CN1255479A - 烯烃混合物经两段加氢甲酰化制备高级羰基合成醇的方法 - Google Patents
烯烃混合物经两段加氢甲酰化制备高级羰基合成醇的方法 Download PDFInfo
- Publication number
- CN1255479A CN1255479A CN99118863A CN99118863A CN1255479A CN 1255479 A CN1255479 A CN 1255479A CN 99118863 A CN99118863 A CN 99118863A CN 99118863 A CN99118863 A CN 99118863A CN 1255479 A CN1255479 A CN 1255479A
- Authority
- CN
- China
- Prior art keywords
- mixture
- hydrogenation
- hydroformylation
- catalyst
- arbitrary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Abstract
Description
1 | 2 | 3 |
C8异构体 | 实施例1和2二-n-丁烯原料(%重量) | 实施例3C8烯烃混合物原料(%重量) |
二甲基己烯 | 23 | 44 |
3-甲基庚烯 | 62 | 51 |
正辛烯 | 15 | 5 |
1 | 2 | 3 | 4 |
根据气相色谱分析的组成 | 实施例1(%重量) | 实施例2(%重量) | 实施例3(%重量) |
C8烯烃 | 6.2 | 27.4 | 7.0 |
C8链烷烃 | 3.3 | 2.4 | 4.5 |
异壬醛 | 55.1 | 48.7 | 51.2 |
酯/甲酸异壬基酯 | 4.5 | 2.0 | 8.8 |
异壬醇 | 23.9 | 18.5 | 18.8 |
残余物 | 7.0 | 1.0 | 9.8 |
Claims (20)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19842368A DE19842368A1 (de) | 1998-09-16 | 1998-09-16 | Verfahren zur Herstellung von höheren Oxoalkoholen aus Olefingemischen durch zweistufige Hydroformylierung |
DE19842368.3 | 1998-09-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1255479A true CN1255479A (zh) | 2000-06-07 |
CN1170800C CN1170800C (zh) | 2004-10-13 |
Family
ID=7881137
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB991188632A Expired - Fee Related CN1170800C (zh) | 1998-09-16 | 1999-09-15 | 烯烃混合物经两段加氢甲酰化制备高级羰基合成醇的方法 |
Country Status (18)
Country | Link |
---|---|
US (1) | US6331657B1 (zh) |
EP (1) | EP0987243B1 (zh) |
JP (1) | JP2000095717A (zh) |
KR (1) | KR100618929B1 (zh) |
CN (1) | CN1170800C (zh) |
AR (1) | AR020446A1 (zh) |
AT (1) | ATE228989T1 (zh) |
BR (1) | BR9904166A (zh) |
CA (1) | CA2282148A1 (zh) |
DE (2) | DE19842368A1 (zh) |
ES (1) | ES2185283T3 (zh) |
ID (1) | ID23134A (zh) |
MY (1) | MY126454A (zh) |
PL (1) | PL335432A1 (zh) |
RO (1) | RO120904B1 (zh) |
SG (1) | SG88756A1 (zh) |
TW (1) | TWI252225B (zh) |
ZA (1) | ZA995926B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100389875C (zh) * | 2006-07-14 | 2008-05-28 | 谷育英 | 一种用于裂解c8馏分加氢反应催化剂及其制备方法和用途 |
CN106164031A (zh) * | 2013-12-13 | 2016-11-23 | 赢创德固赛有限公司 | 利用气体循环和silp技术的两阶段加氢甲酰化 |
CN116063155A (zh) * | 2021-10-29 | 2023-05-05 | 中国石油化工股份有限公司 | 一种烯烃氢甲酰化反应制备醇的方法 |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10034360A1 (de) * | 2000-07-14 | 2002-01-24 | Oxeno Olefinchemie Gmbh | Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen |
DE10058383A1 (de) * | 2000-11-24 | 2002-05-29 | Oxeno Olefinchemie Gmbh | Neue Phosphininverbindungen und deren Metallkomplexe |
DE10062448A1 (de) | 2000-12-14 | 2002-06-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydrierung von Hydroformylierungsgemischen |
DE10135906A1 (de) | 2001-07-24 | 2003-02-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von höheren Olefinen mit Kobaltverbindungen als Katalysator |
US6774275B2 (en) * | 2001-08-21 | 2004-08-10 | Catalytic Distillation Technologies | Pulse flow reaction |
WO2003029180A1 (de) * | 2001-09-26 | 2003-04-10 | Oxeno Olefinchemie Gmbh | Phthalsäurealkylestergemische mit kontrollierter viskosität |
DE10149348A1 (de) | 2001-10-06 | 2003-04-10 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen |
DE10210918B4 (de) | 2002-03-13 | 2004-06-03 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Bisphosphiten |
US6960699B2 (en) | 2002-03-15 | 2005-11-01 | Oxeno Olefinchemie Gmbh | Method for the hydroformylation of olefins |
DE10220801A1 (de) * | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
DE10223593A1 (de) * | 2002-05-27 | 2003-12-11 | Degussa | Hydroxydiphosphine und deren Verwendung in der Katalyse |
DE10225565A1 (de) | 2002-06-10 | 2003-12-18 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen |
DE10327434A1 (de) * | 2002-08-31 | 2004-03-04 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von olefinisch ungesättigten Verbindungen, insbesondere Olefinen in Gegenwart cyclischer Kohlensäureester |
WO2004020380A1 (de) | 2002-08-31 | 2004-03-11 | Oxeno Olefinchemie Gmbh | Verfahren zur hydroformylierung von olefinisch ungesättigten verbindungen, insbesondere olefinen in gegenwart cyclischer kohlensäureester |
US7193116B2 (en) | 2002-08-31 | 2007-03-20 | Oxeno Olefinchemie Gmbh | Method for producing aldehydes by means of hydroformylation of olefinically unsaturated compounds, said hydroformylation being catalyzed by unmodified metal complexes in the presence of cyclic carbonic acid esters |
DE10257499A1 (de) | 2002-12-10 | 2004-07-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen |
DE10329042A1 (de) * | 2003-06-27 | 2005-01-13 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Octen aus Crack-C4 |
US6982355B2 (en) * | 2003-08-25 | 2006-01-03 | Syntroleum Corporation | Integrated Fischer-Tropsch process for production of linear and branched alcohols and olefins |
DE10359628A1 (de) * | 2003-12-18 | 2005-07-21 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Herstellung von 1-Olefinen aus 2-Hydroxyalkanen |
DE10360771A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen |
DE10360772A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Organoacylphosphiten |
DE102004033410A1 (de) * | 2004-02-14 | 2005-09-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen |
DE102004013514A1 (de) * | 2004-03-19 | 2005-10-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen |
DE102004021128A1 (de) * | 2004-04-29 | 2005-11-24 | Oxeno Olefinchemie Gmbh | Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator |
US7208646B2 (en) * | 2004-05-14 | 2007-04-24 | Catalytic Distillation Technologies | Selective hydrogenation of butadiene |
DE102005036039A1 (de) | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 2,7-Octadienylderivaten |
DE102004059292A1 (de) | 2004-12-09 | 2006-06-14 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung |
DE102004059293A1 (de) | 2004-12-09 | 2006-06-14 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen |
DE102004063673A1 (de) * | 2004-12-31 | 2006-07-13 | Oxeno Olefinchemie Gmbh | Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas |
DE102005014055A1 (de) * | 2005-03-23 | 2006-09-28 | Degussa Ag | Unsymmetrisch substituierte Phospholankatalysatoren |
DE102005035816A1 (de) * | 2005-07-30 | 2007-02-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten |
DE102005042464A1 (de) * | 2005-09-07 | 2007-03-08 | Oxeno Olefinchemie Gmbh | Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen |
DE102006058682A1 (de) * | 2006-12-13 | 2008-06-19 | Evonik Oxeno Gmbh | Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung |
DE102008007080A1 (de) | 2008-01-31 | 2009-08-06 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von C9-Alkohol aus C8-Olefinen |
WO2009124979A1 (de) * | 2008-04-10 | 2009-10-15 | Basf Se | C17-alkoholgemisch |
DE102008002188A1 (de) * | 2008-06-03 | 2009-12-10 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung |
US8598390B2 (en) | 2009-12-22 | 2013-12-03 | Dow Technology Investments Llc | Controlling the normal:ISO aldehyde ratio in a mixed ligand hydroformylation process |
CN104725170B (zh) * | 2013-12-19 | 2019-08-23 | 陶氏技术投资有限责任公司 | 加氢甲酰化方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1935900C3 (de) * | 1969-07-15 | 1975-03-13 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Entfernung von Aldehyden und Ketonen aus Kohlenmonoxid enthaltenden Gasströmen |
JPS5841830A (ja) * | 1981-09-07 | 1983-03-11 | Nissan Chem Ind Ltd | オキソ法によるアルコ−ルの製造方法 |
DE3245883A1 (de) * | 1982-12-11 | 1984-06-14 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur hydroformylierung von olefinen |
GB8430223D0 (en) * | 1984-11-30 | 1985-01-09 | Exxon Research Engineering Co | Hydroformylation of olefins |
DE3803464A1 (de) * | 1988-02-05 | 1989-08-17 | Huels Chemische Werke Ag | Verfahren zur herstellung von 2-ethylhexanol durch hydrierung von 2-ethylhexenal in der fluessigphase und katalysator zu seiner herstellung |
DE19524969A1 (de) | 1995-07-08 | 1997-01-09 | Huels Chemische Werke Ag | Verfahren zur Herstellung von 3.3.5-Trimethylcyclohexanon |
DE19524970A1 (de) | 1995-07-08 | 1997-01-09 | Huels Chemische Werke Ag | Verfahren zur Herstellung von 2-Ethylhexanal |
DE19524971A1 (de) | 1995-07-08 | 1997-01-09 | Huels Chemische Werke Ag | Verfahren zur katalytischen Selektivhydrierung von mehrfach ungesättigten organischen Substanzen |
DE19654340A1 (de) * | 1996-12-24 | 1998-08-06 | Huels Chemische Werke Ag | Verfahren zur Herstellung von höheren Oxo-Alkoholen |
-
1998
- 1998-09-16 DE DE19842368A patent/DE19842368A1/de not_active Withdrawn
-
1999
- 1999-05-25 ID IDP990489A patent/ID23134A/id unknown
- 1999-06-22 TW TW088110454A patent/TWI252225B/zh not_active IP Right Cessation
- 1999-07-31 ES ES99115272T patent/ES2185283T3/es not_active Expired - Lifetime
- 1999-07-31 DE DE59903635T patent/DE59903635D1/de not_active Expired - Fee Related
- 1999-07-31 EP EP99115272A patent/EP0987243B1/de not_active Expired - Lifetime
- 1999-07-31 AT AT99115272T patent/ATE228989T1/de not_active IP Right Cessation
- 1999-09-10 SG SG9904462A patent/SG88756A1/en unknown
- 1999-09-13 JP JP11258860A patent/JP2000095717A/ja active Pending
- 1999-09-14 CA CA002282148A patent/CA2282148A1/en not_active Abandoned
- 1999-09-14 KR KR1019990039213A patent/KR100618929B1/ko not_active IP Right Cessation
- 1999-09-15 ZA ZA9905926A patent/ZA995926B/xx unknown
- 1999-09-15 CN CNB991188632A patent/CN1170800C/zh not_active Expired - Fee Related
- 1999-09-15 PL PL99335432A patent/PL335432A1/xx unknown
- 1999-09-15 BR BR9904166-9A patent/BR9904166A/pt not_active IP Right Cessation
- 1999-09-15 AR ARP990104618A patent/AR020446A1/es active IP Right Grant
- 1999-09-15 MY MYPI99003994A patent/MY126454A/en unknown
- 1999-09-15 US US09/396,371 patent/US6331657B1/en not_active Expired - Fee Related
- 1999-09-16 RO RO99-00987A patent/RO120904B1/ro unknown
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100389875C (zh) * | 2006-07-14 | 2008-05-28 | 谷育英 | 一种用于裂解c8馏分加氢反应催化剂及其制备方法和用途 |
CN106164031A (zh) * | 2013-12-13 | 2016-11-23 | 赢创德固赛有限公司 | 利用气体循环和silp技术的两阶段加氢甲酰化 |
CN106164031B (zh) * | 2013-12-13 | 2018-01-19 | 赢创德固赛有限公司 | 利用气体循环和silp技术的两阶段加氢甲酰化 |
CN116063155A (zh) * | 2021-10-29 | 2023-05-05 | 中国石油化工股份有限公司 | 一种烯烃氢甲酰化反应制备醇的方法 |
Also Published As
Publication number | Publication date |
---|---|
RO120904B1 (ro) | 2006-09-29 |
MY126454A (en) | 2006-10-31 |
PL335432A1 (en) | 2000-03-27 |
ATE228989T1 (de) | 2002-12-15 |
ES2185283T3 (es) | 2003-04-16 |
SG88756A1 (en) | 2002-05-21 |
DE59903635D1 (de) | 2003-01-16 |
AR020446A1 (es) | 2002-05-15 |
US6331657B1 (en) | 2001-12-18 |
JP2000095717A (ja) | 2000-04-04 |
KR100618929B1 (ko) | 2006-09-01 |
BR9904166A (pt) | 2000-09-19 |
KR20000023121A (ko) | 2000-04-25 |
CA2282148A1 (en) | 2000-03-16 |
ID23134A (id) | 2000-03-15 |
CN1170800C (zh) | 2004-10-13 |
DE19842368A1 (de) | 2000-03-23 |
TWI252225B (en) | 2006-04-01 |
ZA995926B (en) | 2000-04-04 |
EP0987243B1 (de) | 2002-12-04 |
EP0987243A1 (de) | 2000-03-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1170800C (zh) | 烯烃混合物经两段加氢甲酰化制备高级羰基合成醇的方法 | |
RU2249587C2 (ru) | Способ получения высших оксоспиртов из смесей олефинов | |
CN1165504C (zh) | 加氢甲酰化混合物的选择氢化方法 | |
KR100799476B1 (ko) | 프로필렌의 최대 생산을 위한 c4 올레핀 스트림의처리방법 | |
KR101272392B1 (ko) | 올레핀 이성질화 및 복분해 촉매 | |
JP4214474B2 (ja) | C4オレフィン流からプロピレン及びヘキセンを製造する方法 | |
CN100445253C (zh) | 烯烃醛化方法 | |
US9682898B2 (en) | Oligomerization of C4 streams with very low 1 butene content | |
US6627782B2 (en) | Preparation of 1-olefins | |
CA2364826A1 (en) | Process for the hydrogenation of hydroformylation mixtures | |
CN1333201A (zh) | 羰基合成醛和/或醇的多级制备方法 | |
EP2376405A1 (en) | Process for obtaining high-purity 1-butene from c4 hydrocarbon mixtures | |
CN101104572A (zh) | 用于制备3-甲基丁-1-烯的方法 | |
CN1914138A (zh) | 制备包含8~12个碳原子的烯烃的方法 | |
AU782627B2 (en) | Process for the selective preparation of DIB from I-butene-containing C4 stream | |
CN1547563A (zh) | 通过联合异构化易位和异构化烷基转移来合成端烯烃的方法 | |
US20060173223A1 (en) | Method of increasing the carbon chain length of olefinic compounds | |
MXPA99008458A (es) | Procedimiento para la elaboracion de oxo-alcoholes superiores a partir de mezclas olefinicas porhidroformilacion en dos etapas | |
EP1942090B1 (en) | Process for the production of hexene-1 and ethylene | |
MXPA99008459A (en) | Procedure for obtaining oxo-alcohol superior from olef mixtures | |
CZ326699A3 (cs) | Způsob výroby vyšších oxoalkoholů ze směsí olefinů | |
MXPA99008457A (en) | Procedure for selective hydrogenation of hydroformilac mixtures | |
CZ326799A3 (cs) | Způsob výroby vyšších oxoalkoholů ze směsí olefmů pomocí dvoustupňové hydroformylace |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT INVENTOR; FROM: A. KAZIC; B. SHALTZ; W. DUTSCH; BUESCHKEN W.; F NEIL ULLRICH; TO: A. KAZIC;B. SHALTZ; W. DUTSCH; BUESCHKEN W.; F NEIL ULLRICH; ROETTGER DIRK; CRAUSE D WEISS Effective date: 20010629 |
|
TA01 | Transfer of patent application right |
Effective date of registration: 20010629 Inventor after: A.Kazick Inventor after: B.Shores Inventor after: W.Totsch Inventor after: W.Bishgen Inventor after: F.Neilrich Inventor after: D.Rotje Claus Inventor after: D.Weiss Inventor before: A.Kazick Inventor before: B.Shores Inventor before: W.Totsch Inventor before: W.Bishgen Inventor before: F.Neilrich |
|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |