CA2502694A1 - Acid-coated sand for gravel pack and filter cake clean-up - Google Patents

Acid-coated sand for gravel pack and filter cake clean-up Download PDF

Info

Publication number
CA2502694A1
CA2502694A1 CA002502694A CA2502694A CA2502694A1 CA 2502694 A1 CA2502694 A1 CA 2502694A1 CA 002502694 A CA002502694 A CA 002502694A CA 2502694 A CA2502694 A CA 2502694A CA 2502694 A1 CA2502694 A1 CA 2502694A1
Authority
CA
Canada
Prior art keywords
acid
alpha
hydroxycarboxylic acid
proppants
coated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002502694A
Other languages
French (fr)
Other versions
CA2502694C (en
Inventor
Li-Jein Lee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MI LLC
Original Assignee
M-I L.L.C.
Li-Jein Lee
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by M-I L.L.C., Li-Jein Lee filed Critical M-I L.L.C.
Publication of CA2502694A1 publication Critical patent/CA2502694A1/en
Application granted granted Critical
Publication of CA2502694C publication Critical patent/CA2502694C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/52Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/60Compositions for stimulating production by acting on the underground formation
    • C09K8/80Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open
    • C09K8/805Coated proppants
    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/02Subsoil filtering
    • E21B43/04Gravelling of wells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S507/00Earth boring, well treating, and oil field chemistry
    • Y10S507/901Organically modified inorganic solid
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S507/00Earth boring, well treating, and oil field chemistry
    • Y10S507/922Fracture fluid
    • Y10S507/924Fracture fluid with specified propping feature

Abstract

A method of the preparation and utilization of polymerized alpha- hydroxycarboxylicacid-coated proppants for gravel pack and removal of filter cake that was deposited by reservoir drilling fluid. In a preferred example, polyglycolic-acid-coated sand is used to replace conventional gravel pack sa nd typically used for gravel packing. Under downhole conditions, the acidic by- product generated from the hydration of polyglycolic-acid-coated sand can break down acid-soluble and/or acid-breakable components embedded in the filter cake. This reaction enhances the filter cake removal and the flow of hydrocarbon from the producing formation. The polyglycolic-acid-coated sand may be produced by polymerizing a glycolic acid with a natural or synthetic proppant like 20-40 mesh commercial sand, at temperatures of about 210 ~F or higher.

Claims (26)

1. A proppant comprising a particulate substrate coated with an alpha-hydroxycarboxylic acid which has been polymerized.
2. The proppant of claim 1 wherein the alpha-hydroxycarboxylic acid is selected from glycolic, malic, lactic, gluconic, citric, mandelic, saccharic, mucic, and tartaric acid and mixtures thereof.
3. The proppant of claim 1 wherein the alpha-hydroxycarboxylic acid is glycolic.
4. The proppant of claim 1 wherein the particulate substrate is selected from natural and synthetic silica sand, glass beads, quartz, ceramics, thermoplastic resin, sintered bauxite, and metal oxides.
5. The proppant of claim 1 wherein the particulate substrate is silica sand and the alpha-hydroxycarboxylic acid is glycolic.
6. The proppant of claim 1 wherein the polymerized alpha-hydroxycarboxylic acid content is about 5% to about 20% by weight per dry weight of the particulate substrate.
7. The proppant of claim 1 wherein the polymerized alpha-hydroxycarboxylic acid content is about 8% to about 10% by weight per dry weight of the particulate substrate.
8. A method of making a proppant coated with an alpha-hydroxycarboxylic acid polymer comprising: heating a solution of monomeric alpha-hydroxycarboxylic acid with sized particulate substrate until polymerization of alpha-hydroxycarboxylic acid is completed.
9. The method of claim 8 wherein the monomeric alpha-hydroxycarboxylic acid is selected from glycolic, malic, lactic, gluconic, citric, mandelic, saccharic, mucic, and tartaric acid and mixtures thereof.
10. The method of claim 8 wherein the monomeric alpha-hydroxycarboxylic acid is glycolic acid.
11. The method of claim 8 wherein the particulate substrate is selected from natural and synthetic silica sand, glass beads, quartz, ceramics, thermoplastic resin, sintered bauxite, and metal oxides.
12. The method of claim 8 wherein the completion of polymerization is indicated by a change in the color of the polymerized alpha-hydroxycarboxylic acid/particulate substrate mixture.
13. The method of claim 8 wherein the polymerization is carried out until there is a reduction of moisture content of the said mixture to 5% or less.
14. The method of claim 8 wherein the polymerization is repeated to form multiple layers of polymerized alpha-hydroxycarboxylic acid on the particulate substrate material.
15. The method of claim 8 wherein the polymerization is carried out at a temperature above about 210 °F.
16. The process of using proppants coated with polymerized alpha-hydroxycarboxylic acid for a gravel pack operation to fill the annular space between the formation and production screen and filter cake removal comprising:
combining said proppants with a gravel pack fluid to create a mixture;
pumping said mixture downhole into the annular space between the formation and production screen; and, letting said proppants contact the filter cake until the acid-soluble and acid-breakable components in the filter cake are broken down.
17. The process of claim 16 wherein the proppants are polyglycolic-acid coated sand.
18. The process of claim 16 wherein the gravel pack fluid comprises water, brines, and electrolytes.
19. The process of claim 16 wherein the gravel pack fluid comprises NaCl, KCl, CaCl2, CaBr2 and mixtures thereof.
20. The process of claim 16, wherein the mixture is left in the well for at least 24 hours.
21. The process of claim 16 wherein the proppants coated with polymerized alpha-hydroxycarboxylic acid are mixed with un-coated proppants.
22. The process of claim 21 wherein the proppants are polyglycolic-acid coated sand, and the un-coated proppants are conventional gravel pack sand.
23. A fluid useful for gravel packing a well comprising proppants coated with polymerized alpha-hydroxycarboxylic acid, water, and NaCl, KCl, CaCl2, CaBr2 and mixtures thereof.
24. The fluid of claim 23 wherein the proppants are coated with polyglycolic acid.
25. The process of using proppants coated with polymerized alpha-hydroxycarboxylic acid for a gravel pack operation to fill the annular space between the formation and production screen comprising:
combining said proppants with a gravel pack fluid to create a mixture, and pumping said mixture downhole into the annular space between the formation and production screen.
26. The process of claim 25 wherein the proppants are coated with polyglycolic acid.
CA2502694A 2002-09-20 2003-09-12 Acid-coated sand for gravel pack and filter cake clean-up Expired - Fee Related CA2502694C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/065,141 US6817414B2 (en) 2002-09-20 2002-09-20 Acid coated sand for gravel pack and filter cake clean-up
US10/065,141 2002-09-20
PCT/US2003/028567 WO2004027213A1 (en) 2002-09-20 2003-09-12 Acid-coated sand for gravel pack and filter cake clean-up

Publications (2)

Publication Number Publication Date
CA2502694A1 true CA2502694A1 (en) 2004-04-01
CA2502694C CA2502694C (en) 2011-11-01

Family

ID=31989986

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2502694A Expired - Fee Related CA2502694C (en) 2002-09-20 2003-09-12 Acid-coated sand for gravel pack and filter cake clean-up

Country Status (10)

Country Link
US (2) US6817414B2 (en)
EP (1) EP1546507B1 (en)
AT (1) ATE372444T1 (en)
AU (1) AU2003267138A1 (en)
CA (1) CA2502694C (en)
DE (1) DE60316165T2 (en)
EA (1) EA008279B1 (en)
MX (1) MXPA05003132A (en)
NO (1) NO339018B1 (en)
WO (1) WO2004027213A1 (en)

Families Citing this family (181)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080064613A1 (en) * 2006-09-11 2008-03-13 M-I Llc Dispersant coated weighting agents
US7276466B2 (en) * 2001-06-11 2007-10-02 Halliburton Energy Services, Inc. Compositions and methods for reducing the viscosity of a fluid
US7080688B2 (en) * 2003-08-14 2006-07-25 Halliburton Energy Services, Inc. Compositions and methods for degrading filter cake
US7168489B2 (en) * 2001-06-11 2007-01-30 Halliburton Energy Services, Inc. Orthoester compositions and methods for reducing the viscosified treatment fluids
US7140438B2 (en) * 2003-08-14 2006-11-28 Halliburton Energy Services, Inc. Orthoester compositions and methods of use in subterranean applications
US6691780B2 (en) 2002-04-18 2004-02-17 Halliburton Energy Services, Inc. Tracking of particulate flowback in subterranean wells
US7219731B2 (en) * 2002-08-26 2007-05-22 Schlumberger Technology Corporation Degradable additive for viscoelastic surfactant based fluid systems
US7398826B2 (en) * 2003-11-14 2008-07-15 Schlumberger Technology Corporation Well treatment with dissolvable polymer
US7972997B2 (en) * 2002-09-20 2011-07-05 M-I L.L.C. Process for coating gravel pack sand with polymeric breaker
DE60310978D1 (en) * 2002-10-28 2007-02-15 Schlumberger Technology Bv SELF-CREATED RENDER FILTER CAKE
US8327931B2 (en) 2009-12-08 2012-12-11 Baker Hughes Incorporated Multi-component disappearing tripping ball and method for making the same
US8403037B2 (en) 2009-12-08 2013-03-26 Baker Hughes Incorporated Dissolvable tool and method
US9079246B2 (en) 2009-12-08 2015-07-14 Baker Hughes Incorporated Method of making a nanomatrix powder metal compact
US9109429B2 (en) 2002-12-08 2015-08-18 Baker Hughes Incorporated Engineered powder compact composite material
US9682425B2 (en) 2009-12-08 2017-06-20 Baker Hughes Incorporated Coated metallic powder and method of making the same
US9101978B2 (en) 2002-12-08 2015-08-11 Baker Hughes Incorporated Nanomatrix powder metal compact
KR100487950B1 (en) * 2003-02-03 2005-05-06 삼성전자주식회사 Semiconductor device having a contact hole disposed on a gate electrode overlapped with an active region
US7114570B2 (en) * 2003-04-07 2006-10-03 Halliburton Energy Services, Inc. Methods and compositions for stabilizing unconsolidated subterranean formations
US20040231845A1 (en) 2003-05-15 2004-11-25 Cooke Claude E. Applications of degradable polymers in wells
US20090107684A1 (en) 2007-10-31 2009-04-30 Cooke Jr Claude E Applications of degradable polymers for delayed mechanical changes in wells
US20050130848A1 (en) * 2003-06-27 2005-06-16 Halliburton Energy Services, Inc. Compositions and methods for improving fracture conductivity in a subterranean well
US7044220B2 (en) * 2003-06-27 2006-05-16 Halliburton Energy Services, Inc. Compositions and methods for improving proppant pack permeability and fracture conductivity in a subterranean well
US7032663B2 (en) * 2003-06-27 2006-04-25 Halliburton Energy Services, Inc. Permeable cement and sand control methods utilizing permeable cement in subterranean well bores
US7178596B2 (en) * 2003-06-27 2007-02-20 Halliburton Energy Services, Inc. Methods for improving proppant pack permeability and fracture conductivity in a subterranean well
US7228904B2 (en) * 2003-06-27 2007-06-12 Halliburton Energy Services, Inc. Compositions and methods for improving fracture conductivity in a subterranean well
US7044224B2 (en) * 2003-06-27 2006-05-16 Halliburton Energy Services, Inc. Permeable cement and methods of fracturing utilizing permeable cement in subterranean well bores
US7036587B2 (en) * 2003-06-27 2006-05-02 Halliburton Energy Services, Inc. Methods of diverting treating fluids in subterranean zones and degradable diverting materials
US20050028976A1 (en) * 2003-08-05 2005-02-10 Nguyen Philip D. Compositions and methods for controlling the release of chemicals placed on particulates
US7497278B2 (en) * 2003-08-14 2009-03-03 Halliburton Energy Services, Inc. Methods of degrading filter cakes in a subterranean formation
US8541051B2 (en) 2003-08-14 2013-09-24 Halliburton Energy Services, Inc. On-the fly coating of acid-releasing degradable material onto a particulate
US6997259B2 (en) * 2003-09-05 2006-02-14 Halliburton Energy Services, Inc. Methods for forming a permeable and stable mass in a subterranean formation
US7829507B2 (en) 2003-09-17 2010-11-09 Halliburton Energy Services Inc. Subterranean treatment fluids comprising a degradable bridging agent and methods of treating subterranean formations
US7833944B2 (en) 2003-09-17 2010-11-16 Halliburton Energy Services, Inc. Methods and compositions using crosslinked aliphatic polyesters in well bore applications
US7674753B2 (en) 2003-09-17 2010-03-09 Halliburton Energy Services, Inc. Treatment fluids and methods of forming degradable filter cakes comprising aliphatic polyester and their use in subterranean formations
US7195068B2 (en) * 2003-12-15 2007-03-27 Halliburton Energy Services, Inc. Filter cake degradation compositions and methods of use in subterranean operations
US7204316B2 (en) * 2004-01-20 2007-04-17 Halliburton Energy Services, Inc. Expandable well screen having temporary sealing substance
US7096947B2 (en) * 2004-01-27 2006-08-29 Halliburton Energy Services, Inc. Fluid loss control additives for use in fracturing subterranean formations
US7204312B2 (en) 2004-01-30 2007-04-17 Halliburton Energy Services, Inc. Compositions and methods for the delivery of chemical components in subterranean well bores
US20050173116A1 (en) 2004-02-10 2005-08-11 Nguyen Philip D. Resin compositions and methods of using resin compositions to control proppant flow-back
US20050183741A1 (en) * 2004-02-20 2005-08-25 Surjaatmadja Jim B. Methods of cleaning and cutting using jetted fluids
US7211547B2 (en) 2004-03-03 2007-05-01 Halliburton Energy Services, Inc. Resin compositions and methods of using such resin compositions in subterranean applications
US7172022B2 (en) 2004-03-17 2007-02-06 Halliburton Energy Services, Inc. Cement compositions containing degradable materials and methods of cementing in subterranean formations
GB2412389A (en) * 2004-03-27 2005-09-28 Cleansorb Ltd Process for treating underground formations
GB2412391A (en) * 2004-03-27 2005-09-28 Cleansorb Ltd Process for disruption of filter cakes
US20070078063A1 (en) * 2004-04-26 2007-04-05 Halliburton Energy Services, Inc. Subterranean treatment fluids and methods of treating subterranean formations
US7299875B2 (en) 2004-06-08 2007-11-27 Halliburton Energy Services, Inc. Methods for controlling particulate migration
US7621334B2 (en) * 2005-04-29 2009-11-24 Halliburton Energy Services, Inc. Acidic treatment fluids comprising scleroglucan and/or diutan and associated methods
US7475728B2 (en) * 2004-07-23 2009-01-13 Halliburton Energy Services, Inc. Treatment fluids and methods of use in subterranean formations
US20060032633A1 (en) * 2004-08-10 2006-02-16 Nguyen Philip D Methods and compositions for carrier fluids comprising water-absorbent fibers
US20060046938A1 (en) * 2004-09-02 2006-03-02 Harris Philip C Methods and compositions for delinking crosslinked fluids
US7299869B2 (en) * 2004-09-03 2007-11-27 Halliburton Energy Services, Inc. Carbon foam particulates and methods of using carbon foam particulates in subterranean applications
US7413017B2 (en) * 2004-09-24 2008-08-19 Halliburton Energy Services, Inc. Methods and compositions for inducing tip screenouts in frac-packing operations
US7757768B2 (en) 2004-10-08 2010-07-20 Halliburton Energy Services, Inc. Method and composition for enhancing coverage and displacement of treatment fluids into subterranean formations
US7648946B2 (en) 2004-11-17 2010-01-19 Halliburton Energy Services, Inc. Methods of degrading filter cakes in subterranean formations
US7553800B2 (en) * 2004-11-17 2009-06-30 Halliburton Energy Services, Inc. In-situ filter cake degradation compositions and methods of use in subterranean formations
US7883740B2 (en) 2004-12-12 2011-02-08 Halliburton Energy Services, Inc. Low-quality particulates and methods of making and using improved low-quality particulates
US20060135372A1 (en) * 2004-12-21 2006-06-22 Tetra Technologies, Inc. Controlled degradation of filtercakes and other downhole compositions
US20060169182A1 (en) 2005-01-28 2006-08-03 Halliburton Energy Services, Inc. Methods and compositions relating to the hydrolysis of water-hydrolysable materials
US8030249B2 (en) 2005-01-28 2011-10-04 Halliburton Energy Services, Inc. Methods and compositions relating to the hydrolysis of water-hydrolysable materials
US7267170B2 (en) * 2005-01-31 2007-09-11 Halliburton Energy Services, Inc. Self-degrading fibers and associated methods of use and manufacture
US20080009423A1 (en) 2005-01-31 2008-01-10 Halliburton Energy Services, Inc. Self-degrading fibers and associated methods of use and manufacture
US7497258B2 (en) * 2005-02-01 2009-03-03 Halliburton Energy Services, Inc. Methods of isolating zones in subterranean formations using self-degrading cement compositions
US20060169448A1 (en) * 2005-02-01 2006-08-03 Halliburton Energy Services, Inc. Self-degrading cement compositions and methods of using self-degrading cement compositions in subterranean formations
US7353876B2 (en) * 2005-02-01 2008-04-08 Halliburton Energy Services, Inc. Self-degrading cement compositions and methods of using self-degrading cement compositions in subterranean formations
US20060172989A1 (en) * 2005-02-02 2006-08-03 Michael Konkel Aminoalkoxyphenyl indolone derivatives
US20070298977A1 (en) * 2005-02-02 2007-12-27 Halliburton Energy Services, Inc. Degradable particulate generation and associated methods
US20060169450A1 (en) * 2005-02-02 2006-08-03 Halliburton Energy Services, Inc. Degradable particulate generation and associated methods
US8598092B2 (en) 2005-02-02 2013-12-03 Halliburton Energy Services, Inc. Methods of preparing degradable materials and methods of use in subterranean formations
US20060172895A1 (en) * 2005-02-02 2006-08-03 Halliburton Energy Services, Inc. Degradable particulate generation and associated methods
US7506689B2 (en) * 2005-02-22 2009-03-24 Halliburton Energy Services, Inc. Fracturing fluids comprising degradable diverting agents and methods of use in subterranean formations
US7216705B2 (en) * 2005-02-22 2007-05-15 Halliburton Energy Services, Inc. Methods of placing treatment chemicals
US7799744B2 (en) * 2005-03-09 2010-09-21 Halliburton Energy Services, Inc. Polymer coated particulates
US7308939B2 (en) * 2005-03-09 2007-12-18 Halliburton Energy Services, Inc. Methods of using polymer-coated particulates
US7673686B2 (en) 2005-03-29 2010-03-09 Halliburton Energy Services, Inc. Method of stabilizing unconsolidated formation for sand control
US7677315B2 (en) 2005-05-12 2010-03-16 Halliburton Energy Services, Inc. Degradable surfactants and methods for use
US7662753B2 (en) 2005-05-12 2010-02-16 Halliburton Energy Services, Inc. Degradable surfactants and methods for use
US7337839B2 (en) * 2005-06-10 2008-03-04 Schlumberger Technology Corporation Fluid loss additive for enhanced fracture clean-up
US20060276345A1 (en) * 2005-06-07 2006-12-07 Halliburton Energy Servicers, Inc. Methods controlling the degradation rate of hydrolytically degradable materials
US7318474B2 (en) 2005-07-11 2008-01-15 Halliburton Energy Services, Inc. Methods and compositions for controlling formation fines and reducing proppant flow-back
US7451815B2 (en) * 2005-08-22 2008-11-18 Halliburton Energy Services, Inc. Sand control screen assembly enhanced with disappearing sleeve and burst disc
US20070049501A1 (en) * 2005-09-01 2007-03-01 Halliburton Energy Services, Inc. Fluid-loss control pills comprising breakers that comprise orthoesters and/or poly(orthoesters) and methods of use
US7713916B2 (en) 2005-09-22 2010-05-11 Halliburton Energy Services, Inc. Orthoester-based surfactants and associated methods
US7461697B2 (en) * 2005-11-21 2008-12-09 Halliburton Energy Services, Inc. Methods of modifying particulate surfaces to affect acidic sites thereon
US20100132951A1 (en) * 2005-12-16 2010-06-03 Tetra Technologies, Inc. Controlled De-functionalization of Filtercakes and Other Downhole Compositions
US20070173416A1 (en) * 2006-01-20 2007-07-26 Halliburton Energy Services, Inc. Well treatment compositions for use in acidizing a well
US8613320B2 (en) 2006-02-10 2013-12-24 Halliburton Energy Services, Inc. Compositions and applications of resins in treating subterranean formations
US7819192B2 (en) 2006-02-10 2010-10-26 Halliburton Energy Services, Inc. Consolidating agent emulsions and associated methods
US7926591B2 (en) 2006-02-10 2011-04-19 Halliburton Energy Services, Inc. Aqueous-based emulsified consolidating agents suitable for use in drill-in applications
US7665517B2 (en) 2006-02-15 2010-02-23 Halliburton Energy Services, Inc. Methods of cleaning sand control screens and gravel packs
US7608566B2 (en) * 2006-03-30 2009-10-27 Halliburton Energy Services, Inc. Degradable particulates as friction reducers for the flow of solid particulates and associated methods of use
US8133587B2 (en) * 2006-07-12 2012-03-13 Georgia-Pacific Chemicals Llc Proppant materials comprising a coating of thermoplastic material, and methods of making and using
US8003214B2 (en) * 2006-07-12 2011-08-23 Georgia-Pacific Chemicals Llc Well treating materials comprising coated proppants, and methods
US20080026955A1 (en) * 2006-07-25 2008-01-31 Halliburton Energy Services, Inc. Degradable particulates and associated methods
US20080026960A1 (en) * 2006-07-25 2008-01-31 Halliburton Energy Services, Inc. Degradable particulates and associated methods
US20080026959A1 (en) * 2006-07-25 2008-01-31 Halliburton Energy Services, Inc. Degradable particulates and associated methods
US8329621B2 (en) 2006-07-25 2012-12-11 Halliburton Energy Services, Inc. Degradable particulates and associated methods
US7678743B2 (en) 2006-09-20 2010-03-16 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US7687438B2 (en) 2006-09-20 2010-03-30 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US7678742B2 (en) 2006-09-20 2010-03-16 Halliburton Energy Services, Inc. Drill-in fluids and associated methods
US20080093074A1 (en) * 2006-10-20 2008-04-24 Schlumberger Technology Corporation Communicating Through a Barrier in a Well
US7686080B2 (en) 2006-11-09 2010-03-30 Halliburton Energy Services, Inc. Acid-generating fluid loss control additives and associated methods
US8220548B2 (en) 2007-01-12 2012-07-17 Halliburton Energy Services Inc. Surfactant wash treatment fluids and associated methods
US7934557B2 (en) 2007-02-15 2011-05-03 Halliburton Energy Services, Inc. Methods of completing wells for controlling water and particulate production
US8695708B2 (en) 2007-03-26 2014-04-15 Schlumberger Technology Corporation Method for treating subterranean formation with degradable material
US8058213B2 (en) * 2007-05-11 2011-11-15 Georgia-Pacific Chemicals Llc Increasing buoyancy of well treating materials
US7754659B2 (en) * 2007-05-15 2010-07-13 Georgia-Pacific Chemicals Llc Reducing flow-back in well treating materials
US20090062157A1 (en) * 2007-08-30 2009-03-05 Halliburton Energy Services, Inc. Methods and compositions related to the degradation of degradable polymers involving dehydrated salts and other associated methods
US20090247430A1 (en) * 2008-03-28 2009-10-01 Diankui Fu Elongated particle breakers in low pH fracturing fluids
US8006760B2 (en) 2008-04-10 2011-08-30 Halliburton Energy Services, Inc. Clean fluid systems for partial monolayer fracturing
US7906464B2 (en) 2008-05-13 2011-03-15 Halliburton Energy Services, Inc. Compositions and methods for the removal of oil-based filtercakes
WO2010001323A1 (en) * 2008-07-01 2010-01-07 Schlumberger Canada Limited System, method, and apparatus for injection well clean-up operations
US7833943B2 (en) 2008-09-26 2010-11-16 Halliburton Energy Services Inc. Microemulsifiers and methods of making and using same
US8016040B2 (en) * 2008-11-26 2011-09-13 Schlumberger Technology Corporation Fluid loss control
US7762329B1 (en) 2009-01-27 2010-07-27 Halliburton Energy Services, Inc. Methods for servicing well bores with hardenable resin compositions
US7998910B2 (en) 2009-02-24 2011-08-16 Halliburton Energy Services, Inc. Treatment fluids comprising relative permeability modifiers and methods of use
US8273406B1 (en) 2009-06-19 2012-09-25 Fritz Industries, Inc. Particulate solid coated with a curable resin
US8082992B2 (en) 2009-07-13 2011-12-27 Halliburton Energy Services, Inc. Methods of fluid-controlled geometry stimulation
CA2777748C (en) * 2009-10-20 2017-09-19 Soane Energy Llc Proppants for hydraulic fracturing technologies
US8720555B2 (en) 2009-11-18 2014-05-13 Halliburton Energy Services, Inc. Self-diverting high-rate water packs
US9127515B2 (en) 2010-10-27 2015-09-08 Baker Hughes Incorporated Nanomatrix carbon composite
US8573295B2 (en) 2010-11-16 2013-11-05 Baker Hughes Incorporated Plug and method of unplugging a seat
US8528633B2 (en) 2009-12-08 2013-09-10 Baker Hughes Incorporated Dissolvable tool and method
US8425651B2 (en) 2010-07-30 2013-04-23 Baker Hughes Incorporated Nanomatrix metal composite
US9227243B2 (en) 2009-12-08 2016-01-05 Baker Hughes Incorporated Method of making a powder metal compact
US9243475B2 (en) 2009-12-08 2016-01-26 Baker Hughes Incorporated Extruded powder metal compact
US10240419B2 (en) 2009-12-08 2019-03-26 Baker Hughes, A Ge Company, Llc Downhole flow inhibition tool and method of unplugging a seat
US8424610B2 (en) 2010-03-05 2013-04-23 Baker Hughes Incorporated Flow control arrangement and method
US8776884B2 (en) 2010-08-09 2014-07-15 Baker Hughes Incorporated Formation treatment system and method
US8714248B2 (en) 2010-08-25 2014-05-06 Schlumberger Technology Corporation Method of gravel packing
US9234415B2 (en) 2010-08-25 2016-01-12 Schlumberger Technology Corporation Delivery of particulate material below ground
US8448706B2 (en) * 2010-08-25 2013-05-28 Schlumberger Technology Corporation Delivery of particulate material below ground
US8459353B2 (en) * 2010-08-25 2013-06-11 Schlumberger Technology Corporation Delivery of particulate material below ground
US9090955B2 (en) 2010-10-27 2015-07-28 Baker Hughes Incorporated Nanomatrix powder metal composite
EP2635650B1 (en) * 2010-11-03 2017-02-01 3M Innovative Properties Company Fluid composition comprising glass microspheres and method of making and using the same
US9080098B2 (en) 2011-04-28 2015-07-14 Baker Hughes Incorporated Functionally gradient composite article
US8631876B2 (en) 2011-04-28 2014-01-21 Baker Hughes Incorporated Method of making and using a functionally gradient composite tool
US9139928B2 (en) 2011-06-17 2015-09-22 Baker Hughes Incorporated Corrodible downhole article and method of removing the article from downhole environment
US9707739B2 (en) 2011-07-22 2017-07-18 Baker Hughes Incorporated Intermetallic metallic composite, method of manufacture thereof and articles comprising the same
US8783365B2 (en) 2011-07-28 2014-07-22 Baker Hughes Incorporated Selective hydraulic fracturing tool and method thereof
US9833838B2 (en) 2011-07-29 2017-12-05 Baker Hughes, A Ge Company, Llc Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle
US9643250B2 (en) 2011-07-29 2017-05-09 Baker Hughes Incorporated Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle
US9057242B2 (en) 2011-08-05 2015-06-16 Baker Hughes Incorporated Method of controlling corrosion rate in downhole article, and downhole article having controlled corrosion rate
US9033055B2 (en) 2011-08-17 2015-05-19 Baker Hughes Incorporated Selectively degradable passage restriction and method
US9856547B2 (en) 2011-08-30 2018-01-02 Bakers Hughes, A Ge Company, Llc Nanostructured powder metal compact
US9090956B2 (en) 2011-08-30 2015-07-28 Baker Hughes Incorporated Aluminum alloy powder metal compact
US9109269B2 (en) 2011-08-30 2015-08-18 Baker Hughes Incorporated Magnesium alloy powder metal compact
US9297244B2 (en) 2011-08-31 2016-03-29 Self-Suspending Proppant Llc Self-suspending proppants for hydraulic fracturing comprising a coating of hydrogel-forming polymer
US20140000891A1 (en) 2012-06-21 2014-01-02 Self-Suspending Proppant Llc Self-suspending proppants for hydraulic fracturing
EP2751387B1 (en) 2011-08-31 2019-06-19 Self-Suspending Proppant LLC Self-suspending proppants for hydraulic fracturing
US9868896B2 (en) 2011-08-31 2018-01-16 Self-Suspending Proppant Llc Self-suspending proppants for hydraulic fracturing
US9643144B2 (en) 2011-09-02 2017-05-09 Baker Hughes Incorporated Method to generate and disperse nanostructures in a composite material
US9187990B2 (en) 2011-09-03 2015-11-17 Baker Hughes Incorporated Method of using a degradable shaped charge and perforating gun system
US9133695B2 (en) 2011-09-03 2015-09-15 Baker Hughes Incorporated Degradable shaped charge and perforating gun system
US9347119B2 (en) 2011-09-03 2016-05-24 Baker Hughes Incorporated Degradable high shock impedance material
US8936086B2 (en) 2011-10-04 2015-01-20 Halliburton Energy Services, Inc. Methods of fluid loss control, diversion, and sealing using deformable particulates
US9284812B2 (en) 2011-11-21 2016-03-15 Baker Hughes Incorporated System for increasing swelling efficiency
US9010416B2 (en) 2012-01-25 2015-04-21 Baker Hughes Incorporated Tubular anchoring system and a seat for use in the same
US9068428B2 (en) 2012-02-13 2015-06-30 Baker Hughes Incorporated Selectively corrodible downhole article and method of use
US9605508B2 (en) 2012-05-08 2017-03-28 Baker Hughes Incorporated Disintegrable and conformable metallic seal, and method of making the same
US9745507B2 (en) 2012-08-01 2017-08-29 Halliburton Energy Services, Inc. Synthetic proppants and monodispersed proppants and methods of making the same
US9835608B2 (en) 2012-12-20 2017-12-05 Saudi Arabian Oil Company Method for assessing ablation modulai of mudcakes to predict ease of mudcake removal or cleaning efficiency of cleaning/washing/spacer fluids
US10550319B2 (en) * 2013-04-05 2020-02-04 Halliburton Energy Services, Inc. Wellbore servicing compositions and methods of making and using same
CA2849415C (en) 2013-04-24 2017-02-28 Robert D. Skala Methods for fracturing subterranean formations
US9284479B2 (en) 2013-06-22 2016-03-15 Halliburton Energy Services, Inc. Invert emulsion for swelling elastomer and filtercake removal in a well
US9816339B2 (en) 2013-09-03 2017-11-14 Baker Hughes, A Ge Company, Llc Plug reception assembly and method of reducing restriction in a borehole
US11167343B2 (en) 2014-02-21 2021-11-09 Terves, Llc Galvanically-active in situ formed particles for controlled rate dissolving tools
US10150713B2 (en) 2014-02-21 2018-12-11 Terves, Inc. Fluid activated disintegrating metal system
US9932521B2 (en) 2014-03-05 2018-04-03 Self-Suspending Proppant, Llc Calcium ion tolerant self-suspending proppants
US11078402B2 (en) * 2014-03-26 2021-08-03 Schlumberger Technology Corporation Use of particulate or fibrous materials in gravel pack applications
CN104265248B (en) * 2014-09-10 2017-04-12 甘肃蓝科石化高新装备股份有限公司 Horizontal well sand filling test shaft device
US9910026B2 (en) 2015-01-21 2018-03-06 Baker Hughes, A Ge Company, Llc High temperature tracers for downhole detection of produced water
US10378303B2 (en) 2015-03-05 2019-08-13 Baker Hughes, A Ge Company, Llc Downhole tool and method of forming the same
US11162009B2 (en) 2015-04-08 2021-11-02 Gumpro Drilling Fluid Pvt. Ltd. Lubricant additives for water based drilling fluid
US10407607B2 (en) * 2015-04-08 2019-09-10 Gumpro Drilling Fluid PVT. LTD Solid invert emulsion drilling fluid additives, methods of preparation and use in oil-based drilling fluids
US10221637B2 (en) 2015-08-11 2019-03-05 Baker Hughes, A Ge Company, Llc Methods of manufacturing dissolvable tools via liquid-solid state molding
US10016810B2 (en) 2015-12-14 2018-07-10 Baker Hughes, A Ge Company, Llc Methods of manufacturing degradable tools using a galvanic carrier and tools manufactured thereof
CA3012511A1 (en) 2017-07-27 2019-01-27 Terves Inc. Degradable metal matrix composite
WO2020106655A1 (en) 2018-11-21 2020-05-28 Self-Suspending Proppant Llc Salt-tolerant self-suspending proppants made without extrusion
CN110055048A (en) * 2019-04-17 2019-07-26 中国石油天然气股份有限公司 A kind of pair of fracturing fluid has the overlay film proppant and preparation method for being sustained broken glue effect
CN111670632B (en) * 2020-07-06 2021-12-03 临沂大学 Device and method for improving germination rate of alfalfa under continuous cropping
US11492531B1 (en) * 2021-10-12 2022-11-08 Halliburton Energy Services, Inc. Sand consolidation with a curable resin and filtercake removal fluid

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2948638A (en) * 1956-10-12 1960-08-09 Goodrich Co B F Coated vinyl chloride plastisol resin particles coated with a carboxylic acid salt and method of preparation
US3026938A (en) * 1958-09-02 1962-03-27 Gulf Research Development Co Propping agent for a fracturing process
US3237693A (en) * 1963-10-28 1966-03-01 Gulf Research Development Co Fracturing method and propping agent
US3875937A (en) 1963-10-31 1975-04-08 American Cyanamid Co Surgical dressings of absorbable polymers
US3468853A (en) 1966-06-15 1969-09-23 American Cyanamid Co Process of polymerizing a glycolide
US4272398A (en) 1978-08-17 1981-06-09 The United States Of America As Represented By The Secretary Of Agriculture Microencapsulation process
US4986354A (en) 1988-09-14 1991-01-22 Conoco Inc. Composition and placement process for oil field chemicals
US5075115A (en) 1990-04-02 1991-12-24 Fmc Corporation Process for polymerizing poly(lactic acid)
US5425994A (en) 1992-08-04 1995-06-20 Technisand, Inc. Resin coated particulates comprissing a formaldehyde source-metal compound (FS-MC) complex
DE19650602A1 (en) * 1996-12-06 1998-06-10 Philips Patentverwaltung Phosphor preparation with a hydroxycarboxylic acid coating
GB9726392D0 (en) * 1997-12-12 1998-02-11 Perstop Limited Improvements in or relating to a method of treatment of moulding sand
US6150497A (en) 1998-01-14 2000-11-21 Sherwood Services Ag Method for the production of polyglycolic acid
US6869445B1 (en) * 2000-05-04 2005-03-22 Phillips Plastics Corp. Packable ceramic beads for bone repair
US6394185B1 (en) * 2000-07-27 2002-05-28 Vernon George Constien Product and process for coating wellbore screens
US20020114958A1 (en) * 2000-11-27 2002-08-22 Toray Industries, Inc. Method of coating zeolite crystals, substrate containing zeolite crystals, method of manufacturing zeolite membrane, method of processing zeolite membrane, zeolite membrane, aluminum electrolytic capacitor, degassing membrane and separation method
US7066260B2 (en) * 2002-08-26 2006-06-27 Schlumberger Technology Corporation Dissolving filter cake
US7044220B2 (en) * 2003-06-27 2006-05-16 Halliburton Energy Services, Inc. Compositions and methods for improving proppant pack permeability and fracture conductivity in a subterranean well

Also Published As

Publication number Publication date
EA200500512A1 (en) 2005-10-27
US20040055747A1 (en) 2004-03-25
EA008279B1 (en) 2007-04-27
WO2004027213A1 (en) 2004-04-01
DE60316165D1 (en) 2007-10-18
CA2502694C (en) 2011-11-01
US6817414B2 (en) 2004-11-16
NO339018B1 (en) 2016-11-07
EP1546507A1 (en) 2005-06-29
MXPA05003132A (en) 2005-08-03
ATE372444T1 (en) 2007-09-15
US20040216876A1 (en) 2004-11-04
DE60316165T2 (en) 2008-05-29
EP1546507B1 (en) 2007-09-05
NO20051874L (en) 2005-05-31
AU2003267138A1 (en) 2004-04-08
US7132389B2 (en) 2006-11-07

Similar Documents

Publication Publication Date Title
CA2502694A1 (en) Acid-coated sand for gravel pack and filter cake clean-up
Sharma et al. Injectivity decline in water injection wells: An offshore Gulf of Mexico case study
US7494711B2 (en) Coated plastic beads and methods of using same to treat a wellbore or subterranean formation
US7067445B2 (en) Extended particle size distribution ceramic fracturing proppant
EP1556581B1 (en) Methods of completing wells in unconsolidated formations
CA2137410C (en) Fluid loss control additives
NO20161730A1 (en) Sand aggregate reagents, modified sand, and methods of preparation and use thereof
CA2580304C (en) Curable resin coated low apparent specific gravity beads and method of using the same
US20080234146A1 (en) Proppant and Production Method Thereof
CA2678059C (en) Proppant and method for higher production of a well
CN101657516A (en) High strength ceramic elements and manufacture method thereof and using method
GB2071181A (en) Acids dissolvable cements
CA2520361A1 (en) Well treating composition containing relatively lightweight proppant and acid
CN102575515B (en) Composition and method for producing an ultra-lightweight ceramic proppant
WO2014189820A1 (en) Methods for stimulation and stabilization of subterranean formations
CN108977181A (en) Oil base drilling fluid sealing agent and preparation method
US3593798A (en) Method of reducing the permeability of a thief zone
CA2992942A1 (en) Proppant particles formed from slurry droplets and methods of use
CN115141622B (en) Preparation method of petroleum fracturing propping agent and petroleum fracturing propping agent
CA2963249A1 (en) Proppant particles formed from slurry droplets and methods of use
CN115678533A (en) Low-density high-strength ceramsite proppant using coal gangue as raw material and preparation method thereof

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20180912