CA2332991A1 - Shower cleaning composition comprising a glycoside surfactant - Google Patents
Shower cleaning composition comprising a glycoside surfactant Download PDFInfo
- Publication number
- CA2332991A1 CA2332991A1 CA002332991A CA2332991A CA2332991A1 CA 2332991 A1 CA2332991 A1 CA 2332991A1 CA 002332991 A CA002332991 A CA 002332991A CA 2332991 A CA2332991 A CA 2332991A CA 2332991 A1 CA2332991 A1 CA 2332991A1
- Authority
- CA
- Canada
- Prior art keywords
- composition
- chelating agent
- shower
- cleaning
- organic solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract 31
- 239000004094 surface-active agent Substances 0.000 title claims abstract 10
- 238000004140 cleaning Methods 0.000 title claims abstract 9
- 229930182470 glycoside Natural products 0.000 title claims abstract 7
- 150000002338 glycosides Chemical class 0.000 title claims abstract 7
- 239000002738 chelating agent Substances 0.000 claims abstract 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract 6
- 239000002689 soil Substances 0.000 claims abstract 4
- 238000005201 scrubbing Methods 0.000 claims abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000003960 organic solvent Substances 0.000 claims 7
- 238000000034 method Methods 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims 3
- 239000006185 dispersion Substances 0.000 claims 2
- 229920001515 polyalkylene glycol Polymers 0.000 claims 2
- 125000005207 tetraalkylammonium group Chemical group 0.000 claims 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims 1
- OVBJJZOQPCKUOR-UHFFFAOYSA-L EDTA disodium salt dihydrate Chemical group O.O.[Na+].[Na+].[O-]C(=O)C[NH+](CC([O-])=O)CC[NH+](CC([O-])=O)CC([O-])=O OVBJJZOQPCKUOR-UHFFFAOYSA-L 0.000 claims 1
- 102000004190 Enzymes Human genes 0.000 claims 1
- 108090000790 Enzymes Proteins 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
- -1 alkylene glycols Chemical class 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 claims 1
- 239000000872 buffer Substances 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- KYQODXQIAJFKPH-UHFFFAOYSA-N diazanium;2-[2-[bis(carboxymethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical group [NH4+].[NH4+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O KYQODXQIAJFKPH-UHFFFAOYSA-N 0.000 claims 1
- 150000002009 diols Chemical class 0.000 claims 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims 1
- 239000000975 dye Substances 0.000 claims 1
- 238000005187 foaming Methods 0.000 claims 1
- 239000003205 fragrance Substances 0.000 claims 1
- 239000003752 hydrotrope Substances 0.000 claims 1
- HVAAHUDGWQAAOJ-UHFFFAOYSA-N n-benzylethanamine Chemical class CCNCC1=CC=CC=C1 HVAAHUDGWQAAOJ-UHFFFAOYSA-N 0.000 claims 1
- 239000002304 perfume Substances 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- JZBRFIUYUGTUGG-UHFFFAOYSA-J tetrapotassium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical group [K+].[K+].[K+].[K+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O JZBRFIUYUGTUGG-UHFFFAOYSA-J 0.000 claims 1
- 239000002562 thickening agent Substances 0.000 claims 1
- 238000009736 wetting Methods 0.000 claims 1
- 239000000344 soap Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C11D2111/14—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
Abstract
An improved cleaning composition is provided for shower and tub surfaces which is of the "shower rinsing" type, requiring no scrubbing, wiping, or immediate rinsing. The composition comprises: (a) a glycoside surfactant, the total amount of said surfactant being present in a cleaning effective amount; (b) a chelating agent, said chelating agent present in an amount effective to enhance bathroom soil removal in said composition; and (c) the remainder, water. A solvent such as isopropyl alcohol may also be added. The employment of a glycoside surfactant, especially one having an HLB value of greater than 13, remarkably improves the performance of such a shower rinsing composition both with respect to surface appearance streaking and filming and also bathroom soil and soap scum removing ability.
Claims (20)
1. A cleaning composition for shower and tub surfaces of the type which requires no scrubbing, wiping or immediate rinsing, comprising:
(a) a glycoside surfactant, the total amount of said surfactant being present in a cleaning effective amount;
(b) a chelating agent, said chelating agent present in an amount effective to enhance bathroom soil removal in said composition; and (c) the remainder, water, said cleaning composition characterized by the ability to clean said shower and tub surfaces without streaking or filming.
(a) a glycoside surfactant, the total amount of said surfactant being present in a cleaning effective amount;
(b) a chelating agent, said chelating agent present in an amount effective to enhance bathroom soil removal in said composition; and (c) the remainder, water, said cleaning composition characterized by the ability to clean said shower and tub surfaces without streaking or filming.
2. The composition of Claim 1 further comprising at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25°C, said at least one organic solvent present in a solubilizing- or dispersion-effective amount.
3. The composition of Claim 2 wherein the organic solvent is selected from the group consisting of alkanols, diols, polyalkylene glycols, alkyl ethers of alkylene glycols and polyalkylene glycols, and mixtures thereof.
4. The composition of Claim 3 wherein the organic solvent is isopropyl alcohol.
5. The composition of Claim 1 wherein said composition has a pH of about 5.
6. The composition of Claim 5 wherein said chelating agent is diammonium EDTA.
7. The composition of Claim 5 wherein said chelating agent is disodium EDTA.
8. The composition of Claim 1 wherein said composition has a pH greater than 8.
9. The composition of Claim 8 wherein said composition has a pH of about 12.
10. The composition of Claim 9 wherein said chelating agent is tetrapotassium EDTA.
11. The composition of Claim 1 wherein said glycoside surfactant is an alkyl polyglycoside.
12. The composition of Claim 11 wherein said alkyl polyglycoside has an HLB of greater than 13.
13. The composition of Claim 1 further comprising a quaternary ammonium compound.
14. The composition of Claim 13 wherein the quaternary ammonium compound is selected from the group consisting of mono-long-chain, tri-short chain, tetraalkyl ammonium compounds, di-long-chain, di-short-chain;
tetraalkyl ammonium compounds, trialkyl, mono-benzyl or mono-ethylbenzyl ammonium compounds, and mixtures thereof.
tetraalkyl ammonium compounds, trialkyl, mono-benzyl or mono-ethylbenzyl ammonium compounds, and mixtures thereof.
15. The composition of claim 1 further comprising at least one adjunct selected from the group consisting of builders, buffers, fragrances, perfumes, thickeners, dyes, colorants, pigments, foaming stabilizers, water-insoluble organic solvents, hydrotropes, enzymes, and bleaching agents.
16. A method for cleaning shower and tub surfaces, comprising the steps of:
wetting surfaces of a shower;
applying to the wet shower surfaces after showering with a cleaning composition comprising:
(a) a glycoside surfactant; the total amount of said surfactant being present in a cleaning effective amount;
(b) a chelating agent, said chelating agent present in an amount effective to enhance bathroom soil removal in said composition; and (c) the remainder, water, whereby the shower surfaces are cleaned without the need for scrubbing, wiping, or immediate rinsing, and are free from streaking and filming.
wetting surfaces of a shower;
applying to the wet shower surfaces after showering with a cleaning composition comprising:
(a) a glycoside surfactant; the total amount of said surfactant being present in a cleaning effective amount;
(b) a chelating agent, said chelating agent present in an amount effective to enhance bathroom soil removal in said composition; and (c) the remainder, water, whereby the shower surfaces are cleaned without the need for scrubbing, wiping, or immediate rinsing, and are free from streaking and filming.
17. The method of Claim 16 wherein said composition further comprises at least one water-soluble or dispersible organic solvent having a vapor pressure of at least 0.001 mm Hg at 25°C, said at least one organic solvent present in a solubilizing- or dispersion-effective amount.
18. The method of Claim 16 wherein said glycoside surfactant is an alkyl polyglycoside.
19. The method of Claim 16 wherein said alkyl polyglycoside has an HLB of greater than 13.
20. The method of Claim 16 wherein said composition further comprises a quaternary ammonium compound.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/096,628 | 1998-06-12 | ||
| US09/096,628 US6159916A (en) | 1998-06-12 | 1998-06-12 | Shower rinsing composition |
| PCT/US1999/012223 WO1999064548A1 (en) | 1998-06-12 | 1999-06-02 | Shower rinsing composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2332991A1 true CA2332991A1 (en) | 1999-12-16 |
| CA2332991C CA2332991C (en) | 2009-12-08 |
Family
ID=22258298
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002332991A Expired - Fee Related CA2332991C (en) | 1998-06-12 | 1999-06-02 | Shower cleaning composition comprising a glycoside surfactant |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US6159916A (en) |
| EP (1) | EP1086196A4 (en) |
| JP (1) | JP2002517602A (en) |
| KR (1) | KR20010072610A (en) |
| AR (1) | AR019647A1 (en) |
| AU (1) | AU765589B2 (en) |
| CA (1) | CA2332991C (en) |
| CO (1) | CO5050402A1 (en) |
| WO (1) | WO1999064548A1 (en) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6159916A (en) * | 1998-06-12 | 2000-12-12 | The Clorox Company | Shower rinsing composition |
| AU1106200A (en) * | 1998-10-16 | 2000-05-08 | S.C. Johnson & Son, Inc. | Scrub free formulation for cleaning surfaces |
| GB9911818D0 (en) † | 1999-05-21 | 1999-07-21 | Reckitt & Colman Inc | Improvements in or relating to organic compositions |
| US6350727B1 (en) | 2000-01-28 | 2002-02-26 | Amway Corporation | Non-streaking no-wipe cleaning compositions with improved cleaning capability |
| US6387871B2 (en) | 2000-04-14 | 2002-05-14 | Alticor Inc. | Hard surface cleaner containing an alkyl polyglycoside |
| MXPA02010678A (en) * | 2000-05-02 | 2003-03-10 | Unilever Nv | Composition and process for cleaning floors. |
| GB0013501D0 (en) * | 2000-06-02 | 2000-07-26 | Unilever Plc | Detergent compositions |
| AUPQ984400A0 (en) * | 2000-09-01 | 2000-09-28 | Novapharm Research (Australia) Pty Ltd | Surfactant sytem |
| DE60117850T2 (en) * | 2000-12-14 | 2006-11-23 | Ciba Speciality Chemicals Holding Inc. | SURFACE ACTIVE COMPOSITIONS |
| US7511006B2 (en) * | 2000-12-14 | 2009-03-31 | The Clorox Company | Low residue cleaning solution comprising a C8 to C10 alkylpolyglucoside and glycerol |
| US6821943B2 (en) * | 2001-03-13 | 2004-11-23 | S. C. Johnson & Son, Inc. | Hard surface antimicrobial cleaner with residual antimicrobial effect comprising an organosilane |
| US6395698B1 (en) * | 2001-06-11 | 2002-05-28 | Mason Chemical Company | Corrosion resistant sanitizing/disinfecting cleaning and wood preservative formulation |
| GB2381531A (en) * | 2001-11-02 | 2003-05-07 | Reckitt Benckiser Inc | Hard surface cleaning and disinfecting compositions |
| US6732744B2 (en) * | 2001-12-07 | 2004-05-11 | The Procter & Gamble Company | Method for the ultrasonic treatment of hair and other keratinous fibers |
| US6489280B1 (en) * | 2002-08-26 | 2002-12-03 | Colgate-Palmolive Co. | Light duty liquid cleaning compositions having improved preservative system |
| US6562773B1 (en) * | 2002-08-26 | 2003-05-13 | Colgate-Palmolive Company | Light duty liquid cleaning compositions having improved preservative system |
| US6953617B2 (en) * | 2003-05-14 | 2005-10-11 | Applied Extrusion Technologies, Inc. | High OTR films made from homopolymer polypropylene and 1-butene/ethylene copolymer blends |
| US20050065055A1 (en) * | 2003-09-19 | 2005-03-24 | Jerry Barnes | Aqueous cleaning composition for hard surfaces |
| EP1586627A1 (en) * | 2004-03-25 | 2005-10-19 | The Procter & Gamble Company | Method of removing soap-scum from hard surfaces |
| PL1988986T3 (en) * | 2006-02-22 | 2010-05-31 | Basf Se | Surfactant mixture containing short-chain and also long-chain components |
| EP2039747A1 (en) | 2007-09-17 | 2009-03-25 | The Procter and Gamble Company | Process for treating hard surface |
| EP2039748A1 (en) * | 2007-09-17 | 2009-03-25 | The Procter and Gamble Company | Process of treating inclined hard surface |
| AU2009200259B1 (en) * | 2008-07-30 | 2009-06-18 | Whiteley Corporation Pty Ltd | Biostatic medical cleaning products |
| MX2012005960A (en) | 2009-11-25 | 2012-08-15 | Basf Se | Biodegradable cleaning composition. |
| US8609602B2 (en) * | 2010-07-14 | 2013-12-17 | Anatrace Products, Llc | Cleaning solution |
| US8455551B2 (en) | 2011-03-04 | 2013-06-04 | American Sterilizer Company | Broad spectrum disinfectant |
| US20130176359A1 (en) * | 2012-01-09 | 2013-07-11 | Mark Colby ROBERTS | Print head cleaning composition and method for cleaning print head using same |
| US8648027B2 (en) | 2012-07-06 | 2014-02-11 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising a cationic biocide |
| US10844322B2 (en) | 2012-08-07 | 2020-11-24 | Ecolab Usa Inc. | High flashpoint alcohol-based cleaning, sanitizing and disinfecting composition and method of use on food contact surfaces |
| US9822227B2 (en) | 2014-09-16 | 2017-11-21 | Isola Usa Corp. | High Tg epoxy formulation with good thermal properties |
| US11130933B2 (en) | 2016-01-20 | 2021-09-28 | Rockline Industries, Inc. | Wet wipes containing hydroxy acetophenone and cocamidopropyl PG dimonium chloride phosphate |
| US10433545B2 (en) * | 2016-07-11 | 2019-10-08 | Ecolab Usa Inc. | Non-streaking durable composition for cleaning and disinfecting hard surfaces |
| US11359164B2 (en) * | 2017-03-01 | 2022-06-14 | Rust-Oleum Corporation | Gutter cleaning composition comprising a mixture of three nonionic surfactants |
| CR20230492A (en) | 2021-04-01 | 2023-11-23 | Sterilex LLC | Quat-free powdered disinfectant/sanitizer |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4606850A (en) * | 1985-02-28 | 1986-08-19 | A. E. Staley Manufacturing Company | Hard surface cleaning composition and cleaning method using same |
| US5266690A (en) * | 1991-12-19 | 1993-11-30 | Henkel Corporation | Preparation of alkylpolyglycosides |
| US5424010A (en) * | 1993-01-06 | 1995-06-13 | Duliba; Edward P. | Light duty liquid detergent composition containing 3-methyl-3-methoxy-butanol |
| US5616548A (en) * | 1993-07-14 | 1997-04-01 | Colgate-Palmolive Co. | Stable microemulsion cleaning composition |
| US5536452A (en) * | 1993-12-07 | 1996-07-16 | Black; Robert H. | Aqueous shower rinsing composition and a method for keeping showers clean |
| GB2309706B (en) * | 1996-01-31 | 2000-02-09 | Reckitt & Colman Inc | Liquid detergent composition comprising quaternary ammonium surfactant having germicidal properties |
| US5814590A (en) * | 1996-02-06 | 1998-09-29 | The Procter & Gamble Company | Low streaking and filming hard surface cleaners |
| US5948742A (en) * | 1996-04-12 | 1999-09-07 | The Clorox Company | Aerosol hard surface cleaner with enhanced bathroom soil removal |
| US5948741A (en) * | 1996-04-12 | 1999-09-07 | The Clorox Company | Aerosol hard surface cleaner with enhanced soil removal |
| US5814591A (en) * | 1996-04-12 | 1998-09-29 | The Clorox Company | Hard surface cleaner with enhanced soil removal |
| JP3711176B2 (en) * | 1996-06-21 | 2005-10-26 | 旭電化工業株式会社 | Cleaning composition for hard surface |
| US5837664A (en) * | 1996-07-16 | 1998-11-17 | Black; Robert H. | Aqueous shower rinsing composition and a method for keeping showers clean |
| US6159916A (en) * | 1998-06-12 | 2000-12-12 | The Clorox Company | Shower rinsing composition |
-
1998
- 1998-06-12 US US09/096,628 patent/US6159916A/en not_active Expired - Lifetime
-
1999
- 1999-06-02 KR KR1020007014125A patent/KR20010072610A/en not_active Application Discontinuation
- 1999-06-02 WO PCT/US1999/012223 patent/WO1999064548A1/en not_active Application Discontinuation
- 1999-06-02 JP JP2000553538A patent/JP2002517602A/en active Pending
- 1999-06-02 AU AU43277/99A patent/AU765589B2/en not_active Ceased
- 1999-06-02 EP EP99955493A patent/EP1086196A4/en not_active Withdrawn
- 1999-06-02 CA CA002332991A patent/CA2332991C/en not_active Expired - Fee Related
- 1999-06-10 AR ARP990102770A patent/AR019647A1/en active IP Right Grant
- 1999-06-10 CO CO99036464A patent/CO5050402A1/en unknown
-
2000
- 2000-10-11 US US09/689,543 patent/US6242402B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CA2332991C (en) | 2009-12-08 |
| JP2002517602A (en) | 2002-06-18 |
| AR019647A1 (en) | 2002-02-27 |
| AU765589B2 (en) | 2003-09-25 |
| CO5050402A1 (en) | 2001-06-27 |
| EP1086196A1 (en) | 2001-03-28 |
| WO1999064548A1 (en) | 1999-12-16 |
| US6159916A (en) | 2000-12-12 |
| KR20010072610A (en) | 2001-07-31 |
| AU4327799A (en) | 1999-12-30 |
| EP1086196A4 (en) | 2002-03-20 |
| US6242402B1 (en) | 2001-06-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20140603 |