CN101402835B - White latex adhesive agent for packaging paper product - Google Patents
White latex adhesive agent for packaging paper product Download PDFInfo
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- CN101402835B CN101402835B CN2008100188142A CN200810018814A CN101402835B CN 101402835 B CN101402835 B CN 101402835B CN 2008100188142 A CN2008100188142 A CN 2008100188142A CN 200810018814 A CN200810018814 A CN 200810018814A CN 101402835 B CN101402835 B CN 101402835B
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- titanium dioxide
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Abstract
The invention provides an emulsion adhesive for paper-product packaging and a preparation method thereof. The method comprises: Polyvinyl alcohol, instant starch, polyvinyl acetate emulsion, water and kaolin, swell soil, titanium dioxide pigment, calcium carbonate, rubberlith and sodium hexametahposphate are used as main materials; the solid polyvinyl alcohol is dissolved with the water, later dispersed uniformly with the polyvinyl acetate emulsion, alcohol ester and an antiseptic and grinded into a glue liquid of 160 to 200 meshes; then after the kaolin, the swell soil, the titanium dioxide pigment, the calcium carbonate, the rubberlith, the sodium hexametahposphate and the instant starch are uniformly mixed, water is added for stirring the mixture into a uniformly mixed material; the glue liquid and the uniformly mixed material are dispersed together; moreover, a titanium ester coupling agent is added for obtaining the emulsion adhesive after being uniformly mixed. The emulsion adhesive is friendly to the environment, has fast drying speed, high intensity and low cost, is especially suitable to the sticking operation of high-grade paper boxes, has simple preparation technique and considerable economic benefit as well as has excellent market prospect.
Description
Affiliated technical field
The present invention relates to a kind of white latex adhesive agent for packaging paper product.
Background technology
At present, the tackiness agent that is adopted in the packaging paper product has tackiness agents such as various water-baseds, resin, kind is more, for the high packaging paper product of performance requriements, be generally water-based starch and be made by oxidation, gelatinization technology etc., this kind adhesive techniques content is lower, cost is higher, account for about 20% of packing cost, performance is stable inadequately, and it is bigger influenced by the air themperature seasonal variation, is difficult for storing.In addition, this class tackiness agent also exists following deficiency: the one, and environmental pollution is bigger, and its color is Vandyke brown or deep yellow, and the carton of white can't use, and bumps dirty carton panels easily, causes carton surface major defect, and causing exporting manufacturer can't use; The 2nd, the oxide compound in this tackiness agent is bigger to human body and surrounding environment pollution, and particularly the position pungencys such as tracheae to human body are bigger, and the people can't be stood, and have a strong impact on the healthy of people; The 3rd, this product is an aqueous binder, and cardboard is in the Exposure to Sunlight time when long slightly, and warping deformation easily influence the outward appearance of paper product, and the intensity of cardboard is relatively poor.And existing emulsion adhesive is mainly used in the industries such as wood working, furniture construction, adhering fabric, architectural decoration.
Summary of the invention
For overcoming the deficiencies in the prior art part, the invention provides a kind of non-environmental-pollution, rate of drying is fast, intensity is high, storage cycle is long, cost is low paper product white emulsion binder.
The technical scheme that the present invention solves its technical problem employing is:
A kind of paper product white emulsion binder comprises base-material, color stuffing and auxiliary agent;
Described base-material comprises polyvinyl alcohol, instant starch, polyvinyl acetate emulsion and water, and the parts by weight of its each component are: comprise polyvinyl alcohol 75～85, instant starch 10～15, polyvinyl acetate emulsion 50～100, water 700～800;
Described color stuffing comprises kaolin, wilkinite, titanium dioxide pigment, lime carbonate, zinc sulfide white and Sodium hexametaphosphate 99, and the parts by weight of its each component are: kaolin 50～100,, wilkinite 5～10, titanium dioxide pigment 1～2, lime carbonate 50～80, zinc sulfide white 10～20, Sodium hexametaphosphate 99 0.3～0.6;
Described assistant packet contains titanic acid ester coupling agent, sanitas, alcohol ester, and the parts by weight of each component are: titanate coupling agent 1～2, sanitas 0.5～1, alcohol ester 0.5～1.
Also comprise parts by weight in the above-mentioned auxiliary agent and be 0.03～0.06 part tributyl phosphate, to eliminate the too much foam that in dispersion process, is produced.
Above-mentioned polyvinyl acetate emulsion is the emulsion of concentration 30%.
Above-mentioned polyvinyl alcohol is 1788 type technical grades.
A kind of preparation method of paper product white emulsion binder behind solid-state polyvinyl alcohol and water dissolution, through being uniformly dispersed, and is ground to 160～200 purpose glues with poly-vinyl acetic monomer emulsion, alcohol ester, sanitas; After again kaolin, wilkinite, titanium dioxide pigment, lime carbonate, zinc sulfide white, Sodium hexametaphosphate 99, instant starch being mixed, add entry and stir; Above-mentioned glue and the material that mixes are disperseed together, and add titanate coupling agent, after evenly white emulsion binder.
When above-mentioned glue and the material that mixes disperse together, add tributyl phosphate, to eliminate foam.
Tackiness agent of the present invention is environmentally friendly, rate of drying is fast, intensity is high, cost is low, be specially adapted to the bonding operation of high-grade carton, and preparation technology is simple, and economic benefit is considerable, has good market outlook.
Embodiment
The invention will be further described below in conjunction with embodiment.
One, tackiness agent of the present invention: comprise base-material, color stuffing and auxiliary agent;
Described auxiliary agent comprises polyvinyl alcohol, instant starch, polyvinyl acetate emulsion and water, and the parts by weight of its each component are: polyvinyl alcohol 80, instant starch 13, polyvinyl acetate emulsion 75, water 750;
Described color stuffing comprises kaolin, wilkinite, titanium dioxide pigment, lime carbonate, zinc sulfide white and Sodium hexametaphosphate 99, and the parts by weight of its each component are: kaolin 75, wilkinite 8, titanium dioxide pigment 1.5, lime carbonate 65, zinc sulfide white 15, Sodium hexametaphosphate 99 0.5;
Described assistant packet contains titanic acid ester coupling agent, sanitas, alcohol ester, and the parts by weight of each component are: titanate coupling agent 1.5, sanitas 0.75, alcohol ester 0.75, tributyl phosphate 0.05.
Two, the preparation method of tackiness agent of the present invention:
1, gets 80 parts of 178 solid-state type polyvinyl alcohol and put in the reactor, add 100 parts of cold water, stir, and reactor is warming up to more than 80 ℃, after polyvinyl alcohol dissolved fully, cooling was cooled to room temperature, and above-mentioned polyvinyl alcohol solution is put in the dispersion machine.
2, get in 0.75 part of above-mentioned dispersion machine of adding of 75 parts of the poly-vinyl acetic monomer emulsions of technical grade, 0.75 part on alcohol ester 12-XH6 type, Ke Hua-981 sanitas of 30% concentration, with the polyvinyl alcohol solution dispersion treatment, to mixing;
3, the material of step 2 gained is put into shredder and be ground to 180 orders, make glue;
4, get 75 parts of kaolin, 8 parts of wilkinites, 1.5 parts of titanium dioxide pigments, 65 parts in lime carbonate, 15 parts in zinc sulfide white, 0.5 part of Sodium hexametaphosphate 99,13 parts of instant starch, carry out dry powder blend together, after mixing, join in the stirrer, and add 650 parts water and stir;
5, the material of step 3 and step 4 gained is joined carry out dispersion treatment in the dispersion machine, and add titanate coupling agent; In dispersion process, add 0.05 part tributyl phosphate, to eliminate foam, after mixing, promptly get tackiness agent of the present invention, carry out branch bucket packing.
Three, tackiness agent of the present invention and currently available products all are used for same specification standard export packages carton (415*270*275mm) its performance index control case (seeing Table 1) after testing:
Table 1:
| Performance index | The desired value of currently available products | The desired value of this tackiness agent |
| Outward appearance | Light yellow | Oyster white |
| Titre | 30～40 droplets/minute | 50～60 droplets/minute |
| Rate of drying | More than 2 hours | 20～50 minutes |
| Bond strength | 5～6Kgf/10cm is stupefied | 10～16Kgf/10cm is stupefied |
| Ultimate compression strength | 70～80Kgf | 600～700Kgf |
| Pop strength | 3200Kpa/10cm | 4800Kpa/10cm |
| Transfix intensity | 90Kgf.cm | 210Kgf.cm |
| Side pressure strength | 5800N/M | 11548N/M |
| Cost | 650 yuan/ton | 300 yuan/ton |
As can be seen from Table 1:
1, the outward appearance of tackiness agent of the present invention is white in color, and the outward appearance of currently available products is light yellow, thereby tackiness agent of the present invention can be used for exporting in the white Packaging Box;
2, the titre of tackiness agent of the present invention is 50～60 droplets/minute, and the titre of currently available products is 30～40 droplets/minute, thereby the materials of tackiness agent of the present invention province, can reduce the production cost of carton effectively;
3, the rate of drying of tackiness agent of the present invention is 20～50 minutes, and the rate of drying of currently available products is more than 2 hours, thereby adopts tackiness agent of the present invention to have to hand over and imitate ground and shorten the production cycle;
4, the bond strength of tackiness agent of the present invention is 10～16Kgf/10cm, is more than the twice of bond strength of currently available products 5～6Kgf/10cm;
5, the ultimate compression strength of tackiness agent of the present invention is 600～700Kpa/10cm, is three times of ultimate compression strength of currently available products 70～80Kpa/10cm;
6, the pop strength of tackiness agent of the present invention is 4800Kpa/10cm, is 1.5 times of pop strength of currently available products 3000Kpa/10cm;
7, the intensity that transfixes of tackiness agent of the present invention is 210kgf.cm, is more than 2 times of currently available products 90kgf.cm;
8, the side pressure strength of tackiness agent of the present invention is 11548N/M, is nearly 2 times of currently available products 5800N/M;
9, the cost of tackiness agent of the present invention is 300 yuan/ton, only is 48% of 650 yuan/ton of currently available products costs.
Claims (2)
1. a white latex adhesive agent for packaging paper product is characterized in that: comprise base-material, color stuffing and auxiliary agent;
Described base-material comprises polyvinyl alcohol, instant starch, polyvinyl acetate emulsion and water, and the parts by weight of its each component are: comprise polyvinyl alcohol 75～85, instant starch 10～15, concentration and be 30% polyvinyl acetate emulsion 50～100, water 700～800;
Described color stuffing comprises kaolin, wilkinite, titanium dioxide pigment, lime carbonate, zinc sulfide white and Sodium hexametaphosphate 99, and the parts by weight of its each component are: kaolin 50～100, wilkinite 5～10, titanium dioxide pigment 1～2, lime carbonate 50～80, zinc sulfide white 10～20, Sodium hexametaphosphate 99 0.3～0.6;
Described assistant packet contains titanic acid ester coupling agent, sanitas, alcohol ester, and the parts by weight of each component are: titanate coupling agent 1～2, sanitas 0.5～1, alcohol ester 0.5～1.
2. according to the described a kind of white latex adhesive agent for packaging paper product of claim 1, it is characterized in that: also comprise parts by weight in the above-mentioned auxiliary agent and be 0.03～0.06 part tributyl phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100188142A CN101402835B (en) | 2008-01-25 | 2008-01-25 | White latex adhesive agent for packaging paper product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100188142A CN101402835B (en) | 2008-01-25 | 2008-01-25 | White latex adhesive agent for packaging paper product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101402835A CN101402835A (en) | 2009-04-08 |
| CN101402835B true CN101402835B (en) | 2010-12-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100188142A Expired - Fee Related CN101402835B (en) | 2008-01-25 | 2008-01-25 | White latex adhesive agent for packaging paper product |
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| Country | Link |
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| CN (1) | CN101402835B (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103122223B (en) * | 2013-02-19 | 2015-09-23 | 赵国洪 | A kind of preparation method of tackiness agent |
| CN103333644A (en) * | 2013-05-30 | 2013-10-02 | 安徽祈艾特电子科技有限公司 | Adhesive agent for high-strength paper box and preparation method thereof |
| CN103360996B (en) * | 2013-07-05 | 2016-03-16 | 合肥杰明新材料科技有限公司 | A kind of multifunctional aqueous adhesive and preparation method thereof |
| CN103360995A (en) * | 2013-07-05 | 2013-10-23 | 滁州市鑫彩印务有限公司 | Carton composite adhesive and preparation method thereof |
| CN104194671A (en) * | 2014-08-25 | 2014-12-10 | 海南金海浆纸业有限公司 | Adhesive and preparation method thereof |
| CN106085264A (en) * | 2016-06-16 | 2016-11-09 | 铜陵锋帆彩色印务有限公司 | Anti tear Honey comb like package carton and preparation method thereof |
| CN106366953A (en) * | 2016-08-28 | 2017-02-01 | 梁乔保 | High-temperature-resistant environment-friendly glue |
| CN106147626A (en) * | 2016-08-28 | 2016-11-23 | 梁乔保 | A kind of high viscosity Environment-friendlyglue glue |
| CN107057608A (en) * | 2017-04-27 | 2017-08-18 | 龚彩萍 | A kind of white glue with vinyl binder and preparation method thereof |
| CN107556946A (en) * | 2017-09-25 | 2018-01-09 | 常州市绿意管道有限公司 | A kind of special paper tube adhesive of paper |
| CN107916081A (en) * | 2017-11-14 | 2018-04-17 | 汪逸凡 | A kind of preparation method of foam aluminum sandwich timber-used penertration resistance adhesive |
| CN108641618A (en) * | 2018-05-04 | 2018-10-12 | 宁国市千洪电子有限公司 | A kind of insulating tape |
| CN109096954A (en) * | 2018-07-25 | 2018-12-28 | 湖州光博生物科技有限公司 | A kind of preparation method of Novel glue |
| CN109437679B (en) * | 2018-11-09 | 2020-05-08 | 广西里尔新材料有限公司 | Special binder for soft porcelain |
| CN109795199A (en) * | 2019-03-12 | 2019-05-24 | 陈毫 | A kind of composite buffering packing board and its complex method |
| CN109988528A (en) * | 2019-04-10 | 2019-07-09 | 山东阿华医药材料科技有限公司 | A kind of high viscosity adhesive for paper box and its preparation method and application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4844972A (en) * | 1987-12-23 | 1989-07-04 | Borden, Inc. | Woven-backed vinyl decorative-coverings with starchy-PVA prepaste adhesive |
| CN1181406A (en) * | 1996-10-31 | 1998-05-13 | 普雷马克Rwp控股公司 | Adhesive for bonding decorative melamine treated paper to particle board |
| CN1314446A (en) * | 2000-03-17 | 2001-09-26 | 雅马哈株式会社 | Adhesion agent |
-
2008
- 2008-01-25 CN CN2008100188142A patent/CN101402835B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4844972A (en) * | 1987-12-23 | 1989-07-04 | Borden, Inc. | Woven-backed vinyl decorative-coverings with starchy-PVA prepaste adhesive |
| CN1181406A (en) * | 1996-10-31 | 1998-05-13 | 普雷马克Rwp控股公司 | Adhesive for bonding decorative melamine treated paper to particle board |
| CN1314446A (en) * | 2000-03-17 | 2001-09-26 | 雅马哈株式会社 | Adhesion agent |
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| CN101402835A (en) | 2009-04-08 |
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Effective date of registration: 20160328 Address after: 224011, Salt Road 2, Long Gang Town, Yancheng City, Jiangsu Province Patentee after: Yancheng City salt dragon packing printing factory Address before: 224011, Salt Road 2, Long Gang Town, Yancheng City, Jiangsu Province Patentee before: Yancheng Huamao Packaging Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20101215 Termination date: 20210125 |
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| CF01 | Termination of patent right due to non-payment of annual fee |