CA2475641A1 - Methods of treating and cleaning fibers, carpet yarns and carpets - Google Patents

Methods of treating and cleaning fibers, carpet yarns and carpets Download PDF

Info

Publication number
CA2475641A1
CA2475641A1 CA002475641A CA2475641A CA2475641A1 CA 2475641 A1 CA2475641 A1 CA 2475641A1 CA 002475641 A CA002475641 A CA 002475641A CA 2475641 A CA2475641 A CA 2475641A CA 2475641 A1 CA2475641 A1 CA 2475641A1
Authority
CA
Canada
Prior art keywords
fiber
coated
aqueous treating
carpet
stannous chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002475641A
Other languages
French (fr)
Other versions
CA2475641C (en
Inventor
Dennis J. Jones, Jr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shaw Industries Group Inc
Original Assignee
Shaw Industries Group Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shaw Industries Group Inc filed Critical Shaw Industries Group Inc
Publication of CA2475641A1 publication Critical patent/CA2475641A1/en
Application granted granted Critical
Publication of CA2475641C publication Critical patent/CA2475641C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/238—Tannins, e.g. gallotannic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/20—Halides of elements of Groups 4 or 14 of the Periodic System, e.g. zirconyl chloride
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/248—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing chlorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/41—Phenol-aldehyde or phenol-ketone resins
    • D06M15/412—Phenol-aldehyde or phenol-ketone resins sulfonated

Abstract

Methods of enhancing stain resistance of fibers, carpet yarns and carpets are disclosed. Treating compositions used to enhance the stain resistance of fibers, carpet yarns and carpets are also disclosed.</SD OAB>

Claims (10)

1. A method of treating a fiber comprising the step of:
applying one or more aqueous treating compositions to the fiber, wherein the one or more aqueous treating compositions comprise at least one crosslinking agent selected from the group consisting of antimony potassium tartrate (APT), stannous chloride, and a combination thereof.
2. The method of Claim 1, wherein the step of applying one or more aqueous treating compositions to the fiber comprises:
applying a first aqueous treating composition comprising tannic acid to form a coated fiber;
forming a fixed coated fiber by exposing the coated fiber to heat for a sufficient time to fix the tannic acid on and in the fiber;
and forming an overcoated fiber by applying a second aqueous treating composition to the fixed coated fiber, wherein the second aqueous treating composition comprises stannous chloride, and, optionally, a fluorochemical component.
3. The method of Claim 2, further comprising:
drying the overcoated fiber using dry heat.
4. The method of Claim 2, wherein the first aqueous treating composition further comprises (i) a crosslinking component selected from the group consisting of antimony potassium tartrate, stannous chloride, or combinations thereof; (ii) a stain-resist material comprising at least in part an aqueous emulsion of polymerized monomers, wherein the monomers comprise (meth)acrylic acid, alkyl (meth)acrylic acid, and a substituted or unsubstituted styrene; and (iii) optionally, a fluorochemical component.
5. The method of Claim 4, wherein the first aqueous treating composition further comprises urea sulfate. 6. A treated fiber comprising a fiber having coated thereon at least one crosslinking agent selected from the group consisting of antimony potassium tartrate (APT), stannous chloride, and a combination thereof.
6. A treated fiber comprising a fiber having coated thereon at least one crosslinking agent selected from the group consisting of antimony potassium tartrate (APT), stannous chloride, and a combination thereof.
7. The treated fiber of Claim 6, wherein the fiber has coated thereon tannic acid, at least one stain-resist material, and optionally, a fluorochemical component.
8. The treated fiber of Claim 7, wherein the fiber has coated thereon urea sulfate.
9. A carpet comprising the treated fiber of Claim 6.
10. A method of cleaning a carpet comprising the steps of (a) providing a carpet, wherein the carpet comprises a plurality of fibers having coated thereon at least one crosslinking agent selected from the group consisting of antimony potassium tartrate (APT), stannous chloride, and a combination thereof; and (b) applying a cleaning solution to the carpet, wherein the cleaning solution has a pH of greater than about 8Ø
CA2475641A 2003-07-24 2004-07-23 Methods of treating and cleaning fibers, carpet yarns and carpets Expired - Fee Related CA2475641C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/627,945 US20050015886A1 (en) 2003-07-24 2003-07-24 Methods of treating and cleaning fibers, carpet yarns and carpets
US10/627,945 2003-07-24

Publications (2)

Publication Number Publication Date
CA2475641A1 true CA2475641A1 (en) 2005-01-24
CA2475641C CA2475641C (en) 2012-06-19

Family

ID=34080704

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2475641A Expired - Fee Related CA2475641C (en) 2003-07-24 2004-07-23 Methods of treating and cleaning fibers, carpet yarns and carpets

Country Status (6)

Country Link
US (3) US20050015886A1 (en)
EP (1) EP1518958A3 (en)
JP (1) JP5143999B2 (en)
CN (1) CN1605677B (en)
AU (1) AU2004203326B2 (en)
CA (1) CA2475641C (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050015886A1 (en) * 2003-07-24 2005-01-27 Shaw Industries Group, Inc. Methods of treating and cleaning fibers, carpet yarns and carpets
US7785374B2 (en) * 2005-01-24 2010-08-31 Columbia Insurance Co. Methods and compositions for imparting stain resistance to nylon materials
DE502005001498D1 (en) * 2005-07-15 2007-10-25 Invista Tech Sarl Stain and dirt protection composition
WO2009093562A1 (en) * 2008-01-21 2009-07-30 Kaneka Corporation Flame-retardant fiber, flame-retardant fiber sheet, method for production of the fiber, and method for production of the fiber sheet
WO2010039935A1 (en) * 2008-10-02 2010-04-08 Peach State Labs, Inc. Compositions and methods for treating textile fibers
WO2010132215A2 (en) * 2009-05-12 2010-11-18 Mannington Mills, Inc. Method for imparting bleach and stain resistance to dyed yarns in carpet and products made therewith
CA2817009A1 (en) * 2010-11-12 2012-05-18 Invista Technologies S.A.R.L. Aqueous dispersion of dye, stain-blocker, and fluorochemical and its use in the manufacture of carpet
CN104074046B (en) * 2014-06-11 2016-02-03 周文叶 A kind of method utilizing low-temperature plasma to remove carpet peculiar smell
JP2016073374A (en) * 2014-10-03 2016-05-12 東レ株式会社 Method for producing carpet

Family Cites Families (167)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US362574A (en) * 1887-05-10 Whiffletree
US2480775A (en) * 1948-07-03 1949-08-30 Du Pont Dyeing nylon hosiery
BE635114A (en) * 1962-08-11 1900-01-01
US3799992A (en) 1965-02-18 1974-03-26 Us Agriculture Fluorinated vinyl ethers and use thereof
US3669611A (en) * 1965-10-11 1972-06-13 Teijin Ltd Production of ornamental multitone effect on polyamide textile materials
GB1155552A (en) 1966-04-14 1969-06-18 Geigy Uk Ltd Cleaning and Anti-soiling Compositions
NL136360C (en) 1966-08-04
US3511704A (en) * 1967-03-08 1970-05-12 Viscose Suisse Soc Electrically conductive flock for electrostatic flocking
US3652212A (en) 1967-04-17 1972-03-28 Deering Milliken Res Corp Multi-step in situ polymer formation to produce fabric having improved soiling characteristics
US3606989A (en) 1967-10-19 1971-09-21 Purex Corp Ltd Fabric-treating composition and method
GB1254541A (en) * 1968-01-29 1971-11-24 Courtaulds Ltd Dyeing process
US3948838A (en) 1968-07-25 1976-04-06 Burlington Industries, Inc. Soil release composition
CH1305669D (en) 1968-08-28
US3632421A (en) 1968-12-09 1972-01-04 Deering Milliken Res Corp Textile material with soil release characteristics
US3632422A (en) 1969-12-04 1972-01-04 Burlington Industries Inc Textile fabric having soil release finish and method of making same
US3625754A (en) 1970-02-02 1971-12-07 Beaunit Corp Surface-modified polyester article
US3655566A (en) 1970-03-05 1972-04-11 Purex Corp Ltd Bleach having stable brighteners
US3666680A (en) 1970-03-05 1972-05-30 Purex Corp Ltd Method of combining optical brighteners with polymers for stability in bleach and encapsulated product
US3609989A (en) 1970-04-15 1971-10-05 Westinghouse Electric Corp Control for refrigeration system centrifugal compressor
US3706594A (en) 1971-02-22 1972-12-19 Us Agriculture Fibrous substrate treated with copolymers of fluoroalkyl ethers and maleic anhydride
US3916053A (en) 1971-09-12 1975-10-28 Minnesota Mining & Mfg Carpet treating and treated carpet
US3816167A (en) 1971-10-20 1974-06-11 Minnesota Mining & Mfg Stain-releasing textiles of synthetic fibers and process for treating textiles of synthetic fibers
US3816229A (en) 1972-01-14 1974-06-11 Minnesota Mining & Mfg Plural coated pile fabric
US3993830A (en) 1972-04-28 1976-11-23 Colgate-Palmolive Company Soil-release finish
US3836496A (en) 1972-05-01 1974-09-17 Colgate Palmolive Co Composition for imparting non-permanent soil-release characteristics comprising an aqueous acidic solution of polycarboxylate polymer
US3857757A (en) 1972-11-30 1974-12-31 Gen Electric Means for the oxygen/temperature control of aerobic fermentations
US3854871A (en) 1973-01-31 1974-12-17 Du Pont Textile cleaning process for simultaneous dry cleaning and finishing with stain repellent
GB1464866A (en) * 1973-08-21 1977-02-16 Ici Ltd Coloration process
JPS5540302B2 (en) * 1973-09-19 1980-10-17
US4052158A (en) 1973-11-12 1977-10-04 Stauffer Chemical Company Textile finishing process
US4043964A (en) 1973-11-14 1977-08-23 Minnesota Mining And Manufacturing Company Carpet treating and treated carpet
US3999940A (en) 1975-01-02 1976-12-28 Congoleum Corporation Multicolored pile materials and processes for making the same
IT1054595B (en) 1975-02-04 1981-11-30 Du Pont WATER DISPERSIONS OF PERFLUOROOLEFINIC POLYMERS CONTAINING FILMOGENIC MATERIALS
US4208173A (en) 1975-06-06 1980-06-17 United Merchants And Manufacturers, Inc. Method for treating fabrics
US4071463A (en) 1975-09-11 1978-01-31 The Dow Chemical Company Stable cleaning agents of hypochlorite bleach and detergent
FR2328070A1 (en) 1975-10-17 1977-05-13 Ugine Kuhlmann ANTI-STAIN PRODUCTS ALLOWING THE EASY REMOVAL OF SOIL IN WASHING
US4094701A (en) * 1976-03-18 1978-06-13 Oxy Metal Industries Corporation Method for cleaning tin surfaces
US4076631A (en) 1976-06-14 1978-02-28 Chas. S. Tanner Co. Antisoiling and antistatic textile treating composition
US4081383A (en) 1976-09-02 1978-03-28 Rohm And Haas Company Anti-soiling treatment for carpets and carpet yarns
US4144367A (en) 1977-05-09 1979-03-13 Minnesota Mining And Manufacturing Company Carpet-treating compositions
US4203859A (en) 1977-06-27 1980-05-20 Rohm And Haas Company Solubilized acrylic polymers and carpet shampoos containing the same
US4245994A (en) * 1977-07-29 1981-01-20 Diamond Shamrock Corporation Water soluble polymeric textile treating agent
DE2749386A1 (en) 1977-11-04 1979-05-10 Roehm Gmbh DISPERSIONS OF HYDROPHILIC ACRYLIC RESINS
US4264484A (en) 1979-01-24 1981-04-28 Minnesota Mining And Manufacturing Company Carpet treatment
US4340749A (en) 1979-12-21 1982-07-20 Minnesota Mining And Manufacturing Company Carpet treatment
DE3004824A1 (en) * 1980-02-09 1981-08-20 Bayer Ag, 5090 Leverkusen POLESTABILIZING TEXTILE IMPREGNANT
US4355065A (en) 1980-04-28 1982-10-19 Milliken Research Corporation Soil-resistant textile materials
US4325857A (en) 1980-05-13 1982-04-20 E. I. Du Pont De Nemours And Company Durable antisoling coatings for textile filaments
JPS5843511B2 (en) 1980-08-13 1983-09-27 大日本インキ化学工業株式会社 Antifouling agent
CH647286A5 (en) 1980-10-11 1985-01-15 Sandoz Ag PHOSPHATE-FREE OR LOW-PHOSPHATE DETERGENTS AND CLEANERS.
US4426476A (en) 1982-02-03 1984-01-17 Minnesota Mining And Manufacturing Company Textile treatments
DE3307420A1 (en) 1983-03-03 1984-09-13 Bayer Ag, 5090 Leverkusen TEXTILE EQUIPMENT
US4892558A (en) * 1986-03-06 1990-01-09 Monsanto Company Process for dyeing stain resistant nylon carpets
US4592940A (en) 1983-12-16 1986-06-03 Monsanto Company Stain-resistant nylon carpets impregnated with condensation product of formaldehyde with mixture of diphenolsulfone and phenolsulfonic acid
US4501591A (en) 1983-12-27 1985-02-26 Monsanto Company Process for conveniently providing stain-resistant polyamide carpets
US4780099A (en) 1986-08-26 1988-10-25 E. I. Du Pont De Nemours And Company Method for producing stain resistant polyamide fibers
EP0242496B1 (en) 1986-03-06 1991-12-27 Monsanto Company Stain-resistant nylon fibers
US4842646A (en) * 1986-09-23 1989-06-27 Saranda Consolidated Limited Partnership Substantive dyes, inks and dye baths
US4875901A (en) 1986-10-14 1989-10-24 Minnesota Mining And Manufacturing Company Treating fibrous polyamide articles
US4699812A (en) 1986-11-28 1987-10-13 Allied Corporation Imparting stain resistance to certain fibers
US4865885A (en) 1987-06-19 1989-09-12 Crompton & Knowles Corporation Food color stain blocking fiber agents
JPS6468575A (en) * 1987-09-10 1989-03-14 Asahi Chemical Ind Durable antistaining carpet
US5152803A (en) * 1987-09-28 1992-10-06 Allied-Signal Inc. Methods and compositions to enhance stain resistance of carpet fibers with water-soluble thiocyanate
US5230708A (en) * 1987-09-28 1993-07-27 Allied-Signal Inc. Methods and compositions to enhance stain resistance of nylon carpet fibers: thlocyanate to reduce yellowing
US5110317A (en) 1987-09-28 1992-05-05 Allied-Signal Inc. Methods and compositions to enhance stain resistance of dyed nylon carpet fibers: thiocyanate to reduce yellowing
US5145487A (en) * 1987-09-28 1992-09-08 Allied-Signal Inc. Methods and compositions to enhance stain resistance of carpet fibers using sulfonated aromatic condensates
US4800118A (en) * 1987-11-04 1989-01-24 West Point Pepperell Compositions and methods for imparting stain resistance to textile articles
US5137759A (en) * 1987-12-21 1992-08-11 E. I. Du Pont De Nemours And Company Imparting stain resistance to installed nylon carpets treated with antimicrobial or deodorizing agents
US4925707A (en) * 1987-12-21 1990-05-15 E. I. Du Pont De Nemours And Company Treatment of carpets
US4948650A (en) * 1987-12-21 1990-08-14 E. I. Du Pont De Nemours And Company Stain-resistant textile substrates
US5032136A (en) * 1987-12-21 1991-07-16 E. I. Du Pont De Nemours And Company Process for importing stain-resistance to textile substrates
ZA889534B (en) * 1987-12-21 1990-08-29 Du Pont Stain-resistant aromatic/meleic anhydride polymers
US4883839A (en) 1987-12-21 1989-11-28 E. I. Du Pont De Nemours And Company Stain-resistant agents for textiles
US4937123A (en) * 1988-03-11 1990-06-26 Minnesota Mining And Manufacturing Company Process for providing polyamide materials with stain resistance
US4822373A (en) * 1988-03-11 1989-04-18 Minnesota Mining And Manufacturing Company Process for providing polyamide materials with stain resistance with sulfonated novolak resin and polymethacrylic acd
US4833009A (en) * 1988-03-25 1989-05-23 E. I. Du Pont De Nemours And Company Purification of condensation products
US4908149A (en) * 1988-06-10 1990-03-13 Milliken Research Corporation Cleaning composition for textiles containing sulfonated colorless dye site blocker
US5522580A (en) * 1988-06-14 1996-06-04 Basf Corporation Removing stains from fixed items
US5126138A (en) * 1988-07-19 1992-06-30 Dow Corning Corporation Antimicrobial flourochemically treated plastic (nylon) surfaces
US5108684B1 (en) * 1988-12-14 1994-05-10 Du Pont Process for producing stain-resistant, pigmented nylon fibers
US5009667A (en) 1989-01-31 1991-04-23 Harris Research Inc. Composition and method for providing stain resistance to polyamide fibers using carbonated solutions
US5223340A (en) 1989-04-20 1993-06-29 Peach State Labs, Inc. Stain resistant polyamide fibers
EP0470973B1 (en) * 1989-05-03 1994-03-23 AlliedSignal Inc. Sulfonated aromatic condensates and treatment of polyamide carpets therewith
US5057121A (en) 1989-08-04 1991-10-15 E. I. Du Pont De Nemours And Company Process for imparting stain-resist agent
CA1327856C (en) 1989-09-05 1994-03-15 Barry R. Knowlton Method of enhancing the soil- and stain-resistance characteristics of polyamide and wool fabrics, the fabrics so treated, and treating composition
US5074883A (en) 1989-12-11 1991-12-24 Minnesota Mining And Manufacturing Company Process for providing polyamide materials with stain resistance
US5252375A (en) * 1990-03-22 1993-10-12 Interface, Inc. Permanent stain resistant treatment for polyamide fibers
US5328766A (en) 1990-06-26 1994-07-12 West Point Pepperell, Inc. Stain-resistant, lightfast polyamide textile products and woolen goods and compositions and processes therefor
US5242733A (en) * 1990-08-08 1993-09-07 E. I. Du Pont De Nemours And Company Carpets and fabrics of antistain block copolymer compositions of modified nylon copolymers and high carbon nylons
US5155178A (en) * 1990-08-08 1992-10-13 E. I. Du Pont De Nemours And Company Antistain block copolymer compositions of modified nylon copolymers and high carbon nylons
US5164261A (en) 1990-08-08 1992-11-17 E. I. Du Pont De Nemours And Company Dyed antistain nylon with cationic dye modifier
US5131914A (en) * 1990-12-13 1992-07-21 Hoechst Celanese Corporation Process for preparing multi-colored dyed polyamide substrates including the application of a reactive vinyl sulfone dye and a resist agent
US5460887A (en) * 1990-12-13 1995-10-24 E. I. Du Pont De Nemours And Company Stain-resistant polyamide substrates
US5654068A (en) * 1990-12-13 1997-08-05 E. I. Du Pont De Nemours And Company Stain resists for polyamide substrates
US5232743A (en) * 1991-02-01 1993-08-03 Allied-Signal Inc. Method and composition to enhance acid dye stain resistance of polyamides by improving resistance to detergent washings and products thereof
US5459188A (en) * 1991-04-11 1995-10-17 Peach State Labs, Inc. Soil resistant fibers
US5316850A (en) * 1991-04-12 1994-05-31 Peach State Labs, Inc. Permanently stain resistant textile fibers
US5252232A (en) * 1991-09-20 1993-10-12 E. I. Du Pont De Nemours And Company Stain and soil resistant compositions having freeze-thaw stability
US5229483A (en) * 1992-04-30 1993-07-20 E. I. Du Pont De Nemours And Company Phenolic stain-resists
US5234466A (en) * 1992-07-24 1993-08-10 Peach State Labs, Inc. Lowering of the pH of textile processing solutions by adding urea sulfate as a pH adjusting agent
US5516337A (en) * 1992-09-02 1996-05-14 Minnesota Mining And Manufacturing Company Chemical system for providing fibrous materials with stain resistance
US5417724A (en) * 1992-12-16 1995-05-23 Joseph A. Pacifici Method of treating acid dyed nylon fibers to enhance colorfastness
US5342417A (en) * 1992-12-16 1994-08-30 Pacifici Joseph A Method of treating cationic dyeable nylon fibers to inhibit cold water bleed
US5383972A (en) * 1993-01-12 1995-01-24 Interface Service Management, Inc. Method of carpet cleaning and maintenance
JP3296561B2 (en) * 1993-02-02 2002-07-02 イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー Bis (hydroxyphenyl) sulfone resole as antifouling agent for polyamide
US5358769A (en) * 1993-02-02 1994-10-25 E. I. Du Pont De Nemours And Company Process providing durable stain-resistance by use of maleic anhydride polymers
JPH06306780A (en) * 1993-04-21 1994-11-01 Teijin Ltd Dyeing process for polyamide fiber structure
US5356689A (en) * 1993-04-26 1994-10-18 E. I. Du Pont De Nemours And Company Process providing durable stain-resistance using methacrylic acid polymers
US5403362A (en) * 1993-05-10 1995-04-04 Allegro Natural Dyes Inc. Mordant and method of dyeing fibers
US5639500A (en) * 1993-05-27 1997-06-17 Kraft Foods, Inc. High molecular weight gallotannins as a stain-inhibiting agent for food dyes
US5681604A (en) * 1993-06-29 1997-10-28 Li; Hualin Stain-inhibiting agent for dyes with affinity for protonatable nitrogen, compositions containing same and uses thereof
BE1007555A3 (en) * 1993-09-30 1995-08-01 Denderland Martin Nv Method for resistance to improve the colour spots of yarn and products.
US5401554A (en) 1993-12-21 1995-03-28 Basf Corporation Process for the manufacture of a stain resistant melt colored carpet
US5436049A (en) 1993-12-21 1995-07-25 Basf Corporation Process for the manufacture of a stain resistant carpet
DE69418586T2 (en) * 1994-01-07 1999-11-25 Du Pont Process for the production of a carpet with a liquid-impermeable backing and this carpet
US5348785A (en) * 1994-01-07 1994-09-20 E. I. Du Pont De Nemours And Company Method for manufacturing a carpet having a secondary backing substantially impervious to aqueous solutions and the resultant carpet
US5736468A (en) * 1994-02-02 1998-04-07 Trichromatic Carpet Inc. Stain resistant polyamide substrate treated with sulfonated phosphated resol resin
BE1008060A3 (en) * 1994-02-02 1996-01-03 Denderland Martin Nv Method for resistance of spots on improving the yarn and products.
US5549963A (en) * 1994-02-02 1996-08-27 Trichromatic Carpet Inc. Polyamide materials with durable stain resistance
US5457259A (en) * 1994-02-02 1995-10-10 Trichromatic Carpet Inc. Polyamide materials with durable stain resistance
US5451259A (en) * 1994-02-17 1995-09-19 Krogh; Ole D. ECR plasma source for remote processing
US5906877A (en) * 1994-08-31 1999-05-25 E. I. Du Pont De Nemours & Co. Moisture stable tuftstring carpet
US5939166A (en) * 1994-08-31 1999-08-17 E. I. Du Pont De Nemours And Company Moisture stable tuftstring carpet
CN1054413C (en) * 1994-12-08 2000-07-12 浙江丝绸工学院 Processing method for antisectic and deodorant textile material and its products
US5851595A (en) * 1995-02-13 1998-12-22 Shaw Industries, Inc. Method of treating carpet yarn and carpet to enhance repellency
US5520962A (en) * 1995-02-13 1996-05-28 Shaw Industries, Inc. Method and composition for increasing repellency on carpet and carpet yarn
JPH08246347A (en) * 1995-03-07 1996-09-24 Kanebo Ltd Durable water repellent processing of synthetic fiber structure
US5545833A (en) * 1995-05-30 1996-08-13 Monsanto Company Phosphorus-containing polymers and fibers formed therefrom
US5965232A (en) * 1995-06-26 1999-10-12 E.I. Du Pont De Nemours & Co., Inc. Decorative composite floor coverings
US5618604A (en) * 1995-09-15 1997-04-08 Dohn; George D. Balsa core laminate having bevelled edges
US5770656A (en) * 1995-09-22 1998-06-23 E.I. Du Pont De Nemours And Company Partial fluoroesters or thioesters of maleic acid polymers and their use as soil and stain resists
US5670246A (en) * 1995-09-22 1997-09-23 E. I. Du Pont De Nemours And Company Treatment of polyamide materials with partial fluoroesters or fluorothioesters of maleic acid polymers and sulfonated aromatic condensates
WO1997023674A1 (en) * 1995-12-22 1997-07-03 E.I. Du Pont De Nemours And Company A process for making multicolored yarns and the product thereof
WO1997031149A1 (en) * 1996-02-23 1997-08-28 E.I. Du Pont De Nemours And Company Carboxylic acid-containing polymer/resole resin stain-resists
US5712348A (en) * 1996-03-13 1998-01-27 E. I. Du Pont De Nemours And Company Maleic acid copolymers with fluorinated thioether end-cap
US5662716A (en) * 1996-05-28 1997-09-02 E. I. Du Pont De Nemours And Company Process for increasing stain-resistance of cationic-dyeable modified polyamide fibers
US5756181A (en) * 1996-07-23 1998-05-26 Minnesota Mining And Manufacturing Company Repellent and soil resistant carpet treated with ammonium polycarboxylate salts
EP0922082B1 (en) * 1996-08-16 2003-05-14 E.I. Du Pont De Nemours And Company Fabric cleaning formulations
US5725889A (en) * 1996-09-18 1998-03-10 E. I. Du Pont De Nemours And Company Phenolic stain-resists
US5821177A (en) * 1996-12-16 1998-10-13 Trichromatic Carpet Inc. Enhancement of stain resistance or acid dye fixation, improved light fastness and durability of fibrous poolyamide and wool substrates
JP3906506B2 (en) * 1997-01-16 2007-04-18 ダイキン工業株式会社 Antifouling agent
US5948480A (en) * 1997-03-31 1999-09-07 E.I. Du Pont De Nemours And Company Tandem application of soil and stain resists to carpeting
US6197378B1 (en) * 1997-05-05 2001-03-06 3M Innovative Properties Company Treatment of fibrous substrates to impart repellency, stain resistance, and soil resistance
US6117550A (en) * 1997-10-22 2000-09-12 Prisma Fibers, Inc. Acid dye stain-resistant fiber-forming polyamide composition containing masterbatch concentrate containing reagent and carrier
US6458443B2 (en) * 1998-03-16 2002-10-01 Arrow Engineering, Inc. Compositions and methods for imparting stain resistance
US5945493A (en) * 1998-06-19 1999-08-31 E. I. Du Pont De Nemours And Company Fluorine-containing maleic acid terpolymer soil and stain resists
TW463000B (en) * 1998-11-18 2001-11-11 Asahi Chemical Ind A dyed mixed fiber article composed of polyurethane fiber and a fiber dyeable with a disperse dye and a method of dyeing thereof
WO2000034385A1 (en) * 1998-12-08 2000-06-15 The Dow Chemical Company Mel-bondable polypropylene/ethylene polymer fiber and composition for making the same
US6207594B1 (en) * 1999-01-11 2001-03-27 Trichromatic Carpet Inc. Polyamide substrate having stain resistance, composition and method
US6291048B1 (en) * 1999-02-16 2001-09-18 Eastman Chemical Company Polymeric based carpet
US6023823A (en) * 1999-03-22 2000-02-15 Basf Corporation Method and apparatus for treating strand-like material
US6852134B2 (en) * 1999-07-08 2005-02-08 Invista North America S.A.R.L. Method of imparting stain resistance to a differentially dyeable textile surface and the article produced thereby
GB9923280D0 (en) * 1999-10-01 1999-12-08 Unilever Plc Fabric care composition
US6395655B1 (en) * 1999-12-17 2002-05-28 Trichromatic Carpet Inc. Polyamide fiber substrate having strain resistance, composition and method
US20010052154A1 (en) * 2000-03-15 2001-12-20 Kelly David R. Covalently bonded protectors for nylon fibers, yarns and finished products
US6811574B2 (en) * 2000-07-03 2004-11-02 Dupont Textiles & Interiors, Inc. Method of after-treatment of a dyeable nylon textile surface with a stain resist and the article produced thereby
JP2004502884A (en) * 2000-07-07 2004-01-29 ミリケン・アンド・カンパニー Woven substrate with improved sustained water repellency and soil release and method of making same
US6524492B2 (en) * 2000-12-28 2003-02-25 Peach State Labs, Inc. Composition and method for increasing water and oil repellency of textiles and carpet
US7147669B2 (en) * 2001-04-25 2006-12-12 Daikin Industries, Ltd. Water- and oil-repellent treatment of textile
GB0113109D0 (en) * 2001-05-30 2001-07-18 Du Pont A floor covering
JP2003193370A (en) * 2001-12-25 2003-07-09 Daikin Ind Ltd Water- and oil-repelling processing of textile product
US7157121B2 (en) * 2002-04-29 2007-01-02 Shaw Industries Group, Inc. Method of treating carpet for enhanced liquid repellency
US6860905B2 (en) * 2002-10-01 2005-03-01 Peach State Labs, Inc. Anionic phthalic acid ester compounds and stain resistant compositions
US7335234B2 (en) * 2002-10-16 2008-02-26 Columbia Insurance Company Method of treating fibers, carpet yarns and carpets to enhance repellency
US20040138083A1 (en) * 2003-01-10 2004-07-15 Kimbrell Wiliam C. Substrates having reversibly adaptable surface energy properties and method for making the same
US20040144406A1 (en) * 2003-01-16 2004-07-29 Aram Garabedian Dry aerosol carpet cleaning process
US20050015886A1 (en) * 2003-07-24 2005-01-27 Shaw Industries Group, Inc. Methods of treating and cleaning fibers, carpet yarns and carpets

Also Published As

Publication number Publication date
JP2005133279A (en) 2005-05-26
EP1518958A2 (en) 2005-03-30
US20050015886A1 (en) 2005-01-27
US7488351B2 (en) 2009-02-10
CA2475641C (en) 2012-06-19
JP5143999B2 (en) 2013-02-13
EP1518958A3 (en) 2006-05-10
AU2004203326B2 (en) 2009-06-18
AU2004203326A1 (en) 2005-02-10
CN1605677A (en) 2005-04-13
US20050150057A1 (en) 2005-07-14
US20080047077A1 (en) 2008-02-28
US7276085B2 (en) 2007-10-02
CN1605677B (en) 2010-05-26

Similar Documents

Publication Publication Date Title
CA2475641A1 (en) Methods of treating and cleaning fibers, carpet yarns and carpets
ATE202956T1 (en) METHOD FOR TREATING CARPET YARN AND CARPETS
DE69908910D1 (en) METHOD FOR GRANTING AN ANTIMICROBIAL PROPERTY OF LONG LIFE; FIBERS, TEXTILES OR FABRIC MADE THIS
ATE362521T1 (en) ANTIMICROBIAL TRANSFER SUBSTRATES AND METHOD FOR USE THEREOF
ATE100135T1 (en) SUBSTRATE COATED WITH A STAIN RESISTANT POLYMER CONTAINING A LAUNDRY DETERGENT.
NO994182D0 (en) Carpet, Carpet Back and Method of Preparation Using Homogeneously Branched Ethylene Polymer
JPWO2002031261A1 (en) Water repellent and oil resistant composition
DE602005027079D1 (en) EBE AND METHOD FOR ITS MANUFACTURE
CN108699426A (en) Surface conditioning agent
EP1000962A3 (en) Coated film
ATE262069T1 (en) COMPOSITIONS AND METHODS FOR PROVIDING STAIN RESISTANT PROPERTIES
CA2386256A1 (en) Fabric care composition
JP2005133279A5 (en)
US20060234075A1 (en) Ink-accepting layer forming material and aqueous ink
DE60228854D1 (en) METHOD FOR GALVANIZING PARTICLE FABRICS
DE68905537T2 (en) METHOD FOR EXPANDING CELLULASES IN CLEANING AGENTS.
JP2005503492A (en) Improved polymer grafted cotton fibers and products
CN1863961A (en) Imbibing solutions, method of pretreating substrates with imbibing/coating solutions in preparation for digital printing, and substrates produced therefrom
Ramadan et al. Grafting and quaternization of 2‐(dimethylamino) ethyl methacrylate onto polyamide‐6 fabric pretreated with acetone
BR0015927A (en) Composition and process for cleaning carpets, curtains and covering fabrics, comprising at least one sulphonated copolyester to facilitate the removal of stains and dirt from them
DE60123780D1 (en) ANTIMICROBIAL TRANSFER SUBSTRATES AND METHOD FOR THEIR USE
JPS59179876A (en) Water and oil repelling process of acrylic fiber product
JP2001146682A (en) Colored fabric suitable as interior material or the like and method for producing paper
JPH042881A (en) Fire-proof processing of cellulosic fiber
JP2000212876A (en) Persistently water-repelling glass fiber product and its production

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20220301

MKLA Lapsed

Effective date: 20200831