CA2562977A1 - Strong, lightweight article containing a fine-grained metallic layer - Google Patents

Strong, lightweight article containing a fine-grained metallic layer Download PDF

Info

Publication number
CA2562977A1
CA2562977A1 CA002562977A CA2562977A CA2562977A1 CA 2562977 A1 CA2562977 A1 CA 2562977A1 CA 002562977 A CA002562977 A CA 002562977A CA 2562977 A CA2562977 A CA 2562977A CA 2562977 A1 CA2562977 A1 CA 2562977A1
Authority
CA
Canada
Prior art keywords
article
coating
metal
article according
golf club
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002562977A
Other languages
French (fr)
Other versions
CA2562977C (en
Inventor
Gino Palumbo
Iain Brooks
Konstantinos Panagiotopoulos
Klaus Tomantschger
Jonathan Mccrea
David Limoges
Erb Uwe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Integran Technologies Inc
Original Assignee
Integran Technologies, Inc.
Gino Palumbo
Iain Brooks
Konstantinos Panagiotopoulos
Klaus Tomantschger
Jonathan Mccrea
David Limoges
Erb Uwe
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Integran Technologies, Inc., Gino Palumbo, Iain Brooks, Konstantinos Panagiotopoulos, Klaus Tomantschger, Jonathan Mccrea, David Limoges, Erb Uwe filed Critical Integran Technologies, Inc.
Publication of CA2562977A1 publication Critical patent/CA2562977A1/en
Application granted granted Critical
Publication of CA2562977C publication Critical patent/CA2562977C/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01K—ANIMAL HUSBANDRY; CARE OF BIRDS, FISHES, INSECTS; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K87/00—Fishing rods
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00—Golf clubs
    • A63B53/04—Heads
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00—Golf clubs
    • A63B53/04—Heads
    • A63B53/0466—Heads wood-type
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00—Golf clubs
    • A63B53/10—Non-metallic shafts
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00—Golf clubs
    • A63B53/12—Metallic shafts
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B59/00—Bats, rackets, or the like, not covered by groups A63B49/00 - A63B57/00
    • A63B59/50—Substantially rod-shaped bats for hitting a ball in the air, e.g. for baseball
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B59/00—Bats, rackets, or the like, not covered by groups A63B49/00 - A63B57/00
    • A63B59/70—Bats, rackets, or the like, not covered by groups A63B49/00 - A63B57/00 with bent or angled lower parts for hitting a ball on the ground, on an ice-covered surface, or in the air, e.g. for hockey or hurling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D1/00—Electroforming
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00—Electroplating characterised by the article coated
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45B—WALKING STICKS; UMBRELLAS; LADIES' OR LIKE FANS
    • A45B9/00—Details
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00—Characteristics of used materials
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00—Characteristics of used materials
    • A63B2209/02—Characteristics of used materials with reinforcing fibres, e.g. carbon, polyamide fibres
    • A63B2209/023—Long, oriented fibres, e.g. wound filaments, woven fabrics, mats
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B49/00—Stringed rackets, e.g. for tennis
    • A63B49/02—Frames
    • A63B49/10—Frames made of non-metallic materials, other than wood
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00—Golf clubs
    • A63B53/04—Heads
    • A63B53/0416—Heads having an impact surface provided by a face insert
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B59/00—Bats, rackets, or the like, not covered by groups A63B49/00 - A63B57/00
    • A—HUMAN NECESSITIES
    • A63—SPORTS; GAMES; AMUSEMENTS
    • A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B60/00—Details or accessories of golf clubs, bats, rackets or the like
    • A63B60/54—Details or accessories of golf clubs, bats, rackets or the like with means for damping vibrations
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12014—All metal or with adjacent metals having metal particles
    • Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12708—Sn-base component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12778—Alternative base metals from diverse categories
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/24405—Polymer or resin [e.g., natural or synthetic rubber, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372—Particulate matter
    • Y10T428/24413—Metal or metal compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
    • Y10T428/264—Up to 3 mils
    • Y10T428/265—1 mil or less
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal

Abstract

Articles for automotive, aerospace, manufacturing and defence industry applications including shafts or tubes used, for example, as golf club shafts, ski and hiking poles, fishing rods or bicycle frames, skate blades and snowboards are at least partially coated with an electrodeposited metal, metal alloy or metal matrix composite coating layer. The coating layer having a quasi-isotropic microstructure, a thickness of higher than 30~m and an average grain size between 0.004~m and 10~m. The coating layer provides articles of high resilience, high yield strength, scratch and wear resistance and hardness, and appealing appearance.

Claims (18)

CLAIMS:
1. An article having an electrodeposited metal, metal alloy or metal matrix composite coating layer, having a thickness between 30 µm and 5 mm and up to 5cm, said coating having a quasi-isotropic microstructure and exhibiting a modulus of resilience in the range of 0.25 MPa and 25 MPa.
2. An article according to claim 1, wherein said coating has an average grain size between 0.004 µm and 10 µm.
3. An article according to claim 2, wherein the ratio of coating layer thickness to average grain size is at least 25, preferably greater than 100, still more preferably greater than 1,000 and up to 1,250,000, preferably up to 12,500,000.
4. An article according to claim 2 or 3, wherein said coating is a pure metal selected from the group of Ag, Au, Cu, Co, Cr, Ni, Sn, Fe, Pt and Zn; an alloy of two or more of these metals, or an alloy of at least one of these metals and a component selected from the group consisting of Mo, W, C, P, S and Si.
5. An article according to claim 4, wherein said coating further comprises between 2.5% and 75 % by volume of particulate material.
6. An article according to claim 5, wherein said particulate material is selected from the group consisting of metal powders, metal alloy powders and metal oxide powders of Al, Co, Cu, In, Mg, Ni, Si, Sn, V and Zn; nitrides of Al, B
and Si; graphite, diamond, nanotubes, and/or Buckminster Fullerenes; carbides of B, Cr, Si, W; self lubricating materials such as MoS2 and substantially inert polymeric materials.
7. An article according to any one of claims 1 to 6, wherein said article is a component or part of an automotive, aerospace, manufacturing or defense industry application.
8. An article according to any one of claims 1 to 6, wherein said article is a component or part of a sporting equipment selected, from the group consisting of golf clubs, fishing rods, hockey sticks, baseball bats, tennis racquets, skate blades, snowboards and bicycle frames.
9. An article according to claim 8, wherein said article is a golf club shaft and said layer of coating extends over at least part of the inner or outer surface of said shaft.
9. A golf club shaft according to claim 8 made of a graphite-containing material, wherein said coating contains at least one metal selected from the group of Ni, Co and Fe having an average grain size between 0.004 µm and 10 µm.
10. An article according to any one of claims of 1 to 6 or 8, wherein said article is the faceplate of a golf club head.
11. An article according to any one of claims 1 to 8, wherein said quasi-isotropic metal, metal alloy or metal matrix composite coating, after electrodeposition, is hardened by a heat treatment.
12. An electroformed metallic article having a quasi-isotropic microstructure and an average grain size between 0.004 µm and 10 µm with a yield strength of between 200 MPa and 2,750 MPa.
13. An electroformed metallic article according to claim 12, being the shaft of a golf club composed of a nickel, cobalt or iron based alloy and having a yield strength greater than 1,000 MPa.
14. A golf club shaft according to claim 13, having a hardness of greater than 500 VHN and a ratio of wall thickness to grain size of greater than 9,000.
15. An article of a polymeric material, optionally containing graphite/carbon fibers having a metallic layer or coating, wherein (i) the weight of the coating is between 5 % and 95 % of the total weight of the article; and (ii) said article containing the metallic coating has a torsional stiffness per unit weight improved by at least about 5 % when compared to the torque of the same article not containing the metallic coating.
16. An article according to claim 15, wherein said article is a golf club shaft.
i7. An article according to claim 8, wherein said article is one of:
(i) an undersized cast or forged article;
(ii) a plastic preform; and (iii) a metal article insert and said layer of coating extends over at least part of the inner or outer surface of the article.
18. An article according to claim 17, wherein said article is a golf club head.
CA 2562977 2004-12-17 2005-09-20 Strong, lightweight article containing a fine-grained metallic layer Active CA2562977C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/013,456 US7387578B2 (en) 2004-12-17 2004-12-17 Strong, lightweight article containing a fine-grained metallic layer
US11/013,456 2004-12-17
PCT/CA2005/001429 WO2006063431A1 (en) 2004-12-17 2005-09-20 Strong, lightweight article containing a fine-grained metallic layer

Publications (2)

Publication Number Publication Date
CA2562977A1 true CA2562977A1 (en) 2006-06-22
CA2562977C CA2562977C (en) 2011-11-29

Family

ID=36587481

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2562977 Active CA2562977C (en) 2004-12-17 2005-09-20 Strong, lightweight article containing a fine-grained metallic layer

Country Status (6)

Country Link
US (6) US7387578B2 (en)
EP (2) EP1825029A4 (en)
CA (1) CA2562977C (en)
ES (1) ES2369370T3 (en)
MX (1) MXPA06011663A (en)
WO (2) WO2006063431A1 (en)

Families Citing this family (150)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7399238B2 (en) 2002-09-20 2008-07-15 Callaway Golf Company Iron golf club with nanocrystalline face insert
US9682425B2 (en) 2009-12-08 2017-06-20 Baker Hughes Incorporated Coated metallic powder and method of making the same
US7387578B2 (en) 2004-12-17 2008-06-17 Integran Technologies Inc. Strong, lightweight article containing a fine-grained metallic layer
US7320832B2 (en) * 2004-12-17 2008-01-22 Integran Technologies Inc. Fine-grained metallic coatings having the coefficient of thermal expansion matched to the one of the substrate
US7354354B2 (en) * 2004-12-17 2008-04-08 Integran Technologies Inc. Article comprising a fine-grained metallic material and a polymeric material
EP1919703B1 (en) 2005-08-12 2013-04-24 Modumetal, LLC Compositionally modulated composite materials and methods for making the same
US20090075755A1 (en) * 2005-08-25 2009-03-19 Adams Edwin H Golf Club Head
US7479071B2 (en) 2005-08-25 2009-01-20 Adams Golf Ip, L.P. Golf club head
US20090082132A1 (en) * 2005-08-25 2009-03-26 Adams Edwin H Golf Club Head
US20070142126A1 (en) * 2005-08-25 2007-06-21 Adams Golf Ip, L.P. Golf club head
US20090098948A1 (en) * 2005-08-25 2009-04-16 Adams Edwin H Golf Club Head
US20100190570A1 (en) * 2005-08-25 2010-07-29 Edwin H. Adams Golf club head and golf club shaft
US7556571B2 (en) * 2005-08-25 2009-07-07 Adams Golf Ip, L.P. Golf club head
US20070205537A1 (en) * 2006-03-03 2007-09-06 Phelps Dodge High Performance Conductors Mandrel for thermoplastic tubing manufacture and method relating thereto
US7521128B2 (en) 2006-05-18 2009-04-21 Xtalic Corporation Methods for the implementation of nanocrystalline and amorphous metals and alloys as coatings
US8313585B2 (en) * 2006-09-05 2012-11-20 Philos Jongho Ko Sports equipment comprising diffused titanium nitride
DE202006013873U1 (en) * 2006-09-11 2006-12-28 Heinrich Gillet Gmbh Components of exhaust gas installations, in particular, those made of titanium or its alloys comprise surfaces provided at least in parts with inorganic nano coating not penetrable by oxygen
US20080123475A1 (en) * 2006-11-28 2008-05-29 Seiko Epson Corporation Timepiece component and timepiece having the timepiece component
US20080132345A1 (en) * 2006-12-01 2008-06-05 Mark Dean Dimick Article of manufacture for improved segmented jump cue stick
US20080153621A1 (en) * 2006-12-22 2008-06-26 Callaway Golf Company Nanocrystalline plated putter hosel
US7976976B2 (en) 2007-02-07 2011-07-12 Rosecreek Technologies Inc. Composite current collector
US20090312118A1 (en) * 2007-02-23 2009-12-17 Uday Deshmukh High performance nano-structured metalwood golf club heads and iron heads and components thereof
US20080216383A1 (en) * 2007-03-07 2008-09-11 David Pierick High performance nano-metal hybrid fishing tackle
US7837579B2 (en) * 2007-03-20 2010-11-23 Powermetal Technologies, Inc. Baseball and softball bats with fused nano-structured metals and alloys
US7438647B1 (en) * 2007-04-03 2008-10-21 Callaway Golf Company Nanocrystalline plated golf club head
US8814723B2 (en) 2007-04-05 2014-08-26 Nike, Inc. Rotational molded golf club heads
US7615249B1 (en) * 2007-06-13 2009-11-10 Kudwa Douglas G Method for preparing arrow shafts with lubricant coatings
US20090029796A1 (en) * 2007-07-24 2009-01-29 Karsten Manufacturing Corporation Multiple Material Iron-Type Golf Club Head
US8113530B2 (en) * 2007-08-29 2012-02-14 Powermetal Technologies, Inc. Nano-metal bicycle frame and related components
US20090082133A1 (en) * 2007-09-20 2009-03-26 Nelson Precision Casting Co., Ltd. Plating layer structure of golf club head and forming method thereof
US20090090634A1 (en) * 2007-10-03 2009-04-09 Sifco Selective Plating Method of plating metal onto titanium
CN102099125B (en) 2007-10-04 2014-04-09 因泰格兰科技有限公司 Metal coated structural parts for portable electronic devices
US20090097954A1 (en) * 2007-10-15 2009-04-16 Stephen Dunlap Sheet Separator and Method
US9033819B2 (en) 2012-05-16 2015-05-19 Taylor Made Golf Company, Inc. Golf club head with face insert
US9005420B2 (en) * 2007-12-20 2015-04-14 Integran Technologies Inc. Variable property electrodepositing of metallic structures
US8062496B2 (en) * 2008-04-18 2011-11-22 Integran Technologies Inc. Electroplating method and apparatus
DE102008022311A1 (en) 2008-05-06 2009-11-12 Schaeffler Kg Cage for rolling elements of a bearing
WO2010005983A2 (en) 2008-07-07 2010-01-14 Modumetal Llc Property modulated materials and methods of making the same
US8083246B2 (en) 2008-09-19 2011-12-27 Philip White Plated bicycle fork steerer tube
US9119906B2 (en) 2008-09-24 2015-09-01 Integran Technologies, Inc. In-vivo biodegradable medical implant
US8128994B1 (en) 2008-09-30 2012-03-06 Taylor Made Golf Company, Inc. Method of applying decorative layers to a steel shaft
US8342989B2 (en) 2008-11-14 2013-01-01 Head Technology Gmbh Sporting goods with graphene material
US8366130B2 (en) 2008-11-21 2013-02-05 Fox Factory, Inc. Methods and apparatus for selective stiffness of vehicle suspension
US9051022B2 (en) 2008-11-21 2015-06-09 Fox Factory, Inc. Methods and apparatus for selective stiffness of vehicle suspension
EP2376353A1 (en) * 2009-01-12 2011-10-19 Laitram, LLC Metal-fused plastic conveyor belt components and methods of making
US20100201088A1 (en) * 2009-02-06 2010-08-12 Martin Newman Compressive coatings for ice skate blades and methods for applying the same
CA2750484A1 (en) 2009-02-17 2010-12-16 Applied Nanostructured Solutions, Llc Composites comprising carbon nanotubes on fiber
US8394507B2 (en) 2009-06-02 2013-03-12 Integran Technologies, Inc. Metal-clad polymer article
US8309233B2 (en) 2009-06-02 2012-11-13 Integran Technologies, Inc. Electrodeposited metallic-materials comprising cobalt on ferrous-alloy substrates
US8906515B2 (en) * 2009-06-02 2014-12-09 Integran Technologies, Inc. Metal-clad polymer article
US8247050B2 (en) * 2009-06-02 2012-08-21 Integran Technologies, Inc. Metal-coated polymer article of high durability and vacuum and/or pressure integrity
US8367217B2 (en) * 2009-06-02 2013-02-05 Integran Technologies, Inc. Electrodeposited metallic-materials comprising cobalt on iron-alloy substrates with enhanced fatigue performance
US8545994B2 (en) * 2009-06-02 2013-10-01 Integran Technologies Inc. Electrodeposited metallic materials comprising cobalt
EP2440691B1 (en) 2009-06-08 2019-10-23 Modumetal, Inc. Electrodeposited, nanolaminate coatings and claddings for corrosion protection
JP5643835B2 (en) * 2009-11-23 2014-12-17 アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーＡｐｐｌｉｅｄ Ｎａｎｏｓｔｒｕｃｔｕｒｅｄｓｏｌｕｔｉｏｎｓ， Ｌｌｃ CNT-adapted sea-based composite structure
US20110124253A1 (en) * 2009-11-23 2011-05-26 Applied Nanostructured Solutions, Llc Cnt-infused fibers in carbon-carbon composites
US10240419B2 (en) 2009-12-08 2019-03-26 Baker Hughes, A Ge Company, Llc Downhole flow inhibition tool and method of unplugging a seat
US8545963B2 (en) 2009-12-14 2013-10-01 Applied Nanostructured Solutions, Llc Flame-resistant composite materials and articles containing carbon nanotube-infused fiber materials
JP2011142973A (en) * 2010-01-13 2011-07-28 Bridgestone Sports Co Ltd Golf club shaft and golf club
CA2785803A1 (en) 2010-02-02 2011-11-24 Applied Nanostructured Solutions, Llc Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom
US20120121925A1 (en) * 2010-03-12 2012-05-17 Xtalic Corporation Coated articles, electrodeposition baths, and related systems
US20110220511A1 (en) * 2010-03-12 2011-09-15 Xtalic Corporation Electrodeposition baths and systems
US9694562B2 (en) 2010-03-12 2017-07-04 Xtalic Corporation Coated articles and methods
US8486319B2 (en) 2010-05-24 2013-07-16 Integran Technologies Inc. Articles with super-hydrophobic and/or self-cleaning surfaces and method of making same
US9303322B2 (en) * 2010-05-24 2016-04-05 Integran Technologies Inc. Metallic articles with hydrophobic surfaces
CA2803194C (en) 2010-06-23 2018-10-16 Rsem, Limited Partnership Magnetic drape reducing magnetic interferences e.g., in surgical applications
US8518826B2 (en) 2010-07-13 2013-08-27 Lam Research Corporation Metallization processes, mixtures, and electronic devices
EP2596150B1 (en) 2010-07-22 2020-06-17 Modumetal, Inc. Material and process for electrochemical deposition of nanolaminated brass alloys
US9017854B2 (en) 2010-08-30 2015-04-28 Applied Nanostructured Solutions, Llc Structural energy storage assemblies and methods for production thereof
US8871297B2 (en) 2010-09-30 2014-10-28 Barry Barnett Method of applying a nanocrystalline coating to a gas turbine engine component
CA2805778C (en) * 2010-09-30 2014-12-09 Technique Surface Lab Inc. Ice skate blades and method for improving performances thereof
US20120082553A1 (en) * 2010-09-30 2012-04-05 Andreas Eleftheriou Metal encapsulated stator vane
US20120082556A1 (en) * 2010-09-30 2012-04-05 Enzo Macchia Nanocrystalline metal coated composite airfoil
US9587645B2 (en) 2010-09-30 2017-03-07 Pratt & Whitney Canada Corp. Airfoil blade
US9429029B2 (en) * 2010-09-30 2016-08-30 Pratt & Whitney Canada Corp. Gas turbine blade and method of protecting same
US20120135819A1 (en) * 2010-11-29 2012-05-31 Integran Technologies Inc. Golf club head and face insert with electroformed fine-grained materials
US8631876B2 (en) 2011-04-28 2014-01-21 Baker Hughes Incorporated Method of making and using a functionally gradient composite tool
US9139928B2 (en) 2011-06-17 2015-09-22 Baker Hughes Incorporated Corrodible downhole article and method of removing the article from downhole environment
US9707739B2 (en) 2011-07-22 2017-07-18 Baker Hughes Incorporated Intermetallic metallic composite, method of manufacture thereof and articles comprising the same
US9833838B2 (en) 2011-07-29 2017-12-05 Baker Hughes, A Ge Company, Llc Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle
US9643250B2 (en) 2011-07-29 2017-05-09 Baker Hughes Incorporated Method of controlling the corrosion rate of alloy particles, alloy particle with controlled corrosion rate, and articles comprising the particle
WO2013028873A1 (en) 2011-08-23 2013-02-28 Nike International Ltd. Golf club and golf club head structures having nano coating
US9856547B2 (en) 2011-08-30 2018-01-02 Bakers Hughes, A Ge Company, Llc Nanostructured powder metal compact
US9109269B2 (en) * 2011-08-30 2015-08-18 Baker Hughes Incorporated Magnesium alloy powder metal compact
US9090956B2 (en) 2011-08-30 2015-07-28 Baker Hughes Incorporated Aluminum alloy powder metal compact
US9643144B2 (en) 2011-09-02 2017-05-09 Baker Hughes Incorporated Method to generate and disperse nanostructures in a composite material
US8936517B2 (en) 2011-10-31 2015-01-20 Fujikura Composite America, Inc. Light-weight coatings having enhanced durability
US9249521B2 (en) 2011-11-04 2016-02-02 Integran Technologies Inc. Flow-through consumable anodes
US9010416B2 (en) 2012-01-25 2015-04-21 Baker Hughes Incorporated Tubular anchoring system and a seat for use in the same
US9427835B2 (en) 2012-02-29 2016-08-30 Pratt & Whitney Canada Corp. Nano-metal coated vane component for gas turbine engines and method of manufacturing same
US9605508B2 (en) 2012-05-08 2017-03-28 Baker Hughes Incorporated Disintegrable and conformable metallic seal, and method of making the same
US11351424B2 (en) * 2012-10-23 2022-06-07 Karsten Manufacturing Corporation Adjustable sole weight of a golf club head
US9004240B2 (en) 2013-02-27 2015-04-14 Integran Technologies Inc. Friction liner
WO2014145771A1 (en) 2013-03-15 2014-09-18 Modumetal, Inc. Electrodeposited compositions and nanolaminated alloys for articles prepared by additive manufacturing processes
BR112015022235A2 (en) 2013-03-15 2017-07-18 Modumetal Inc nanolaminated coatings
CN105189828B (en) 2013-03-15 2018-05-15 莫杜美拓有限公司 Nickel chromium triangle nanometer laminate coat with high rigidity
US9126085B2 (en) 2013-03-15 2015-09-08 Nike, Inc. Golf club head structures having split, multi-part heads
EP2971266A4 (en) 2013-03-15 2017-03-01 Modumetal, Inc. A method and apparatus for continuously applying nanolaminate metal coatings
EP3019723A4 (en) 2013-07-09 2017-05-10 United Technologies Corporation Plated polymer compressor
WO2015006472A1 (en) * 2013-07-09 2015-01-15 United Technologies Corporation Plated polymeric sporting goods
CA2917643A1 (en) * 2013-07-09 2015-01-15 United Technologies Corporation Industrial products formed from plated polymers
US10402716B2 (en) 2013-07-09 2019-09-03 United Technologies Corporation Non-contact strain measurement
WO2015006433A2 (en) 2013-07-09 2015-01-15 United Technologies Corporation Plated polymer fan
US11267576B2 (en) 2013-07-09 2022-03-08 Raytheon Technologies Corporation Plated polymer nosecone
WO2015006421A1 (en) 2013-07-09 2015-01-15 United Technologies Corporation Metal-encapsulated polymeric article
JP2016535941A (en) 2013-09-30 2016-11-17 スペシャルティ ミネラルズ （ミシガン） インコーポレーテツド Enhanced heat spreader
ITTO20130915A1 (en) * 2013-11-12 2015-05-13 Alenia Aermacchi Spa PROCEDURE FOR THE MANUFACTURE OF AN AERONAUTICAL COMPONENT EQUIPPED WITH A PROTECTION FROM ABRASION AND HEAT, AND AERONAUTICAL COMPONENT REALIZED BY SUCH PROCEDURE.
US20150140340A1 (en) 2013-11-21 2015-05-21 Nano And Advanced Materials Institute Limited Thermal resistant mirror-like coating
US9205455B2 (en) 2014-01-09 2015-12-08 Nano And Advanced Materials Institute Limited Surface treatment of mirror finish
US10865465B2 (en) 2017-07-27 2020-12-15 Terves, Llc Degradable metal matrix composite
US10150713B2 (en) 2014-02-21 2018-12-11 Terves, Inc. Fluid activated disintegrating metal system
US11167343B2 (en) 2014-02-21 2021-11-09 Terves, Llc Galvanically-active in situ formed particles for controlled rate dissolving tools
US9925440B2 (en) 2014-05-13 2018-03-27 Bauer Hockey, Llc Sporting goods including microlattice structures
US10016662B1 (en) 2014-05-21 2018-07-10 Taylor Made Golf Company, Inc. Golf club
US9975011B1 (en) 2014-05-21 2018-05-22 Taylor Made Golf Company, Inc. Golf club
US10005889B2 (en) * 2014-06-03 2018-06-26 Conductive Composites Company Ip, Llc Fishing rod with enhanced tactile response
CA2961508A1 (en) 2014-09-18 2016-03-24 Modumetal, Inc. A method and apparatus for continuously applying nanolaminate metal coatings
EA201790644A1 (en) 2014-09-18 2017-08-31 Модьюметал, Инк. METHODS OF PRODUCTION OF PRODUCTS ELECTRICAL PLANTING AND PROCESSES OF LAYERED SYNTHESIS
US10378303B2 (en) 2015-03-05 2019-08-13 Baker Hughes, A Ge Company, Llc Downhole tool and method of forming the same
US10327429B2 (en) * 2015-06-02 2019-06-25 G-Rods International Llc Incorporation of graphene in various components and method of manufacturing
US10221637B2 (en) 2015-08-11 2019-03-05 Baker Hughes, A Ge Company, Llc Methods of manufacturing dissolvable tools via liquid-solid state molding
US10183202B1 (en) 2015-08-14 2019-01-22 Taylor Made Golf Company, Inc. Golf club head
US9914027B1 (en) 2015-08-14 2018-03-13 Taylor Made Golf Company, Inc. Golf club head
US20180126230A1 (en) * 2015-09-24 2018-05-10 Acushnet Company Golf club
US10016810B2 (en) 2015-12-14 2018-07-10 Baker Hughes, A Ge Company, Llc Methods of manufacturing degradable tools using a galvanic carrier and tools manufactured thereof
WO2017116943A1 (en) 2015-12-27 2017-07-06 Karsten Manufacturing Corporation Golf club heads with stronger, more flexible, and lighter materials
JP6817228B2 (en) * 2016-01-27 2021-01-20 グローブライド株式会社 A fishing thread guide having a high hardness surface layer and a fishing rod provided with the fishing thread guide.
WO2017165634A1 (en) * 2016-03-23 2017-09-28 Maxterial, Inc. Articles including adhesion enhancing coatings and methods of producing them
US10752999B2 (en) 2016-04-18 2020-08-25 Rolls-Royce Corporation High strength aerospace components
AR109584A1 (en) 2016-09-08 2018-12-26 Modumetal Inc PROCESSES TO PROVIDE LAMINATED COATINGS ON WORK PARTS, AND THE ARTICLES OBTAINED WITH THE SAME
US20180105945A1 (en) * 2016-10-13 2018-04-19 Alligant Scientific, LLC Metal deposits, compositions, and methods for making the same
US10207160B2 (en) 2016-12-30 2019-02-19 Taylor Made Golf Company, Inc. Golf club heads
US10712007B2 (en) 2017-01-27 2020-07-14 General Electric Company Pneumatically-actuated fuel nozzle air flow modulator
CN110637107B (en) 2017-03-24 2022-08-19 莫杜美拓有限公司 Lift plunger with electroplated layer and system and method for producing the same
EP3381250B1 (en) * 2017-03-31 2020-06-03 Scheppach Fabrikation von Holzbearbeitungsmaschinen GmbH Gardening device for cultivating soil, and sowing or planting method with the aid of such gardening device
CN110770372B (en) 2017-04-21 2022-10-11 莫杜美拓有限公司 Tubular article having an electrodeposited coating and system and method for producing same
US20180345099A1 (en) 2017-06-05 2018-12-06 Taylor Made Golf Company, Inc. Golf club heads
US20190290973A1 (en) * 2018-03-23 2019-09-26 Bridgestone Sports Co.,Ltd. Golf club head
CN112272717B (en) 2018-04-27 2024-01-05 莫杜美拓有限公司 Apparatus, system, and method for producing multiple articles with nanolaminate coatings using rotation
US11203815B2 (en) 2018-10-24 2021-12-21 General Electric Company Methods of forming high-temperature electroformed components and related components
US10702753B2 (en) * 2018-11-08 2020-07-07 Easton Diamond Sports, Llc Strengthening ball bats and other composite structures with nano-additives
US10610753B1 (en) * 2018-11-28 2020-04-07 Eaton Intelligent Power Limited Flexible golf club grip with stable cap
JP7233991B2 (en) * 2019-03-18 2023-03-07 Ｄｏｗａメタルテック株式会社 Composite plated material and its manufacturing method
CN110714219A (en) * 2019-11-04 2020-01-21 吉林大学 Method for electroplating nickel on magnesium alloy micro-arc oxidation surface
US11746877B2 (en) 2019-12-11 2023-09-05 Rolls-Royce Corporation High strength vibration damping components
US11280016B2 (en) 2020-03-19 2022-03-22 Integran Technologies Inc. Apparatus and method for in-situ electrosleeving and in-situ electropolishing internal walls of metallic conduits
US20220087237A1 (en) * 2020-09-18 2022-03-24 Advanced Angling Materials, Inc. Fishing hook and tackle
US20220203188A1 (en) * 2020-12-29 2022-06-30 East Coast Dyes, Inc. Clear lacrosse head
GB2622117A (en) * 2022-09-05 2024-03-06 Unison Ind Llc Electroforming method and system
CN115354378A (en) * 2022-10-20 2022-11-18 帝京半导体科技(苏州)有限公司 Anti-static wear-resistant hard anodic oxidation treatment process and application thereof

Family Cites Families (103)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL68330C (en) 1950-11-03
US3061525A (en) * 1959-06-22 1962-10-30 Platecraft Of America Inc Method for electroforming and coating
US3655433A (en) * 1970-07-06 1972-04-11 Standard Oil Co Platable polymers
USRE33767E (en) * 1971-12-15 1991-12-10 Surface Technology, Inc. Method for concomitant particulate diamond deposition in electroless plating, and the product thereof
ATA493572A (en) * 1972-06-08 1975-04-15 Fischer Gmbh BALL HIT AND METHOD OF ITS MANUFACTURING
US3812566A (en) * 1972-07-03 1974-05-28 Oxy Metal Finishing Corp Composite nickel iron electroplate and method of making said electroplate
US3806429A (en) 1972-07-03 1974-04-23 Oxy Metal Finishing Corp Electrodeposition of bright nickel-iron deposits,electrolytes therefor and coating an article with a composite nickel-iron,chromium coating
US3867264A (en) 1973-03-30 1975-02-18 Bell & Howell Co Electroforming process
US3974044A (en) 1975-03-31 1976-08-10 Oxy Metal Industries Corporation Bath and method for the electrodeposition of bright nickel-iron deposits
US4113248A (en) * 1976-05-07 1978-09-12 Aikoh Co., Ltd. Baseball bat made of light alloy
JPS52156173U (en) * 1976-05-19 1977-11-26
US4084819A (en) 1976-11-02 1978-04-18 Exxon Research & Engineering Co. Golf club shaft for irons
US4124208A (en) * 1977-05-09 1978-11-07 Numerical Control, Inc. Hockey stick construction
US4279707A (en) * 1978-12-18 1981-07-21 International Business Machines Corporation Electroplating of nickel-iron alloys for uniformity of nickel/iron ratio using a low density plating current
US4179343A (en) 1979-02-12 1979-12-18 Oxy Metal Industries Corporation Electroplating bath and process for producing bright, high-leveling nickel iron electrodeposits
US4319750A (en) 1979-04-30 1982-03-16 Aldila, Inc. Golf shaft having controlled flex zone
JPS5950269B2 (en) * 1980-05-23 1984-12-07 住友軽金属工業株式会社 Coating composition for corrosion protection on the inner surface of heat exchanger tubes
JPS57171691A (en) 1981-04-13 1982-10-22 Tadashi Hoashi Automatic brush plating method
US4533146A (en) 1983-05-12 1985-08-06 John Schaar Arrow and components thereof
US4461680A (en) * 1983-12-30 1984-07-24 The United States Of America As Represented By The Secretary Of Commerce Process and bath for electroplating nickel-chromium alloys
US4556607A (en) * 1984-03-28 1985-12-03 Sastri Suri A Surface coatings and subcoats
DE3815833A1 (en) * 1988-05-09 1989-11-23 Seilstorfer Gmbh & Co Metallur CORROSION RESISTANT COLD WORK STEEL AND STEEL MATRIX HARD PLASTIC COMPOSITE HAVING THIS COLD WORK STEEL
JPH0298376A (en) 1988-10-04 1990-04-10 Ryobi Ltd Shaft for golf club and manufacture thereof
US5131986A (en) 1989-12-01 1992-07-21 Yamaha Corporation Golf club head and its manufacturing
US4951953A (en) * 1990-02-15 1990-08-28 Kim Dong S T Golf club
JPH04224730A (en) 1990-12-27 1992-08-14 Kowa Co Ophthalmological apparatus
JP2515185B2 (en) * 1991-05-09 1996-07-10 住友ゴム工業株式会社 Golf club head and manufacturing method thereof
US5665441A (en) 1991-10-29 1997-09-09 Daiwa Seiko, Inc. Hollow cylindricall member
US20050103408A1 (en) * 1992-02-11 2005-05-19 Kuehmann Charles J. Nanocarbide precipitation strengthened ultrahigh-strength, corrosion resistant, structural steels
JP2954775B2 (en) * 1992-02-14 1999-09-27 ワイケイケイ株式会社 High-strength rapidly solidified alloy consisting of fine crystal structure
US5433797A (en) * 1992-11-30 1995-07-18 Queen's University Nanocrystalline metals
US5352266A (en) * 1992-11-30 1994-10-04 Queen'university At Kingston Nanocrystalline metals and process of producing the same
US5320386A (en) * 1993-03-22 1994-06-14 Halvati Sport Limited Composite titanium ski pole and method of making same
JPH06292745A (en) 1993-04-12 1994-10-21 Kobe Steel Ltd Golf club shaft
JP2546611B2 (en) 1993-08-27 1996-10-23 晴文 山中 Plated golf clubs
JP3020222B2 (en) 1993-08-31 2000-03-15 ソマール株式会社 Golf club shaft and method of manufacturing the same
US5516415A (en) * 1993-11-16 1996-05-14 Ontario Hydro Process and apparatus for in situ electroforming a structural layer of metal bonded to an internal wall of a metal tube
JP3333025B2 (en) * 1993-12-08 2002-10-07 日本パーカライジング株式会社 Electro-composite plating method and apparatus for metal material
US5603667A (en) 1993-12-28 1997-02-18 Bridgestone Sports Co., Ltd. Golf club head
CA2169216A1 (en) * 1995-02-09 1996-08-10 Richard A. Reed Metalized hockey stick
FR2730416A1 (en) 1995-02-13 1996-08-14 Taylor Made Golf Co Golf club shaft
US5538769A (en) * 1995-04-05 1996-07-23 Berkley, Inc. Graphite composite shaft with reinforced tip
US6030851A (en) 1995-06-07 2000-02-29 Grandmont; Paul E. Method for overpressure protected pressure sensor
US6106417A (en) * 1995-08-22 2000-08-22 Head Sport Aktiengesellschaft Lightweight tennis racket having high frequency
JP3205495B2 (en) * 1995-11-17 2001-09-04 ワイケイケイ株式会社 Golf club head
GB2325414B (en) * 1995-12-04 1999-05-26 Amorphous Technologies Interna Golf club made of a bulk-solidifying amorphous metal
JPH09266967A (en) * 1996-04-02 1997-10-14 T-Mu Vision Kurafutsu:Kk Low torque golf club shaft made of metal plated graphite
JPH09285568A (en) 1996-04-23 1997-11-04 Bridgestone Sports Co Ltd Tennis racket
JPH09285569A (en) 1996-04-23 1997-11-04 Bridgestone Sports Co Ltd Tennis racket
US5755826A (en) 1996-05-21 1998-05-26 Taylor Made Golf Company, Inc. Golf club shaft and process for manufacturing same
US5713800A (en) * 1996-12-05 1998-02-03 Su; Charles Golf club head
US5851158A (en) * 1997-04-03 1998-12-22 Winrow; Thomas L. Coating for sports implements
US6582320B2 (en) 1997-06-06 2003-06-24 Edwin B. Fendel Hybrid golf club shaft
US5945157A (en) * 1997-08-12 1999-08-31 Lee; Tsung Chi Method of coating golf club head under vacuum condition with open hanger type shot blasting machine
US6193614B1 (en) 1997-09-09 2001-02-27 Daiwa Seiko, Inc. Golf club head
US6139444A (en) * 1997-11-26 2000-10-31 Taylor Made Golf Company, Inc. Golf shaft and method of manufacturing the same
JP3269075B2 (en) * 1998-03-23 2002-03-25 株式会社遠藤製作所 Golf club and manufacturing method thereof
US6042493A (en) * 1998-05-14 2000-03-28 Jas. D. Easton, Inc. Tubular metal bat internally reinforced with fiber and metallic composite
US6354960B1 (en) 1998-06-24 2002-03-12 Rapport Composites U.S.A., Inc. Golf club shaft with controllable feel and balance using combination of fiber reinforced plastics and metal-coated fiber-reinforced plastics
JP3659812B2 (en) 1998-08-20 2005-06-15 ブリヂストンスポーツ株式会社 Racket frame
JP2002523154A (en) * 1998-08-21 2002-07-30 ダンロップ マックスフライ スポーツ コーポレーション Golf club iron with multilayer structure
JP2000144292A (en) * 1998-10-30 2000-05-26 Sumitomo Electric Ind Ltd Production of aluminum alloy and aluminum alloy member
US6080504A (en) 1998-11-02 2000-06-27 Faraday Technology, Inc. Electrodeposition of catalytic metals using pulsed electric fields
US20020061374A1 (en) * 1999-01-29 2002-05-23 O'brien Frank Composite tubular member having impact resistant member
DE19929116A1 (en) * 1999-06-24 2000-12-28 Linde Gas Ag Golf clubs with a tension-specific club face and process for producing the coating
US6334824B1 (en) * 1999-08-16 2002-01-01 Jas. D. Easton, Inc. Governed performance metal shell bat
US6355340B1 (en) * 1999-08-20 2002-03-12 M Cubed Technologies, Inc. Low expansion metal matrix composites
US6509107B2 (en) * 2000-05-05 2003-01-21 Solvay Engineered Polymers Platable engineered polyolefin alloys
JP3708792B2 (en) * 2000-05-12 2005-10-19 明久 井上 Golf club head
US6461260B1 (en) 2000-05-15 2002-10-08 Worth, Inc. Composite wrap bat
US6468672B1 (en) 2000-06-29 2002-10-22 Lacks Enterprises, Inc. Decorative chrome electroplate on plastics
WO2002044437A2 (en) * 2000-11-02 2002-06-06 Composite Tool Company, Inc. High strength alloys and methods for making same
US20020082111A1 (en) 2000-12-21 2002-06-27 Hedrick Michael W. Metal and composite golf club shaft
US6860821B2 (en) 2000-12-25 2005-03-01 Maimiya-Op Co., Ltd. Golf shaft, forming method therefor and golf club
US20020098906A1 (en) * 2001-01-19 2002-07-25 Hsu Patrick C.T. Golf axial club with a vacuum electroplated layer on the surface
JP2002210048A (en) * 2001-01-24 2002-07-30 Sumitomo Rubber Ind Ltd Manufacturing method of golf club head
US6908401B2 (en) 2001-02-28 2005-06-21 Michael H. L. Cheng Shaft for use in golf clubs and other shaft-based instruments and method of making the same
US6692377B2 (en) 2001-12-21 2004-02-17 Callaway Golf Company Graphite shaft with foil modified torsion
DE60329094D1 (en) * 2002-02-01 2009-10-15 Liquidmetal Technologies THERMOPLASTIC CASTING OF AMORPHOUS ALLOYS
US20030157995A1 (en) * 2002-02-19 2003-08-21 Spalding Sports Worldwide, Inc. Explosion bonded laminated face inserts for golf clubs
AU2003217868A1 (en) 2002-03-04 2003-09-22 Vyatek Sports, Inc. Design and manufacturing method for multi-material tube structures
JP2005530926A (en) 2002-06-25 2005-10-13 インテグラン・テクノロジーズ・インコーポレーテッド Process for electroplating metal and metal matrix composite foils, coatings, and micro components
US20030234181A1 (en) * 2002-06-25 2003-12-25 Gino Palumbo Process for in-situ electroforming a structural layer of metallic material to an outside wall of a metal tube
WO2004001102A1 (en) 2002-06-25 2003-12-31 Integran Technologies Inc. Process for in-situ electroforming a structural layer of metallic material to an outside wall of a metal tube
US7335908B2 (en) * 2002-07-08 2008-02-26 Qunano Ab Nanostructures and methods for manufacturing the same
US7766772B2 (en) * 2002-08-16 2010-08-03 Warrior Sports, Inc. Lacrosse handle
US20040043825A1 (en) 2002-08-27 2004-03-04 Graeme Horwood Golf club shaft set
US6729970B2 (en) 2002-08-27 2004-05-04 True Temper Sports, Inc. Hybrid golf club shaft set
JP4257581B2 (en) * 2002-09-20 2009-04-22 株式会社豊田中央研究所 Titanium alloy and manufacturing method thereof
AU2003266649A1 (en) * 2002-09-27 2004-04-19 Nano Technology Institute, Inc Nano-crystal austenitic steel bulk material having ultra-hardness and toughness and excellent corrosion resistance, and method for production thereof
US20040092330A1 (en) * 2002-11-12 2004-05-13 Meyer Jeffrey W. Hybrid golf club shaft
US6805642B2 (en) 2002-11-12 2004-10-19 Acushnet Company Hybrid golf club shaft
US20040147346A1 (en) * 2003-01-24 2004-07-29 Casasanta Joseph G. Grip for a hockey stick with a hollow-ended shaft
KR100505004B1 (en) 2003-02-20 2005-08-01 주식회사 나노인바 ELECTROLYTE FOR NANOCRYSTALLINE Fe-Ni ALLOYS WITH LOW THERMAL EXPANSION
JP2004269982A (en) * 2003-03-10 2004-09-30 Daido Steel Co Ltd High-strength low-alloyed titanium alloy and its production method
US7309412B2 (en) * 2003-04-11 2007-12-18 Lynntech, Inc. Compositions and coatings including quasicrystals
US20040209262A1 (en) 2003-04-21 2004-10-21 Bass Jay K. Biopolymeric arrays comprising test probes for two or more different species and methods for using the same
KR100505002B1 (en) * 2003-04-24 2005-08-01 주식회사 나노인바 Nani invar alloyes and the process of producing the same
KR100507555B1 (en) * 2003-06-17 2005-08-17 한국과학기술연구원 Cu-based bulk metallic glass matrix composite with high melting point metals and production method of the same
US7320832B2 (en) * 2004-12-17 2008-01-22 Integran Technologies Inc. Fine-grained metallic coatings having the coefficient of thermal expansion matched to the one of the substrate
US7387578B2 (en) * 2004-12-17 2008-06-17 Integran Technologies Inc. Strong, lightweight article containing a fine-grained metallic layer
US7354354B2 (en) * 2004-12-17 2008-04-08 Integran Technologies Inc. Article comprising a fine-grained metallic material and a polymeric material
US20120135819A1 (en) * 2010-11-29 2012-05-31 Integran Technologies Inc. Golf club head and face insert with electroformed fine-grained materials

Also Published As

Publication number Publication date
US7387578B2 (en) 2008-06-17
MXPA06011663A (en) 2007-01-23
US20060160636A1 (en) 2006-07-20
US20060135281A1 (en) 2006-06-22
US7771289B2 (en) 2010-08-10
EP1825029A1 (en) 2007-08-29
EP1825029A4 (en) 2007-11-21
CA2562977C (en) 2011-11-29
WO2006063431A1 (en) 2006-06-22
US7591745B2 (en) 2009-09-22
US20080119307A1 (en) 2008-05-22
US20110294594A1 (en) 2011-12-01
US20110003171A1 (en) 2011-01-06
WO2006066010A2 (en) 2006-06-22
EP2270261A3 (en) 2015-09-23
EP2270261A2 (en) 2011-01-05
US8025979B2 (en) 2011-09-27
WO2006066010A3 (en) 2006-10-19
US20090298624A1 (en) 2009-12-03
ES2369370T3 (en) 2011-11-29
US7803072B2 (en) 2010-09-28

Similar Documents

Publication Publication Date Title
CA2562977A1 (en) Strong, lightweight article containing a fine-grained metallic layer
US7553553B2 (en) Article comprising a fine-grained metallic material and a polymeric material
US20150072809A1 (en) Article with protective sheath
JP2010155075A (en) Titanium alloy for golf-club head, and clubhead comprising the same
US7837579B2 (en) Baseball and softball bats with fused nano-structured metals and alloys
CN1172168A (en) Ultra-hard alloy for wrist watch and decoration
US20040171434A1 (en) Golf club head of ductile or gray iron
US20130287976A1 (en) Anisotropic elongated metallic structural member
US20050006007A1 (en) Low density iron based alloy for a golf club head
TW460591B (en) Low-density and high-ductility of iron based materials for golf head
TWI235677B (en) Low density and high ductility ferric-based alloy material for golf iron club head
JPS6088570A (en) Golf club
JP2001198249A (en) Shaft of golf club and fabricating method therefor and golf club using the shaft
KR20030037535A (en) Alloy Composition for the Use of Golf Putter Heads and a Golf Putter Head thereby

Legal Events

Date Code Title Description
EEER Examination request