer and having a reduced amount of fluorinated surfactant
US6956085B2 (en) * 2003-02-14 2005-10-18 3M Innovative Properties Company Fluoroelastomer compositions
DE10313966A1 (en) * 2003-03-25 2004-10-14 AHC-Oberflächentechnik GmbH & Co. OHG Process for increasing the corrosion resistance of tubes and tubes manufactured in this way
ITMI20030774A1 (en) * 2003-04-15 2004-10-16 Solvay Solexis Spa FLUORINATED POLYMERS.
US20040241396A1 (en) * 2003-05-29 2004-12-02 3M Innovative Properties Company Method of modifying a surface of a substrate and articles therefrom
US20040241395A1 (en) * 2003-05-29 2004-12-02 3M Innovative Properties Company Method of modifying a surface of a substrate and articles therefrom
US6986947B2 (en) * 2003-10-09 2006-01-17 3M Innovative Properties Company Method of modifying a fluoropolymer and articles thereby
DE60336400D1 (en) * 2003-10-24 2011-04-28 3M Innovative Properties Co Aqueous dispersions of polytetrafluoroethylene particles
US7273531B2 (en) * 2003-11-05 2007-09-25 3M Innovative Properties Company Method of modifying a fluoropolymeric substrate and composite articles thereby
US7943388B2 (en) * 2003-11-14 2011-05-17 3M Innovative Properties Company Acoustic sensors and methods
EP1533325B1 (en) * 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
JP5021317B2 (en) * 2003-12-30 2012-09-05 スリーエム イノベイティブ プロパティズ カンパニー Methods and compositions for agglomerating fluoropolymers
ATE433350T1 (en) * 2004-03-01 2009-06-15 3M Innovative Properties Co METHOD FOR COATING AN OBJECT WITH A PLASTIC DISPERSION CONTAINING FLUORINE
FR2871469A1 (en) * 2004-06-10 2005-12-16 Arkema Sa PROCESS FOR PRODUCING FLUORINE POLYMER
ATE406423T1 (en) * 2004-07-05 2008-09-15 3M Innovative Properties Co PTFE PRIMER FOR METAL SUBSTRATES
US20060105285A1 (en) * 2004-11-17 2006-05-18 Naiyong Jing Nonelastomeric dental article with a protective fluoropolymer layer
US20060105179A1 (en) * 2004-11-17 2006-05-18 Hofman Gerald R A Elastomeric dental article with a protective fluoropolymer layer
US7402630B2 (en) * 2004-12-16 2008-07-22 3M Innovative Properties Company Curing compositions for fluoropolymers
US7214740B2 (en) * 2005-05-03 2007-05-08 3M Innovative Properties Company Fluorinated ionomers with reduced amounts of carbonyl end groups
GB2427170A (en) * 2005-06-17 2006-12-20 3M Innovative Properties Co Fluoropolymer film having glass microspheres
GB0525978D0 (en) 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
GB0514387D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
GB0514398D0 (en) * 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
US20080015304A1 (en) 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
GB0523853D0 (en) 2005-11-24 2006-01-04 3M Innovative Properties Co Fluorinated surfactants for use in making a fluoropolymer
US7671112B2 (en) * 2005-07-15 2010-03-02 3M Innovative Properties Company Method of making fluoropolymer dispersion
US7294677B2 (en) * 2005-08-25 2007-11-13 3M Innovative Properties Company Catalyst for making fluoroelastomer compositions and methods of using the same
GB2430437A (en) * 2005-09-27 2007-03-28 3M Innovative Properties Co Method of making a fluoropolymer
US7728087B2 (en) * 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
US20070276103A1 (en) * 2006-05-25 2007-11-29 3M Innovative Properties Company Fluorinated Surfactants
US7754795B2 (en) 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
US8119750B2 (en) * 2006-07-13 2012-02-21 3M Innovative Properties Company Explosion taming surfactants for the production of perfluoropolymers
US20100227992A1 (en) * 2006-08-24 2010-09-09 Klaus Hintzer Process for producing fluoropolymers
WO2008026707A1 (en) * 2006-08-31 2008-03-06 Asahi Glass Company, Limited Perfluorocarboxylic acid salt and method for producing the same
US20080070182A1 (en) * 2006-09-20 2008-03-20 3M Innovative Properties Company Orthodontic elements and other medical devices with a fluorinated polymer, and methods
JP5588679B2 (en) 2006-11-09 2014-09-10 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー Aqueous polymerization of fluorinated monomers using a polymerization agent containing fluoropolyether acid or salt and a short chain fluorosurfactant
ATE512165T1 (en) * 2006-11-09 2011-06-15 Du Pont AQUEOUS POLYMERIZATION OF FLUORINATED MONOMERS USING A POLYMERIZING AGENT COMPRISING FLUOROPOLYETHER ACID OR SALT AND HYDROCARBON SURFACTANT
CN101535351B (en) 2006-11-09 2012-03-21 纳幕尔杜邦公司 Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and siloxane surfactant
KR101500018B1 (en) * 2007-02-16 2015-03-06 쓰리엠 이노베이티브 프로퍼티즈 캄파니 System and process for the removal of fluorochemicals from water
US20080264864A1 (en) * 2007-04-27 2008-10-30 3M Innovative Properties Company PROCESS FOR REMOVING FLUORINATED EMULSIFIER FROM FLUOROPOLMER DISPERSIONS USING AN ANION-EXCHANGE RESIN AND A pH-DEPENDENT SURFACTANT AND FLUOROPOLYMER DISPERSIONS CONTAINING A pH-DEPENDENT SURFACTANT
US8338517B2 (en) * 2007-05-23 2012-12-25 3M Innovative Properties Company Aqueous compositions of fluorinated surfactants and methods of using the same
WO2008154345A1 (en) * 2007-06-06 2008-12-18 3M Innovative Properties Company Fluorinated ether compositions and methods of using the same
WO2009036131A2 (en) * 2007-09-14 2009-03-19 3M Innovative Properties Company Ultra low viscosity iodine containing amorphous fluoropolymers
US8288492B2 (en) * 2007-10-23 2012-10-16 E I Du Pont De Nemours And Company Difunctional oligomers of perfluoro(methyl vinyl ether)
US20090124755A1 (en) * 2007-11-09 2009-05-14 Dupont Performance Elastomers L.L.C. Process for producing fluoropolymers
US7754810B2 (en) * 2007-11-09 2010-07-13 Dupont Performance Elastomers Process for producing fluoropolymers
CN102007150B (en) * 2008-02-29 2015-09-23 3M创新有限公司 There is the Perfluoroelastomer of low carbonyl endgroup ratios
US20090281241A1 (en) 2008-05-09 2009-11-12 E. I. Du Pont De Nemours And Company Aqueous Polymerization of Fluorinated Monomer Using a Mixture of Fluoropolyether Acids or Salts
EP2143738A1 (en) 2008-07-08 2010-01-13 Solvay Solexis S.p.A. Method for manufacturing fluoropolymers
US8703889B2 (en) * 2008-07-08 2014-04-22 Solvay Solexis S.P.A. Method for manufacturing fluoropolymers
EA201100053A1 (en) * 2008-07-18 2011-08-30 3М Инновейтив Пропертиз Компани FLUORINATED ESSENTIAL COMPOUNDS AND METHODS OF THEIR APPLICATION
CN102282191A (en) * 2008-11-25 2011-12-14 3M创新有限公司 Fluorinated ether urethanes and methods of using the same
CN102317403A (en) 2008-12-18 2012-01-11 3M创新有限公司 Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions
EP2445939B1 (en) 2009-06-25 2020-09-23 3M Innovative Properties Company Curing compositions for fluoropolymers
EP2513173B1 (en) 2009-12-18 2013-09-25 Solvay Specialty Polymers Italy S.p.A. Process for manufacturing a dispersion of a vinylidene fluoride polymer
WO2011073344A1 (en) 2009-12-18 2011-06-23 Solvay Solexis S.P.A. Method for manufacturing fluoroelastomers
CN102762611B (en) 2009-12-18 2015-11-25 索尔维特殊聚合物意大利有限公司 Produce the method for fluoropolymer
EP2651880B1 (en) * 2010-12-17 2017-10-04 3M Innovative Properties Company Preparation of perfluorovinyl ether sulfinic acids and their salts
US9580526B2 (en) 2010-12-17 2017-02-28 3M Innovative Properties Company Partially fluorinated polysulfinic acids and their salts
JP5844819B2 (en) * 2010-12-17 2016-01-20 スリーエム イノベイティブ プロパティズ カンパニー Preparation of oligomers and co-oligomers of highly fluorinated sulfinic acids and their salts
EP2651863B1 (en) 2010-12-17 2019-12-04 3M Innovative Properties Company Methods of making partially fluorinated sulfinic acid monomers and their salts
JP6081922B2 (en) * 2010-12-17 2017-02-15 スリーエム イノベイティブ プロパティズ カンパニー Highly fluorinated sulfinic acid oligomers and co-oligomers and their salts
WO2012083107A2 (en) * 2010-12-17 2012-06-21 3M Innovative Properties Company Fluorine-containing polymer comprising a sulfinate-containing molecule
WO2012082707A1 (en) 2010-12-17 2012-06-21 3M Innovative Properties Company Microemulsions and fluoropolymers made using microemulsions
JP2014519501A (en) 2011-05-26 2014-08-14 ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. Hydrofluoro compounds
CN103582627B (en) * 2011-06-03 2016-08-31 3M创新有限公司 The fluoro-alkyl sulfinic acid of allyl ether end-blocking and salt thereof
EP2557109B1 (en) 2011-08-11 2019-01-23 3M Innovative Properties Company Method of bonding a fluoroelastomer compound to a metal substrate using low molecular weight functional hydrocarbons as bonding promoter
WO2013037707A1 (en) 2011-09-14 2013-03-21 Solvay Specialty Polymers Italy S.P.A. Polymerization process
US9902879B2 (en) 2011-09-29 2018-02-27 3M Innovative Properties Company Catalyzing amino-substituted organosilane ester primers
CN104080854B (en) 2011-12-16 2016-12-07 3M创新有限公司 Derive from the processing aid compositions of molecule containing sulfinate
CN104583247B (en) 2012-06-20 2016-12-21 索尔维特殊聚合物意大利有限公司 TFE copolymer
WO2013189824A1 (en) 2012-06-20 2013-12-27 Solvay Specialty Polymers Italy S.P.A. Tetrafluoroethylene copolymers
KR102120657B1 (en) 2012-11-05 2020-06-09 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Peroxide-curable fluoropolymer composition including solvent and method of using the same
WO2014088820A1 (en) 2012-12-04 2014-06-12 3M Innovative Properties Company Highly fluorinated polymers
JP6204488B2 (en) 2012-12-04 2017-09-27 スリーエム イノベイティブ プロパティズ カンパニー Partially fluorinated polymer
JP6360073B2 (en) 2012-12-20 2018-07-18 スリーエム イノベイティブ プロパティズ カンパニー COMPOSITE PARTICLES CONTAINING FLUOROPOLYMER, METHOD FOR PRODUCING THE SAME, AND ARTICLE CONTAINING THE COMPOSITE PARTICLES
CN105358591A (en) 2013-06-28 2016-02-24 索尔维特殊聚合物意大利有限公司 Fluoroelastomers
BR112016008623A2 (en) 2013-09-20 2018-05-02 3M Innovative Properties Co additive, composition and polymer processing methods.
CN103833874B (en) * 2014-03-07 2016-08-17 中昊晨光化工研究院有限公司 A kind of fluorubber and synthetic method thereof
JP6620113B2 (en) 2014-05-12 2019-12-11 ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. Process for controlled polymerization of fluoromonomers
WO2015173194A1 (en) 2014-05-12 2015-11-19 Solvay Specialty Polymers Italy S.P.A. Fluoroelastomers
JP6840073B2 (en) 2014-09-30 2021-03-10 ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. Method for producing fluoropolymer dispersion system
EP3230777B1 (en) 2014-12-09 2019-01-30 3M Innovative Properties Company System having a telecommunications element being concealed by a reflective structure comprising a polymer optical multilayer film
WO2016130894A1 (en) 2015-02-12 2016-08-18 3M Innovative Properties Company Tetrafluoroethylene copolymers having sulfonyl groups
CN107223139B (en) 2015-02-12 2020-06-30 3M创新有限公司 Tetrafluoroethylene/hexafluoropropylene copolymers containing perfluoroalkoxyalkyl side groups and methods of making and using the same
CN107223140A (en) 2015-02-12 2017-09-29 3M创新有限公司 Include the tetrafluoroethylene/hexafluoropropylene copolymer of perfluoro alkoxy alkyl side base
US10723102B2 (en) 2015-04-20 2020-07-28 3M Innovative Properties Company Durable low emissivity window film constructions
EP3353221B1 (en) 2015-09-23 2023-06-07 3M Innovative Properties Company Method of making a copolymer of tetrafluoroethylene having sulfonyl pendant groups
EP3362515B1 (en) 2015-10-13 2018-12-26 3M Innovative Properties Company Fluoropolymer processing additive, compositions, and methods
WO2017083688A1 (en) 2015-11-13 2017-05-18 3M Innovative Properties Company Compositions including a bimodal blend of amorphous fluoropolymers and their uses
CN108699190B (en) 2015-12-14 2021-10-12 索尔维特殊聚合物意大利有限公司 Process for making fluoroelastomers
CN108699198B (en) 2016-01-21 2021-06-08 3M创新有限公司 Additive treatment of fluoropolymers
CN108779209A (en) * 2016-03-07 2018-11-09 3M创新有限公司 Fluorinated copolymers with sulphonyl side group and the method for preparing ionomer
TW201815845A (en) 2016-05-17 2018-05-01 3M新設資產公司 Compositions including copolymers of vinylidene fluoride and tetrafluoroethylene and methods of using the same
US11028198B2 (en) 2016-08-17 2021-06-08 3M Innovative Properties Company Tetrafluoroethylene and perfluorinated allyl ether copolymers
WO2018118956A1 (en) 2016-12-20 2018-06-28 3M Innovative Properties Company Composition including fluoropolymer and inorganic filler and method of making a three-dimensional article
WO2018167190A1 (en) 2017-03-17 2018-09-20 Solvay Specialty Polymers Italy S.P.A. Method for making fluoropolymers
EP3375798A1 (en) 2017-03-17 2018-09-19 Solvay Specialty Polymers Italy S.p.A. Method for making fluoropolymers
CN110506091B (en) 2017-04-14 2021-10-22 3M创新有限公司 Durable low emissivity window film constructions
JP6859455B2 (en) 2017-05-19 2021-04-14 スリーエム イノベイティブ プロパティズ カンパニー A method for producing a polyfluoroylated allyl ether and a compound related to the method.
WO2019002180A1 (en) * 2017-06-30 2019-01-03 Solvay Specialty Polymers Italy S.P.A. Method for manufacturing partially fluorinated polymers
CN111201251B (en) 2017-09-08 2022-06-17 索尔维特殊聚合物意大利有限公司 Process for making fluoropolymers
KR20200054213A (en) 2017-09-14 2020-05-19 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Fluoropolymer dispersion, fluoropolymer dispersion production method, catalyst ink and polymer electrolyte membrane
US11919984B2 (en) 2018-02-19 2024-03-05 3M Innovative Properties Company Blends of crosslinking agents for fluoroelastomers
CN111757908A (en) 2018-02-19 2020-10-09 3M创新有限公司 Curable fluoroelastomer compositions
CN111757906A (en) 2018-02-19 2020-10-09 3M创新有限公司 Curable fluoroelastomer compositions
WO2019197915A1 (en) 2018-04-10 2019-10-17 3M Innovative Properties Company Blends of crosslinking agents for fluoroelastomers
GB201807544D0 (en) 2018-05-09 2018-06-20 3M Innovative Properties Co Fluoropolymers with very low amounts of a fluorinated alkanoic acid or its salts
WO2019239284A1 (en) 2018-06-13 2019-12-19 3M Innovative Properties Company Curable fluoroelastomer composition
CN111954662B (en) * 2018-07-09 2022-06-14 旭化成株式会社 Vinyl sulfonic anhydride, process for producing the same, and process for producing vinyl sulfonyl fluoride
WO2020035776A1 (en) 2018-08-13 2020-02-20 3M Innovative Properties Company Curable fluoroelastomer composition
TW202033573A (en) 2018-12-17 2020-09-16 美商3M新設資產公司 Composition including curable fluoropolymer and curative and methods of making and using them
WO2020183306A1 (en) 2019-03-12 2020-09-17 3M Innovative Properties Company Dispersible perfluorosulfonic acid ionomer compositions
EP3950725A4 (en) 2019-05-08 2023-07-19 Daikin Industries, Ltd. Fluoropolymer production method and fluoropolymer
US20220227696A1 (en) 2019-06-04 2022-07-21 3M Innovative Properties Company Multifunctional Fluorinated Compound, Fluorinated Polymers Made from the Compound, and Related Methods
EP4069755A1 (en) 2019-12-02 2022-10-12 3M Innovative Properties Company Dispersible particles of perfluorosulfonic acid ionomer
CN114901710B (en) 2019-12-20 2024-01-30 3M创新有限公司 Fluorinated copolymers and compositions and articles comprising the same
JP6989792B2 (en) 2019-12-25 2022-01-12 ダイキン工業株式会社 Fluoropolymer manufacturing method
CN115667198A (en) 2020-03-19 2023-01-31 3M创新有限公司 Perfluorinated allyl ethers and perfluorinated allylamines and methods of making and using the same
EP4133542A1 (en) 2020-04-09 2023-02-15 3M Innovative Properties Company Composite including fluorinated polymer and salt nanoparticles and articles including the same
FR3110168B1 (en) 2020-05-15 2022-08-26 Arkema France Process for producing thermally stable and highly crystalline vinylidene fluoride polymers
EP4019580A1 (en) 2020-12-28 2022-06-29 3M Innovative Properties Company Reduction of fluorinated acid in fluoropolymers
WO2022180547A1 (en) 2021-02-26 2022-09-01 3M Innovative Properties Company Process for making a fluoropolymer and fluoropolymer made therefrom
WO2022259087A1 (en) 2021-06-11 2022-12-15 3M Innovative Properties Company Method of making a fluoropolymer dispersion having a low amount of perfluoroalkanoic acids or salts thereof and the fluoropolymer comprises a low ionic end group ratio
WO2023057926A1 (en) 2021-10-07 2023-04-13 3M Innovative Properties Company Composite including fluorinated polymer and lithium fluoride nanoparticles and articles including the same
WO2023110696A1 (en) 2021-12-17 2023-06-22 Solvay Specialty Polymers Italy S.P.A. Method for the emulsion polymerization of fluoromonomer
WO2023165912A1 (en) 2022-03-01 2023-09-07 Solvay Specialty Polymers Italy S.P.A. Method for making fluoropolymers containing ion exchange groups

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL67722C (en) * 1947-02-07
DE1019827B (en) * 1951-03-06 1957-11-21 Degussa Process for the preparation of polymerization products
US2768156A (en) * 1951-03-08 1956-10-23 Heraeus Gmbh W C Process for the production of polymerisation products using sulphinc acid salts
FR1069088A (en) * 1954-03-01 1954-07-05 Heraeus Gmbh W C Process for increasing the activity of catalysts used in the preparation of polymerization products
US2862946A (en) * 1956-04-02 1958-12-02 Stauffer Chemical Co Esters of sulfenic acids and their preparation
GB836741A (en) * 1958-02-03 1960-06-09 Ici Ltd Improved polymerisation process
US3083220A (en) * 1958-07-03 1963-03-26 Du Pont Process for the preparation of fluosulfonates
DE1174989B (en) * 1962-01-10 1964-07-30 Basf Ag Process for the production of emulsion polymers
GB1004395A (en) * 1963-05-18 1965-09-15 Daikin Ind Ltd Method of polymerizing fluoroolefins in aqueous medium
US3337518A (en) * 1964-01-24 1967-08-22 Exxon Research Engineering Co Polymerization initiators consisting of halogenated sulfur containing organic compounds having at least one s(o)n functional group
DE1301516B (en) * 1966-07-21 1969-08-21 Cassella Farbwerke Mainkur Ag Process for the production of homo- and co-polymers from olefinically unsaturated monomers
US3492259A (en) * 1966-09-09 1970-01-27 Du Pont Process for polymerizing vinyl fluoride
NL155270B (en) * 1967-12-19 1977-12-15 Chatillon Italiana Fibre PROCESS FOR THE POLYMERIZATION IN THE MASS OF VINYL CHLORIDE, IF MIXED WITH AT LEAST ANOTHER COPOLYMERIZABLE MONOMER.
US3842019A (en) * 1969-04-04 1974-10-15 Minnesota Mining & Mfg Use of sulfonic acid salts in cationic polymerization
JPS4928675B1 (en) * 1970-01-30 1974-07-29
US4287320A (en) * 1974-08-01 1981-09-01 Minnesota Mining And Manufacturing Company Composition of fluoroelastomer and diorganosulfuroxide
FR2286153A1 (en) * 1974-09-24 1976-04-23 Ugine Kuhlmann POLYMERIZATION OR COPOLYMERIZATION PROCESS IN EMULSION OF VINYLIDENE FLUORIDE
US4035565A (en) * 1975-03-27 1977-07-12 E. I. Du Pont De Nemours And Company Fluoropolymer containing a small amount of bromine-containing olefin units
DE2739282C2 (en) * 1976-08-31 1985-03-28 Kuraray Co., Ltd., Kurashiki, Okayama Use of a curing system consisting of a peroxide, a secondary or tertiary amine and an alkali or alkaline earth metal salt of an arylsulfinic acid for the production of an adhesive
JPS5330193A (en) * 1976-08-31 1978-03-22 Kuraray Co Human body hard tissue adhesive compostion
US4420431A (en) * 1979-02-13 1983-12-13 Phillips Petroleum Company Salts of 3-cyano-3-alkene-sulfinic acids and salts of 3-carbamoyl-3-alkene sulfonic acids and preparations thereof
US4233421A (en) * 1979-02-26 1980-11-11 Minnesota Mining And Manufacturing Company Fluoroelastomer composition containing sulfonium curing agents
US4450263A (en) * 1979-08-30 1984-05-22 Minnesota Mining And Manufacturing Company Fluoropolymer gum of vinylidene fluoride, hexafluoropropene, and bromodifluoroethylene
DE3069835D1 (en) * 1980-09-19 1985-01-31 Asahi Glass Co Ltd Process for producing propylene-tetrafluoroethylene copolymer
US4381384A (en) * 1981-08-17 1983-04-26 E. I. Du Pont De Nemours And Company Continuous polymerization process
US4558141A (en) * 1981-11-19 1985-12-10 E. I. Du Pont De Nemours And Company Perfluorodioxole and its polymers
US4514197A (en) * 1983-02-15 1985-04-30 Armbruster Joseph M Filter for air circulator
US4574139A (en) * 1983-06-17 1986-03-04 Kuraray Co., Ltd. Polymer having a fluorine-containing end group and production of the same
US4626587A (en) * 1984-01-16 1986-12-02 E. I. Du Pont De Nemours And Company Extrusion finishing of perfluorinated copolymers
US4564662A (en) * 1984-02-23 1986-01-14 Minnesota Mining And Manufacturing Company Fluorocarbon elastomer
US5086123A (en) * 1984-02-27 1992-02-04 Minnesota Mining And Manufacturing Company Fluoroelastomer compositions containing fluoroaliphatic sulfonamides as curing agents
US4524197A (en) * 1984-08-28 1985-06-18 E. I. Du Pont De Nemours And Company Process for making vinylidene fluoride containing fluoroelastomers
JPS61152652A (en) * 1984-12-27 1986-07-11 Daikin Ind Ltd Fluorine-containing diacyl peroxide and use thereof
US4743658A (en) * 1985-10-21 1988-05-10 E. I. Du Pont De Nemours And Company Stable tetrafluoroethylene copolymers
US4882390A (en) * 1988-04-01 1989-11-21 Minnesota Mining And Manufacturing Company Fluoroelastomer composition with organo-onium compounds
FR2644466B1 (en) * 1989-03-15 1992-08-14 Solvay PROCESS FOR THE MANUFACTURE OF VINYLIDENE FLUORIDE POLYMERS AND USE OF VINYLIDENE FLUORIDE POLYMERS FOR THE FORMULATION OF PAINTS
US5134211A (en) * 1990-01-31 1992-07-28 E. I. Du Pont De Nemours And Company Hydroxy containing fluorovinyl compounds and polymers thereof
JP2921026B2 (en) * 1990-05-14 1999-07-19 ダイキン工業株式会社 Tetrafluoroethylene copolymer and method for producing the same
DE4038588A1 (en) * 1990-12-04 1992-06-11 Bayer Ag UNCROSSLINKED COPOLYMERISATES WITH REACTIVE DOUBLE BINDINGS MADE OF FLUOROMONERS AND ALKENYL (ISO) CYANURATES

Also Published As

Publication number Publication date
JP3457317B2 (en) 2003-10-14
EP0690880A1 (en) 1996-01-10
RU2131888C1 (en) 1999-06-20
US5285002A (en) 1994-02-08
CA2156722C (en) 2005-03-29
CN1041206C (en) 1998-12-16
CN1119870A (en) 1996-04-03
EP0690880B1 (en) 1997-09-24
AU6094594A (en) 1994-10-11
DE69405859T2 (en) 1998-05-20
WO1994021697A1 (en) 1994-09-29
US5378782A (en) 1995-01-03
JPH08508062A (en) 1996-08-27
DE69405859D1 (en) 1997-10-30

Similar Documents

Publication Publication Date Title
CA2156722A1 (en) Fluorine-containing polymers and preparation and use thereof
DE69405680T2 (en) Process for the (co) polymerization of fluorine-containing olefinic monomers in aqueous emulsion
KR900007872A (en) Process for preparing aqueous dispersion, aqueous dispersion and aqueous coating composition
RU1833395C (en) Method of tetrafluoroethylene copolymer synthesis
CA2164032A1 (en) Polymerization Processes
CA2202834A1 (en) Water repellent coating composition and coating films and coated articles using the same
ATE158310T1 (en) (CO)POLYMERIZATION OF FLUORINATED OLEFINIC MONOMERS IN AQUEOUS EMULSION
AU645536B2 (en) Emulsion polymers for high performance aqueous coatings
CA2164645A1 (en) Hardened and fire retardant wood products
PL319938A1 (en) Cellulose ethers in emulsive polymerisation suspensions
MX9705866A (en) Crosslinked polymers containing urethane groups.
ES519009A0 (en) PROCEDURE FOR OBTAINING DISPERSIONS OF POLYMERS OF RETICULAR GRAFT.
DE69116381T2 (en) POLYMER BLENDS FOR AQUEOUS DISPERSIONS WITH IMPROVED FREEZER-DEFROST STABILITY
ES2138415T3 (en) FLOWERED RUBBER.
CA2171666A1 (en) Improved cured composite and process therefor
DE3778091D1 (en) EMULSION POLYMERS REINFORCED WITH RESIN AND METHOD FOR THE PRODUCTION THEREOF.
WO1999000104A3 (en) Aqueous cosmetic compounds
EP0779336A3 (en) A lubricant for a thermoplastic resin
ATE148473T1 (en) RADICAL (CO-)POLYMERIZATION PROCESS OF FLUORINATED OLEFINIC MONOMERS IN AQUEOUS EMULSION
EP0882746A3 (en) Process for producing fluorine-containing acrylic or methacrylic polymers
JPS5536230A (en) Antifouling coating compound
JPS5443284A (en) Dope for forming soft contact lens
EP0843184A3 (en) Ocular lens material
JPS557831A (en) Graft polymerization and polymer composition prepared thereby
EP0838484A4 (en) Functional block copolymer and process for preparing the same

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed