CA2268834A1 - Impact-modified thermoplastic polyolefins and articles fabricated therefrom - Google Patents

Impact-modified thermoplastic polyolefins and articles fabricated therefrom

Info

Publication number
CA2268834A1
CA2268834A1 CA002268834A CA2268834A CA2268834A1 CA 2268834 A1 CA2268834 A1 CA 2268834A1 CA 002268834 A CA002268834 A CA 002268834A CA 2268834 A CA2268834 A CA 2268834A CA 2268834 A1 CA2268834 A1 CA 2268834A1
Authority
CA
Canada
Prior art keywords
thermoplastic
compositions
impact modifier
improved
impact
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002268834A
Other languages
French (fr)
Other versions
CA2268834C (en
Inventor
Kalyan Sehanobish
Shaofu Wu
Larry A. Meiske
Pak-Wing S. Chum
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
The Dow Chemical Company
Kalyan Sehanobish
Shaofu Wu
Larry A. Meiske
Pak-Wing S. Chum
Dow Global Technologies Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company, Kalyan Sehanobish, Shaofu Wu, Larry A. Meiske, Pak-Wing S. Chum, Dow Global Technologies Inc. filed Critical The Dow Chemical Company
Publication of CA2268834A1 publication Critical patent/CA2268834A1/en
Application granted granted Critical
Publication of CA2268834C publication Critical patent/CA2268834C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]

Abstract

Melt processible thermoplastic compositions and method for making them are described, these compositions comprising a thermoplastic polymer resin matrix selected from the group consisting of thermoplastic polyurethanes, polyvinyl chlorides, styrenics, engineering thermoplastics, and polyolefins, at least 25 percent (by weight based on the total composition) of an elastomeric impact modifier dispersed as discrete particles in the thermoplastic matrix (a); and at least 10 percent (by weight based on the total composition) of at least one homogeneous linear or substantially linear ethylene polymer dispersed as discrete particles in at least the impact modifier (b), the ethylene polymer having a molecular weight distribution less than 3.5 and a density of at least 0.04 g/cm3 higher than the density of the impact modifier component (b), wherein the elastic modulus of the thermoplastic component (a) is at least 200 times greater than the elastic modulus of the impact modifier component (b). These thermoplastic compositions have improved processability. Processes for fabricating articles from them are described. The articles made with these compositions have improved properties such as low temperature impact strength, improved percent elongation to break, greater stiffness, and improved weld line strength, making them useful for applications requiring both strength and flexibility in low temperature environments, such as automotive components and facia.
CA002268834A 1996-10-31 1997-10-01 Impact-modified thermoplastic polyolefins and articles fabricated therefrom Expired - Fee Related CA2268834C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/741,648 US5861463A (en) 1996-10-31 1996-10-31 Impact-modified thermoplastic polyolefins and articles fabricated therefrom
US08/741,648 1996-10-31
PCT/US1997/017848 WO1998018865A1 (en) 1996-10-31 1997-10-01 Impact-modified thermoplastic polyolefins and articles fabricated therefrom

Publications (2)

Publication Number Publication Date
CA2268834A1 true CA2268834A1 (en) 1998-05-07
CA2268834C CA2268834C (en) 2008-07-08

Family

ID=24981592

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002268834A Expired - Fee Related CA2268834C (en) 1996-10-31 1997-10-01 Impact-modified thermoplastic polyolefins and articles fabricated therefrom

Country Status (14)

Country Link
US (2) US5861463A (en)
EP (1) EP0935639B1 (en)
JP (1) JP2001503096A (en)
KR (1) KR100507456B1 (en)
AR (1) AR013620A1 (en)
AT (1) ATE232226T1 (en)
AU (1) AU4666797A (en)
BR (1) BR9712604A (en)
CA (1) CA2268834C (en)
DE (1) DE69718926T2 (en)
ES (1) ES2187829T3 (en)
TW (1) TW517072B (en)
WO (1) WO1998018865A1 (en)
ZA (1) ZA979769B (en)

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JP5062854B2 (en) * 2005-12-27 2012-10-31 ポリワン コーポレイション Polyhalogenated vinyl-uncrosslinked elastomer alloy
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JP5620998B2 (en) * 2009-11-25 2014-11-05 ダウ グローバル テクノロジーズ エルエルシー Polymer molded product with low haze and high transparency
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Also Published As

Publication number Publication date
US6140420A (en) 2000-10-31
EP0935639B1 (en) 2003-02-05
KR20000052833A (en) 2000-08-25
JP2001503096A (en) 2001-03-06
EP0935639A1 (en) 1999-08-18
AU4666797A (en) 1998-05-22
CA2268834C (en) 2008-07-08
ZA979769B (en) 1999-04-30
DE69718926D1 (en) 2003-03-13
DE69718926T2 (en) 2003-11-13
ATE232226T1 (en) 2003-02-15
US5861463A (en) 1999-01-19
TW517072B (en) 2003-01-11
KR100507456B1 (en) 2005-08-10
WO1998018865A1 (en) 1998-05-07
BR9712604A (en) 1999-10-26
AR013620A1 (en) 2001-01-10
ES2187829T3 (en) 2003-06-16

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