CA2684312A1 - Extrusion mold and method of use - Google Patents

Extrusion mold and method of use Download PDF

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Publication number
CA2684312A1
CA2684312A1 CA002684312A CA2684312A CA2684312A1 CA 2684312 A1 CA2684312 A1 CA 2684312A1 CA 002684312 A CA002684312 A CA 002684312A CA 2684312 A CA2684312 A CA 2684312A CA 2684312 A1 CA2684312 A1 CA 2684312A1
Authority
CA
Canada
Prior art keywords
venting
extrusion head
extrusion
mixture
gaps
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002684312A
Other languages
French (fr)
Inventor
Elie Helou, Jr.
David Dellinger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Biosphere Holdings Corp
Original Assignee
Biosphere Holdings Corporation
Elie Helou, Jr.
David Dellinger
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Biosphere Holdings Corporation, Elie Helou, Jr., David Dellinger filed Critical Biosphere Holdings Corporation
Publication of CA2684312A1 publication Critical patent/CA2684312A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21CMACHINES OR EQUIPMENT FOR MAKING OR PROCESSING DOUGHS; HANDLING BAKED ARTICLES MADE FROM DOUGH
    • A21C11/00Other machines for forming the dough into its final shape before cooking or baking
    • A21C11/16Extruding machines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/06Rod-shaped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/32Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/50Details of extruders
    • B29C48/76Venting, drying means; Degassing means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/12Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2003/00Use of starch or derivatives as moulding material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S425/00Plastic article or earthenware shaping or treating: apparatus
    • Y10S425/812Venting

Abstract

In one embodiment of the invention a mold system and method of use are provided such that aqueous starch-based compositions and baked goods articles that use the conversion of water to steam may be produced using an extruder that allows the venting of such gases and/or steam. The extruder is vented in such a way as to allow steam to escape, but retain the composition until the exit end.

Description

EXTRUSION MOLD AND METHOD OF USE
CROSS-REFERENCE TO RELATED APPLICATION

[0001] The present application claims priority to U.S. Patent Application No. 11/648,129, filed on December 28, 2006, the disclosure of which is incorporated by reference herein in its entirety, including drawings.

FIELD OF THE INVENTION

[00021 The present invention relates generally to systems and methods for creating extruded products while venting steam and/or gases during the extrusion process.

BACKGROUND OF THE INVENTION

[00031 The pressure to use biodegradable disposable packaging has been steadily increasing in the last decade. As recently as March, 2003, Taiwan has outlawed the use of Styrofoam in disposable packaging. Even China's major cities such as Beijing and Shanghai have outlawed the use of Styrofoam materials in disposable packaging. Various attempts have been made in the prior art to manufacture starch based disposables for use in food service items such as trays, plates, and bowls. Some methods include producing starch based packaging that has materials vented in excess of the final product as can be evidenced when one inspects the finished product.

However, these technologies use male and female molds and not extrusion dies. Attempts to extrude starch do not include venting during the extrusion process, and instead include injection gases in an attempt to foam the starch.
[00041 Further, the majority of the existing extrusion processes using starch are geared towards producing thick sheeted materials that are then bonded together to form packaging materials that replace thick Styrofoam.
Examples are protective packaging for shipping television sets or other similar electronic or heavy systems. Unfortunately, existing efforts have not been successful for producing articles such as toilet paper rolls, chop sticks, or straws primarily due to the inability to reduce pressures during the baking-extrusion process.

[00051 Accordingly, there is a need for improved systems and methods for extruding materials while continually venting gases during the extrusion process without any substantial material losses.

SUMMARY OF THE INVENTION

[00061 In one embodiment of the present invention a method of extruding a materal is provided comprising the steps of providing an extrusion head having a plurality of venting gaps for venting a gas; providing an extrusion mixture comprising fibers and water to the extrusion head; extruding the mixture through the extrusion head wherein the step of extruding comprises heating the mixture within the extrusion head such that the gas is release from the mixture; venting the gas from the extrusion head through the plurality of venting gaps such that the remaining mixture is substantially retained by the extrusion head.

[00071 In another embodiment, an extrusion head is provided comprising a plurality of venting gaps, wherein the venting gaps are dimensioned to allow for the venting of a gas but substantial retention of the remaining material to be extruded during extrusion and wherein the venting gaps are both radial and axial and the extrusion head is multi-piece.

BRIEF DESCRIPTION OF THE DRAWINGS

[00081 In order to fully understand the manner in which the above-recited details and other advantages and objects of the invention are obtained, a more detailed description of the invention will be rendered by reference to specific embodiments thereof which are illustrated in the included drawings.
Understanding that these drawings depict only typical embodiments of the invention and are not therefore to be considered as limiting of its scope, the invention will be described and explained with additional specifity and detail through the use of accompanying drawing in which:

[0009] Figure 1 is a view of a basic venting feature of an embodiment of the present invention.

[0010] Figure 2 is a view of a cross section of an extruder head of an embodiment of the present invention.
[0011] Figure 3 is a perspective view of a venting feature applied in an axial and trans-axial fashion to the extruder head of an embodiment of the present invention.

[00121 Figure 4 is a cross section view of an extruder head of an embodiment of the present invention with a venting features with a center mandrel used to allow the formation of tube shapes.

[00131 Figure 5 is a perspective view of an extruder head of an embodiment of the present invention showing a mix with or without fibers going through the extruder and exiting formed on the other end.

[00141 Figure 6 is a perspective view of an extruder head of an embodiment of the present invention showing continuous fibers and mix being introduced to the extruder and exiting formed on the other end..

[00151 Figure 7 is a cross section view of a formed product of an embodiment of the present invention with continuous fibers in a relatively straight configuration in a tube and rod configuration.

[00161 Figure 8 is a perspective view of the extruder of an embodiment of the present invention being fed fibers that are braided or knitted then introduced into the opening along with the starch mixture.

[00171 Figure 9 is a perspective exploded view of the various pieces of an embodiment of the present invention that are designed in such a way as they fit into an outer sleeve that would hold them together but still allow venting of the steam or gases.
DETAILED DESCRIPTION

[00181 The following description of the invention is intended to illustrate various embodiments of the invention. As such, the specific modifications discussed are not to be construed as limitations on the scope of the invention.

It will be apparent to one skilled in the art that various equivalents, changes, and modifications may be made without departing from the scope of the invention, and it is understood that such equivalent embodiments are to be included herein.

[0019] In an embodiment of the present invention, the characteristics of baked goods are used to provide high efficiency systems and methods for extruding starch-based articles as well as similar behavior materials. The systems and methods of the present embodiment accomplish the ability to extrude thin and thick walled extrusions that could not previously be produced due to the inability to vent gases during the extrusion process.

[00201 In the present embodiment, vents may be added within an extrusion tunnel, axially and/or through a cross section. Thus, referring to Figures 1-3, one embodiment of the inventive systems comprises a multi-piece extrusion head 10. The extrusion head 10 comprises one or more axial venting gaps 20 and/or radial venting gaps 30 that extend along the mating perimeter of the different pieces of the extrusion head 10. The size of the venting gaps 20, 30 can be constant or vary and are preferably from between about 0.001" to about 0.006" to allow steam and/or other gases to escape during the extrusion process, but contain the material to be extruded. The extrusion head 10 may also comprise venting gaps 20, 30 along the axis of the extrusion as well as radially between multiple pieces that are then attached together or may comprise only axial venting gaps 20 or only radial venting gaps 30.

[00211 In one aspect of the present embodiment the composition to be extruded can be water, alcohol or other liquid based. The composition may or may not contain additives such as fibers to improve the properties of the composition.

[00221 According to another embodiment of the invention, during the extrusion process, fibers can be chopped up and mixed in an extrusion mixture or fibers can be continuous and pulled through as is performed in composite pulltrusions. For pulltrusions, the fibers are pulled through a material flow opening of the extruder and are baked directly into the starch mixture. This can form a very axially strong product since the fibers are continuous.

[00231 According to another embodiment of the invention, the fibers can be knitted together to form different shapes that are then pulled through the extruder and baked into the starch. This method allows for biaxially strong extrusions. It also allows the user to customize required strength solutions by producing a fiber matrix that is then baked into the starch matrix.
[00241 According to another embodiment of the invention, the addition of a center mandrel with or without venting features on this mandrel and heated or unheated which would allow for the formation of tubes such as paper roll centers, toilet paper centers, and straws.

[00251 One feature of some embodiments of the invention is that the number of venting gaps can be customized, i.e., increased or reduced in numbers or size, to better control the steam and gas release process. It is important to note that not only round shapes but squares, rectangles, octagonal, namely, any cross-section that can be extruded, could be developed for this process. As previously mentioned, the addition of center mandrels could help in forming tube like sections instead of purely solid shapes.

[00261 Methods according to some embodiments of the invention generally comprise the steps of mixing at least water and starch together to form a starch-based composition then extruding the composition through the special die heads. The heat starts to bake the starch which in turn forms a skin wherever it comes into contact with the heated extruder surfaces. In addition, the heat turns the water in the composition to steam which is allowed to escape via the venting features. The mixture can have premixed fibers in it or continuous fibers that can also be stitched together or weaved in a shape to improve the overall strength of the finished product.

[00271 These and other features of embodiments of the present invention will become more fully apparent from the following description and appended claims, or may be learned by the practice of the invention as set forth hereinafter.

[00281 In another embodiment of the present invention mold systems and methods of use are provided such that aqueous starch-based compositions and baked goods articles that use the conversion of water to steam may be produced using an extruder that allows the venting of such gases and/or steam. The extruder is vented in such a way as to allow steam to escape, but retain the composition until the exit end.

[00291 More particularly, some embodiments use the physical property of starch and other baked goods to allow the release of steam without releasing the composition. When the mixture first contacts the heated surfaces of the extruder, they form a skin and the water in the mixture starts to turn to steam.

This method of allowing the venting of the steam at multiple areas along the extrusion path allows for more dense products that can withstand much higher forces. By adding steam release gaps using the several different methods describes herein, the baking time can be reduced thus increasing output.

[00301 By methods of the present embodiment one may produce tube and other extruded shapes that would be cheaper than existing paper and plastic products. Moreover, the overall process tends to be relatively benign and does not use the harsh chemicals normally associated with paper or plastic products.

[0031] In another embodiment of the present invention, the above extrusion concept may be applied to any material that can be placed in a cavity which when exposed to the heated surface produces a skin that is semi-permeable to the liquid being turned to gas and is not limited to aqueous based mixtures. Moreover, the mixtures can be edible or non-edible and could include various components for modifying the properties of the mixture, such as the addition of scents or other materials.

[0032] Referring to Figure 4, a cross-section of an extruder head having venting gaps 100 and an inner mandrel 110 that would be used for tube structure manufacturing is shown.

[0033] Referring to Figure 5, a trimetric view showing the extrusion of a tube structure 200 through an extruder head 210 from mix 220 with fiber 230.
[0034] Referring to Figure 6, a trimetric view showing a mix 300 and continuous fibers 310 being introduced to the extruder head 320 to produce an extrusion 330. Referring to Figure 7a, a cross section of the extrusion 330 is shown demonstrating fiber 310 orientations for a tube extrusion, and referring to Figure 7b, a cross section of the extrusion 330 is shown demonstrating fiber 310 orientations for a rod configuration. As can been seen in Figures 7a and 7b, the fiber 310 is oriented along the length of the tube or rod.
[0035] Referring to Figure 8, a continuous fiber 400 being knitted into a general cohesive shape 410 is shown being inserted into a mix 420 which is then extruded through the extruder head 430 to form the extrusion 440.

[0036] Referring to Figure 9, a trimetric view of an extruder head 500 that may be inserted into a pipe 510 or similar to hold the individual pieces of the extruder head together is shown.

[0037] As stated above, the foregoing is merely intended to illustrate various embodiments of the present invention. The specific modifications discussed above are not to be construed as limitations on the scope of the invention. It will be apparent to one skilled in the art that various equivalents, changes, and modifications may be made without departing from the scope of the invention, and it is understood that such equivalent embodiments are to be included herein. All references cited herein are incorporated by reference as if fully set forth herein.

Claims (11)

1. An extrusion head comprising:

at least one venting gap, wherein the venting gap is dimensioned to allow for the venting of a gas but substantial retention of the remaining material to be extruded during extrusion.
2. The extrusion head of claim 1 further comprising a multi-piece extrusion head.
3. The extrusion head of claim 2 further comprising a plurality of venting gaps.
4. The extrusion head of claim 3 wherein the plurality of venting gaps comprises radial venting gaps.
5. The extrusion head of claim 3 wherein the plurality of venting gaps comprises axial venting gaps.
6. The extrusion head of claim 3 wherein the plurality of venting gaps comprises both axial and radial venting gaps.
7. An extrusion head comprising:

a plurality of venting gaps, wherein the venting gaps are dimensioned to allow for the venting of a gas but substantial retention of the remaining material to be extruded during extrusion;
wherein the venting gaps are both radial and axial and wherein the extrusion head is multi-piece.
8. A method of extruding comprising:

providing an extrusion head comprising a plurality of venting gaps for venting a gas;

providing an extrusion mixture to the extrusion head;
extruding the mixture through the extrusion head wherein the step of extruding comprises heating the mixture within the extrusion head such that the gas is release from the mixture;
venting the gas from the extrusion head through the plurality of venting gaps such that the remaining mixture is substantially retained by the extrusion head.
9. The method of claim 8 wherein the mixture comprises fibers.
10. The method of claim 8 wherein the mixture comprises a water based mixture.
11. A method of extruding comprising:

providing an extrusion head comprising a plurality of venting gaps for venting a gas;

providing an extrusion mixture comprising fibers and water to the extrusion head;

extruding the mixture through the extrusion head wherein the step of extruding comprises heating the mixture within the extrusion head such that the gas is release from the mixture;
venting the gas from the extrusion head through the plurality of venting gaps such that the remaining mixture is substantially retained by the extrusion head.
CA002684312A 2006-12-28 2007-12-27 Extrusion mold and method of use Abandoned CA2684312A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/648,129 2006-12-28
US11/648,129 US8087921B2 (en) 2003-06-27 2006-12-28 Extrusion mold and method of use
PCT/US2007/088989 WO2008083247A2 (en) 2006-12-28 2007-12-27 Extrusion mold and method of use

Publications (1)

Publication Number Publication Date
CA2684312A1 true CA2684312A1 (en) 2008-07-10

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CA002684312A Abandoned CA2684312A1 (en) 2006-12-28 2007-12-27 Extrusion mold and method of use

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US (2) US8087921B2 (en)
EP (1) EP2136650A4 (en)
CA (1) CA2684312A1 (en)
WO (1) WO2008083247A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
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WO2022098345A1 (en) * 2020-11-03 2022-05-12 Gang Chen A low cost biodegradable drinking straw

Family Cites Families (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1875482A (en) 1932-09-06 Frank s
US2102786A (en) * 1931-11-14 1937-12-21 Quaker Oats Co Vented nozzle
US2488189A (en) * 1946-11-01 1949-11-15 Dow Chemical Co Extrusion machine
NL224151A (en) * 1957-01-22 1900-01-01
US3169272A (en) * 1962-10-30 1965-02-16 Continental Oil Co Apparatus for making plastic tubing
US3772076A (en) 1970-01-26 1973-11-13 Hercules Inc Reaction products of epihalohydrin and polymers of diallylamine and their use in paper
DE3378462D1 (en) * 1982-08-17 1988-12-22 Dainippon Printing Co Ltd Method and device for injection molding articles while simultaneously forming patterns thereon
US4491417A (en) * 1983-04-29 1985-01-01 Usm Corporation Devolatilizing mixing extruder
US4828769A (en) * 1986-05-05 1989-05-09 Galic/Maus Ventures Method for injection molding articles
US5232496A (en) * 1988-08-19 1993-08-03 E. Khashoggi Industries Process for producing improved building material and product thereof
US5695811A (en) 1989-10-10 1997-12-09 E. Khashoggi Industries Methods and compositions for bonding a cement-based overlay on a cement-based substrate
WO1991012186A1 (en) 1990-02-06 1991-08-22 Biopac Biologische Verpackungssysteme Gesellschaftm.B.H. Process for manufacturing decomposable, thin-walled starch-based mouldings
US5356579A (en) * 1990-05-18 1994-10-18 E. Khashoggi Industries Methods of manufacture and use for low density hydraulically bonded cement compositions
AU7962291A (en) * 1990-05-18 1991-12-10 E. Khashoggi Industries Hydraulically bonded cement compositions and their methods of manufacture and use
US5637412A (en) * 1990-05-18 1997-06-10 E. Khashoggi Industries Compressed hydraulically bonded composite articles
US5169566A (en) 1990-05-18 1992-12-08 E. Khashoggi Industries Engineered cementitious contaminant barriers and their method of manufacture
US5100586A (en) * 1990-07-20 1992-03-31 E. Khashoggi Industries Cementitious hazardous waste containers and their method of manufacture
US5209880A (en) * 1990-07-27 1993-05-11 Neo-Ex Lab. Inc. Process for making a sun visor by molding a pair of shells and bonding them together
US5352111A (en) * 1990-12-19 1994-10-04 Selbak's Cookie Cones, Inc. Apparatus for removing a hand held food product from a baking mold
US5412005A (en) * 1991-05-03 1995-05-02 Novamont S.P.A. Biodegradable polymeric compositions based on starch and thermoplastic polymers
US5279658A (en) * 1991-09-19 1994-01-18 David Aung Composition suitable for forming into shaped articles, process for preparing the composition, process for preparing shaped articles using the composition, and shaped articles so-formed
US5205863A (en) 1991-11-14 1993-04-27 International Communications & Energy Agricultural biodegradable plastics
US5354621A (en) * 1992-07-02 1994-10-11 Beltec International Biodegradable construction material and manufacturing method
US6277899B1 (en) * 1992-08-03 2001-08-21 Novamont S.P.A. Biodegradable polymeric composition
US5545450A (en) * 1992-08-11 1996-08-13 E. Khashoggi Industries Molded articles having an inorganically filled organic polymer matrix
US5506046A (en) 1992-08-11 1996-04-09 E. Khashoggi Industries Articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix
US5830548A (en) * 1992-08-11 1998-11-03 E. Khashoggi Industries, Llc Articles of manufacture and methods for manufacturing laminate structures including inorganically filled sheets
US5580409A (en) * 1992-08-11 1996-12-03 E. Khashoggi Industries Methods for manufacturing articles of manufacture from hydraulically settable sheets
US5549859A (en) * 1992-08-11 1996-08-27 E. Khashoggi Industries Methods for the extrusion of novel, highly plastic and moldable hydraulically settable compositions
US5508072A (en) * 1992-08-11 1996-04-16 E. Khashoggi Industries Sheets having a highly inorganically filled organic polymer matrix
US5658603A (en) 1992-08-11 1997-08-19 E. Khashoggi Industries Systems for molding articles having an inorganically filled organic polymer matrix
US5545297A (en) * 1992-08-11 1996-08-13 E. Khashoggi Industries Methods for continuously placing filaments within hydraulically settable compositions being extruded into articles of manufacture
US5683772A (en) * 1992-08-11 1997-11-04 E. Khashoggi Industries Articles having a starch-bound cellular matrix reinforced with uniformly dispersed fibers
US5660903A (en) * 1992-08-11 1997-08-26 E. Khashoggi Industries Sheets having a highly inorganically filled organic polymer matrix
US5641584A (en) * 1992-08-11 1997-06-24 E. Khashoggi Industries Highly insulative cementitious matrices and methods for their manufacture
US5810961A (en) * 1993-11-19 1998-09-22 E. Khashoggi Industries, Llc Methods for manufacturing molded sheets having a high starch content
US5800647A (en) * 1992-08-11 1998-09-01 E. Khashoggi Industries, Llc Methods for manufacturing articles from sheets having a highly inorganically filled organic polymer matrix
US5662731A (en) * 1992-08-11 1997-09-02 E. Khashoggi Industries Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix
US5453310A (en) * 1992-08-11 1995-09-26 E. Khashoggi Industries Cementitious materials for use in packaging containers and their methods of manufacture
US5582670A (en) * 1992-08-11 1996-12-10 E. Khashoggi Industries Methods for the manufacture of sheets having a highly inorganically filled organic polymer matrix
US5580624A (en) * 1992-08-11 1996-12-03 E. Khashoggi Industries Food and beverage containers made from inorganic aggregates and polysaccharide, protein, or synthetic organic binders, and the methods of manufacturing such containers
US5709827A (en) * 1992-08-11 1998-01-20 E. Khashoggi Industries Methods for manufacturing articles having a starch-bound cellular matrix
US5851634A (en) * 1992-08-11 1998-12-22 E. Khashoggi Industries Hinges for highly inorganically filled composite materials
US5720913A (en) * 1992-08-11 1998-02-24 E. Khashoggi Industries Methods for manufacturing sheets from hydraulically settable compositions
US5830305A (en) * 1992-08-11 1998-11-03 E. Khashoggi Industries, Llc Methods of molding articles having an inorganically filled organic polymer matrix
US5527387A (en) * 1992-08-11 1996-06-18 E. Khashoggi Industries Computer implemented processes for microstructurally engineering cementious mixtures
US5783126A (en) * 1992-08-11 1998-07-21 E. Khashoggi Industries Method for manufacturing articles having inorganically filled, starch-bound cellular matrix
EP0662029A4 (en) * 1992-08-11 1998-04-01 Khashoggi E Ind Hydraulically settable containers.
US5928741A (en) * 1992-08-11 1999-07-27 E. Khashoggi Industries, Llc Laminated articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix
US5679145A (en) * 1992-08-11 1997-10-21 E. Khashoggi Industries Starch-based compositions having uniformly dispersed fibers used to manufacture high strength articles having a fiber-reinforced, starch-bound cellular matrix
US5665439A (en) * 1992-08-11 1997-09-09 E. Khashoggi Industries Articles of manufacture fashioned from hydraulically settable sheets
US5618341A (en) * 1992-08-11 1997-04-08 E. Khashoggi Industries Methods for uniformly dispersing fibers within starch-based compositions
US5631097A (en) * 1992-08-11 1997-05-20 E. Khashoggi Industries Laminate insulation barriers having a cementitious structural matrix and methods for their manufacture
US5716675A (en) * 1992-11-25 1998-02-10 E. Khashoggi Industries Methods for treating the surface of starch-based articles with glycerin
US5543186A (en) * 1993-02-17 1996-08-06 E. Khashoggi Industries Sealable liquid-tight, thin-walled containers made from hydraulically settable materials
KR100311933B1 (en) * 1993-03-30 2001-12-17 오노 알버어스 Epoxy Ester Composition
AT401708B (en) 1993-06-17 1996-11-25 Auer Guenter Ing MULTI-PIECE BAKING FORM TO MAKE AN EDIBLE ICE CREAM
US5602188A (en) 1993-07-13 1997-02-11 Suzuki Sogyo Co., Ltd. Biodegradable resin foam and method and apparatus for producing same
US5738921A (en) * 1993-08-10 1998-04-14 E. Khashoggi Industries, Llc Compositions and methods for manufacturing sealable, liquid-tight containers comprising an inorganically filled matrix
US6083586A (en) * 1993-11-19 2000-07-04 E. Khashoggi Industries, Llc Sheets having a starch-based binding matrix
US5736209A (en) * 1993-11-19 1998-04-07 E. Kashoggi, Industries, Llc Compositions having a high ungelatinized starch content and sheets molded therefrom
DE59406378D1 (en) 1993-12-06 1998-08-06 Haas Franz Waffelmasch METHOD FOR THE PRODUCTION OF ROTABLE, THIN-WALLED MOLDED BODIES BASED ON STARCH
US5776388A (en) * 1994-02-07 1998-07-07 E. Khashoggi Industries, Llc Methods for molding articles which include a hinged starch-bound cellular matrix
US5843544A (en) 1994-02-07 1998-12-01 E. Khashoggi Industries Articles which include a hinged starch-bound cellular matrix
US5705203A (en) * 1994-02-07 1998-01-06 E. Khashoggi Industries Systems for molding articles which include a hinged starch-bound cellular matrix
US5925302A (en) * 1994-04-25 1999-07-20 Dai Nippon Printing Co., Ltd. Method for forming a pattern onto an article during injection molding
US5523293A (en) 1994-05-25 1996-06-04 Iowa State University Research Foundation, Inc. Soy protein-based thermoplastic composition for preparing molded articles
US5516046A (en) * 1994-07-06 1996-05-14 The Babcock & Wilcox Company Extended wear life low pressure drop right angle multi-exit orifice dual-fluid atomizer with replaceable wear materials
CA2224393A1 (en) 1995-06-14 1997-01-03 Franz Haas Waffelmaschinen Industriegesellschaft M.B.H. Process for manufacturing degradable thin-walled mouldings
AT407330B (en) 1995-07-07 2001-02-26 Mke Metall U Kunststoffwaren E METHOD FOR PRODUCING CONTAINERS, MUGS, TABLETS, MUGS OR. DGL. MADE FROM EDIBLE AND EASILY BIODEGRADABLE MATERIAL
US5665152A (en) * 1995-11-29 1997-09-09 Midwest Grain Products Biodegradable grain protein-based solid articles and forming methods
US5786080A (en) * 1996-04-03 1998-07-28 E. Khashoggi Industries Compositions and methods for manufacturing ettringite coated fibers and aggregates
US6168857B1 (en) * 1996-04-09 2001-01-02 E. Khashoggi Industries, Llc Compositions and methods for manufacturing starch-based compositions
US5686824A (en) * 1996-09-27 1997-11-11 National Semiconductor Corporation Voltage regulator with virtually zero power dissipation
US5783240A (en) 1996-10-16 1998-07-21 Wenger Manufacturing, Inc. Method of producing high protein, high fat sinking aquatic feed
JP3742204B2 (en) 1996-11-21 2006-02-01 日世株式会社 Method for producing shaped baked confectionery
DE19703798C2 (en) * 1997-02-01 2000-01-27 Berstorff Gmbh Masch Hermann Gear extruder
JP3439646B2 (en) * 1998-02-20 2003-08-25 大日本印刷株式会社 Injection molding simultaneous painting equipment
WO1999063015A1 (en) * 1998-06-05 1999-12-09 Snidow Steven B Organic composite material
SE513602C2 (en) * 1999-02-17 2000-10-09 Stora Kopparbergs Bergslags Ab Gluing composition, method for making glued paper or glued cardboard, and glued paper or glued cardboard
US6240836B1 (en) * 1999-08-05 2001-06-05 Paul W. Garbo Aluminum foil compression mold and method of molding food
US7067651B2 (en) * 1999-09-16 2006-06-27 Kasetsart University Non-synthetic biodegradable starch-based composition for production of shaped bodies
US6231970B1 (en) * 2000-01-11 2001-05-15 E. Khashoggi Industries, Llc Thermoplastic starch compositions incorporating a particulate filler component
US20030143417A1 (en) * 2000-01-11 2003-07-31 Anneliese Kesselring Composition for producing biological degradable shaped bodies and method for producing such a composition
US6494704B1 (en) 2000-03-31 2002-12-17 E. Khashoggi Industries, Llc Mold apparatus
US6379446B1 (en) * 2000-04-03 2002-04-30 E. Khashoggi Industries, Llc. Methods for dispersing fibers within aqueous compositions
US6214399B1 (en) * 2000-05-09 2001-04-10 Paul W. Garbo Apparatus and method for molding food
US6347934B1 (en) * 2000-05-10 2002-02-19 E. Khashoggi Industries, Llc. System for metering and delivering a moldable composition into a mold
JP3868757B2 (en) * 2001-04-25 2007-01-17 株式会社神戸製鋼所 Rubber composition kneading apparatus and kneading method
CN100402593C (en) * 2002-01-11 2008-07-16 新冰有限公司 Biodegradable or compostable vessel
WO2003089527A1 (en) 2002-04-19 2003-10-30 Evco Research, Llc Moisture resistant, repulpable paper products and method of making same
US6797213B2 (en) * 2002-10-15 2004-09-28 Frito-Lay North America, Inc Method and apparatus for producing a curly puff extrudate
CA2509087C (en) 2003-01-08 2013-03-12 Texas Tech University Castor oil/epoxidized soybean oil based elastomeric compositions
US8382888B2 (en) * 2003-08-27 2013-02-26 Biosphere Industries, Llc Composition for use in edible biodegradable articles and method of use
US7481645B2 (en) 2003-06-27 2009-01-27 Biosphere Industries, Llc Method for use in baking articles of manufacture and mold for use in said method
AU2004269027A1 (en) 2003-08-27 2005-03-10 Biosphere Industries, Llc Composition for use in biodegradable articles and method of use
US20060057319A1 (en) 2004-09-11 2006-03-16 Gleich Klaus F Methods and systems for making fiber reinforced products and resultant products
US8302213B2 (en) * 2004-10-08 2012-11-06 Ig Holdings Llc Helmets and vests
US7989524B2 (en) 2005-07-19 2011-08-02 The United States Of America, As Represented By The Secretary Of Agriculture Fiber-reinforced starch-based compositions and methods of manufacture and use

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US20070202228A1 (en) 2007-08-30
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