CA2175452C

CA2175452C - Method of production of extruded cereal-based fried food containing added protein

Info

Publication number: CA2175452C
Application number: CA002175452A
Authority: CA
Inventors: Maria Delores Villagran; David Arthur Lanner; Lori Jean Toman; Martin Alfred Mishkin; Nancy Coultrip Dawes
Original assignee: Procter and Gamble Co
Current assignee: Pringles SARL
Priority date: 1993-11-24
Filing date: 1993-11-24
Publication date: 1999-01-12
Anticipated expiration: 2013-11-24
Also published as: CA2175452A1

Abstract

An improved method for the production of extruded cereal grain-based fried food products having improved qualities is provided.
In the improved method, the cereal grain-based food product is formed by extrusion of a cereal grain dough mass containing a protein, followed by frying the extruded cereal grain dough to produce a fried cereal grain food product having reduced gumminess or toothpacking and grittiness.

Description

WO 9S/14396 2 ~ 7 5 4 5 2 PCT/US93/11442 .i.. _ .

Method of product~on of extruded cereal-based fr~ed food contaln~g added prote~n BACKGROUND OF THE PRESENT lNv~llON
The present invention is directed to a method for the production of an extruded cereal grain-based fried food product.
s As described by Matz, Snack Food Technology, conventional corn chip processes begin with a corn meal or corn masa. Both white and yellow corn of the dent type are added to a vat containing heated water and a p~oyoLLionate amount of lime. The mixture is heated to the boiling point, the heat is cut off, and the contents of the vat are permitted to stand undisturbed for 10 to 20 hours. During this time, the corn hulls are hydrated and partially hydrolyzed. The hulls are softened to a jelly-like consistency and are easily removed later in the process. The starch is also gelatinzed. By the end of the steeping period, the corn kernels have absorbed approximately 50% by weight water.
The hulls are removed in a washer by jets of water which also remove any remaining lime. The w~ch~ kernels are then transferred to a stone mill where they are ground into a dough or masa.
The masa is formed (usually by hand) into large cylindrical loaves and fed into hydraulically powered extrusion presses. The cylindrical chamber of the press contains a closely fitting piston which forces the dough through a die plate having a series of slot-like ports. A
cutting device severs the extruded strands into pieces. Alternatively, the dough can be rolled out into a thin sheet from which shapes can be cut. Dough pieces fall directly into heated cooking oil. After the moisture content of the cut dough has been reduced to about a few 5 ~
_ 2 percent, the resulting cooked corn product i8 salted, cooled, and packaged.
Such conventional processes of producing corn chips suffer from various disadvantages including the fact that the chips are gritty and subject to toothpacking.
One method of addressing such disadvantages is described in commonly-assigned U.S. Patent No.
4,645,679 which describes a method for the production of corn chips which involves comminuting a hydrated starch material such as potato starch with hydrated corn.

OBJECTS AND SUMMARY OF THE PRESENT lNv~NLlON
It is accordingly an~object of an aspect of the present invention to provide a method for the production of an extruded fried cereal grain-based food product which presents an expanded, delaminated - structure resulting in a tortilla-like appearance and improved chip texture.
An aspect of the invention is as follows:
A process for the production of corn-based extruded fried food product comprising the steps of:
feeding a cereal grain flour and water together with a protein source to an extruder, said cereal grain being selected from the group consisting of white and yellow corn, and said protein source being selected from the group consisting of soy protein concentrate and isolate, pea protein, corn protein, rice protein, and dairy proteins;
extruding said admixture to form a dough, said dough comprising from about 70 to 95 percent by weight (dry basis) of said cereal grain flour, and from about 4.5 to 25 percent by weight of said protein source (dry basis), said cereal grain flour 5 ~
'~ 2a comprised of non-pregelatinized cereal grain and the remainder from O up to about 40% by weight (dry basis) of partially pre-gelatinized cereal grain;
forming said dough into a sheet and cutting ~aid sheet into multiple segments of desired shape; and deep frying said segments to form said food product.

-~ ~' A

Wo95/14396 2 ~ ~ ~ 4 5 2 PCT~Sg3/11442 DETAILED DESCRIPTION OF THE PRESENT INVENTION
The present invention will described in terms of the use of corn, although as described below, the present invention is easily applicable to various other cereal grains such as wheat, rice, barley, and oats, and is not intended to be limited in scope or content to the use of corn. Exemplary corn grains include those formed from both yellow and white corn.
Mixtures of such grain sources can also be employed with advantage.
The present invention enables corn chips (such as tortilla chips) to be produced which may be described as crisp with a high degree of lS lubricity, fast mouthmelt and reduced hardness.
Such products have a distinctive corn flavor of moderate intensity.
Tortillas are generally considered to be comprised of a mixture of flour, water, salt and oil to form a dough which is then sheeted and cut into the conventional tortilla shape and size. Conventionally, in contrast to the present invention, such products are baked and optionally additionally fried in order to form the desired end product. However, as discussed in detail below, it has been found that frying the dough in the absence of a hAking step having a composition as described herein can result in the production of a highly desirable product which has a tortilla-like structure.
An acceptable corn or cereal grain flour can be proAnre~ by any method which yields an acceptable comminuted product, such as grinding.
It is particularly advantageous in terms of texture to comminute the corn by cutting with a

2 ~ 7 5 4 52 PCT/US93/11442 cutting mill such as an Urschel Comitrol, manufactured by Urschel Laboratories, Inc. of Valparaiso, Indiana. See U.S. Patent No.

3,728,311 which describes the use of such a cutting mill in the comminuting of corn.
The cereal grain which is used in practice of the present invention comprises in major proportion raw or native cereal grain flour which has not been precooked or pregelatinized, and may contain up to about 40% by weight (dry basis) of partially precooked or pregelatinized cereal grain. By partially gelatinized is meant cereal grain which is approximately 70-80 %
gelatinized.
In accordance with the present invention, a protein source is compounded with the dough in order to provide a protein-containing dough.
Exemplary protein sources include but are not limited to soy protein concentrate and isolate, pea protein, corn protein (zein), rice protein or dairy proteins (such as lactalbumin, casein, whey solids and non-fat dry milk), as well as mixLu~es thereof.
Such protein sources are generally employed with advantage in amounts ranging from about 4.5 to about 25 percent by weight (dry basis).
In the noted blend, the cereal grain flour is generally present in an amount within the range of from 70 to 95 percent by weight (dry basis).
When a protein is added to corn flour or a blend of grains, protein-starch interactions and viscosity increase. This results in higher merhAnical energy development (friction) to the 21 75~52 WO 95/14396 PCT/US93tl 1442 extruders. As the protein undergoes structural changes, the water holding capacity increases resulting in a dry sheet. As the water level in the extruders is increased, the starch hydrates to a greater extent increasing the viscosity and the degree of cook of the starch. The extra water does not reduce the friction (which generates heat) within the extruders; instead, the friction increases due to the protein-protein and protein-starch interactions. As a result of these interactions, the rheology of the dough changes, creating a stronger, more elastic dough capable of holding more water during sheeting.
During frying, the high water levels (about 35%) along with the addition of heat split and expand the round pieces of flexible sheet dough, causing bubbles of larger volume to form than the bubbles obtained in the absence of protein (similar to tortilla chip expansion).
This PYpAn~ed texture is not a surface phenomenon. This eYr~nAed structure is due to the gas trapping capacity of the dough, making possible the containment of evolved steam. The surface of the chip is dense like a tortilla chip but crispier and exhibiting a delaminated structure.
The extrusion process yields dough which is subjected to additional work input to enhAnce hydration and gelatization of the corn, to reduce grittinecs of the finished corn chip, and to improve cohesiveness of the dough.
Such additional work input is provided by extruding the dough in an extruder. The extrusion step is undertaken at a te~rerature in 2~ 75452 WO95/14396 PCT~S93/11442 the range of from about 190 to 360 F. (barrel temperature of the extruder) for a residence time of from about 1 to 4 minutes.
Any conventional coo~ing extruder can be employed for such extrusion, although it is preferred that a twin screw extruder be employed.
The extrusion temperature is a function of both the extruder jacket temperature and the amount of work input to the dough. Extrusion imparts both mechanical work and compression-type work to the dough.
The extruded dough having a thickness in the range of from 0.25 to 0.60 inch is next formed into a sheet. While the dough may be milled in any workable manner, acceptable results have been obtained by milling the dough with multiple sequential conventional two-roll mills. These sheeting rolls comprise front roll and a back roll which rotate about generally parallel longit~ nAl axes. The back roll has a diameter slightly larger than that of the front roll.
A milled-dough is thus produced having a thick~esc on the order of from about 0.020 to 0.040 inches. While the thickness of the resulting sheet is not critical, it is desirable to avoid production of sheet which is too thick to avoid adversely affecting the mouthmelting characteristic of the product.
After the dough is milled into a sheet, dough pieces or segments are formed from the sheet. Typically, dough segments are formed by cutting the sheet into pieces of desired shape and size. For example, segments can be formed "~ .

having the rectangular shape of most commercial corn chips, or the triangular, oval or round shape of tortilla chips.
The thus-produced segments are then deep-fried in oil by conventional means. Any kind of frying oil may be used, such as vegetable oil or ~n;~l fat. The oil or fat can be hydrogenated.
Suitable oils include corn oil, soybean oil, palm oil, sunflower seed oil, and mixtures thereof. Suitable animal fats include lard and tallow. Marine fats and oils such as menhaden can be used. The above list is merely exemplary and not intended to be inclusive.
Preferably, a frying temperature of from about 375 to 390 F. is employed.
The finiche~ chips are crisp, delaminated, non-gritty, and lubricious. The fat content of the chips can be between about 25% to about 27%
by weight, preferably about 25% by weight.
Salt or other flavor enhancers or seasonings may be applied to the finished corn chip. Preferably, the corn chip has from about 0.8 to 1.4 % by weight of salt, and most preferably about 1.5% by weight of salt. Other flavor ~nh~Drs and seasonings that can be used are salt substitutes, such as potassium chloride, ammonium chloride, seasoning salt, and herbal salts. Cheeses and synthetic ~h~e flavors can also be employed.
Inaredient ~ (D.B.
~, white ~u~co~................... 86.04 soy protein concentrate 12.26 sodium carboxymethylcellulose 1.5 acetylated monoglycerides 0.2 WO95/14396 2 1 7~452 PCT/US93/11442 The blend is transferred by gravity to a K-tron feeder which feeds the blend to the first extruder at a 4:1 ratio of dry solids to water.
A dough is formed by mixing and work input which continues for a period of time of approximately 45 seconds. The twin screw moves at a speed of 300 rpm, causing the product to move forward toward the extruder die, which is connected to a constriction (causing back pressure). The incremental increase in pressure increases mechanical energy development in this stage of the process. At the end of the constriction is the entrance of the second extruder. ~rom the ex~t of this extruder, rope of extrudate come through the die and are sheeted to form a cohesive/non-sticky dough. Extrusion of ground corn cont~ini ng protein and carboxymethylcellulose produces extrudates that form 5 LL ~ elastic doughs able to withstand stretching during sheeting and forming. Protein changes the rheology of extrudates due to increased torque and pressure within the extruder. The sheet is cut and fried in corn oil. Fi ni she~ chips are seasoned on one side after cooling. The fried chip has a pleasant corn flavor, and a light, ~Y~n~e~, delaminated structure with a uniform porosity, producing a tortilla-like texture.
Extrusion of corn without carboxymethylcelluose or protein forms a dough which at high water levels of 25 to 30% falls apart during sheeting and forming. ~he dough produces corn chips that do not have the expanded, delaminated structure seen with the W095/14396 2 1 7 ~ ~ 5 2 PCT/US93/11442 addition of the protein and the carboxymethylcellulose components.
~ Products produced which do not contain the carboxymethylcellulose component were determined to be denser, drier, and show higher levels of grittiness and toothpacking than products containing both the protein and the carboxymethylcellulose.

The process of Example 1 was employed to produce a fried corn snack with an increased protein level; i.e., 18% protein based on the total dry solids, using the following blend:
Inqredient % (D.B.) yellow corn 52.8 partially precooked corn 17.0 soy protein isolate 11.5 soy protein concentrate 12.0 sodium carboxymethylcellulose 1.4 lysine-hydrochloride 0.03 calcium carbonate 2.0 maltodextrin 3.0 acetylated monoglycerides 0.2 Calcium carbonate was added as a calcium fortification source. The water-holding capacity of the dough was found to increase with the pre~?~e of protein. In order to sheet this dough (which was found to be tough and dry), the water levels were increased about 20%. High protein levels were found to increase the torque in both extruders. Therefore, the addition of the protein enhances the degree of cook in the first extruder by increasing the SME (specific mech~nical energy). The finished chip presented a bubbly delaminated structure similar to a tortilla chip. The products were found to have WO 95/14396 2 l 7 S 4 5 2 PCT/US93/11412 a bland flavor and improved texture shown by increased crispiness and crunchiness.
However, the addition of very high levels of protein to the blend, as in the case of fortified snacks, resulted in products having slower breakdown during chewing. Toothpacking of products also increased. In this case, the CMC effect on toothpacking and mouthmelt is more important.
The extrusion temperature and screw speed, as well as the frying conditions, were the same as those used for low levels of protein.

Extrusion is a water-limited system, and although protein increases the water-holdinq capacity of the dough, there is still competition for the available water between protein, starch and the gum. The gum complexes the protein and allows the starch to absorb water and swell. Using the extrusion procedures of Example 1, and using the basic formulation of Example 2, levels of precooked yellow corn were used to partially replace the white popcorn to increase the hydration rate, ensure swelling and therefore increase gelatinization of the dough.
The extrusion temperatures in the last 5 zones of the cooker were dropped to 220 F. from 360 F., to reduce the possibility of overworking the dough. Overworked doughs result in dense products with a gummy texture. This is the result of starch degradation (mainly amylopectin) during extrusion. The emulsifier level was increased to twice the level required to run a 100% blend of white popcorn. Only 2 1 7 5 4 5 2 PCT~S93/114~2 after these process steps occurred was an elastic, cohesive sheet obtained. It was found that the addition of approximately 25% of precooked corn in the blend enabled substantially optimum results to be achieved.
The procedure of Example 1 was repeated with the following blends to form additional types of food products:

Tortilla-like Corn Chip Ingredient % (D.B.) yellow dent corn 89.7 soy protein isolate 7.17 sodium carboxymethylcellulose 1.47 acetylated monoglycerides 0.2 sugar 1.44 Protein and Calcium Fortified Corn ChiD
Ingredient % (D.B.
yellow corn 69.5 soy protein concentrate 12.0 soy protein isolate 12.0 sodium carboxymethylcellulose 1.4 acetylated monoglycerides 0.1 lysine-hydrochloride 0.03 calcium carbonate 2.0 maltodextrin 3.0 ~)r 1 7 t~ ~ r 7 PCT111S93/1 1442 WO 9S/14396 ~ ~ ~ J ~

Multi-Grain Chip with Tortilla-like A~earance Inqredient % (D.B.) yellow corn 50.0 rice flour 23.0 wheat flour 18.8 soy protein isolate 7.0 sodium carboxymethylcellulose1.0 acetylated monoglycerides 0.2 Protein and Calcium Fortified Multi-Grain ChiD
Inqredient % (D.B.) yellow corn 46.0 rice flour 20.0 wheat flour 14.8 casein 18.0 sodium carboxymethylcellulose1.0 acetylated monoglycerides 0.2 Protein Fortified Multi-Grain Chip Inqredient ~ (D.B.) yellow corn 50.0 rice flour 23.0 wheat flour 18.8 non-fat dry milk 7.0 sodium carboxymethylcellulose1.0 acetylated monoglycerides 0.2 .,,~

EXAMPLE g Multi-Grain Chip with Tortilla-like Appearance Ingredient % (D.B.) yellow corn so.o rice flour 23.0 wheat flour 18.8 soy protein isolate 7.0 sodium carboxymethylcellulose 1.0 acetylated monoglycerides 0.2 Fried products have been examined by an expert sensory panel to determine eating guality, crispiness, crunchiness, etc. The panel evaluated each of the products produced in accordance with the procedures of Examples 4-9 above. Each attribute was rated on a nine point intensity scale. For example, when rating crispiness, a rating of 1 would indicate that the product was "not crisp", whereas a rating of 9 would mean that the product was "extremely crisp". With regard to mouthmelt (fast to slow) and toothpacking, a low number on the nine point scale is indicative of desirability.
The ratings of the expert sensory panel for the products of Examples 4-9 are summarized below in Table I:

Wo95/14396 2 1 7 5 ~ 5~ ~ PCT~S93/11442 comDatlson of Effect of Gum and Proteln ln corn ch~D Product 8amDle wPc WPc+SPI wPc~spc WPC~SPI/
SPC+CMC
~nqredlent ~otal Proteln (~) 8 17 17.6 18 80y Protein ~) isol~te o ll o 6 concentrate o o 16.5 8 80dlum carboxymethyl Cellulose ~%) ~ O 0 haltodextrln ~) o o 2 2 ~at (%) 25 29 28 27 Attrlbute~
crlsplness 5.4c6.7b 6.8b 7.4a C~u"~hlness 5.~b6.3ab 6.0b 6.6a ~outhmelt/sreakdown 4.7b4.5b 5.2a 4.3b ~oothpacklng 5.0a5.oa 5.4a 4.4b olly Texture 3.7 3.5 3.6 3.4 Grltty 4.3 4.2 3.9 4.2 ~outhcoatlng 3.l 3.0 3.2 3.l overall ~lavor 5.4 5.4 5.0 5.2 ~nchar~cterl~tlc ~lavor 2.l 2.l 2.2 l.8 hote~ The abbrevlatlon WPc denotes whlte ~o~corll The abbrevlatlon cMc denotes sodlum carboxymethyl-cellulose The abbrevlatlon SPI denotes 80y proteln lsolate The abbrev~atlon SPc denotes soy proteln concentrate The notatlons a, b and c denote the slgnlf~cance o~
the dlfference between the ~G~Ucts - ~ 2 1 75452 WO9S/14396 PCT~Sg3/11442 The expert panel, upon sampling the products, concluded that the texture of products containing neither the added protein or the added gum were denser, drier, and showed higher levels of grittiness and toothpacking than did products containing protein and the added gum.
The flavor of products containing only the added protein was found to be pleasant, while having the appearance of tortilla chips.
However, toothpacking, commonly detected in extruded corn products, was evident. Products containing the gum in addition to the protein exhibited reduced toothpacking without lS negatively affecting other attributes.
From the above data, it can also be concluded that the addition of soy protein isolate without the concurrent addition of carboxymethylcellulose increased the crispiness of the product, while permitting the product to exhibit a flavor similar to that of the control sample.
It can also be concluded from the Examples that the addition of the gum increases sheet strength and water-holding capacity which contributes to the delaminated texture, while also reducing toothpacking. The increase in water-holding capacity also results in high fat levels after frying. The higher fat content of the fried product provides an increased lubricity effect.
Using the procedure of Example l, the following additional blends were prepared and tested by an expert sensory panel as summarized 3S in the data summarized in Table II:

- 2 1 7 5 4 5 2 PCT~S93/11442 Ingredient % (D.B.
white popcorn 96.72 sodium carboxymethylcellulose l.5 sugar l.5 acetylated monoglycerides 0.2 B-carotene 0.08 Inqredient % (D.B.
white popcorn 90.72 soy protein concentrate 6.0 sodium carboxymethylcellulose l.5 sugar l.5 acetylated monoglycerides 0.2 B-carotene 0.08 EXAMPLE l2 Inqredient % (D.B.
white popcorn 88.57 soy protein concentrate 8.l9 sodium carboxymethylcellulose l.46 sugar l.49 acetylated monoglycerides 0.21 B-carotene 0.08 PCT~S93/114~2 WO9Stl4396 TABLE ~I
comDarlson of Effect of Gum and Proteln ln corn ChiP Product ~amDle WPC~CMC WPC+CMC+SPC WPC~CMC+SPC
Total Proteln ~) o.oo 6.0 8.0 crlsplness 6.49 6.24 5.56b Crunchlnes~ 6.63a 6.02b 5.56b Mouthmelt/~reakdown 4.S6a 4.46a 3.88b Toothpacklng 4.29 4.68 4.44 Ol~y/Greasy 3.24 3.12 3.1~
G~ltty 4.32a 4.22a 3.68b Mouthcoatlng z.83 2.90 3.24 overall ~lavor 5.Z4 5.02 5.24 Vncharacterlstlc ~lavor 1.41 1.46 1.34 Acceptance 5.76 5.90 s.68 corn ~lavor 5.05 4.73 4.~6 8altlnes~ 3.93 4.27 4.24 clly Text~re 3.63 3.34 3.73 hote~ The abbrevlatlon WPC denotes whlte popcorn The abbrevlatlon CMC denotes sodlum carLo~ ~thyl-cellulose The abbre~latlon SPC denotes soy proteln concentrate The notatlons a b and c denote the slgnlflcance of the dlfference between the product~

From the data of Table II it can be concluded that the increase of the amount of protein from 6 to 8~ reduces grittiness exhibited by the product, while also producing a faster mouthmelt.

.

Claims

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. A process for the production of corn-based extruded fried food product comprising the steps of:
feeding a cereal grain flour and water together with a protein source to an extruder, said cereal grain being selected from the group consisting of white and yellow corn, and said protein source being selected from the group consisting of soy protein concentrate and isolate, pea protein, corn protein, rice protein, and dairy proteins;
extruding said admixture to form a dough, said dough comprising from about 70 to 95 percent by weight (dry basic) of said cereal grain flour, and from about 4.5 to 25 percent by weight of said protein source (dry basis), said cereal grain flour comprised of non-pregelatinized cereal grain and the remainder from 0 up to about 40% by weight (dry basis) of partially pre-gelatinized cereal grain;
forming said dough into a sheet and cutting said sheet into multiple segments of desired shape; and deep frying said segments to form said food product.

2. The process of Claim 1, wherein said protein source is soy protein isolate.

3. The process Claim 1, wherein said extrusion step occurs at a temperature in the range of from about 190° to 360°F.

4. The process of Claim 1, wherein said frying step occurs at a temperature in the range of from about 375° to 390°F.

5. The process of Claim 1, wherein said extruded dough is cut into the shape of tortilla chips.

6. The process of Claim 1, wherein said cereal grain is selected from the group consisting of corn, wheat, barley, oats and rice, and mixtures thereof.

7. The product prepared by the process of Claim 1.