CA2321709A1 - Solid acid catalyst, method for producing the same and reaction method using the same - Google Patents

Solid acid catalyst, method for producing the same and reaction method using the same Download PDF

Info

Publication number
CA2321709A1
CA2321709A1 CA002321709A CA2321709A CA2321709A1 CA 2321709 A1 CA2321709 A1 CA 2321709A1 CA 002321709 A CA002321709 A CA 002321709A CA 2321709 A CA2321709 A CA 2321709A CA 2321709 A1 CA2321709 A1 CA 2321709A1
Authority
CA
Canada
Prior art keywords
same
acid catalyst
solid acid
support
zirconia
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002321709A
Other languages
French (fr)
Other versions
CA2321709C (en
Inventor
Kenji Matsuzawa
Kohjiroh Aimoto
Kazuhiro Seki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eneos Corp
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2321709A1 publication Critical patent/CA2321709A1/en
Application granted granted Critical
Publication of CA2321709C publication Critical patent/CA2321709C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B01J35/657—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/2206—Catalytic processes not covered by C07C5/23 - C07C5/31
    • C07C5/2213—Catalytic processes not covered by C07C5/23 - C07C5/31 with metal oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767—Changing the number of side-chains
    • C07C5/277—Catalytic processes
    • C07C5/2791—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00—Aliphatic saturated hydrocarbons
    • C07C9/14—Aliphatic saturated hydrocarbons with five to fifteen carbon atoms
    • C07C9/16—Branched-chain hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A method for producing a solid acid catalyst is provided which produces a shaped material of a solid acid catalyst containing a sulfureous component but have a high activity and having a practically sufficient handleability and mechanical strength.
The method comprises (a) fabricating a support comprising a portion of zirconia and/or hydrated zirconia and a portion of alumina and/or hydrated alumina and having a peak in diameter in the range of 0.05 to 1 µm in a pore diameter distribution of 0.05 to 10 µm; and having a sulfureous component supported on the support or (b) fabricating a support comprising a portion of zirconia and/or hydrated zirconia and a portion of alumina and/or hydrated alumina and including pores having a pore diameter of not less than 0.05 µm and not more than 1 µm occupy a pore volume of 0.05 to 0.5 ml/g and pores having a pore diameter of above 1 µm and not more than 10 µm occupy a pore volume of below 0.05 ml/g; and having a sulfureous component supported on the support.
CA002321709A 1998-03-04 1999-02-26 Solid acid catalyst, method for producing the same and reaction method using the same Expired - Lifetime CA2321709C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP6761498 1998-03-04
JP10-067614 1998-03-04
PCT/JP1999/000922 WO1999044738A1 (en) 1998-03-04 1999-02-26 Solid acid catalyst, method for preparing the same and reaction using the same

Publications (2)

Publication Number Publication Date
CA2321709A1 true CA2321709A1 (en) 1999-09-10
CA2321709C CA2321709C (en) 2004-01-27

Family

ID=13350025

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002321709A Expired - Lifetime CA2321709C (en) 1998-03-04 1999-02-26 Solid acid catalyst, method for producing the same and reaction method using the same

Country Status (12)

Country Link
US (1) US6420305B1 (en)
EP (1) EP1060791B1 (en)
JP (1) JP3553878B2 (en)
KR (1) KR100388310B1 (en)
CN (1) CN1131105C (en)
AT (1) ATE269756T1 (en)
CA (1) CA2321709C (en)
DE (1) DE69918274T2 (en)
DK (1) DK1060791T3 (en)
ES (1) ES2223164T3 (en)
RU (1) RU2190465C2 (en)
WO (1) WO1999044738A1 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7132582B2 (en) * 2003-05-30 2006-11-07 Council Of Scientific And Industrial Research Catalytic process for the preparation of isolongifolene
US6737380B2 (en) * 2001-02-05 2004-05-18 Petroleum Energy Center Solid acid catalyst, production method thereof, and method for hydrodesulfurizing and isomerizing light hydrocarbon oil using the same
US7026268B2 (en) * 2001-03-02 2006-04-11 Japan Energy Corporation Solid acid catalyst containing platinum group metal component and method for preparation thereof
GB0121871D0 (en) * 2001-09-11 2001-10-31 Bp Plc Hydrogen production
CN1193824C (en) * 2001-10-19 2005-03-23 松下电器产业株式会社 Purified catalyst, its preparing method and gas purifying apparatus
US20050124745A1 (en) * 2002-04-19 2005-06-09 Saint-Gobain Ceramics & Plastics, Inc. Flame retardant composites
JP4646684B2 (en) * 2005-04-18 2011-03-09 株式会社日本触媒 Gas phase oxidation catalyst and method for producing acrylic acid using the same
US8460768B2 (en) * 2008-12-17 2013-06-11 Saint-Gobain Ceramics & Plastics, Inc. Applications of shaped nano alumina hydrate in inkjet paper
JP5552306B2 (en) * 2009-02-24 2014-07-16 花王株式会社 Method for producing ether compound
CN101781223B (en) * 2009-12-25 2013-01-23 华东师范大学 Method for catalytically synthesizing aminated compounds by using carbon-silicon solid acid as catalysts
US9592498B2 (en) * 2010-11-16 2017-03-14 Rhodia Operations Porous inorganic composite oxide
CN102553659B (en) * 2010-12-30 2014-05-28 中国石油化工股份有限公司 Regeneration method of solid super acidic catalyst
CN102649093B (en) * 2011-02-24 2014-05-28 中国石油化工股份有限公司 Pretreatment method for solid super acidic catalyst
WO2014210605A2 (en) * 2013-06-28 2014-12-31 Autonomic Technologies, Inc. Implantable medical device and method for laser processing
US10384196B2 (en) * 2014-12-26 2019-08-20 Kellogg Brown & Root Llc Highly selective catalyst and method of isomerization of C4—C7 paraffin hydrocarbons
JP7444894B2 (en) 2019-01-25 2024-03-06 中国石油化工股▲ふん▼有限公司 Solid acid catalyst, its production, and its use

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3032599A (en) 1958-05-05 1962-05-01 Phillips Petroleum Co Sulfate-treated zirconia-gel catalyst
JPS596181A (en) 1982-07-02 1984-01-13 Mitsubishi Motors Corp Carry-in device of seat
DE3586228D1 (en) 1984-09-10 1992-07-23 Light Oil Utilization Res Ass SOLID STRONG ACID CATALYST.
JPS61254250A (en) * 1985-05-02 1986-11-12 Cataler Kogyo Kk Preparation of catalyst carrier
FR2611739B1 (en) 1987-03-06 1989-07-07 Inst Francais Du Petrole METHOD FOR ACTIVATION OF A CATALYST FOR ISOMERIZATION OF NORMAL PARAFFINS
JP2610490B2 (en) * 1988-09-08 1997-05-14 コスモ石油株式会社 Solid acid catalyst for alkylation reaction
US5365010A (en) * 1990-09-26 1994-11-15 Catalytica, Inc. Method for regenerating Lewis acid-promoted transition alumina catalysts used for isoparaffin alkylation by calcination
JP3157541B2 (en) 1991-06-21 2001-04-16 日本電気株式会社 Semiconductor package with heat sink
JPH0529505A (en) 1991-07-23 1993-02-05 Sansha Electric Mfg Co Ltd Radiator and electric power control apparatus
JP2768063B2 (en) 1991-07-24 1998-06-25 松下電器産業株式会社 Radiator
JPH0529506A (en) 1991-07-25 1993-02-05 Nec Corp Semiconductor device
JP3251313B2 (en) 1991-10-03 2002-01-28 株式会社ジャパンエナジー Method for producing alumina-based solid acid catalyst
JPH0938494A (en) * 1995-07-28 1997-02-10 Sekiyu Sangyo Kasseika Center Catalyst compacting method using alumina as binder
WO1998009727A1 (en) 1996-09-05 1998-03-12 Japan Energy Corporation Solid acid catalyst and process for preparing the same

Also Published As

Publication number Publication date
EP1060791A4 (en) 2001-07-18
DK1060791T3 (en) 2004-10-18
KR20010041474A (en) 2001-05-25
RU2190465C2 (en) 2002-10-10
WO1999044738A1 (en) 1999-09-10
JP3553878B2 (en) 2004-08-11
US6420305B1 (en) 2002-07-16
KR100388310B1 (en) 2003-06-25
CN1291914A (en) 2001-04-18
DE69918274T2 (en) 2005-07-07
DE69918274D1 (en) 2004-07-29
ES2223164T3 (en) 2005-02-16
CN1131105C (en) 2003-12-17
CA2321709C (en) 2004-01-27
EP1060791A1 (en) 2000-12-20
EP1060791B1 (en) 2004-06-23
ATE269756T1 (en) 2004-07-15

Similar Documents

Publication Publication Date Title
CA2321709A1 (en) Solid acid catalyst, method for producing the same and reaction method using the same
CA2207527A1 (en) Method of producing a chemical compound
CA2510100A1 (en) High activity gamma alumina catalysts
AU599098B2 (en) Porous anodic aluminium oxide membrane catalyst support
AU3791095A (en) Sol-gel process for obtaining pure and mixed oxide zirconia spheres, microspheres and washcoats, useful as catalysts or catalyst supports
AU7261098A (en) Process for making surface modified porous membrane with perfluorocarbon copolymer
WO2001091873A3 (en) Polysulfonamide matrices
AU3030997A (en) Oxidation catalyst and process for the production of epoxides from olefines, hydrogen and oxygen using said oxidation catalyst
WO2002026351A1 (en) Catalyst-carrying filter
CA2204431A1 (en) Method for making supported catalyst systems, and catalyst systems therefrom
WO2002016259A3 (en) Catalytic oxidation process
EP0896566A4 (en) Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them
AU6748294A (en) Surface impregnated catalyst, process for the production thereof, and use thereof for the preparation of vinyl acetate
CA2320485A1 (en) Catalyst for hydrofining and method for preparation thereof
CA2146399A1 (en) Bearing Material of Porous SiC Having a Trimodal Pore Composition
CA2012990A1 (en) Porous solid phosphoric acid catalyst system and process using same
FR2632874B1 (en)
WO2000022011A3 (en) Supported polymerization catalysts
CA2306788A1 (en) A process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals
AU3098095A (en) Low macropore resid conversion catalyst
AU3597399A (en) Supported catalyst containing pseudo-boehmite and gamma-Al2O3, production of same and its use for producing 1,2-dichloroethane
WO2001052985A3 (en) Gel catalysts and methods for their use in catalytic dehydrogenation processes
HUP9601489A2 (en) High activity catalytic system for the synthesis of poly (ethyleneterephthalate), polyethyleneterephthalate produced thereby and the use thereof
AU1732600A (en) Catalyst of a heteropoly acid salt on a non-metallic porous support and process for preparation thereof
ES2145700A1 (en) Titanium-containing solid catalyst

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry

Effective date: 20190226