CN103979489B - Adopt the cogeneration technology of MAGNESIUM METAL or aluminium continuous hydrogen production - Google Patents
Adopt the cogeneration technology of MAGNESIUM METAL or aluminium continuous hydrogen production Download PDFInfo
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- CN103979489B CN103979489B CN201310049017.1A CN201310049017A CN103979489B CN 103979489 B CN103979489 B CN 103979489B CN 201310049017 A CN201310049017 A CN 201310049017A CN 103979489 B CN103979489 B CN 103979489B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Abstract
The present invention relates to a kind of cogeneration technology adopting MAGNESIUM METAL or aluminium continuous hydrogen production, comprise and first storage battery two is taken turns out electrode with power supply system for being electrically connected, power supply system is through voltage detecting warning circuit, give intelligent control unit and each pump, valve, sensor power after voltage detecting is qualified, voltage detecting is defective forbids power supply; The specific equipment realizing this technique comprises reactor, lye tank, MAGNESIUM METAL or aluminum feedstock case, hydrogen fuel cell, tailing case, hot-water system, peristaltic pump, service pump, hydrogen gas circulating pump, exhaust solenoid valve, driven spherical valve, the first magnetic valve, extraction valve, the second magnetic valve, aqueous vapor separation water discharge valve, the first pressure transmitter, the second pressure transmitter, upper liquid level sensor.The present invention is applicable to hydrolyzable metal preparing hydrogen, generating power, has design science, that rational in infrastructure, control is done is convenient, the feature of safety environment protecting energy saving, can realize hydrogen manufacturing, generating, the carrying out continuously of heat supply.
Description
Technical field
The invention belongs to a kind of technique and specific equipment thereof of power generation and heat supply, concrete a kind ofly adopt MAGNESIUM METAL and water to react or the technique of hydrogen hydrogen supply fuel cell power generation that metallic aluminium and alkaline reaction produce and specific equipment thereof.
Background technology
Current hydrogen production process is mainly divided into electrolytic hydrogen production, organic-fuel reformation hydrogen production, hydrolyzable metal hydrogen manufacturing, and our technology is the category belonging to hydrolyzable metal hydrogen manufacturing.Adopt the continuous hydrolysis process for making hydrogen containing aluminium or magnesium in the cogeneration technology of MAGNESIUM METAL or metallic aluminium continuous hydrogen production, adopt the continuous hydrolysis process for making hydrogen containing magnesium in the technique of MAGNESIUM METAL continuous seepage hydrogen and magnesium hydroxide, both continuous hydrolysis process for making hydrogen are different.
Patent CN200610043857.7, CN201180013857.1 and CN201210111586.X belong to reformation hydrogen production, do not conflict with our application.Patent CN200710011042.5 is the aluminium alloy reaction material of hydrolyzable metal hydrogen manufacturing, patent CN200910042939.3 is the hydrolytic hydrogen production material of Al-Li alloy, and our technology is the cogeneration technology of aluminium or magnesium hydrolysis, and MAGNESIUM METAL produces the technique of hydrogen and magnesium hydroxide.Patent CN201010288644.7 is the continuous hydrogen production system of aluminium and water reaction, although have " continuous hydrogen production " in its title, but its hydrolytic hydrogen production technique is not identical with our two kinds of continuous hydrolysis process for making hydrogen, this patent does not illustrate how aluminium powder enters its reactor (0.1 ~ 0.2MPa) continuously.In our two kinds of continuous hydrolysis process for making hydrogen, aluminium powder or magnesium powder pump into reactor continuously, safely by liquid carrier, then coordinate self water feeding and automatically collect tailing system, achieve continuous hydrolysis hydrogen manufacturing truly.In addition, owing to being continuous hydrolysis hydrogen manufacturing, technological process need not use pressurized vessel (more than 0.1MPa) to carry out storage of hydrogen, so our reactor pressure lower (0.06 ~ 0.08MPa), safety coefficient is higher.
Summary of the invention
An object of the present invention is to solve the problem, a kind of cogeneration technology adopting MAGNESIUM METAL or aluminium continuous hydrogen production is proposed, the cogeneration technology of this employing MAGNESIUM METAL or aluminium continuous hydrogen production can supply continuously for feed liquid and water (or alkali lye), and the discharge of tailing and collection can not affect the generation of hydrogen and heat energy, achieve the cogeneration of continuous hydrogen production.
Two of object of the present invention is to solve the problem, a kind of specific equipment adopting the cogeneration technology of MAGNESIUM METAL or aluminium continuous hydrogen production is proposed, feature that is convenient, safety environment protecting energy saving that the specific equipment of the cogeneration technology of this employing MAGNESIUM METAL or aluminium continuous hydrogen production has design science, rational in infrastructure, control is done.
An object of the present invention is achieved through the following technical solutions:
Adopt the cogeneration technology of MAGNESIUM METAL or aluminium continuous hydrogen production, it is characterized in that: comprise the following steps:
1., first to make the feed liquid being easy to pumping be precondition magnesium powder (or aluminium powder) and glycerol being mixed in proportion, store battery two output electrodes and power supply system are supplied to be electrically connected, power supply system detects each alarm sensor circuit, give intelligent control unit and each pump after alarm free, valve powers, have Alarm Disable to power;
2., service pump is started to injecting water (or alkali lye) in reactor by intelligent control unit, start peristaltic pump magnesium powder (or aluminium powder) and glycerol are mixed in proportion the suspension feed liquid material made are injected in reactor simultaneously, start hydrogen gas circulating pump simultaneously, start cooling water circulating pump to the interchanger outside reactor, hot-water system water filling simultaneously, prepare to lower the temperature to reactor;
3. when after reactor exhaust solenoid valve time-delay closing, by pressure transmitter detection reaction device internal pressure value, when reactor pressure rises on prescribed value, reactor starts to hydrogen fuel cell for hydrogen, a hydrogen fuel cell generating part charges a battery, another part is powered to power supply system, some through DC-AC inversion system to mains-supplied, check whether the material box liquid level sensor in MAGNESIUM METAL or aluminum feedstock case reaches lower value simultaneously, check whether water (or alkali lye) the case liquid level sensor in water (or alkali lye) case reaches lower value, check whether the tailing case liquid level sensor in tailing case reaches higher limit, reach alarm, and time-delay closing service pump, peristaltic pump, when reactor pressure is increased beyond safety value, positive opening reactor exhaust solenoid valve, when reactor pressure drops under prescribed value, starting peristaltic pump is injected in reactor by advance magnesium powder (or aluminium powder) and glycerol being mixed in proportion the suspension feed liquid material made in MAGNESIUM METAL or aluminum feedstock case, when reactor pressure is got back on prescribed value, close peristaltic pump, by timing register to the time timing of peristaltic pump material loading, driven spherical valve under material loading time-out unlatching reactor is to tailing case discharge, when opening first, the hydrogen gas circulating pump be connected with tailing case and extraction valve and vent valve are to air pump drainage air and time-delay closing, when again opening, the hydrogen gas circulating pump be connected with tailing case and extraction valve, inject hydrogen by the pipeline extended at the bottom of reactor in reactor, when liquid level in reactor drops under lower liquid level sensor, driven spherical valve below off-response device, check the pressure transmitter on tailing case simultaneously, when pressure is greater than higher limit, open the extraction valve be connected with tailing case, hydrogen gas circulating pump injects hydrogen by the pipeline extended at the bottom of reactor in reactor, when pressure is less than lower value, close the extraction valve be connected with tailing case,
4., when by checking that in reactor, liquid level does not arrive on upper liquid level sensor, service pump is started, to injecting water (or alkali lye) in reactor; When by checking that in reactor, liquid level arrives on upper liquid level sensor, closing service pump, stopping to injecting water (or alkali lye) in reactor;
5., when finding that reactor temperature exceedes prescribed value by hot-water system, starting warning circuit, and stopping the operation of service pump, peristaltic pump, starting cooling water circulating pump simultaneously.
Two of object of the present invention is achieved through the following technical solutions:
Adopt the specific equipment of the cogeneration technology of MAGNESIUM METAL or aluminium continuous hydrogen production, it is characterized in that: comprise reactor, water (or alkali lye) case, MAGNESIUM METAL or aluminum feedstock case, hydrogen fuel cell, tailing case, hot-water system, peristaltic pump, service pump, hydrogen gas circulating pump, exhaust solenoid valve, driven spherical valve, magnetic valve, magnetic valve, magnetic valve, aqueous vapor is separated water discharge valve, pressure transmitter, pressure transmitter, upper liquid level sensor, lower liquid level sensor, tailing case liquid level sensor, water (or alkali lye) case liquid level sensor, material box liquid level sensor, intelligent control unit, described reactor is an encloses container, and be provided with liquid level sensor and lower liquid level sensor in described reactor, described reactor head passes through pipeline, service pump is connected with water (or alkali lye) case feed flow, and described reactor head passes through pipeline, peristaltic pump is connected with MAGNESIUM METAL or aluminum feedstock case feed, and described reactor head passes through pipeline, aqueous vapor is separated water discharge valve, pressure transmitter, exhaust solenoid valve, magnetic valve is connected with hydrogen fuel cell air feed, and described reactor head has one to extend to pipeline at the bottom of reactor, and described reactor bottom passes through pipeline, driven spherical valve is connected with tailing case discharge, and described tailing case is a sealed vessel, and described tailing case passes through pipeline, pressure transmitter, magnetic valve, hydrogen gas circulating pump, the pipeline that magnetic valve extends at the bottom of reactor with one of reactor head is connected, an interchanger is had outside described reactor, described interchanger supplies hot tie-in by pipeline and hot-water system, material box liquid level sensor is provided with in described MAGNESIUM METAL or aluminum feedstock case, water (or alkali lye) case liquid level sensor is provided with in described water (or alkali lye) case, tailing case liquid level sensor is provided with, described exhaust solenoid valve in described tailing case, driven spherical valve, magnetic valve, magnetic valve, magnetic valve, aqueous vapor is separated water discharge valve, pressure transmitter, pressure transmitter, upper liquid level sensor, lower liquid level sensor, tailing case liquid level sensor, lye tank liquid level sensor, material box liquid level sensor and intelligent control unit control linkage.
The embodiment that specific equipment of the present invention improves further and supplements:
Described peristaltic pump also can adopt spiral pump.
Described intelligent control unit can adopt the one in micro-chip, computer, cogeneration switchboard.
Present invention process utilizes metallic aluminium and alkali lye to react, and produces hydrogen and a large amount of heat energy.Hydrogen is supplied to the generating of proton membrane hydrogen fuel cell, and heat energy is derived by cooling circulating water, provides heating and hot water.Under catalyst action, MAGNESIUM METAL and normal-temperature water react, and produce hydrogen and magnesium hydroxide, and release a large amount of heat energy.The generating of hydrogen supply proton membrane hydrogen fuel cell, magnesium hydroxide is recycled, and heat energy is derived by cooling circulating water, provides heating and hot water.Aluminium powder and glycerol (glycerine) are mixed in proportion, make the suspension feed liquid of thickness, this feed liquid can be delivered in reactor by peristaltic pump or spiral pump continuously, safely, and the alkali lye sent here with lye pump recurs reaction.Magnesium powder and glycerol are mixed in proportion, make the suspension feed liquid of thickness, this feed liquid can be delivered in reactor by peristaltic pump or spiral pump continuously, safely, and the normal-temperature water sent here with water pump recurs reaction.In addition, glycerol has froth breaking effect, the generation of foam in inhibited reaction process.
Specific equipment of the present invention is blown into reactor bottom by the pipeline extended to bottom reaction hydrogen, in order to promote reaction and to prevent precipitation, and has the function of pump drainage tailing case air and collection tailing case hydrogen; The pressure transmitter be connected with reactor is utilized to control pressure in reactor, this pressure transmitter be connected with reactor possesses the effect that moisture in monitoring reactor (or alkali lye) is measured simultaneously, when moisture (or alkali lye) amount is lower, the lengthy pressure of reactor is in lower value, reactor tailing valve is impelled to open, because feed liquid and water (or alkali lye) can supply continuously, and the discharge of tailing and collection can not affect the generation of hydrogen and heat energy, achieve the cogeneration of continuous hydrogen production.
Accompanying drawing explanation
Fig. 1 is schematic diagram of the present invention;
Fig. 2 is the control flow chart of intelligent control system of the present invention;
Embodiment
Below in conjunction with drawings and Examples, the present invention is further illustrated:
Embodiment: see accompanying drawing 1,2,
Adopt the cogeneration technology of MAGNESIUM METAL or aluminium continuous hydrogen production,
Comprise the following steps:
1., first to make the feed liquid being easy to pumping be precondition magnesium powder (or aluminium powder) and glycerol being mixed in proportion, store battery two output electrodes and power supply system are supplied to be electrically connected, power supply system detects each alarm sensor circuit, give intelligent control unit and each pump after alarm free, valve powers, have Alarm Disable to power;
2., service pump B is started by intelligent control unit
2to injecting water (or alkali lye) in reactor 1, start peristaltic pump B simultaneously
1magnesium powder (or aluminium powder) and glycerol are mixed in proportion the suspension feed liquid material made to be injected in reactor, starts hydrogen gas circulating pump B simultaneously
3, start cooling water circulating pump to the interchanger outside reactor, hot-water system 6 water filling simultaneously, prepare to lower the temperature to reactor;
3. as reactor exhaust solenoid valve F
1after time-delay closing, by pressure transmitter Y
1detection reaction device internal pressure value, when reactor pressure rises on prescribed value, reactor starts to hydrogen fuel cell 4 for hydrogen, a hydrogen fuel cell generating part charges a battery, another part is powered to power supply system, some to mains-supplied, checks the material box liquid level sensor S in MAGNESIUM METAL (or aluminium) material box 3 through DC-AC inversion system simultaneously
5whether reach lower value, check water (or alkali lye) the case liquid level sensor S in water (or alkali lye) case 2
4whether reach lower value, check the tailing case liquid level sensor S in tailing case 5
3whether reach higher limit, reach alarm, and time-delay closing service pump B
2, peristaltic pump B
1; When reactor pressure is increased beyond safety value, positive opening reactor exhaust solenoid valve F
1; When reactor pressure drops under prescribed value, start peristaltic pump B
1being injected in reactor by advance magnesium powder (or aluminium powder) and glycerol being mixed in proportion the suspension feed liquid material made in MAGNESIUM METAL or aluminum feedstock case 3, when reactor pressure is got back on prescribed value, closing peristaltic pump B
1; By timing register to the time timing of peristaltic pump material loading, material loading time-out opens the driven spherical valve F under reactor
2to tailing case 5 discharge, when opening first, the hydrogen gas circulating pump B be connected with tailing case
3with extraction valve F
3and vent valve F
4to air pump drainage air and time-delay closing, when again opening, the hydrogen gas circulating pump B be connected with tailing case
3with extraction valve F
3, in reactor, inject hydrogen by the pipeline extended at the bottom of reactor; When liquid level in reactor drops to lower liquid level sensor S
2under time, the driven spherical valve F below off-response device
2, check the pressure transmitter Y on tailing case simultaneously
2, when pressure is greater than higher limit, open the extraction valve F be connected with tailing case
3, hydrogen gas circulating pump B
3in reactor, hydrogen is injected by the pipeline extended at the bottom of reactor; When pressure is less than lower value, close the extraction valve F be connected with tailing case
3;
4., when not arriving upper liquid level sensor S by liquid level in inspection reactor
1on time, start service pump B
2, to injecting water (or alkali lye) in reactor; When arriving upper liquid level sensor S by liquid level in inspection reactor
1on time, close service pump B
2, stop to injecting water (or alkali lye) in reactor;
5., when finding that reactor temperature exceedes prescribed value by hot-water system 6, starting warning circuit, and stopping service pump B
2, peristaltic pump B
1operation, start cooling water circulating pump simultaneously.
Adopt the specific equipment of the cogeneration technology of MAGNESIUM METAL or aluminium continuous hydrogen production, comprise reactor 1, water (or alkali lye) case 2, MAGNESIUM METAL or aluminum feedstock case 3, hydrogen fuel cell 4, tailing case 5, hot-water system 6, peristaltic pump B
1, service pump B
2, hydrogen gas circulating pump B
3, exhaust solenoid valve F
1, driven spherical valve F
2, magnetic valve F
3, magnetic valve F
4, magnetic valve F
5, aqueous vapor is separated water discharge valve F
6, pressure transmitter Y
1, pressure transmitter Y
2, upper liquid level sensor S
1, lower liquid level sensor S
2, tailing case liquid level sensor S
3, water (or alkali lye) case liquid level sensor S
4, material box liquid level sensor S
5, intelligent control unit, described reactor is an encloses container, is provided with liquid level sensor S in described reactor
1with lower liquid level sensor S
2, described reactor head is by pipeline, service pump B
2be connected with water (or alkali lye) case 2 feed flow, described reactor head is by pipeline, peristaltic pump B
1be connected with MAGNESIUM METAL or aluminum feedstock case 3 feed, described reactor head is separated water discharge valve F by pipeline, aqueous vapor
6, pressure transmitter Y
1, exhaust solenoid valve F
1, magnetic valve F
5be connected with hydrogen fuel cell 4 air feed, described reactor head has one to extend to pipeline at the bottom of reactor, and described reactor bottom is by pipeline, driven spherical valve F
2be connected with tailing case 5 discharge, described tailing case is a sealed vessel, and described tailing case is by pipeline, pressure transmitter Y
2, magnetic valve F
3, hydrogen gas circulating pump B
3, magnetic valve F
4the pipeline extended at the bottom of reactor with one of reactor head is connected, and has an interchanger outside described reactor, and described interchanger supplies hot tie-in by pipeline and hot-water system, is provided with material box liquid level sensor S in described MAGNESIUM METAL or aluminum feedstock case 3
5, in described water (or alkali lye) case 2, be provided with water (or alkali lye) case liquid level sensor S
4, in described tailing case 5, be provided with tailing case liquid level sensor S
3, described exhaust solenoid valve F
1, driven spherical valve F
2, magnetic valve F
3, magnetic valve F
4, magnetic valve F
5, aqueous vapor is separated water discharge valve F
6, pressure transmitter Y
1, pressure transmitter Y
2, upper liquid level sensor S
1, lower liquid level sensor S
2, tailing case liquid level sensor S
3, lye tank liquid level sensor S
4, material box liquid level sensor S
5with intelligent control unit control linkage.Described intelligent control unit can adopt cogeneration switchboard.
Last it is noted that obviously, above-described embodiment is only for example of the present invention is clearly described, and the restriction not to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here exhaustive without the need to also giving all embodiments.And thus the apparent change of extending out or variation be still among protection scope of the present invention.
Claims (4)
1. adopt a cogeneration technology for MAGNESIUM METAL or aluminium continuous hydrogen production, it is characterized in that: comprise the following steps:
1., first to make the feed liquid being easy to pumping be precondition magnesium powder or aluminium powder and glycerol being mixed in proportion, store battery two output electrodes and power supply system are supplied to be electrically connected, power supply system detects each alarm sensor circuit, give intelligent control unit and each pump after alarm free, valve powers, have Alarm Disable to power;
2., service pump (B is started by intelligent control unit
2) inject alkali lye in reactor (1), start peristaltic pump (B simultaneously
1) magnesium powder or aluminium powder and glycerol are mixed in proportion the suspension feed liquid material made are injected in reactor, start hydrogen gas circulating pump (B simultaneously
3), start cooling water circulating pump to the interchanger outside reactor, hot-water system (6) water filling simultaneously, prepare to lower the temperature to reactor;
3. as reactor exhaust solenoid valve (F
1) after time-delay closing, by the first pressure transmitter (Y
1) detection reaction device internal pressure value, when reactor pressure rises on prescribed value, reactor starts to hydrogen fuel cell (4) for hydrogen, a hydrogen fuel cell generating part charges a battery, another part is powered to power supply system, some to mains-supplied, checks the material box liquid level sensor (S in MAGNESIUM METAL material box (3) through DC-AC inversion system simultaneously
5) whether reach lower value, check the lye tank liquid level sensor (S in lye tank (2)
4) whether reach lower value, check the tailing case liquid level sensor (S in tailing case (5)
3) whether reach higher limit, reach alarm, and time delay stops service pump (B
2), peristaltic pump (B
1) transport; When reactor pressure is increased beyond safety value, positive opening reactor exhaust solenoid valve (F
1); When reactor pressure drops under prescribed value, then by upper liquid level sensor (S
1), lower liquid level sensor (S
2) check in reactor, whether liquid level declines, and is to decline, and starts service pump (B
2) inject normal-temperature water in reactor (1), start peristaltic pump (B simultaneously
1) be injected in reactor by advance magnesium powder or aluminium powder and glycerol being mixed in proportion the suspension feed liquid material made in MAGNESIUM METAL or aluminum feedstock case (3), by timing register to the time timing of peristaltic pump material loading, material loading time-out starts the driven spherical valve (F under reactor
2) to tailing case (5) discharge, open the hydrogen gas circulating pump (B be connected with tailing case first
3) and vent valve (F
4) to air pump drainage air and time-delay closing, again open the hydrogen gas circulating pump (B be connected with tailing case
3), in reactor, inject hydrogen by the pipeline extended at the bottom of reactor; When liquid level in reactor drops to lower liquid level sensor (S
2) under in limited time, the driven spherical valve (F below off-response device
2), check the second pressure transmitter (Y on tailing case simultaneously
2), when pressure is greater than higher limit, open the hydrogen gas circulating pump (B be connected with tailing case
3), in reactor, inject hydrogen by the pipeline extended at the bottom of reactor; When pressure is less than lower value, close the hydrogen gas circulating pump (B be connected with tailing case
3);
4., when dropping to lower liquid level sensor (S by liquid level in inspection reactor
2) in limited time upper, by timer initiation peristaltic pump (B
1) in reactor, inject magnesium powder or aluminium powder and glycerol be mixed in proportion the suspension feed liquid material made, close service pump (B simultaneously
2), stop injecting alkali lye in reactor; When not dropping to lower liquid level sensor (S by liquid level in inspection reactor
2) in limited time upper, start service pump (B
2), inject alkali lye in reactor;
5., when finding that reactor temperature exceedes prescribed value by hot-water system (6), starting warning circuit, and stopping service pump (B
2), peristaltic pump (B
1) operation, start cooling water circulating pump simultaneously.
2. the specific equipment of the cogeneration technology of employing MAGNESIUM METAL according to claim 1 or aluminium continuous hydrogen production, is characterized in that: comprise reactor (1), lye tank (2), MAGNESIUM METAL or aluminum feedstock case (3), hydrogen fuel cell (4), tailing case (5), hot-water system (6), peristaltic pump (B
1), service pump (B
2), hydrogen gas circulating pump (B
3), exhaust solenoid valve (F
1), driven spherical valve (F
2), the first magnetic valve (F
3), vent valve (F
4), the second magnetic valve (F
5), aqueous vapor is separated water discharge valve (F
6), the first pressure transmitter (Y
1), the second pressure transmitter (Y
2), upper liquid level sensor (S
1), lower liquid level sensor (S
2), tailing case liquid level sensor (S
3), lye tank liquid level sensor (S
4), material box liquid level sensor (S
5), intelligent control unit, described reactor is an encloses container, is provided with liquid level sensor (S in described reactor
1) and lower liquid level sensor (S
2), described reactor head is by pipeline, service pump (B
2) be connected with lye tank (2) feed flow, described reactor head is by pipeline, peristaltic pump (B
1) be connected with MAGNESIUM METAL or aluminum feedstock case (3) feed, described reactor head is separated water discharge valve (F by pipeline, aqueous vapor
6), the first pressure transmitter (Y
1), exhaust solenoid valve (F
1), the second magnetic valve (F
5) be connected with hydrogen fuel cell (4) air feed, described reactor head has one to extend to pipeline at the bottom of reactor, and described reactor bottom is by pipeline, driven spherical valve (F
2) be connected with tailing case (5) discharge, described tailing case is a sealed vessel, and described tailing case is by pipeline, the second pressure transmitter (Y
2), the first magnetic valve (F
3), hydrogen gas circulating pump (B
3), vent valve (F
4) be connected with the pipeline that one of reactor head extends at the bottom of reactor, an interchanger is had outside described reactor, described interchanger supplies hot tie-in by pipeline and hot-water system, is provided with material box liquid level sensor (S in described MAGNESIUM METAL or aluminum feedstock case (3)
5), be provided with lye tank liquid level sensor (S in described lye tank (2)
4), be provided with tailing case liquid level sensor (S in described tailing case (5)
3), described exhaust solenoid valve (F
1), driven spherical valve (F
2), the first magnetic valve (F
3), vent valve (F
4), the second magnetic valve (F
5), aqueous vapor is separated water discharge valve (F
6), the first pressure transmitter (Y
1), the second pressure transmitter (Y
2), upper liquid level sensor (S
1), lower liquid level sensor (S
2), tailing case liquid level sensor (S
3), lye tank liquid level sensor (S
4), material box liquid level sensor (S
5) and intelligent control unit control linkage.
3. the specific equipment of the cogeneration technology of employing MAGNESIUM METAL according to claim 2 or aluminium continuous hydrogen production, is characterized in that: described peristaltic pump (B
1) also can adopt spiral pump.
4. the specific equipment of the cogeneration technology of employing MAGNESIUM METAL according to claim 2 or aluminium continuous hydrogen production, is characterized in that: described intelligent control unit can adopt micro-chip, computer, thermoelectricity to connect for the one in switchboard.
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| US10088398B2 (en) | 2015-02-11 | 2018-10-02 | Emd Millipore Corporation | Stirred cell and method of using same |
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| CN109795985A (en) * | 2017-11-16 | 2019-05-24 | 银隆新能源股份有限公司 | Circulating renewable energy hydrolytic hydrogen production system and method based on aluminium energy storage |
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