CA2523588A1 - Multi-scale cermets for high temperature erosion-corrosion service - Google Patents
Multi-scale cermets for high temperature erosion-corrosion service Download PDFInfo
- Publication number
- CA2523588A1 CA2523588A1 CA 2523588 CA2523588A CA2523588A1 CA 2523588 A1 CA2523588 A1 CA 2523588A1 CA 2523588 CA2523588 CA 2523588 CA 2523588 A CA2523588 A CA 2523588A CA 2523588 A1 CA2523588 A1 CA 2523588A1
- Authority
- CA
- Canada
- Prior art keywords
- cermet
- cermet composition
- group
- phase
- vol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/14—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on borides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Abstract
A cermet composition represented by the formula (PQ)(RS)Xcomprising: a ceramic phase (PQ), a binder phase (RS) and X wherein X is at least one member selected from the group consisting of an oxide dispersoid E, an intermetallic compound F and a derivative compound G wherein said ceramic phase (PQ) is dispersed in the binder phase (RS) as particles of diameter in the range of about 0.5 to 3000 microns, and said X is dispersed in the binder phase (RS) as particles in the size range of about 1 nm to 400 nm.
Claims (15)
1. A cermet composition represented by the formula (PQ)(RS)X
comprising: a ceramic phase (PQ), a binder phase (RS) and X wherein X is at least one member selected from the group consisting of an oxide dispersoid E, an intermetallic compound F and a derivative compound G wherein said ceramic phase (PQ) is dispersed in the binder phase (RS) as particles of diameter in the range of about 0.5 to 3000 microns, and said X is dispersed in the binder phase (RS) as particles in the size range of about 1 nm to 400 nm.
comprising: a ceramic phase (PQ), a binder phase (RS) and X wherein X is at least one member selected from the group consisting of an oxide dispersoid E, an intermetallic compound F and a derivative compound G wherein said ceramic phase (PQ) is dispersed in the binder phase (RS) as particles of diameter in the range of about 0.5 to 3000 microns, and said X is dispersed in the binder phase (RS) as particles in the size range of about 1 nm to 400 nm.
2. The cermet composition of claim 1 wherein the ceramic phase (PQ) comprises a metal P selected from the group consisting of Al, Si, Mg, Group IV, Group V, Group VI elements and mixtures thereof and Q, which is selected from the group consisting of carbide, nitride, boride, carbonitride, oxide and mixtures thereof, wherein ceramic phase (PQ) ranges from of about 30 to 95 vol% based on the volume of cermet composition.
3. The cermet composition of claim 2 wherein the ceramic phase (PQ) the molar ratio of P to Q can vary in the range of 0.5:1 to 30:1.
4. The cermet composition of claim 2 wherein the ceramic phase (PQ) ranges from of about 55 to 95 vol% based on the volume of the cermet.
5. The cermet composition of claim 1 wherein the binder phase (RS) comprises a base metal R selected from the group consisting of Fe, Ni, Co, Mn and mixtures thereof and an alloying metal S selected from Si, Cr, Ti, Al, Nb, Mo and mixtures thereof and wherein the binder phase (RS) is in the range of 4.5 to 70 vol% based on the volume of the cermet and the base metal R to alloying metal S mass ratio ranges from 50/50 to 90/10.
6. The cermet composition of claim 1 wherein the oxide dispersoids E is selected from the group consisting of oxides Al, Ti, Nb, Zr, Hf, V, Ta, Cr, Mo, W, Fe, Mn, Ni, Si, Y and mixtures thereof and ranges from of about 0.1 to 10 vol% based on the volume of the cermet.
7. The cermet composition of claim 1 wherein the intermetallic compound F is selected from the group consisting of gamma prime (.gamma.') and beta (.beta.) such as Ni3Al, Ni3Ti, Ni3Nb, NiAl, Ni2AlTi, NiTi, Ni2AlSi, FeAl, Fe3Al, CoAl, Co3Al, Ti3Al, Al3Ti, TiAl, Ti2AlNb, TiAl2Mn, TaAl3, NbAl3 and mixtures thereof and ranges from of about 0.1 to 10 vol% based on the volume of the cermet.
8. The cermet composition of claim 1 wherein the derivative compound G is derived from ceramic phase (PQ) or ceramic phase (PQ) and binder phase (RS) and ranges from about 0.01 to 10 vol% based on the volume of the cermet.
9. The cermet composition of claim 1 having a fracture toughness greater than about 3 MPa.cndot.m1/2.
10. The cermet composition of claim 1 having an erosion rate less than about 1×10 -6cc/gram of SiC erodant.
11. The cermet composition of claim 1 having corrosion rate less than about 1×10 -10 g2/cm4.cndot.s or an average oxide scale of less than 150 µm thickness when subject to 100 cc/min air at 800°C for at least 65 hours.
12. The cermet composition of claim 1 having an erosion rate less than about 1×10 -6cc/gram of SiC erodant and a corrosion rate less than about 1×10 -10 g2/cm4.cndot.s or an average oxide scale of less than 150 µm thickness when subject to 100 cc/min air at 800°C for at least 65 hours.
13. A method for protecting a metal surface subject to erosion at temperatures up to 850°C, the method comprising providing the metal surface with a cermet composition according to claims 1-12.
14. A method for protecting a metal surface subject to erosion at temperatures in the range of 300°C to 850°C, the method comprising providing the metal surface with a cermet composition according to claims 1-12.
15. The method of claim 13 wherein said surface comprises the inner surface of a fluid-solids separation cyclone.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US47199503P | 2003-05-20 | 2003-05-20 | |
| US60/471,995 | 2003-05-20 | ||
| US10/829,819 US7316724B2 (en) | 2003-05-20 | 2004-04-22 | Multi-scale cermets for high temperature erosion-corrosion service |
| US10/829,819 | 2004-04-22 | ||
| PCT/US2004/015553 WO2004104246A1 (en) | 2003-05-20 | 2004-05-18 | Multi-scale cermets for high temperature erosion-corrosion service |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2523588A1 true CA2523588A1 (en) | 2004-12-02 |
Family
ID=33479310
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA 2523588 Abandoned CA2523588A1 (en) | 2003-05-20 | 2004-05-18 | Multi-scale cermets for high temperature erosion-corrosion service |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US7316724B2 (en) |
| EP (1) | EP1633901B1 (en) |
| JP (1) | JP2007517978A (en) |
| KR (1) | KR20060012007A (en) |
| AT (1) | ATE417133T1 (en) |
| AU (1) | AU2004242137B8 (en) |
| BR (1) | BRPI0410417A (en) |
| CA (1) | CA2523588A1 (en) |
| DE (1) | DE602004018311D1 (en) |
| DK (1) | DK1633901T3 (en) |
| ES (1) | ES2319532T3 (en) |
| MX (1) | MXPA05011601A (en) |
| RU (1) | RU2360024C2 (en) |
| SG (1) | SG141421A1 (en) |
| WO (1) | WO2004104246A1 (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7731776B2 (en) * | 2005-12-02 | 2010-06-08 | Exxonmobil Research And Engineering Company | Bimodal and multimodal dense boride cermets with superior erosion performance |
| US7842139B2 (en) * | 2006-06-30 | 2010-11-30 | Exxonmobil Research And Engineering Company | Erosion resistant cermet linings for oil and gas exploration, refining and petrochemical processing applications |
| GB2465737B (en) * | 2007-10-09 | 2013-03-20 | Cameron Int Corp | Erosion resistant material |
| CA2705769A1 (en) * | 2007-11-20 | 2009-05-28 | Exxonmobil Research And Engineering Company | Bimodal and multimodal dense boride cermets with low melting point binder |
| US20110312860A1 (en) * | 2010-06-17 | 2011-12-22 | General Electric Company | Wear-resistant and low-friction coatings and articles coated therewith |
| JP6202787B2 (en) * | 2012-05-31 | 2017-09-27 | 株式会社アライドマテリアル | Molybdenum heat-resistant alloy, friction stir welding tool, and manufacturing method |
| ES2751392T3 (en) * | 2014-07-14 | 2020-03-31 | MTU Aero Engines AG | Al-rich high-temperature Ti-Al alloy |
| CN106498207B (en) * | 2016-10-28 | 2017-10-27 | 成都理工大学 | In-situ preparation contains Ni3The preparation method of the cermet of Al Binder Phase |
| CN106498208B (en) * | 2016-10-28 | 2017-11-07 | 成都理工大学 | Ni in Binder Phase3The generated in-situ cermet material preparation methods of Al |
| CN106498257B (en) * | 2016-10-28 | 2017-10-27 | 成都理工大学 | In-situ preparation contains Ni3The preparation method of the hard alloy of Al Binder Phase |
| CN106521206B (en) * | 2016-10-28 | 2017-11-14 | 成都理工大学 | A kind of preparation method of the cermet material of high temperature resistance softening |
| CN106521207B (en) * | 2016-10-28 | 2017-11-14 | 成都理工大学 | A kind of preparation method of the hard alloy of high temperature resistance softening |
| CN106319271B (en) * | 2016-10-28 | 2018-01-30 | 成都理工大学 | Ni in Binder Phase3The generated in-situ hard alloy preparation methods of Al |
| CN106636832B (en) * | 2016-10-28 | 2018-05-22 | 成都理工大学 | A kind of preparation method of the cermet material of the Binder Phase containing intermetallic compound |
| CN106636835B (en) * | 2016-10-28 | 2018-05-22 | 成都理工大学 | A kind of preparation method of the hard alloy of the Binder Phase containing intermetallic compound |
| CN109336614B (en) * | 2018-10-31 | 2020-07-03 | 燕山大学 | Preparation method of Sialon/Ti-22Al-25Nb ceramic matrix composite material |
| CN111647771B (en) * | 2020-04-17 | 2021-10-15 | 中国航发北京航空材料研究院 | Multi-element composite anti-oxidation Ti2AlNb alloy and preparation method thereof |
| CN111394637B (en) * | 2020-04-17 | 2021-06-01 | 中国航发北京航空材料研究院 | Ti2AlNb alloy and preparation method of bar thereof |
| CN111621659A (en) * | 2020-06-29 | 2020-09-04 | 西安工程大学 | Method for preparing Ti2AlNb alloy by powder metallurgy method |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3493351A (en) * | 1968-06-14 | 1970-02-03 | Du Pont | Metal bonded carbide compositions |
| US3547673A (en) * | 1969-02-19 | 1970-12-15 | Wall Colmonoy Corp | Method of forming cermet-type protective coatings on heat resistant alloys |
| US3705791A (en) * | 1970-09-18 | 1972-12-12 | Wall Colmonoy Corp | Cermet alloy composition |
| US3864093A (en) * | 1972-11-17 | 1975-02-04 | Union Carbide Corp | High-temperature, wear-resistant coating |
| GB1559647A (en) * | 1976-09-07 | 1980-01-23 | Special Metals Corp | Method of making oxide dispersion strengthened metallic powder |
| US4124737A (en) * | 1976-12-30 | 1978-11-07 | Union Carbide Corporation | High temperature wear resistant coating composition |
| US4101713A (en) * | 1977-01-14 | 1978-07-18 | General Electric Company | Flame spray oxidation and corrosion resistant superalloys |
| JPS55125257A (en) * | 1979-03-20 | 1980-09-26 | Nachi Fujikoshi Corp | Sintered body for cutting tool and manufacture thereof |
| SE457537B (en) | 1981-09-04 | 1989-01-09 | Sumitomo Electric Industries | DIAMOND PRESSURE BODY FOR A TOOL AND WAY TO MANUFACTURE IT |
| US4475983A (en) | 1982-09-03 | 1984-10-09 | At&T Bell Laboratories | Base metal composite electrical contact material |
| US4479743A (en) * | 1983-06-15 | 1984-10-30 | Stahl Ronald F | Wear resistant insert for particulate material flow ducts |
| US4615913A (en) | 1984-03-13 | 1986-10-07 | Kaman Sciences Corporation | Multilayered chromium oxide bonded, hardened and densified coatings and method of making same |
| SE453474B (en) | 1984-06-27 | 1988-02-08 | Santrade Ltd | COMPOUND BODY COATED WITH LAYERS OF POLYCristalline DIAMANT |
| US5981081A (en) * | 1984-09-18 | 1999-11-09 | Union Carbide Coatings Service Corporation | Transition metal boride coatings |
| JPS61183439A (en) * | 1985-02-06 | 1986-08-16 | Hitachi Metals Ltd | Wear resistant sintered hard alloy having superior oxidation resistance |
| SE454059B (en) * | 1985-09-12 | 1988-03-28 | Santrade Ltd | SET TO MANUFACTURE POWDER PARTICLES FOR FINE CORN MATERIAL ALLOYS |
| US4808055A (en) | 1987-04-15 | 1989-02-28 | Metallurgical Industries, Inc. | Turbine blade with restored tip |
| US4806161A (en) | 1987-12-04 | 1989-02-21 | Teleflex Incorporated | Coating compositions |
| JPH02213445A (en) * | 1988-10-06 | 1990-08-24 | Hitachi Metals Ltd | Cermet alloy |
| DE68913704T2 (en) | 1988-12-27 | 1994-06-16 | Hitachi Metals Ltd | Cermet alloy. |
| JP2926836B2 (en) * | 1989-02-22 | 1999-07-28 | 住友電気工業株式会社 | Nitrogen-containing cermet alloy |
| JPH0747793B2 (en) * | 1991-04-26 | 1995-05-24 | 株式会社クボタ | Oxide dispersion strengthened heat resistant sintered alloy |
| FR2678286B1 (en) | 1991-06-28 | 1994-06-17 | Sandvik Hard Materials Sa | CERMETS BASED ON TRANSITIONAL METALS, THEIR MANUFACTURE AND THEIR APPLICATIONS. |
| SE9201928D0 (en) | 1992-06-22 | 1992-06-22 | Sandvik Ab | SINTERED EXTREMELY FINE-GRAINED TITANIUM BASED CARBONITRIDE ALLOY WITH IMPROVED TOUGHNESS AND / OR WEAR RESISTANCE |
| US5449536A (en) * | 1992-12-18 | 1995-09-12 | United Technologies Corporation | Method for the application of coatings of oxide dispersion strengthened metals by laser powder injection |
| DE19505628A1 (en) | 1995-02-18 | 1996-08-22 | Hans Prof Dr Ing Berns | Process for producing a wear-resistant, tough material |
| MX9602104A (en) * | 1995-06-12 | 1998-04-30 | Praxair Technology Inc | Method for producing a tib2-based coating and the coated article so produced. |
| SE9701859D0 (en) * | 1997-05-15 | 1997-05-15 | Sandvik Ab | Titanium based carbonitride alloy with nitrogen enriched surface zone |
| JP2000135425A (en) * | 1998-10-29 | 2000-05-16 | Toshiba Mach Co Ltd | Agitating blade of sand kneading device |
| DE10117657B4 (en) | 2001-04-09 | 2011-06-09 | Widia Gmbh | Complex boride cermet body and use of this body |
| DE10135790B4 (en) | 2001-07-23 | 2005-07-14 | Kennametal Inc. | Fine grained cemented carbide and its use |
-
2004
- 2004-04-22 US US10/829,819 patent/US7316724B2/en not_active Expired - Fee Related
- 2004-05-18 WO PCT/US2004/015553 patent/WO2004104246A1/en active Application Filing
- 2004-05-18 AT AT04752549T patent/ATE417133T1/en not_active IP Right Cessation
- 2004-05-18 DK DK04752549T patent/DK1633901T3/en active
- 2004-05-18 MX MXPA05011601A patent/MXPA05011601A/en active IP Right Grant
- 2004-05-18 AU AU2004242137A patent/AU2004242137B8/en not_active Ceased
- 2004-05-18 RU RU2005136133A patent/RU2360024C2/en not_active IP Right Cessation
- 2004-05-18 BR BRPI0410417 patent/BRPI0410417A/en not_active IP Right Cessation
- 2004-05-18 DE DE200460018311 patent/DE602004018311D1/en not_active Expired - Fee Related
- 2004-05-18 ES ES04752549T patent/ES2319532T3/en active Active
- 2004-05-18 CA CA 2523588 patent/CA2523588A1/en not_active Abandoned
- 2004-05-18 KR KR1020057021946A patent/KR20060012007A/en not_active Application Discontinuation
- 2004-05-18 JP JP2006533185A patent/JP2007517978A/en active Pending
- 2004-05-18 EP EP04752549A patent/EP1633901B1/en not_active Not-in-force
- 2004-05-18 SG SG200800228-9A patent/SG141421A1/en unknown
-
2007
- 2007-07-17 US US11/879,354 patent/US20120177933A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA05011601A (en) | 2006-01-23 |
| US20070131054A1 (en) | 2007-06-14 |
| BRPI0410417A (en) | 2006-05-30 |
| RU2360024C2 (en) | 2009-06-27 |
| AU2004242137A1 (en) | 2004-12-02 |
| EP1633901B1 (en) | 2008-12-10 |
| RU2005136133A (en) | 2006-06-27 |
| DK1633901T3 (en) | 2009-04-06 |
| DE602004018311D1 (en) | 2009-01-22 |
| KR20060012007A (en) | 2006-02-06 |
| US7316724B2 (en) | 2008-01-08 |
| SG141421A1 (en) | 2008-04-28 |
| WO2004104246A1 (en) | 2004-12-02 |
| ES2319532T3 (en) | 2009-05-08 |
| AU2004242137B2 (en) | 2009-07-16 |
| ATE417133T1 (en) | 2008-12-15 |
| JP2007517978A (en) | 2007-07-05 |
| US20120177933A1 (en) | 2012-07-12 |
| EP1633901A1 (en) | 2006-03-15 |
| AU2004242137B8 (en) | 2009-08-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |
Effective date: 20140206 |