CA2384241C - Papermaking apparatus and process for removing water from a cellulosic web - Google Patents

Papermaking apparatus and process for removing water from a cellulosic web Download PDF

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Publication number
CA2384241C
CA2384241C CA002384241A CA2384241A CA2384241C CA 2384241 C CA2384241 C CA 2384241C CA 002384241 A CA002384241 A CA 002384241A CA 2384241 A CA2384241 A CA 2384241A CA 2384241 C CA2384241 C CA 2384241C
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Prior art keywords
imprinting
web
cellulosic web
imprinting member
cellulosic
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Expired - Fee Related
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CA002384241A
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French (fr)
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CA2384241A1 (en
Inventor
Dean Van Phan
Paul Dennis Trokhan
Peter Graves Ayers
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Procter and Gamble Co
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Procter and Gamble Co
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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/006Making patterned paper
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S162/00Paper making and fiber liberation
    • Y10S162/903Paper forming member, e.g. fourdrinier, sheet forming member
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/102Woven scrim
    • Y10T442/133Inorganic fiber-containing scrim
    • Y10T442/141Including a woven fabric which is not a scrim

Abstract

An apparatus and process for removing water from a cellulosic web. The papermaking apparatus comprises imprinting member having an absolute void volume that enables a hydraulic connection to be formed between a cellulosic web and a capillary dewatering member when compressed in a nip. The absolute void volume is predetermined based on an estimate of the volume of water expressed from the cellulosic web.

Description

PAPERMAKING APPARATUS AND PROCESS FOR REMOVING WATER
FROM A CELLULOSIC WEB
FIELD OF THE INVENTION
The present invention relates to papermaking, and more particularly to an apparatus and process for removing water from a cellulosic web.
BACKGROUND OF THE INVENTION
Cellulosic fibrous structures, such as paper towels, facial tissues, napkins and toilet tissues, are a staple of every day life. The large demand for and constant usage of such consumer products has created a demand for improved versions of these products and, likewise, improvement in the methods of their manufacture. Such cellulosic fibrous structures are manufactured by depositing an aqueous slurry from a headbox onto a Fourdrinier wire or a twin wire paper machine. Either such forming wire is an endless belt through which initial dewatering occurs and fiber rearrangement takes place.
After the initial formation of the web, which later becomes the cellulosic fibrous structure, the papermaking machine transports the web to the dry end of the machine. In the dry end of a conventional machine, a press felt compacts the web into a single region, i.e., uniform density and basis weight, cellulosic fibrous structure prior to final drying.
The final drying is usually accomplished by a heated drum, such as a Yankee drying drum.
One of the significant improvements to the manufacturing process is the use of through-air-drying to replace conventional press felt dewatering. Through air drying yields significant improvements in consumer products. In through-air-drying, like press felt drying, the web begins on a forming wire which receives an aqueous slurry of less than one percent consistency (the weight percentage of fibers in the aqueous slurry) from a headbox. Initial dewatering takes place on the forming wire. From the forming wire,
2 tlae web is transferred to an air pervious through-air-drying belt. This "wet transfer"
r,~pically occurs at a pickup shoe (PUS), at which point the web may be first molded to the topography of the through air drying belt. This molding is disclosed in EP
0140404 issued to Trokhn on April 27, 1988.
Through air drying yields structured paper having regions of different densities.
This type of paper has been used in commercially successful products, such as Bounty paper towels and Charmin and Charmin Ultra brands of bath tissues. Traditional conventional felt drying does not produce the structured paper and its attendant advantages. However, it has been desired to produce structured paper using conventional felt drying at speeds approaching that of the through air dried systems.
Attempts have been made utilizing a conventional felt having a patterned framework thereon for imprinting the embryonic web. Examples of these attempts in the ai-t include commonly assigned U.S. Patent Nos. 5,556,509, issued Sept. 17, 1996 to Trokhan et al.; 5,580,423, issued Dec. 3, 1996 to Ampulski et al.; 5,609,725, issued Mar.
l :l, 1997 to Phan; 5,629,052, issued May 13, 1997 to Trokhan et al.;
5,637,194, issued June 10, 1997 to Ampulski et al.; 5,674,663, issued Oct. 7, 1997 to McFarland et al.; and 5,709,775 issued Jan. 20, 1998 to Trokhan et al.
Other attempts have been made by transporting a paper web on a separate imprinting fabric and compressing the combination in a compression nip formed between two rolls. U.S. Pat. 4,421,600 issued December 20, 1983 to Hostetler discloses an apparatus having two felts, three pressing operations, and a separate woven imprinting fabric. In Hostetler the web is transported on the imprinting fabric through the pressing operations before being delivered to the Yankee dryer.
Another such attempt in the art is illustrated by U.S. 4,309,246 issued Jan.
5, 1982 to Hulit et al.. Hulit et al. describes three configurations where a nip is formed between two rolls. In each configuration, a paper web is carried on an imprinting fabric having compaction elements defined by knuckles formed at warp and weft crossover points. The imprinting fabric, web and a felt are compressed between the rolls.
Each of the aforementioned attempts in the art, requires a complex nip system in order to bring the imprinting fabric/paper web combination into contact with a dewatering felt. These systems create very expensive propositions for retrofitting existing conventional machinery, as additional space, drives, etc. are typically required to add the separate felt loop. What's more, in order to sufficiently dewater the paper web, the systems are required to operate at lower speeds than through air dried systems.
Commonly assigned U.S. Patent. 5,637,194 issued June 10, 1997 to Ampulski et al., discloses an alternative paper machine embodiment where a first dewatering felt is positioned adjacent a face of the imprinting member as the molded web is carried on the imprinting member from a first compression nip formed between two pressure rolls and a second dewatering felt to a second compression nip formed between a pressure roll and a Yankee drying drum. The imprinting member imprints the molded web and carries it to the Yankee drying drum.
The presence of the first felt adjacent the imprinting member at the two compression nips results in additional water removal from the web prior to transfer to the Yankee drum.
The present invention provides a web patterning apparatus suitable for making str:vctured paper on a conventional papermaking machine without the need for an additional dewatering felt or compression nip. The invention provides a web patterning apparatus capable of dewatering a paper web using conventional felt dewatering techniques with a single compression nip system while operating at speeds approaching that of through air dried systems.

SUMMARY OF THE INVENTION
The invention comprises papermaking apparatus and process for removing water from a cellulosic web. The papermaking apparatus comprises an imprinting member having an absolute void volume that enables a hydraulic connection to be formed between a cellulosic web and a capillary dewatering member when compressed in a nip.
The absolute void volume is predetermined based on an estimate of the volume of water expressed from the cellulosic web at the nip. For the present invention, the ratio of the volume of water expelled from the web to the absolute void volume of the imprinting member is at least about 0.5.
The nip can be formed between first and second rolls juxtaposed coaxially. The cellulosic web is carried on the topside of the imprinting member. The cellulosic web and imprinting member are interposed in the nip such that the top surface of the cellulosic web is in contacting relationship with the periphery of the first roll. In the nip, the backside of the imprinting member is in contacting relationship with the top surface of a capillary dewatering member while the back surface of the capillary dewatering member is in contacting relationship with the periphery of the second roll. The nip compresses the paper web, the imprinting member, and the capillary dewatering member. Water expelled from the web passes through the imprinting member to the capillary dewatering member forming a hydraulic connection therebetween.

BRIEF DESCRIPTION OF THE DRAWINGS
While the specification concludes with claims particularly pointing out and distinctly claiming the present invention, the invention will be better understood from the following description taken in conjunction with the accompanying drawings in which like 5 designations are used to designate substantially identical elements, and in which:
Fig. 1 is a vertical side elevational view of a papermaking machine according to the present invention.
Fig. 2 is a fragmentary top plan view of the imprinting member shown in Fig.
1.
Fig. 3 is a vertical sectional view taken along lines 3-3 of Fig. 1.
DETAILED DESCRIPTION OF THE INVENTION
Definitions:
As used herein, the following terms have the following meanings:
Hydraulic connection is a continuous link formed by water or other similar liquid.
Void volume (VV) is the open space providing a path for fluids.
Relative Void Volume (VVRelative) is the ratio of VV to the Total Volume of space occupied by a given sample.
Absolute Void Volume (VVAbsonte) is the volumetric measure of VV per unit area
3 cm in Z .
cm Machine direction, designated MD, is the direction parallel to the flow of the cellulosic web through the product manufacturing equipment.
Cross machine direction, designated CD, is the direction perpendicular to the machine direction in the same plane of the cellulosic web.
Capillary dewatering member is a device for removing water via capillary attraction.
Caliper is the macroscopic thickness of a sample measured as described below.
Basis weight (BW) is the weight of cellulosic fibers (in grams, g) per unit area (cmz) of a sample of a cellulosic web reported in g cmZ .

Also, as used herein, paper web is synonymous with cellulosic web.
The present invention comprises an apparatus for dewatering a cellulosic web 20.
Referring to Figure 1, an aqueous slurry comprising cellulosic fibers and water is discharged from a headbox 10 onto a forming wire 15 and then transferred to a drying apparatus comprising an imprinting member 30 shown as an endless belt. The imprinting member 30 carries the cellulosic web 20 containing a volume of water to a nip 38 formed between two coaxial rolls. The first roll 70 can be heated roll such as a Yankee drying drum as shown in Figure 1. The second roll 35 can be a pressure roll having a periphery with a capillary dewatering member 60 disposed thereon. The capillary dewatering member 60 can be a felt and the pressure roll can be a vacuum pressure roll.
The capillary dewatering member 60 includes a top surface 62 and a bottom surface 64. In the nip 38, the bottom surface 64 of the capillary dewatering member 60 interfaces with the second roll 35 while the top surface 62 interfaces with a backside 32 of the imprinting member 30 such that the cellulosic web 20 carried on the topside 31 of the imprinting member 30 interfaces with the first roll 70. The nip 38 compresses the capillary dewatering member 60, imprinting member 30 and cellulosic web 20 combination, squeezing a volume of water from the web, through the imprinting member 30 to the capillary dewatering member 60. At the same time, the imprinting member 30 imprints the cellulosic web while transferring it to the Yankee drying drum 70.
If desired, a vacuum may be applied through the second roll 35 to the capillary dewatering member 60. This vacuum assists in water removal from the capillary dewatering member 60, and hence from the cellulosic web 20. The second roll 35 may be a vacuum pressure roll. A steam box is disposed opposite the vacuum pressure roll 35.
The steam box ejects steam through the cellulosic web 20. As the steam passes through and/or condenses in the cellulosic web 20, it elevates the temperature and reduces the viscosity of water contained therein, promoting better dewatering. The steam and/or condensate is collected by the vacuum pressure roll 35.
Of course, one of ordinary skill will recognize that the simultaneous imprinting, dewatering and transfer operations may occur in embodiments other than these requiring a Yankee drying drum 70. For example, two flat surfaces may be juxtaposed together to form an elongate nip 38 therebetween. Alternatively, two rolls may be utilized, neither of which roll is heated. The rolls may be, for example, part of a calendar stack, or an operation which prints a functional additive onto the surface of the web.
Functional additives include: lotions emollients, dimethicones, softeners, perfumes, menthols, etc.
which are well known in the art.
It has been found that for a given imprinting member 30 the amount of water removed from the cellulosic web 20 in the nip 38 is directly related to the hydraulic connection formed between the cellulosic web 20 and the capillary dewatering member 60 via the imprinting member 30. The imprinting member 30 has an absolute void volume which can be designed to optimize the hydraulic connection and maximize corresponding water removal.
The amount of water in a cellulosic web 20 is evaluated in terms of consistency which is the percentage by weight of cellulosic fibers making up a web of fibers and water. Consistency is determined by the following expression g of Fibers Consistency =
g of Fibers + g of Water and g of Water _ 1 g of Fibers Consistency Upon entering the nip 38, a cellulosic web 20 can have an ingoing consistency of about 0.22 comprising about 4.54 g of water The desired consistency for a of fibers ' cellulosic web 20 exiting the nip 38 is about 0.40 comprising about 2.50 g of water Thus about 2.04 g of water is removed at the nip.
of fibers ' ~ of fibers Given the Basis weight of the cellulosic web upon exiting the nip, the volume of water expelled at the nip is determined by the following:
V _ g of water X BW g of fibers X 1 water per unit area - g of fibers cm' p water where BW = basis weight of the web exiting the nip.

Pw"~, = density of water = ( 1 g , ) cm In order to maximize water removal at the nip, the ratio of the volume of water expelled from the cellulosic web 20 to the absolute void volume of the imprinting member 30 is at least about 0.5. The ratio of the volume of water expelled from the cellulosic web 20 to the absolute void volume of the imprinting member 30 can be at least about 0.7. In some embodiments, the ratio can be greater than 1Ø
The imprinting member can comprise woven fabric. Woven fabrics typically comprise warp and weft filaments where warp filaments are parallel to the machine direction and weft figment are parallel to the cross machine direction. The warp and weft filaments form discontinuous knuckles where the filaments cross over one another in succession. These discontinuous knuckles provide discrete imprinted areas in the cellulosic web 20 during the papermaking process. As used herein the term "long knuckles" is used to define discontinuous knuckles formed as the warp and weft filaments crass over two ar more warp or weft filament, respectively.
The knuckle imprint area of the woven fabric may be enhanced by sanding the surface of the filaments at the warp and weft crossover points. Such sanded woven fabrics are made in accordance with the teachings of U.S. Patent No.
3,573,164, issued to Friedberg et al. on March 30, 1971 and U.S. Patent No. 3,905,863 issued to Ayers on September 16, 1975:
Absolute void volume of the woven fabric can be determined by measuring caliper and weight of a sample of woven fabric of known area. The caliper is measured by placing the sample of woven fabric on a horizontal flat surface and confining it bet~areen the flat surface and a load foot having a horizontal loading surface, where the load foot loading surface has a circular surface area of about 3.14 square inches and applies a confining pressure of about 15 glcmz (0.21 psi) to the sample. The caliper is the resulting gap between the flat surface and the load foot loading surface. Such measurements can be obtained on a VIR Electronic Thickness Tester Model II
available from Thwing-Albert, Philadelphia, Pa.
The density of the filaments is determined while the density of the void spaces is assumed to be 0 gm/cc. For example, polyester (PET) filaments have a density of 1.38 g/cm3. The sample of known area is weighed, thereby yielding the mass of the test sample. The absolute void volume ( VVAbsolute ) per unit area of woven fabric is then calculated by the following formula (with unit conversions where appropriate):
S VVAbsolme Vtotal Vfilaments - (t x A) - (m/r) where, Vtotal = total volume of test sample (t x A).
Vstaments = solid volume of the woven fabric equal to the volume of the constituent filaments alone.
t = caliper of test sample.
A = area of test sample.
m = mass of test sample.
r= density of filaments Relative void volume is determined by the following:
_ VVAbsolute Relative Total For the present invention, maximum water removal at the nip can be achieved for a woven fabric where the VVRelative ranges from a low limit of about 0.05, preferably a low limit of 0.10, to a high limit of about 0.45, preferably a high limit of about 0.4. For a sanded woven fabric the high limit of WRelat;~e is about 0.30.
Figure 2 illustrates an imprinting member 30 wherein the woven fabric serves as a reinforcing structure for a resinous knuckle pattern 42. Figure 3 illustrates a cross section of unit cell of an imprinting member 30 in a compression nip 38 formed between a Yankee drum 70 and a pressure roll 35. The imprinting member 30 has a topside 31 in contacting relationship with the cellulosic web 20 and a back side 32 in contacting relationship with a capillary dewatering member 60. For this embodiment, the knuckle pattern 42 defines deflection conduits 46. The capillary dewatering member 60 comprises a dewatering felt. In the nip 38, the knuckle pattern 42 compress the cellulosic web 20 compacting the fibers while simultaneously forcing the water into the deflection conduits 46. In the deflection conduits 46, the water flows through the absolute void 5 volume of the reinforcing structure forming a hydraulic connection with the capillary dewatering member. The cellulosic fibers become captured by the solid volume of the reinforcing structure 44 forming low density pillow areas in the cellulosic web 20.
The VVAbsolute of an imprinting member 30 having a resinous knuckle pattern 42 as shown in Figure 2, is determined by immersing a sample of the imprinting member 30 in 10 a bath of melted Polyethylene Glycol 1000 (PEG) to a depth slightly exceeding the thickness of the sample. After assuring that all air is expelled from the immersed sample, the PEG is allowed to resolidify. The PEG above the topside 31, below the backside 32 and along the edges of the sample is removed from the sample and the sample is reweighed. The difference in weight between the sample with and without PEG is the weight of the PEG filling the absolute void volume. The absolute void volume and the solid volume of the sample is determined by the following expressions:
_ grams of PEG
VVAbsotute PpEG
where ppEG = density of PEG
'SVAbsolute VFilaments + VResinous Knuckles mfilaments + M Resinous Knuckles rfilaments Resinous Knuckles where SVAbsolute = Absolute Solid Volume mfilaments = mass of filaments rfilaments = density of filaments M = mass of the resinous knuckles Resinous Knuckles PResinous Knuckles = density of resinous knuckles For the present invention, maximum water removal at the nip can be achieved for a reinforcing structure 42 having a resinous knuckle pattern 44 disposed thereon where the WR~,~,;~~ ranges from a low limit of about 0.05, preferably a tow limit of 0.10, to a high limit of about 0.45, preferably a high limit of about 0.28. Most preferably, the ~IVR~,a,;~~ for a reinforcing structure having a resinous knuckle pattern disposed thereon is about 0.19.
Imprinting Member The imprinting member 30 can be an imprinting fabric. The imprinting fabric is macroscopically monoplanar. The plane of the imprinting fabric defines its X-Y
directions. Perpendicular to the X-Y directions and the plane of the imprinting fabric is the Z-direction of the imprinting fabric. Likewise, the cellulosic web 20 according to the present invention can be thought of as macroscopically monoplanar and lying in an X-Y
plane. Perpendicular to the X-Y directions and the plane of the web is the Z-direction of the cellulosic web 20.
The imprinting fabric includes a topside 31 which contacts the cellulosic web that is carried thereon and a backside 32 which contacts the dewatering felt.
The imprinting fabric comprises a woven fabric comparable to woven fabrics commonly used in the papermaking industry for imprinting fabrics. Such imprinting fabrics which are known to be suitable for this purpose are illustrated in commonly assigned U.S. Patents 3,301,746 issued Jan. 31, 1967 to Sanford et al.; 3,905,863 issued Sept. 16, 1975 to Ayers; and
4,239,065 issued Dec. 16, 1982 to Trokhan .
The filaments of the woven fabric may be so woven and complimentarily se~pentinely configured in at least the Z-direction of the lamina to provide a first grouping or array of coplanar top-surface-plane crossovers of both warp and weft filaments and a prf;determined second grouping or array of sub-top-surface crossovers. The arrays are interspersed so that portions of the top-surface-plane crossovers define an array of wicker-basket-like cavities in the top surface of the fabric. The cavities are disposed in staggered relation in both the machine direction and the cross machine direction such that each cavity spans at least one sub-top-surface crossover. A woven fabric having such arrays may be made according to commonly assigned U.S. Patents 4,239,065, issued December 16, 1980 to Trokhan; and 4,191,069, issued March 4, 1980 to Trokhan, the disclosures of which are incorporated herein by reference.
For a woven fabric the term shed is used to define the number of warp filaments involved in a minimum repeating unit. The term "square weave" is defined as a weave of n-shed wherein each filament of one set of filaments (e.g., wefts or warps), alternately crosses over one and under n-1 filaments of the other set of filaments (e.g.
wefts or warps) and each filament of the other set of filaments alternately passes under one and over n-1 filaments of the first set of filaments.
The woven fabric for the present invention is required to form and support the cellulosic web 20 and allow water to pass through. The woven fabric for the imprinting fabric can comprise a "semi-twill" having a shed of 3 where each warp filament passes over two weft filaments and under one weft filament in succession and each weft filament passes over one warp filament and under two warp filaments in succession. The woven fabric for the imprinting fabric may also comprise a "square weave" having a shed of 2 where each warp filament passes over one weft filament and under one weft filament in succession and each weft filament passes over one warp filament and under one warp filament in succession.
The caliper of the woven l~,tbric may vary. howwur. in ordr to facilitate the Inydrnulic connection beW een the crlluloaic web ?tl ,111(1 the capillary ciewatcrin;= member 6() the caliper of the imprintin~T titbric ahould ran~~r li~om about ().01 1 inch (0.?''~) mm) to abo~it (1.0?6 inch f (1.66() mm j.
In an alternative embodiment of the present invention, the imprinting fabric may comprise a multi-layer fabric having at least two layers of interwoven yarn, a cellulosic vveb 20 facing first layer and a dewatering felt facing second layer opposite the first layer.
):;ach layer of the interwoven yarns is further comprised of interwoven warp and weft yarns. For this embodiment, the first lamina further comprises tie yarns interwoven with tine respective yarns of the cellulosic web 20 facing layer and the dewatering felt facing hayer. Illustrative belts having multiple layers of interwoven yarns are found in commonly assigned U.S. Pat. Nos. 5,496,624 issued March 5, 1996 to Stelljes et al.
5,500,277 issued March 19, 1996 to Trokhan et al. and 5,566,724 issued October 22, 1996 to Trokhan et al.

The woven fabric of the imprinting fabric may serve as a reinforcing structure for the belt and provide support for a knuckle pattern 42 as illustrated in Figure 2. Such knuckle pattern preferably comprises a cured polymeric photosensitive resin disposed on the cellulosic web 20 contacting surface of the reinforcing structure 42.
Preferably the knuckle pattern 42 defines a predetermined pattern which imprints a like pattern onto the paper which is carried thereon. A particularly preferred pattern for the knuckle pattern 42 is an essentially continuous network. If the preferred essentially continuous network pattern is selected for the knuckle pattern 42, discrete deflection conduits will extend between the first surface and the second surface of the imprinting fabric. The essentially continuous network surrounds and defines the deflection conduits.
The projcctcd surface area of the continuous network top surface can provide about ~ to about S0 hercer~t of the hrcyected area of the cellulosic web 20 contacting surface ?2 of the imprinting fabric and is ~rcfcrably about ?5 lacrccnt to about ?~ percent of the web contacting surface 22 and still more preferably about 50 to about CS percent of the web contactin<~ surface 22.
The reinforcing structure 44 provides support for the knuckle pattern 42 and can comprise of various configurations, as previously described. Portions of the reinforcing structure 44 prevent fibers used in papermaking from passing completely through the deflection conduits and thereby reduces the occurrences of pinholes. If one does not wish to use a woven fabric for the reinforcing structure, a nonwoven element, screen, net, or a plate having a plurality of holes therethrough may provide adequate strength and support for the knuckle pattern 42 of the present invention.
The imprinting fabric having the knuckle pattern 42 disposed thereon according to the present invention may be made according to any of commonly assigned U.S.
Patents:
4,514,345, issued April 30, 1985 to Johnson et al.; 4,528,239, issued July 9, 1985 to Trokhan; 5,098,522, issued March 24, 1992; 5,260,171, issued Nov. 9, 1993 to Smurkoski et al.; 5,275,700, issued Jan. 4, 1994 to Trokhan; 5,328,565, issued July 12, 1994 to Rasch et al.; 5,334,289, issued Aug. 2, 1994 to Trokhan et al.;
5,431,786, issued July 1 l, 1995 to Rasch et al.; 5,496,624, issued March 5, 1996 to Stelljes, Jr. et al.;
5,500,277, issued March 19, 1996 to Trokhan et al.; 5,514,523, issued May 7, 1996 to Trokhan et al.; 5,554,467, issued Sept. 10, 1996, to Trokhan et al.;
5,566,724, issued Oct.
22, 1996 to Trokhan et al.; 5,624,790, issued April 29, 1997 to Trokhan et al.; and 5,628,876, issued May 13, 1997 to Ayers et al.
Preferably, the knuckle pattern 42 extends outwardly from the knuckles of the reinforcing structure a distance less than about 0.15 millimeters (0.006 inch), more preferably less than about 0.10 millimeters (0.004 inch) and still more preferably less than about 0.05 millimeters (0.002 inch). The knuckle pattern 42 can be approximately coincident the elevation of the knuckles of the reinforcing structure 44. By having the knuckle pattern 42 extending outwardly such a short distance from the reinforcing structure, a softer product may be produced. Specifically, the short distance provides for the absence of deflection or molding of the paper into the imprinting surface of the imprinting fabric as occurs in the prior art. Thus, the resulting paper will have a smoother surface and less tactile roughness.
Furthermore, by having the knuckle pattern 42 extend outwardly from the reinforcing structure such a short distance, the reinforcing structure will contact the paper at top surface knuckles disposed within the deflection conduits. This arrangement further compacts the paper at the points coincident the knuckles against the Yankee drying drum, decreasing the X-Y spacing between compacted regions.
Thus, more frequent and closely spaced contact between the cellulosic web 20 and the Yankee occurs. One of the benefits of the present invention is that the imprinting of the web and transfer to the Yankee occur simultaneously, eliminating the multi-operational steps involving separate compression nips of the.prior art. Also, by transfernng substantially full contact of the paper to the Yankee - rather than just the imprinted region as occurs in the prior art - full contact drying can be obtained.
If desired, in place of the imprinting fabric having the knuckle pattern 42 described above, a belt having a jacquard weave or Bobby weave may be utilized. Such a belt may be utilized as an imprinting member 30 or reinforcing structure.
Illustrative belts having a jacquard weave or Bobby weave are found in U.S. Pat. Nos. 5,429,686 issued July 4, 1995 to Chiu et al. and 5,672,248 issued Sept. 30, 1997 to Wendt et al.
Capillary Dewatering Member The capillary dewatering member 60 can be a dewatering felt. The dewatering felt is macroscopically monoplanar. The plane of the dewatering felt defines its X-Y

directions. Perpendicular to the X-Y directions and the plane of the dewatering felt is the Z~~direction of the second lamina.
A suitable dewatering felt comprises a nonwoven batt of natural or synthetic fibers joined, such as by needling, to a secondary base formed of woven filaments.
The secondary 5 base serves as a support structure for the batt of fibers. Suitable materials from which the nonwoven batt can be formed include but are not limited to natural fibers such as wool and synthetic fibers such as polyester and nylon. The fibers from which the batt is formed can have a denier of between about 3 and about 20 grams per 9000 meters of filament length.
The dewatering felt can have a layered construction, and can comprise a mixture 10 of fiber types and sizes. The layers of felt are formed to promote transport of water re<;eived from the web contacting surface of the imprinting member 30 away from a first felt surface and toward a second felt surface. The felt layer can have a relatively high density and relatively small pore size adjacent the felt surface in contact with the backside 32 of the imprinting member 30 as compared to the density and pore size of the 15 felt layer adjacent the felt surface in contact with the pressure roll 35.
The dewater~ing felt can have an air permeability of between about 5 and about cubic feet per minute (cfm) (0.002 m3/sec - 0.142 m3/sec) with an air permeability of less than 50 cfm (0.24 m'/sec) being preferred for use with the present invention.
Air permeability in cfm is a measure of the number of cubic feet of air per minute that pass through a one square foot area of a felt layer, at a pressure differential across the dewatering felt thickness of about 0.5 inch (12.7 mm) of water. The air permeability is measured using a Valmet permeability measuring device (Model Wigo Taifun Type 1000) available from the Valmet Corp. of Helsinki, Finland.
If desired, other capillary dewatering members may be used in place of the felt 60 described above. For example, a foam capillary dewatering member may be selected. Such a foam has an average pore size of less than 50 microns. Suitable foams may be made in accordance with commonly assigned U.S. Patent No. 5,260,345 issued Nov. 9, 1993 to DesMarais et al. and 5,625,222 issued July 22, 1997 to DesMarais et al.
Alternatively, a limiting orifice drying medium may be used as a capillary dewaterzng member. Such a medium may be made of various laminae, superimposed in faces to face relationship. The laminae have an interstitial flow area smaller than that of the interstitial areas between fibers in the paper. A suitable limiting orifice drying member may be made in accordance with commonly assigned U.S. Patents 5,625,961 issued May 6, 1997 to Ensign et al. and 5,274,930 issued Jan. 4, 1994 to Ensign et al.
The cellulosic web 20 may also be foreshortened, as is known in the art.
Foreshortening can be accomplished by creping the web 20 from a rigid surface, and preferably from a cylinder. A Yankee drying drum 70 is commonly used for this purpose. Creping is accomplished with a doctor blade as is well known in the art.
Creping may be accomplished according to commonly assigned U:S. Patent 4,919,756, issued April 24, 1992 to Sawdai .
Alternatively or additionally, foreshortening may be accomplished via wet microcontraction as taught in commonly assigned U.S. Patent 4,440,597, issued April 3, 1984 to Wells et al.
The Paper The tissue paper produced according to the present invention is macroscopically monoplanar where the plane of the paper defines its X-Y directions and having a Z
direction orthogonal thereto. The tissue paper of the present invention has two regions.
The first region comprises an imprinted region which is imprinted against the knuckle pattern 42 of the imprinting member 30. The second region of the paper comprises a plurality of domes dispersed throughout the imprinted region. The domes generally correspond in geometry, and during papermaking, in position to the deflection conduits 46 in the imprinting member 30.
The first region can comprise a plurality of imprinted regions. The first plurality of regions lie in X-Y plane; and the second plurality of regions extend outwardly from the X-Y plane. The second plurality of regions has a lower density than the first plurality of regions. The density of the first and second regions can be measured according to U.S. Patent No. 5,277,761 issued to Phan et al. 3anuary 11, 1994 and U.S.
Patent No. 5.443,691 issued to Phan et al. April 22, 1995 During foreshortening as described above, at least one foreshortening ridge is produced in the second plurality of regions. Such at least one foreshortening ridge is spaced apart from the plane in the Z direction.
While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is intended to cover in the appended claims all such changes and modifications that are within the scope of the invention.

Claims (7)

WHAT IS CLAIMED IS:
1. A process of removing water from a cellulosic web (20), the process comprising the steps of:
providing a first roll (70) and a second roll (35) juxtaposed together to form a nip therebetween;
providing an imprinting member (30) having a top surface (31) having a resinous knuckle pattern (42) disposed thereon for imprinting the web (20) and a bottom surface (32) opposed thereto, the imprinting member having an absolute void volume;
placing the cellulosic web (20) on the top surface (31) of the imprinting member (30);
providing a capillary dewatering member (60) having a top surface (62) and a bottom surface (64), wherein the top surface (62) is juxtaposed with the bottom surface (32) of the imprinting member (30);
interposing the cellulose web (20), the imprinting member (30), and the capillary dewatering member (60) in the nip, the cellulosic web (20) being in contact with the first roll (70), and the bottom surface (64) of the capillary dewatering member (60) being in contact with the second roll (35), whereby the volume of water is expelled from the cellulosic web (20) and through the imprinting member (30) forming a hydraulic connection between the cellulosic web (20) and the capillary dewatering member (60) such that the ratio of the volume of water expelled from the web (20) to the absolute void volume of the imprinting member (30) is at least about 0.5.
2. An apparatus for dewatering a cellulosic web (20) comprising a capillary dewatering member (60) having a top surface (62) and a bottom surface (64), and an imprinting member (30) comprising a top surface (31) having a resinous knuckle pattern (42) and a reinforcing structure (44) having a bottom surface (32) juxtaposed with the top surface (64) of the capillary dewatering member (60), the imprinting member (30) having a relative void volume ranging from about 0.05 to about 0.4.
3. An apparatus according to claim 2 wherein the imprinting member (30) has a relative void volume ranging from about 0.05 to about 0.28.
4. An apparatus according to claim 3 wherein the knuckle pattern (42) extends outwardly from the reinforcing structure (44) a distance less than about 0.15 millimeters.
5. An apparatus according to claim 2 wherein the imprinting member (30) further comprises a woven fabric, the imprinting member has a relative void volume that is less than about 0.3.
6. An apparatus according to claim 5 wherein the woven fabric is sanded.
7. An apparatus according to claim 6 wherein the woven fabric is unsanded, the imprinting member has a relative void volume that is less than about 0.4
CA002384241A 1999-09-07 2000-09-06 Papermaking apparatus and process for removing water from a cellulosic web Expired - Fee Related CA2384241C (en)

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Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6790315B2 (en) * 1999-06-17 2004-09-14 Metso Paper Karlstad Ab Drying section and method for drying a paper web
US6610619B2 (en) * 1999-12-29 2003-08-26 Kimberly-Clark Worldwide, Inc. Patterned felts for bulk and visual aesthetic development of a tissue basesheet
DE10129613A1 (en) * 2001-06-20 2003-01-02 Voith Paper Patent Gmbh Method and device for producing a fibrous web provided with a three-dimensional surface structure
DE10134906A1 (en) * 2001-07-18 2003-02-06 Voith Paper Patent Gmbh Method and device for producing a fibrous web provided with a three-dimensional structure
US7150110B2 (en) 2002-01-24 2006-12-19 Voith Paper Patent Gmbh Method and an apparatus for manufacturing a fiber web provided with a three-dimensional surface structure
US7294239B2 (en) 2004-01-30 2007-11-13 Voith Paper Patent Gmbh Method and an apparatus for manufacturing and drying a fiber web provided with a three-dimensional surface structure
EP2821135A1 (en) 2004-02-05 2015-01-07 EMD Millipore Corporation Porous adsorptive or chromatographic media
SE529130C2 (en) * 2004-05-26 2007-05-08 Metso Paper Karlstad Ab Paper machine for manufacturing fiber web of paper, comprises clothing that exhibits three-dimensional structure for structuring fiber web
US7510630B2 (en) * 2005-04-20 2009-03-31 Albany International Corp. Extended couch nip on cylinder former
PL2334869T3 (en) * 2008-09-11 2018-11-30 Albany International Corp. Permeable belt for the manufacture of tissue, towel and nonwovens
FR2953863B1 (en) * 2009-12-11 2012-01-06 Procter & Gamble BELT FOR MANUFACTURING PAPER
IT1400014B1 (en) * 2010-05-05 2013-05-09 Cartigliano Off Spa METHOD AND PLANT FOR LEATHER MOLDING
US8298376B2 (en) 2010-08-19 2012-10-30 The Procter & Gamble Company Patterned framework for a papermaking belt
US8313617B2 (en) 2010-08-19 2012-11-20 The Procter & Gamble Company Patterned framework for a papermaking belt
US8163130B2 (en) 2010-08-19 2012-04-24 The Proctor & Gamble Company Paper product having unique physical properties
US8211271B2 (en) 2010-08-19 2012-07-03 The Procter & Gamble Company Paper product having unique physical properties
CN102080346B (en) * 2010-11-25 2011-12-28 山东轻工业学院 Application of cation nano microcrystalline cellulose as paper reinforcing agent
RU2485236C2 (en) * 2011-05-12 2013-06-20 Виктор Иванович Макуха Compact device for pressing paper or cardboard
US9631659B2 (en) * 2013-04-26 2017-04-25 Honda Motor Co., Ltd. Multi-material joints and methods
CA2957329A1 (en) * 2014-08-05 2016-02-11 The Procter & Gamble Company Fibrous structures
US10132042B2 (en) 2015-03-10 2018-11-20 The Procter & Gamble Company Fibrous structures
EA034072B1 (en) 2014-09-25 2019-12-24 Джиписипи Айпи Холдингз Элэлси Method of making paper products using a multilayer creping belt
USD847519S1 (en) 2017-03-14 2019-05-07 The Procter & Gamble Company Paper product
USD845672S1 (en) * 2017-09-15 2019-04-16 Breathablebaby, Llc Crib liner
USD846307S1 (en) * 2017-09-15 2019-04-23 Breathablebaby, Llc Crib liner
USD862928S1 (en) * 2017-09-15 2019-10-15 Breathablebaby, Llc Crib liner
USD906695S1 (en) * 2017-09-15 2021-01-05 Breathablebaby, Llc Fabric material having a pattern resembling mesh
USD876105S1 (en) * 2017-09-15 2020-02-25 Breathablebaby, Llc Mesh with pattern
USD846310S1 (en) * 2017-09-15 2019-04-23 Breathablebaby, Llc Crib liner
USD845671S1 (en) * 2017-09-15 2019-04-16 Breathablebaby, Llc Crib liner
USD845670S1 (en) * 2017-09-15 2019-04-16 Breathablebaby, Llc Crib liner
USD859032S1 (en) * 2017-09-15 2019-09-10 Breathablebaby, Llc Crib liner
USD878769S1 (en) * 2017-09-15 2020-03-24 Breathablebaby, Llc Mesh with pattern
USD846309S1 (en) * 2017-09-15 2019-04-23 Breathablebaby, Llc Crib liner
USD846308S1 (en) * 2017-09-15 2019-04-23 Breathablebaby, Llc Crib liner
DE102018124016A1 (en) * 2018-09-28 2019-11-21 Voith Patent Gmbh Device and method for dewatering a fibrous web
CA3064406C (en) 2018-12-10 2023-03-07 The Procter & Gamble Company Fibrous structures
DE102019122292A1 (en) * 2019-08-20 2020-08-20 Voith Patent Gmbh Device and method for producing a fibrous web

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3537954A (en) 1967-05-08 1970-11-03 Beloit Corp Papermaking machine
US3573164A (en) 1967-08-22 1971-03-30 Procter & Gamble Fabrics with improved web transfer characteristics
US3905863A (en) 1973-06-08 1975-09-16 Procter & Gamble Process for forming absorbent paper by imprinting a semi-twill fabric knuckle pattern thereon prior to final drying and paper thereof
US3994771A (en) * 1975-05-30 1976-11-30 The Procter & Gamble Company Process for forming a layered paper web having improved bulk, tactile impression and absorbency and paper thereof
US4039246A (en) * 1976-01-22 1977-08-02 General Dynamics Corporation Optical scanning apparatus with two mirrors rotatable about a common axis
FI770610A (en) 1977-02-24 1978-08-25 Valmet Oy TISSUEPAPPERSMASKIN
FI771295A (en) 1977-04-22 1978-10-23 Nokia Oy Ab TISSUEPAPPERSMASKIN
US4309246A (en) 1977-06-20 1982-01-05 Crown Zellerbach Corporation Papermaking apparatus and method
US4421600A (en) 1981-07-06 1983-12-20 Crown Zellerbach Corporation Tri-nip papermaking system
US4529480A (en) 1983-08-23 1985-07-16 The Procter & Gamble Company Tissue paper
US4528239A (en) 1983-08-23 1985-07-09 The Procter & Gamble Company Deflection member
US5073235A (en) * 1990-04-12 1991-12-17 The Procter & Gamble Company Process for chemically treating papermaking belts
US5098522A (en) 1990-06-29 1992-03-24 The Procter & Gamble Company Papermaking belt and method of making the same using a textured casting surface
CA2083600C (en) * 1990-06-29 1996-11-12 Paul Dennis Trokhan Papermaking belt and method of making the same using differential light transmission techniques
US5679222A (en) * 1990-06-29 1997-10-21 The Procter & Gamble Company Paper having improved pinhole characteristics and papermaking belt for making the same
CA2069193C (en) * 1991-06-19 1996-01-09 David M. Rasch Tissue paper having large scale aesthetically discernible patterns and apparatus for making the same
US5245025A (en) 1991-06-28 1993-09-14 The Procter & Gamble Company Method and apparatus for making cellulosic fibrous structures by selectively obturated drainage and cellulosic fibrous structures produced thereby
TW244342B (en) * 1992-07-29 1995-04-01 Procter & Gamble
CA2178586C (en) 1993-12-20 2000-07-04 Robert Stanley Ampulski Wet pressed paper web and method of making the same
CA2192317C (en) 1994-06-29 2000-07-18 Paul Dennis Trokhan Web patterning apparatus comprising a felt layer and a photosensitive resin layer
US5556509A (en) 1994-06-29 1996-09-17 The Procter & Gamble Company Paper structures having at least three regions including a transition region interconnecting relatively thinner regions disposed at different elevations, and apparatus and process for making the same
US5871887A (en) * 1994-06-29 1999-02-16 The Procter & Gamble Company Web patterning apparatus comprising a felt layer and a photosensitive resin layer
US5549790A (en) 1994-06-29 1996-08-27 The Procter & Gamble Company Multi-region paper structures having a transition region interconnecting relatively thinner regions disposed at different elevations, and apparatus and process for making the same
EP0809729B1 (en) 1995-02-15 2000-10-11 The Procter & Gamble Company Method of applying a photosensitive resin to a substrate for use in papermaking
US5629052A (en) 1995-02-15 1997-05-13 The Procter & Gamble Company Method of applying a curable resin to a substrate for use in papermaking
JPH11510567A (en) * 1995-06-28 1999-09-14 ザ、プロクター、エンド、ギャンブル、カンパニー Crepe tissue paper showing unique combination of physical attributes
US5693187A (en) * 1996-04-30 1997-12-02 The Procter & Gamble Company High absorbance/low reflectance felts with a pattern layer
US5840403A (en) * 1996-06-14 1998-11-24 The Procter & Gamble Company Multi-elevational tissue paper containing selectively disposed chemical papermaking additive
US6010598A (en) * 1997-05-08 2000-01-04 The Procter & Gamble Company Papermaking belt with improved life
US5830316A (en) 1997-05-16 1998-11-03 The Procter & Gamble Company Method of wet pressing tissue paper with three felt layers
US5900122A (en) * 1997-05-19 1999-05-04 The Procter & Gamble Company Cellulosic web, method and apparatus for making the same using papermaking belt having angled cross-sectional structure, and method of making the belt
US5948210A (en) * 1997-05-19 1999-09-07 The Procter & Gamble Company Cellulosic web, method and apparatus for making the same using papermaking belt having angled cross-sectional structure, and method of making the belt
US5938893A (en) * 1997-08-15 1999-08-17 The Procter & Gamble Company Fibrous structure and process for making same
US5906710A (en) * 1997-06-23 1999-05-25 The Procter & Gamble Company Paper having penninsular segments
JP2002506936A (en) 1998-03-17 2002-03-05 ザ、プロクター、エンド、ギャンブル、カンパニー Apparatus and method for producing structured paper and structured paper produced thereby
US6860968B1 (en) * 2000-05-24 2005-03-01 Kimberly-Clark Worldwide, Inc. Tissue impulse drying

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MXPA02002493A (en) 2002-08-27
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DE60015580T2 (en) 2006-03-02
EP1212483B2 (en) 2009-07-29
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DE60015580T3 (en) 2010-01-28
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CA2384241A1 (en) 2001-03-15
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