CA2412607A1 - Novel photoinitiators and applications therefor - Google Patents
Novel photoinitiators and applications therefor Download PDFInfo
- Publication number
- CA2412607A1 CA2412607A1 CA002412607A CA2412607A CA2412607A1 CA 2412607 A1 CA2412607 A1 CA 2412607A1 CA 002412607 A CA002412607 A CA 002412607A CA 2412607 A CA2412607 A CA 2412607A CA 2412607 A1 CA2412607 A1 CA 2412607A1
- Authority
- CA
- Canada
- Prior art keywords
- carbon atoms
- alkyl group
- photoinitiator
- group
- generating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 24
- 125000000217 alkyl group Chemical group 0.000 claims abstract 16
- 238000000034 method Methods 0.000 claims abstract 14
- 239000000203 mixture Substances 0.000 claims abstract 10
- 125000003545 alkoxy group Chemical group 0.000 claims abstract 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract 4
- 125000003118 aryl group Chemical group 0.000 claims abstract 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 4
- 239000001257 hydrogen Substances 0.000 claims abstract 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 4
- 239000000463 material Substances 0.000 claims abstract 3
- 230000000379 polymerizing effect Effects 0.000 claims abstract 2
- -1 hexafluorophosphate Chemical compound 0.000 claims 5
- 230000001678 irradiating effect Effects 0.000 claims 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 2
- 230000005855 radiation Effects 0.000 claims 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 238000010030 laminating Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
Abstract
The present invention is directed to new, energy-efficient, photoinitiators having the following formula: whrein Z each independlently represent the formula (II) wherein R1, R2, R3 and R4 each independently represent hydrogen, an alkyl group having from one to six carbon atoms, an alkoxy group having from one to six carbon atoms, or a halogen-substituted alkyl group; R5, R6, R7 and R8 each independently represent an alkyl group having from one to six carbon atoms, an aryl group, or a halogen-substituted alkyl group having from one to six carbon atoms; wherein R9 represents (R10)2O or (R10)3N, wherein R10 represents H or an alkyl group having from one to eight carbon atoms; and wherein R11 represents H, an alkyl group having from one to eight carbon atoms, a benzyl group or an aralkyl group. The present invention is also directed to a method of generating a reactive species, methods of polymerizing polymerizable materials, methods of curing an unsaturated oligomer/monomer mixture, and methods of laminating using the photoinitiators of the present invention. In addition, the present invention is directed to ink compositions, adhesive compositions and resins, and methods of printing using the above-described photoinitiators.
Claims (20)
1. A photoinitiator having the general formula:
wherein Z each independently represents wherein R1, R2, R3 and R4 each independently represent hydrogen, an alkyl group having from one to six carbon atoms, an alkoxy group having from one to six carbon atoms, or a halogen-substituted alkyl group; R5, R6, R7 and R8 each independently represent an alkyl group having from one to six carbon atoms, an aryl group, or a halogen-substituted alkyl group having from one to six carbon atoms; wherein R9 represents (R10)2O or (R10)3N;
wherein R10 represents H or an alkyl group having from one to eight carbon atoms; and wherein R11 represents H, an alkyl group having from one to eight carbon atoms, a benzyl group or an aralkyl group.
wherein Z each independently represents wherein R1, R2, R3 and R4 each independently represent hydrogen, an alkyl group having from one to six carbon atoms, an alkoxy group having from one to six carbon atoms, or a halogen-substituted alkyl group; R5, R6, R7 and R8 each independently represent an alkyl group having from one to six carbon atoms, an aryl group, or a halogen-substituted alkyl group having from one to six carbon atoms; wherein R9 represents (R10)2O or (R10)3N;
wherein R10 represents H or an alkyl group having from one to eight carbon atoms; and wherein R11 represents H, an alkyl group having from one to eight carbon atoms, a benzyl group or an aralkyl group.
2. The photoinitiator of Claim 1, wherein the photoinitiator comprises:
or
or
3. The photoinitiator of Claim 1, wherein the photoinitiator is associated with one or more counterions.
4. The photoinitiator of Claim 1, wherein the one or more counterions comprise tetraphenylboron, tetrachloroboron, tetrafluoroboron, hexafluorophosphate, perchlorate, or a combination thereof.
5. The photoinitiator of Claim 4, wherein the one or more counterions comprise tetraphenylboron or tetrafluoroboron.
6. The photoinitiator of Claim 3, wherein the photoinitiator and the one or more counterions comprise
7. A method of generating a reactive species, comprising:
irradiating the photoinitiator of Claim 1 with radiation.
irradiating the photoinitiator of Claim 1 with radiation.
8. A method of polymerizing a polymerizable material, comprising:
irradiating an admixture of a polymerizable material and the photoinitiator of Claim 1.
irradiating an admixture of a polymerizable material and the photoinitiator of Claim 1.
9. A method of generating a reactive species, comprising:
irradiating a photoinitiator with radiation, wherein at least one cationic free radical and at least one nitrogen radical species are generated.
irradiating a photoinitiator with radiation, wherein at least one cationic free radical and at least one nitrogen radical species are generated.
10. The method of generating a reactive species of Claim 9, wherein the photoinitiator has the general formula:
wherein Z each independently represent wherein R1, R2, R3 and R4 each independently represent hydrogen, an alkyl group having from one to six carbon atoms, an alkoxy group having from one to six carbon atoms, or a halogen-substituted alkyl group; R5, R6, R7 and R8 each independently represent an alkyl group having from one to six carbon atoms, an aryl group, or a halogen-substituted alkyl group having from one to six carbon atoms; wherein R9 represents (R10)2O or (R10)3N;
wherein R10 represents H or an alkyl group having from one to eight carbon atoms; and wherein R11 represents H, an alkyl group having from one to eight carbon atoms, a benzyl group or an aralkyl group.
wherein Z each independently represent wherein R1, R2, R3 and R4 each independently represent hydrogen, an alkyl group having from one to six carbon atoms, an alkoxy group having from one to six carbon atoms, or a halogen-substituted alkyl group; R5, R6, R7 and R8 each independently represent an alkyl group having from one to six carbon atoms, an aryl group, or a halogen-substituted alkyl group having from one to six carbon atoms; wherein R9 represents (R10)2O or (R10)3N;
wherein R10 represents H or an alkyl group having from one to eight carbon atoms; and wherein R11 represents H, an alkyl group having from one to eight carbon atoms, a benzyl group or an aralkyl group.
11. The method of generating a reactive species of Claim 10, wherein the photoinitiator comprises:
12. The method of generating a reactive species of Claim 10, wherein the photoinitiator is associated with one or more counterions.
13. The method of generating a reactive species of Claim 12, wherein the one or more counterions comprise tetraphenylboron, tetrachloroboron, tetrafluoroboron, hexafluorophosphate, perchlorate, or a combination thereof.
14. The method of generating a reactive species of Claim 13, wherein the one or more counterions comprise tetraphenylboron or tetrafluoroboron.
15. The method of generating a reactive species of Claim 12, wherein the photoinitiator and the one or more counterions comprise
16. A photoreactive composition comprising at least one photoinitiator and at least one counterion, wherein the composition is capable of generating at least one cationic free radical and at least one nitrogen radical species.
17. The photoreactive composition of Claim 16, wherein the photoinitiator having the general formula:
wherein Z each independently represent wherein R1, R2, R3 and R4 each independently represent hydrogen, an alkyl group having from one to six carbon atoms, an alkoxy group having from one to six carbon atoms, or a halogen-substituted alkyl group; R5, R6, R7 and R8 each independently represent an alkyl group having from one to six carbon atoms, an aryl group, or a halogen-substituted alkyl group having from one to six carbon atoms; wherein R9 represents (R10)2O or (R10)3N;
wherein R10 represents H or an alkyl group having from one to eight carbon atoms; and wherein R11 represents H, an alkyl group having from one to eight carbon atoms, a benzyl group or an aralkyl group.
wherein Z each independently represent wherein R1, R2, R3 and R4 each independently represent hydrogen, an alkyl group having from one to six carbon atoms, an alkoxy group having from one to six carbon atoms, or a halogen-substituted alkyl group; R5, R6, R7 and R8 each independently represent an alkyl group having from one to six carbon atoms, an aryl group, or a halogen-substituted alkyl group having from one to six carbon atoms; wherein R9 represents (R10)2O or (R10)3N;
wherein R10 represents H or an alkyl group having from one to eight carbon atoms; and wherein R11 represents H, an alkyl group having from one to eight carbon atoms, a benzyl group or an aralkyl group.
18. The photoreactive composition of Claim 16, wherein the photoinitiator comprises:
19. The photoreactive composition of Claim 16, wherein the at least one counterion comprises tetraphenylboron, tetrachloroboron, tetrafluoroboron, hexafluorophosphate, perchlorate, or a combination thereof.
20. The photoreactive composition of Claim 16, wherein the composition comprises
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US21242800P | 2000-06-19 | 2000-06-19 | |
US60/212,428 | 2000-06-19 | ||
PCT/US2001/019525 WO2002000735A1 (en) | 2000-06-19 | 2001-06-19 | Novel photoinitiators and applications therefor |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2412607A1 true CA2412607A1 (en) | 2002-01-03 |
CA2412607C CA2412607C (en) | 2010-12-21 |
Family
ID=22790958
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2412607A Expired - Fee Related CA2412607C (en) | 2000-06-19 | 2001-06-19 | Novel photoinitiators and applications therefor |
Country Status (10)
Country | Link |
---|---|
US (1) | US6486227B2 (en) |
EP (1) | EP1297022B1 (en) |
JP (1) | JP2004501987A (en) |
KR (1) | KR100772772B1 (en) |
AT (1) | ATE333471T1 (en) |
AU (1) | AU2001269905A1 (en) |
CA (1) | CA2412607C (en) |
DE (1) | DE60121588T2 (en) |
MX (1) | MXPA02012011A (en) |
WO (1) | WO2002000735A1 (en) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1519839B1 (en) * | 2002-07-01 | 2011-10-05 | Inca Digital Printers Limited | Printing with ink |
GB2396331A (en) * | 2002-12-20 | 2004-06-23 | Inca Digital Printers Ltd | Curing ink |
EP1572467B1 (en) * | 2002-12-20 | 2019-10-23 | Inca Digital Printers Limited | Curing |
US8409618B2 (en) | 2002-12-20 | 2013-04-02 | Kimberly-Clark Worldwide, Inc. | Odor-reducing quinone compounds |
US7666410B2 (en) | 2002-12-20 | 2010-02-23 | Kimberly-Clark Worldwide, Inc. | Delivery system for functional compounds |
US6780896B2 (en) | 2002-12-20 | 2004-08-24 | Kimberly-Clark Worldwide, Inc. | Stabilized photoinitiators and applications thereof |
US7262229B2 (en) * | 2004-05-03 | 2007-08-28 | Flint Group | Ink for excimer curing |
FR2876983B1 (en) * | 2004-10-22 | 2007-02-16 | Eads Space Transp Sa Sa | RIGIDIFICATION OF INFLATABLE DEPLOYMENT STRUCTURES ESPECIALLY FOR SPATIAL USE |
US7763061B2 (en) | 2004-12-23 | 2010-07-27 | Kimberly-Clark Worldwide, Inc. | Thermal coverings |
TWI476292B (en) * | 2005-08-30 | 2015-03-11 | 尖端科技材料股份有限公司 | Boron ion implantation using alternative fluorinated boron precursors, and formation of large boron hydrides for implantation |
US20100112795A1 (en) * | 2005-08-30 | 2010-05-06 | Advanced Technology Materials, Inc. | Method of forming ultra-shallow junctions for semiconductor devices |
US7935538B2 (en) | 2006-12-15 | 2011-05-03 | Kimberly-Clark Worldwide, Inc. | Indicator immobilization on assay devices |
US7785496B1 (en) | 2007-01-26 | 2010-08-31 | Clemson University Research Foundation | Electrochromic inks including conducting polymer colloidal nanocomposites, devices including the electrochromic inks and methods of forming same |
US8052829B2 (en) * | 2007-10-26 | 2011-11-08 | Dymax Corporation | Photopolymerizable compositions containing an oxonol dye |
US20090157024A1 (en) * | 2007-12-14 | 2009-06-18 | Kimberly-Clark Worldwide, Inc. | Hydration Test Devices |
US8134042B2 (en) | 2007-12-14 | 2012-03-13 | Kimberly-Clark Worldwide, Inc. | Wetness sensors |
US8222476B2 (en) | 2008-10-31 | 2012-07-17 | Kimberly-Clark Worldwide, Inc. | Absorbent articles with impending leakage sensors |
US20110021011A1 (en) | 2009-07-23 | 2011-01-27 | Advanced Technology Materials, Inc. | Carbon materials for carbon implantation |
US8138071B2 (en) * | 2009-10-27 | 2012-03-20 | Advanced Technology Materials, Inc. | Isotopically-enriched boron-containing compounds, and methods of making and using same |
US8062965B2 (en) * | 2009-10-27 | 2011-11-22 | Advanced Technology Materials, Inc. | Isotopically-enriched boron-containing compounds, and methods of making and using same |
US8598022B2 (en) | 2009-10-27 | 2013-12-03 | Advanced Technology Materials, Inc. | Isotopically-enriched boron-containing compounds, and methods of making and using same |
US8779383B2 (en) | 2010-02-26 | 2014-07-15 | Advanced Technology Materials, Inc. | Enriched silicon precursor compositions and apparatus and processes for utilizing same |
TWI582836B (en) | 2010-02-26 | 2017-05-11 | 恩特葛瑞斯股份有限公司 | Method and apparatus for enhanced lifetime and performance of ion source in an ion implantation system |
US8623292B2 (en) | 2010-08-17 | 2014-01-07 | Kimberly-Clark Worldwide, Inc. | Dehydration sensors with ion-responsive and charged polymeric surfactants |
CN106237934B (en) | 2010-08-30 | 2019-08-27 | 恩特格里斯公司 | By solid material prepare compound or in which mesosome and use the device and method of the compound and intermediate |
TWI583442B (en) | 2011-10-10 | 2017-05-21 | 恩特葛瑞斯股份有限公司 | B2f4 manufacturing process |
SG11201404872SA (en) | 2012-02-14 | 2014-09-26 | Advanced Tech Materials | Carbon dopant gas and co-flow for implant beam and source life performance improvement |
SG10201801299YA (en) | 2013-08-16 | 2018-03-28 | Entegris Inc | Silicon implantation in substrates and provision of silicon precursor compositions therefor |
KR102587532B1 (en) | 2015-02-27 | 2023-10-11 | 킴벌리-클라크 월드와이드, 인크. | Absorbent Article Leakage Evaluation System |
WO2018186842A1 (en) | 2017-04-05 | 2018-10-11 | Kimberly-Clark Worldwide, Inc. | Garment for detecting absorbent article leakage and methods of detecting absorbent article leakage utilizing the same |
Family Cites Families (359)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA461082A (en) | 1949-11-15 | Jozsef Biro Laszlo | Writing paste | |
US28225A (en) | 1860-05-08 | Improvement in apparatus for defecating cane-juice | ||
CA779239A (en) | 1968-02-27 | General Electric Company | Information recording | |
CA571792A (en) | 1959-03-03 | Ciba Limited | Process for printing textiles and printing preparations therefor | |
US1325971A (en) | 1919-12-23 | Kazue akashi | ||
CA458808A (en) | 1949-08-09 | L. Gardner Frank | Cleat assembly for athletic shoes | |
US3123647A (en) | 1964-03-03 | Certificate of correction | ||
US28789A (en) | 1860-06-19 | Boiler foe | ||
CA93103A (en) | 1905-04-18 | 1905-05-16 | George Nikel | Elevator bucket |
BE398850A (en) | 1932-09-30 | |||
US1013544A (en) | 1910-08-30 | 1912-01-02 | Equilibrator Company | Ink. |
US1364406A (en) | 1920-04-24 | 1921-01-04 | Chester Novelty Company Inc | Ink-stick |
DE498028C (en) | 1929-05-15 | 1930-07-14 | I G Farbenindustrie Akt Ges | Fixable layer for the color fading process |
GB355686A (en) | 1929-06-08 | 1931-08-26 | Kodak Ltd | Improvements in or relating to combined kinematographic and sound record films |
DE503314C (en) | 1929-07-30 | 1930-07-29 | I G Farbenindustrie Akt Ges | Layers of fading paint |
BE369421A (en) | 1929-09-09 | |||
BE381968A (en) | 1930-08-14 | |||
BE390157A (en) | 1931-08-04 | |||
US2062304A (en) | 1931-11-19 | 1936-12-01 | Gaspar Bela | Process for the production of a colored sound film |
US2049005A (en) | 1932-01-04 | 1936-07-28 | Gaspar Bela | Color-photographic bleach out dyestuff layers |
BE397731A (en) | 1932-07-21 | |||
US2125015A (en) | 1932-10-26 | 1938-07-26 | Gaspar Bela | Multicolor photographic material and a process for using the same |
US2106539A (en) | 1933-07-13 | 1938-01-25 | Gen Aniline Works Inc | Stable diazo salt preparations and process of preparing them |
US2054390A (en) | 1934-08-09 | 1936-09-15 | Photographic bleachjng-out layers | |
DE678456C (en) | 1935-01-05 | 1939-07-18 | Bela Gaspar Dr | Process for the production of photographic or cinematographic images with and without sound recordings, in which dye images are combined with a silver image |
BE417861A (en) | 1935-05-04 | |||
US2220178A (en) | 1936-01-09 | 1940-11-05 | Gen Aniline & Film Corp | Process of producing a sound track on a light-sensitive color film |
GB486006A (en) | 1936-10-27 | 1938-05-27 | Christopher William Crouch Whe | Improvements in colour photography |
US2159280A (en) | 1936-12-31 | 1939-05-23 | Eastman Kodak Co | Sound image on multilayer film |
GB492711A (en) | 1937-03-22 | 1938-09-22 | Bela Gaspar | Process for the production of a combined coloured picture and sound record film |
CH197808A (en) | 1937-06-28 | 1938-05-31 | Fritz Busenhart | Air humidifier on radiators. |
US2230590A (en) | 1938-01-22 | 1941-02-04 | Gen Aniline & Film Corp | Color photographic process |
BE433290A (en) | 1938-03-16 | |||
GB518612A (en) | 1938-07-27 | 1940-03-04 | Bela Gaspar | Process for the manufacture of combined picture and sound films |
BE437152A (en) | 1938-12-03 | |||
US2416145A (en) | 1938-12-27 | 1947-02-18 | Eterpen Sa Financiera | Writing paste |
GB539912A (en) | 1939-08-07 | 1941-09-29 | Durand & Huguenin Ag | Process for the manufacture of new preparations containing the components for the production of ice colours and their application to textile printing |
BE439901A (en) | 1939-11-20 | |||
US2312751A (en) | 1940-05-08 | 1943-03-02 | Standard Oil Dev Co | Preparation of unsaturated ketones |
GB600451A (en) | 1940-11-06 | 1948-04-09 | American Cyanamid Co | Direct dye planographic printing compositions |
US2346090A (en) | 1942-08-19 | 1944-04-04 | Eastman Kodak Co | Photographic bleach-out layer |
FR996646A (en) | 1945-05-11 | 1951-12-24 | Process for obtaining color films by subtractive trichrome synthesis, and its application to sound cinematography | |
GB618616A (en) | 1946-09-25 | 1949-02-24 | George Trapp Douglas | Improvements in textile printing processes |
GB626727A (en) | 1946-11-29 | 1949-07-20 | Geoffrey Bond Harrison | Improvements in or relating to the recording of sound tracks in colour film |
US2647080A (en) | 1950-06-30 | 1953-07-28 | Du Pont | Light-stabilized photopolymerization of acrylic esters |
DE903529C (en) | 1951-09-01 | 1954-02-08 | Kalle & Co Ag | Photosensitive layers |
US2732301A (en) | 1952-10-15 | 1956-01-24 | Chxcxch | |
BE529607A (en) | 1953-06-18 | |||
NL189059A (en) | 1953-07-13 | |||
DE1119510B (en) | 1956-03-14 | 1961-12-14 | Bayer Ag | Process for the production of insoluble, crosslinked high molecular weight polyesters |
DE1047013B (en) | 1956-05-15 | 1958-12-18 | Agfa Ag | Process for photothermographic imaging |
DE1039835B (en) | 1956-07-21 | 1958-09-25 | Bayer Ag | Photographic process for the preparation of dye images |
DE1040562B (en) | 1956-08-23 | 1958-10-09 | Hoechst Ag | Process for the production of solid, durable diazonium compounds |
DE1047787B (en) | 1956-08-24 | 1958-12-31 | Hoechst Ag | Process for the production of solid, durable diazonium compounds |
DE1045414B (en) | 1956-09-19 | 1958-12-04 | Hoechst Ag | Process for the production of solid, durable diazonium compounds |
US2992198A (en) | 1956-12-24 | 1961-07-11 | Funahashi Takaji | Process of producing liquid color |
US2936241A (en) | 1957-05-16 | 1960-05-10 | Sperry Rand Corp | Non-printing indicia ink |
US2940853A (en) | 1958-08-21 | 1960-06-14 | Eastman Kodak Co | Azide sensitized resin photographic resist |
DE1154069B (en) | 1958-12-27 | 1963-09-12 | Bayer Ag | Process for the production of water-insoluble azo dyes on structures made of aromatic polyesters, in particular polyethylene terephthalates, synthetic polyamides and polyurethanes |
IT649406A (en) | 1960-03-24 | |||
US3104973A (en) | 1960-08-05 | 1963-09-24 | Horizons Inc | Photographic bleaching out of cyanine dyes |
NL270002A (en) | 1960-10-08 | |||
NL270722A (en) | 1960-10-27 | |||
US3154416A (en) | 1961-03-30 | 1964-10-27 | Horizons Inc | Photographic process |
US3121632A (en) | 1961-08-30 | 1964-02-18 | Horizons Inc | Photographic process and composition including leuco triphenylmethane dyes |
US3155509A (en) | 1961-09-05 | 1964-11-03 | Horizons Inc | Photographic process |
US3140948A (en) | 1961-10-18 | 1964-07-14 | Horizons Inc | Photography |
US3445234A (en) | 1962-10-31 | 1969-05-20 | Du Pont | Leuco dye/hexaarylbiimidazole imageforming composition |
US3305361A (en) | 1962-12-28 | 1967-02-21 | Gen Electric | Information recording |
US3300314A (en) | 1963-02-01 | 1967-01-24 | Eastman Kodak Co | Nonsilver, light-sensitive photographic elements |
US3284205A (en) | 1963-09-17 | 1966-11-08 | Horizons Inc | Benzotriazole and heterocyclic ketimide activators for leuco compounds |
NL125868C (en) | 1964-01-29 | |||
US3359109A (en) | 1964-04-29 | 1967-12-19 | Du Pont | Leuco dye-n, n. o-triacylhydroxylamine light-sensitive dye former compositions |
US3341492A (en) | 1964-05-11 | 1967-09-12 | Celanese Corp | Polyamides stabilized with iodine and/or bromine substituted phenols |
GB1070863A (en) | 1964-06-12 | 1967-06-07 | Gevaert Photo Prod Nv | Light-sensitive photographic materials |
US3397984A (en) | 1965-08-19 | 1968-08-20 | Eastman Kodak Co | Silver dye bleach materials improving image density |
US3418118A (en) | 1965-06-03 | 1968-12-24 | Du Pont | Photographic processes and products |
US3479185A (en) | 1965-06-03 | 1969-11-18 | Du Pont | Photopolymerizable compositions and layers containing 2,4,5-triphenylimidazoyl dimers |
US3488269A (en) | 1965-09-15 | 1970-01-06 | Technical Operations Inc | Labile hydrogen initiators for visible light photopolymerization |
US3502476A (en) | 1965-10-20 | 1970-03-24 | Konishiroku Photo Ind | Light-sensitive photographic materials |
GB1184054A (en) | 1966-04-05 | 1970-03-11 | Agfa Gevaert Nv | Thermographic Recording Processes and Materials |
US3528814A (en) | 1966-04-29 | 1970-09-15 | Agfa Gevaert Ag | Sensitization of light-sensitive polymers |
US3547646A (en) | 1966-12-16 | 1970-12-15 | Keuffel & Esser Co | Light-sensitive imaging material containing hydrazones |
US3503744A (en) | 1967-02-16 | 1970-03-31 | Keuffel & Esser Co | Photographic bleaching out of azomethine and azoaniline dyes |
US3607863A (en) | 1967-02-28 | 1971-09-21 | Dyckerhoff Zementwerke Ag | Clathrate compounds |
SE312870B (en) | 1967-07-17 | 1969-07-28 | Asea Ab | |
US3642472A (en) | 1967-08-30 | 1972-02-15 | Holotron Corp | Bleaching of holograms |
US3574624A (en) | 1968-02-08 | 1971-04-13 | Eastman Kodak Co | Photographic elements containing dithiolium salts |
US3615562A (en) | 1968-04-25 | 1971-10-26 | Rca Corp | Cyanine dye photographic film |
US3549367A (en) | 1968-05-24 | 1970-12-22 | Du Pont | Photopolymerizable compositions containing triarylimidazolyl dimers and p-aminophenyl ketones |
DE1769854C3 (en) | 1968-07-26 | 1982-08-19 | Bayer Ag, 5090 Leverkusen | Photoinitiators and processes for photopolymerization |
US3595655A (en) | 1968-10-03 | 1971-07-27 | Little Inc A | Non-silver direct positive dyes bleachout system using polymethine dyes and colorless activators |
US3595658A (en) | 1968-10-03 | 1971-07-27 | Little Inc A | Non-silver direct positive dye bleachout system using polymethine dyes and colored activators |
US3595659A (en) | 1968-10-03 | 1971-07-27 | Little Inc A | Non-silver direct positive dye bleachout system using indigoid dyes and colored activators |
US3595657A (en) | 1968-10-03 | 1971-07-27 | Little Inc A | Non-silver direct positive dye bleachout system using indigoid dyes and colorless activators |
US3914166A (en) | 1968-11-06 | 1975-10-21 | Bayer Ag | Butyric acid derivatives as novel photosensitizers |
JPS4912180B1 (en) | 1969-04-21 | 1974-03-22 | ||
US3697280A (en) | 1969-05-22 | 1972-10-10 | Du Pont | Hexaarylbiimidazole-selected aromatic hydrocarbon compositions |
US3647467A (en) | 1969-05-22 | 1972-03-07 | Du Pont | Hexaarylbiimidazole-heterocyclic compound compositions |
US3617288A (en) | 1969-09-12 | 1971-11-02 | Minnesota Mining & Mfg | Propenone sensitizers for the photolysis of organic halogen compounds |
BE757961A (en) * | 1969-10-24 | 1971-04-01 | Ici Ltd | METHODS FOR SAVING AN IMAGE |
US3695879A (en) | 1970-04-20 | 1972-10-03 | Ibm | Hologram life extension |
US3689565A (en) | 1970-05-04 | 1972-09-05 | Horst Hoffmann | {60 -methylolbenzoin ethers |
US3873500A (en) | 1970-06-16 | 1975-03-25 | Agency Ind Science Techn | Photosensitive polymers |
NL7113828A (en) | 1970-10-15 | 1972-04-18 | ||
JPS4926584B1 (en) | 1970-11-26 | 1974-07-10 | ||
US3705043A (en) | 1970-12-07 | 1972-12-05 | Dick Co Ab | Infrared absorptive jet printing ink composition |
US3671251A (en) | 1970-12-10 | 1972-06-20 | Eastman Kodak Co | Sensitized pyrylium photobleachable dye in gelatin |
US3707371A (en) | 1970-12-14 | 1972-12-26 | Xerox Corp | Photosensitive element comprising a polymer matrix including styrene,auramine o,and a proxide and the use thereof in volume recording |
JPS509178B1 (en) | 1970-12-28 | 1975-04-10 | ||
US3671096A (en) | 1971-02-03 | 1972-06-20 | Us Navy | Erasable holographic recording |
US3887450A (en) | 1971-02-04 | 1975-06-03 | Dynachem Corp | Photopolymerizable compositions containing polymeric binding agents |
US3694241A (en) | 1971-04-19 | 1972-09-26 | Grace W R & Co | Method for chemically printing |
US3901779A (en) | 1971-05-13 | 1975-08-26 | Dow Chemical Co | Vinyl ester resin and process for curing same with ionizing radiation in the presence of amines |
BE787339A (en) | 1971-09-14 | 1973-02-09 | Agfa Gevaert Nv | PHOTOGRAPHIC REGISTRATION AND REPRODUCTION OF INFORMATION |
GB1408265A (en) | 1971-10-18 | 1975-10-01 | Ici Ltd | Photopolymerisable composition |
US4004998A (en) | 1971-11-18 | 1977-01-25 | Sun Chemical Corporation | Photopolymerizable compounds and compositions comprising the product of the reaction of a hydroxy-containing ester and a monocarboxy-substituted benzophenone |
US3926641A (en) | 1971-11-18 | 1975-12-16 | Sun Chemical Corp | Photopolymerizable compositions comprising polycarboxysubstituted benzophenone reaction products |
US3765896A (en) | 1971-11-22 | 1973-10-16 | Eastman Kodak Co | Photographic element containing a light sensitive photobleachant and a colored stable 2-amino-aryl-7-oxyl-3-oxide-2-imidazoline free radical |
US3729313A (en) | 1971-12-06 | 1973-04-24 | Minnesota Mining & Mfg | Novel photosensitive systems comprising diaryliodonium compounds and their use |
US3801329A (en) | 1971-12-17 | 1974-04-02 | Union Carbide Corp | Radiation curable coating compositions |
JPS5034966B2 (en) | 1972-07-24 | 1975-11-12 | ||
US3914165A (en) | 1972-09-18 | 1975-10-21 | Desoto Inc | Radiation curable non-gelled michael addition reaction products |
US4012256A (en) | 1972-09-25 | 1977-03-15 | Keuffel & Esser Company | Photo-imaging utilizing alkali-activated photopolymerizable compositions |
US3933682A (en) | 1973-01-31 | 1976-01-20 | Sun Chemical Corporation | Photopolymerization co-initiator systems |
JPS5148516B2 (en) | 1973-02-07 | 1976-12-21 | ||
US3915824A (en) | 1973-03-30 | 1975-10-28 | Scm Corp | Uv and laser curing of the polymerizable binder |
US4251622A (en) | 1973-05-25 | 1981-02-17 | Nippon Paint Co., Ltd. | Photo-sensitive composition for dry formation of image |
JPS5040538A (en) | 1973-07-06 | 1975-04-14 | ||
JPS5041536A (en) | 1973-08-03 | 1975-04-16 | ||
GB1469641A (en) | 1973-09-20 | 1977-04-06 | Agfa Gevaert | Stabilization of photosensitive recording material |
US4022674A (en) | 1973-10-11 | 1977-05-10 | Sun Chemical Corporation | Photopolymerizable compounds and compositions comprising the product of the reaction of a monomeric ester and a polycarboxy-substituted benzophenone |
US3960685A (en) | 1973-11-12 | 1976-06-01 | Sumitomo Chemical Company, Limited | Photosensitive resin composition containing pullulan or esters thereof |
US3988154A (en) | 1974-02-19 | 1976-10-26 | Eastman Kodak Company | Photographic supports and elements utilizing photobleachable omicron-nitroarylidene dyes |
US3984248A (en) | 1974-02-19 | 1976-10-05 | Eastman Kodak Company | Photographic polymeric film supports containing photobleachable o-nitroarylidene dyes |
US4058400A (en) | 1974-05-02 | 1977-11-15 | General Electric Company | Cationically polymerizable compositions containing group VIa onium salts |
US4043819A (en) | 1974-06-11 | 1977-08-23 | Ciba-Geigy Ag | Photo-polymerizable material for the preparation of stable polymeric images and process for making them by photopolymerization in a matrix |
US4017652A (en) | 1974-10-23 | 1977-04-12 | Ppg Industries, Inc. | Photocatalyst system and ultraviolet light curable coating compositions containing the same |
US4179577A (en) | 1974-11-30 | 1979-12-18 | Ciba-Geigy Corporation | Polymerisable esters derived from a phenolic unsaturated ketone |
US4181807A (en) | 1974-11-30 | 1980-01-01 | Ciba-Geigy Corporation | Polymerizable esters derived from a glycidyl ether of a phenolic unsaturated ketone |
GB1489419A (en) | 1974-11-30 | 1977-10-19 | Ciba Geigy Ag | Polymerisable esters |
JPS5442617B2 (en) | 1974-12-28 | 1979-12-15 | ||
DE2500520A1 (en) | 1975-01-08 | 1976-07-15 | Schickedanz Willi | METHOD OF MAKING COLOR COPIES |
US4024324A (en) | 1975-07-17 | 1977-05-17 | Uop Inc. | Novel polyolefin composition of matter |
GB1525159A (en) | 1975-10-27 | 1978-09-20 | Fuji Photo Film Co Ltd | Desensitization of colour developer |
JPS5265425A (en) | 1975-11-24 | 1977-05-30 | Minnesota Mining & Mfg | Image forming composition |
JPS5299776A (en) | 1976-02-18 | 1977-08-22 | Hitachi Ltd | Radiation sensitive high polymeric material |
US4144156A (en) | 1976-04-14 | 1979-03-13 | Basf Aktiengesellschaft | Manufacture of unsymmetric monoacetals of aromatic 1,2-diketones employable as photoiniatiators |
JPS5928323B2 (en) | 1976-08-12 | 1984-07-12 | 富士写真フイルム株式会社 | Photopolymerizable composition |
US4048034A (en) | 1976-08-27 | 1977-09-13 | Uop Inc. | Photopolymerization using an alpha-aminoacetophenone |
US4100047A (en) | 1976-10-12 | 1978-07-11 | Mobil Oil Corporation | Ultraviolet curable aqueous coatings |
US4054719A (en) | 1976-11-23 | 1977-10-18 | American Cyanamid Company | Phenacyl ester photosensitizers for radiation-curable coatings |
JPS5928326B2 (en) | 1976-12-02 | 1984-07-12 | 富士写真フイルム株式会社 | Photopolymerizable composition |
CH603767A5 (en) | 1976-12-27 | 1978-08-31 | Sandoz Ag | Spray dried basic dyes |
JPS6026122B2 (en) | 1977-01-20 | 1985-06-21 | 富士写真フイルム株式会社 | Photopolymerizable composition |
US4141807A (en) | 1977-03-01 | 1979-02-27 | Stauffer Chemical Company | Photopolymerizable composition stabilized with nitrogen-containing aromatic compounds |
DE2722264C2 (en) | 1977-05-17 | 1984-06-28 | Merck Patent Gmbh, 6100 Darmstadt | Use of substituted oxyalkylphenones as photosensitizers |
US4111699A (en) | 1977-06-06 | 1978-09-05 | Eastman Kodak Company | O-nitro-o-azaarylidene photobleachable dyes and photographic elements utilizing them |
US4110112A (en) | 1977-06-23 | 1978-08-29 | Neste Oy | Photosensitive material containing 2,3-di(2,3-diiodopropoxy)-propyl cellulose and uses thereof |
US4250096A (en) | 1977-10-14 | 1981-02-10 | Ciba-Geigy Corporation | 3- and 4-Azidophthalic acid derivatives |
JPS5474728A (en) | 1977-11-28 | 1979-06-15 | Fuji Photo Film Co Ltd | Photosensitive composition |
JPS5928328B2 (en) | 1977-11-29 | 1984-07-12 | 富士写真フイルム株式会社 | Photopolymerizable composition |
US4391867A (en) | 1977-12-16 | 1983-07-05 | E. I. Du Pont De Nemours & Co. | Polyvinyl butyral ink formulation |
US4318791A (en) | 1977-12-22 | 1982-03-09 | Ciba-Geigy Corporation | Use of aromatic-aliphatic ketones as photo sensitizers |
US4345011A (en) | 1978-01-30 | 1982-08-17 | Eastman Kodak Company | Color imaging devices and color filter arrays using photo-bleachable dyes |
US4199420A (en) | 1978-04-06 | 1980-04-22 | Stauffer Chemical Company | Alkoxymethylbenzophenones as photoinitiators for photopolymerizable compositions and process based thereon |
US4162162A (en) | 1978-05-08 | 1979-07-24 | E. I. Du Pont De Nemours And Company | Derivatives of aryl ketones and p-dialkyl-aminoarylaldehydes as visible sensitizers of photopolymerizable compositions |
JPS54152091A (en) | 1978-05-22 | 1979-11-29 | Fuji Photo Film Co Ltd | Photopolymerizable composition |
DE2962442D1 (en) | 1978-07-13 | 1982-05-19 | Ciba Geigy Ag | COMPOSITIONS PHOTODURCISSABLES |
JPS6053300B2 (en) | 1978-08-29 | 1985-11-25 | 富士写真フイルム株式会社 | Photosensitive resin composition |
JPS5550001A (en) | 1978-10-06 | 1980-04-11 | Fuji Photo Film Co Ltd | Photo-polymerizable composition |
JPS5577742A (en) | 1978-12-08 | 1980-06-11 | Fuji Photo Film Co Ltd | Photosensitive composition |
JPS5592370A (en) | 1978-12-29 | 1980-07-12 | Nissan Chem Ind Ltd | Phenoxypyridine derivative and its preparation |
CA1160880A (en) | 1979-02-02 | 1984-01-24 | Keith E. Whitmore | Imaging with nonplanar support elements |
US4197080A (en) | 1979-02-14 | 1980-04-08 | Eastman Kodak Company | Radiation-cleavable nondiffusible compounds and photographic elements and processes employing them |
JPS55133032A (en) | 1979-04-03 | 1980-10-16 | Ricoh Co Ltd | Photosensitive composition |
US4289844A (en) | 1979-06-18 | 1981-09-15 | Eastman Kodak Company | Photopolymerizable compositions featuring novel co-initiators |
JPS566236A (en) | 1979-06-28 | 1981-01-22 | Fuji Photo Film Co Ltd | Photosensitive material and pattern forming method using it |
JPS5664335A (en) | 1979-10-29 | 1981-06-01 | Fuji Photo Film Co Ltd | Photosensitive composition |
JPS5677189A (en) | 1979-11-30 | 1981-06-25 | Fuji Photo Film Co Ltd | Recording material |
US4370401A (en) | 1979-12-07 | 1983-01-25 | Minnesota Mining And Manufacturing Company | Light sensitive, thermally developable imaging system |
DE3008411A1 (en) | 1980-03-05 | 1981-09-10 | Merck Patent Gmbh, 6100 Darmstadt | NEW AROMATIC-ALIPHATIC KETONES, THEIR USE AS PHOTOINITIATORS AND PHOTOPOLYMERIZABLE SYSTEMS CONTAINING SUCH KETONES |
US4373017A (en) | 1980-03-05 | 1983-02-08 | Konishiroku Photo Industry Co., Ltd. | Photosensitive compound and photosensitive material containing it |
DE3010148A1 (en) | 1980-03-15 | 1981-09-24 | Merck Patent Gmbh, 6100 Darmstadt | NEW MIXTURES BASED ON AROMATIC-ALIPHATIC KETONES, THEIR USE AS PHOTOINITIATORS AND PHOTOPOLYMERIZABLE SYSTEMS CONTAINING SUCH MIXTURES |
US4351893A (en) | 1980-12-31 | 1982-09-28 | E. I. Du Pont De Nemours And Company | Derivatives of aryl ketones as visible sensitizers of photopolymerizable compositions |
US4268667A (en) | 1980-04-21 | 1981-05-19 | E. I. Du Pont De Nemours And Company | Derivatives of aryl ketones based on 9,10-dihydro-9,10-ethanoanthracene and p-dialkyl-aminoaryl aldehydes as visible sensitizers for photopolymerizable compositions |
DE3160641D1 (en) | 1980-05-13 | 1983-08-25 | Ciba Geigy Ag | Process for the preparation of benzene or naphthalene alkenyl carboxylic acid derivatives |
US4343891A (en) | 1980-05-23 | 1982-08-10 | Minnesota Mining And Manufacturing Company | Fixing of tetra (hydrocarbyl) borate salt imaging systems |
US4307182A (en) | 1980-05-23 | 1981-12-22 | Minnesota Mining And Manufacturing Company | Imaging systems with tetra(aliphatic) borate salts |
JPS56167139A (en) | 1980-05-27 | 1981-12-22 | Daikin Ind Ltd | Sensitive material |
JPS5720734A (en) | 1980-07-15 | 1982-02-03 | Fuji Photo Film Co Ltd | Heat developing photosensitive material |
US4416961A (en) | 1980-09-11 | 1983-11-22 | Eastman Kodak Company | Color imaging devices and color filter arrays using photo-bleachable dyes |
DE3041153A1 (en) | 1980-10-31 | 1982-06-16 | Bayer Ag, 5090 Leverkusen | METHOD FOR IMPROVING THE LIGHT FASTNESS OF POLYAMIDE COLORS |
US4369283A (en) | 1981-03-06 | 1983-01-18 | E. I. Du Pont De Nemours & Company | High solids can coating composition containing epoxy, acrylic and aminoplast resins |
US4372582A (en) | 1981-03-30 | 1983-02-08 | Minnesota Mining And Manufacturing Company | Stabilizer for electron doner-acceptor carbonless copying systems |
US4350753A (en) | 1981-06-15 | 1982-09-21 | Polychrome Corporation | Positive acting composition yielding pre-development high visibility image after radiation exposure comprising radiation sensitive diazo oxide and haloalkyl-s-triazine with novolak and dyestuff |
JPS57207065A (en) | 1981-06-17 | 1982-12-18 | Seiko Epson Corp | Ink jet recorder |
DE3126433A1 (en) | 1981-07-04 | 1983-01-13 | Merck Patent Gmbh, 6100 Darmstadt | Novel mixtures based on substituted dialkoxyacetophenones, their use as photoinitiators, and photopolymerisable systems containing such mixtures |
US4508570A (en) | 1981-10-21 | 1985-04-02 | Ricoh Company, Ltd. | Aqueous ink for ink-jet printing |
JPS5872139A (en) | 1981-10-26 | 1983-04-30 | Tokyo Ohka Kogyo Co Ltd | Photosensitive material |
EP0088050B1 (en) | 1982-02-26 | 1986-09-03 | Ciba-Geigy Ag | Coloured photo-hardenable composition |
US4425424A (en) | 1982-04-08 | 1984-01-10 | Eastman Kodak Company | Dye-forming compositions |
US4495041A (en) | 1982-04-15 | 1985-01-22 | Mobil Oil Corporation | Photochemical process using shape-selective photoassisted heterogenous catalyst compositions |
JPS5936174A (en) | 1982-08-23 | 1984-02-28 | Ricoh Co Ltd | Water-based ink for ink jet recording |
DE3380028D1 (en) | 1982-10-01 | 1989-07-13 | Ciba Geigy Ag | Propiophenone derivatives as photoinitiators in the photopolymerization |
US4450227A (en) | 1982-10-25 | 1984-05-22 | Minnesota Mining And Manufacturing Company | Dispersed imaging systems with tetra (hydrocarbyl) borate salts |
US4447521A (en) | 1982-10-25 | 1984-05-08 | Minnesota Mining And Manufacturing Company | Fixing of tetra(hydrocarbyl)borate salt imaging systems |
JPS5980475A (en) | 1982-10-29 | 1984-05-09 | Ricoh Co Ltd | Aqueous ink composition |
US5108874A (en) | 1982-11-01 | 1992-04-28 | Microsi, Inc. | Composite useful in photolithography |
US4559371A (en) | 1983-02-18 | 1985-12-17 | Ciba Geigy Corporation | Photocurable colored compositions employing alpha-amino phenone initiator |
GB2136590B (en) | 1983-03-15 | 1986-01-02 | Minnesota Mining & Mfg | Dye-bleach materials and process |
US4510392A (en) | 1983-04-08 | 1985-04-09 | E. I. Du Pont De Nemours And Company | Autoradiogram marking process |
DE3415033C2 (en) | 1983-04-20 | 1986-04-03 | Hitachi Chemical Co., Ltd. | 4'-Azidobenzal-2-methoxyacetophenone, process for its preparation and photosensitive composition containing it |
GB8311252D0 (en) | 1983-04-26 | 1983-06-02 | Ciba Geigy Ag | Photocrosslinking process |
IE55632B1 (en) | 1983-05-09 | 1990-12-05 | Vickers Plc | Improvements in or relating to radiation sensitive plates |
US4475999A (en) | 1983-06-06 | 1984-10-09 | Stauffer Chemical Company | Sensitization of glyoxylate photoinitiators |
US4595745A (en) | 1983-06-27 | 1986-06-17 | Ube Industries, Ltd. | Organic solvent-soluble photosensitive polyamide resin |
US4702996A (en) | 1983-09-28 | 1987-10-27 | General Electric Company | Method of enhancing the contrast of images and materials therefor |
JPS6083029A (en) | 1983-10-13 | 1985-05-11 | Mitsui Toatsu Chem Inc | Optical recording medium |
GB8333853D0 (en) | 1983-12-20 | 1984-02-01 | Ciba Geigy Ag | Production of images |
US4571377A (en) | 1984-01-23 | 1986-02-18 | Battelle Memorial Institute | Photopolymerizable composition containing a photosensitive donor and photoinitiating acceptor |
JPH0697339B2 (en) | 1984-02-02 | 1994-11-30 | 富士写真フイルム株式会社 | Photopolymerizable composition |
GB8402937D0 (en) | 1984-02-03 | 1984-03-07 | Ciba Geigy Ag | Production of images |
US4701402A (en) | 1984-02-13 | 1987-10-20 | Minnesota Mining And Manufacturing Company | Oxidative imaging |
US4620875A (en) | 1984-04-10 | 1986-11-04 | Ricoh Company, Ltd. | Aqueous ink composition |
US4534838A (en) | 1984-04-16 | 1985-08-13 | Loctite Corporation | Siloxane polyphotoinitiators of the substituted acetophenone type |
US4745042A (en) | 1984-04-19 | 1988-05-17 | Matsushita Electric Industrial Co., Ltd. | Water-soluble photopolymer and method of forming pattern by use of the same |
JPS60264279A (en) | 1984-06-13 | 1985-12-27 | Fuji Photo Film Co Ltd | Recording material |
JPS612771A (en) | 1984-06-14 | 1986-01-08 | Taoka Chem Co Ltd | Ink composition |
JPH0755582B2 (en) | 1984-07-27 | 1995-06-14 | 株式会社リコー | Two-color thermosensitive recording label |
US4632895A (en) | 1984-08-23 | 1986-12-30 | Minnesota Mining And Manufacturing Company | Diffusion or sublimation transfer imaging system |
US4663275A (en) | 1984-09-04 | 1987-05-05 | General Electric Company | Photolithographic method and combination including barrier layer |
US4632891A (en) | 1984-10-04 | 1986-12-30 | Ciba-Geigy Corporation | Process for the production of images |
JPS61101568A (en) | 1984-10-23 | 1986-05-20 | Ricoh Co Ltd | Water based ink |
JPS61101574A (en) | 1984-10-23 | 1986-05-20 | Ricoh Co Ltd | Water based ink |
JPS61101572A (en) | 1984-10-23 | 1986-05-20 | Ricoh Co Ltd | Water based ink |
US4565769A (en) | 1984-11-21 | 1986-01-21 | E. I. Du Pont De Nemours And Company | Polymeric sensitizers for photopolymer composition |
IE56890B1 (en) | 1984-12-30 | 1992-01-15 | Scully Richard L | Photosensitive composition for direct positive colour photograph |
JPH0613653B2 (en) | 1985-02-26 | 1994-02-23 | 株式会社リコー | Aqueous ink composition |
JPH0710620B2 (en) | 1985-03-28 | 1995-02-08 | 株式会社リコー | Two-color thermosensitive recording label |
EP0196901A3 (en) | 1985-03-29 | 1988-10-19 | Taoka Chemical Co., Ltd | Copper phthalocyanine compound and aqueous ink composition comprising the same |
DE3512179A1 (en) | 1985-04-03 | 1986-12-04 | Merck Patent Gmbh, 6100 Darmstadt | PHOTO INITIATORS FOR PHOTOPOLYMERIZATION IN AQUEOUS SYSTEMS |
JPS61238874A (en) | 1985-04-17 | 1986-10-24 | Ricoh Co Ltd | Water-based ink composition |
JPH0621930B2 (en) | 1985-05-01 | 1994-03-23 | 富士写真フイルム株式会社 | Photoresponsive material |
EP0200843B1 (en) | 1985-05-09 | 1988-06-22 | Ciba-Geigy Ag | Process for the photochemical stabilisation of undyed and dyed polyamide fibrous material and its mixtures |
US4720450A (en) | 1985-06-03 | 1988-01-19 | Polaroid Corporation | Thermal imaging method |
IT1187703B (en) | 1985-07-23 | 1987-12-23 | Lamberti Fratelli Spa | SUBSTITUTED BENZOPHENONES AND THEIR LIQUID MIXTURES, SUITABLE FOR USE AS PHOTOPOLYMERIZATION INITIATORS |
CA1270089A (en) | 1985-08-01 | 1990-06-05 | Masami Kawabata | Photopolymerizable composition |
US4786586A (en) | 1985-08-06 | 1988-11-22 | Morton Thiokol, Inc. | Radiation curable coating for photographic laminate |
US4622286A (en) | 1985-09-16 | 1986-11-11 | E. I. Du Pont De Nemours And Company | Photoimaging composition containing admixture of leuco dye and 2,4,5-triphenylimidazolyl dimer |
JPS62102241A (en) | 1985-10-30 | 1987-05-12 | Tokyo Ohka Kogyo Co Ltd | Photosensitive composition |
US4772541A (en) | 1985-11-20 | 1988-09-20 | The Mead Corporation | Photohardenable compositions containing a dye borate complex and photosensitive materials employing the same |
DE3650107T2 (en) | 1985-11-20 | 1995-05-24 | Mead Corp | Ionic dyes. |
DE3609320A1 (en) | 1986-03-20 | 1987-09-24 | Basf Ag | PHOTOCHROME SYSTEM, LAYERS MADE THEREOF AND THEIR USE |
EP0239376A3 (en) | 1986-03-27 | 1988-05-11 | Gec-Marconi Limited | Contrast enhanced photolithography |
US4755450A (en) | 1986-04-22 | 1988-07-05 | Minnesota Mining And Manufacturing Company | Spectral sensitizing dyes in photopolymerizable systems |
US4895880A (en) | 1986-05-06 | 1990-01-23 | The Mead Corporation | Photocurable compositions containing photobleachable ionic dye complexes |
US4849320A (en) | 1986-05-10 | 1989-07-18 | Ciba-Geigy Corporation | Method of forming images |
US4925770A (en) | 1986-05-20 | 1990-05-15 | Director General Of Agency Of Industrial Science And Technology | Contrast-enhancing agent for photolithography |
US4724021A (en) | 1986-07-23 | 1988-02-09 | E. I. Du Pont De Nemours And Company | Method for making porous bottom-layer dielectric composite structure |
US5002993A (en) | 1986-07-25 | 1991-03-26 | Microsi, Inc. | Contrast enhancement layer compositions, alkylnitrones, and use |
US4711802A (en) | 1986-08-14 | 1987-12-08 | E. I. Du Pont De Nemours And Company | Aqueous ink for use on fluorocarbon surfaces |
JPH0610727B2 (en) | 1986-09-17 | 1994-02-09 | 富士写真フイルム株式会社 | Photoresponsive material |
US4800149A (en) | 1986-10-10 | 1989-01-24 | The Mead Corporation | Photohardenable compositions containing a dye borate complex and photosensitive materials employing the same |
DE3637717A1 (en) | 1986-11-05 | 1988-05-11 | Hoechst Ag | LIGHT-SENSITIVE MIXTURE, THIS RECORDING MATERIAL AND METHOD FOR PRODUCING POSITIVE OR NEGATIVE RELIEF COPIES USING THIS MATERIAL |
US4952478A (en) | 1986-12-02 | 1990-08-28 | Canon Kabushiki Kaisha | Transfer recording medium comprising a layer changing its transferability when provided with light and heat |
US4902725A (en) | 1986-12-22 | 1990-02-20 | General Electric Company | Photocurable acrylic coating composition |
DE3738567A1 (en) | 1987-03-12 | 1988-09-22 | Merck Patent Gmbh | COREACTIVE PHOTOINITIATORS |
US5028792A (en) | 1987-03-19 | 1991-07-02 | Xytronyx, Inc. | System for the visualization of exposure to ultraviolet radiation |
ATE89262T1 (en) | 1987-03-26 | 1993-05-15 | Ciba Geigy Ag | NEW ALPHA-AMINOACETOPHENONES AS PHOTOINITIATORS. |
US4766050A (en) | 1987-03-27 | 1988-08-23 | The Mead Corporation | Imaging system with integral cover sheet |
JPH07120036B2 (en) | 1987-07-06 | 1995-12-20 | 富士写真フイルム株式会社 | Photopolymerizable composition |
WO1989001186A1 (en) | 1987-07-28 | 1989-02-09 | Nippon Kayaku Kabushiki Kaisha | Photosensitive resin composition and color filter |
US5196295A (en) | 1987-07-31 | 1993-03-23 | Microsi, Inc. | Spin castable mixtures useful for making deep-UV contrast enhancement layers |
US4853037A (en) | 1987-10-30 | 1989-08-01 | Hewlett-Packard Company | Low glycol inks for plain paper printing |
JPH01223446A (en) | 1988-03-03 | 1989-09-06 | Fuji Photo Film Co Ltd | Photoimage forming material and photoimage forming system using same |
DE3807381A1 (en) | 1988-03-07 | 1989-09-21 | Hoechst Ag | HETEROCYCLIC COMPOUNDS CONTAINING 4,6-BIS-TRICHLOROMETHYL-S-TRIAZIN-2-YL-GROUPS, PROCESS FOR THE PREPARATION THEREOF AND LIGHT-SENSITIVE MIXTURE CONTAINING THIS COMPOUND |
US5106723A (en) | 1988-03-10 | 1992-04-21 | Microsi, Inc. | Contrast enhancement layer compositions, alkylnitrones, and use |
US5279652A (en) | 1988-03-24 | 1994-01-18 | Rainer Kaufmann | Use of solids as antiblocking additives for marker liquids |
DE3815622A1 (en) | 1988-05-07 | 1989-11-16 | Merck Patent Gmbh | PHOTOINITIATOR DISPERSIONS |
US5262276A (en) | 1988-05-11 | 1993-11-16 | Fuji Photo Film Co., Ltd. | Light-sensitive compositions |
US4987056A (en) | 1988-06-02 | 1991-01-22 | Toyo Boseki Kabushiki Kaisha | Photopolymerizable composition |
US5003142A (en) | 1988-06-03 | 1991-03-26 | E. I. Du Pont De Nemours And Company | Easy opening microwave pouch |
US4886774A (en) | 1988-08-09 | 1989-12-12 | Alfred Doi | Ultraviolet protective overcoat for application to heat sensitive record materials |
DE3826947A1 (en) | 1988-08-09 | 1990-02-22 | Merck Patent Gmbh | THIOXANTHON DERIVATIVES, THEIR USE AS PHOTOINITIATORS, PHOTOPOLYMERIZABLE BINDING SYSTEMS AND METHOD FOR THE PRODUCTION OF A RADIATION-COATED COATING |
JPH0820734B2 (en) | 1988-08-11 | 1996-03-04 | 富士写真フイルム株式会社 | Photosensitive composition and photopolymerizable composition using the same |
US5334455A (en) | 1988-08-12 | 1994-08-02 | Stamicarbon B.V. | Free-radical curable compositions |
US5034526A (en) | 1988-09-07 | 1991-07-23 | Minnesota Mining And Manufacturing Company | Halomethyl-1,3,5-triazines containing a sensitizer moiety |
US5187045A (en) | 1988-09-07 | 1993-02-16 | Minnesota Mining And Manufacturing Company | Halomethyl-1,3,5-triazines containing a sensitizer moiety |
DE3830914A1 (en) | 1988-09-10 | 1990-03-22 | Hoechst Ag | PHOTOPOLYMERIZABLE MIXTURE, RECORDING MATERIAL MADE THEREOF, AND METHOD FOR PRODUCING COPIES |
DE3833437A1 (en) | 1988-10-01 | 1990-04-05 | Basf Ag | RADIATION SENSITIVE MIXTURES AND THEIR USE |
DE3833438A1 (en) | 1988-10-01 | 1990-04-05 | Basf Ag | RADIATION SENSITIVE MIXTURES AND THEIR USE |
JP2547626B2 (en) | 1988-10-07 | 1996-10-23 | 富士写真フイルム株式会社 | Method for producing monomer |
DE68921146T2 (en) | 1988-11-11 | 1995-06-14 | Fuji Photo Film Co Ltd | Photosensitive composition. |
US5045435A (en) | 1988-11-25 | 1991-09-03 | Armstrong World Industries, Inc. | Water-borne, alkali-developable, photoresist coating compositions and their preparation |
US5185236A (en) | 1988-12-09 | 1993-02-09 | Fuji Photo Film Co., Ltd. | Full color recording materials and a method of forming colored images |
JP2604453B2 (en) | 1988-12-14 | 1997-04-30 | 積水化学工業株式会社 | Acrylic adhesive tape |
US4954416A (en) | 1988-12-21 | 1990-09-04 | Minnesota Mining And Manufacturing Company | Tethered sulfonium salt photoinitiators for free radical polymerization |
JPH02289856A (en) | 1989-01-18 | 1990-11-29 | Fuji Photo Film Co Ltd | Photosensitive and thermosensitive composition and recording material and image forming method using the same |
US5230982A (en) | 1989-03-09 | 1993-07-27 | The Mead Corporation | Photoinitiator compositions containing disulfides and photohardenable compositions containing the same |
US5130406A (en) * | 1989-03-21 | 1992-07-14 | Ciba-Geigy Corporation | Initiators for materials which can be polymerized cationically |
KR900014930A (en) | 1989-03-27 | 1990-10-25 | 로레인 제이. 프란시스 | Dye borate photoinitiator and photocurable composition containing same |
DE59008517D1 (en) | 1989-08-25 | 1995-03-30 | Ciba Geigy Ag | Light stabilized inks. |
US5362916A (en) | 1989-09-06 | 1994-11-08 | Tropix, Inc. | Synthesis of mercaptaryl or hydroxyaryl enol ether alkali metal salts |
US5098806A (en) | 1989-09-22 | 1992-03-24 | Board Of Regents, The University Of Texas System | Photosensitive elements based on polymeric matrices of diacetylenes and spiropyrans and the use thereof as coatings to prevent document reproduction |
US5176984A (en) | 1989-10-25 | 1993-01-05 | The Mead Corporation | Photohardenable compositions containing a borate salt |
JPH03155554A (en) | 1989-11-14 | 1991-07-03 | Japan Synthetic Rubber Co Ltd | Radiation sensitive resin composition |
US5026425A (en) | 1989-12-11 | 1991-06-25 | Hewlett-Packard Company | Waterfastness of DB-168 ink by cation substitution |
JP2632066B2 (en) | 1990-04-06 | 1997-07-16 | 富士写真フイルム株式会社 | Positive image forming method |
US5053320A (en) | 1990-04-16 | 1991-10-01 | Richard L. Scully | Direct dry negative color printing process and composition |
US5153104A (en) | 1990-06-18 | 1992-10-06 | Minnesota Mining And Manufacturing Company | Thermally developable light-sensitive layers containing photobleachable sensitizers |
US5153105A (en) | 1990-06-18 | 1992-10-06 | Minnesota Mining And Manufacturing Company | Thermally developable light sensitive imageable layers containing photobleachable dyes |
US5275646A (en) | 1990-06-27 | 1994-01-04 | Domino Printing Sciences Plc | Ink composition |
US5187049A (en) | 1990-07-16 | 1993-02-16 | Minnesota Mining And Manufacturing Company | Photosensitive thermally developed compositions |
JP3244288B2 (en) | 1990-07-23 | 2002-01-07 | 昭和電工株式会社 | Near infrared decolorable recording material |
TW207021B (en) | 1990-07-23 | 1993-06-01 | Showa Denko Kk | |
US5089374A (en) | 1990-08-20 | 1992-02-18 | Eastman Kodak Company | Novel bis-onium salts and the use thereof as photoinitiators |
US5281261A (en) | 1990-08-31 | 1994-01-25 | Xerox Corporation | Ink compositions containing modified pigment particles |
JP3019381B2 (en) | 1990-08-31 | 2000-03-13 | ソニー株式会社 | Optical recording medium |
US5224197A (en) | 1990-09-06 | 1993-06-29 | The United States Of America As Represented By The Secretary Of The Air Force | Integrated optics using photodarkened polystyrene |
US5208136A (en) | 1990-09-06 | 1993-05-04 | The United States Of America As Represented By The Secretary Of The Air Force | Fabricating of integrated optics |
JP2642776B2 (en) | 1990-09-10 | 1997-08-20 | 三田工業株式会社 | Information recording medium and information recording method |
JPH04153079A (en) | 1990-10-18 | 1992-05-26 | Digital Sutoriimu:Kk | Erasable and rewritable paper, printing ink and printing apparatus and erasing apparatus using them |
US5254429A (en) | 1990-12-14 | 1993-10-19 | Anocoil | Photopolymerizable coating composition and lithographic printing plate produced therefrom |
JPH06504628A (en) | 1990-12-20 | 1994-05-26 | エクソン・ケミカル・パテンツ・インク | UV/EB curable butyl copolymers for lithography and anti-corrosion coating applications |
US5198330A (en) | 1991-10-11 | 1993-03-30 | Eastman Kodak Company | Photographic element with optical brighteners having reduced migration |
US5415976A (en) | 1991-10-25 | 1995-05-16 | Minnesota Mining And Manufacturing Company | Aminoketone sensitizers for photopolymer compositions |
US5455143A (en) | 1991-10-25 | 1995-10-03 | Minnesota Mining And Manufacturing Company | Aminoketone sensitizers for aqueous soluble photopolymer compositions |
US5362592A (en) | 1991-11-14 | 1994-11-08 | Showa Denko K.K. | Decolorizable toner |
DE4142956C2 (en) | 1991-12-24 | 1996-08-14 | Du Pont Deutschland | Bleachable antihalation system for photographic materials |
US5219703A (en) | 1992-02-10 | 1993-06-15 | Eastman Kodak Company | Laser-induced thermal dye transfer with bleachable near-infrared absorbing sensitizers |
US5226957A (en) | 1992-03-17 | 1993-07-13 | Hewlett-Packard Company | Solubilization of water-insoluble dyes via microemulsions for bleedless, non-threading, high print quality inks for thermal ink-jet printers |
US5344483A (en) | 1992-03-30 | 1994-09-06 | Porelon, Inc. | High-density, low-viscosity ink for use in ink jet printers |
US5503664A (en) | 1992-05-20 | 1996-04-02 | Seiko Epson Corporation | Ink compositions for ink jet printing |
US5258274A (en) | 1992-05-22 | 1993-11-02 | Minnesota Mining And Manufacturing Company | Thermal dye bleach construction sensitive to ultraviolet radiation |
US5300403A (en) | 1992-06-18 | 1994-04-05 | International Business Machines Corporation | Line width control in a radiation sensitive polyimide |
US5296275A (en) | 1992-07-01 | 1994-03-22 | Xytronyx, Inc. | Phototranschromic ink |
EP0585679A1 (en) | 1992-09-01 | 1994-03-09 | Konica Corporation | Method for forming a photographic color image |
JP3151547B2 (en) | 1992-09-07 | 2001-04-03 | パイロットインキ株式会社 | Aqueous ink composition for writing instruments |
JP3176444B2 (en) | 1992-10-01 | 2001-06-18 | 株式会社リコー | Aqueous ink and recording method using the same |
DE4234222A1 (en) | 1992-10-10 | 1994-04-14 | Cassella Ag | Water-soluble sulfur dyes, their preparation and use |
US5292556A (en) | 1992-12-22 | 1994-03-08 | E. I. Du Pont De Nemours And Company | Method for preparing negative-working wash-off relief images |
US5426164A (en) | 1992-12-24 | 1995-06-20 | The Dow Chemical Company | Photodefinable polymers containing perfluorocyclobutane groups |
US5455074A (en) | 1992-12-29 | 1995-10-03 | Kimberly-Clark Corporation | Laminating method and products made thereby |
US5330860A (en) | 1993-04-26 | 1994-07-19 | E. I. Du Pont De Nemours And Company | Membrane and electrode structure |
US5721287A (en) | 1993-08-05 | 1998-02-24 | Kimberly-Clark Worldwide, Inc. | Method of mutating a colorant by irradiation |
US5506079A (en) | 1994-02-28 | 1996-04-09 | Ricoh Company, Ltd. | Magnetic composition, magnetic toner and ink containing the magnetic composition |
US5739175A (en) | 1995-06-05 | 1998-04-14 | Kimberly-Clark Worldwide, Inc. | Photoreactor composition containing an arylketoalkene wavelength-specific sensitizer |
US5685754A (en) | 1994-06-30 | 1997-11-11 | Kimberly-Clark Corporation | Method of generating a reactive species and polymer coating applications therefor |
US5476540A (en) | 1994-10-05 | 1995-12-19 | Hewlett Packard Corporation | Gel-forming inks for use in the alleviation of bleed |
US5747550A (en) | 1995-06-05 | 1998-05-05 | Kimberly-Clark Worldwide, Inc. | Method of generating a reactive species and polymerizing an unsaturated polymerizable material |
US5798015A (en) | 1995-06-05 | 1998-08-25 | Kimberly-Clark Worldwide, Inc. | Method of laminating a structure with adhesive containing a photoreactor composition |
US5849411A (en) | 1995-06-05 | 1998-12-15 | Kimberly-Clark Worldwide, Inc. | Polymer film, nonwoven web and fibers containing a photoreactor composition |
US5811199A (en) | 1995-06-05 | 1998-09-22 | Kimberly-Clark Worldwide, Inc. | Adhesive compositions containing a photoreactor composition |
GB9515304D0 (en) | 1995-07-26 | 1995-09-20 | Ilford Ag | Azo dyes |
US5795985A (en) * | 1996-03-05 | 1998-08-18 | Ciba Specialty Chemicals Corporation | Phenyl alkyl ketone substituted by cyclic amine and a process for the preparation thereof |
JP3206439B2 (en) | 1996-06-28 | 2001-09-10 | 東海興業株式会社 | Molding manufacturing method and apparatus |
DE69736547T2 (en) | 1996-09-13 | 2007-09-13 | Dainippon Ink And Chemicals, Inc. | INK JET INK AND METHOD FOR PRODUCING A DISPERSION OF DYED FINE PARTICLES FOR THIS INK |
TW452575B (en) | 1996-12-06 | 2001-09-01 | Ciba Sc Holding Ag | New Α-aminoacetophenone photoinitiators and photopolymerizable compositions comprising these photoinitiators |
-
2001
- 2001-06-19 WO PCT/US2001/019525 patent/WO2002000735A1/en active IP Right Grant
- 2001-06-19 AT AT01948460T patent/ATE333471T1/en not_active IP Right Cessation
- 2001-06-19 CA CA2412607A patent/CA2412607C/en not_active Expired - Fee Related
- 2001-06-19 MX MXPA02012011A patent/MXPA02012011A/en active IP Right Grant
- 2001-06-19 US US09/884,896 patent/US6486227B2/en not_active Expired - Lifetime
- 2001-06-19 KR KR1020027017284A patent/KR100772772B1/en active IP Right Grant
- 2001-06-19 EP EP01948460A patent/EP1297022B1/en not_active Expired - Lifetime
- 2001-06-19 DE DE60121588T patent/DE60121588T2/en not_active Expired - Lifetime
- 2001-06-19 JP JP2002505857A patent/JP2004501987A/en not_active Abandoned
- 2001-06-19 AU AU2001269905A patent/AU2001269905A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
ATE333471T1 (en) | 2006-08-15 |
KR100772772B1 (en) | 2007-11-01 |
DE60121588D1 (en) | 2006-08-31 |
US20020099111A1 (en) | 2002-07-25 |
DE60121588T2 (en) | 2006-11-16 |
US6486227B2 (en) | 2002-11-26 |
MXPA02012011A (en) | 2003-04-22 |
EP1297022B1 (en) | 2006-07-19 |
EP1297022A1 (en) | 2003-04-02 |
AU2001269905A1 (en) | 2002-01-08 |
KR20030011359A (en) | 2003-02-07 |
WO2002000735A1 (en) | 2002-01-03 |
CA2412607C (en) | 2010-12-21 |
JP2004501987A (en) | 2004-01-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2412607A1 (en) | Novel photoinitiators and applications therefor | |
BR9401197A (en) | Process for the hardening of ethylenically unsaturated polymerizable compounds, use of compounds, compositions and process for coating surfaces. | |
US6369124B1 (en) | Polymerization processes using aliphatic maleimides | |
ES2138196T3 (en) | HARDENABLE, SPRAYABLE COMPOSITIONS INTENDED TO REINFORCE RIGID AND THIN PLATES. | |
JPS55118030A (en) | Photopolymerizable composition | |
EP0372556A3 (en) | Improved uv curable compositions | |
AU2003216432A1 (en) | Thioxanthone derivatives, and their use as cationic photoinitiators | |
ATE138084T1 (en) | CUREABLE EPOXY RESIN MIXTURES CONTAINING POLYOXYALKYLENEDITHIOLS AND POLYAMINES | |
KR910014477A (en) | Radiation-curable wear resistant cyclic ether acrylate coating composition | |
CA2006074A1 (en) | Photopolymerizable mixture and photopolymerizable copying material containing same | |
KR910003439A (en) | Photopolymerizable mixtures and recording materials prepared therefrom | |
MY141765A (en) | Photosensitive resin composition, photosensitive element using the same, process for producing resist pattern, and process for producing printed wiring board | |
KR960703923A (en) | Orthospiroester Compound, Resin Composition and Cured Product | |
WO2000018750A3 (en) | Chelates comprising chinoid groups as photoinitiators | |
CA2334563A1 (en) | Use of 2,2,6,6 tetraalkylpiperidine-n-oxyl radicals having long alkyl chains as polymerization regulators | |
KR910006437A (en) | Radiation curable transparent coating composition containing basic colloidal silica | |
DE10345903A1 (en) | Reactive paint for use in electronics, printing, furniture, parquet flooring and paper industry, comprises thermal or combined initiator system including thermal initiators and UV initiators and reactive oligomers | |
ES8701487A1 (en) | Polymerisable composition. | |
KR910012121A (en) | Process for obtaining texture coating from photo-curable urea-containing composition | |
TW353666B (en) | Curable resin composition | |
KR910012804A (en) | Photocurable Amine-Containing Compositions | |
KR910012809A (en) | Photocurable Urethane-Containing Compositions | |
RU2001108411A (en) | Dental material based on cationic polymerizable monomers | |
US20040235976A1 (en) | Polymerization processes using alphatic maleimides | |
JPS54102389A (en) | Curable resin composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20140619 |