CN102027931B - Synergistic herbicide composition containing triclopyr and hexazinone and application thereof - Google Patents
Synergistic herbicide composition containing triclopyr and hexazinone and application thereof Download PDFInfo
- Publication number
- CN102027931B CN102027931B CN 200910036186 CN200910036186A CN102027931B CN 102027931 B CN102027931 B CN 102027931B CN 200910036186 CN200910036186 CN 200910036186 CN 200910036186 A CN200910036186 A CN 200910036186A CN 102027931 B CN102027931 B CN 102027931B
- Authority
- CN
- China
- Prior art keywords
- hexazinone
- triclopyr
- herbicide
- application
- synergistic herbicide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses a synergistic herbicide composition containing triclopyr and hexazinone and application thereof. In the herbicide composition, the triclopyr and the hexazinone are taken as the main active ingredients; and the mass ratio of the triclopyr to the hexazinone is 1-75: 1-75. The herbicide composition can be used for preparing herbicide for killing weeds in a woodland or non-cultivated land. Compared with single-composition herbicide, the herbicide composition has a broad herbicide spectrum and acts for a long time on the premise of improving herbicide effect, is safe for the forests and the afterculture crops, and particularly has an obvious effect of controlling various graminaccae, broadleaf weeds and undershrub in the woodland or the non-cultivated land.
Description
Technical field
The invention belongs to technical field of pesticide, especially the weed killer herbicide field relates to the binary built agent of Triclopyr and hexazinone.This Herbicidal combinations can be applicable to forest land, uncultivated area weeding.
Background technology
Triclopyr (triclopyr), chemical name: 3,5,6-three Chloro-2-Pyridyle fluoroacetic acid, its chemical formula is: C
7H
4Cl
3NO
3
Triclopyr is a kind of translocated herbicide, acts on metabolism of nucleic acid, makes plant produce excessive nucleic acid, make some structural transformations become meristematic tissue, cause blade, stem and root growth deformity, reserve substance exhausts, the vascular bundle tissue is by embolism or break, and plant is dead gradually.In soil, can be decomposed by microorganism rapidly.For weeds and the shrub of preventing and kill off forest land and uncultivated area, as: alternanthera philoxeroides, Veronica, fern, Eupatorium adenophorum, abrotanum etc.But the Triclopyr herbicidal spectrum is single, and is invalid to grassy weed, in addition, it is larger in pedo relict, and a pair of second stubble crop or interplanting in woodland crop are shone into poisoning, therefore, in order thoroughly to kill except the weeds in forest land and the uncultivated area and to improve safety, many and other herbicide mixtures of Triclopyr.
Hexazinone (hexazinone), chemical name: 3-cyclohexyl-6-(dimethylamino)-1-methyl isophthalic acid, 3,5-triazine-2,4-(1H, 3H)-diketone, its chemical formula is: C
12H
20N
4O
2Hexazinone is interior suction selective herbicide, mainly suppresses photosynthesis of plant, and plant roots, leaf can both absorb, and mainly by the xylem conduction, makes metabolic disorder, causes death.To the not injury of pine tree root, it is good woods weed killer herbicide.Be applicable to evergreen softwood forest, such as tending [after young plantations such as Korean pine, pinus sylvestris var. mongolica, dragon spruce, masson pines.Before the afforestation weeding go out filling, safeguard forest fire protection line and stand improvement etc., can prevent and kill off most of unifacial leaf and broadleaf weed and woody plant chrysanthemum honeysuckle, false spiraea, fibert, willow leaf meadow sweet, wilsonii, aspen, wooden birch, linden, Manchurian ash, yellow POLO, walnut and seize etc.But hexazinone drug effect process is slower, weeds 1 month, shrub 2 months, arbor 3-10 month.Therefore, seriously restricted the use of this medicament.
Forest land and uncultivated area weed killer herbicide are subjected to weeds large limit the in grass age at present, the herbicide spectrum is also limited, be used alone the weed killer herbicide single dose and can not control completely effectively the generation of forest land and uncultivated area weeds and undershrub, moreover some weed killer herbicide is because water-soluble large or the field lasting period is oversize, consumption is excessive or the inhomogeneous residual hazard that all easily causes this season crop or succession crop of dispenser.Therefore, but selection herbicide spectrum of the present invention is different, being made into mixture after two kinds of suitable decrements of weed killer herbicide of the Triclopyr of pluses and minuses complementation and hexazinone uses, so both enlarged the herbicide spectrum, obviously improved herbicidal effect, and effectively controlled the generation of undershrub, also avoided the too much residual poisoning to succession crop or interplanting crops of medicament.
Summary of the invention
The purpose of this invention is to provide a kind of Synergistic herbicide compositions that contains Triclopyr and hexazinone.
Another object of the present invention provides this Herbicidal combinations for the preparation of the application in the weed killer herbicide of forest land or uncultivated area weeding.
A kind of Synergistic herbicide compositions that contains Triclopyr and hexazinone is characterized in that this Herbicidal combinations take Triclopyr and hexazinone as main active ingredient, and the mass ratio of Triclopyr and hexazinone is 1～75: 1～75.The mass ratio of preferred Triclopyr and hexazinone is 1～40: 1～55, most preferably 1～30: 1～30.
In Synergistic herbicide compositions, the two quality percentage composition in Herbicidal combinations of Triclopyr and hexazinone is 1～85%, and the preferred mass percentage composition is 10～80%, and most preferably the quality percentage composition is 30～80%.
In the binary built preparation of Triclopyr of the present invention and hexazinone, except the active ingredients such as Triclopyr and hexazinone, can also add the auxiliary agents such as conventional surfactants, thickener, solvent or solid packing that allow on the pesticidal preparations and be mixed with any one formulation that allows on the agricultural chemicals.Preferably be processed into suspending agent, wetting powder, soluble powder, soluble liquid, water dispersible granules, granule, missible oil etc.Can adopt when using and the conventional known method such as spray.
Described surfactant specifically can adopt alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, methyl naphthalene sulfonate formaldehyde condensate, polyoxyethylene nonylphenol ether, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) etc., solid packing can be selected kaolin, diatomite etc., and solvent can adopt ethylene glycol, cyclohexanone, dimethylbenzene, water etc.These auxiliary agents can alone or mixing and usefulness, also can add other auxiliary material that allows on the pesticidal preparations.
" % " of the present invention is weight percentage.
Synergistic herbicide compositions of the present invention can be used in forest land or uncultivated area postemergence weed control, particularly uses in various grass family, broad leaved weed and the undershrub to have remarkable result in preventing and kill off forest land or uncultivated area.
Herbicidal combinations of the present invention has the following advantages:
1, activity of weeding is high.Triclopyr acts on metabolism of nucleic acid, and hexazinone mainly is inhibited photosynthesis, that is to say, Herbicidal combinations of the present invention can kill weeds by two kinds of different modes, can greatly improve the removing activity of Herbicidal combinations.
2, herbicidal spectrum is wide.Greenweed is prevented and kill off grass family, broad leaved weed and undershrub surely, and hexazinone can be prevented and kill off various weeds and some woody plants, and after both mixed, herbicidal spectrum was wider.
3, delay Weed Resistance.Herbicidal combinations of the present invention has different mechanisms, can prevent and treat various resistant weeds, and delays weeds generation resistance, prolongs the service life of medicament.
4,, safe.Herbicidal combinations of the present invention is applied to forest land or uncultivated area weeding, and it can prevent and kill off various grass family, broad leaved weed and undershrub in forest land or the uncultivated area, and under the prerequisite that has improved drug effect, its safety to forest and succession crop also is improved.
Therefore, Synergistic herbicide compositions of the present invention can be used in the weed killer herbicide for the preparation of forest land or uncultivated area weeding, is particularly using in the weed killer herbicide in grass family, broad leaved weed and the undershrub for the preparation of preventing and kill off in forest land or the uncultivated area.
Embodiment
Embodiment 1
Hexazinone 18%, Triclopyr 20%, methyl naphthalene sulfonate formaldehyde condensate 6%, polyoxyethylene nonylphenol ether 3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, water to 100%, being mixed with the quality percentage composition according to the formulation method of routine is 38% suspending agent.
Embodiment 2
Hexazinone 12%, Triclopyr 18%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 8%, alkylphenol polyoxyethylene 7%, neopelex 3%, sodium lignin sulfonate supplies 100%, and being mixed with the quality percentage composition according to the formulation method of routine is 30% soluble powder.
Embodiment 3
Hexazinone 15%, Triclopyr 60%, lauryl sodium sulfate 5%, ammonium sulfate 3%, polyvinyl alcohol 2%, kaolin to 100%, being mixed with the quality percentage composition according to the formulation method of routine is 72% water dispersible granules.
Embodiment 4
Hexazinone 60%, Triclopyr 20%, NNO (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 6%, wooden sodium iodate 5%, kaolin to 100%, being mixed with the quality percentage composition according to the formulation method of routine is 80% wetting powder.
Embodiment 5
Hexazinone 9%, Triclopyr 1%, alkylphenol polyoxyethylene 5%, ammonium sulfate 6%, polyvinyl alcohol 2%, kaolin to 100%, being mixed with the quality percentage composition according to the formulation method of routine is 10% granule.
Embodiment 6
Hexazinone 1%, Triclopyr 39%, calcium dodecyl benzene sulfonate 8%, alkylphenol polyoxyethylene 7%, dimethylbenzene supplies 100%, and being mixed with the quality percentage composition according to the formulation method of routine is 40% soluble powder.
Embodiment 7
Hexazinone 1%, Triclopyr 3%, alkylphenol polyoxyethylene 4%, phenethyl phenol polyethenoxy ether 15%, dimethylbenzene to 100% drops into above raw material and mixes the method for preparing routinely missible oil in the mixing kettle to make the quality percentage composition be 4% missible oil.
Embodiment 8
1), toxicity determination test
Utilize the preparation among the embodiment 1～4, measure it to the co-toxicity coefficient of acalypha copperleaf.
Test method: the seed of quantitative acalypha copperleaf is seeded in respectively in the Disposable paper cup of 9cm, sows 10～15 seeds in every glass, in illumination box, cultivate, treat acalypha copperleaf 3～6 leaves during the phase, do the composition spray processing of spraying in crawler type.Continuation cultivation in the greenhouse after processing, routine observation is respectively processed the preventive effect to weeds, and the weeds fresh weight behind the 30d after each processing of weighing is pressed the abundant method of Sun Yun (nineteen sixty proposition), calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient shows that greater than 100 two kinds of active principles have synergistic effect, and co-toxicity coefficient shows that less than 100 two kinds of active principles have antagonism.Measurement result is as shown in table 1.
Table 1 toxicity measurement result
As can be seen from the above table, the co-toxicity coefficient after two kinds of active principles are composite illustrates that all greater than 100 the present invention has obvious synergistic effect.
2, field control effectiveness test.
Reagent agent:
4 kinds of binary built Herbicidal combinations among the embodiment 1～4.
The contrast medicament:
75% hexazinone water dispersible granules (commercially available), 48% Triclopyr missible oil (commercially available).
For studying thing: the coniferous tree seedling
The coniferous tree seedling grows fine, and robust plant is without other damage by disease and insect.
Prevent and kill off object:
Green foxtail, lady's-grass, clearvers, amaranth, grey dish, acalypha copperleaf, undershrub etc.
Test method:
According to the area of experimental plot, the accurate good various medicaments of weighing, and after being watered dilution, utilize knapsack sprayer, carry out even spraying, the Fan spray head of sprinkler selection weed killer herbicide special use.During spraying, note liquid is evenly sprayed application in the experimental plot phenomenon of accomplishing there is not drain spray, spraying more.
After the test respectively behind medicine 20d, 40d observe the weeds death condition, and the activity of weeding of more various medicaments (consumption is the consumption of every mu of ground active ingredient).In addition, also to behind medicine, observe the condition of production of crop in 1～15d, to investigate medicament whether crop be had poisoning.
Embodiments of the invention preparation weeding test effect see the following form 2 (20d behind the medicine) and table 3 (40d behind the medicine).
Table 2 test of pesticide effectiveness result (20d behind the medicine)
| Treatment agent | Consumption (ga.i/ mu) | Grass family preventive effect (%) | Broad leaved weed preventive effect (%) | Undershrub preventive effect (%) |
| Embodiment 1 | 110 | 93 | 91 | 92 |
| Embodiment 2 | 110 | 94 | 94 | 91 |
| Embodiment 3 | 110 | 91 | 92 | 90 |
| Embodiment 4 | 110 | 90 | 92 | 91 |
| 75% hexazinone water dispersible granules | 150 | 85 | 78 | 80 |
| 48% Triclopyr missible oil | 130 | - | 82 | 79 |
Table 3 test of pesticide effectiveness result (40d behind the medicine)
| Treatment agent | Consumption (ga.i/ mu) | Grass family preventive effect (%) | Broad leaved weed preventive effect (%) | Undershrub preventive effect (%) |
| Embodiment 1 | 110 | 85 | 87 | 90 |
| Embodiment 2 | 110 | 89 | 88 | 89 |
| Embodiment 3 | 110 | 84 | 86 | 88 |
| Embodiment 4 | 110 | 85 | 87 | 90 |
| 75% hexazinone water dispersible granules | 150 | 75 | 68 | 79 |
| 48% Triclopyr missible oil | 130 | - | 70 | 75 |
Can find out from table 2 and table 3, the present invention has significant preventive effect to various grass family, broad leaved weed and undershrub, and synergy is remarkable, and the lasting period is long.
Table 4 medicament is to the security survey result of crop
Each needle sapling of processing in the residential quarter grows fine, and has no any medicine spot, illustrates that various medicaments are to the equal safety of coniferous tree.
Claims (3)
1. Synergistic herbicide compositions that contains Triclopyr and hexazinone is characterized in that this Herbicidal combinations take Triclopyr and hexazinone as active ingredient, and this Synergistic herbicide compositions is specially:
Hexazinone 18%, Triclopyr 20%, methyl naphthalene sulfonate formaldehyde condensate 6%, polyoxyethylene nonylphenol ether 3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, add water to 100%, being mixed with the quality percentage composition according to the formulation method of routine is 38% suspending agent;
Perhaps hexazinone 12%, Triclopyr 18%, and sodium methylene bis-naphthalene sulfonate 8%, alkylphenol polyoxyethylene 7%, neopelex 3%, sodium lignin sulfonate supplies 100%, and being mixed with the quality percentage composition according to the formulation method of routine is 30% soluble powder;
Perhaps hexazinone 15%, Triclopyr 60%, and lauryl sodium sulfate 5%, ammonium sulfate 3%, polyvinyl alcohol 2% adds kaolin to 100%, and being mixed with the quality percentage composition according to the formulation method of routine is 75% water dispersible granules.
2. Synergistic herbicide compositions claimed in claim 1 is for the preparation of the application in the weed killer herbicide of forest land, uncultivated area weeding.
3. application according to claim 2 is characterized in that described Synergistic herbicide compositions is for the preparation of the application in the weed killer herbicide of preventing and kill off various grass family, broad leaved weed and undershrub in forest land, the uncultivated area.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910036186 CN102027931B (en) | 2009-09-28 | 2009-09-28 | Synergistic herbicide composition containing triclopyr and hexazinone and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910036186 CN102027931B (en) | 2009-09-28 | 2009-09-28 | Synergistic herbicide composition containing triclopyr and hexazinone and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102027931A CN102027931A (en) | 2011-04-27 |
| CN102027931B true CN102027931B (en) | 2013-09-18 |
Family
ID=43881812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200910036186 Active CN102027931B (en) | 2009-09-28 | 2009-09-28 | Synergistic herbicide composition containing triclopyr and hexazinone and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102027931B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102805084A (en) * | 2012-08-31 | 2012-12-05 | 广西田园生化股份有限公司 | Weeding combination containing hexazinone |
| CN114651821A (en) * | 2021-12-29 | 2022-06-24 | 中国铁道科学研究院集团有限公司金属及化学研究所 | Herbicide composition for railway lines and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6713433B2 (en) * | 1999-08-11 | 2004-03-30 | Monsanto Technology, Llc | Coformulation of an oil-soluble herbicide and a water-soluble herbicide |
| CN1514686A (en) * | 2001-02-14 | 2004-07-21 | ������ɽ���� | Coformulation of oil-soluble herbicide and water-soluble heribcide as stable oil-in-water emulsion or microemulsion |
-
2009
- 2009-09-28 CN CN 200910036186 patent/CN102027931B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6713433B2 (en) * | 1999-08-11 | 2004-03-30 | Monsanto Technology, Llc | Coformulation of an oil-soluble herbicide and a water-soluble herbicide |
| CN1514686A (en) * | 2001-02-14 | 2004-07-21 | ������ɽ���� | Coformulation of oil-soluble herbicide and water-soluble heribcide as stable oil-in-water emulsion or microemulsion |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102027931A (en) | 2011-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102027988A (en) | Synergistic herbicide composition comprising triclopyr and glufosinate and application thereof | |
| CN102027905B (en) | Synergic weeding composition containing clopyralid and fluroxypyr and application thereof | |
| CN102027931B (en) | Synergistic herbicide composition containing triclopyr and hexazinone and application thereof | |
| CN102027919B (en) | Synergistic herbicide composition containing fluroxypyr and pendimethialin and application thereof | |
| CN102027969A (en) | Herbicidal composition containing clopyralid and tribenuron-methyl and application thereof | |
| CN102265850A (en) | Weeding composition containing bentazone, clopyralid and atrazine, and application thereof | |
| CN102265852A (en) | Weeding composition containing bentazone and propanil and application thereof | |
| CN102027932A (en) | Synergistic weeding composition containing clopyralid and carfentrazone-ethyl and application thereof | |
| CN102027920A (en) | Synergistic herbicidal composition containing triclopyr and picloram and use thereof | |
| CN102027945A (en) | Synergistic weeding composition containing clopyralid and bentazone | |
| CN104604907A (en) | Dicamba and pyributicarb herbicidal composition and application thereof | |
| CN104604915A (en) | Dicamba and pyrazosulfuron-ethyl herbicidal composition and application thereof | |
| CN102027918A (en) | Synergistic herbicidal composition containing clopyralid and dicamba | |
| CN102027921B (en) | Synergistic herbicidal composition containing picloram and bromoxynil and application thereof | |
| CN102027924B (en) | Herbicidal composition containing picloram and dicamba | |
| CN102027970B (en) | Herbicidal composition containing clopyralid and thifensulfuron-methyl and application thereof | |
| CN105379742A (en) | Compound weeding composition containing clodinafop-propargyl and methabenzthiazuron and application thereof | |
| CN105379718A (en) | Compound weeding composition containing clodinafop-propargyl and oxyfluorfen and application thereof | |
| CN102027939A (en) | Weeding composition containing triclopyr and simazine and application thereof | |
| CN102027923B (en) | Synergistic herbicidal composition containing picloram and pendimethalin and application thereof | |
| CN102027968B (en) | Synergistic herbicidal composition containing clopyralid and bensulfuron-methyl and application thereof | |
| CN104604900A (en) | Weeding composition containing dicamba and pyridate, and application thereof | |
| CN104604856A (en) | Weeding composition containing dicamba and aclonifen, and application thereof | |
| CN102027959B (en) | Synergistic herbicidal composition containing clopyralid and chlortoluron and application thereof | |
| CN102027960B (en) | Herbicidal composition containing picloram and isoproturon and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |