CA2224558A1 - Automatic dishwashing compositions comprising cobalt catalysts - Google Patents

Automatic dishwashing compositions comprising cobalt catalysts

Info

Publication number
CA2224558A1
CA2224558A1 CA002224558A CA2224558A CA2224558A1 CA 2224558 A1 CA2224558 A1 CA 2224558A1 CA 002224558 A CA002224558 A CA 002224558A CA 2224558 A CA2224558 A CA 2224558A CA 2224558 A1 CA2224558 A1 CA 2224558A1
Authority
CA
Canada
Prior art keywords
cobalt
automatic dishwashing
cobalt catalysts
catalysts
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002224558A
Other languages
French (fr)
Other versions
CA2224558C (en
Inventor
William Michael Scheper
Christopher Mark Perkins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
The Procter & Gamble Company
William Michael Scheper
Christopher Mark Perkins
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27050452&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2224558(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by The Procter & Gamble Company, William Michael Scheper, Christopher Mark Perkins filed Critical The Procter & Gamble Company
Publication of CA2224558A1 publication Critical patent/CA2224558A1/en
Application granted granted Critical
Publication of CA2224558C publication Critical patent/CA2224558C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes

Abstract

Automatic dishwashing detergent compositions comprising certain cobalt catalysts are provided. More specifically, the invention relates to automatic dishwashing detergents which provide enhanced cleaning/bleaching benefits (especially tea stain removal) through the selection of cobalt bleach catalyst having the formula: [Co(NH3)n(M)m(B)b]Ty, wherein cobalt is in the +3 oxidation state; n is 4 or 5 (preferably 5); M is one or more ligands coordinated to the cobalt by one site; m is 0, 1 or 2 (preferably 1), B is a ligand coordinated to the cobalt by two sites; b is 0 or 1 (preferably 0), and when b = 0, then m + n = 6, and when b - 1, then m = O and n = 4; and T is one or more appropriately selected counteranions present in a number y, where y is an integer to obtain a charge-balance salt (preferably y is 1 to 3; most preferably 2 when T is a -1 charged anion); and wherein further sait catalyst has a base hydrolysis rate constant of less than 0.23 M-1 s-1 (25 °C). Preferred automatic dishwashing compositions comprise amylase and/or protease enzymes. Included are methods for washing tableware in domestic automatic dishwashing appliances using the cobalt catalysts.
CA002224558A 1995-06-16 1996-05-17 Automatic dishwashing compositions comprising cobalt catalysts Expired - Fee Related CA2224558C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US49146295A 1995-06-16 1995-06-16
US50819395A 1995-07-27 1995-07-27
US08/508,193 1995-07-27
US08/491,462 1995-07-27
PCT/US1996/007129 WO1997000312A1 (en) 1995-06-16 1996-05-17 Automatic dishwashing compositions comprising cobalt catalysts

Publications (2)

Publication Number Publication Date
CA2224558A1 true CA2224558A1 (en) 1997-01-03
CA2224558C CA2224558C (en) 2003-07-15

Family

ID=27050452

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002224558A Expired - Fee Related CA2224558C (en) 1995-06-16 1996-05-17 Automatic dishwashing compositions comprising cobalt catalysts

Country Status (12)

Country Link
US (2) US5705464A (en)
EP (1) EP0832176B1 (en)
JP (1) JP4592832B2 (en)
CN (1) CN1192774A (en)
AT (1) ATE203051T1 (en)
AU (1) AU5862396A (en)
BR (1) BR9609284A (en)
CA (1) CA2224558C (en)
DE (1) DE69613842T2 (en)
ES (1) ES2158320T3 (en)
TR (1) TR199701633T1 (en)
WO (1) WO1997000312A1 (en)

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US5705464A (en) 1998-01-06
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JP4592832B2 (en) 2010-12-08
AU5862396A (en) 1997-01-15

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