CA2168614A1 - Removal of carbon dioxide from gas streams - Google Patents
Removal of carbon dioxide from gas streamsInfo
- Publication number
- CA2168614A1 CA2168614A1 CA002168614A CA2168614A CA2168614A1 CA 2168614 A1 CA2168614 A1 CA 2168614A1 CA 002168614 A CA002168614 A CA 002168614A CA 2168614 A CA2168614 A CA 2168614A CA 2168614 A1 CA2168614 A1 CA 2168614A1
- Authority
- CA
- Canada
- Prior art keywords
- adsorption
- carbon dioxide
- clinoptilolite
- air
- gas stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/0476—Vacuum pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/165—Natural alumino-silicates, e.g. zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/104—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/10—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/18—Noble gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/24—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/416—Further details for adsorption processes and devices involving cryogenic temperature treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S95/00—Gas separation: processes
- Y10S95/90—Solid sorbent
- Y10S95/902—Molecular sieve
Abstract
Carbon dioxide is removed from a gas stream by passing the gas stream through a bed of natural or synthetic clinoptilolite or their chemically-modified derivatives. The process is particularly advantageous when applied to the removal of ppm levels of carbon dioxide from gas streams at temperatures above 20°C.
Description
- ~168614 REMOVAL OF CARBON DIOXIDE FROM GAS STREAMS
FIFI n OF THF INVFNTION
This invention relates to the removal of carbon dioxide from gas streams, and more particularly to the prepurification of air by the removal of carbon dioxide from air prior to air separation.
BACKGROUND OF THF INVFNTION
Gases that occur in nature or which are produced in industrial processes often contain carbon dioxide in small amounts. For example atmospheric air generally contains about 300 or more parts per million (ppm) carbon dioxide.
Because of certain process constraints or a particular end use that the gas is 10 intended for, it may sometimes be desirable or necessary to remove the carbondioxide from the gas. For example, air that is separated into various component products by cryogenic distillation (cryogenic air separation) must be substantially free of both carbon dioxide and moisture. Cryogenic air separation is carried out at temperatures well below the freezing point of carbon dioxide and water.
15 Consequently, if these components are not removed prior to cooling of the air they will freeze in and eventually clog the air separation process equipment.
Small amounts of carbon dioxide and moisture are removed from gas streams by various techniques, such as condensation, reversing heat exchange freezing and adsorption. A particularly preferred method is adsorption using an adsorbent which adsorbs carbon dioxide (and water vapor) more strongly than it adsorbs other components of the gas stream. For example, it is common to remove carbon dioxide from an air stream that is to be cryogenically separated, by passing the gas stream through a bed of zeolite 13X. U. S. Patent No. 3,885,927,issued to Sherman et al. on May 27, 1975, discloses the use of type X zeolite containing at least 90 equivalent percent barium cations for the removal of carbon dioxide from gas streams containing not more than 1000 ppm carbon dioxide, at temperatures of -40 to 120F. U. S. Patent No. 4,775,396, issued to Rastelli et al. on October 4, 1988, discloses the adsorption of carbon dioxide from gas streams by pressure swing adsorption at temperatures of -50 to 100C., the adsorbent being a zeolite having a SiO2/AI203 molar ratio of from 2 to 100 and containing at least 20 equivalent percent of one or more cations selected from zinc, rare earth, hydrogen and ammonium cations and not more than 80 equivalent percent of alkali metal or alkaline earth metal cations.
Zeolite 13X efficiently removes small amounts of carbon dioxide (and water vapor) from air streams at low temperatures, i.e. temperatures of about 5C or lower, because it more strongly adsorbs these components than it adsorbs nitrogen, oxygen or argon. However, the carbon dioxide selectivity, and, to a greater extent, the adsorption capacity of zeolite 13X diminish rapidly as the temperature of the gas being separated increases, and the separation process becomes infeasible at temperatures above about 20 C . Since ambient temperatures are often above the preferred 5C adsorption temperature, and since, because of the heat of adsorption, there is a tendency for adsorption bedtemperatures to increase considerably during the course of an adsorption process, it is usually necessary to cool air fed to a adsorption-based air prepurification plant by means of external refrigeration to maintain the gas at temperatures below 20C. This reduces the overall efficiency of the air separation process, since energy must be consumed to provide the necessary refrigeration.
FIFI n OF THF INVFNTION
This invention relates to the removal of carbon dioxide from gas streams, and more particularly to the prepurification of air by the removal of carbon dioxide from air prior to air separation.
BACKGROUND OF THF INVFNTION
Gases that occur in nature or which are produced in industrial processes often contain carbon dioxide in small amounts. For example atmospheric air generally contains about 300 or more parts per million (ppm) carbon dioxide.
Because of certain process constraints or a particular end use that the gas is 10 intended for, it may sometimes be desirable or necessary to remove the carbondioxide from the gas. For example, air that is separated into various component products by cryogenic distillation (cryogenic air separation) must be substantially free of both carbon dioxide and moisture. Cryogenic air separation is carried out at temperatures well below the freezing point of carbon dioxide and water.
15 Consequently, if these components are not removed prior to cooling of the air they will freeze in and eventually clog the air separation process equipment.
Small amounts of carbon dioxide and moisture are removed from gas streams by various techniques, such as condensation, reversing heat exchange freezing and adsorption. A particularly preferred method is adsorption using an adsorbent which adsorbs carbon dioxide (and water vapor) more strongly than it adsorbs other components of the gas stream. For example, it is common to remove carbon dioxide from an air stream that is to be cryogenically separated, by passing the gas stream through a bed of zeolite 13X. U. S. Patent No. 3,885,927,issued to Sherman et al. on May 27, 1975, discloses the use of type X zeolite containing at least 90 equivalent percent barium cations for the removal of carbon dioxide from gas streams containing not more than 1000 ppm carbon dioxide, at temperatures of -40 to 120F. U. S. Patent No. 4,775,396, issued to Rastelli et al. on October 4, 1988, discloses the adsorption of carbon dioxide from gas streams by pressure swing adsorption at temperatures of -50 to 100C., the adsorbent being a zeolite having a SiO2/AI203 molar ratio of from 2 to 100 and containing at least 20 equivalent percent of one or more cations selected from zinc, rare earth, hydrogen and ammonium cations and not more than 80 equivalent percent of alkali metal or alkaline earth metal cations.
Zeolite 13X efficiently removes small amounts of carbon dioxide (and water vapor) from air streams at low temperatures, i.e. temperatures of about 5C or lower, because it more strongly adsorbs these components than it adsorbs nitrogen, oxygen or argon. However, the carbon dioxide selectivity, and, to a greater extent, the adsorption capacity of zeolite 13X diminish rapidly as the temperature of the gas being separated increases, and the separation process becomes infeasible at temperatures above about 20 C . Since ambient temperatures are often above the preferred 5C adsorption temperature, and since, because of the heat of adsorption, there is a tendency for adsorption bedtemperatures to increase considerably during the course of an adsorption process, it is usually necessary to cool air fed to a adsorption-based air prepurification plant by means of external refrigeration to maintain the gas at temperatures below 20C. This reduces the overall efficiency of the air separation process, since energy must be consumed to provide the necessary refrigeration.
2 1 6 ~
It would be very advantageous to completely eliminate the need for refrigeration or to significantly reduce the amount of refrigeration required incommercial air separation adsorption-based prepurification procedures, since that would enhance the overall economic attractiveness of the air separation process.5 The present invention provides a novel carbon dioxide adsorption process whichprovides such an advantage, and eliminates the need for environmentally harmful refrigerants, such as the freons.
SUMMARY OF THF INVFNTION
According to the invention, a gas stream is purified by the removal of 10 carbon dioxide from the gas stream by passing the gas stream through a bed ofclinoptilolite at a temperature in the range of about -50 to about 80.C. The process of the invention can be used to purify any gas that is less strongly adsorbed by clinoptilolite than carbon dioxide and which contains not more than about 1000 parts per million (ppm) levels of carbon dioxide as an impurity. Typical 15 of gases that can be purified by the process of the invention are air, nitrogen, oxygen, argon, methane, etc.
The adsorbent may be natural clinoptilolite, or it may be cation-exchanged with one or more of the various monovalent, divalent or trivalent ions selected from Groups IA, IIA and IIIA of the Periodic Table, lanthanide series ions, chromium 20 (Ill), iron (Ill), zinc (Il) or copper (Il). Preferred adsorbents are clinoptilolite having as exchangeable cations one or more of sodium, potassium, lithium, calcium, magnesium, barium, strontium, aluminum, scandium, gallium, indium, yttrium, lanthanum, cerium, praseodymium and neodymium ions. The most preferred cations are sodium, lithium, calcium, magnesium, aluminum, cerium and lanthanum 25 and mixtures of these.
216861~
The adsorption step of the process of the invention is beneficially carried out at temperatures in the range of about 20 to about 80C. Very good results are obtained when the adsorption step is carried out at a temperature in the range of about 30 to about 60C.
The carbon dioxide purification is preferably carried out by a cyclic process, more preferable as pressure swing adsorption (PSA), temperature swing adsorption(TSA), or combinations of these. In the most preferred embodiment, the process is a TSA process.
The carbon dioxide concentration of gas streams purified by the process of the invention is preferable not more than 600 ppm, and most preferably not more than 350 ppm.
The process of the invention can comprise the single operation of carbon dioxide adsorption, or it may comprise a combination of purification operations,including carbon dioxide adsorption and one or more of air separation, hydrogen oxidation, carbon monoxide oxidation, etc. In a preferred procedure carbon dioxide is removed from air by the above-described adsorption method and the purified air is separated by cryogenic distillation into nitrogen, oxygen, argon or combinations of two or more of these.
The carbon dioxide adsorption step with the clinoptilolite adsorbent can also be used to remove moisture from the gas stream, if present. In a preferred embodiment, moisture is removed prior to carbon dioxide adsorption by, for example, passing the gas stream through a desiccant, preferably alumina, silica gel or mixtures of these.
DFTAII FD DFSCRIPTION OF THF INVFNTION
The process of the invention is particularly useful for removing carbon dioxide at low concentrations i.e. parts per million (ppm) levels, from gas streams -- ~168619 at temperatures above about 20C. Although the process can be successfully used to remove carbon dioxide from gas streams which contain the carbon dioxide at concentrations greater than 1000 ppm, it is most effective for removing carbon dioxide from a gas stream when the carbon dioxide is present in the gas stream 5 at concentrations up to about 1000 parts per million (ppm).
The adsorbents useful in the process of the invention are the natural and synthetic clinoptilolites and their chemically modified derivatives. Natural clinoptilolite generally has as exchangeable cations one or more of potassium ions, sodium ions, calcium ions and magnesium ions. Cation-exchanged natural or 10 synthetic clinoptilolite may also be used in the invention. Included among the ions that may occupy exchangeable cation sites on the clinoptilolite adsorbent are ions of Groups IA, IIA, IIIA, IIIB of the periodic table, trivalent ions of the lanthanide series of elements, zinc (Il) ion, copper (Il) ion, chromium (Ill) ion, iron (Ill) ion, the ammonium ion, the hydronium ion or mixtures of two or more ions from any of 15 these categories. Preferred Group IA ions are sodium, potassium and lithium ions;
preferred Group IIA ions are magnesium, calcium, strontium and barium ions;
preferred Group IIIA and IIIB ions are aluminum, scandium, gallium, indium and yttrium; and preferred trivalent lanthanide ions are lanthanum, cerium, praseodymium and neodymium. The most preferred clinoptilolites are the natural 20 and synthetic clinoptilolites having as exchangeable cations one or more ionsselected from: sodium, potassium, lithium, calcium, magnesium and barium ions.
The process of the invention may be carried out in a single adsorption vessel or a battery of two or more beds arranged in parallel and adapted to be operatedin a cyclic process comprising adsorption and desorption. In such systems the 25 beds are cycled out of phase to assure a pseudo-continuous flow of purified gas from the adsorption system.
The process of the invention is generally practiced as a cyclical process, such as temperature swing adsorption, pressure swing adsorption, vacuum swing adsorption, or combinations of these. The process is particularly useful for removing small amounts of carbon dioxide from air by temperature swing adsorption. The carbon dioxide removal process is ideally coupled with an air separation process, such as cryogenic distillation of air, to produce high purity nitrogen, oxygen, argon or combinations of two or more of these high purity gas products.
The temperature at which the adsorption step is carried out may vary from a minimum temperature of about -50C to a maximum of about 80C. It has been discovered that the efficiency of the adsorption process does not drop off with increasing adsorption temperature, as rapidly as when conventional adsorbents are used in the process. This feature makes the process advantageous for use in warmweather climates where the temperature during the adsorption step is above about20C, or even above about 40C. Although the adsorption process can be carried out at temperatures up to about 80C, it is preferable that the temperature not exceed about 60C and most preferable that it not exceed about 50C.
The absolute pressures at which the adsorption step is carried out generally ranges from about 0.2 to about 20 bar, and preferably ranges from about 1 to 10 bar When the adsorption process is PSA the regeneration step is generally carried out a temperature in the neighborhood of the temperature at which the adsorption step is carried out and at an absolute pressure lower than the adsorption pressure. The pressure during the regeneration step of PSA cycles is usually in the range of about 200 to about 5000 millibar, and preferably in the 8 range of about 100 to about 2000 millibar. When the adsorption process is TSA, bed regeneration is carried out at a temperature higher than the adsorption temperature, usually in the range of about 50 to about 250 C, and preferably in the range of about 100 to 200 C. In the TSA embodiment, the pressure can be the same during the adsorption and regeneration steps, but it is often preferred to desorb to about atmospheric pressure. When a combination PSA/TSA process is employed, the temperature and pressure during the bed regeneration step are 5 higher and lower, respectively, than they are during the adsorption step.
In starting a cyclical process according to the invention, the gaseous feed stream from which carbon dioxide is to be removed is introduced into an adsorption vessel containing a bed of the above-mentioned adsorbent. As the gas passes through the bed of adsorbent carbon dioxide is adsorbed and a substantially 10 carbon dioxide-free nonadsorbed product gas passes out of the adsorption vessel through the nonadsorbed gas outlet. As the adsorption step proceeds, a carbon dioxide front forms in the adsorbent bed and slowly moves toward the nonadsorbed gas outlet end of the bed. When the adsorbed carbon dioxide front traveling through the adsorption vessel(s) in which the adsorption step is being15 carried out reaches the desired point in the vessel(s), the adsorption process in these vessel(s) is terminated and these vessel(s) enter the regeneration mode.
During regeneration, the carbon dioxide-loaded vessels are depressurized, if theadsorption cycle is pressure swing adsorption; heated, if a temperature swing adsorption cycle is employed; or both depressurized and heated, if a combination20 pressure swing-temperature swing process is used.
The method of regeneration of the adsorption beds depends upon the type of adsorption process employed. In the case of pressure swing adsorption, the regeneration phase generally includes a countercurrent depressurization step during which the beds are vented countercurrently until they attain the desired lower 25 pressure. If desired the pressure in the beds may be reduced to subatmospheric pressure by means of a vacuum inducing device, such as a vacuum pump.
In some cases, in addition to the countercurrent depressurization step(s), it may be desirable to countercurrently purge the bed with the nonadsorbed product - 21~614 gas stream exiting the adsorbent bed(s). In this case the bed(s) may be countercurrently purged with nonadsorbed gas, and the purge step is usually initiated towards the end of the countercurrent depressurization step, or subsequent thereto. During this purge step, the purge gas can be introduced into5 the adsorbent bed from an intermediate storage facility when the adsorption system comprises a single adsorber; or from another adsorber that is in the adsorption phase, when the adsorption system comprises multiple adsorbers arranged in parallel and operated out of phase.
The adsorption cycle may contain steps other than the fundamental steps 10 of adsorption and regeneration. For example, it may be advantageous to depressurize the adsorption bed in multiple steps, with the first depressurization product being used to partially pressurize another bed in the adsorption system.This will further reduce the amount of gaseous impurities in the nonadsorbed product gas.
According to a preferred embodiment of the invention, a gas stream, such as air, is introduced into an adsorption vessel containing a clinoptilolite of the type described above. The gas stream may be at a temperature as low as -50C, or less, or as high as 80C. Provided that the concentration of carbon dioxide in the gas stream is not significantly greater than about 1000 ppm, substantially all of 20 the carbon dioxide will be removed from the gas stream, and the substantiallycarbon dioxide-free product gas will issue from the nonadsorbed product gas outlet of the adsorption vessel. When the carbon dioxide adsorption front reaches a predetermined point in the adsorption vessel, usually near the nonadsorbed product gas outlet, the adsorption process in the vessel is terminated, and the adsorbent 25 bed contained in the vessel is regenerated in one of the methods described above.
If the adsorption plant is a multiple bed system, adsorption will immediately begin in a second bed, so that the continuity of the purification process will not be interrupted. The prepurified gas can be subjected to further processing. For example, in cryogenic air separation operations, the prepurified air is sent to a - 2~6861~
cryogenic distillation (or adsorption) plant for fractionation into one or more high purity gases. If desired, a waste gas stream from the air separation plant can be recycled to the prepurification plant for use a purge gas during bed regeneration.
It will be appreciated that it is within the scope of the present invention to 5 utilize conventional equipment to monitor and automatically regulate the flow of gases within the system so that it can be fully automated to run continuously inan efficient manner.
The invention is further illustrated by the following example in which, unless otherwise indicated, parts, percentages and ratios are on a volume basis.
FXAM Pl F
Equilibrium adsorption isotherms for carbon dioxide were measured using a Cahn microbalance at a series of pressures in the range of 2 to 300 mbar at temperatures of 5C, 35C and 50C for a conventional sodium X zeolite (NaX) having silicon-to-aluminum atomic ratio of 1.25, and for an Indonesian natural 15 clinoptilolite which was first beneficiated by washing with hot water, and then extensively ion-exchanged with calcium chloride solution of 80C. Chemical analysis of the clinoptilolite sample (Indonesian natural clinoptilolite) showed its weight percentage composition to be: 64.7% SiO2; 13.8% Al2O3; 3.9% CaO;
2.5% K2O; 1.0% Fe2O3; 0.8% MgO; 0.26% TiO2; 0.23% Na2O; and 0.01 % MnO.
20 Each sample of adsorbent (about 60 mg) was activated by being evacuated at 350C for 1.5 hours in situ in the Cahn microbalance before the first run and between the isotherms taken at each temperature. Each test was conducted until equilibrium was achieved, which required up to 3 hours for the lowest partial pressures of carbon dioxide. The results of the experiments are recorded in the 25 table.
2168~1~
Pressure., mbar 2 5 10 50 100 300 Adsorbent Temp., C Carbon Dioxide Uptake, mmol/gm of adsorbent NaX 5 1.24 1.80 2.23 3.53 4.11 4.79 Ca Clino.1 5 1.13 1.31 1.46 1.89 2.04 2.18 NaX 35 0.45 0.87 1.26 2.26 2.78 3.73 Ca Clino. 35 0.81 1.04 1.17 1.47 1.65 1.93 NaX 50 0.25 0.55 0.87 1.83 2.27 3.14 Ca Clino. 50 0.64 0.91 1.07 1.34 1.48 1.76 1 calcium clinoptilolite From the table it is clear that at moderately high C2 partial pressures (e.g.
300 mbar) the calcium clinoptilolite used in this example has a much lower C02 capacity than does conventional sodium X adsorbent. The unexpected nature of this invention is exemplified in the results obtained at less than or equal to 5 mbar of C2 ~ which is typical of air at a pressure of about 15 atmospheres, and at a15 temperature greater than 20C. The capacities of the adsorbents of this invention are more than 20% greater, and in some cases more than twice those of the conventional type X adsorbent under the same conditions.
Although the invention has been described with particular reference to specific equipment arrangements, to specific adsorption cycles, and to specific 20 experiments, these features are merely exemplary of the invention and variations are contemplated. For example, the adsorption cycle may include more than two bed equalization steps, and the purge step and/or the nonadsorbed product backfill step may be included or eliminated, as desired. Furthermore, the duration of the 2i~8614 individual steps and the operating conditions may be varied. The scope of the invention is limited only by the breadth of the appended claims.
It would be very advantageous to completely eliminate the need for refrigeration or to significantly reduce the amount of refrigeration required incommercial air separation adsorption-based prepurification procedures, since that would enhance the overall economic attractiveness of the air separation process.5 The present invention provides a novel carbon dioxide adsorption process whichprovides such an advantage, and eliminates the need for environmentally harmful refrigerants, such as the freons.
SUMMARY OF THF INVFNTION
According to the invention, a gas stream is purified by the removal of 10 carbon dioxide from the gas stream by passing the gas stream through a bed ofclinoptilolite at a temperature in the range of about -50 to about 80.C. The process of the invention can be used to purify any gas that is less strongly adsorbed by clinoptilolite than carbon dioxide and which contains not more than about 1000 parts per million (ppm) levels of carbon dioxide as an impurity. Typical 15 of gases that can be purified by the process of the invention are air, nitrogen, oxygen, argon, methane, etc.
The adsorbent may be natural clinoptilolite, or it may be cation-exchanged with one or more of the various monovalent, divalent or trivalent ions selected from Groups IA, IIA and IIIA of the Periodic Table, lanthanide series ions, chromium 20 (Ill), iron (Ill), zinc (Il) or copper (Il). Preferred adsorbents are clinoptilolite having as exchangeable cations one or more of sodium, potassium, lithium, calcium, magnesium, barium, strontium, aluminum, scandium, gallium, indium, yttrium, lanthanum, cerium, praseodymium and neodymium ions. The most preferred cations are sodium, lithium, calcium, magnesium, aluminum, cerium and lanthanum 25 and mixtures of these.
216861~
The adsorption step of the process of the invention is beneficially carried out at temperatures in the range of about 20 to about 80C. Very good results are obtained when the adsorption step is carried out at a temperature in the range of about 30 to about 60C.
The carbon dioxide purification is preferably carried out by a cyclic process, more preferable as pressure swing adsorption (PSA), temperature swing adsorption(TSA), or combinations of these. In the most preferred embodiment, the process is a TSA process.
The carbon dioxide concentration of gas streams purified by the process of the invention is preferable not more than 600 ppm, and most preferably not more than 350 ppm.
The process of the invention can comprise the single operation of carbon dioxide adsorption, or it may comprise a combination of purification operations,including carbon dioxide adsorption and one or more of air separation, hydrogen oxidation, carbon monoxide oxidation, etc. In a preferred procedure carbon dioxide is removed from air by the above-described adsorption method and the purified air is separated by cryogenic distillation into nitrogen, oxygen, argon or combinations of two or more of these.
The carbon dioxide adsorption step with the clinoptilolite adsorbent can also be used to remove moisture from the gas stream, if present. In a preferred embodiment, moisture is removed prior to carbon dioxide adsorption by, for example, passing the gas stream through a desiccant, preferably alumina, silica gel or mixtures of these.
DFTAII FD DFSCRIPTION OF THF INVFNTION
The process of the invention is particularly useful for removing carbon dioxide at low concentrations i.e. parts per million (ppm) levels, from gas streams -- ~168619 at temperatures above about 20C. Although the process can be successfully used to remove carbon dioxide from gas streams which contain the carbon dioxide at concentrations greater than 1000 ppm, it is most effective for removing carbon dioxide from a gas stream when the carbon dioxide is present in the gas stream 5 at concentrations up to about 1000 parts per million (ppm).
The adsorbents useful in the process of the invention are the natural and synthetic clinoptilolites and their chemically modified derivatives. Natural clinoptilolite generally has as exchangeable cations one or more of potassium ions, sodium ions, calcium ions and magnesium ions. Cation-exchanged natural or 10 synthetic clinoptilolite may also be used in the invention. Included among the ions that may occupy exchangeable cation sites on the clinoptilolite adsorbent are ions of Groups IA, IIA, IIIA, IIIB of the periodic table, trivalent ions of the lanthanide series of elements, zinc (Il) ion, copper (Il) ion, chromium (Ill) ion, iron (Ill) ion, the ammonium ion, the hydronium ion or mixtures of two or more ions from any of 15 these categories. Preferred Group IA ions are sodium, potassium and lithium ions;
preferred Group IIA ions are magnesium, calcium, strontium and barium ions;
preferred Group IIIA and IIIB ions are aluminum, scandium, gallium, indium and yttrium; and preferred trivalent lanthanide ions are lanthanum, cerium, praseodymium and neodymium. The most preferred clinoptilolites are the natural 20 and synthetic clinoptilolites having as exchangeable cations one or more ionsselected from: sodium, potassium, lithium, calcium, magnesium and barium ions.
The process of the invention may be carried out in a single adsorption vessel or a battery of two or more beds arranged in parallel and adapted to be operatedin a cyclic process comprising adsorption and desorption. In such systems the 25 beds are cycled out of phase to assure a pseudo-continuous flow of purified gas from the adsorption system.
The process of the invention is generally practiced as a cyclical process, such as temperature swing adsorption, pressure swing adsorption, vacuum swing adsorption, or combinations of these. The process is particularly useful for removing small amounts of carbon dioxide from air by temperature swing adsorption. The carbon dioxide removal process is ideally coupled with an air separation process, such as cryogenic distillation of air, to produce high purity nitrogen, oxygen, argon or combinations of two or more of these high purity gas products.
The temperature at which the adsorption step is carried out may vary from a minimum temperature of about -50C to a maximum of about 80C. It has been discovered that the efficiency of the adsorption process does not drop off with increasing adsorption temperature, as rapidly as when conventional adsorbents are used in the process. This feature makes the process advantageous for use in warmweather climates where the temperature during the adsorption step is above about20C, or even above about 40C. Although the adsorption process can be carried out at temperatures up to about 80C, it is preferable that the temperature not exceed about 60C and most preferable that it not exceed about 50C.
The absolute pressures at which the adsorption step is carried out generally ranges from about 0.2 to about 20 bar, and preferably ranges from about 1 to 10 bar When the adsorption process is PSA the regeneration step is generally carried out a temperature in the neighborhood of the temperature at which the adsorption step is carried out and at an absolute pressure lower than the adsorption pressure. The pressure during the regeneration step of PSA cycles is usually in the range of about 200 to about 5000 millibar, and preferably in the 8 range of about 100 to about 2000 millibar. When the adsorption process is TSA, bed regeneration is carried out at a temperature higher than the adsorption temperature, usually in the range of about 50 to about 250 C, and preferably in the range of about 100 to 200 C. In the TSA embodiment, the pressure can be the same during the adsorption and regeneration steps, but it is often preferred to desorb to about atmospheric pressure. When a combination PSA/TSA process is employed, the temperature and pressure during the bed regeneration step are 5 higher and lower, respectively, than they are during the adsorption step.
In starting a cyclical process according to the invention, the gaseous feed stream from which carbon dioxide is to be removed is introduced into an adsorption vessel containing a bed of the above-mentioned adsorbent. As the gas passes through the bed of adsorbent carbon dioxide is adsorbed and a substantially 10 carbon dioxide-free nonadsorbed product gas passes out of the adsorption vessel through the nonadsorbed gas outlet. As the adsorption step proceeds, a carbon dioxide front forms in the adsorbent bed and slowly moves toward the nonadsorbed gas outlet end of the bed. When the adsorbed carbon dioxide front traveling through the adsorption vessel(s) in which the adsorption step is being15 carried out reaches the desired point in the vessel(s), the adsorption process in these vessel(s) is terminated and these vessel(s) enter the regeneration mode.
During regeneration, the carbon dioxide-loaded vessels are depressurized, if theadsorption cycle is pressure swing adsorption; heated, if a temperature swing adsorption cycle is employed; or both depressurized and heated, if a combination20 pressure swing-temperature swing process is used.
The method of regeneration of the adsorption beds depends upon the type of adsorption process employed. In the case of pressure swing adsorption, the regeneration phase generally includes a countercurrent depressurization step during which the beds are vented countercurrently until they attain the desired lower 25 pressure. If desired the pressure in the beds may be reduced to subatmospheric pressure by means of a vacuum inducing device, such as a vacuum pump.
In some cases, in addition to the countercurrent depressurization step(s), it may be desirable to countercurrently purge the bed with the nonadsorbed product - 21~614 gas stream exiting the adsorbent bed(s). In this case the bed(s) may be countercurrently purged with nonadsorbed gas, and the purge step is usually initiated towards the end of the countercurrent depressurization step, or subsequent thereto. During this purge step, the purge gas can be introduced into5 the adsorbent bed from an intermediate storage facility when the adsorption system comprises a single adsorber; or from another adsorber that is in the adsorption phase, when the adsorption system comprises multiple adsorbers arranged in parallel and operated out of phase.
The adsorption cycle may contain steps other than the fundamental steps 10 of adsorption and regeneration. For example, it may be advantageous to depressurize the adsorption bed in multiple steps, with the first depressurization product being used to partially pressurize another bed in the adsorption system.This will further reduce the amount of gaseous impurities in the nonadsorbed product gas.
According to a preferred embodiment of the invention, a gas stream, such as air, is introduced into an adsorption vessel containing a clinoptilolite of the type described above. The gas stream may be at a temperature as low as -50C, or less, or as high as 80C. Provided that the concentration of carbon dioxide in the gas stream is not significantly greater than about 1000 ppm, substantially all of 20 the carbon dioxide will be removed from the gas stream, and the substantiallycarbon dioxide-free product gas will issue from the nonadsorbed product gas outlet of the adsorption vessel. When the carbon dioxide adsorption front reaches a predetermined point in the adsorption vessel, usually near the nonadsorbed product gas outlet, the adsorption process in the vessel is terminated, and the adsorbent 25 bed contained in the vessel is regenerated in one of the methods described above.
If the adsorption plant is a multiple bed system, adsorption will immediately begin in a second bed, so that the continuity of the purification process will not be interrupted. The prepurified gas can be subjected to further processing. For example, in cryogenic air separation operations, the prepurified air is sent to a - 2~6861~
cryogenic distillation (or adsorption) plant for fractionation into one or more high purity gases. If desired, a waste gas stream from the air separation plant can be recycled to the prepurification plant for use a purge gas during bed regeneration.
It will be appreciated that it is within the scope of the present invention to 5 utilize conventional equipment to monitor and automatically regulate the flow of gases within the system so that it can be fully automated to run continuously inan efficient manner.
The invention is further illustrated by the following example in which, unless otherwise indicated, parts, percentages and ratios are on a volume basis.
FXAM Pl F
Equilibrium adsorption isotherms for carbon dioxide were measured using a Cahn microbalance at a series of pressures in the range of 2 to 300 mbar at temperatures of 5C, 35C and 50C for a conventional sodium X zeolite (NaX) having silicon-to-aluminum atomic ratio of 1.25, and for an Indonesian natural 15 clinoptilolite which was first beneficiated by washing with hot water, and then extensively ion-exchanged with calcium chloride solution of 80C. Chemical analysis of the clinoptilolite sample (Indonesian natural clinoptilolite) showed its weight percentage composition to be: 64.7% SiO2; 13.8% Al2O3; 3.9% CaO;
2.5% K2O; 1.0% Fe2O3; 0.8% MgO; 0.26% TiO2; 0.23% Na2O; and 0.01 % MnO.
20 Each sample of adsorbent (about 60 mg) was activated by being evacuated at 350C for 1.5 hours in situ in the Cahn microbalance before the first run and between the isotherms taken at each temperature. Each test was conducted until equilibrium was achieved, which required up to 3 hours for the lowest partial pressures of carbon dioxide. The results of the experiments are recorded in the 25 table.
2168~1~
Pressure., mbar 2 5 10 50 100 300 Adsorbent Temp., C Carbon Dioxide Uptake, mmol/gm of adsorbent NaX 5 1.24 1.80 2.23 3.53 4.11 4.79 Ca Clino.1 5 1.13 1.31 1.46 1.89 2.04 2.18 NaX 35 0.45 0.87 1.26 2.26 2.78 3.73 Ca Clino. 35 0.81 1.04 1.17 1.47 1.65 1.93 NaX 50 0.25 0.55 0.87 1.83 2.27 3.14 Ca Clino. 50 0.64 0.91 1.07 1.34 1.48 1.76 1 calcium clinoptilolite From the table it is clear that at moderately high C2 partial pressures (e.g.
300 mbar) the calcium clinoptilolite used in this example has a much lower C02 capacity than does conventional sodium X adsorbent. The unexpected nature of this invention is exemplified in the results obtained at less than or equal to 5 mbar of C2 ~ which is typical of air at a pressure of about 15 atmospheres, and at a15 temperature greater than 20C. The capacities of the adsorbents of this invention are more than 20% greater, and in some cases more than twice those of the conventional type X adsorbent under the same conditions.
Although the invention has been described with particular reference to specific equipment arrangements, to specific adsorption cycles, and to specific 20 experiments, these features are merely exemplary of the invention and variations are contemplated. For example, the adsorption cycle may include more than two bed equalization steps, and the purge step and/or the nonadsorbed product backfill step may be included or eliminated, as desired. Furthermore, the duration of the 2i~8614 individual steps and the operating conditions may be varied. The scope of the invention is limited only by the breadth of the appended claims.
Claims (17)
1. A method of removing carbon dioxide from a gas stream which contains carbon dioxide as an impurity, comprising subjecting said gas stream to adsorption using clinoptilolite at a temperature in the range of about -20 to about 80°C.
2. The method of claim 1, wherein the adsorption is part of a process selected from temperature swing adsorption, pressure swing adsorption, vacuum swing adsorption and combinations of these.
3. The method of claim 2, wherein said adsorbent is clinoptilolite whose exchangeable cations are selected from ions of Group 1A, Group 2A, Group 3A, Group 3B, the lanthanide series and mixtures of these.
4. The method of claim 2, wherein said adsorption step is carried out at a temperature in the range of about 20 to about 80°C.
5. The method of any one of claims 1, 2 or 4, wherein said adsorbent is selected from natural clinoptilolite, synthetic clinoptilolite, sodium-exchangedclinoptilolite, potassium-exchanged clinoptilolite, lithium-exchanged clinoptilolite, calcium-exchanged clinoptilolite magnesium-exchanged clinoptilolite, barium-exchanged clinoptilolite, and mixtures of these.
6. The method of any one of claims 1, 2 or 4, wherein the concentration of carbon dioxide in said gas stream is not greater than about 1000 ppm.
7. The method of any one of claims 1, 2 or 4, wherein said gas stream is oxygen, nitrogen, argon or mixtures of these.
8. The method of claim 7, wherein the adsorption step of said process is carried out at a temperature in the range of about 30 to about 60°C.
9. The method of claim 8, wherein said gas stream is air.
10. The method of claim 7, additionally comprising, prior to removing carbon dioxide from said gas stream, removing water vapor from the gas stream by passing the gas stream through an adsorbent selected from alumina, silica gel, and mixtures of these.
11. A method of separating air comprising the steps:
(a) prepurifying air by subjecting the air to a temperature swing adsorption process using clinoptilolite as adsorbent, thereby adsorbing carbon dioxide from the air; and (b) subjecting the prepurified air to cryogenic distillation, thereby producing high purity nitrogen, high purity oxygen or both of these.
(a) prepurifying air by subjecting the air to a temperature swing adsorption process using clinoptilolite as adsorbent, thereby adsorbing carbon dioxide from the air; and (b) subjecting the prepurified air to cryogenic distillation, thereby producing high purity nitrogen, high purity oxygen or both of these.
12. The method of claim 11, wherein said adsorbent additionally adsorbs water vapor from said air.
13. The method of claim 11, additionally comprising, prior to step (a), the stepof removing water vapor from the air by passing the air through an adsorbent selected from alumina, silica gel and mixtures of these.
14. The method of claim 1 1, wherein the adsorption phase of step (a) is carriedout at a temperature in the range of about 20 to about 80°C.
15. The method of claim 1 1, wherein the concentration of carbon dioxide in saidair is not greater than about 500 ppm.
16. The method of claim 11, wherein said adsorbent is selected from natural clinoptilolite, lithium-exchanged clinoptilolite, calcium-exchanged clinoptilolite and mixtures of these.
17. The method of claim 16, wherein the adsorption phase of step (a) is carried out at a temperature in the range of about 30 to about 60°C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US407,817 | 1995-03-21 | ||
US08/407,817 US5587003A (en) | 1995-03-21 | 1995-03-21 | Removal of carbon dioxide from gas streams |
Publications (1)
Publication Number | Publication Date |
---|---|
CA2168614A1 true CA2168614A1 (en) | 1996-09-22 |
Family
ID=23613632
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002168614A Abandoned CA2168614A1 (en) | 1995-03-21 | 1996-02-01 | Removal of carbon dioxide from gas streams |
Country Status (13)
Country | Link |
---|---|
US (1) | US5587003A (en) |
EP (1) | EP0733393A1 (en) |
JP (1) | JPH08266844A (en) |
KR (1) | KR960033518A (en) |
CN (1) | CN1137418A (en) |
AU (1) | AU4804196A (en) |
CA (1) | CA2168614A1 (en) |
NZ (1) | NZ280939A (en) |
PL (1) | PL313373A1 (en) |
SG (1) | SG44733A1 (en) |
TR (1) | TR199600881A2 (en) |
TW (1) | TW592788B (en) |
ZA (1) | ZA962222B (en) |
Families Citing this family (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2296712B (en) * | 1995-01-05 | 1999-02-24 | British Gas Plc | Absorbents for separating nitrogen from a feed gas |
US5938819A (en) * | 1997-06-25 | 1999-08-17 | Gas Separation Technology Llc | Bulk separation of carbon dioxide from methane using natural clinoptilolite |
US5980611A (en) * | 1997-09-25 | 1999-11-09 | The Boc Group, Inc. | Air purification process |
US6238460B1 (en) | 1997-09-26 | 2001-05-29 | The Boc Group, Inc. | Air purification process |
FR2773499B1 (en) * | 1998-01-14 | 2000-02-11 | Air Liquide | AIR PURIFICATION PROCESS BEFORE CRYOGENIC DISTILLATION |
CA2264418C (en) * | 1998-03-12 | 2002-05-14 | Adeola Florence Ojo | Removal of carbon dioxide from gas streams |
US6183539B1 (en) | 1998-07-01 | 2001-02-06 | Zeochem Co. | Molecular sieve adsorbent for gas purification and preparation thereof |
FR2790823B1 (en) * | 1999-03-12 | 2001-06-15 | Air Liquide | PROCESS AND INSTALLATION FOR AIR PURIFICATION AND SEPARATION BY CRYOGENIC ROUTE WITHOUT PRECOOLING |
EP1142622B1 (en) * | 2000-04-04 | 2006-06-21 | Tosoh Corporation | Method of adsorptive separation of carbon dioxide |
US8124036B1 (en) | 2005-10-27 | 2012-02-28 | ADA-ES, Inc. | Additives for mercury oxidation in coal-fired power plants |
ES2717932T3 (en) * | 2001-01-05 | 2019-06-26 | Air Prod & Chem | Apparatus for manufacturing coating compositions, laminates and adsorption elements |
EP1249264A1 (en) * | 2001-04-11 | 2002-10-16 | Ammonia Casale S.A. | Process for the separation and recovery of carbon dioxide from waste gas or fumes produced by combustible oxidation |
FR2832077B1 (en) * | 2001-11-12 | 2004-08-27 | Air Liquide | ZEOLITIC BARYUM AND CALCIUM ADSORBENT FOR THE PURIFICATION OF GAS, PARTICULARLY AIR |
CN1309454C (en) * | 2001-12-20 | 2007-04-11 | 普莱克斯技术有限公司 | Method and apparatus for gas purification |
AU2003239922A1 (en) * | 2002-05-31 | 2003-12-19 | Praxair Technology, Inc. | Production of high purity and ultra-high purity gas |
US6942719B2 (en) * | 2003-06-30 | 2005-09-13 | The Boeing Company | Methods and systems for pressure swing regeneration for hydrogen generation |
US6962617B2 (en) * | 2003-07-03 | 2005-11-08 | Lehigh University | Method of removing mercury from exhaust gases |
US20050137443A1 (en) * | 2003-12-19 | 2005-06-23 | Gorawara Jayant K. | Regenerative removal of trace carbon monoxide |
FR2868338B1 (en) * | 2004-03-31 | 2007-02-02 | Ceca Sa Sa | ADSORBENT ZEOLITIC COMPOSITION, PROCESS FOR THE PREPARATION AND USE THEREOF FOR THE REMOVAL OF H20 AND / OR H2S FROM GASEOUS OR LIQUID MIXTURES |
CA2848601C (en) | 2004-06-28 | 2018-10-30 | Nox Ii, Ltd. | Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels |
CA2601239C (en) | 2005-03-17 | 2013-07-16 | Nox Ii, Ltd. | Reducing mercury emissions from the burning of coal |
ES2698259T5 (en) | 2005-03-17 | 2022-06-21 | Nox Ii Int Ltd | Reduction of mercury emissions from coal combustion |
US8150776B2 (en) | 2006-01-18 | 2012-04-03 | Nox Ii, Ltd. | Methods of operating a coal burning facility |
FR2931699B1 (en) * | 2008-05-28 | 2011-02-11 | Rhodia Operations | PROCESS FOR TREATING GAS TO DECREASE CARBON DIOXIDE CONTENT |
CA2657127C (en) | 2009-03-05 | 2016-07-05 | The Governors Of The University Of Alberta | Removal of carbon dioxide from paraffins |
US8951487B2 (en) | 2010-10-25 | 2015-02-10 | ADA-ES, Inc. | Hot-side method and system |
US8524179B2 (en) | 2010-10-25 | 2013-09-03 | ADA-ES, Inc. | Hot-side method and system |
US8496894B2 (en) | 2010-02-04 | 2013-07-30 | ADA-ES, Inc. | Method and system for controlling mercury emissions from coal-fired thermal processes |
US8372362B2 (en) | 2010-02-04 | 2013-02-12 | ADA-ES, Inc. | Method and system for controlling mercury emissions from coal-fired thermal processes |
US11298657B2 (en) | 2010-10-25 | 2022-04-12 | ADA-ES, Inc. | Hot-side method and system |
CA2792732C (en) | 2010-03-10 | 2018-07-31 | Martin A. Dillon | Process for dilute phase injection of dry alkaline materials |
US8784757B2 (en) | 2010-03-10 | 2014-07-22 | ADA-ES, Inc. | Air treatment process for dilute phase injection of dry alkaline materials |
FR2970184B1 (en) | 2011-01-07 | 2013-08-02 | Air Liquide | ZEOLITIC COMPOSITION SUITABLE FOR AIR CLEANING |
US8845986B2 (en) | 2011-05-13 | 2014-09-30 | ADA-ES, Inc. | Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers |
WO2013004932A1 (en) | 2011-07-07 | 2013-01-10 | L'air Liquide,Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for purifying a gas stream with control of the purity |
US9017452B2 (en) | 2011-11-14 | 2015-04-28 | ADA-ES, Inc. | System and method for dense phase sorbent injection |
CN103998376B (en) * | 2011-12-20 | 2016-02-10 | 东曹株式会社 | Strontium exchanges clinoptilolite |
US8883099B2 (en) | 2012-04-11 | 2014-11-11 | ADA-ES, Inc. | Control of wet scrubber oxidation inhibitor and byproduct recovery |
US9411321B2 (en) * | 2012-06-20 | 2016-08-09 | Fisher Controls International Llc | Methods and system for minor loop feedback fallback |
US8974756B2 (en) | 2012-07-25 | 2015-03-10 | ADA-ES, Inc. | Process to enhance mixing of dry sorbents and flue gas for air pollution control |
US9957454B2 (en) | 2012-08-10 | 2018-05-01 | ADA-ES, Inc. | Method and additive for controlling nitrogen oxide emissions |
US10350545B2 (en) | 2014-11-25 | 2019-07-16 | ADA-ES, Inc. | Low pressure drop static mixing system |
US10895417B2 (en) | 2016-03-25 | 2021-01-19 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method for the production of air gases by the cryogenic separation of air with improved front end purification and air compression |
EP3630338A4 (en) | 2017-05-24 | 2021-03-03 | BASF Corporation | Gas dehydration with mixed adsorbent/desiccant beds |
CN109012572A (en) * | 2018-08-03 | 2018-12-18 | 中国地质大学(武汉) | A kind of coal bed gas/shale gas enrichment preparation method of adsorbent material |
US11029086B2 (en) | 2018-12-21 | 2021-06-08 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and apparatus for reducing process disturbances during pressurization of an adsorber in an air separation unit |
US11137205B2 (en) | 2018-12-21 | 2021-10-05 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and apparatus for eliminating heat bumps following regeneration of adsorbers in an air separation unit |
CN110787587A (en) | 2019-11-08 | 2020-02-14 | 乔治洛德方法研究和开发液化空气有限公司 | Air separation purification pressure equalizing system and control method |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2064137B2 (en) * | 1970-12-28 | 1971-09-16 | METHOD AND DEVICE FOR ADSORPTIVE REMOVAL OF WATER AND ONE OR MORE OTHER COMPONENTS FROM GASES | |
US3751878A (en) * | 1972-10-20 | 1973-08-14 | Union Carbide Corp | Bulk separation of carbon dioxide from natural gas |
US4012206A (en) * | 1972-12-02 | 1977-03-15 | Gas Developments Corporation | Air cleaning adsorption process |
US3885927A (en) * | 1974-02-05 | 1975-05-27 | Union Carbide Corp | Process for removing carbon dioxide from gas streams |
SU552102A1 (en) * | 1975-03-14 | 1977-03-30 | Белорусский технологический институт им.С.М.Кирова | The method of obtaining the adsorbent |
JPS5299973A (en) * | 1976-02-18 | 1977-08-22 | Toray Ind Inc | Adsorption and separation apparatus of mixed gas |
SU679228A1 (en) * | 1976-08-23 | 1979-08-15 | Институт Газа Ан Украинской Сср | Method of cleaning gas mixtures from carbon monoxide by adsorption |
ZA791382B (en) * | 1978-03-24 | 1980-04-30 | Air Prod & Chem | Method of regenerating adsorbents |
US4264340A (en) * | 1979-02-28 | 1981-04-28 | Air Products And Chemicals, Inc. | Vacuum swing adsorption for air fractionation |
US4249915A (en) * | 1979-05-30 | 1981-02-10 | Air Products And Chemicals, Inc. | Removal of water and carbon dioxide from air |
US4233038A (en) * | 1979-08-06 | 1980-11-11 | Air Products And Chemicals, Inc. | Reactivation system for water-carbon dioxide adsorbers |
JPS5681119A (en) * | 1979-12-07 | 1981-07-02 | Toray Ind Inc | Separation of mixed gas |
DE3345438A1 (en) * | 1983-12-15 | 1985-06-27 | Linde Ag, 6200 Wiesbaden | METHOD FOR ADSORPTIVELY SEPARATING WATER VAPOR AND CARBON DIOXIDE FROM A GAS FLOW |
DE3567579D1 (en) * | 1984-07-04 | 1989-02-23 | Nippon Kokan Kk | Method of separating carbon monoxide |
JPS61255995A (en) * | 1985-05-09 | 1986-11-13 | Kansai Coke & Chem Co Ltd | Production of high-calorie gas |
JPH062575B2 (en) * | 1985-12-05 | 1994-01-12 | 東ソー株式会社 | Clinoptilolite-type zeolite and method for producing the same |
US4711645A (en) * | 1986-02-10 | 1987-12-08 | Air Products And Chemicals, Inc. | Removal of water and carbon dioxide from atmospheric air |
US4732584A (en) * | 1986-05-22 | 1988-03-22 | Air Products And Chemicals, Inc. | Process for the purification of permanent gases using chabazite adsorbents |
US4747854A (en) * | 1986-05-22 | 1988-05-31 | Air Products And Chemicals, Inc. | Selective chromatographic process using an ion-exchanged, dehydrated chabazite adsorbent |
JPS63139990A (en) * | 1986-12-02 | 1988-06-11 | Kansai Coke & Chem Co Ltd | Manufacture of high-calorie gas |
US4775396A (en) * | 1987-11-05 | 1988-10-04 | Union Carbide Corporation | Selective adsorption of CO2 on zeolites |
US4935580A (en) * | 1988-06-14 | 1990-06-19 | Uop | Process for purification of hydrocarbons using metal exchanged clinoptilolite to remove carbon dioxide |
US5045515A (en) * | 1988-06-14 | 1991-09-03 | Uop | Process for preparing zeolitic adsorbents |
US4964889A (en) * | 1989-12-04 | 1990-10-23 | Uop | Selective adsorption on magnesium-containing clinoptilolites |
CN1027802C (en) * | 1990-01-19 | 1995-03-08 | 波克集团股份有限公司 | Low temp. purification of gases |
US5202096A (en) * | 1990-01-19 | 1993-04-13 | The Boc Group, Inc. | Apparatus for low temperature purification of gases |
US5156657A (en) * | 1990-03-29 | 1992-10-20 | The Boc Group, Inc. | Process for pre-purification of air for separation |
US5232474A (en) * | 1990-04-20 | 1993-08-03 | The Boc Group, Inc. | Pre-purification of air for separation |
-
1995
- 1995-03-21 US US08/407,817 patent/US5587003A/en not_active Expired - Fee Related
-
1996
- 1996-02-01 CA CA002168614A patent/CA2168614A1/en not_active Abandoned
- 1996-02-05 NZ NZ280939A patent/NZ280939A/en unknown
- 1996-03-02 TW TW085102539A patent/TW592788B/en active
- 1996-03-12 AU AU48041/96A patent/AU4804196A/en not_active Abandoned
- 1996-03-19 ZA ZA962222A patent/ZA962222B/en unknown
- 1996-03-19 EP EP96301840A patent/EP0733393A1/en not_active Withdrawn
- 1996-03-20 TR TR96/00216A patent/TR199600881A2/en unknown
- 1996-03-20 SG SG1996006563A patent/SG44733A1/en unknown
- 1996-03-20 KR KR1019960007601A patent/KR960033518A/en active IP Right Grant
- 1996-03-20 PL PL96313373A patent/PL313373A1/en unknown
- 1996-03-21 CN CN96104114A patent/CN1137418A/en active Pending
- 1996-03-21 JP JP8064149A patent/JPH08266844A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
AU4804196A (en) | 1996-10-03 |
TR199600881A2 (en) | 1996-10-21 |
SG44733A1 (en) | 1997-12-19 |
TW592788B (en) | 2004-06-21 |
PL313373A1 (en) | 1996-09-30 |
EP0733393A1 (en) | 1996-09-25 |
NZ280939A (en) | 1997-12-19 |
US5587003A (en) | 1996-12-24 |
CN1137418A (en) | 1996-12-11 |
KR960033518A (en) | 1996-10-22 |
JPH08266844A (en) | 1996-10-15 |
ZA962222B (en) | 1996-09-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5587003A (en) | Removal of carbon dioxide from gas streams | |
US5531808A (en) | Removal of carbon dioxide from gas streams | |
CA2264418C (en) | Removal of carbon dioxide from gas streams | |
US6270557B1 (en) | Process for purifying air by adsorption before cryogenic distillation | |
US5968234A (en) | Temperature swing adsorption with regeneration by elevated pressure ASU nitrogen-enriched gas | |
US4711645A (en) | Removal of water and carbon dioxide from atmospheric air | |
US6273939B1 (en) | Process for purifying a gas stream of its N2O impurities | |
US6616732B1 (en) | Zeolite adsorbents, method for obtaining them and their use for removing carbonates from a gas stream | |
US6468328B2 (en) | Oxygen production by adsorption | |
EP0128580B1 (en) | Process for drying gas streams | |
JPH04227814A (en) | Improved air separation pressure variable adsorption method | |
US6125655A (en) | Process for purifying air by adsorbing CO2 and H2 O impurities on calcined alumina | |
US5980611A (en) | Air purification process | |
RU95102214A (en) | TYPE X ZEOLITE, METHOD FOR PRODUCING LITHIUM AND TREVALENT ION EXCHANGE TYPE X ZEOLITE AND METHOD FOR SEPARATING NITROGEN FROM GAS MIXTURE | |
US6238460B1 (en) | Air purification process | |
EP0284850B1 (en) | Improved adsorptive purification process | |
KR940008730A (en) | Nitrogen adsorption method using divalent cation exchanged lithium X-zeolite | |
US7011695B2 (en) | Barium-and calcium-based zeolitic adsorbent for gas purification in particular air | |
EP1221337A1 (en) | Pressure swing adsorption process for removing carbon dioxide and water vapour from a gas mixture | |
US6240745B1 (en) | Process and plant for the purification and cryogenic separation of air without precooling | |
JPH04363109A (en) | Method for concentrating gaseous chlorine | |
JPH02207838A (en) | Adsorbent for separating oxygen and nitrogen, adsorbing method and applying device |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
FZDE | Discontinued |