CA2167571A1 - Hydrometallurgical process for the recovery of precious metal values from precious metal ores with thiosulfate lixiviant - Google Patents
Hydrometallurgical process for the recovery of precious metal values from precious metal ores with thiosulfate lixiviantInfo
- Publication number
- CA2167571A1 CA2167571A1 CA002167571A CA2167571A CA2167571A1 CA 2167571 A1 CA2167571 A1 CA 2167571A1 CA 002167571 A CA002167571 A CA 002167571A CA 2167571 A CA2167571 A CA 2167571A CA 2167571 A1 CA2167571 A1 CA 2167571A1
- Authority
- CA
- Canada
- Prior art keywords
- precious metal
- values
- ore
- lixiviant
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
A hydrometallurgical process for the re-covery of precious metal values from refractory precious metal ore materials containing organic carbonaceous matter in which solubilized gold complexes are absorbed by leaching the ore with a thiosulfate lixiviant. A heap (1) of such particulate ore material is contacted with a lix-iviant solution (10) at conditions conductive to the formation of stable precious metal thiosul-fate complexes. Thiosulfate lixiviant is then recovered from the body of the ore particulates after a period of contact sufficient for the lix-iviant solution to become pregnant (20) with precious metal values, which values are then recovered from the lixiviant solution (80).
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/094,791 | 1993-07-28 | ||
US08/094,791 US5354359A (en) | 1992-04-01 | 1993-07-28 | Hydrometallurgical process for the recovery of precious metal values from precious metal ores with thiosulfate lixiviant |
PCT/US1993/008756 WO1995004164A1 (en) | 1993-07-28 | 1993-09-16 | Hydrometallurgical process for the recovery of precious metal values from precious metal ores with thiosulfate lixiviant |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2167571A1 true CA2167571A1 (en) | 1995-02-09 |
CA2167571C CA2167571C (en) | 2003-11-25 |
Family
ID=22247194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002167571A Expired - Lifetime CA2167571C (en) | 1993-07-28 | 1993-09-16 | Hydrometallurgical process for the recovery of precious metal values from precious metal ores with thiosulfate lixiviant |
Country Status (14)
Country | Link |
---|---|
US (1) | US5354359A (en) |
EP (1) | EP0712445A4 (en) |
CN (1) | CN1040029C (en) |
AU (1) | AU685755B2 (en) |
BR (1) | BR9307876A (en) |
CA (1) | CA2167571C (en) |
CO (1) | CO4410259A1 (en) |
CR (1) | CR4903A (en) |
EC (1) | ECSP930984A (en) |
MX (1) | MX9305978A (en) |
RU (1) | RU2125107C1 (en) |
WO (1) | WO1995004164A1 (en) |
ZA (1) | ZA937288B (en) |
ZW (1) | ZW13193A1 (en) |
Families Citing this family (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5431717A (en) * | 1993-12-03 | 1995-07-11 | Geobiotics, Inc. | Method for rendering refractory sulfide ores more susceptible to biooxidation |
US5785736A (en) * | 1995-02-10 | 1998-07-28 | Barrick Gold Corporation | Gold recovery from refractory carbonaceous ores by pressure oxidation, thiosulfate leaching and resin-in-pulp adsorption |
US5536297A (en) * | 1995-02-10 | 1996-07-16 | Barrick Gold Corporation | Gold recovery from refractory carbonaceous ores by pressure oxidation and thiosulfate leaching |
EA000950B1 (en) * | 1996-06-26 | 2000-06-26 | Хенкель Корпорейшн | Process for the recovery of precious metal values from aqueous ammoniacal thiosulfate leach solutions |
US6197214B1 (en) | 1996-06-26 | 2001-03-06 | Henkel Corporation | Ammonium thiosulfate complex of gold or silver and an amine |
US6207443B1 (en) | 1998-03-02 | 2001-03-27 | Placer Dome, Inc. | Method for initiating heap bioleaching of sulfidic ores |
US6251163B1 (en) | 1998-03-04 | 2001-06-26 | Placer Dome, Inc. | Method for recovering gold from refractory carbonaceous ores |
US6368381B1 (en) | 1998-03-11 | 2002-04-09 | Placer Dome Technical Services, Ltd. | Autoclave using agitator and sparge tube to provide high oxygen transfer rate to metal-containing solutions |
US6379919B1 (en) | 1999-05-28 | 2002-04-30 | Oxidor Corporation Inc | Method for isolating thiocyanate resistant bacteria |
US6498031B1 (en) | 1999-05-28 | 2002-12-24 | Oxidor Corporation, Inc. | Column reactor for testing and evaluating refractory ores |
AUPQ456299A0 (en) * | 1999-12-09 | 2000-01-13 | Geo2 Limited | Recovery of precious metals |
US20030154822A1 (en) * | 1999-12-09 | 2003-08-21 | John Hall | Recovery of precious metals |
US6344068B1 (en) | 2000-04-04 | 2002-02-05 | Barrick Gold Corporation | Process for recovering gold from thiosulfate leach solutions and slurries with ion exchange resin |
US6660059B2 (en) * | 2000-05-19 | 2003-12-09 | Placer Dome Technical Services Limited | Method for thiosulfate leaching of precious metal-containing materials |
US6500231B1 (en) | 2001-03-29 | 2002-12-31 | Newmont Usa Limited | Recovery of precious metals from thiosulfate solutions |
US6632264B2 (en) | 2001-04-17 | 2003-10-14 | The University Of British Columbia | Gold recovery from thiosulfate leaching |
AU2007211912B2 (en) * | 2002-11-15 | 2008-01-31 | Placer Dome Technical Services Limited | Method for thiosulfate leaching of precious metal-containing materials |
US7722840B2 (en) * | 2002-11-15 | 2010-05-25 | Placer Dome Technical Services Limited | Method for thiosulfate leaching of precious metal-containing materials |
EP1433860A1 (en) * | 2002-12-23 | 2004-06-30 | Paques B.V. | Process for regenerating thiosulphate from a spent thiosulphate gold leachant |
US20040237721A1 (en) * | 2003-05-29 | 2004-12-02 | Morteza Baghalha | Anoxic leaching of precious metals with thiosulfate and precious metal oxidants |
TW200624151A (en) | 2004-11-12 | 2006-07-16 | Monsanto Technology Llc | Recovery of noble metals from aqueous process streams |
US7604783B2 (en) | 2004-12-22 | 2009-10-20 | Placer Dome Technical Services Limited | Reduction of lime consumption when treating refractor gold ores or concentrates |
US8287050B2 (en) | 2005-07-18 | 2012-10-16 | Osum Oil Sands Corp. | Method of increasing reservoir permeability |
US7572317B2 (en) * | 2005-11-10 | 2009-08-11 | Barrick Gold Corporation | Thiosulfate generation in situ in precious metal recovery |
CN101421426B (en) * | 2006-03-03 | 2015-05-27 | 鑫亚国际有限公司 | Process for extracting gold from gold-bearing ore |
US8061888B2 (en) | 2006-03-17 | 2011-11-22 | Barrick Gold Corporation | Autoclave with underflow dividers |
WO2007112562A1 (en) * | 2006-03-31 | 2007-10-11 | Bioteq Environmental Technologies Inc. | Nickel sulphide precipitation processes |
AU2007236501B2 (en) * | 2006-04-07 | 2013-05-09 | Metal Asia International Ltd. | Precious metal recovery from solution |
CA2649850A1 (en) | 2006-04-21 | 2007-11-01 | Osum Oil Sands Corp. | Method of drilling from a shaft for underground recovery of hydrocarbons |
US8252254B2 (en) | 2006-06-15 | 2012-08-28 | Barrick Gold Corporation | Process for reduced alkali consumption in the recovery of silver |
CA2666506A1 (en) | 2006-10-16 | 2008-04-24 | Osum Oil Sands Corp. | Method of collecting hydrocarbons using a barrier tunnel |
US8313152B2 (en) | 2006-11-22 | 2012-11-20 | Osum Oil Sands Corp. | Recovery of bitumen by hydraulic excavation |
JP4221617B2 (en) * | 2007-05-23 | 2009-02-12 | 北海道特殊飼料株式会社 | Animal and plant residue dry fermented feed, dry fertilizer, etc. |
EA020950B1 (en) | 2007-09-17 | 2015-03-31 | Баррик Гольд Корпорейшн | Method to improve recovery of gold from double refractory gold ores |
CA2698238C (en) | 2007-10-22 | 2014-04-01 | Osum Oil Sands Corp. | Method of removing carbon dioxide emissions from in-situ recovery of bitumen and heavy oil |
CA2713536C (en) | 2008-02-06 | 2013-06-25 | Osum Oil Sands Corp. | Method of controlling a recovery and upgrading operation in a reservoir |
CA2718885C (en) | 2008-05-20 | 2014-05-06 | Osum Oil Sands Corp. | Method of managing carbon reduction for hydrocarbon producers |
EP2649211B1 (en) | 2010-12-07 | 2020-05-13 | Barrick Gold Corporation | Co-current and counter current resin-in-leach in gold leaching processes |
AR086933A1 (en) | 2011-06-15 | 2014-01-29 | Barrick Gold Corp | METHOD FOR RECOVERING PRECIOUS METALS AND COPPER OF LIXIVIATE SOLUTIONS |
US8931642B2 (en) | 2013-01-14 | 2015-01-13 | William D. Simmons | Activated flotation circuit for processing combined oxide and sulfide ores |
CN103194598A (en) * | 2013-04-19 | 2013-07-10 | 贵州东华工程股份有限公司 | Method for improving recovery rate of gold ore difficult to treat by adopting sulfuric acid leaching reduction process |
US10161016B2 (en) * | 2013-05-29 | 2018-12-25 | Barrick Gold Corporation | Method for pre-treatment of gold-bearing oxide ores |
CN103409623A (en) * | 2013-07-26 | 2013-11-27 | 中南大学 | Method for reducing consumption of thiosulfate in gold leaching system |
CN104862494B (en) * | 2015-05-05 | 2017-04-05 | 中南大学 | A kind of technique that gold is soaked in the gold mine from sulfide |
CN105344485B (en) * | 2015-10-16 | 2018-03-02 | 中南大学 | The method for reclaiming gold and its intergrowth from difficult-treating gold mine based on sulphur oil aggregative flotation |
CN105441677A (en) * | 2016-01-13 | 2016-03-30 | 南京信息工程大学 | Method utilizing by-product ammonium thiosulfate for leaching precious metal from flotation concentrate |
CN107400778B (en) * | 2017-08-08 | 2019-01-18 | 中南大学 | A method of desorbing golden thiosulfate anion complex ion from strong-base anion-exchange resin |
CN107488789B (en) * | 2017-08-11 | 2019-01-18 | 中南大学 | A method of the co-desorption gold thiosulfate anion complex ion from strong-base anion-exchange resin |
CN107893160B (en) * | 2017-12-19 | 2019-04-12 | 东北大学 | Thiosulfate and the technique for mentioning gold from difficult-treating gold mine is prepared in situ |
PE20211512A1 (en) | 2019-01-21 | 2021-08-11 | Barrick Gold Corp | METHOD FOR CARBON-CATALYZED THOSULFATE LEACHING OF MATERIALS CONTAINING GOLD |
US20230080921A1 (en) * | 2020-02-07 | 2023-03-16 | University Of Kentucky Research Foundation | Extraction of copper, gold and other elements from waste materials |
CN111549220B (en) * | 2020-04-09 | 2022-02-18 | 中国恩菲工程技术有限公司 | Method for extracting valuable metals from low-grade metal sulfide ores |
EP4200452A1 (en) | 2020-08-18 | 2023-06-28 | Enviro Metals, LLC | Metal refinement |
CN114934176B (en) * | 2022-05-06 | 2023-02-17 | 北京科技大学 | System and method for reinforcing copper sulfide ore biological heap leaching by using intermittent liquid distribution |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1073681A (en) * | 1976-02-20 | 1980-03-18 | Roman M. Genik-Sas-Berezowsky | Recovery of precious metals from metal sulphides |
US4269622A (en) * | 1979-12-28 | 1981-05-26 | Kerley Jr Bernard J | Recovery of precious metals from difficult ores |
US4369061A (en) * | 1979-12-28 | 1983-01-18 | Kerley Jr Bernard J | Recovery of precious metals from difficult ores |
DE3347165A1 (en) * | 1983-12-27 | 1985-07-04 | Skw Trostberg Ag, 8223 Trostberg | METHOD FOR EXTRACTION OF PRECIOUS METALS |
US4654078A (en) * | 1985-07-12 | 1987-03-31 | Perez Ariel E | Method for recovery of precious metals from difficult ores with copper-ammonium thiosulfate |
US4738718A (en) * | 1985-10-28 | 1988-04-19 | Freeport Minerals Company | Method for the recovery of gold using autoclaving |
US4723998A (en) * | 1985-11-29 | 1988-02-09 | Freeport Minerals Co | Recovery of gold from carbonaceous ores by simultaneous chlorine leach and ion exchange resin adsorption process |
US4801329A (en) * | 1987-03-12 | 1989-01-31 | Ensci Incorporated | Metal value recovery from carbonaceous ores |
US4765827A (en) * | 1987-01-20 | 1988-08-23 | Ensci, Inc. | Metal value recovery |
US4778519A (en) * | 1987-02-24 | 1988-10-18 | Batric Pesic | Recovery of precious metals from a thiourea leach |
US4816235A (en) * | 1987-02-24 | 1989-03-28 | Batric Pesic | Silver and manganese recovery using acidified thiourea |
US4923510A (en) * | 1988-10-31 | 1990-05-08 | Gopalan Ramadorai | Treatment of refractory carbonaceous sulfide ores for gold recovery |
US4902345A (en) * | 1989-01-12 | 1990-02-20 | Newmont Gold Co. | Treatment of refractory carbonaceous and sulfidic ores or concentrates for precious metal recovery |
MY105658A (en) * | 1989-03-07 | 1994-11-30 | Butler Dean R | Noble metal recovery |
GB8914037D0 (en) * | 1989-06-19 | 1989-08-09 | Univ Cardiff | Dissolving values of platinum group metals from ores and concentrates |
GB9002311D0 (en) * | 1990-02-02 | 1990-04-04 | Rio Tinto Minerals Dev | Separation process |
US5127942A (en) * | 1990-09-21 | 1992-07-07 | Newmont Mining Corporation | Microbial consortium treatment of refractory precious metal ores |
US5332559A (en) * | 1991-07-10 | 1994-07-26 | Newmont Gold Co. | Biooxidation process for recovery of metal values from sulphur-containing ore materials |
US5236492A (en) * | 1992-07-29 | 1993-08-17 | Fmc Gold Company | Recovery of precious metal values from refractory ores |
-
1993
- 1993-07-28 US US08/094,791 patent/US5354359A/en not_active Expired - Lifetime
- 1993-09-16 EP EP93921627A patent/EP0712445A4/en not_active Withdrawn
- 1993-09-16 CA CA002167571A patent/CA2167571C/en not_active Expired - Lifetime
- 1993-09-16 BR BR9307876A patent/BR9307876A/en not_active IP Right Cessation
- 1993-09-16 WO PCT/US1993/008756 patent/WO1995004164A1/en not_active Application Discontinuation
- 1993-09-16 AU AU49257/93A patent/AU685755B2/en not_active Expired
- 1993-09-16 RU RU96102036/02A patent/RU2125107C1/en not_active IP Right Cessation
- 1993-09-27 EC EC1993000984A patent/ECSP930984A/en unknown
- 1993-09-28 CO CO93410544A patent/CO4410259A1/en unknown
- 1993-09-28 MX MX9305978A patent/MX9305978A/en unknown
- 1993-09-30 ZA ZA937288A patent/ZA937288B/en unknown
- 1993-10-08 ZW ZW13193A patent/ZW13193A1/en unknown
- 1993-10-27 CN CN93119680A patent/CN1040029C/en not_active Expired - Lifetime
-
1994
- 1994-02-10 CR CR4903A patent/CR4903A/en unknown
Also Published As
Publication number | Publication date |
---|---|
CN1098142A (en) | 1995-02-01 |
ZA937288B (en) | 1994-04-25 |
EP0712445A1 (en) | 1996-05-22 |
US5354359A (en) | 1994-10-11 |
CR4903A (en) | 1994-07-27 |
CA2167571C (en) | 2003-11-25 |
CN1040029C (en) | 1998-09-30 |
AU4925793A (en) | 1995-02-28 |
RU2125107C1 (en) | 1999-01-20 |
EP0712445A4 (en) | 1997-01-02 |
ECSP930984A (en) | 1994-06-27 |
BR9307876A (en) | 1996-08-06 |
WO1995004164A1 (en) | 1995-02-09 |
AU685755B2 (en) | 1998-01-29 |
CO4410259A1 (en) | 1997-01-09 |
MX9305978A (en) | 1995-01-31 |
ZW13193A1 (en) | 1994-05-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request |