CA2365842A1 - Bright metallized film laminate - Google Patents

Bright metallized film laminate Download PDF

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Publication number
CA2365842A1
CA2365842A1 CA002365842A CA2365842A CA2365842A1 CA 2365842 A1 CA2365842 A1 CA 2365842A1 CA 002365842 A CA002365842 A CA 002365842A CA 2365842 A CA2365842 A CA 2365842A CA 2365842 A1 CA2365842 A1 CA 2365842A1
Authority
CA
Canada
Prior art keywords
layer
polyvinylidene difluoride
metallized laminate
laminate according
containing film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002365842A
Other languages
French (fr)
Other versions
CA2365842C (en
Inventor
Thomas R. Fields
Don Smith
Quan Song
Mark O. Outlaw
Kenneth W. Dick
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo Nobel Coatings Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of CA2365842A1 publication Critical patent/CA2365842A1/en
Application granted granted Critical
Publication of CA2365842C publication Critical patent/CA2365842C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/20—Inorganic coating
    • B32B2255/205—Metallic coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/406—Bright, glossy, shiny surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00—Polyvinylhalogenides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24917—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including metal layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31—Surface property or characteristic of web, sheet or block
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers

Abstract

A bright metallized laminate is disclosed that includes a polyvinylidene difluoride-acrylic film having microscopically smooth surfaces, a discontinuous layer of indium islands deposited on the polyvinylidene difluoride-acrylic film, an adhesive layer bonded to the surface of the discontinuous indium layer opposite the polyvinylidene difluoride-acrylic film, and a thermoplastic backing layer bonded to the adhesive layer opposit e the discontinuous layer of indium islands. An associated method is disclosed for forming the bright metallized laminate that includes the steps of castin g a polyvinylidene difluoride-acrylic film to a polymeric substrate, depositin g a discontinuous layer of indium islands upon the polyvinylidene difluoride- acrylic film, placing a polymeric film onto the discontinuous layer of indiu m islands, and press polishing the polyvinylidene difluoride-acrylic film and the discontinuous indium layer. The polyvinylidene difluoride-acrylic film demonstrates a roughness average (RA) of about 0.75 micron or less, and a distinctness of image (DO) of about 95 or more.

Claims (33)

1. A bright metallized laminate, comprising:
a polyvinylidene difluoride-containing film having microscopically smooth surfaces; and a discontinuous layer of indium islands deposited on said polyvinylidene difluoride film.
2. A bright metallized laminate according to Claim 1, further comprising an adhesive layer bonded to the surface of said discontinuous indium layer opposite said polyvinylidene difluoride-containing film.
3. A bright metallized laminate according to Claim 2, wherein said adhesive layer is an adhesive selected from the group consisting of alcohol-based adhesives and water-based adhesives.
4. A bright metallized laminate according to Claim 2, wherein said adhesive layer is comprised of a polyurethane layer and an acrylic layer, said polyurethane layer of said adhesive layer being positioned between said discontinuous indium layer and said acrylic layer of said adhesive layer.
5. A bright metallized laminate according to any of Claims 2-4, further comprising a thermoplastic backing layer bonded to said adhesive layer opposite said discontinuous indium layer.
6. A bright metallized laminate according to Claim 5, wherein said thermoplastic backing layer is selected from the group consisting of polyvinyl chloride, thermoplastic olefins, acrylonitrile-butadiene-styrene copolymers, polycarbonates, polystyrenes, and blends of these polymers.
7. A bright metallized laminate according to any of the previous claims, further comprising a thermoplastic leveling layer that is positioned between said polyvinylidene difluoride-containing film and said discontinuous indium layer.
8. A bright metallized laminate according to Claim 7, wherein said leveling layer is a polymer selected from the group consisting of polyurethane and acrylate polymers.
9. A bright metallized laminate according to Claim 7 or 8, further comprising a thermoplastic primer layer positioned between said polyvinylidene difluoride-acrylic film and said thermoplastic leveling layer.
10. A bright metallized laminate according to Claim 9, wherein said thermoplastic primer layer is comprised of an acrylic compound.
11. A bright metallized laminate according to any of the previous claims, wherein the metallized laminate incorporates a component selected from the group consisting of a tinted polyvinylidene difluoride-acrylic film, a tinted thermoplastic leveling layer, a tinted adhesive layer, and a tinted thermoplastic backing layer.
12. A bright metallized laminate according to any of the previous claims, further comprising an extensible polyurethane mask layer on the surface of said polyvinylidene difluoride-containing film opposite said discontinuous indium layer.
13. A bright metallized laminate according to any of the previous claims, wherein said polyvinylidene difluoride-containing film comprises between about 30% and 90% by weight of polyvinylidene difluoride and between about 10% and 70% by weight of an acrylic polymer.
14. A bright metallized laminate according to any of the previous claims, wherein the surface of said polyvinylidene difluoride-acrylic film has a roughness average of about 0.75 micron or less.
15. A part formed from the bright metallized laminate of any of the previous claims.
16. A part according to Claim 15, wherein said part has been formed using a technique selected from the group consisting of injection molding, blow molding, compression molding, thermoforming, in-mold forming, and die-cutting.
17. A part according to Claim 15, wherein said part is an injection-molded part that further comprises a filler material within the interior of said injection-molded part and a strength forming resin between said injection-molded part and said filler material.
18. A method of using the bright metallized laminate of any of Claims 1-14, comprising:
heating the metallized laminate to a temperature warmer than the surface of an article to which the metallized laminate is to be bonded;
placing the metallized laminate over the article while the metallized laminate is warmer than the surface of the article; and creating a vacuum around the article to shape and bond the laminate to the contours of the article.
19. A method according to Claim 18, wherein the step of placing the metallized laminate over the article comprises placing a metallized laminate having a temperature of between about 280 and 370 degrees Fahrenheit over article having a surface temperature of less than about 120 degrees Fahrenheit.
20. A method for forming a bright metallized laminate, comprising:
applying a polyvinylidene difluoride-containing film to a polymeric substrate; and depositing a discontinuous layer of indium islands upon the polyvinylidene difluoride-containing film.
21. A method for forming a bright metallized laminate according to Claim 20, further comprising:
placing a polymeric film, preferably a polyester film, onto the discontinuous layer of indium islands;
press polishing the polyvinylidene difluoride-containing film and the discontinuous indium layer, preferably between rollers; and thereafter removing the polymeric film from the discontinuous indium layer.
22. A method for forming a bright metallized laminate according to Claim 20, further comprising:
placing a polymeric film, preferably a polyester film, onto the polyvinylidene difluoride-containing film opposite the polymeric substrate;

press polishing the polyvinylidene difluoride-containing film, preferably between a heated nip formed by rollers; and removing the polymeric film from the polyvinylidene difluoride-containing film all before the step of depositing a discontinuous layer of indium islands upon the polyvinylidene difluoride-containing film.
23. A method for forming a bright metallized laminate according to any of Claims 20-22, further comprising depositing a polyurethane leveling layer onto the polyvinylidene difluoride-containing film prior to the step of depositing a discontinuous layer of indium islands upon the polyurethane leveling layer.
24. A method for forming a bright metallized laminate according to Claim 23 further comprising depositing an acrylic primer layer onto the polyvinylidene difluoride-containing film before the step of depositing a polyurethane leveling layer onto the polyvinylidene difluoride-containing film.
25. A method for forming a bright metallized laminate according to any of Claims 20-24, wherein the step of applying the polyvinylidene difluoride-containing film to the polymeric substrate comprises casting the polyvinylidene difluoride-containing film onto the polymeric substrate.
26. A method for forming a bright metallized laminate according to Claim 25, wherein the step of casting the polyvinylidene difluoride-containing film onto the polymeric substrate comprises a technique selected from the group consisting of a knife-over roll coating process, a reverse roll coating process, and a slot die coating process.
27. A method for forming a bright metallized laminate according to Claim 25, wherein the step of casting the polyvinylidene difluoride-containing film onto the polymeric substrate comprises casting a polyvinylidene difluoride-acrylic film onto a polyester substrate.
28. A method for forming a bright metallized laminate according any of Claims 20-27, further comprising placing an adhesive layer on the surface of the discontinuous indium layer opposite the polyvinylidene difluoride-containing film.
29. A method for forming a bright metallized laminate according to Claim 28, wherein the step of placing an adhesive layer onto the surface of the discontinuous indium layer comprises coating the surface of the discontinuous indium layer with an adhesive selected from the group consisting of alcohol-based adhesives and water-based adhesives.
30. A method for forming a bright metallized laminate according to Claim 28, wherein the step of placing adhesive layer onto the discontinuous indium layer comprises:
depositing an acrylic adhesive layer onto a polyester adhesive-carrier substrate;
depositing a polyurethane adhesive layer onto the acrylic adhesive layer, opposite the polyester adhesive-carrier substrate;
bonding the polyurethane adhesive layer to the discontinuous indium layer; and removing the polyester adhesive-carrier substrate from the acrylic adhesive layer.
31. A method for forming a bright metallized laminate according to any of Claims 28-30, further comprising bonding a thermoplastic backing layer to the adhesive layer.
32. A method for forming a bright metallized laminate according to Claim 31, wherein the step of bonding a thermoplastic backing layer to the adhesive layer comprises bonding a backing layer selected from the group consisting of polyvinyl chloride, thermoplastic olefins, acrylonitrile-butadiene-styrene copolymers, polycarbonates, polystyrenes, and blends of these polymers.
33. A method for forming a bright metallized laminate according to any of any of Claims 20-32, further comprising:
removing the polymeric substrate from the polyvinylidene difluoride-containing film; and placing an extensible polyurethane mask layer onto the surface of the polyvinylidene difluoride-containing film opposite the discontinuous indium layer.
CA2365842A 1999-03-12 2000-03-09 Bright metallized film laminate Expired - Lifetime CA2365842C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/268,085 US6287672B1 (en) 1999-03-12 1999-03-12 Bright metallized film laminate
US09/268,085 1999-03-12
PCT/US2000/006173 WO2000073061A2 (en) 1999-03-12 2000-03-09 Bright metallized film laminate

Publications (2)

Publication Number Publication Date
CA2365842A1 true CA2365842A1 (en) 2000-12-07
CA2365842C CA2365842C (en) 2010-11-23

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CA2365842A Expired - Lifetime CA2365842C (en) 1999-03-12 2000-03-09 Bright metallized film laminate

Country Status (11)

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US (3) US6287672B1 (en)
EP (1) EP1161342B1 (en)
JP (1) JP4885363B2 (en)
KR (1) KR20020006027A (en)
AT (1) ATE267697T1 (en)
AU (1) AU7569400A (en)
BR (1) BR0008918B1 (en)
CA (1) CA2365842C (en)
DE (1) DE60011054T2 (en)
MX (1) MXPA01009260A (en)
WO (1) WO2000073061A2 (en)

Families Citing this family (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6287672B1 (en) * 1999-03-12 2001-09-11 Rexam, Inc. Bright metallized film laminate
ATE459488T1 (en) * 1999-09-28 2010-03-15 Kyodo Printing Co Ltd TRANSMISSION BODY AND METHODS OF USE
US6858287B2 (en) 2001-08-10 2005-02-22 Soliant Llc Formable bright film having discontinuous metallic layers
JP2005507796A (en) * 2001-10-31 2005-03-24 スリーエム イノベイティブ プロパティズ カンパニー Non-self-supporting polymer film thermoforming method and article made therefrom
AU2002363242A1 (en) * 2001-10-31 2003-05-12 3M Innovative Properties Company Cross-linked primer composition and use thereof in thermoformable films
JP4022819B2 (en) * 2002-12-26 2007-12-19 豊田合成株式会社 Radio wave transmission cover
JP4195236B2 (en) * 2002-03-26 2008-12-10 日本ウェーブロック株式会社 Metal-tone decorative sheet for forming metal-like molded product, method for producing the same, and metal-style decorative sheet intermediate material for forming metal-like molded product
US7032534B1 (en) * 2002-05-31 2006-04-25 Knittel Engraving Co., Inc. Article for use against backgrounds of various colors and method of manufacture
DE10242526B4 (en) * 2002-09-12 2004-12-09 Daimlerchrysler Ag Plastic vehicle parts with integrated antenna elements and method for their production and use of the vehicle parts
US7393550B2 (en) * 2003-02-21 2008-07-01 Frito-Lay North America, Inv. Method for reducing acrylamide formation in thermally processed foods
US7811618B2 (en) 2002-09-19 2010-10-12 Frito-Lay North America, Inc. Method for reducing asparagine in food products
US7037540B2 (en) * 2002-09-19 2006-05-02 Frito-Lay North America, Inc. Method for reducing acrylamide formation in thermally processed foods
US8110240B2 (en) 2003-02-21 2012-02-07 Frito-Lay North America, Inc. Method for reducing acrylamide formation in thermally processed foods
US20040219366A1 (en) * 2003-05-02 2004-11-04 Johnson John R. Bright formable metalized film laminate
US20040231211A1 (en) * 2003-05-02 2004-11-25 Johnson John R. Three-dimensional automobile badge
US6720065B1 (en) 2003-05-29 2004-04-13 Dupont Teijin Films U.S. Limited Partnership Decorative laminated panel with high distinctness of image
US7862876B2 (en) * 2004-01-20 2011-01-04 Panasonic Corporation Film for suppressing conduction of radiation heat and heat insulating material using the same
US20050196594A1 (en) * 2004-03-02 2005-09-08 Illinois Tool Works, Inc. In-mold label composition and process
WO2006102592A1 (en) * 2005-03-24 2006-09-28 3M Innovative Properties Company Metallized films and articles containing the same
CN101184615A (en) * 2005-03-24 2008-05-21 3M创新有限公司 Corrosion resistant metallized films and methods of making the same
US7073849B1 (en) * 2005-06-08 2006-07-11 Mitchell Nunes Snap-on chrome plated automotive grille overlay
JP4936689B2 (en) * 2005-07-25 2012-05-23 株式会社ウェーブロック・アドバンスト・テクノロジー Metal decoration sheet for deep drawing molding
US7854985B2 (en) * 2005-11-18 2010-12-21 Soliant Llc Decorative paint film laminate
CN101426646B (en) * 2006-04-19 2013-10-09 东丽株式会社 Biaxially oriented polyester film for molded part
US20070284097A1 (en) * 2006-06-08 2007-12-13 Halliburton Energy Services, Inc. Consumable downhole tools
US20080257549A1 (en) * 2006-06-08 2008-10-23 Halliburton Energy Services, Inc. Consumable Downhole Tools
US20080070055A1 (en) * 2006-09-18 2008-03-20 King Charles L Adhesive decorative paper and method for manufacturing same
US20080311357A1 (en) * 2006-12-29 2008-12-18 Collins & Aikman Corporation Laminate construction containing discontinuous metal layer
US20080202764A1 (en) * 2007-02-22 2008-08-28 Halliburton Energy Services, Inc. Consumable downhole tools
US8486684B2 (en) 2007-08-13 2013-07-16 Frito-Lay North America, Inc. Method for increasing asparaginase activity in a solution
US20100285308A1 (en) * 2007-10-29 2010-11-11 Merritt William H Composite Articles Having Excellent Adhesion Strength And Methods Of Forming The Same
US8062451B2 (en) * 2008-02-22 2011-11-22 Delta Engineered Plastics Post molding application of an extruded film to an injection molded part
US8327926B2 (en) 2008-03-26 2012-12-11 Robertson Intellectual Properties, LLC Method for removing a consumable downhole tool
US8235102B1 (en) 2008-03-26 2012-08-07 Robertson Intellectual Properties, LLC Consumable downhole tool
US8284248B2 (en) 2009-08-25 2012-10-09 Frito-Lay North America, Inc. Method for real time detection of defects in a food product
US8158175B2 (en) 2008-08-28 2012-04-17 Frito-Lay North America, Inc. Method for real time measurement of acrylamide in a food product
US9095145B2 (en) 2008-09-05 2015-08-04 Frito-Lay North America, Inc. Method and system for the direct injection of asparaginase into a food process
US9215886B2 (en) 2008-12-05 2015-12-22 Frito-Lay North America, Inc. Method for making a low-acrylamide content snack with desired organoleptical properties
WO2010077132A1 (en) 2008-12-31 2010-07-08 Draka Comteq B.V. Uvled apparatus for curing glass-fiber coatings
EP2388239B1 (en) 2010-05-20 2017-02-15 Draka Comteq B.V. Curing apparatus employing angled UV-LEDs
US8871311B2 (en) 2010-06-03 2014-10-28 Draka Comteq, B.V. Curing method employing UV sources that emit differing ranges of UV radiation
EP2418183B1 (en) 2010-08-10 2018-07-25 Draka Comteq B.V. Method for curing coated glass fibres providing increased UVLED intensitiy
US10086555B2 (en) 2011-10-27 2018-10-02 Whirlpool Corporation Method for forming a laminated part
EP2803753A1 (en) 2013-05-13 2014-11-19 Grendene S/A Soft and flexible metallized polymeric article, method for producing the same, footwear with soft and flexible metallized polymeric component, method for producing footwear.
CN103523376A (en) * 2013-10-20 2014-01-22 江苏申凯包装高新技术股份有限公司 Light refraction color change anti-fake compound packaging film
WO2016109963A1 (en) * 2015-01-08 2016-07-14 Colgate-Palmolive Company Holographic laminate and the tube made thereof
US20170062144A1 (en) * 2015-09-01 2017-03-02 General Electric Company Manufacturing processes for forming metallized film capacitors and related metallized film capacitors
US10116610B2 (en) 2016-08-31 2018-10-30 Keystone Automotive Operations, Inc. Automotive wheel overlay attachment system
JP2019107789A (en) * 2017-12-15 2019-07-04 株式会社小糸製作所 Resin molded article and vehicle component
JP6980537B2 (en) * 2018-01-12 2021-12-15 株式会社ウェーブロック・アドバンスト・テクノロジー Metal layer holding film, metal-like decorative sheet intermediate, metal-like decorative sheet, extrusion laminated body, metal-like molded body, injection molded body, manufacturing method of metal-like molded body, manufacturing method of injection molded body and extrusion laminating How to make a body
US10162090B1 (en) 2018-02-20 2018-12-25 3M Innovative Properties Company Conformable reflective film having specified reflectivity when stretched at room temperature
US11827762B2 (en) * 2018-06-01 2023-11-28 Dai Nippon Printing Co., Ltd. Metallic decorative member, and metallic decorative molded body using same
KR101950380B1 (en) * 2018-08-06 2019-02-20 이준수 Environment-friendly decoration film having metallic luster and manufacturing method thereof
US11541633B2 (en) * 2020-01-10 2023-01-03 GM Global Technology Operations LLC Hybrid parts including additive manufacturing
JP7244879B2 (en) * 2020-02-10 2023-03-23 尾池工業株式会社 Metal-like decorative film, metal-like vehicle interior and exterior parts, metal-like molding
JP2021133615A (en) * 2020-02-27 2021-09-13 スリーエム イノベイティブ プロパティズ カンパニー Vapor deposition sheet for decoration

Family Cites Families (79)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS582822B2 (en) 1974-11-21 1983-01-18 呉羽化学工業株式会社 color sheet
US4101698A (en) 1975-07-14 1978-07-18 Avery International Corp. Elastomeric reflective metal surfaces
US4211822A (en) 1977-01-07 1980-07-08 The Dow Chemical Company Highly reflective multilayer metal/polymer composites
US4115619A (en) 1977-01-07 1978-09-19 The Dow Chemical Company Highly reflective multilayer metal/polymer composites
US4241129A (en) 1978-12-15 1980-12-23 The Dow Chemical Company Delamination resistant multilayer metal/polymer composites
US4431711A (en) 1980-03-25 1984-02-14 Ex-Cell-O Corporation Vacuum metallizing a dielectric substrate with indium and products thereof
US4407871A (en) 1980-03-25 1983-10-04 Ex-Cell-O Corporation Vacuum metallized dielectric substrates and method of making same
US4351864A (en) 1981-05-06 1982-09-28 The Standard Products Company Molding having encapsulated metallized film
US4403004A (en) 1981-10-23 1983-09-06 Transfer Print Foils, Inc. Sandwich metalized resin laminate
JPS60135250A (en) * 1983-12-23 1985-07-18 尾池工業株式会社 Metallic gloss film
US4671985A (en) 1984-11-05 1987-06-09 Swiss Aluminium Ltd. Thin, deformable composite laminate
US4684353A (en) 1985-08-19 1987-08-04 Dunmore Corporation Flexible electroluminescent film laminate
JPS62156942A (en) 1985-12-28 1987-07-11 東洋紡績株式会社 Double-layer gas-barriering film or sheet and manufacture thereof
US4816324A (en) 1986-05-14 1989-03-28 Atlantic Richfield Company Flexible photovoltaic device
US4931324A (en) 1986-10-28 1990-06-05 Rexham Corporation Decorative sheet material simulating the appearance of a base coat/clear coat paint finish
US4943680A (en) 1986-10-28 1990-07-24 Rexham Corporation Method of making a decorative sheet material simulating the appearance of a base coat/clear coat paint finish
US4810540A (en) 1986-10-28 1989-03-07 Rexham Corporation Decorative sheet material simulating the appearance of a base coat/clear coat paint finish
US5342666A (en) 1986-10-28 1994-08-30 Rexham Industries Corp. Injection molded plastic article with integral weatherable pigmented film surface
USRE35894E (en) 1986-10-28 1998-09-08 Rexam Industries Corp. Injection molded plastic article with integral weatherable pigmented film surface
USRE36457E (en) 1986-10-28 1999-12-21 Rexam Industries, Corp. Injection molded plastic article with integrated weatherable pigmented film surface
CA1292603C (en) * 1986-10-28 1991-12-03 Thomas M. Ellison Injection molded plastic article with integral weatherable pigmented film surface
US4837068A (en) 1987-01-27 1989-06-06 The Foxboro Company Compliant diaphragm material
US5707697A (en) 1987-03-27 1998-01-13 Avery Dennison Corporation Dry paint transfer product having high DOI automotive paint coat
US6835267B1 (en) 1987-03-27 2004-12-28 Avery Dennison Corporation Dry paint transfer process and product
US4713143A (en) 1987-04-16 1987-12-15 Davidson Textron Inc. Etching of vacuum metallized indium
US4928908A (en) 1987-06-12 1990-05-29 Reiko Co., Ltd. Balloon made of metal vapor deposited film
JPS63311986A (en) * 1987-06-12 1988-12-20 株式会社麗光 Metallized film balloon
JP2571401B2 (en) * 1987-10-27 1997-01-16 尾池工業株式会社 Metallic gloss sheet with excellent moldability
JPH01188334A (en) * 1988-01-23 1989-07-27 Oike Ind Co Ltd Metallic decorative sheet
DE3815265A1 (en) 1988-05-05 1989-11-16 Kolbenschmidt Ag MATERIAL FOR COMPOSITE BEARINGS AND METHOD FOR THE PRODUCTION THEREOF
US4877683A (en) 1988-05-25 1989-10-31 E. I. Du Pont De Nemours And Company Fluoropolymer laminates
US4988540A (en) 1988-05-25 1991-01-29 E. I. Du Pont De Nemours And Company Method of making fluoropolymer laminates
US4913760A (en) 1988-08-29 1990-04-03 Eastman Kodak Company Method of manufacturing a dried, thermoformable, paint-coated sheet material having gloss and smoothness
US4904526A (en) 1988-08-29 1990-02-27 3M Company Electrically conductive metal oxide coatings
US5055346A (en) 1988-08-30 1991-10-08 Frank Rohrbacher Thermoplastic acrylic polymer coated composite structure
US5035940A (en) 1988-09-19 1991-07-30 Rexham Corporation Aluminum-fluoropolymer laminate
US4875262A (en) 1988-09-23 1989-10-24 Eastman Kodak Company Process for manufacturing a grain chill roller
US5118372A (en) 1988-11-21 1992-06-02 Eastman Kodak Company Method of forming a protective and decorative sheet material on a substrate
US4918800A (en) 1989-04-03 1990-04-24 Eastman Kodak Company Continuous method for making decorative sheet materials
US5037680A (en) 1989-07-10 1991-08-06 Decoma International Inc. Exterior automotive component with pigmented substrate and clear coating
US5418056A (en) 1989-11-24 1995-05-23 Mitsuboshi Belting Ltd. Polymer composite with dispersed fine grains and a method for manufacturing the same
US4952293A (en) * 1989-12-29 1990-08-28 Xerox Corporation Polymer electrodeposition process
JPH03225322A (en) 1990-01-31 1991-10-04 Ricoh Co Ltd Recording medium
US5028492A (en) 1990-03-13 1991-07-02 Olin Corporation Composite coating for electrical connectors
US5141702A (en) 1990-03-13 1992-08-25 Olin Corporation Method of making coated electrical connectors
JP2965616B2 (en) 1990-04-17 1999-10-18 株式会社リコー Image recording body and image recording method
JPH0435938A (en) * 1990-05-31 1992-02-06 Minnesota Mining & Mfg Co <3M> Laminated film having metal-like luster
US5215826A (en) 1990-09-25 1993-06-01 Rexham Industries Corp. Surfacing film with thermoformable carrier layer
US5968663A (en) 1991-07-24 1999-10-19 Alusuisse Technology & Management Ltd. Stretch-formable laminate
US5290625A (en) 1992-05-22 1994-03-01 Davidson Textron Inc. System for making bright aluminum parts
AU5322594A (en) 1992-10-29 1994-05-24 Dow Chemical Company, The Formable reflective multilayer body
US5353154A (en) 1992-11-02 1994-10-04 The Dow Chemical Company Polymeric reflective materials utilizing a back light source
CA2084716C (en) 1992-11-05 1999-11-16 John R. Johnson Exterior automotive laminate with pressure-sensitive adhesive
US5284679A (en) 1992-11-16 1994-02-08 Davidson Textron Inc. Method for making bright trim articles
US5320869A (en) 1992-12-04 1994-06-14 Davidson Textron Inc. Method for producing high gloss bright colored plastic articles
US6071621A (en) 1993-06-11 2000-06-06 3M Innovative Properties Company Metallized film and decorative articles made therewith
WO1995023688A1 (en) 1994-03-02 1995-09-08 Hicks & Otis Prints, Incorporated Vehicle part having weather sealed mirror finish decorative portion integral therewith
US5985418A (en) 1994-05-25 1999-11-16 Textron Automotive Interiors, Inc. Radiation cured island coating system
JP2970997B2 (en) 1994-07-01 1999-11-02 株式会社クラレ Laminate having polyurethane layer
US6083628A (en) 1994-11-04 2000-07-04 Sigma Laboratories Of Arizona, Inc. Hybrid polymer film
EP0762943B1 (en) 1995-04-21 2003-05-28 Textron Automotive Interiors Inc. Radiation cured island coating system
JP3894571B2 (en) 1995-06-06 2007-03-22 レイケム・コーポレイション Flexible electrode carrying article
US6113838A (en) 1995-06-07 2000-09-05 Avery Dennison Corporation Control of metallic appearance in automotive cast paint films
US5750234A (en) 1996-06-07 1998-05-12 Avery Dennison Corporation Interior automotive laminate with thermoplastic low gloss coating
US5653927A (en) 1995-06-07 1997-08-05 Avery Dennison Corporation Control of metallic appearance in automotive cast paint films
ZA964731B (en) * 1995-06-07 1997-01-07 Avery Dennison Corp A Legal Bo Extrusion coating process for making protective and decorative films
US5985079A (en) 1996-03-28 1999-11-16 Rexam Industries Corp. Flexible composite surfacing film and method for producing same
US5919537A (en) 1996-06-18 1999-07-06 Android Industries Of Michigan, L.L.C. Decorative films and laminated formable sheets with dual protective film layers
US5895624A (en) 1996-06-18 1999-04-20 Android Industries Of Michigan, Llc Method and apparatus for forming thick wall plastic sheets having formable decorative film layers
US5688598A (en) 1996-06-28 1997-11-18 Morton International, Inc. Non-blistering thick film coating compositions and method for providing non-blistering thick film coatings on metal surfaces
US6060135A (en) 1996-10-07 2000-05-09 E. I. Du Pont De Nemours And Company Lustrous laminate film structures
US6017639A (en) 1996-10-23 2000-01-25 Valspar Corporation Vinylidene difluoride-based coating compositions
JPH10170710A (en) 1996-12-12 1998-06-26 Minnesota Mining & Mfg Co <3M> Light retroreflective sheet
JPH10193549A (en) * 1997-01-08 1998-07-28 Hashimoto Forming Ind Co Ltd Decoration trim exhibiting metallic lustrous color, its manufacture and laminated film used for the method
US5759727A (en) 1997-01-21 1998-06-02 Xerox Corporation Method of generating simulated photographic quality images on luminescent, mirror coated, melt-formed backing substrates
US5968657A (en) 1997-08-18 1999-10-19 3M Innovative Properties Company Paint film assembly with masking film and method of making same
US5976671A (en) 1997-10-20 1999-11-02 The Boeing Company Polyvinylidene fluoride-based decorative laminate
JP2001526983A (en) * 1997-12-31 2001-12-25 テクストロン・システムズ・コーポレイション Metallized sheets, composites and methods for their production
US6287672B1 (en) * 1999-03-12 2001-09-11 Rexam, Inc. Bright metallized film laminate

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JP4885363B2 (en) 2012-02-29
AU7569400A (en) 2000-12-18
WO2000073061A2 (en) 2000-12-07
MXPA01009260A (en) 2003-07-14
EP1161342A2 (en) 2001-12-12
KR20020006027A (en) 2002-01-18
DE60011054D1 (en) 2004-07-01
ATE267697T1 (en) 2004-06-15
WO2000073061A3 (en) 2001-06-28
US6287672B1 (en) 2001-09-11
US6565955B2 (en) 2003-05-20
US20020048665A1 (en) 2002-04-25
EP1161342B1 (en) 2004-05-26
BR0008918A (en) 2001-12-18
BR0008918B1 (en) 2009-05-05
DE60011054T2 (en) 2005-04-07
US20010051255A1 (en) 2001-12-13
CA2365842C (en) 2010-11-23

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