CA2319145A1 - Raffinate hydroconversion process - Google Patents

Raffinate hydroconversion process Download PDF

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Publication number
CA2319145A1
CA2319145A1 CA002319145A CA2319145A CA2319145A1 CA 2319145 A1 CA2319145 A1 CA 2319145A1 CA 002319145 A CA002319145 A CA 002319145A CA 2319145 A CA2319145 A CA 2319145A CA 2319145 A1 CA2319145 A1 CA 2319145A1
Authority
CA
Canada
Prior art keywords
raffinate
followed
hydroconversion process
hydroconversion
dewaxed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002319145A
Other languages
French (fr)
Other versions
CA2319145C (en
Inventor
Ian Alfred Cody
Douglas Raymond Boate
William John Murphy
Daniel Paul Leta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2319145A1 publication Critical patent/CA2319145A1/en
Application granted granted Critical
Publication of CA2319145C publication Critical patent/CA2319145C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/043Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a change in the structural skeleton
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • C10G65/08Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a hydrogenation of the aromatic hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/04Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
    • C10G67/0409Extraction of unsaturated hydrocarbons
    • C10G67/0418The hydrotreatment being a hydrorefining
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10Lubricating oil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

A process for producing a high VI/low volatility lubricating oil basestock.
The process comprises subjecting the raffinate from a solvent extraction step (40) to a two-step, single-stage hydroconversion process wherein the first step involves severe hydroconversion of the raffinate (42) followed by a cold hydrofinishing step (50). The effluent from the cold hydrofinishing step (52) in then catalytically dewaxed or in the alternative, solvent dewaxed followed by catalytic dewaxing (60).
CA002319145A 1998-02-13 1999-02-12 Raffinate hydroconversion process Expired - Fee Related CA2319145C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/023,438 US5935416A (en) 1996-06-28 1998-02-13 Raffinate hydroconversion process
US09/023,438 1998-02-13
PCT/US1999/003109 WO1999041338A1 (en) 1998-02-13 1999-02-12 Raffinate hydroconversion process

Publications (2)

Publication Number Publication Date
CA2319145A1 true CA2319145A1 (en) 1999-08-19
CA2319145C CA2319145C (en) 2007-10-09

Family

ID=21815106

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002319145A Expired - Fee Related CA2319145C (en) 1998-02-13 1999-02-12 Raffinate hydroconversion process

Country Status (7)

Country Link
US (1) US5935416A (en)
EP (1) EP1054940A4 (en)
JP (1) JP2002503757A (en)
KR (1) KR100592145B1 (en)
AU (1) AU743100B2 (en)
CA (1) CA2319145C (en)
WO (1) WO1999041338A1 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6592748B2 (en) * 1996-06-28 2003-07-15 Exxonmobil Research And Engineering Company Reffinate hydroconversion process
US6974535B2 (en) 1996-12-17 2005-12-13 Exxonmobil Research And Engineering Company Hydroconversion process for making lubricating oil basestockes
US7569136B2 (en) 1997-06-24 2009-08-04 Ackerson Michael D Control system method and apparatus for two phase hydroprocessing
US7291257B2 (en) * 1997-06-24 2007-11-06 Process Dynamics, Inc. Two phase hydroprocessing
DE69825590T2 (en) * 1997-06-24 2005-09-15 Process Dynamics, Inc., Fayetteville Two-phase hydroprocessing method
US6333298B1 (en) * 1999-07-16 2001-12-25 Infineum International Limited Molybdenum-free low volatility lubricating oil composition
US6416655B1 (en) * 1999-07-23 2002-07-09 Exxonmobil Research And Engineering Company Selective extraction using mixed solvent system
FR2797883B1 (en) * 1999-08-24 2004-12-17 Inst Francais Du Petrole PROCESS FOR PRODUCING OILS WITH A HIGH VISCOSITY INDEX
WO2002006427A1 (en) * 2000-07-17 2002-01-24 Shell Internationale Research Maatschappij B.V. Process to prepare water-white lubricant base oil
RU2278147C2 (en) * 2001-04-19 2006-06-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Method of production of the base oil with the high content of the saturated hydrocarbons
CN100457862C (en) * 2004-10-29 2009-02-04 中国石油化工股份有限公司 One-step hydrogenation method for producing super white oil
US7851418B2 (en) 2005-06-03 2010-12-14 Exxonmobil Research And Engineering Company Ashless detergents and formulated lubricating oil containing same
US20070093398A1 (en) 2005-10-21 2007-04-26 Habeeb Jacob J Two-stroke lubricating oils
US8299005B2 (en) 2006-05-09 2012-10-30 Exxonmobil Research And Engineering Company Lubricating oil composition
US7863229B2 (en) 2006-06-23 2011-01-04 Exxonmobil Research And Engineering Company Lubricating compositions
CN102021034B (en) * 2009-09-15 2013-12-04 中国石油天然气股份有限公司 Method for preparing white micro-crystalline wax
WO2012100068A2 (en) 2011-01-19 2012-07-26 Process Dynamics, Inc. Process for hydroprocessing of non-petroleum feestocks
WO2013019512A1 (en) 2011-07-29 2013-02-07 Saudi Arabian Oil Company Integrated selective hydrocracking and fluid catalytic cracking process
US10557092B2 (en) 2016-08-03 2020-02-11 Exxonmobil Research And Engineering Company Raffinate hydroconversion for production of high performance base stocks

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3732154A (en) * 1969-02-19 1973-05-08 Sun Oil Co Catalytic hydrofinishing of lube oil product of solvent extraction of petroleum distillate
US3691067A (en) * 1970-03-04 1972-09-12 Texaco Inc Production of lubricating oils by hydrotreating and distillation
US3779896A (en) * 1971-08-04 1973-12-18 Texaco Inc Lube oil manufacture
US4437975A (en) * 1977-07-20 1984-03-20 Mobil Oil Corporation Manufacture of lube base stock oil
US4211635A (en) * 1979-04-23 1980-07-08 Mobil Oil Corporation Catalytic conversion of hydrocarbons
US4229282A (en) * 1979-04-27 1980-10-21 Mobil Oil Corporation Catalytic dewaxing of hydrocarbon oils
US4383913A (en) * 1981-10-09 1983-05-17 Chevron Research Company Hydrocracking to produce lube oil base stocks
US4610778A (en) * 1983-04-01 1986-09-09 Mobil Oil Corporation Two-stage hydrocarbon dewaxing process
US4636299A (en) * 1984-12-24 1987-01-13 Standard Oil Company (Indiana) Process for the manufacture of lubricating oils
US4952303A (en) * 1985-07-10 1990-08-28 Mobil Oil Corp. Process for preparing a very high quality lube base stock oil
US4627908A (en) * 1985-10-24 1986-12-09 Chevron Research Company Process for stabilizing lube base stocks derived from bright stock
US5013422A (en) * 1986-07-29 1991-05-07 Mobil Oil Corp. Catalytic hydrocracking process
GB8629476D0 (en) * 1986-12-10 1987-01-21 Shell Int Research Manufacture of lubricating base oils
FR2626005A1 (en) * 1988-01-14 1989-07-21 Shell Int Research PROCESS FOR PREPARING A BASIC LUBRICATING OIL
CA2047923C (en) * 1990-08-14 2002-11-19 Heather A. Boucher Hydrotreating heavy hydroisomerate fractionator bottoms to produce quality light oil upon subsequent refractionation
US5273645A (en) * 1991-09-17 1993-12-28 Amoco Corporation Manufacture of lubricating oils
US5292426A (en) * 1991-10-18 1994-03-08 Texaco Inc. Wax conversion process
US5393408A (en) * 1992-04-30 1995-02-28 Chevron Research And Technology Company Process for the stabilization of lubricating oil base stocks
US5300213A (en) * 1992-11-30 1994-04-05 Mobil Oil Corporation Process for making basestocks for automatic transmission fluids
US5302279A (en) * 1992-12-23 1994-04-12 Mobil Oil Corporation Lubricant production by hydroisomerization of solvent extracted feedstocks
FR2711667B1 (en) * 1993-10-25 1996-02-02 Inst Francais Du Petrole Process for the improved production of middle distillates together with the production of oils having high viscosity indices and viscosities, from heavy petroleum fractions.
US5976353A (en) * 1996-06-28 1999-11-02 Exxon Research And Engineering Co Raffinate hydroconversion process (JHT-9601)

Also Published As

Publication number Publication date
KR20010089108A (en) 2001-09-29
EP1054940A1 (en) 2000-11-29
US5935416A (en) 1999-08-10
WO1999041338A1 (en) 1999-08-19
JP2002503757A (en) 2002-02-05
AU743100B2 (en) 2002-01-17
EP1054940A4 (en) 2005-02-09
AU2676699A (en) 1999-08-30
CA2319145C (en) 2007-10-09
KR100592145B1 (en) 2006-06-23

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Effective date: 20140212