CA2493635A1 - Acidic hard surface cleaners - Google Patents

Acidic hard surface cleaners Download PDF

Info

Publication number
CA2493635A1
CA2493635A1 CA002493635A CA2493635A CA2493635A1 CA 2493635 A1 CA2493635 A1 CA 2493635A1 CA 002493635 A CA002493635 A CA 002493635A CA 2493635 A CA2493635 A CA 2493635A CA 2493635 A1 CA2493635 A1 CA 2493635A1
Authority
CA
Canada
Prior art keywords
acid
agents
chelating agent
carboxymethyl
tetra
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002493635A
Other languages
French (fr)
Other versions
CA2493635C (en
Inventor
Ralph Edward Rypkema
Maria Vieitez Koretzky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt Benckiser LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=9940974&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2493635(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CA2493635A1 publication Critical patent/CA2493635A1/en
Application granted granted Critical
Publication of CA2493635C publication Critical patent/CA2493635C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/32—Amides; Substituted amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043—For use with aerosol devices
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3788—Graft polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Abstract

The present invention relates to cleaning compositions for hard surfaces whi ch comprise: (a) at least one cationic surfactant having germicidal properties; (b) at least one nonionic surfactant, (c) a chelating agent selected from th e group alkali metal, ammonium and substituted ammonium polyacetates, carboxylates, polycarboxylates and polyhydroxysulfonates; optionall (cl) a precipitating builder selected from the group potassium carbonate and potassium oxalate; optionally (d) an effective amount of propellant; (e) water; and (f) optional components selected from coloring agents; fragrances and fragrance solubilizers; viscosity modifying agents, pH adjusting agents and pH buffers including organic and inorganic salts, hydrotropes; anti- spotting agents; anti-oxidants, preservatives, and corrosion inhibitors.</SD OAB>

Claims (12)

1. A composition comprising (a) at least one cationic surfactant having germicidal properties;
(b) at least one nonionic surfactant;
(c) a chelating agent selected from the group alkali metal, ammonium and substituted ammonium polyacetates, carboxylates, polycarboxylates and polyhydroxysulfonates;
optionally (c1) a precipitating builder selected from the group potassium carbonate and potassium oxalate;
optionally (d) an effective amount of propellant;
(e) water; and (f) optional components selected from coloring agents, fragrances and fragrance solubilizers, viscosity modifying agents, pH adjusting agents and pH buffers including organic and inorganic salts, hydrotropes, anti-spotting agents, anti-oxidants, preservatives, and corrosion inhibitors.
2. The composition according to claim 1 wherein the nonionic surfactant is an alcohol ethoxylate.
3. The composition according to claim 1 wherein the nonionic surfactant is a mixture of alcohol ethoxylate and amine oxide.
4. The compositions according to any one of claims 1 to 3 wherein the (c) chelating agent is selected from sodium, potassium, lithium, ammonium and substituted ammonium salts of ethylenediaminetetraacetic acid, ethylenediaminetriacetic acid, ethylenediaminetetrapropionic acid, diethylenetriaminepentaacetic acid, nitrilotriacetic acid, N-hydroxyethylethylenediaminetriacetic acid, oxydisuccinic acid, iminodisuccinic acid, ethylenediamine disuccinic acid, triethylenetetraaminehexaacetic acid, ethanoldiglycines, proprylenediaminetetraacetic acid, methylglycinediacetic acid, N,N,N',N'-tetra(carboxymethyl)-2,6-diaminohexanoic acid, N,N,N',N' tetra(carboxymethyl)-2,5-diaminopentanoic acid, N,N,N',N'-tetra(carboxymethyl)-2,4-diaminobutyric acid and 2-hydroxy-3-aminopropionic-N,N-diacetic acid, or a derivative thereof.
5. The compositions according to any one of claims 1 to 4 wherein (c) chelating agent is selected from disodium ethanoldiglycinate and tetrasodium salt of ethylenediaminetetraacetic acid.
6. The compositions according to any one of claims 1 to 5 which contain a propellant.
7. A composition comprising (a) at least one cationic surfactant having germicidal properties;
(b) a nonionic surfactant mixture comprising alcohol ethoxylate and amine oxide;
(c) a chelating agent selected from the group alkali metal, ammonium and substituted ammonium polyacetates, carboxylates, polycarboxylates and polyhydroxysulfonates;
optionally (c1) a precipitating builder selected from the group potassium carbonate and potassium oxalate;
optionally (d) an effective amount of propellant;
(e) water; and (f) optional components selected from coloring agents, fragrances and fragrance solubilizers, viscosity modifying agents, pH adjusting agents and pH buffers including organic and inorganic salts, hydrotropes, anti-spotting agents, anti-oxidants, preservatives, and corrosion inhibitors.
8. The compositions according to claim 7 wherein the (c) chelating agent is selected from sodium, potassium, lithium, ammonium and substituted ammonium salts of ethylenediaminetetraacetic acid, ethylenediaminetriacetic acid, ethylenediaminetetrapropionic acid, diethylenetriaminepentaacetic acid, nitrilotriacetic acid, N-hydroxyethylethylenediaminetriacetic acid, oxydisuccinic acid, iminodisuccinic acid, ethylenediamine disuccinic acid, triethylenetetraaminehexaacetic acid, ethanoldiglycines, proprylenediaminetetraacetic acid, methylglycinediacetic acid, N,N,N',N'-tetra(carboxymethyl)-2,6-diaminohexanoic acid, N,N,N',N' tetra(carboxymethyl)-2,5-diaminopentanoic acid, N,N,N',N'-tetra(carboxymethyl)-2,4-diaminobutyric acid and 2-hydroxy-3-aminopropionic-N,N-diacetic acid, or a derivative thereof.
9. The compositions according to any one of claims 7 and 8 wherein (c) chelating agent is selected from disodium ethanoldiglycinate and tetrasodium salt of ethylenediaminetetraacetic acid.
10. The compositions according to any one of claims 7 to 9 which contain a propellant.
11. The compositions as described in Examples Ex. 1 to Ex. 26.
12. A process for the removal of stains from hard surfaces which comprises the step of applying an effective amount of the composition according to any one of claims 1 to 11 to a hard surface needing such treatment.
CA2493635A 2002-07-24 2003-07-14 Acidic hard surface cleaners Expired - Fee Related CA2493635C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB0217093.4 2002-07-24
GB0217093A GB2391234A (en) 2002-07-24 2002-07-24 Hard surface cleaning compositions
PCT/GB2003/003047 WO2004009754A1 (en) 2002-07-24 2003-07-14 Acidic hard surface cleaners

Publications (2)

Publication Number Publication Date
CA2493635A1 true CA2493635A1 (en) 2004-01-29
CA2493635C CA2493635C (en) 2011-05-24

Family

ID=9940974

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2493635A Expired - Fee Related CA2493635C (en) 2002-07-24 2003-07-14 Acidic hard surface cleaners

Country Status (12)

Country Link
US (1) US20060111265A1 (en)
EP (1) EP1523545B1 (en)
AT (1) ATE407999T1 (en)
AU (1) AU2003281521B2 (en)
BR (1) BR0312881A (en)
CA (1) CA2493635C (en)
DE (1) DE60323496D1 (en)
ES (1) ES2309327T3 (en)
GB (1) GB2391234A (en)
MX (1) MXPA05000968A (en)
PL (1) PL205141B1 (en)
WO (1) WO2004009754A1 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5155851B2 (en) * 2005-04-14 2013-03-06 コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ Cleaning liquid for electric personal care equipment
US20090318322A1 (en) * 2005-12-30 2009-12-24 Taylor Timothy J Antibacterial compositions comprising quaternary ammonium germicides and alkamine oxides having reduced irritation potential
DE102006006765A1 (en) * 2006-02-13 2007-08-16 Schülke & Mayr GmbH Alkaline disinfectant and cleaner with improved cleaning performance
US8501988B2 (en) * 2008-04-17 2013-08-06 Ecolab Usa Inc. Synthesis and applications of amino carboxylates
US7838484B2 (en) * 2008-04-18 2010-11-23 Ecolab Inc. Cleaner concentrate comprising ethanoldiglycine and a tertiary surfactant mixture
WO2010078287A1 (en) * 2008-12-29 2010-07-08 3M Innovative Properties Company All surface cleaner protector
US8293696B2 (en) * 2009-02-06 2012-10-23 Ecolab, Inc. Alkaline composition comprising a chelant mixture, including HEIDA, and method of producing same
EP2809765A1 (en) * 2012-01-30 2014-12-10 Reckitt Benckiser LLC Stable, viscous, peroxide containing lavatory treatment compositions
BR112014008261A2 (en) * 2012-07-16 2017-04-18 Reckitt Benckiser Llc self-adhesive washbasin treatment compositions
DE102013218448A1 (en) * 2013-09-13 2015-03-19 Schülke & Mayr GmbH Method for determining the cleaning performance of formulations
US10000728B2 (en) 2015-07-17 2018-06-19 S. C. Johnson & Son, Inc. Cleaning composition with propellant
US10633614B2 (en) * 2015-11-02 2020-04-28 Vanguard Soap LLC Natural laundry soaps
DE102016202846A1 (en) 2016-02-24 2017-08-24 Henkel Ag & Co. Kgaa Detergents or cleaners with improved antimicrobial activity
GB201611745D0 (en) * 2016-07-05 2016-08-17 Biocillin Therapeutics Ltd Hygiene products
US10308897B2 (en) * 2017-04-24 2019-06-04 Gpcp Ip Holdings Llc Alkaline sanitizing soap preparations containing quaternary ammonium chloride agents
WO2024013193A1 (en) * 2022-07-12 2024-01-18 Basf Se Alkoxylated alkanols for enhancing the activity of antimicrobial agents
WO2024020975A1 (en) * 2022-07-29 2024-02-01 Ecolab Usa Inc. Non-oxidizing 2 in 1 cleaning and sanitizing foaming compositions

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3158635A (en) * 1959-03-18 1964-11-24 Stauffer Chemical Co Bis-adduction products and methods of preparing same
US4464293A (en) * 1982-04-12 1984-08-07 Dobrin Robert J Liquid cleaner-disinfectant composition for use in wiping down dental operatories
EP0133900A3 (en) * 1983-08-10 1986-02-19 Sterling Drug Inc. Liquid disinfectant laundry detergents
USH269H (en) * 1985-03-11 1987-05-05 A. E. Staley Manufacturing Company Disinfectant and/or sanitizing cleaner compositions
GB8625103D0 (en) * 1986-10-20 1986-11-26 Unilever Plc Disinfectant compositions
US4704233A (en) * 1986-11-10 1987-11-03 The Procter & Gamble Company Detergent compositions containing ethylenediamine-N,N'-disuccinic acid
DE3712330A1 (en) * 1987-04-11 1988-10-20 Basf Ag 2-HYDROXY-3-AMINO-PROPIONIC ACID-N, N-DIACETIC ACID AND THEIR DERIVATIVES, THEIR PRODUCTION AND USE, IN PARTICULAR AS A COMPLEXING AGENT AND THE DETERGENT AND CLEANING AGENT CONTAINING THEM
EP0639636B1 (en) * 1993-08-19 2001-10-31 Kao Corporation Germicidal-disinfectant detergent composition
CA2132811A1 (en) * 1993-11-01 1995-05-02 Beth T. G. Graubart Antimicrobial dish washing liquid
CA2132274A1 (en) * 1993-11-01 1995-05-02 Janet G. Gardella Foaming antibacterial liquid formulation for cleaning kitchen surfaces
EP0691397B1 (en) * 1994-07-07 2004-10-06 The Clorox Company Antimicrobial hard surface cleaner
US5576284A (en) * 1994-09-26 1996-11-19 Henkel Kommanditgesellschaft Auf Aktien Disinfecting cleanser for hard surfaces
US6013615A (en) * 1995-07-26 2000-01-11 The Clorox Company Antimicrobial hard surface cleaner
GB9521837D0 (en) * 1995-10-25 1996-01-03 Reckitt & Colman Inc Improved compositions containing organic compounds
GB2309706B (en) * 1996-01-31 2000-02-09 Reckitt & Colman Inc Liquid detergent composition comprising quaternary ammonium surfactant having germicidal properties
US5814591A (en) * 1996-04-12 1998-09-29 The Clorox Company Hard surface cleaner with enhanced soil removal
US5948741A (en) * 1996-04-12 1999-09-07 The Clorox Company Aerosol hard surface cleaner with enhanced soil removal
GB2322552B (en) * 1997-03-01 2001-05-16 Reckitt & Colman Inc Liquid disinfectant concentrate
US6339057B1 (en) * 1997-04-14 2002-01-15 Stepan Company High foaming detergent composition having a non-ionic surfactant base
WO1999019438A1 (en) * 1997-10-15 1999-04-22 Stepan Company High foaming detergent composition having non-ionic surfactant base
JPH11171843A (en) * 1997-11-18 1999-06-29 Mitsubishi Rayon Co Ltd High-bulk density (s,s)-ethylenediamine-n,n'-disuccinic acid crystal and acquisition thereof
EP1034245B1 (en) * 1997-11-28 2003-09-17 Reckitt Benckiser Inc. Concentrated liquid cleaner for hard surfaces
GB2331758B (en) * 1997-11-28 2002-04-17 Reckitt & Colman Inc Disinfectant compositions
GB2336371B (en) * 1998-04-14 2002-05-08 Reckitt & Colman Inc Aqueous disinfecting and cleaning compositions
GB2336375A (en) * 1998-04-14 1999-10-20 Reckitt & Colman Inc Liquid disinfectant composition
GB2336372B (en) * 1998-04-14 2002-05-01 Reckitt & Colman Inc Aqueous disinfecting and cleaning compositions
EP0966883A1 (en) * 1998-06-26 1999-12-29 The Procter & Gamble Company The use of an anti-microbial compound for disinfection
US6413920B1 (en) * 1998-07-10 2002-07-02 Procter & Gamble Company Amine reaction compounds comprising one or more active ingredient
GB9901702D0 (en) * 1999-01-27 1999-03-17 Reckitt & Colman Inc Improvements in or relating to organic compositions
US5985813A (en) * 1999-04-07 1999-11-16 Colgate-Palmolive Co. Liquid cleaning compositions based on cationic surfactant, nonionic surfactant and nonionic polymer
US6425406B1 (en) * 1999-09-14 2002-07-30 S. C. Johnson & Son, Inc. Toilet bowl cleaning method
US6667287B2 (en) * 2000-04-20 2003-12-23 Colgate-Palmolive Company Light duty cleaning composition comprising an amine oxide and polyacrylic acid homopolymer
US20030104969A1 (en) * 2000-05-11 2003-06-05 Caswell Debra Sue Laundry system having unitized dosing
US6821943B2 (en) * 2001-03-13 2004-11-23 S. C. Johnson & Son, Inc. Hard surface antimicrobial cleaner with residual antimicrobial effect comprising an organosilane
US6395698B1 (en) * 2001-06-11 2002-05-28 Mason Chemical Company Corrosion resistant sanitizing/disinfecting cleaning and wood preservative formulation
EP1419229A4 (en) * 2001-08-24 2008-04-30 Clorox Co Improved cleaning composition

Also Published As

Publication number Publication date
WO2004009754A1 (en) 2004-01-29
DE60323496D1 (en) 2008-10-23
GB0217093D0 (en) 2002-09-04
CA2493635C (en) 2011-05-24
ATE407999T1 (en) 2008-09-15
EP1523545B1 (en) 2008-09-10
BR0312881A (en) 2005-06-28
PL205141B1 (en) 2010-03-31
AU2003281521B2 (en) 2009-05-21
PL374859A1 (en) 2005-11-14
ES2309327T3 (en) 2008-12-16
US20060111265A1 (en) 2006-05-25
EP1523545A1 (en) 2005-04-20
AU2003281521A1 (en) 2004-02-09
MXPA05000968A (en) 2005-06-08
GB2391234A (en) 2004-02-04

Similar Documents

Publication Publication Date Title
CA2493635A1 (en) Acidic hard surface cleaners
EP3204532B1 (en) Ph neutral deruster composition
JP2011516656A5 (en)
CA2016424A1 (en) Chelating agents and detergent and cleaning compositions containing them
ZA200501382B (en) Water soluble sachet containing hard surface cleaner
WO1995003389A1 (en) High wetting-power detergent
JP2010070805A (en) Descaling and rust-preventive agent
CN103789775A (en) Compound rapid medical apparatus rust remover
AR021225A1 (en) COMPOSITION AND PROCESS TO REMOVE ACID GASES
US5922667A (en) Cleaning gels
MXPA01006925A (en) Aqueous cleaning compositions.
JP2021517597A (en) Aqueous cleaning formulation
JP7144821B2 (en) liquid detergent composition
JP6110260B2 (en) Engine cleaning composition and engine cleaning method
EP1891190B1 (en) Aqueous cleaning compositions
JPH08505413A (en) Cleaning composition combining high hydrophilicity and high hydrophobicity nonionic surfactant
JP2616847B2 (en) Additives for alkaline cleaners for metal products and alkaline cleaner compositions for metal products containing the same
JP2001323299A (en) Liquid detergent composition
RU2019116014A (en) PHOSPHATE-FREE DETERGENT COMPOSITIONS AND THEIR APPLICATIONS
JP4024446B2 (en) Liquid detergent composition
JPH11152497A (en) Detergent composition for washing car
JPH11158492A (en) Detergent composition for steel sheet surface
JP2951755B2 (en) Cleaning composition for hard surfaces
JP2608256B2 (en) Liquid detergent composition
JP2011132381A (en) Cleaner for metal

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20150714