CA2191309C - Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby - Google Patents

Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby

Info

Publication number
CA2191309C
CA2191309C CA 2191309 CA2191309A CA2191309C CA 2191309 C CA2191309 C CA 2191309C CA 2191309 CA2191309 CA 2191309 CA 2191309 A CA2191309 A CA 2191309A CA 2191309 C CA2191309 C CA 2191309C
Authority
CA
Canada
Prior art keywords
layer
machine direction
yarns
cross
direction yarns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA 2191309
Other languages
French (fr)
Other versions
CA2191309A1 (en
Inventor
Michael Gomer Stelljes Jr.
Glenn David Boutilier
Paul Dennis Trokhan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of CA2191309A1 publication Critical patent/CA2191309A1/en
Application granted granted Critical
Publication of CA2191309C publication Critical patent/CA2191309C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F1/00Wet end of machines for making continuous webs of paper
    • D21F1/0027Screen-cloths
    • D21F1/0036Multi-layer screen-cloths
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/006Making patterned paper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24298Noncircular aperture [e.g., slit, diamond, rectangular, etc.]
    • Y10T428/24306Diamond or hexagonal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322Composite web or sheet
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3472Woven fabric including an additional woven fabric layer

Abstract

A papermaking belt, comprising either a forming wire or a through-air-drying belt. The papermaking belt comprises a reinforcing structure having two layers tied together and a resinous framework. The yarns of the first layer are interwoven so that, except for the tie yarns, each yarn remains within 1.5 yarn diameters of the top plane defined by the knuckles of the first layer. The belt has a thickness of at least 2.5 times the yarn diameter for rigidity.

Description

MULTIPLE LAYER PAPERMAICING BELT PROVIDING ll~IPROVED FIBER
~ SUPPORT FOR CELLULOSIC FIBROUS STRUCTURES, AND
CFr.r.ULOSIC FIBROUS STRUCTURES PRODUCED THEREBY

The present invention relates to papermaking, and more parkicularly to belts used in papermaking. Such belts reduce non-uniform fiber distribution and/or pinholes and other irregularities indigenous to molding fibers into a three dimensional belt.
BACKGROUND OF THE INVENTION
Cellulosic fibrous structures, such as paper towels, facial tissues, and toilet tissues, are a staple of every day life. The large demand and constant usage for such consumer products has created a demand for improved versions of these products and) likewise, improvement in the methods of their manufacture. Such cellulosic fibrous structures are manufactured by depositing an aqueous slurry from a headbox onto a Fourdrinier wire or a twin wire paper machine. Either such forming wire is an endless belt through which initial dewatering occurs and fiber rearrangement takes place. Frequently, fiber loss occurs due to fibers flowing through the forming wire along with the liquid carrier from the headbox.
After the initial formation of the web, which later becomes the cellulosic fibrous structure the papermaking machine transports the web to the dry end of the machine. In the dry end of a conventional machine, a press felt compacts the web ' ' into a single region cellulosic fibrous structure prior to final drying.
The final drying is usually accomplished by a heated drum, such as a Yankee drying drum.
One of the significant aforementioned improvements to the manufacturing process, which yields a significant improvement in the resulting consumer products, is the use of through-air drying to replace conventional press felt dewatening. In WO 95133887 ~ pC'1'/L.'S95/06536 5 through-air drying, like press felt drying, the web begins on a forming wire which receives an aqueous slurry of less than one percent consistency (the weight percentage of fibers in the aqueous slurry) from a headbox. Initial dewatering takes place on the forming wire) but the forming wire is not usually exposed to web consistencies of greater than 30 percent. From the forming wire, the web is transferred to an air pervious through air drying belt.
Air passes through the web and the through-air-drying belt to continue the dewatering process. The air passing the through-air-drying belt and the web is driven by vacuum transfer slots, other vacuum boxes or shoes) predryer rolls, etc.
This air molds the web to the topography of the through-air-drying belt and 15 increases the consistency of the web. Such molding creates a more three dimensional web, but also creates pinholes if the fibers are deflected so far in the .
third dimension that a breach in fiber continuity occurs.
The web is then transported to the final drying stage where the web is also imprinted. At the final drying stage, the through air drying belt transfers the web to 20 a heated drum, such as a Yankee drying drum for final drying. During this transfer, portions of the web are densified during imprinting to yield a multi-region structure.
Many such mufti-region structures have been widely accepted as preferred consumer products. An example of an early through-air-drying belt which achieved great commercial success is described in U.S. Patent 3,301,746, issued January 31, 25 to Sanford et al.
Over time) fiuther improvements became necessary. A significant improvement in through-air-drying belts is the use of a resinous fi~amework on a reinforcing structure. This arrangement allows drying belts to impart continuous patterns, or) patterns in any desired form) rather than only the discrete patterns 3 0 achievable by the woven belts of the prior art. Examples of such belts and the cellulosic fibrous structura made thereby can be found in U.S. Patents 4,514,345, issued April 30) 1985 to Johnson et al.; 4,528,239, issued July 9, 1985 to Trokhan;
4,529,480, issued July 1c5, 1985 to Trokhan; and 4,637,859, issued January 20, to Trokhan. The foregoing four patents 3 5 show preferred constructions of patterned resinous fi~amework and reinforcing type through~air-drying belts, and the products made thereon. Such belts have been used to produce extremely commerciaDy successfiil products such as Bounty papa towels and Charmin Ultra toilet tissue, both produced and sold by the instant assignee.

W 0 95133887 PCTlUS95/06536 As noted above, such through-air-dtying belts used a reinforcing element to stabilize the resin. The reinforcing element also controlled the deflection of the a papermaking fibers resulting from vacuum applied to the backside of the belt and airflow through the belt. The early belts of this type used a fine mesh reinforcing element, typically having approximately fifty machine direction and fifty cross-machine direction yarns per inch. While such a fine mesh was acceptable from the standpoint of controlling fiber deflection into the belt, it was unable to stand the environment of a typical papermaking machine. For example, such a belt was so flexible that destructive folds and creases often occurred. The fine vams did not provide adequate seam strength and would often burn at the high temperatures I5 encountered in papermaking.
Yet other drawbacks were noted in the early embodiments of this type of through-air-drying belt. For example, the continuous pattern used to produce the consumer preferred product did not allow leakage through the backside of the belt.
In fact, such leakage was minimized by the necessity to securely lock the resinous pattern onto the reinforcing structure. Unfortunately, when the lock-on of the resin to the reinforcing structure was maximized, the short rise time over which the differential pressure was applied to an individual region of fibers during the application of vacuum often putted the fibers through the reinforcing element, resulting in process hygiene problems and product acceptance problems, such as pinholes.
A new generation of patterned resinous framework and reinforcing structure through-air-drying belts addressed some of these issues. Ttus generation utilized a dual layer reinforcing structure having vertically stacked machine direction yarns. A
single cross-machine direction yarn system tied the two machine direction yarns together.
For paper toweling, a relatively coarse mesh, such as tlw~ty-five machine direction yams and thirty cross-maclvne direction yams per inch, dual layer design significantly improved the seam strength and creasing problems. The dual layer design also allowed some backside leakage to occur. Such allowance was caused by a 35 _ using less precure energy in joining the resin to the reinforcing structure, resulting in a compromise between the desired backside leakage and the ability to lock the resin . onto the reinforcing structure.
Later designs used an opaque backside filament in the dual layer design, allowing for higher precure energy and better lock-on of the resin to the reinforcing structure, while maintaining adequate backside leakage. Tlus design effectively WO 95133887 pC't'/L'S95/06536 5 decoupled the tradeoff between adequate resin lock-on and adequate backside leakage in the prior art. Examples of such improvements in this type of belt are illustrated by gyp, Patent Application Serial No. 2 ,155, 222 .
Yet other ways to obtain a backside texture are illustrated by U.S. Patents 5,098,522) issued March 24, 1992 to 10 Smurkoski et al.; 5,260,171, issued November 9) 1993 to Smurkoski et al.;
and 5,275,700, issued January 4) 1994 to Trokhan, which patents show how to obtain a backside texture on a patterned resin and reinforcing structure through-air-drying belt.
15 As such resinous framework and reinforcing structure belts were used to make tissue products, such as the commercially successful Charmin Ultra noted above, new issues arose. For example) one problem in tissue making is the formation of small pinholes in the deflected areas of the web. It has recently been learned that pinholes are strongly related to the weave configuration of the reinforcing element 20 of the patterned resinous through-air-drying belt.
Standard patterned resinous through-air-drying belts maximize the projected open area, so that airflow therethrough is not reduced or unduly blocked.
Patterned resinous through-air-drying belts common in the prior art use a dual layer design reinforcing eltment having vertically stacked warps. Generally) the wisdom has 25 been to use relatively large diameter yarns, to increase belt life. Belt life is important not only because of the cost of the belts, but more importantly due to the expensive downtime incurred when a worn beh must be removed and a new belt installed.
Unfortunately, larger diameter yarns require larger holes thaebetween in order to accommodate the weave. The larger holes permit short fibers, such as Eucalyptus) 30 to be pulled through the belt and thereby create pinhola. Unfortunately) short fibers, such as Eucaiyptirs, are heavily consumer preferred due to the softness they create iri the resulting cetlulosic fibrous structure.
This problem can be overcome by adding more yarns per inch woven in the same pattern. However) this "solution" reduces the open area available for air flow.
3 5 If the yarns are made smaller to reopen the open area, the flexural rigidity and integrity of the reinforcing structure of the belt is compromised and the belt life is thereby reduced. Accordingly, the prior art required a trade-off between the necessary open area (for airflow) and fiber diameter (for pinholing and belt life).
One attempt to achieve both good fiber support, and the flexural rigidity and 40 belt integrity necessary to achieve a viable belt life was to use a combination of large w'O 95133887 CA 0 21913 0 9 19 9 8 - 10 - 0 5 pCT/L,'$g5106536 5 and small machine direction yarns. The large diameter yarns are disposed on the reinforcing layer for fabric durability, and the smaller diameter machine direction yarns are stacked on the web facing layer for fiber support and pinhole reduction.
Furthermore, a small machine direction yarn in the first layer may be placed between large machine direction yarns of the second layer for added fiber support.
This 10 attempt still did not produce wholly satisfactory results in pinhole reduction efforts due to a lack of planarity. Accordingly, it is necessary to turn to yet a different parameter than those utilized above to decouple the trade-offs required by the prior art.
One attempt to find a different parameter was to add a machine direction yarn 15 between each pair of stacked machine direction yarns, so that s single cross-machine direction yarn tied together stacked machine direction yarns. However, one problem this attempt encountered was the machine direction yarns not supported immediately thereunder by another yarn tended to sag ~ increasing pinholing. Additionally, the cross-machine direction yarns which tied the two layers together went from the 20 extreme of one layer to the extreme of the other layer. This deviation from planarity also increased pinholing.
A second attempt increased the tie fi-equency of the cross-machine direction yarns firom a six shed to a four shed. However, similar problems occurred - including sagging of the machine direction yarns of the upper layer which 25 were stacked with the machine direction yarns of the lower layer, due to either inadequate support from the other yarns, or due to being pulled towards the second layer by the cross-machine direction yarns.
Thex approaches were not successful. Clearly yet another approach was nxessary.
30 Likewise, the weave pattern must be applicable to press felts. Press felts dewater a cellulosic web by compaction. Suitable press felts may be made in accordanbe with U.S. Pstent 3,652,389 issued March 28) 1972 to HeUand;
4,752,519 issued June 21, 1988 to Boyer et al.; and 4,922,627 issued May 8, to Romero Hernaadez.
The necessary approach recognizes that pinholing in a through-air-drying belt and fiber loss in a forming wire are unexpectedly related to the yarns that support the fibers - rather than the open spaces between the yarns. The web facing yarns must remain clox to the top plane of the first layer) to provide adequate fiber support. Still, the weave pattern must accommodate large diameter yarns in order to provide adequate belt life.
Accordingly, it is an aspect of an object of this invention to provide a forming wire which reduces fiber loss and non-uniform fiber distribution in specific areas of the resulting product. It is another aspect of an object of this invention to provide a patterned resinous through-air-drying papermaking belt which overcomes the prior art trade-off of belt life and reduced pinholing.
Additionally, it is an aspect of an object of this invention to provide an improved patterned resinous through-air-drying belt having sufficient open area to efficiently use during manufacturing. It is also an aspect of an object of this invention to provide a patterned resinous through-air-drying belt which produces an aesthetically acceptable consumer product comprising a fibrous structure.
SUMMARY OF THE INVENTION
In accordance with one embodiment, the invention comprises a papermaking belt comprising a reinforcing structure. The reinforcing structure has a web facing first layer of interwoven machine direction yarns and cross-machine direction yarns. The yarns of the first layer have a yarn diameter and are interwoven in a weave comprising knuckles. The knuckles define a web facing top plane. Each yarn of the first layer has a top dead center longitude. The top dead center longitude remains within 1.5 yarn diameters of the top plane. The reinforcing structure also comprises a machine facing second layer of interwoven machine direction yarns and cross-machine direction yarns, which are interwoven into a weave. The first layer and second layer are tied together by a plurality of tie yarns which do not remain within 1.5 yarn diameters of the top plane. The reinforcing structure has a thickness at least 2.5 times as great as the yarn diameter.
The belt further comprises a pattern layer extending outwardly from the first layer and into the second layer. The pattern layer provides a web contacting surface facing outwardly from the top dead center longitude of the first layer and connects 6a the first and second layers, stabilizing the first layer relative to the second layer during the manufacture of cellulosic fibrous structures thereon.
In accordance with a further embodiment, the invention provides a papermaking belt comprising a reinforcing structure comprising a web facing first layer of interwoven machine direction yarns and cross-machine direction yarns, the machine direction and cross-machine direction yarns of the first layer having a yarn diameter and being interwoven in a weave comprising knuckles, the knuckles defining a web facing top plane, each yarn of the first layer having a top dead center longitude, the top dead center longitude remaining within 1.5 yarn diameters of the top plane;
a machine facing second layer of interwoven machine direction yarns and cross-machine direction yarns, the machine direction and cross-machine direction yarns of the second layer being interwoven in a weave, the first layer and the second layer being tied together by a plurality of tie yarns which do not remain within 1.5 yarn diameters of the top plane;
adjunct cross-machine direction or adjunct machine direction tie yarns interwoven with respective machine direction yarns or cross-machine direction yarns of the web facing layer and the machine facing layer to tie the first layer and the second layer relative to one another, the adjunct tie yarns not remaining within one yarn diameter of the top plane, wherein the reinforcing structure has a thickness at least 2.5 times as great as the yarn diameter; and a pattern layer extending outwardly from the first layer and into the second layer, wherein the pattern layer provides a web contacting surface facing outwardly from the top dead center longitude of the first layer, the pattern layer connecting the first layer and the second layer, whereby the pattern layer stabilizes the first layer relative to the second layer during the manufacturing of cellulosic fibrous structures thereon.
In accordance with a further embodiment, the invention provides a papermaking belt comprising a reinforcing structure, the structure comprising a 6b web facing first layer of interwoven machine direction yarns and cross-machine direction yarns, the machine direction and cross-machine direction yarns of the first layer having a yarn diameter and being interwoven in a weave comprising knuckles, the knuckles defining a web facing top plane, each yarn of the first layer having a top dead center longitude, the top dead center longitude remaining within 1.5 yarn diameters of the top plane;
a machine facing second layer of interwoven machine direction yarns and cross-machine direction yarns, the machine direction and cross-machine direction yarns of the second layer being interwoven in a weave, the first layer and the second layer being tied together by a plurality of tie yarns which do not remain within one yarn diameter of the top plane;
wherein a plurality of the machine direction yarns or the cross-machine direction yarns of the second layer are interwoven with respective cross-machine direction yarns or machine direction yarns of the first layer as integral tie yarns to tie the first layer and the second layer relative to one another, the integral tie yarns not remaining within 1.5 yarn diameters of the top plane, wherein the reinforcing structure has a thickness at least 2.5 times as great as the yarn diameter;
and a pattern layer extending outwardly from the first layer and into the second layer, wherein the pattern layer provides a web contacting surface facing outwardly from the top dead center longitude of the first layer, the pattern layer connecting the first layer and the second layer, whereby the pattern layer stabilizes the first layer relative to the second layer during the manufacture of cellulosic fibrous structures thereon.
BRIEF DESCRIPTION OF THE DRAWINGS
Figure 1 is a top plan view shown partially in cutaway of a belt according to the present invention having cross-machine direction adjunct tie yarns.
Figure 2 is a vertical sectional view taken along line 2-2 of Figure 1 and having the pattern layer partially removed for clarity.

WO 95133887 PCT/US95f06536 Figure 3 is a top plan view shown partially in cutaway of a belt according to the present invention having machine direction integral tie yarns in the second layer.
Figures 4A and 4B are vertical sectional views taken along line 4A: 4A and 4B-4B of Figure 3 and having the pattern layers partially removed for clarity.
Figure 5 is a top plan view shown partially in cutaway of a belt according to the present invention having machine direction integral tie yarns in both the first and second layers.
Figures 6A and 6B are vertical sectional views taken along line 6A: 6A and 6B-6B of Figure 5 and having the pattern layers partially removed for clarity.
DETAILED DESCRIPTION OF THE INVENTION
Referring to Figures 1 and 2, the belt 10 of the present invention is preferably an endless belt and may r~eive cellulosic fibers discharged from a headbox or carry a web of cellulosic fibers to a drying apparatus, typically a heated drum, such as a Yankee drying drum (not shown). Thus) the endless belt 10 may either be executed as a forming wire, a press felt, or as a through-air-drying belt, as needed.
The papemraking belt 10 of the present invention, in either such execution, comprises two primary elements: a reinforcing structure 12 and optional pattern layer 30. The reinforcing structure 12 is further comprised of at least two layers, a web facing first layer 16 and a machine facing second layer 18. Each layer 16, 18 of the reinforcing structure 12 is further comprised of interwoven machine direction yarns 120, 220 and cross-machine direction yarns 122, 222. The reinforcing structure 12 further comprises tie yarns 320, 322 interwoven with the respective yarns 100 of the web facing layer 16 and the machine facing layer 18.
As used herein, "yarns 100" is generic to and inclusive of machine direction yarns 120, cross-machine direction yarns 122 of the first layer 16, as well as machine direction yarns 220 and cross-machine direction yams 222 of the second layer 18.
The second pr9mary element of the belt 10 is the pattern layer 30. The pattern layer 30 is cast finm a resin onto the top of the first layer 16 of the reinforcing structure 12. The pattern layer 30 penetrates the reinforcing structure 12 and is ( 35 cured into any desired binary pattern by irradiating liquid resin with actinic radiation through a binary mask having opaque sections and transparent sections.
The belt 10 has two opposed surfaces, a web contacting surface 40 disposed on the outwardly facing surface of the pattern layer 30 and an opposed backside 42.
The backside 42 of the belt 10 contacts the machinery used during the papermaking WO 95/33887 pCZ'IL'S95/06536 w operation. Such machinery (not illustrated) includes a vacuum pickup shoe, vacuum box, various rollers) etc.
The belt 10 may further comprise conduits 44 extending from and in fluid communication with the web contacting surface 40 of the belt 10 to the backside 42 of the belt 10. The conduits 44 allow deflection of the cellulosic fibers normal to the plane of the belt 10 during the papermaking operation.
The conduits 44 may be discrete) as shown, if an essentially continuous pattern layer 30 is selected. Alternatively) the pattern layer 30 can be discrete and the conduits 44 may be essentially continuous. Such an arrangement is easily envisioned by one skilled in the art as generally opposite that illustrated in Figure 1.
Such an arrangement, having a discrete pattern layer 30 and an esxntially continuous conduit 44, is illustrated in Figure 4 of the aforementioned U.S. Patent 4,514,345 issued to Johnson et al. Of course, it will be recognized by one skilled in the art that any combination of discrete and continuous patterns may be selected as well.
The pattern Iaya 30 is cast from photosensitive resin The preferred method for applying the photosensitive resin forming the pattern layer 30 to the reinforcing structure 12 in the desired pattern is to coat the reinforcing layer with the photoxnsitive resin in a liquid form. Actinic radiation, having an activating wavelength matched to the cure of the resin, illuminates the liquid photosensitive resin through a mask having transparent and opaque regions. The actinic radiation pasxs through the transparent regions and cures the resin therebelow into the desired pattern. The liquid resin shielded by the opaque regions of the mask is not cured and is washed sway) leaving the conduits 44 in the pattern layer 30.
It has been found, as identified in the aforementioned ~.~,Patent Application Serial No. 215 5 2 ? 2 ~~ in the name of Trokhan et al. .
that opaque machine direction yarns 220 or cross-machine direction yarns 222 may be utilized to mask the portion of the reinforcing structure 12 between such machine direction yarns 220 and cross-machine direction yarns 222 and the backside 3 5 42 of the belt 10 to create a backside texture. The aforementioned application is incorporated herein by reference for the purpox of illustrating how to incorporate such opaque yarns 220, 222 into a reinforcing structure 12 according to the prexnt invention. The yarns 220, 222 of the second layer 18 may be made opaque by coating the outsides of such yarns 220) 222) adding fillers such as carbon black or titanium dioxide, etc.

W O 95733887 21913 0 9 . ; -. ~ .. PGT~595/06536 . ', ~- ,. , The pattern layer 30 extends from the backside 42 of the second layer 18 of the reinforcing structure 12, outwardly from and beyond the first layer 16 of the reinforcing structure 12. Of course, as discussed more fully below, not all of the ~ pattern layer 30 extends to the outermost plane of the backside 42 of the belt 10.
Instead, some portions of the pattern layer 30 do not extend below particular yarns 220, 222 of the second layer 18 of the reinforcing structure 12. The pattern layer 30 also extends beyond and outwardly from the top dead center longitude TI)C of the first layer 16 a distance of about 0.002 inches (0.05 millimeter) to about 0.050 inches (1.3 millimeters). The dimension of the pattern layer 30 perpendicular to and beyond the first layer 16 generally increases as the pattern becomes coarser.
The distance the pattern layer 30 extends from the top dead center longitude TI3C
of the first layer 16 is measured from the plane 46 in the first layer 16, furthest from the backside 42 of the second layer 18.
The term "machine direction" refers to that direction which is parallel to the principal flow of the paper web through the papermaking apparatus. The "cross machine direction" is perpendicular to the machine direction and ties within the plane of the belt 10. A "knuckle" is the intersection of a machine direction yam 120, 220 and a cross-machine direction yam 122, 222. The "shed" is the minimum number of yams 100 necessary to make a repeating unit in the principal direction of a yarn 100 under consideration.
The machine direction and cross-machine direction yarns 120, 122 are interwoven into a web fitting first layer 16. Such a first layer 16 may have a one-over, one-under square weave, or any other weave which has a minimal deviation from the top plane 46. Preferably the machine direction and cross-machine direction yarns 120, 122 comprising the first layer 16 are substantially transparent to actinic radiation which is used to cure the pattern layer 30. Such yarns 120, 122 are considered to be substantially transparent if actinic radiation can pass through the greatest cross-sectional dimension of the yams 120, 122 in a direction generally perpendicular to the plane of the belt 10 and still sufficiently cure photosensitive resin therebelow.
~ 35 The machine direction yarns 220 and cross-machine direction yarns 222 are also interwoven into a machine facing second layer 18. The yams 220, ~ 222, ~ particularly the cross-machine direction yarns 222, of the machine facing second layer 18 are preferably larger than the yams 120, 122 of the first layer 16, to improve seam strength. Tlus result may be accomplished by providing cross-machine direction yarns 222 of the second layer 18 which are larger in diameter than w0 95133887 , a PCT/US95106536 1 ' ; -:, 2m3Q.~ ;, i.l n I ' 5 the machine direction yarns 120 of the first layer - if yams 100 having a round cross section are utilized.
The web facing first layer 16 is woven so that the top dead center longitude TDC of each yarn 120, 122 of the first layer I6 that is in~the top plane 46 does not extend more than 1.5 yarn diameters D, and preferably not more than 1.0 yam 10 diameters D away from the top plane 46 at any position, and remains within 1.0 or I.5 yarn diameters D of the top plane 46 at all positions, unless such yarn 120, 122 is a tie yarn 320, 322. The yarn diameter D is based on the diameters) of the yarns 120, 122 of the first layer 16. If yarns 120, 122 having different diameters are utilized, the yarn diameter D is the diameter of the largest yam 120, 122 of the first I5 layer 16. If yams 120, 122 having a non-round cross section are utilized, the yarn diameter D is considered to be the maximum dimension through such yarn 120, taken perpendicular to the plane of the belt 10. The top dead center longitude TDC
of a yarn 100 is that line parallel to the major axis of the yarn 100 and disposed on the circumference of the yam 100 at the position closest to top plane 46.
The top dead center longitudes TDC of the yams 120) 122 remain within 1.0 diameters D of the top plane 46 if a monoplanar weave is utilized. The top dead center longitudes TDC of the yams 120, 122 remain within 1.5 yam diameters D
if a weave having sub-top surface knuckles is utilized.
To determine whether or not the top dead center longitudes TDC of the yarns 120, 122 remains within L0 or 1.5 yarn diameters D of the top plane 46 an imaginary cutting plane 1.0 or 1.5 yam diameters D is drawn parallel to the top plane 46 (and disposed towards the backside 42 of the reinforcing structure 12).
The top dead center longitudes TDC of yarns 120, 122 which form knuckles 48 defining the top plane 46 are considered to remain within 1.0 or 1.5 yam diameters D of the top plane 46 if such top dead center longitudes TDC do not intercept the respective imaginary cutting plane.
In accordance with the present invention, the yarns 120, 122 of the first layer 16 may be interwoven in a weave of N over and N under, where N equals a positive integer, 1, 2, 3.... A preferred weave of N over and N under ~is a square weave having N equal to 1.
Another preferred weave is an N over, 1 under weave, etc., so long as the yarns I20, 122 of the first layer 16 cross over the respective interwoven yams 122, 120 of the first layer 16, such that such yarns 120, 122 are on the top dead center longitude TDC of the first Layer 16, more than om the backside of the first layer 16.

WO 95!33887 ~ I g ~ 3 Q ~ PCT/US95~06336 For N greater than 1, preferably the N over yams 120, 122 are cross-machine direction yarns 122) in order to maximize fiber support.
Also) the reinforcing structure 12 of the belt 10 according to the present invention has a thickness t at least 2.5 times as great as one yam diameter D, as defined above, and more preferably at least 3.0 times as great as one yam diameter D. Such a thickness t is important in providing sufficient belt 10 rigidity, so that belt 10 life is not unduly compromised.
The thickness t of the reinforcing structure 12 is measured using an Emveco Model 210A digital micrometer made by the Emveco Company of Newburg) Oregon, or similar apparatus, using a 3.0 pounds per square inch loading applied IS through a round 0.875 inch diameter foot. The reinforcing structure 12 may be loaded up to a maximum of 20 pounds per lineal inch in the machine direction while tested for thickness. The reinforcing structure 12 must be maintained at 50-100°F
during testing.
The machine direction and cross-machine direction yams 220, 222 coimprising the second layer 18 may be woven in any suitable shed and pattern, such as a square weave, as shown, or a twill or broken twill weave. If desired, the second layer 18 may have a cross-machine direction yam 222 in every other position, corresponding to alternating cross-machine direction yams 122 of the first layer. It is more important that the first layer 16 have multiple and more closely spaced cross machine direction yarns 122) to provide sufficient fiber support. Generally, the machine direction yarns 220 of the second layer 18 occur with a frequency coincident that of the machine direction yarns 120 of the first layer 16, in order to preserve seam strength and improve belt rigidity.
Adjunct tie yarns 320, 322 may be interposed between and interwoven with the first layer 16 and the second layer 18. The adjunct tie yams 320, 322 may be machine direction tie yams 320 which are interwoven with respective cross-machine direction yarns 122, 222 of the first and second layers 16, 18, or cross-machine direction tie yarns 322) which are interwoven with the respective machine direction yarns 120, 220 of the first and second layers 16, 18. As used herein, tie yarns 320, 322 are considered to be "adjunct" if such tie yarns 320, 322 do not comprise a yarn 100 inherent in the weave selected for either of the first or second layers 16, 18, but instead is in addition to, and may even disrupt, the weave of the first or second layers 16, 18.

~.~; r~ 3. :. ~ 12 Preferably the adjunct tie yarns 320, 322 are smaller in diameter than the yarns 100 of the first and second layers 16, 18, so such tie yams 320, 322 do not unduly reduce the projected open area of the belt 10.
A preferred weave pattern for the adjunct tie yarns 320) 322 has the least number of tie points necessary to stabilize the first layer 16 relative to the second layer 18. The tie yarns 324 are preferably oriented in the cross-machine direction because this arrangement is generally easier to weave.
Contrary to the types of weave patterns dictated by the prior art, the stabilizing effect of the pattern layer 30 minimizes the number of tie yarns 320, 322 necessary to engage the first layer 16 and the second layer 18. This is because the pattern layer 30 stabilizes the first layer 16 relative to the second layer 18 once casting is complete and throughout the paper manufacturing process.
Accordingly, smaller and fewer adjunct tie yarns 320, 322 may be selected, than the yarns used to make the first or second layers 16, 18.
Adjunct tie yarns 320, 322 having relatively fewer and smaller yarns 20, 22 are desirable, because the adjunct tie yams 320, 322, of course, reduce the projected open area of the belt 10. It is desirable that the entire reinforcing structure 12 have a large projected open area. The large open area is important in providing a sufficient path for the air flow therethiough to occur. If limiting orifice drying, such as is beneficially described in U.S. Patent 5,274,930 issued January 4, 1994 to Ensign et al. is desired, it becomes even more important that the belt 10 has sufficient open area.
More importantly, the reinforcing stmcture 12 according to the present invention must allow sufficient air flow perpendicular to the plane of the reinforcing structure 12. The reinforcing structure 12 preferably has an air permeability of at least 900 standard cubic feet per minute per square foot) preferably at least 1,000 standard cubic feet per minute per square foot, and more preferably at least 1,100 standard cubic feet per minute per square foot. ~f course the pattern layer 30 will reduce the sir permeability of the belt 10 according to the particular pattern selected.
The air permeability of a remfforcing structure 12 is measured under a tension of 15 pounds per linear inch using a Valmet Permeability Measuring Device finm the Valmet Company of Finland at a differential pressure of 100 Pascals. If any portion of the reinforcing structure 12 meets the aforementioned air permeability limitations, the entire reinforcing structure 12 is considered to meet these limitations.
Referring to Figures 3 and 4, if desired, the adjunct tie yams 320, 322 may be omitted. Instead of adjunct tie yarns 320) 322, a plurality of machine direction yarns Wo 95f33887 ~., . ~. 1 x PCT/US9S/06536 i or cross-machine direction yarns 320) 322 of the second layer 18 may be interwoven with respective ttoss-machine direction or machine direction yarns 122, 120 of the first layer 16. These interwoven yarns 320, 322 which do not remain in the plane of the second layer 18 are hereinafter referred to as 'integral tie yams" 320, becaux rhea integral tie yarns 320, 322 which join the fins and second layers I6, 18, and stabilize the second lays 18 relative to the &rst lays 16 ue inherently found in the weave of at (east one such layer 16, 1 E. The yarns 100 which remain within the plane of the first or second lays 16, 18 are referred to as non-tie yens 100.
Preferably the integral tie yens 320, 322 of the second layer 18 which ue inte.wovm with the respective cross~machine direction or machine direction yarns 122) 120 of the first layer 16 ue machine direction tie yens 320) to maximize scam strength. However) amngements having cross-machine direction integral tie yams 322 may be utilized.
1n an alternative embodiment (not shown), the integral tie yarns 320) 322 may extend from the fast layer 16 and be interwoven with the respective machine direction or cross-machine direction yarns 220, 222 of the second layer 18.
This embodiment may be easily emrisioned by turning Figure 4 upside down.
Referring to Fgttres 5 and 6, the itttegnt tie yarns 320) 324 rnay emanate firom both the first and second layers 16) 18, in a combination of the two foregoing teachings. Of courx, one skilled in the art will recognize this arrangement may be used in conjunction with adjunct tie yarns 320) 322 as well.
White other embodiments of the invention are fesu'ble) given the various combinations and permutations of the foregoing teachings, it is not intended to thereby limit the present invention to only that which is shown and described abov e.

Claims (19)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A papermaking belt comprising:
a reinforcing structure comprising:
a web facing first layer of interwoven machine direction yarns and cross-machine direction yarns, said machine direction and cross-machine direction yarns of said first layer having a yarn diameter and being interwoven in a weave comprising knuckles, said knuckles defining a web facing top plane, each yarn of said first layer having a top dead center longitude, said top dead center longitude remaining within 1.5 yarn diameters of said top plane;
a machine facing second layer of interwoven machine direction yarns and cross-machine direction yarns, said machine direction and cross-machine direction yarns of said second layer being interwoven in a weave, said first layer and said second layer being tied together by a plurality of tie yarns which do not remain within 1.5 yarn diameters of said top plane, wherein said reinforcing structure has a thickness at least 2.5 times as great as said yarn diameter, and a pattern layer extending outwardly from said first layer and into said second layer, wherein said pattern layer provides a web contacting surface facing outwardly from top dead center longitude of said first layer, said pattern layer connecting said first layer and said second layer, whereby said pattern layer stabilizes said first layer relative to said second layer during the manufacture of cellulosic fibrous structures thereon.
2. A papermaking belt comprising:
a reinforcing structure comprising:
a web fitting first layer of interwoven machine direction yarns and cross-machine direction yarns, said machine direction and cross-machine direction yarns of said first layer having a yarn diameter and being interwoven in a weave comprising knuckles, said knuckles defining a web facing top plane, each yarn of said first layer having a top dead center longitude, said top dead center longitude remaining within 1.5 yarn diameters of said top plane;
a machine facing second layer of interwoven machine direction yarns and cross-machine direction yarns, said machine direction and cross-machine direction yarns of said second layer being interwoven in a weave, said first layer and said second layer being tied together by a plurality of tie yarns which do not remain within 1.5 yarn diameters of said top plane;
adjunct cross-machine direction or adjunct machine direction tie yarns interwoven with respective machine direction yarns or cross-machine direction yarns of said web facing layer and said machine facing layer to tie said first layer and said second layer relative to one another, said adjunct tie yarns not remaining within one yarn diameter of said top plane, wherein said reinforcing structure has a thickness at least 2.5 times as great as said yarn diameter; and a pattern layer extending outwardly from said first layer and into said second layer, wherein said pattern layer provides a web contacting surface facing outwardly from top dead center longitude of said first layer, said pattern layer connecting said first layer and said second layer, whereby said pattern layer stabilizes said first layer relative to said second layer during the manufacture of cellulosic fibrous structures thereon.
3. A papermaking belt comprising:
a reinforcing structure comprising:
a web facing first layer of interwoven machine direction yarns and cross-machine direction yarns, said machine direction and cross-machine direction yarns of said first layer having a yarn diameter and being interwoven in a weave comprising knuckles, said knuckles defining a web facing top plane, each yarn of said first layer having a top dead center longitude, said top dead center longitude remaining within 1.5 yarn diameters of said top plane;
a machine facing second layer of interwoven machine direction yarns and cross-machine direction yarns, said machine direction and cross-machine direction yarns of said second layer being interwoven in a weave, said first layer and said second layer being tied together by a plurality of tie yarns which do not remain within one yam diameter of said top plane, wherein a plurality of said machine direction yarns or said cross-machine direction yarns of said second layer are interwoven with respective cross-machine direction yarns or machine direction yarns of said first layer as integral tie yarns to tie said first layer and said second layer relative to one another, said integral tie yarns not remaining within 1.5 yarn diameters of said top plane, wherein said reinforcing structure has a thickness at least 2.5 times as great as said yarn diameter; and a pattern layer extending outwardly from said first layer and into said second layer, wherein said pattern layer provides a web contacting surface facing outwardly from top dead center longitude of said first layer, said pattern layer connecting said first layer and said second layer, whereby said pattern layer stabilizes said first layer relative to said second layer during the manufacture of cellulosic fibrous structures thereon.
4. A papermaking belt according to Claim 2 wherein said machine direction yarns and said cross-machine direction yarns of said first layer are generally orthogonal and thereby form knuckles, wherein less than fifteen percent of said knuckles are interwoven with said plurality of yarns extending from said second layer.
5. A papermaking belt according to Claim 3 wherein said machine direction yarns and said cross-machine direction yarns of said first layer are generally orthogonal and thereby form knuckles, wherein less than fifteen percent of said knuckles are interwoven with said plurality of yarns extending from said second layer.
6. A papermaking belt according to Claim 4 wherein said machine direction yarns and said cross-machine direction yarns of said first layer are generally orthogonal and thereby form knuckles, wherein one percent to five percent of said knuckles are interwoven with said plurality of yarns extending from said second layer.
7. A papermaking belt according to Claim 5 wherein said machine direction yarns and said cross-machine direction yarns of said first layer are generally orthogonal and thereby form knuckles, wherein one percent to five percent of said knuckles are interwoven with said plurality of yarns extending from said second layer.
8. A papermaking belt according to Claim 6 wherein said yarns of said first layer are interwoven in an N over, 1 under weave.
9. A papermaking belt according to Claim 7 wherein said yarns of said first layer are interwoven in an N over, 1 under weave.
10. A papermaking belt according to Claim 8 wherein said N over yarns are cross-machine direction yarns.
11. A papermaking belt according to Claim 9 wherein said N over yarns are cross-machine direction yarns.
12. A papermaking belt according to Claim 11 wherein N equals 1.
13. A papermaking belt according to Claim 12 wherein N equals 1.
14. A papermaking belt according to Claim 2 wherein said papermaking belt is a forming wire.
15. A papermaking belt according to Claim 3 wherein said papermaking belt is a forming wire.
16. A papermaking belt according to Claim 2 wherein said papermaking belt is a through-air-drying belt.
17. A papermaking belt according to Claim 3 wherein said papermaking belt is a through-air-drying belt.
18. A papermaking belt according to Claim 6 wherein said reinforcing structure has an air permeability of at least 900 standard cubic feet per minute per square foot.
19. A papermaking belt according to Claim 7 wherein said reinforcing structure has an air permeability of at least 900 standard cubic feet per minute per square foot.
CA 2191309 1994-06-02 1995-05-23 Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby Expired - Lifetime CA2191309C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/254,387 1994-06-02
US08/254,387 US5496624A (en) 1994-06-02 1994-06-02 Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby
PCT/US1995/006536 WO1995033887A1 (en) 1994-06-02 1995-05-23 Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby

Publications (2)

Publication Number Publication Date
CA2191309A1 CA2191309A1 (en) 1995-12-14
CA2191309C true CA2191309C (en) 1999-09-07

Family

ID=22964107

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2191309 Expired - Lifetime CA2191309C (en) 1994-06-02 1995-05-23 Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby

Country Status (16)

Country Link
US (2) US5496624A (en)
EP (1) EP0763158B1 (en)
JP (1) JPH10501308A (en)
KR (1) KR100231619B1 (en)
AT (1) ATE179472T1 (en)
AU (1) AU700550B2 (en)
BR (1) BR9507823A (en)
CA (1) CA2191309C (en)
CZ (1) CZ9603511A3 (en)
DE (1) DE69509383T2 (en)
ES (1) ES2130617T3 (en)
FI (1) FI964788A0 (en)
HU (1) HUT77901A (en)
MX (1) MX9606001A (en)
NO (1) NO965129L (en)
WO (1) WO1995033887A1 (en)

Families Citing this family (152)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5679222A (en) * 1990-06-29 1997-10-21 The Procter & Gamble Company Paper having improved pinhole characteristics and papermaking belt for making the same
EP0536320B1 (en) * 1990-06-29 1994-08-31 The Procter & Gamble Company Papermaking belt and method of making the same using differential light transmission techniques
US5500277A (en) * 1994-06-02 1996-03-19 The Procter & Gamble Company Multiple layer, multiple opacity backside textured belt
US5496624A (en) * 1994-06-02 1996-03-05 The Procter & Gamble Company Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby
US5954097A (en) * 1996-08-14 1999-09-21 The Procter & Gamble Company Papermaking fabric having bilaterally alternating tie yarns
US6010598A (en) * 1997-05-08 2000-01-04 The Procter & Gamble Company Papermaking belt with improved life
US6039839A (en) * 1998-02-03 2000-03-21 The Procter & Gamble Company Method for making paper structures having a decorative pattern
US6547924B2 (en) 1998-03-20 2003-04-15 Metso Paper Karlstad Ab Paper machine for and method of manufacturing textured soft paper
US6103067A (en) * 1998-04-07 2000-08-15 The Procter & Gamble Company Papermaking belt providing improved drying efficiency for cellulosic fibrous structures
US7265067B1 (en) 1998-06-19 2007-09-04 The Procter & Gamble Company Apparatus for making structured paper
US6110324A (en) * 1998-06-25 2000-08-29 The Procter & Gamble Company Papermaking belt having reinforcing piles
US6149849A (en) * 1998-08-14 2000-11-21 The Procter & Gamble Copmany Process and apparatus for making papermaking belt
US6099781A (en) * 1998-08-14 2000-08-08 The Procter & Gamble Company Papermaking belt and process and apparatus for making same
US6251331B1 (en) 1998-09-09 2001-06-26 The Procter & Gamble Company Process and apparatus for making papermaking belt using fluid pressure differential
US6344241B1 (en) 1999-06-07 2002-02-05 The Procter & Gamble Company Process and apparatus for making papermaking belt using extrusion
US6358594B1 (en) 1999-06-07 2002-03-19 The Procter & Gamble Company Papermaking belt
US6117270A (en) 1999-07-01 2000-09-12 The Procter & Gamble Company Papermaking belts having a patterned framework with synclines therein and paper made therewith
US6576091B1 (en) 2000-10-24 2003-06-10 The Procter & Gamble Company Multi-layer deflection member and process for making same
US6576090B1 (en) 2000-10-24 2003-06-10 The Procter & Gamble Company Deflection member having suspended portions and process for making same
US6660129B1 (en) 2000-10-24 2003-12-09 The Procter & Gamble Company Fibrous structure having increased surface area
US6743571B1 (en) 2000-10-24 2004-06-01 The Procter & Gamble Company Mask for differential curing and process for making same
US6420100B1 (en) 2000-10-24 2002-07-16 The Procter & Gamble Company Process for making deflection member using three-dimensional mask
US6610173B1 (en) * 2000-11-03 2003-08-26 Kimberly-Clark Worldwide, Inc. Three-dimensional tissue and methods for making the same
US6749721B2 (en) 2000-12-22 2004-06-15 Kimberly-Clark Worldwide, Inc. Process for incorporating poorly substantive paper modifying agents into a paper sheet via wet end addition
US6787000B2 (en) 2001-11-02 2004-09-07 Kimberly-Clark Worldwide, Inc. Fabric comprising nonwoven elements for use in the manufacture of tissue products having visually discernable background texture regions bordered by curvilinear decorative elements and method thereof
US6790314B2 (en) 2001-11-02 2004-09-14 Kimberly-Clark Worldwide, Inc. Fabric for use in the manufacture of tissue products having visually discernable background texture regions bordered by curvilinear decorative elements and method thereof
US6749719B2 (en) * 2001-11-02 2004-06-15 Kimberly-Clark Worldwide, Inc. Method of manufacture tissue products having visually discernable background texture regions bordered by curvilinear decorative elements
US6746570B2 (en) * 2001-11-02 2004-06-08 Kimberly-Clark Worldwide, Inc. Absorbent tissue products having visually discernable background texture
US6821385B2 (en) 2001-11-02 2004-11-23 Kimberly-Clark Worldwide, Inc. Method of manufacture of tissue products having visually discernable background texture regions bordered by curvilinear decorative elements using fabrics comprising nonwoven elements
US6837956B2 (en) * 2001-11-30 2005-01-04 Kimberly-Clark Worldwide, Inc. System for aperturing and coaperturing webs and web assemblies
US6824650B2 (en) * 2001-12-18 2004-11-30 Kimberly-Clark Worldwide, Inc. Fibrous materials treated with a polyvinylamine polymer
US7214633B2 (en) * 2001-12-18 2007-05-08 Kimberly-Clark Worldwide, Inc. Polyvinylamine treatments to improve dyeing of cellulosic materials
US7799968B2 (en) 2001-12-21 2010-09-21 Kimberly-Clark Worldwide, Inc. Sponge-like pad comprising paper layers and method of manufacture
US20030157000A1 (en) * 2002-02-15 2003-08-21 Kimberly-Clark Worldwide, Inc. Fluidized bed activated by excimer plasma and materials produced therefrom
WO2004018780A2 (en) * 2002-08-26 2004-03-04 Advanced Geotech Systems, Inc. Improved biplanar net structure for fluid drainage, particularly for geotechnical use
US6911114B2 (en) * 2002-10-01 2005-06-28 Kimberly-Clark Worldwide, Inc. Tissue with semi-synthetic cationic polymer
US6834684B2 (en) * 2002-10-24 2004-12-28 Albany International Corp. Paired warp triple layer forming fabrics with optimum sheet building characteristics
US7048012B2 (en) * 2002-10-24 2006-05-23 Albany International Corp. Paired warp triple layer forming fabrics with optimum sheet building characteristics
US20040084162A1 (en) 2002-11-06 2004-05-06 Shannon Thomas Gerard Low slough tissue products and method for making same
US7029756B2 (en) * 2002-11-06 2006-04-18 Kimberly-Clark Worldwide, Inc. Soft tissue hydrophilic tissue products containing polysiloxane and having unique absorbent properties
US6951598B2 (en) * 2002-11-06 2005-10-04 Kimberly-Clark Worldwide, Inc. Hydrophobically modified cationic acrylate copolymer/polysiloxane blends and use in tissue
US20040084164A1 (en) * 2002-11-06 2004-05-06 Shannon Thomas Gerard Soft tissue products containing polysiloxane having a high z-directional gradient
US20040102118A1 (en) * 2002-11-27 2004-05-27 Hay Stewart Lister High permeability woven members employing paired machine direction yarns for use in papermaking machine
US6827821B2 (en) * 2002-12-02 2004-12-07 Voith Fabrics Heidenheim Gmbh & Co. Kg High permeability, multi-layer woven members employing machine direction binder yarns for use in papermaking machine
US20040110017A1 (en) * 2002-12-09 2004-06-10 Lonsky Werner Franz Wilhelm Yellowing prevention of cellulose-based consumer products
US20040115451A1 (en) * 2002-12-09 2004-06-17 Kimberly-Clark Worldwide, Inc. Yellowing prevention of cellulose-based consumer products
US20040111817A1 (en) * 2002-12-17 2004-06-17 Kimberly-Clark Worldwide, Inc. Disposable scrubbing product
US7994079B2 (en) * 2002-12-17 2011-08-09 Kimberly-Clark Worldwide, Inc. Meltblown scrubbing product
US6878238B2 (en) * 2002-12-19 2005-04-12 Kimberly-Clark Worldwide, Inc. Non-woven through air dryer and transfer fabrics for tissue making
US6949167B2 (en) * 2002-12-19 2005-09-27 Kimberly-Clark Worldwide, Inc. Tissue products having uniformly deposited hydrophobic additives and controlled wettability
US6875315B2 (en) 2002-12-19 2005-04-05 Kimberly-Clark Worldwide, Inc. Non-woven through air dryer and transfer fabrics for tissue making
US7147751B2 (en) 2002-12-20 2006-12-12 Kimberly-Clark Worldwide, Inc. Wiping products having a low coefficient of friction in the wet state and process for producing same
US6994770B2 (en) * 2002-12-20 2006-02-07 Kimberly-Clark Worldwide, Inc. Strength additives for tissue products
US6896766B2 (en) * 2002-12-20 2005-05-24 Kimberly-Clark Worldwide, Inc. Paper wiping products treated with a hydrophobic additive
US6916402B2 (en) * 2002-12-23 2005-07-12 Kimberly-Clark Worldwide, Inc. Process for bonding chemical additives on to substrates containing cellulosic materials and products thereof
US7052580B2 (en) * 2003-02-06 2006-05-30 The Procter & Gamble Company Unitary fibrous structure comprising cellulosic and synthetic fibers
US7067038B2 (en) * 2003-02-06 2006-06-27 The Procter & Gamble Company Process for making unitary fibrous structure comprising randomly distributed cellulosic fibers and non-randomly distributed synthetic fibers
US20040163785A1 (en) * 2003-02-20 2004-08-26 Shannon Thomas Gerard Paper wiping products treated with a polysiloxane composition
US7396593B2 (en) 2003-05-19 2008-07-08 Kimberly-Clark Worldwide, Inc. Single ply tissue products surface treated with a softening agent
GB0318220D0 (en) * 2003-08-04 2003-09-03 Astenjohnson Inc Triple layer industrial fabric for through-air drying process
US7141142B2 (en) * 2003-09-26 2006-11-28 Kimberly-Clark Worldwide, Inc. Method of making paper using reformable fabrics
US7007722B2 (en) * 2003-11-17 2006-03-07 Voith Paper Patent Gmbh Forming fabric
US7811948B2 (en) * 2003-12-19 2010-10-12 Kimberly-Clark Worldwide, Inc. Tissue sheets containing multiple polysiloxanes and having regions of varying hydrophobicity
US7147752B2 (en) 2003-12-19 2006-12-12 Kimberly-Clark Worldwide, Inc. Hydrophilic fibers containing substantive polysiloxanes and tissue products made therefrom
US7479578B2 (en) * 2003-12-19 2009-01-20 Kimberly-Clark Worldwide, Inc. Highly wettable—highly flexible fluff fibers and disposable absorbent products made of those
US7186318B2 (en) * 2003-12-19 2007-03-06 Kimberly-Clark Worldwide, Inc. Soft tissue hydrophilic tissue products containing polysiloxane and having unique absorbent properties
US20050136772A1 (en) * 2003-12-23 2005-06-23 Kimberly-Clark Worldwide, Inc. Composite structures containing tissue webs and other nonwovens
US20060070712A1 (en) * 2004-10-01 2006-04-06 Runge Troy M Absorbent articles comprising thermoplastic resin pretreated fibers
US20060086472A1 (en) * 2004-10-27 2006-04-27 Kimberly-Clark Worldwide, Inc. Soft durable paper product
US20060093788A1 (en) * 2004-10-29 2006-05-04 Kimberly-Clark Worldwide, Inc. Disposable food preparation mats, cutting sheets, placemats, and the like
US7332451B2 (en) * 2004-11-17 2008-02-19 The Procter & Gamble Company Papermachine clothing having reduced void spaces
US20060127641A1 (en) * 2004-12-14 2006-06-15 The Procter & Gamble Company Papermachine clothing having reduced void spaces
US20060135026A1 (en) * 2004-12-22 2006-06-22 Kimberly-Clark Worldwide, Inc. Composite cleaning products having shape resilient layer
US7676088B2 (en) * 2004-12-23 2010-03-09 Asml Netherlands B.V. Imprint lithography
US7670459B2 (en) * 2004-12-29 2010-03-02 Kimberly-Clark Worldwide, Inc. Soft and durable tissue products containing a softening agent
US7374639B2 (en) * 2005-06-08 2008-05-20 The Procter & Gamble Company Papermaking belt
US8911850B2 (en) * 2005-06-08 2014-12-16 The Procter & Gamble Company Amorphous patterns comprising elongate protrusions for use with web materials
US7694433B2 (en) 2005-06-08 2010-04-13 The Procter & Gamble Company Web handling apparatus and process for providing steam to a web material
US20070048357A1 (en) * 2005-08-31 2007-03-01 Kimberly-Clark Worldwide, Inc. Fibrous wiping products
US20070093157A1 (en) * 2005-10-20 2007-04-26 Kimberly-Clark Worldwide, Inc. High speed, pressure bonded, thin sheet laminate
US20070098984A1 (en) * 2005-11-01 2007-05-03 Peterson James F Ii Fiber with release-material sheath for papermaking belts
US8778386B2 (en) * 2005-12-13 2014-07-15 Kimberly-Clark Worldwide, Inc. Anti-microbial substrates with peroxide treatment
US8444811B2 (en) 2005-12-15 2013-05-21 Kimberly-Clark Worldwide, Inc. Process for increasing the basis weight of sheet materials
US7842163B2 (en) * 2005-12-15 2010-11-30 Kimberly-Clark Worldwide, Inc. Embossed tissue products
US20070137811A1 (en) * 2005-12-15 2007-06-21 Kimberly-Clark Worldwide, Inc. Premoistened tissue products
US7879191B2 (en) * 2005-12-15 2011-02-01 Kimberly-Clark Worldwide, Inc. Wiping products having enhanced cleaning abilities
US8282776B2 (en) * 2005-12-15 2012-10-09 Kimberly-Clark Worldwide, Inc. Wiping product having enhanced oil absorbency
US7837831B2 (en) * 2005-12-15 2010-11-23 Kimberly-Clark Worldwide, Inc. Tissue products containing a polymer dispersion
US7820010B2 (en) * 2005-12-15 2010-10-26 Kimberly-Clark Worldwide, Inc. Treated tissue products having increased strength
US7883604B2 (en) * 2005-12-15 2011-02-08 Kimberly-Clark Worldwide, Inc. Creping process and products made therefrom
US7988824B2 (en) * 2005-12-15 2011-08-02 Kimberly-Clark Worldwide, Inc. Tissue product having a transferable additive composition
US7879189B2 (en) * 2005-12-15 2011-02-01 Kimberly-Clark Worldwide, Inc. Additive compositions for treating various base sheets
US7879188B2 (en) * 2005-12-15 2011-02-01 Kimberly-Clark Worldwide, Inc. Additive compositions for treating various base sheets
US7807023B2 (en) * 2005-12-15 2010-10-05 Kimberly-Clark Worldwide, Inc. Process for increasing the basis weight of sheet materials
US8029646B2 (en) 2005-12-15 2011-10-04 Dow Global Technologies Llc Cellulose articles containing an additive composition
US7837832B2 (en) 2005-12-15 2010-11-23 Dow Global Technologies, Inc. Additive compositions for treating various base sheets
US20070141936A1 (en) * 2005-12-15 2007-06-21 Bunyard William C Dispersible wet wipes with improved dispensing
US7799411B2 (en) * 2006-10-31 2010-09-21 The Procter & Gamble Company Absorbent paper product having non-embossed surface features
US7914649B2 (en) * 2006-10-31 2011-03-29 The Procter & Gamble Company Papermaking belt for making multi-elevation paper structures
US7785443B2 (en) 2006-12-07 2010-08-31 Kimberly-Clark Worldwide, Inc. Process for producing tissue products
US7604025B2 (en) * 2006-12-22 2009-10-20 Voith Patent Gmbh Forming fabric having offset binding warps
US7743795B2 (en) * 2006-12-22 2010-06-29 Voith Patent Gmbh Forming fabric having binding weft yarns
US7588662B2 (en) 2007-03-22 2009-09-15 Kimberly-Clark Worldwide, Inc. Tissue products containing non-fibrous polymeric surface structures and a topically-applied softening composition
US8372766B2 (en) * 2007-07-31 2013-02-12 Kimberly-Clark Worldwide, Inc. Conductive webs
US8058194B2 (en) * 2007-07-31 2011-11-15 Kimberly-Clark Worldwide, Inc. Conductive webs
US8697934B2 (en) * 2007-07-31 2014-04-15 Kimberly-Clark Worldwide, Inc. Sensor products using conductive webs
US20090057169A1 (en) * 2007-08-31 2009-03-05 Benjamin Joseph Kruchoski Spindle and Spindle Attachments for Coreless and Flexible Core Rolled Tissue Products
US20090057456A1 (en) * 2007-08-31 2009-03-05 Thomas Gerard Shannon Rolled Tissue Product Having a Flexible Core
US7879194B2 (en) * 2007-09-06 2011-02-01 Voith Patent Gmbh Structured forming fabric and method
US7879193B2 (en) 2007-09-06 2011-02-01 Voith Patent Gmbh Structured forming fabric and method
US7879195B2 (en) * 2007-09-06 2011-02-01 Voith Patent Gmbh Structured forming fabric and method
US7878224B2 (en) * 2008-02-19 2011-02-01 Voith Patent Gmbh Forming fabric having binding warp yarns
US7861747B2 (en) * 2008-02-19 2011-01-04 Voith Patent Gmbh Forming fabric having exchanging and/or binding warp yarns
US20100119779A1 (en) * 2008-05-07 2010-05-13 Ward William Ostendorf Paper product with visual signaling upon use
US20100112320A1 (en) * 2008-05-07 2010-05-06 Ward William Ostendorf Paper product with visual signaling upon use
US20090280297A1 (en) * 2008-05-07 2009-11-12 Rebecca Howland Spitzer Paper product with visual signaling upon use
JP5461532B2 (en) * 2008-05-29 2014-04-02 キンバリー クラーク ワールドワイド インコーポレイテッド Conductive web having electrical path and method for manufacturing the same
US7944401B2 (en) 2008-05-29 2011-05-17 Kimberly-Clark Worldwide, Inc. Radiating element for a signal emitting apparatus
US8940323B2 (en) 2008-05-30 2015-01-27 Kimberly-Clark Worldwide, Inc. Tissue products having a cooling sensation when contacted with skin
US8002950B2 (en) * 2008-06-11 2011-08-23 Voith Patent Gmbh Structured fabric for papermaking and method
US8172982B2 (en) * 2008-12-22 2012-05-08 Kimberly-Clark Worldwide, Inc. Conductive webs and process for making same
US8110072B2 (en) * 2009-03-13 2012-02-07 The Procter & Gamble Company Through air dried papermaking machine employing an impermeable transfer belt
US8105463B2 (en) 2009-03-20 2012-01-31 Kimberly-Clark Worldwide, Inc. Creped tissue sheets treated with an additive composition according to a pattern
US8795717B2 (en) 2009-11-20 2014-08-05 Kimberly-Clark Worldwide, Inc. Tissue products including a temperature change composition containing phase change components within a non-interfering molecular scaffold
USD636608S1 (en) 2009-11-09 2011-04-26 The Procter & Gamble Company Paper product
US8480852B2 (en) 2009-11-20 2013-07-09 Kimberly-Clark Worldwide, Inc. Cooling substrates with hydrophilic containment layer and method of making
US9181465B2 (en) * 2009-11-20 2015-11-10 Kimberly-Clark Worldwide, Inc. Temperature change compositions and tissue products providing a cooling sensation
US8287693B2 (en) 2010-05-03 2012-10-16 The Procter & Gamble Company Papermaking belt having increased de-watering capability
US8282783B2 (en) 2010-05-03 2012-10-09 The Procter & Gamble Company Papermaking belt having a permeable reinforcing structure
US8163130B2 (en) 2010-08-19 2012-04-24 The Proctor & Gamble Company Paper product having unique physical properties
US8313617B2 (en) 2010-08-19 2012-11-20 The Procter & Gamble Company Patterned framework for a papermaking belt
US8298376B2 (en) 2010-08-19 2012-10-30 The Procter & Gamble Company Patterned framework for a papermaking belt
US8211271B2 (en) 2010-08-19 2012-07-03 The Procter & Gamble Company Paper product having unique physical properties
FI20115222L (en) * 2011-03-04 2012-09-05 Metso Fabrics Oy Paper machine fabric
ES2633188T3 (en) 2011-09-30 2017-09-19 Kemira Oyj Paper and papermaking process
US9777434B2 (en) 2011-12-22 2017-10-03 Kemira Dyj Compositions and methods of making paper products
WO2013179139A1 (en) 2012-05-30 2013-12-05 Kemira Oyj Compositions and methods of making paper products
EP2864542B1 (en) 2012-06-22 2018-11-28 Kemira Oyj Compositions and methods of making paper products
KR20150064078A (en) 2012-09-26 2015-06-10 케미라 오와이제이 Absorbent materials, products including absorbent materials, compositions, and methods of making absorbent materials
PT2929087T (en) 2012-12-06 2017-03-23 Kemira Oyj Compositions used in paper and methods of making paper
US9562326B2 (en) 2013-03-14 2017-02-07 Kemira Oyj Compositions and methods of making paper products
US10213990B2 (en) 2013-12-31 2019-02-26 Kimberly-Clark Worldwide, Inc. Methods to make stretchable elastic laminates
US9358759B2 (en) 2013-12-19 2016-06-07 Kimberly-Clark Worldwide, Inc. Multilayered elastic laminates with enhanced strength and elasticity and methods of making thereof
US9802392B2 (en) 2014-03-31 2017-10-31 Kimberly-Clark Worldwide, Inc. Microtextured multilayered elastic laminates with enhanced strength and elasticity and methods of making thereof
US10132042B2 (en) 2015-03-10 2018-11-20 The Procter & Gamble Company Fibrous structures
MX2017002074A (en) 2014-09-03 2017-05-04 Kimberly Clark Co Multilayered elastic laminates with enhanced strength and elasticity and methods of making thereof.
CA2958904C (en) 2014-09-25 2022-06-21 Georgia-Pacific Consumer Products Lp Methods of making paper products using a multilayer creping belt, and paper products made using a multilayer creping belt
US10765570B2 (en) 2014-11-18 2020-09-08 The Procter & Gamble Company Absorbent articles having distribution materials
EP3023084B1 (en) 2014-11-18 2020-06-17 The Procter and Gamble Company Absorbent article and distribution material
US10517775B2 (en) 2014-11-18 2019-12-31 The Procter & Gamble Company Absorbent articles having distribution materials
WO2017156203A1 (en) 2016-03-11 2017-09-14 The Procter & Gamble Company A three-dimensional substrate comprising a tissue layer
US11408129B2 (en) 2018-12-10 2022-08-09 The Procter & Gamble Company Fibrous structures

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3322617A (en) * 1964-05-22 1967-05-30 Dexter Corp Paper making apparatus to form paper with a simulated woven texture
SE430425C (en) * 1981-06-23 1986-09-19 Nordiskafilt Ab PREPARATION WIRES FOR PAPER, CELLULOSA OR SIMILAR MACHINES
JPS61289195A (en) * 1985-06-17 1986-12-19 日本フイルコン株式会社 Papermaking double fabric
US5114777B2 (en) * 1985-08-05 1997-11-18 Wangner Systems Corp Woven multilayer papermaking fabric having increased stability and permeability and method
US4995429A (en) * 1986-02-05 1991-02-26 Albany International Corp. Paper machine fabric
DE3635000A1 (en) * 1986-10-14 1988-04-21 Oberdorfer Fa F DOUBLE-LAYER PAPER MACHINE SCREEN WITH COARSE-TEXTURED RUNNING SIDE AND FINE-STRUCTURED PAPER SIDE
JPS63145496A (en) * 1986-12-02 1988-06-17 日本フイルコン株式会社 Papermaking multilayer fabric
FI78329B (en) * 1987-02-10 1989-03-31 Tamfelt Oy Ab PAPPERSMASKINDUK.
US4989647A (en) * 1988-04-08 1991-02-05 Huyck Corporaiton Dual warp forming fabric with a diagonal knuckle pattern
US4921750A (en) * 1988-05-25 1990-05-01 Asten Group, Inc. Papermaker's thru-dryer embossing fabric
US4942077A (en) * 1989-05-23 1990-07-17 Kimberly-Clark Corporation Tissue webs having a regular pattern of densified areas
US4967805A (en) * 1989-05-23 1990-11-06 B.I. Industries, Inc. Multi-ply forming fabric providing varying widths of machine direction drainage channels
US5013330A (en) * 1989-12-04 1991-05-07 Asten Group, Inc. Multi-layered papermakers fabric for thru-dryer application
US5025839A (en) * 1990-03-29 1991-06-25 Asten Group, Inc. Two-ply papermakers forming fabric with zig-zagging MD yarns
EP0536320B1 (en) * 1990-06-29 1994-08-31 The Procter & Gamble Company Papermaking belt and method of making the same using differential light transmission techniques
US5101866A (en) * 1991-01-15 1992-04-07 Niagara Lockport Industries Inc. Double layer papermakers fabric having extra support yarns
US5496624A (en) * 1994-06-02 1996-03-05 The Procter & Gamble Company Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby

Also Published As

Publication number Publication date
MX9606001A (en) 1997-12-31
WO1995033887A1 (en) 1995-12-14
KR100231619B1 (en) 1999-11-15
FI964788A (en) 1996-11-29
ES2130617T3 (en) 1999-07-01
HU9603306D0 (en) 1997-01-28
DE69509383T2 (en) 1999-11-18
NO965129D0 (en) 1996-12-02
FI964788A0 (en) 1996-11-29
CA2191309A1 (en) 1995-12-14
AU700550B2 (en) 1999-01-07
NO965129L (en) 1996-12-02
KR970703467A (en) 1997-07-03
ATE179472T1 (en) 1999-05-15
US5840411A (en) 1998-11-24
DE69509383D1 (en) 1999-06-02
EP0763158B1 (en) 1999-04-28
EP0763158A1 (en) 1997-03-19
US5496624A (en) 1996-03-05
AU2646995A (en) 1996-01-04
BR9507823A (en) 1997-09-16
CZ9603511A3 (en) 2001-11-14
HUT77901A (en) 1998-09-28
JPH10501308A (en) 1998-02-03

Similar Documents

Publication Publication Date Title
CA2191309C (en) Multiple layer papermaking belt providing improved fiber support for cellulosic fibrous structures, and cellulosic fibrous structures produced thereby
CA2191308C (en) Multiple layer, multiple opacity backside textured belt and method of making the same
EP0851060B1 (en) Papermaking apparatus having semicontinuous pattern
CA2142930C (en) Triple layer papermaking fabric providing improved fiber support
US4633596A (en) Paper machine clothing
EP1196656B1 (en) Patterned paper and papermaking belt for making such paper
CA2263168C (en) Papermaking belt having bilaterally alternating tie yarns
EP1015684B1 (en) Multiple layer foraminous belts with fugitive tie yarns
KR20050086505A (en) Multi-layered forming fabric with a top layer of twinned wefts and an extra middle layer of wefts
KR100231620B1 (en) Multiple layer, multiple opacity backside textured belt and method of making the same
CA2206750C (en) Papermaking belt having semicontinuous pattern and paper made thereon
MXPA00002798A (en) Multiple layer foraminous belts with fugitive tie yarns

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20150525