CA2600801A1 - Compositions containing expandable microspheres and an ionic compound, as well as methods of making and using the same - Google Patents

Compositions containing expandable microspheres and an ionic compound, as well as methods of making and using the same Download PDF

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Publication number
CA2600801A1
CA2600801A1 CA002600801A CA2600801A CA2600801A1 CA 2600801 A1 CA2600801 A1 CA 2600801A1 CA 002600801 A CA002600801 A CA 002600801A CA 2600801 A CA2600801 A CA 2600801A CA 2600801 A1 CA2600801 A1 CA 2600801A1
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CA
Canada
Prior art keywords
ionic compound
composition according
substrate
compound
particle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002600801A
Other languages
French (fr)
Other versions
CA2600801C (en
Inventor
Krishna K. Mohan
Cynthia A. Goliber
Yaoliang Hong
Peter M. Froass
Herbert Young
D. W. Anderson
Richard D. Faber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Paper Co
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CA2750039A priority Critical patent/CA2750039A1/en
Publication of CA2600801A1 publication Critical patent/CA2600801A1/en
Application granted granted Critical
Publication of CA2600801C publication Critical patent/CA2600801C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52Additives of definite length or shape
    • D21H21/54Additives of definite length or shape being spherical, e.g. microcapsules, beads
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/69Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22Agents rendering paper porous, absorbent or bulky
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/04Addition to the pulp; After-treatment of added substances in the pulp
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/46Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/56Polyamines; Polyimines; Polyester-imides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/04Addition to the pulp; After-treatment of added substances in the pulp
    • D21H23/06Controlling the addition
    • D21H23/08Controlling the addition by measuring pulp properties, e.g. zeta potential, pH
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1303Paper containing [e.g., paperboard, cardboard, fiberboard, etc.]

Abstract

This invention relates to composition containing expandable microspheres and at least one ionic compound and having a zeta potential that is greater than or equal to zero mV at a pH of about 9.0 or less at an ionic strength of from 10"6 M to 0.1M., as well as methods of making and using the composition.

Claims (38)

1. A composition, comprising at least one expandable microsphere and at least one ionic compound, wherein said composition has a zeta potential that is greater than or equal to zero mV at a pH of about 9.0 or less at an ionic strength of from 10 -6 M
to 0.1 M.
2. The composition according to Claim 1, wherein said zeta potential is greater than zero mV.
3. The composition according to Claim 1, wherein said zeta potential ranges from greater than zero to +150 mV.
4. The composition according to Claim 1, wherein said zeta potential ranges from greater than +20 to +130 mV.
5. The composition according to Claim 1, wherein said ionic compound is at least one compound selected from the group consisting of an organic and inorganic ionic compound.
6. The composition according to Claim 1, wherein said ionic compound is at least one polyorganic compound.
7. The composition according to Claim 1, wherein said ionic compound is at least one polyamine compound.
8. The composition according to Claim 1, wherein said ionic compound is crosslinked, branched, or combinations thereof.
9. The composition according to Claim 1, wherein said ionic compound is at least one polyethyleneimine compound.
10. The composition according to Claim 1, wherein said ionic compound is at least one polyethyleneimine compound having a molecular weight of at least 600 weight average molecular weight.
11. The composition according to Claim 1, wherein said ionic compound is at least one polyethyleneimine compound having a molecular weight of from 600 to 40,000 weight average molecular weight.
12. The composition according to Claim 1, wherein said ionic compound is cationic.
13. The composition according to Claim 1, wherein said ionic compound comprises at least one member selected from the group consisting of alumina and silica.
14. The composition according to Claim 1, wherein said ionic compound comprises a colloid comprising at least one member selected from the group consisting of silica, alumina, tin oxide, zirconia, antimony oxide, iron oxide, and rare earth metal oxides.
15. The composition according to Claim 1, wherein said ionic compound comprises a sol comprising at least one member selected from the group consisting of silica, alumina, tin oxide, zirconia, antimony oxide, iron oxide, and rare earth metal oxides.
16. The composition according to Claim 1, wherein the composition is a particle.
17. The composition according to Claim 16, wherein an outside surface of the at least one expandable microsphere is bound to the ionic compound.
18. The composition according to Claim 16, wherein an outside surface of the at least one expandable microsphere is non-covalently bound to the ionic compound.
19. The particle according to Claim 16, wherein the outside surface of at least one expandable microsphere is anionic.
20. The particle according to Claim 16, wherein the ionic compound is cationic.

20. A method of making the composition according to Claim 1, comprising contacting the at least one expandable microsphere with the at least one ionic compound to form a mixture.
21. The method according to Claim 20, further comprising centrifuging the mixture to form a first phase comprising at least one ionic compound and a second phase comprising the particle.
22. A method of making the composition according to Claim 1, comprising adsorbing at least one ionic compound to at least one expandable microsphere
23. The composition according to Claim 1, further comprising a plurality of cellulose fibers.
24. The composition according to Claim 23, wherein an outside surface of the at least one expandable microsphere is bound to the ionic compound.
25. The composition according to Claim 23, wherein an outside surface of the at least one expandable microsphere is non-covalently bound to the ionic compound.
26. A method of making the composition according to Claim 23, comprising contacting the at least one expandable microsphere with the at least one ionic compound to form a particle, and contacting said particle with said plurality of cellulose fibers.
27. A method of making the composition according to Claim 23, comprising contacting the at least one expandable microsphere with the at least one ionic compound to form a particle; and injecting the particle into a solution comprising a plurality of cellulose fibers.
28. A paper or paperboard substrate, comprising a plurality of cellulose fibers;
from 0.1 to 5 wt% of a plurality of expandable microspheres; wherein the substrate has a Sheffield Smoothness of less than 250 SU as measured by TAPPI
test method T 538 om-1; and a scanning 2nd cyan print mottle of not more than 6.
29. The substrate according to Claim 28, wherein an outside surface of the expandable microspheres are bound to an ionic compound.
30. The substrate according to Claim 28, comprising from 0.1 to 3 wt% of a plurality of expandable microspheres.
31. The substrate according to Claim 28, comprising from 0.1 to 2 wt% of a plurality of expandable microspheres.
32. The substrate according to Claim 28, further comprising at least one coating layer.
33. The substrate according to Claim 28, wherein the coating layer comprises at least one top coat and at least one base coat.
34. The substrate according to Claim 28, wherein the Sheffield Smoothness is less than 250 SU and the scanning print mottle is less than 6 after calendaring said substrate, as measured by TAPPI test method T 538 om-1.
35. The substrate according to Claim 28, wherein the substrate has a Parker Print Surface Smoothness of from about 1.0 to 0.5 as measured by TAPPI test method T

555 om-99
36. An article, comprising the substrate according to Claim 28.
37. The article according to Claim 33, wherein the article is a folding carton.
38. An article, comprising at least one paper or paperboard substrate wherein as least one substrate comprises a web of cellulose fibers and a bulking agent; wherein the article weighs equal to or less than one ounce; and wherein the article has a weight whose difference from 1 ounce is an absolute value that is more than that of a conventional package having the same number of layers.
CA2600801A 2005-03-11 2006-03-13 Compositions containing expandable microspheres and an ionic compound, as well as methods of making and using the same Expired - Fee Related CA2600801C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2750039A CA2750039A1 (en) 2005-03-11 2006-03-13 Substrate comprising expandable microspheres

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US66070305P 2005-03-11 2005-03-11
US60/660,703 2005-03-11
PCT/US2006/009015 WO2006099364A1 (en) 2005-03-11 2006-03-13 Compositions containing expandable microspheres and an ionic compound, as well as methods of making and using the same

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CA2750039A Division CA2750039A1 (en) 2005-03-11 2006-03-13 Substrate comprising expandable microspheres

Publications (2)

Publication Number Publication Date
CA2600801A1 true CA2600801A1 (en) 2006-09-21
CA2600801C CA2600801C (en) 2012-07-10

Family

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Family Applications (2)

Application Number Title Priority Date Filing Date
CA2750039A Abandoned CA2750039A1 (en) 2005-03-11 2006-03-13 Substrate comprising expandable microspheres
CA2600801A Expired - Fee Related CA2600801C (en) 2005-03-11 2006-03-13 Compositions containing expandable microspheres and an ionic compound, as well as methods of making and using the same

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CA2750039A Abandoned CA2750039A1 (en) 2005-03-11 2006-03-13 Substrate comprising expandable microspheres

Country Status (11)

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US (5) US8034847B2 (en)
EP (3) EP2357279A1 (en)
JP (2) JP5302670B2 (en)
KR (2) KR101192031B1 (en)
CN (1) CN101137790A (en)
AU (1) AU2006223142B2 (en)
BR (1) BRPI0608029A2 (en)
CA (2) CA2750039A1 (en)
MX (1) MX2007011113A (en)
RU (2) RU2506363C2 (en)
WO (1) WO2006099364A1 (en)

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