CN1300185C - 含有异丁烯型单体交替共聚物的热固性组合物 - Google Patents
含有异丁烯型单体交替共聚物的热固性组合物 Download PDFInfo
- Publication number
- CN1300185C CN1300185C CNB038050501A CN03805050A CN1300185C CN 1300185 C CN1300185 C CN 1300185C CN B038050501 A CNB038050501 A CN B038050501A CN 03805050 A CN03805050 A CN 03805050A CN 1300185 C CN1300185 C CN 1300185C
- Authority
- CN
- China
- Prior art keywords
- composition
- acid
- monomer
- multipolymer
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 408
- 239000000178 monomer Substances 0.000 title claims abstract description 259
- 229920001187 thermosetting polymer Polymers 0.000 title claims abstract description 123
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 229920005603 alternating copolymer Polymers 0.000 title description 17
- 229920001577 copolymer Polymers 0.000 claims abstract description 103
- 125000000524 functional group Chemical group 0.000 claims abstract description 99
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 claims abstract description 84
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000007788 liquid Substances 0.000 claims abstract description 49
- 239000002841 Lewis acid Substances 0.000 claims abstract description 16
- 150000007517 lewis acids Chemical class 0.000 claims abstract description 16
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 16
- 150000003624 transition metals Chemical class 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims description 88
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 75
- -1 maleic acid ester Chemical class 0.000 claims description 74
- 239000000126 substance Substances 0.000 claims description 74
- 239000003795 chemical substances by application Substances 0.000 claims description 73
- 229920005989 resin Polymers 0.000 claims description 58
- 239000011347 resin Substances 0.000 claims description 58
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 35
- 239000005056 polyisocyanate Substances 0.000 claims description 34
- 229920001228 polyisocyanate Polymers 0.000 claims description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 31
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 31
- 150000002148 esters Chemical class 0.000 claims description 31
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 30
- 239000002253 acid Substances 0.000 claims description 27
- 239000012855 volatile organic compound Substances 0.000 claims description 24
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 22
- 229910052799 carbon Inorganic materials 0.000 claims description 22
- 239000004593 Epoxy Substances 0.000 claims description 20
- 229920001451 polypropylene glycol Polymers 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 13
- 150000001721 carbon Chemical group 0.000 claims description 13
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 12
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 11
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 10
- 150000001408 amides Chemical class 0.000 claims description 10
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 10
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000012948 isocyanate Substances 0.000 claims description 9
- 150000002513 isocyanates Chemical class 0.000 claims description 9
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 9
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 claims description 8
- 125000005442 diisocyanate group Chemical group 0.000 claims description 8
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 7
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 claims description 7
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 6
- 239000011976 maleic acid Substances 0.000 claims description 6
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 claims description 6
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 claims description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical group [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 5
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims description 5
- 239000013638 trimer Substances 0.000 claims description 5
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 5
- AKABKVXLWWIVIW-UHFFFAOYSA-N 1,1-diisocyanatohexane Chemical compound CCCCCC(N=C=O)N=C=O AKABKVXLWWIVIW-UHFFFAOYSA-N 0.000 claims description 4
- PFSWSMIOAKYXAH-UHFFFAOYSA-N 1-(1,2-dihydroxyethoxy)ethane-1,2-diol Chemical compound OCC(O)OC(O)CO PFSWSMIOAKYXAH-UHFFFAOYSA-N 0.000 claims description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical class C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 4
- 125000004494 ethyl ester group Chemical group 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- WHIVNJATOVLWBW-SNAWJCMRSA-N methylethyl ketone oxime Chemical compound CC\C(C)=N\O WHIVNJATOVLWBW-SNAWJCMRSA-N 0.000 claims description 4
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical group CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical group S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 3
- 125000005376 alkyl siloxane group Chemical group 0.000 claims description 3
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 claims description 3
- 238000007046 ethoxylation reaction Methods 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 125000004407 fluoroaryl group Chemical group 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
- ARZLUCYKIWYSHR-UHFFFAOYSA-N hydroxymethoxymethanol Chemical compound OCOCO ARZLUCYKIWYSHR-UHFFFAOYSA-N 0.000 claims description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 3
- UGVYTRVYOYKZSO-UHFFFAOYSA-N n-butoxy-2-methylprop-2-enamide Chemical compound CCCCONC(=O)C(C)=C UGVYTRVYOYKZSO-UHFFFAOYSA-N 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical group 0.000 claims description 3
- 150000003568 thioethers Chemical group 0.000 claims description 3
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 2
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
- 125000000304 alkynyl group Chemical group 0.000 claims description 2
- 229910052728 basic metal Inorganic materials 0.000 claims description 2
- 150000003818 basic metals Chemical class 0.000 claims description 2
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 2
- UTSYWKJYFPPRAP-UHFFFAOYSA-N n-(butoxymethyl)prop-2-enamide Chemical compound CCCCOCNC(=O)C=C UTSYWKJYFPPRAP-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims 4
- 150000003851 azoles Chemical class 0.000 claims 4
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims 2
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 claims 2
- YFVKHKCZBSGZPE-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-2-(propylamino)propan-1-one Chemical compound CCCNC(C)C(=O)C1=CC=C2OCOC2=C1 YFVKHKCZBSGZPE-UHFFFAOYSA-N 0.000 claims 1
- SNTWKPAKVQFCCF-UHFFFAOYSA-N 2,3-dihydro-1h-triazole Chemical compound N1NC=CN1 SNTWKPAKVQFCCF-UHFFFAOYSA-N 0.000 claims 1
- DPNXHTDWGGVXID-UHFFFAOYSA-N 2-isocyanatoethyl prop-2-enoate Chemical compound C=CC(=O)OCCN=C=O DPNXHTDWGGVXID-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 95
- 238000004070 electrodeposition Methods 0.000 abstract description 23
- 239000000843 powder Substances 0.000 abstract description 19
- 239000003431 cross linking reagent Substances 0.000 abstract 2
- 239000002994 raw material Substances 0.000 description 224
- 238000000576 coating method Methods 0.000 description 177
- 239000011248 coating agent Substances 0.000 description 156
- 239000011541 reaction mixture Substances 0.000 description 78
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 67
- 229920000642 polymer Polymers 0.000 description 57
- 239000008199 coating composition Substances 0.000 description 56
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 52
- 238000006243 chemical reaction Methods 0.000 description 50
- 230000015572 biosynthetic process Effects 0.000 description 49
- 238000012360 testing method Methods 0.000 description 44
- 238000006116 polymerization reaction Methods 0.000 description 42
- 239000000758 substrate Substances 0.000 description 42
- 238000003756 stirring Methods 0.000 description 41
- 239000000049 pigment Substances 0.000 description 39
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 38
- 230000008569 process Effects 0.000 description 36
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 35
- 238000001816 cooling Methods 0.000 description 33
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 29
- 239000007789 gas Substances 0.000 description 29
- 239000000463 material Substances 0.000 description 29
- 239000008367 deionised water Substances 0.000 description 28
- 229910021641 deionized water Inorganic materials 0.000 description 28
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 28
- 229910052757 nitrogen Inorganic materials 0.000 description 28
- 238000005502 peroxidation Methods 0.000 description 28
- 238000002360 preparation method Methods 0.000 description 27
- 238000001228 spectrum Methods 0.000 description 27
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 26
- 239000006185 dispersion Substances 0.000 description 25
- 239000002904 solvent Substances 0.000 description 25
- 239000000654 additive Substances 0.000 description 22
- 239000010935 stainless steel Substances 0.000 description 22
- 229910001220 stainless steel Inorganic materials 0.000 description 22
- 230000000996 additive effect Effects 0.000 description 21
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 20
- 239000002987 primer (paints) Substances 0.000 description 19
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 18
- 239000003973 paint Substances 0.000 description 17
- 229910000831 Steel Inorganic materials 0.000 description 16
- 239000002131 composite material Substances 0.000 description 16
- 239000003999 initiator Substances 0.000 description 16
- 239000010959 steel Substances 0.000 description 16
- 238000003786 synthesis reaction Methods 0.000 description 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 15
- 239000002585 base Substances 0.000 description 14
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 14
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- 239000012071 phase Substances 0.000 description 13
- 239000002002 slurry Substances 0.000 description 13
- 238000005507 spraying Methods 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- 239000000376 reactant Substances 0.000 description 12
- 238000000151 deposition Methods 0.000 description 11
- 230000008021 deposition Effects 0.000 description 11
- 238000001035 drying Methods 0.000 description 11
- 238000007701 flash-distillation Methods 0.000 description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 10
- 239000004744 fabric Substances 0.000 description 10
- 150000003839 salts Chemical group 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- 239000004925 Acrylic resin Substances 0.000 description 9
- 229920000178 Acrylic resin Polymers 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000004132 cross linking Methods 0.000 description 9
- 235000019439 ethyl acetate Nutrition 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 230000000704 physical effect Effects 0.000 description 9
- 150000003254 radicals Chemical class 0.000 description 9
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 8
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 229920003180 amino resin Polymers 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 8
- 239000010445 mica Substances 0.000 description 8
- 229910052618 mica group Inorganic materials 0.000 description 8
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 8
- 238000010992 reflux Methods 0.000 description 8
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 7
- 229920000877 Melamine resin Polymers 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 7
- 230000037452 priming Effects 0.000 description 7
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 6
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 238000007334 copolymerization reaction Methods 0.000 description 6
- 239000012972 dimethylethanolamine Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 6
- GPUKMTQLSWHBLZ-UHFFFAOYSA-N 1-phenyltridecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCC(S(O)(=O)=O)C1=CC=CC=C1 GPUKMTQLSWHBLZ-UHFFFAOYSA-N 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 150000001768 cations Chemical group 0.000 description 5
- 239000004567 concrete Substances 0.000 description 5
- 230000002950 deficient Effects 0.000 description 5
- 238000007590 electrostatic spraying Methods 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 125000003010 ionic group Chemical group 0.000 description 5
- 230000014759 maintenance of location Effects 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 150000002894 organic compounds Chemical class 0.000 description 5
- 150000002924 oxiranes Chemical group 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- 125000000746 allylic group Chemical group 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000010560 atom transfer radical polymerization reaction Methods 0.000 description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical class CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 238000005097 cold rolling Methods 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 4
- 238000009925 jellying Methods 0.000 description 4
- 150000002576 ketones Chemical class 0.000 description 4
- 239000004310 lactic acid Substances 0.000 description 4
- 235000014655 lactic acid Nutrition 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000008399 tap water Substances 0.000 description 4
- 235000020679 tap water Nutrition 0.000 description 4
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- BPIUIOXAFBGMNB-UHFFFAOYSA-N 1-hexoxyhexane Chemical compound CCCCCCOCCCCCC BPIUIOXAFBGMNB-UHFFFAOYSA-N 0.000 description 3
- LHENQXAPVKABON-UHFFFAOYSA-N 1-methoxypropan-1-ol Chemical compound CCC(O)OC LHENQXAPVKABON-UHFFFAOYSA-N 0.000 description 3
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 3
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 3
- RUDMCWOFBGNJTR-UHFFFAOYSA-N C(C)C(C(=O)O)CCCC.C(C)(C)(CC)OOC(C)(C)CC Chemical compound C(C)C(C(=O)O)CCCC.C(C)(C)(CC)OOC(C)(C)CC RUDMCWOFBGNJTR-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 239000005058 Isophorone diisocyanate Substances 0.000 description 3
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 description 3
- 229920002732 Polyanhydride Polymers 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 230000007547 defect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- DOMLXBPXLNDFAB-UHFFFAOYSA-N ethoxyethane;methyl prop-2-enoate Chemical compound CCOCC.COC(=O)C=C DOMLXBPXLNDFAB-UHFFFAOYSA-N 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 3
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 3
- 229920001427 mPEG Polymers 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 description 3
- GTCAXTIRRLKXRU-UHFFFAOYSA-N methyl carbamate Chemical compound COC(N)=O GTCAXTIRRLKXRU-UHFFFAOYSA-N 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- 239000007870 radical polymerization initiator Substances 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 239000000341 volatile oil Substances 0.000 description 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- OELQSSWXRGADDE-UHFFFAOYSA-N 2-methylprop-2-eneperoxoic acid Chemical compound CC(=C)C(=O)OO OELQSSWXRGADDE-UHFFFAOYSA-N 0.000 description 2
- NDAJNMAAXXIADY-UHFFFAOYSA-N 2-methylpropanimidamide Chemical compound CC(C)C(N)=N NDAJNMAAXXIADY-UHFFFAOYSA-N 0.000 description 2
- XRUKRHLZDVJJSX-UHFFFAOYSA-N 4-cyanopentanoic acid Chemical compound N#CC(C)CCC(O)=O XRUKRHLZDVJJSX-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000005233 alkylalcohol group Chemical group 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 229940043232 butyl acetate Drugs 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- WIHMDCQAEONXND-UHFFFAOYSA-M butyl-hydroxy-oxotin Chemical compound CCCC[Sn](O)=O WIHMDCQAEONXND-UHFFFAOYSA-M 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- CJOBVZJTOIVNNF-UHFFFAOYSA-N cadmium sulfide Chemical compound [Cd]=S CJOBVZJTOIVNNF-UHFFFAOYSA-N 0.000 description 2
- 229960000846 camphor Drugs 0.000 description 2
- 229930008380 camphor Natural products 0.000 description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 239000010883 coal ash Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000006184 cosolvent Substances 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000004434 industrial solvent Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 230000003902 lesion Effects 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 2
- 229910001507 metal halide Inorganic materials 0.000 description 2
- JQKFLNWRTBPECK-UHFFFAOYSA-N methoxymethane;propane-1,2-diol Chemical compound COC.CC(O)CO JQKFLNWRTBPECK-UHFFFAOYSA-N 0.000 description 2
- REOJLIXKJWXUGB-UHFFFAOYSA-N mofebutazone Chemical group O=C1C(CCCC)C(=O)NN1C1=CC=CC=C1 REOJLIXKJWXUGB-UHFFFAOYSA-N 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- 239000001327 prunus amygdalus amara l. extract Substances 0.000 description 2
- 239000012966 redox initiator Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 239000013008 thixotropic agent Substances 0.000 description 2
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical class [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 238000005491 wire drawing Methods 0.000 description 2
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 2
- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- QLLUAUADIMPKIH-UHFFFAOYSA-N 1,2-bis(ethenyl)naphthalene Chemical compound C1=CC=CC2=C(C=C)C(C=C)=CC=C21 QLLUAUADIMPKIH-UHFFFAOYSA-N 0.000 description 1
- CRRUGYDDEMGVDY-UHFFFAOYSA-N 1-bromoethylbenzene Chemical compound CC(Br)C1=CC=CC=C1 CRRUGYDDEMGVDY-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical class CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- RCEJCSULJQNRQQ-UHFFFAOYSA-N 2-methylbutanenitrile Chemical compound CCC(C)C#N RCEJCSULJQNRQQ-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- DUJMVKJJUANUMQ-UHFFFAOYSA-N 4-methylpentanenitrile Chemical compound CC(C)CCC#N DUJMVKJJUANUMQ-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000532370 Atla Species 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- GTJVPLGQFHDOAC-UHFFFAOYSA-N C(C(=O)O)(=O)O.C(CCCCCCC)[Sn]CCCCCCCC Chemical compound C(C(=O)O)(=O)O.C(CCCCCCC)[Sn]CCCCCCCC GTJVPLGQFHDOAC-UHFFFAOYSA-N 0.000 description 1
- OYODMWWQEZNGIS-UHFFFAOYSA-L C(O)C(CC)(CO)CO.C(CCCCCCCCCCC)(=O)[O-].C(CCC)[Sn+2]CCCC.C(CCCCCCCCCCC)(=O)[O-] Chemical compound C(O)C(CC)(CO)CO.C(CCCCCCCCCCC)(=O)[O-].C(CCC)[Sn+2]CCCC.C(CCCCCCCCCCC)(=O)[O-] OYODMWWQEZNGIS-UHFFFAOYSA-L 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102100026735 Coagulation factor VIII Human genes 0.000 description 1
- 229910021589 Copper(I) bromide Inorganic materials 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- 229920013685 Estron Polymers 0.000 description 1
- DNXHEGUUPJUMQT-CBZIJGRNSA-N Estrone Chemical compound OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 DNXHEGUUPJUMQT-CBZIJGRNSA-N 0.000 description 1
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910001335 Galvanized steel Inorganic materials 0.000 description 1
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- RFFFKMOABOFIDF-UHFFFAOYSA-N Pentanenitrile Chemical compound CCCCC#N RFFFKMOABOFIDF-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- GPVDHNVGGIAOQT-UHFFFAOYSA-N Veratric acid Natural products COC1=CC=C(C(O)=O)C(OC)=C1 GPVDHNVGGIAOQT-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-M crotonate Chemical compound C\C=C\C([O-])=O LDHQCZJRKDOVOX-NSCUHMNNSA-M 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- WVIIMZNLDWSIRH-UHFFFAOYSA-N cyclohexylcyclohexane Chemical compound C1CCCCC1C1CCCCC1 WVIIMZNLDWSIRH-UHFFFAOYSA-N 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- XJOBOFWTZOKMOH-UHFFFAOYSA-N decanoyl decaneperoxoate Chemical compound CCCCCCCCCC(=O)OOC(=O)CCCCCCCCC XJOBOFWTZOKMOH-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- RJGHQTVXGKYATR-UHFFFAOYSA-L dibutyl(dichloro)stannane Chemical compound CCCC[Sn](Cl)(Cl)CCCC RJGHQTVXGKYATR-UHFFFAOYSA-L 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- ISOLMABRZPQKOV-UHFFFAOYSA-N diethyl 2-acetamidopropanedioate Chemical compound CCOC(=O)C(NC(C)=O)C(=O)OCC ISOLMABRZPQKOV-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- WASQWSOJHCZDFK-UHFFFAOYSA-N diketene Chemical compound C=C1CC(=O)O1 WASQWSOJHCZDFK-UHFFFAOYSA-N 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- BRWZYZWZBMGMMG-UHFFFAOYSA-J dodecanoate tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BRWZYZWZBMGMMG-UHFFFAOYSA-J 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000009503 electrostatic coating Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 229960003399 estrone Drugs 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012628 flowing agent Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- WOLATMHLPFJRGC-UHFFFAOYSA-N furan-2,5-dione;styrene Chemical compound O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 WOLATMHLPFJRGC-UHFFFAOYSA-N 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 230000002650 habitual effect Effects 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 229940119545 isobornyl methacrylate Drugs 0.000 description 1
- CPJRRXSHAYUTGL-UHFFFAOYSA-N isopentenyl alcohol Chemical compound CC(=C)CCO CPJRRXSHAYUTGL-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 1
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- 229930015698 phenylpropene Natural products 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- YARNEMCKJLFQHG-UHFFFAOYSA-N prop-1-ene;styrene Chemical compound CC=C.C=CC1=CC=CC=C1 YARNEMCKJLFQHG-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- GNFWGDKKNWGGJY-UHFFFAOYSA-N propanimidamide Chemical compound CCC(N)=N GNFWGDKKNWGGJY-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000019086 sulfide ion homeostasis Effects 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- JKUYRAMKJLMYLO-UHFFFAOYSA-N tert-butyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OC(C)(C)C JKUYRAMKJLMYLO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 239000012970 tertiary amine catalyst Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
- JTCWXISSLCZBQV-UHFFFAOYSA-N tribol Natural products CC(CO)CCC1OC2(O)CC3C4CC=C5CC(CCC5(C)C4CCC3(C)C2C1C)OC6OC(CO)C(OC7OC(C)C(O)C(O)C7O)C(O)C6OC8OC(C)C(O)C(O)C8O JTCWXISSLCZBQV-UHFFFAOYSA-N 0.000 description 1
- HFMRLLVZHLGNAO-UHFFFAOYSA-N trimethylsilyloxysilicon Chemical compound C[Si](C)(C)O[Si] HFMRLLVZHLGNAO-UHFFFAOYSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/57—Three layers or more the last layer being a clear coat
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0209—Multistage baking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/04—Polymers provided for in subclasses C08C or C08F
- C08F290/046—Polymers of unsaturated carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/798—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing urethdione groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
- C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
- C08G18/8022—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with polyols having at least three hydroxy groups
- C08G18/8025—Masked aliphatic or cycloaliphatic polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/807—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
- C08G18/8074—Lactams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09D123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09D123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/007—Processes for applying liquids or other fluent materials using an electrostatic field
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/067—Curing or cross-linking the coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/53—Base coat plus clear coat type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
- C08G2150/20—Compositions for powder coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/068—Copolymers with monomers not covered by C08L33/06 containing glycidyl groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
Abstract
Description
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 337.00 |
原料2 | 叔戊基过氧(己酸2-乙酯) | 33.70 |
原料3 | 甲基丙烯酸甲酯 | 337.00 |
丙烯酸羟基丙酯 | 112.30 | |
丙烯酸丁酯 | 337.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 500 |
异丙醇 | 400 | |
原料2 | 过氧化二-叔戊基 | 20 |
异丙醇 | 100 | |
原料3 | 丙烯酸羟基丙酯 | 250 |
丙烯酸丁酯 | 250 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 500 |
异丙醇 | 400 | |
原料2 | 过氧化二-叔戊基 | 20 |
异丙醇 | 100 | |
原料3 | 丙烯酸羟基乙酯 | 250 |
丙烯酸丁酯 | 250 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1120.00 |
原料2 | 过氧化二-叔戊基 | 93.60 |
原料3 | 丙烯酸 | 144.00 |
丙烯酸羟基丙酯 | 720.00 | |
丙烯酸丁酯 | 1136.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1000.00 |
原料2 | 过氧化二-叔戊基 | 85.80 |
原料3 | 丙烯酸羟基乙酯 | 714.20 |
丙烯酸丁酯 | 1142.90 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1359.20 |
原料2 | 过氧化二-叔戊基 | 116.60 |
原料3 | 丙烯酸羟基丙酯 | 970.80 |
丙烯酸丁酯 | 1553.40 |
成分 | 重量份(克) | |
原料1 | 异丁烯 | 1000.00 |
原料2 | 过氧化二-叔戊基 | 85.80 |
原料3 | 丙烯酸羟基丙酯 | 714.20 |
丙烯酸丁酯 | 1142.90 |
成分 | 重量份(克) | |
原料1 | 甲苯 | 500.00 |
原料2 | 过氧化二-叔戊基 | 69.00 |
原料3 | 丙烯酸羟基丙酯 | 690.00 |
丙烯酸丁酯 | 1150.00 | |
苯乙烯 | 460.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 500.00 |
异丙醇 | 400.00 | |
原料2 | 过氧化二-叔戊基 | 30.00 |
异丙醇 | 100.00 | |
原料3 | 丙烯酸羟基丙酯 | 450.00 |
甲基丙烯酸丁酯 | 200.00 | |
苯乙烯 | 100.00 | |
丙烯酸 | 30.00 | |
丙烯酸丁酯 | 220.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1000.00 |
原料2 | 过氧化二-叔戊基 | 90.00 |
原料3 | 丙烯酸羟基丙酯 | 900.00 |
甲基丙烯酸丁酯 | 400.00 | |
苯乙烯 | 200.00 | |
丙烯酸丁酯 | 500.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1000.00 |
原料2 | 过氧化二-叔戊基 | 90.00 |
原料3 | 丙烯酸羟基丙酯 | 450.00 |
甲基丙烯酸丁酯 | 400.00 | |
苯乙烯 | 200.00 | |
甲基丙烯酸羟基乙酯 | 450.00 | |
丙烯酸丁酯 | 500.00 | |
原料4 | 二甲苯 | 250.00 |
成分 | 重量份(克) | |
原料1 | 丙烯酸/二异丁烯共聚物溶液(实施例4-J) | 1067.30 |
二甲苯 | 85.60 | |
芳族100(ExxonMobil) | 85.60 | |
氨基甲酸甲酯 | 169.00 | |
丁基锡酸 | 2.23 | |
亚磷酸三苯酯 | 2.23 |
成分 | 重量份(克) | |
原料1 | 丙烯酸/二异丁烯共聚物溶液(实施例4-K) | 1172.90 |
氨基甲酸甲酯 | 169.00 | |
丁基锡酸 | 2.40 | |
亚磷酸三苯酯 | 2.40 |
成分 | 重量份(克) | |
原料1 | 异丁烯 | 500.00 |
原料2 | 过氧化二-叔戊基 | 75.00 |
原料3 | 丙烯酸羟基乙酯 | 750.00 |
丙烯酸2-乙基己酯 | 1000.00 | |
甲基丙烯酸二甲基氨基乙酯 | 250.00 | |
原料4 | 2-丁氧基乙醇 | 250.00 |
成分 | 重量份(克) |
去离子水 | 1103.4 |
DMPA | 63.7 |
异丁烯/甲基丙烯酸二甲基氨基乙酯-交替-丙烯酸羟基乙酯/丙烯酸2-乙基己酯(实施例5-N) | 867.2 |
去离子水 | 1220.5 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1000.00 |
原料2 | 过氧化二-叔戊基 | 85.70 |
原料3 | 丙烯酸羟基丙酯 | 714.30 |
丙烯酸2-乙基己酯 | 714.30 | |
甲基丙烯酸二甲基氨基乙酯 | 238.10 | |
丙烯酸乙酯 | 238.10 |
成分 | 重量份(克) |
去离子水 | 986.9 |
DMPA | 63.7 |
二异丁烯/甲基丙烯酸二甲基氨基乙酯-交替-丙烯酸羟基乙酯/丙烯酸2-乙基己酯/丙烯酸乙酯(实施例5-O) | 983.7 |
去离子水 | 628.0 |
成分 | 重量份(克) | |
原料1 | 甲苯 | 500.00 |
原料2 | 过氧化二-叔戊基 | 45.00 |
原料3 | 丙烯酸羟基丙酯 | 450.00 |
丙烯酸丁酯 | 1050.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 300.00 |
原料2 | 过氧化二-叔戊基 | 90.00 |
原料3 | 丙烯酸羟基丙酯 | 855.00 |
丙烯酸丁酯 | 1995.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 310.00 |
原料2 | 过氧化二-叔戊基 | 45.00 |
原料3 | 丙烯酸羟基丙酯 | 382.50 |
丙烯酸丁酯 | 892.5 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 450.00 |
原料2 | 过氧化二-叔戊基 | 45.00 |
原料3 | 丙烯酸羟基丙酯 | 382.50 |
丙烯酸丁酯 | 892.50 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 750.00 |
原料2 | 过氧化二-叔戊基 | 45.00 |
原料3 | 丙烯酸羟基丙酯 | 337.50 |
丙烯酸丁酯 | 787.50 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1000.00 |
原料2 | 过氧化二-叔戊基 | 91.30 |
原料3 | 丙烯酸羟基丙酯 | 785.60 |
丙烯酸丁酯 | 1207.20 | |
丙烯酸 | 50.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1000.00 |
原料2 | 过氧化二-叔戊基 | 91.30 |
原料3 | 丙烯酸羟基丙酯 | 785.60 |
丙烯酸丁酯 | 1207.20 | |
丙烯腈 | 50.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1000.00 |
原料2 | 过氧化二-叔戊基 | 91.30 |
原料3 | 丙烯酸羟基丙酯 | 392.80 |
丙烯酸羟基乙酯 | 392.80 | |
丙烯酸丁酯 | 1207.90 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 1000.00 |
原料2 | 过氧化二-叔戊基 | 90.00 |
原料3 | 丙烯酸羟基丙酯 | 900.00 |
丙烯酸异冰片酯 | 400.00 | |
丙烯酸丁酯 | 500.00 | |
苯乙烯 | 200.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 100.00 |
原料2 | 叔戊基过氧(己酸2-乙酯) | 12 |
原料3 | 正丁氧基甲基丙烯酰胺(在丁醇中的50%溶液) | 10.00 |
丙烯酸羟基丙酯 | 78.50 | |
丙烯酸丁酯 | 120.70 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 100.00 |
原料2 | 叔戊基过氧(己酸2-乙酯) | 12 |
原料3 | 聚(乙二醇)甲基醚丙烯酸酯 | 5.00 |
丙烯酸羟基丙酯 | 78.50 | |
丙烯酸丁酯 | 120.70 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 336.00 |
原料2 | 叔戊基过氧(己酸2-乙酯) | 12 |
原料3 | 丙烯酸甲酯 | 21.50 |
丙烯酸丁酯 | 128.00 |
成分 | 重量份(克) | |
原料1 | 二异丁烯 | 224.00 |
原料2 | 叔戊基过氧(己酸2-乙酯) | 12 |
原料3 | 丙烯酸异冰片酯 | 104.2 |
丙烯酸丁酯 | 64.1 |
成分 | 重量份(克) | |
原料1 | Dowanol PM | 500.00 |
二异丁烯 | 896.00 | |
原料2 | 叔戊基过氧(己酸2-乙酯) | 24 |
原料3 | 丙烯酸 | 400.00 |
成分 | 重量份(克) |
二异丁烯n-甲氧基丙醇1苯乙烯丙烯酸缩水甘油酯丙烯酸羟基丙酯叔戊基过氧-2-乙基己酸酯叔戊基过氧-2-乙基己酸酯叔戊基过氧-2-乙基己酸酯 | 100070033012015034812 |
重量份(克) | |||
成分 | 实施例9(对比) | 实施例9-N | 实施例9-O |
E80031 | 817.0 | 735.3 | 735.3 |
实施例5-N-D的胺盐分散液 | 128.8 | ||
实施例5-O-D的胺盐分散液 | 108.5 | ||
E80082 | 230.7 | 230.7 | 230.7 |
去离子水 | 2752.4 | 2725.6 | 2725.6 |
浴 | ICO | LUB | P80 |
实施例9(对比) | 0 | 0 | 0 |
实施例9-N | ++ | ++ | ++ |
实施例9-O | ++ | ++ | ++ |
物料 | 实施例A | 实施例B | 实施例C |
有机混合料 | (克) | (克) | (克) |
蜜胺1 | 25.0 | 25.0 | 25.0 |
蜜胺2 | 6.3 | 6.3 | 6.3 |
光稳定剂3 | 1.4 | 1.4 | 1.4 |
颜料浆4 | 23.5 | 23.5 | 23.5 |
颜料浆5 | 6.5 | 6.5 | 6.5 |
磷酸盐化环氧6 | 0.4 | 0.4 | 0.4 |
N-丁氧基丙醇 | 45.0 | 45.0 | 45.0 |
含水混合料 | (克) | (克) | (克) |
矿物精油7 | 6.0 | 6.0 | 6.0 |
苯乙烯-丙烯酸树脂8 | 132.1 | ||
胶乳聚酯* | 140.0 | ||
实施例2-D的聚合物 | 71.1 | ||
去离子水 | 50.0 | 50.0 | 50.0 |
水性丙烯酸分散液9 | 23.1 | 23.1 | 23.1 |
存在于去离子水中的50wt.%DMEA | 4.5 | 4.5 | 4.5 |
预混物 | (克) | (克) | (克) |
去离子水 | 10.0 | 10.0 | 10.0 |
存在于去离子水中的50wt.%DMEA | 4.5 | 4.5 | 4.5 |
低聚型聚酯 | 5.0 | 5.0 | 5.0 |
调节混合料 | (克) | (克) | (克) |
去离子水 | 43.0 | 43.0 | 43.0 |
存在于去离子水中的50wt.%DMEA | 1.1 | 1.1 | 1.1 |
涂层 | 实施例A | 实施例B | 实施例C |
试验 | |||
20°光泽 | 85 | 92 | 86 |
DOI | 75 | 73 | 83 |
粘合性 | 10 | 10 | 10 |
破缺性 | 6 | 9 | 9- |
物料 | 实施例D | 实施例E | 实施例F | 实施例G |
(克) | (克) | (克) | ||
MAK | 7.3 | 7.3 | 7.3 | 7.3 |
二甲苯 | 2.2 | 2.2 | 2.2 | 2.2 |
芳族10011 | 7.5 | 7.5 | 7.5 | 7.5 |
EGMHE | 0.7 | 0.7 | 0.7 | 0.7 |
乙醇 | 3.3 | 3.3 | 3.3 | 3.3 |
氨基树脂12 | 49.9 | |||
氨基树脂13 | 40.0 | 40.0 | 40.0 | |
丙烯酸树脂** | 73.8 | |||
实施例1-A的聚合物 | 71.7 | |||
实施例1-B的聚合物 | 60.0 | |||
实施例1-C的聚合物 | 60.0 | |||
催化剂14 | 1.0 | 1.4 | 1.2 | 1.2 |
芳族10011 | 11.0 | 10.0 | 3.3 | 3.3 |
MAK | 11.0 | 10.0 | 3.3 | 3.3 |
二甲苯 | 11.0 | 10.0 | 3.3 | 3.3 |
MAK | 16.8 | 24.0 | 1.5 | 2.5 |
乙酸丁酯 | 4.2 | 6.0 | 1.5 | 2.5 |
涂层 | 实施例D | 实施例E | 实施例F | 实施例G |
试验 | ||||
20°光泽 | 92 | 87 | 86 | 87 |
Tukon(努氏硬度) | 14 | 10 | 12 | 10 |
划伤保留率(%) | 75 | 52 | 15 | 56 |
总固体(wt.%) | 53 | 51 | 52 | 64 |
酸侵蚀性评分 | 10 | 10 | 3 | 10 |
VOC | 3.9 | * | 3.3 | 2.9 |
陷穴 | 1- | * | 47.5 | * |
物料 | 实施例H | 实施例I | 实施例J | 实施例K |
(克) | (克) | (克) | ||
3-乙氧基丙酸酯 | 17.6 | |||
MEPGA | 9.3 | |||
丙烯酸树脂** | 68.3 | |||
实施例1-A的聚合物 | 99.9 | |||
实施例1-B的聚合物 | 60.7 | |||
实施例1-C的聚合物 | 57.9 | |||
多异氰酸酯15 | 47.6 | |||
多异氰酸酯16 | 23.5 | 56.2 | 60.1 | |
二月桂酸二丁基锡 | 0.05 | 0.05 | 0.05 | 0.05 |
3-乙氧基丙酸酯 | 5.0 | 26.0 | 21.0 | 27.0 |
MEPGA | 5.0 | 16.0 | 21.0 | 27.0 |
涂层 | 实施例H | 实施例I | 实施例J | 实施例K |
试验 | ||||
20°光泽 | 86 | 82 | 88 | 80 |
Tukon(努氏硬度) | 13 | 15 | 10 | 13 |
划伤保留率(%) | 18 | 9 | 72 | 10 |
总固体(wt.%) | 52 | 63 | 63 | 58 |
酸侵蚀性评分 | 4 | 1 | 10 | 1 |
VOC | 3.9 | * | 3.3 | * |
陷穴 | 1- | * | 47.5 | * |
物料 | 实施例L | 实施例M | 实施例N | 实施例O | 实施例P | 实施例Q |
(g) | (g) | (g) | (g) | (g) | (g) | |
二甲苯 | 2.3 | 2.3 | 2.3 | 2.3 | 2.3 | 2.3 |
芳族10011 | 8.5 | 8.5 | 8.5 | 8.5 | 8.5 | 8.5 |
EGMHE | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 |
甲基乙基酮 | 8.5 | 8.5 | 8.5 | 8.5 | 8.5 | 8.5 |
光稳定剂17 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
光稳定剂18 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 |
煅制二氧化硅分散液 | 16.2 | 16.2 | 16.2 | 16.2 | 16.2 | 16.2 |
氨基树脂12 | 47.0 | 47.0 | 47.0 | 47.0 | 47.0 | 47.0 |
乙醇 | 5.5 | 5.5 | 5.5 | 5.5 | 5.5 | 5.5 |
丙烯酸树脂*** | 68 6 | |||||
实施例4-I的聚合物 | 59.3 | |||||
实施例4-J的聚合物 | 56.7 | |||||
实施例4-K的聚合物 | 55.6 | |||||
实施例4-L的聚合物 | 56.8 | |||||
实施例4-M的聚合物 | 55.0 | |||||
光稳定剂19 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 |
流动添加剂20 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 |
流动添加剂21 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
催化剂14 | 0.9 | 0.9 | 0.9 | 0.9 | 0.9 | 0.9 |
涂层 | 实施例L | 实施例M | 实施例N | 实施例O | 实施例P | 实施例Q |
试验 | ||||||
20°光泽 | 90 | 86 | 88 | 88 | 89 | 87 |
DOI | 90 | 95 | 92 | 92 | 90 | 89 |
Tukon(努氏硬度) | 12 | 8 | 10 | 11 | 11 | 11 |
划伤保留率(%) | 96 | 91 | 94 | 99 | 98 | 95 |
总固体(wt.%) | 57 | 66 | 59 | 59 | 59 | 59 |
酸侵蚀性评分 | 10 | * | 10 | 10 | 2 | 4 |
物料 | 实施例R | 实施例S | 实施例T | 实施例U |
(g) | (g) | (g) | (g) | |
DIBK | 55.1 | 55.1 | 55.1 | 55.1 |
二甲苯 | 55.1 | 55.1 | 55.1 | 55.1 |
甲基乙基酮 | 18.8 | 18.8 | 18.8 | 18.8 |
乙酸N-丁基酯 | 17.6 | 17.6 | 17.6 | 17.6 |
光稳定剂24 | 10.6 | 10.6 | 10.6 | 10.6 |
微凝胶25 | 87.0 | 87.0 | 87.0 | 87.0 |
氨基树脂12 | 171.0 | 171.0 | 171.0 | 171.0 |
实施例3-H的聚合物 | 91.9 | |||
实施例3-E的聚合物 | 84.8 | |||
实施例3-F的聚合物 | 89.8 | |||
实施例3-G的聚合物 | 84.8 | |||
膨润土分散液 | 87.3 | 87.3 | 87.3 | 87.3 |
磷酸盐化环氧聚合物溶液 | 1.2 | 1.2 | 1.2 | 1.2 |
催化剂14 | 5.7 | 5.7 | 5.7 | 5.7 |
品红颜料浆 | 42.4 | 42.4 | 42.4 | 42.4 |
红色颜料浆 | 134.8 | 134.8 | 134.8 | 134.8 |
橙色云母26 | 1.2 | 1.2 | 1.2 | 1.2 |
铜云母27 | 6.9 | 6.9 | 6.9 | 6.9 |
黄褐色云母28 | 32.0 | 32.0 | 32.0 | 32.0 |
铝粉浆29 | 1.3 | 1.3 | 1.3 | 1.3 |
涂层 | 实施例R | 实施例S | 实施例T | 实施例U |
试验 | ||||
总固体(wt.%) | 45.8 | 48.7 | 44.7 | 41.7 |
VOC(wt.%) | 4.5 | 4.3 | 4.6 | 4.8 |
20°光泽 | 88.6 | 88.6 | 88.8 | 89.3 |
划伤性 | 90.3 | 92.2 | 91.8 | 90.6 |
耐水斑性 | 3 | 3 | 2.5 | 3 |
耐酸斑性 | 2/5.5 | 1/5.5 | 1.5/5.5 | 1/5.5 |
破缺性 | B6 | B6 | B6 | B5 |
粘合性 | 100% | 100% | 100% | 100% |
流挂性 | 1.52 | 1.7 | 1.56 | 1.62 |
爆裂性 | 0.45 | <0.6 | 1.44 | 1.19 |
成分 | 重量份(克) |
异佛尔酮二异氰酸酯甲基异丁基酮二月桂酸二丁基锡三羟甲基丙烷己内酰胺丙二醇甲基异丁基酮 | 1110.0160.01.0156.4735.87.6280.0 |
成分 | 重量份(克) |
实施例8-DD的丙烯酸-二异丁烯聚合物硫代二乙醇乳酸上述的氨基甲酸酯交联剂去离子水去离子水去离子水 | 1310.0366.081.8662.554.01784.21353.5 |
成分 | 重量份 |
表48中所述的可电沉积的树脂CA92630去离子水正己基乙二醇31 | 1079.45.31115.322.0 |
物料 | 实施例V(g) |
实施例8-CC的聚合物 | 7.0 |
羟基烷基酰胺32 | 4.7 |
脱气剂33 | 0.1 |
流动剂34 | 0.1 |
实施例V | |
胶凝点 | 30秒 |
Mek双重摩擦 | >100 |
成分 | 重量份(克) | |
原料1 | 聚(异丁烯-交替-马来酸酐)35 | 200.00 |
原料2 | M-pyrol | 400.00 |
原料3 | DiH2O | 54.00 |
物料 | 实施例X | 实施例Y |
甲基正戊基酮 | 25 | |
丁基醚二甘醇乙酸酯 | 5.0 | |
N-戊醇 | 4.1 | |
甲醇 | 32.0 | |
GMA丙烯酸树脂35 | 87.89 | 86.1 |
酸官能的交联剂36 | 63.69 | |
聚(异丁烯-交替-马来酸) | 97.84 |
对比X | 实施例Y | |
Mek双重摩擦 | 20 | 1 |
物料 | 实施例Z | 实施例AA | 实施例BB | 实施例CC | 实施例DD | 实施例EE |
(g) | (g) | (g) | (g) | (g) | (g) | |
MAK | 7.3 | 7.3 | 7.3 | 7.3 | 7.3 | 7.3 |
二甲苯 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 |
芳族10011 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 |
EGMHE | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 |
乙醇 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 |
氨基树脂12 | 49.9 | |||||
氨基树脂13 | 40.0 | 40.0 | 40.0 | 40.0 | 40.0 | |
丙烯酸树脂** | 73.8 | |||||
实施例6-P的聚合物 | 78.5 | |||||
实施例6-Q的聚合物 | 62.1 | |||||
实施例6-R的聚合物 | 64.8 | |||||
实施例6-S的聚合物 | 67.1 | |||||
实施例6-T的聚合物 | 78.5 | |||||
催化剂14 | 1.0 | 1.4 | 1.4 | 1.4 | 1.4 | 1.4 |
芳族10011 | 6.0 | 0.0 | 6.0 | 2.6 | 3.0 | 0.0 |
MAK | 6.0 | 0.0 | 6.0 | 2.6 | 3.0 | 0.0 |
二甲苯 | 6.0 | 0.0 | 6.0 | 2.6 | 3.0 | 0.0 |
MAK | 14.4 | 0.0 | 14.4 | 6.4 | 7.2 | 0.0 |
2-丁氧基乙醇乙酸酯 | 3.6 | 0.0 | 3.6 | 1.6 | 1.8 | 0.0 |
涂层 | 实施例Z | 实施例AA | 实施例BB | 实施例CC | 实施例DD | 实施例EE |
试验 | ||||||
百分比固体含量 | 51.4 | 63.1 | 55.9 | 59.2 | 61.6 | 63.9 |
20°光泽 | 92.2 | 86.6 | 86.6 | 87.0 | 86.7 | 85.9 |
DOI | 96 | 96 | 96 | 96 | 96 | 95 |
VOC | 4.0 | 3.2 | 3.6 | 3.3 | 3.2 | 3.0 |
陷穴性 | 1.0 | 55 | 60 | 76 | 82 | 85 |
物料 | 实施例FF | 实施例GG | 实施例HH | 实施例II | 实施例JJ | 实施例KK | 实施例LL |
(g) | (g) | (g) | (g) | (g) | (g) | (g) | |
MAK | 7.3 | 7.3 | 7.3 | 7.3 | 7.3 | 7.3 | 7.3 |
二甲苯 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 | 2.2 |
芳族10011 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 | 7.5 |
EGMHE | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 | 0.7 |
乙醇 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 | 3.3 |
氨基树脂12 | 49.9 | ||||||
氨基树脂13 | 40.0 | 40.0 | 40.0 | 40.0 | 40.0 | 40.0 | |
丙烯酸树脂** | 73.8 | ||||||
实施例7-U的聚合物 | 72.6 | ||||||
实施例7-V的聚合物 | 72.4 | ||||||
实施例7-W的聚合物 | 73.9 | ||||||
实施例7-X的聚合物 | 72.3 | ||||||
实施例7-Y的聚合物 | 66.0 | ||||||
实施例7-Z的聚合物 | 76.5 | ||||||
催化剂14 | 1.0 | 1.4 | 1.4 | 1.4 | 1.3 | 1.3 | 1.4 |
芳族10011 | 6.0 | 1.7 | 2.7 | 2.0 | 2.7 | 9.2 | 9.7 |
MAK | 6.0 | 1.7 | 2.7 | 2.0 | 2.7 | 9.2 | 9.7 |
二甲苯 | 6.0 | 1.7 | 2.7 | 2.0 | 2.7 | 9.2 | 9.7 |
MAK | 14.4 | 4.0 | 6.4 | 4.8 | 6.4 | 22.1 | 23.2 |
2-丁氧基乙醇乙酸酯 | 3.6 | 1.0 | 1.6 | 1.2 | 1.6 | 5.5 | 5.8 |
涂层 | 实施例FF | 实施例GG | 实施例HH | 实施例II | 实施例JJ | 实施例KK | 实施例LL |
试验 | |||||||
%固体 | 51.4 | 61.2 | 60.6 | 61.0 | 59.2 | 49.3 | 49.3 |
20°光泽 | 92 | 85 | 86 | 87 | 89 | 82 | 86 |
DOI | 96 | 96 | 96 | 96 | 95 | 89 | 94 |
陷穴性 | 1 | 77 | 75 | 77 | 52 | 74 | 70 |
Claims (19)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/077,645 US6784248B2 (en) | 2002-02-15 | 2002-02-15 | Thermosetting compositions containing alternating copolymers of isobutylene type monomers |
US10/077,645 | 2002-02-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1639204A CN1639204A (zh) | 2005-07-13 |
CN1300185C true CN1300185C (zh) | 2007-02-14 |
Family
ID=27752701
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB038050501A Expired - Fee Related CN1300185C (zh) | 2002-02-15 | 2003-01-29 | 含有异丁烯型单体交替共聚物的热固性组合物 |
Country Status (12)
Country | Link |
---|---|
US (9) | US6784248B2 (zh) |
EP (2) | EP1474454B1 (zh) |
JP (5) | JP3993563B2 (zh) |
KR (1) | KR100611868B1 (zh) |
CN (1) | CN1300185C (zh) |
AU (2) | AU2003210715B2 (zh) |
BR (1) | BR0307577A (zh) |
CA (2) | CA2476090C (zh) |
DE (4) | DE60330118D1 (zh) |
ES (4) | ES2334562T3 (zh) |
TW (1) | TWI312358B (zh) |
WO (2) | WO2003070781A1 (zh) |
Families Citing this family (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5807937A (en) * | 1995-11-15 | 1998-09-15 | Carnegie Mellon University | Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties |
US6784248B2 (en) * | 2002-02-15 | 2004-08-31 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing alternating copolymers of isobutylene type monomers |
US6686432B2 (en) * | 2002-02-15 | 2004-02-03 | Ppg Industries Ohio, Inc. | Alternating copolymers of isobutylene type monomers |
CA2476302C (en) * | 2002-02-15 | 2010-09-21 | Ppg Industries Ohio, Inc. | Waterborne thermosetting compositions containing alternating copolymers of isobutylene type monomers |
US7132477B2 (en) * | 2002-02-15 | 2006-11-07 | Ppg Industries Ohio, Inc. | Powder coating compositions |
WO2003070783A1 (en) | 2002-02-15 | 2003-08-28 | Ppg Industries Ohio, Inc. | Waterborne film-forming compositions containing alternating copolymers of isobutylene type monomers |
DE602004001517T2 (de) * | 2003-03-12 | 2006-12-28 | Ciba Speciality Chemicals Holding Inc. | Hydroxylaminester enthaltende beschichtungszusammensetzung |
US20050032978A1 (en) * | 2003-08-06 | 2005-02-10 | O'dwyer James B. | Etherified carbamate functional copolymers of isobutylene type monomers, and their use in curable compositions |
US7105588B2 (en) * | 2003-10-10 | 2006-09-12 | E. I. Du Pont De Nemours And Company | Screen printable hydrogel for medical applications |
DE102004008772A1 (de) * | 2004-02-23 | 2005-09-08 | Institut für Neue Materialien Gemeinnützige GmbH | Abriebbeständige und alkalibeständige Beschichtungen oder Formkörper mit Niedrigenergieoberfläche |
EP1725590A4 (en) * | 2004-03-05 | 2013-08-07 | Univ Carnegie Mellon | PROCESS FOR ATOM TRANSFER RADICAL POLYMERIZATION |
WO2006019797A1 (en) * | 2004-07-14 | 2006-02-23 | 3M Innovative Properties Company | Dental compositions containing oxirane monomers |
US20060025534A1 (en) * | 2004-07-30 | 2006-02-02 | Johnson Jeffery W | High solids coating composition based on thermal initiated free-radical polymerization |
MX2007003525A (es) * | 2004-09-30 | 2007-06-05 | Ppg Ind Ohio Inc | Composiciones de revestimiento termoestable que comprenden un copolimero formado a partir de clorotrifluoroetileno y metodos para elaborar copolimeros formados a partir de clorotrifluoroetileno. |
CA2581192C (en) * | 2004-09-30 | 2010-05-11 | Ppg Industries Ohio,Inc., | Fluoropolymers, methods for their production, and thermosetting compositions containing them |
WO2006048708A2 (ja) * | 2004-10-08 | 2006-05-11 | Basf Coatings Japan Ltd. | 塗料用水酸基含有樹脂組成物、塗料組成物、塗装仕上げ方法及び塗装物品 |
MX2007004463A (es) | 2004-10-20 | 2007-05-07 | Valspar Sourcing Inc | Composiciones de recubrimiento para latas y metodos de recubrimiento. |
US8241618B2 (en) * | 2005-01-27 | 2012-08-14 | Lubrizol Advanced Materials, Inc. | Process for producing a hydrophobically modified polymer for use with personal care compositions |
US20060182975A1 (en) * | 2005-02-17 | 2006-08-17 | Reichhold, Inc. | Thermoset polymer substrates |
DE102005023728A1 (de) * | 2005-05-23 | 2006-11-30 | Basf Coatings Ag | Lackschichtbildendes Korrosionsschutzmittel und Verfahren zu dessen stromfreier Applikation |
WO2007025086A2 (en) | 2005-08-23 | 2007-03-01 | Carnegie Mellon University | Atom transfer radical polymerization in microemulsion and true emulsion polymerization |
WO2007025310A1 (en) * | 2005-08-26 | 2007-03-01 | Carnegie Mellon University | Polymerization process with catalyst reactivation |
JP2007126623A (ja) * | 2005-10-05 | 2007-05-24 | Dainippon Ink & Chem Inc | 床用水性塗料および床塗工方法 |
US7547739B2 (en) * | 2005-12-20 | 2009-06-16 | E. I. Du Pont De Nemours And Company | Powder coating composition providing low gloss |
DE102005062442B4 (de) * | 2005-12-27 | 2012-10-04 | Lohmann Gmbh & Co. Kg | Verfahren zur Herstellung eines bifunktionalen Haftklebesystems, bifunktionales Haftklebesystem und dessen Verwendung |
WO2007079541A1 (en) * | 2006-01-12 | 2007-07-19 | John Lyndon Garnett | Radiation curable system |
KR20120009507A (ko) * | 2006-01-20 | 2012-01-31 | 히다치 가세고교 가부시끼가이샤 | 수지 조성물의 경화물을 이용한 광학부재 |
US8101251B2 (en) * | 2006-07-03 | 2012-01-24 | Dow Corning Corporation | Chemically curing all-in-one warm edge spacer and seal |
JP5463612B2 (ja) * | 2006-09-28 | 2014-04-09 | 横浜ゴム株式会社 | ウレタンエマルジョン |
WO2008057163A2 (en) * | 2006-10-09 | 2008-05-15 | Carnegie Mellon University | Preparation of functional gel particles with a dual crosslink network |
DE102006053291A1 (de) * | 2006-11-13 | 2008-05-15 | Basf Coatings Ag | Lackschichtbildendes Korrosionsschutzmittel mit guter Haftung und Verfahren zu dessen stromfreier Applikation |
DE102006053292A1 (de) * | 2006-11-13 | 2008-05-15 | Basf Coatings Ag | Lackschichtbildendes Korrosionsschutzmittel mit verminderter Rißbildung und Verfahren zu dessen stromfreier Applikation |
US7737223B2 (en) * | 2006-12-19 | 2010-06-15 | Ppg Industries Ohio, Inc. | Coating compositions containing amine-hydroxy functional polymer and/or amine-carbamate functional polymer |
DE102007012406A1 (de) * | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Verfahren zur Korrosionsschutzausrüstung metallischer Substrate |
US7790202B1 (en) * | 2007-04-09 | 2010-09-07 | Martell Helen D | Multi-purpose skin composition |
GB2463199B (en) | 2007-05-23 | 2012-09-26 | Univ Carnegie Mellon | Atom transfer dispersion polymerization |
WO2009023353A1 (en) * | 2007-05-23 | 2009-02-19 | Carnegie Mellon University | Hybrid particle composite structures with reduced scattering |
MY149319A (en) * | 2007-06-20 | 2013-08-30 | Kansai Paint Co Ltd | Multilayer coating film-forming method |
US20090298989A1 (en) * | 2008-05-28 | 2009-12-03 | Funston Sr Randall A | 2K Waterborne Polyurethane Coating System and Methods Thereof |
CN102076427B (zh) * | 2008-06-24 | 2013-10-30 | 关西涂料株式会社 | 多层涂膜形成方法 |
US7763350B2 (en) * | 2008-07-01 | 2010-07-27 | Ppg Industries Ohio, Inc. | Coated articles demonstrating heat reduction and noise reduction properties |
US20100004353A1 (en) * | 2008-07-01 | 2010-01-07 | Ppg Industries Ohio, Inc. | Waterborne film-forming compositions having heat reflective properties |
KR101540688B1 (ko) * | 2008-11-12 | 2015-07-31 | 주식회사 케이씨씨 | 아크릴 수지를 포함하는 투명 도료 조성물 |
US20100160561A1 (en) * | 2008-12-24 | 2010-06-24 | Ppg Industries Ohio, Inc. | Copolymers of alpha-olefin type monomers and curable film-forming compositions containing them |
DE102009007632A1 (de) | 2009-02-05 | 2010-08-12 | Basf Coatings Ag | Beschichtungsmittel für korrosionsstabile Lackierungen |
US8962764B2 (en) | 2009-03-27 | 2015-02-24 | Carnegie Mellon University | Preparation of functional star macromolecules |
EP2482995B1 (en) * | 2009-09-28 | 2018-04-11 | Carrier Corporation | Dual powder coating method |
KR101212668B1 (ko) * | 2009-11-20 | 2012-12-14 | 제일모직주식회사 | 고분자, 보호막 조성물 및 이를 이용한 패턴 형성 방법 |
TWI565779B (zh) * | 2010-05-13 | 2017-01-11 | 明基材料股份有限公司 | 黏著劑之組成物及其製造方法 |
WO2012059490A1 (en) * | 2010-11-02 | 2012-05-10 | Akzo Nobel Coatings International B.V. | Matte textured powder monocoat coating compositions |
US9644042B2 (en) | 2010-12-17 | 2017-05-09 | Carnegie Mellon University | Electrochemically mediated atom transfer radical polymerization |
US20120184653A1 (en) * | 2011-01-18 | 2012-07-19 | Liang Wang | Synthesis of linear phosphorus-containing functional fluorocopolymer |
JP5587230B2 (ja) * | 2011-03-25 | 2014-09-10 | 富士フイルム株式会社 | 太陽電池用バックシート及びその製造方法、並びに太陽電池モジュール |
EP2747753B1 (en) | 2011-08-22 | 2023-03-29 | Carnegie Mellon University | Atom transfer radical polymerization under biologically compatible conditions |
KR101506027B1 (ko) * | 2011-10-24 | 2015-03-25 | 팰리스 카가쿠 가부시기가이샤 | 고정 지립 와이어 톱용 수용성 절단액, 그것을 이용한 절단 방법 및 그 리사이클 방법 |
US9533297B2 (en) | 2012-02-23 | 2017-01-03 | Carnegie Mellon University | Ligands designed to provide highly active catalyst complexes |
US9259821B2 (en) * | 2014-06-25 | 2016-02-16 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | Chemical mechanical polishing layer formulation with conditioning tolerance |
US9982070B2 (en) | 2015-01-12 | 2018-05-29 | Carnegie Mellon University | Aqueous ATRP in the presence of an activator regenerator |
CN107848223A (zh) | 2015-05-26 | 2018-03-27 | 加拿大圣戈班爱德福思有限公司 | 玻璃毡强化 |
CA2997048C (en) | 2015-09-02 | 2023-05-23 | Threebond Co., Ltd. | Photocurable resin composition, fuel cell, and sealing method |
KR20180053338A (ko) * | 2015-09-11 | 2018-05-21 | 피피지 인더스트리즈 오하이오 인코포레이티드 | 다활성화된 메틸렌 수지 및 폴리이소시아네이트를 함유하는 경화성 코팅 조성물 |
JP6974332B2 (ja) * | 2016-02-11 | 2021-12-01 | ヘンケル アイピー アンド ホールディング ゲゼルシャフト ミット ベシュレンクテル ハフツング | ペンダントヒドロキシル官能基を有するオレフィン−アクリレートコポリマーおよびその使用 |
KR20190010876A (ko) | 2016-05-24 | 2019-01-31 | 바스프 코팅스 게엠베하 | 개선된 내오염성 및 (자기)세정 특성을 갖는 코팅제 및 그로부터 제조된 코팅 및 그의 용도 |
EP4053225A1 (en) * | 2016-10-19 | 2022-09-07 | Swimc Llc | Acylic polymers and compositions containing such polymers |
JP6762209B2 (ja) * | 2016-11-29 | 2020-09-30 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | アクリル樹脂及びメラミン樹脂を主体樹脂とするトップコート用塗料組成物 |
US11174325B2 (en) | 2017-01-12 | 2021-11-16 | Carnegie Mellon University | Surfactant assisted formation of a catalyst complex for emulsion atom transfer radical polymerization processes |
US10370555B2 (en) | 2017-05-16 | 2019-08-06 | Ppg Industries Ohio, Inc. | Curable film-forming compositions containing hydroxyl functional acrylic polymers and bisurea compounds and multilayer composite coatings |
EP3652259B1 (en) | 2017-07-14 | 2024-03-20 | PPG Industries Ohio, Inc. | Curable film-forming compositions containing reactive functional polymers and polysiloxane resins, multilayer composite coatings, and methods for their use |
CN113166577B (zh) * | 2018-11-02 | 2022-10-11 | 迈图高新材料公司 | 具有早期耐水性的涂料 |
CN110003441B (zh) * | 2019-04-22 | 2021-06-22 | 广州大学 | 一种uv固化水性异氰酸酯接枝氟硅氧烷改性环氧丙烯酸树脂的制备方法 |
CN111116815B (zh) * | 2020-01-07 | 2021-08-20 | 复旦大学 | 一种三氟氯乙烯与乙烯基醚的光控制交替共聚方法 |
CN114292567B (zh) * | 2022-01-25 | 2022-07-15 | 中国科学院长春应用化学研究所 | 一种粉末涂料组合物及其制备厚度可控静电喷涂涂层的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1213171A (en) * | 1967-02-28 | 1970-11-18 | Du Pont | Polymerisation process |
GB1339981A (en) * | 1970-03-04 | 1973-12-05 | Sumitomo Chemical Co | Curable copolymers |
US5115083A (en) * | 1989-11-06 | 1992-05-19 | The Lubrizol Corporation | Curable aminoplast compositions and catalysts for curing same |
Family Cites Families (104)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2411599A (en) | 1940-11-09 | 1946-11-26 | Standard Oil Dev Co | Polymerization process |
US2378629A (en) | 1941-09-10 | 1945-06-19 | Du Pont | Copolymers of maleic anhydride |
US2531196A (en) | 1942-10-20 | 1950-11-21 | Du Pont | Vinyl polymers and process for producing the same |
US2468664A (en) | 1945-08-28 | 1949-04-26 | Du Pont | Tetrafluoroethylene copolymers |
US2751367A (en) | 1952-06-14 | 1956-06-19 | American Cyanamid Co | Friable polyacrylate powders |
DE1045658B (de) | 1956-07-23 | 1958-12-04 | Roehm & Haas Gmbh | Verfahren zur Herstellung von Derivaten der Polymethacrylsaeure aus Polymeth-acrylsaeuremethylester bzw. aus zum ueberwiegenden Teil aus Methacrylsaeure-methylester aufgebauten Mischpolymerisaten durch alkalische Hydrolyse oder durch Alkoholyse |
GB1121614A (en) | 1964-10-30 | 1968-07-31 | Du Pont | Elastomers |
US3380974A (en) | 1964-10-30 | 1968-04-30 | Du Pont | Tetrafluoroethylene, isobutylene, carboxylic copolymers |
JPS4936822B1 (zh) * | 1970-03-04 | 1974-10-03 | ||
CA963599A (en) | 1970-03-04 | 1975-02-25 | Sumitomo Chemical Company | Sulfur-curable olefin-acrylic ester interpolymer |
US3984299A (en) | 1970-06-19 | 1976-10-05 | Ppg Industries, Inc. | Process for electrodepositing cationic compositions |
US4025407A (en) | 1971-05-05 | 1977-05-24 | Ppg Industries, Inc. | Method for preparing high solids films employing a plurality of curing mechanisms |
US3947338A (en) | 1971-10-28 | 1976-03-30 | Ppg Industries, Inc. | Method of electrodepositing self-crosslinking cationic compositions |
CH582719A5 (zh) * | 1973-09-12 | 1976-12-15 | Ciba Geigy Ag | |
JPS50136315A (zh) | 1974-04-17 | 1975-10-29 | ||
GB1469090A (en) | 1974-06-27 | 1977-03-30 | Ceskoslovenska Akademie Ved | Polymers of acyloxyalkyl methacrylates method for their preparation |
US4147688A (en) | 1975-03-19 | 1979-04-03 | Ppg Industries, Inc. | Method of preparing dispersions of gelled polymeric microparticles and products produced thereby |
US4043953A (en) | 1975-05-02 | 1977-08-23 | Ppg Industries, Inc. | Ambient temperature, moisture-curable acrylic-silane coating compositions having improved potlife |
US4147679A (en) | 1976-06-02 | 1979-04-03 | Ppg Industries, Inc. | Water-reduced urethane coating compositions |
US4147685A (en) | 1977-01-28 | 1979-04-03 | General Electric Company | Primer compositions for adhering silicone compositions |
US4177301A (en) | 1977-01-28 | 1979-12-04 | General Electric Company | Primer compositions for adhering silicone compositions |
AU515845B2 (en) | 1977-04-25 | 1981-05-07 | Ici Ltd. | Multiple layer coating process |
GB2073609B (en) | 1980-04-14 | 1984-05-02 | Ici Ltd | Coating process |
US4303581A (en) | 1980-07-16 | 1981-12-01 | Ppg Industries, Inc. | Water dispersed primer-surfacer composition |
JPS6021686B2 (ja) | 1980-08-08 | 1985-05-29 | 旭硝子株式会社 | 常温硬化可能な含フツ素共重合体 |
US4681918A (en) | 1981-06-30 | 1987-07-21 | E. I. Du Pont De Nemours And Company | "Living" polymers and process for their preparation |
US4468307A (en) | 1981-09-14 | 1984-08-28 | Ppg Industries, Inc. | Method of cationic electrodeposition |
JPS58136605A (ja) | 1982-02-05 | 1983-08-13 | Asahi Glass Co Ltd | カルボキシル基含有含フツ素重合体の製造方法 |
US4493056A (en) | 1982-06-30 | 1985-01-08 | International Business Machines Corporation | RAM Utilizing offset contact regions for increased storage capacitance |
DE3328276A1 (de) | 1983-08-05 | 1985-02-21 | Hoechst Ag, 6230 Frankfurt | Polyacrylnitrile mit geringem k-wert, verfahren zu ihrer herstellung und geeignete verwendung |
US4487860A (en) * | 1983-12-05 | 1984-12-11 | Scm Corporation | Aqueous self-curing polymeric blends |
JPS60206621A (ja) * | 1984-03-31 | 1985-10-18 | Kureha Chem Ind Co Ltd | 弗化ビニリデン系樹脂フイルム,その製法および金属化フイルム |
JPS6128544A (ja) | 1984-07-20 | 1986-02-08 | Nippon Oil & Fats Co Ltd | 熱硬化性樹脂組成物 |
GB8510690D0 (en) | 1985-04-26 | 1985-06-05 | Bostik Ltd | Moisture curable sealants |
US4681811A (en) | 1985-08-19 | 1987-07-21 | Ppg Industries, Inc. | Color plus clear coatings employing polyepoxides and polyacid curing agents in the clear coat |
US4732790A (en) | 1986-08-21 | 1988-03-22 | Ppg Industries, Inc. | Color plus clear application of thermosetting high solids coating composition of hydroxy-functional epoxies and anhydrides |
US5214101A (en) | 1986-09-29 | 1993-05-25 | Ppg Industries, Inc. | Powder coating composition comprising a co-reactable particulate mixture of carboxylic acid group-containing polymers and beta-hydroxyalkylamide curing agent |
US4937288A (en) | 1986-09-29 | 1990-06-26 | Ppg Industries, Inc. | Powder coating composition |
JP2609256B2 (ja) | 1987-07-21 | 1997-05-14 | 鐘淵化学工業株式会社 | 硬化性組成物 |
KR910004817B1 (ko) | 1987-07-31 | 1991-07-13 | 니혼유시 가부시기가이샤 | 열경화성분체도료조성물 |
US4798746A (en) | 1987-08-24 | 1989-01-17 | Ppg Industries, Inc. | Basecoat/clearcoat method of coating utilizing an anhydride additive in the thermoplastic polymer-containing basecoat for improved repairability |
MX169697B (es) | 1987-12-28 | 1993-07-19 | Ppg Industries Inc | Mejoras a composiciones fraguables por radiacion basadas sobre poliesteres insaturados y compuestos teniendo por lo menos dos grupos de vinil eter |
US4889890A (en) | 1987-12-30 | 1989-12-26 | Ppg Industries, Inc. | Powder coating curing system containing a beta-hydroxyalkylamide |
US4877837A (en) * | 1988-10-07 | 1989-10-31 | The Glidden Company | Epoxy functional and silicone thermosetting powder coatings |
EP0365098B1 (en) | 1988-10-21 | 1993-12-08 | Akzo Nobel N.V. | Waterborne coatings and binder systems for use therein |
US5084541A (en) | 1988-12-19 | 1992-01-28 | American Cyanamid Company | Triazine crosslinking agents and curable compositions |
US4997900A (en) | 1988-12-27 | 1991-03-05 | Cargill, Incorporated | Powder coating comprising acetone oxime blocked diisocyanate and polyester |
US4968751A (en) * | 1989-03-20 | 1990-11-06 | The Glidden Company | Acrylic/silicone resins for powder coatings |
US5071904A (en) | 1989-05-30 | 1991-12-10 | Ppg Industries, Inc. | Waterborne coating compositions for automotive applications |
US5202382A (en) | 1989-09-18 | 1993-04-13 | Ppg Industries, Inc. | Thermosetting powder coating composition containing a mixture of low Tg and high Tg polymers with acid functional groups |
US5098955A (en) | 1989-09-18 | 1992-03-24 | Ppg Industries, Inc. | Powder coating composition low Tg and high Tg polymers with acid groups |
US5025085A (en) * | 1989-11-06 | 1991-06-18 | The Lubrizol Corporation | Curable aminoplast compositions and catalysts for curing same |
US5182355A (en) | 1990-04-05 | 1993-01-26 | Ppg Industries, Inc. | Polyurethane polyanhydride oligomers and method of preparation |
JP3097093B2 (ja) | 1990-04-20 | 2000-10-10 | ダイキン工業株式会社 | 含フッ素共重合体およびそれを用いた硬化用組成物 |
US5096556A (en) | 1990-06-25 | 1992-03-17 | Ppg Industries, Inc. | Cationic microgels and their use in electrodeposition |
JPH07110890B2 (ja) * | 1990-06-29 | 1995-11-29 | ダイキン工業株式会社 | 含フッ素共重合体およびそれを用いた塗料用組成物 |
US5216081A (en) * | 1990-06-29 | 1993-06-01 | Daikin Industries, Ltd. | Fluorine-containing copolymer and curable composition containing the same |
US5239012A (en) | 1991-02-21 | 1993-08-24 | Ppg Industries, Inc. | Ambient temperature curing compositions containing a hydroxy component and an anhydride component and an onium salt |
DE4123478A1 (de) | 1991-07-16 | 1993-01-21 | Goldschmidt Ag Th | Polyacrylsaeureester mit quaternaeren ammonium- und langkettigen kohlenwasserstoffoxy-gruppen |
US5424380A (en) | 1991-10-31 | 1995-06-13 | Tosoh Corporation | Resin composition |
US5270391A (en) * | 1991-11-27 | 1993-12-14 | Mitsui Toatsu Chemicals, Inc. | Composition for thermosetting powder coating |
US5508337A (en) | 1992-02-11 | 1996-04-16 | Bayer Aktiengesellschaft | Powder coating compositions, a process for their preparation, and their use for the coating of heat resistant substrates |
US5356973A (en) | 1992-08-31 | 1994-10-18 | Ppg Industries, Inc. | Aqueous based coating compositions having improved metallic pigment orientation |
US5605965A (en) | 1992-10-23 | 1997-02-25 | Basf Corporation | High gloss and/or high DOI coating utilizing carbamate-functional polymer composition |
GB9222490D0 (en) | 1992-10-26 | 1992-12-09 | Rohm & Haas | Means for imparting improved adhesion to polypropylene substrates |
TW242644B (zh) | 1992-10-30 | 1995-03-11 | Ppg Industries Inc | |
DE4306537A1 (de) | 1993-03-03 | 1994-09-08 | Goldschmidt Ag Th | Polymethacrylsäureester, deren Estergruppen in alpha- und gegebenenfalls zusätzlich in omega-Stellung von den in der Kette befindlichen Estergruppen abweichen |
US5407707A (en) | 1993-11-01 | 1995-04-18 | Ppg Industries, Inc. | Powder coating composition based on epoxy containing polymers and polyacid curing agents |
US5554692A (en) | 1994-01-06 | 1996-09-10 | Ferro Corporation | Blocked isocyanate crosslinkers based on pentaerythritol for use in thermosetting coatings |
DE4406157A1 (de) | 1994-02-25 | 1995-08-31 | Bayer Ag | Pulverlack und seine Verwendung |
DE69512902T2 (de) | 1994-04-13 | 2000-05-11 | Ppg Ind Ohio Inc | Wärmehärtende pulverlackzusammensetzungen |
US5976701A (en) | 1994-04-29 | 1999-11-02 | Ppg Industries Ohio, Inc. | Flexible aminoplast-curable film-forming compositions and composite coating |
US5508349A (en) | 1994-05-09 | 1996-04-16 | Basf Corporation | Reactive flow agent for powder coatings |
US5763548A (en) | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
US5807937A (en) | 1995-11-15 | 1998-09-15 | Carnegie Mellon University | Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties |
US5777061A (en) | 1996-02-14 | 1998-07-07 | Bayer Corporation | Blocked polyisocyanate crosslinkers for providing improved flow properties to coating compositions |
AU707368B2 (en) | 1996-02-16 | 1999-07-08 | Ppg Industries Ohio, Inc. | Coating compositions with flow modifiers and the flow modifiers and multilayered coatings |
US5703176B1 (en) | 1996-03-18 | 2000-10-03 | Para Chem Southern Inc | Polyacrylate thickener and method for making same |
US5789487A (en) | 1996-07-10 | 1998-08-04 | Carnegie-Mellon University | Preparation of novel homo- and copolymers using atom transfer radical polymerization |
US5820987A (en) | 1996-08-21 | 1998-10-13 | Ppg Industries, Inc. | Cationic electrocoating compositions, method of making, and use |
US6077608A (en) | 1996-09-19 | 2000-06-20 | Ppg Industries Ohio, Inc. | Multilayered coating with powder clear coating and substrates therewith and method |
US6114489A (en) | 1997-03-27 | 2000-09-05 | Herberts Gmbh | Reactive hyperbranched polymers for powder coatings |
DE19721728C2 (de) | 1997-05-24 | 2001-07-12 | Byk Chemie Gmbh | Dispergiermittel für Pigmente oder Füllstoffe auf der Basis von Acrylsäurealkylester-Polymeren, Verwendung und Verfahren zur Herstellung |
CA2321452C (en) | 1998-02-18 | 2004-05-25 | Ppg Industries Ohio, Inc. | Multi-component composite coating composition and coated substrate |
US6153697A (en) | 1998-03-18 | 2000-11-28 | Ppg Industries Ohio, Inc. | Fluoropolymers and coating compositions |
US6306965B1 (en) | 1998-08-31 | 2001-10-23 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing carbamate-functional polylmers prepared using atom transfer radical polymerization |
US6319987B1 (en) * | 1998-08-31 | 2001-11-20 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing hydroxyl-functional polymers prepared using atom transfer radical polymerization |
US6365666B1 (en) * | 1998-08-31 | 2002-04-02 | Ppg Industries Ohio, Inc. | Electrodepositable coating compositions comprising onium salt group-containing polymers prepared by atom transfer radical polymerization |
US6355729B1 (en) * | 1998-08-31 | 2002-03-12 | Ppg Industries Ohio, Inc. | Electrodepositable coating compositions comprising amine salt group-containing polymers prepared by atom transfer radical polymerization |
US6191225B1 (en) * | 1998-08-31 | 2001-02-20 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing carboxylic acid functional polymers and epoxy functional polymers prepared by atom transfer radical polymerization |
US6111001A (en) | 1998-11-24 | 2000-08-29 | Ppg Industries Ohio, Inc. | Compositions containing rheology modifiers with functional group-containing polymers |
US6069185A (en) | 1998-11-25 | 2000-05-30 | Dow Corning Asia, Ltd. | Radiation curable compositions containing alkenyl ether functional polyisobutylenes |
US6054549A (en) | 1998-11-25 | 2000-04-25 | Dow Corning Asia, Ltd. | Alkenyl ether functional polyisobutylenes and methods for the preparation thereof |
US6197883B1 (en) | 1999-06-03 | 2001-03-06 | Ppg Industries Ohio, Inc. | Thermosetting coating compositions containing flow modifiers prepared by controlled radical polymerization |
DE19928353C1 (de) | 1999-06-21 | 2001-02-22 | Roehm Gmbh | Poly(meth)acrylatplastisole mit verbesserter Weichmacherverträglichkeit, Verfahren zu ihrer Herstellung sowie Verwendung |
US6423778B1 (en) | 1999-06-30 | 2002-07-23 | Basf Corporation | Process for coating olefinic substrates |
US6414077B1 (en) | 1999-07-29 | 2002-07-02 | Schnee-Morehead, Inc. | Moisture curable acrylic sealants |
US6348554B1 (en) * | 1999-11-30 | 2002-02-19 | Rohmax Additives Gmbh | Method for preparation of a liquid polymer composition and use of this composition |
US6451928B1 (en) | 2000-09-21 | 2002-09-17 | Ppg Industries Ohio, Inc. | Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers |
US6875832B2 (en) * | 2001-04-24 | 2005-04-05 | Ppg Industries Ohio, Inc. | Synthesis of vinyl polymers by controlled radical polymerization |
US6784248B2 (en) * | 2002-02-15 | 2004-08-31 | Ppg Industries Ohio, Inc. | Thermosetting compositions containing alternating copolymers of isobutylene type monomers |
US6677422B2 (en) * | 2002-02-15 | 2004-01-13 | Ppg Industries Ohio, Inc. | Method of making alternating copolymers of isobutylene type monomers |
US6686432B2 (en) * | 2002-02-15 | 2004-02-03 | Ppg Industries Ohio, Inc. | Alternating copolymers of isobutylene type monomers |
CA2476302C (en) * | 2002-02-15 | 2010-09-21 | Ppg Industries Ohio, Inc. | Waterborne thermosetting compositions containing alternating copolymers of isobutylene type monomers |
-
2002
- 2002-02-15 US US10/077,645 patent/US6784248B2/en not_active Expired - Fee Related
-
2003
- 2003-01-21 US US10/348,367 patent/US6900279B2/en not_active Expired - Fee Related
- 2003-01-29 EP EP20030742703 patent/EP1474454B1/en not_active Expired - Fee Related
- 2003-01-29 CN CNB038050501A patent/CN1300185C/zh not_active Expired - Fee Related
- 2003-01-29 DE DE60330118T patent/DE60330118D1/de not_active Expired - Lifetime
- 2003-01-29 CA CA 2476090 patent/CA2476090C/en not_active Expired - Fee Related
- 2003-01-29 WO PCT/US2003/002629 patent/WO2003070781A1/en active Application Filing
- 2003-01-29 KR KR1020047012717A patent/KR100611868B1/ko not_active IP Right Cessation
- 2003-01-29 JP JP2003569688A patent/JP3993563B2/ja not_active Expired - Fee Related
- 2003-01-29 ES ES03742703T patent/ES2334562T3/es not_active Expired - Lifetime
- 2003-01-29 BR BR0307577A patent/BR0307577A/pt not_active Application Discontinuation
- 2003-01-29 AU AU2003210715A patent/AU2003210715B2/en not_active Ceased
- 2003-02-04 US US10/357,580 patent/US6803426B2/en not_active Expired - Fee Related
- 2003-02-04 US US10/357,817 patent/US6784247B2/en not_active Expired - Fee Related
- 2003-02-04 US US10/358,041 patent/US6803413B2/en not_active Expired - Fee Related
- 2003-02-04 US US10/357,791 patent/US7019041B2/en not_active Expired - Fee Related
- 2003-02-12 CA CA 2476079 patent/CA2476079A1/en not_active Abandoned
- 2003-02-12 ES ES03742725T patent/ES2311716T3/es not_active Expired - Lifetime
- 2003-02-12 AU AU2003216252A patent/AU2003216252A1/en not_active Abandoned
- 2003-02-12 JP JP2003569730A patent/JP4219277B2/ja not_active Expired - Fee Related
- 2003-02-12 DE DE60322666T patent/DE60322666D1/de not_active Expired - Fee Related
- 2003-02-12 WO PCT/US2003/004193 patent/WO2003070826A2/en active Application Filing
- 2003-02-12 DE DE60325553T patent/DE60325553D1/de not_active Expired - Lifetime
- 2003-02-12 EP EP20030742725 patent/EP1474479B1/en not_active Expired - Fee Related
- 2003-02-12 ES ES03742724T patent/ES2318146T3/es not_active Expired - Lifetime
- 2003-02-13 DE DE60322022T patent/DE60322022D1/de not_active Expired - Lifetime
- 2003-02-13 ES ES03709071T patent/ES2309302T3/es not_active Expired - Lifetime
- 2003-02-14 TW TW92103067A patent/TWI312358B/zh not_active IP Right Cessation
-
2004
- 2004-07-09 US US10/887,693 patent/US7122600B2/en not_active Expired - Fee Related
- 2004-07-09 US US10/887,733 patent/US7125931B2/en not_active Expired - Fee Related
- 2004-07-09 US US10/887,682 patent/US7132476B2/en not_active Expired - Fee Related
-
2006
- 2006-10-31 JP JP2006297171A patent/JP2007023300A/ja active Pending
-
2007
- 2007-07-05 JP JP2007177830A patent/JP2007332381A/ja active Pending
-
2009
- 2009-04-16 JP JP2009100406A patent/JP2009155664A/ja not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1213171A (en) * | 1967-02-28 | 1970-11-18 | Du Pont | Polymerisation process |
GB1339981A (en) * | 1970-03-04 | 1973-12-05 | Sumitomo Chemical Co | Curable copolymers |
US5115083A (en) * | 1989-11-06 | 1992-05-19 | The Lubrizol Corporation | Curable aminoplast compositions and catalysts for curing same |
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1300185C (zh) | 含有异丁烯型单体交替共聚物的热固性组合物 | |
CN1305920C (zh) | 异丁烯型单体的交替共聚物 | |
CN100335519C (zh) | 含有聚氨酯分散体和高度交联的聚合物颗粒的涂料组合物 | |
CN1105759C (zh) | 防污染涂料组合物 | |
CN1163559C (zh) | 涂料组合物及制法和无机氧化物溶胶分散组分的制法 | |
CN1209392C (zh) | 由含侧氟碳基的环状单体得到的聚合物表面活性剂 | |
CN1117126C (zh) | 污染附着防止剂和涂料用组合物 | |
CN1188478C (zh) | 预油漆和从预油漆制备油漆的方法 | |
CN1128849C (zh) | 适合用于电沉积的阳离子树脂和封闭的多异氰酸酯固化剂 | |
CN1131876C (zh) | 水性反应性腻子(ⅰ) | |
CN1073137C (zh) | 水基涂料用固化性树脂组合物 | |
CN1246366C (zh) | 嵌段聚合物和包含它的抗静电剂 | |
CN1055944C (zh) | 涂料组合物及涂覆物 | |
CN1246401C (zh) | 梳形共聚物的水分散体和由它生产的涂料 | |
CN1656126A (zh) | 高度交联的聚合物颗粒和含有该颗粒的涂料组合物 | |
CN1231514C (zh) | 高官能度的低粘度多异氰酸酯组合物及其制备方法 | |
CN1654570A (zh) | 金属底漆组合物和生产复合涂膜的方法 | |
CN1742064A (zh) | 涂料组合物 | |
CN101065454A (zh) | 复合粉体涂料、其制造方法及粉体涂料的调色方法 | |
CN1639210A (zh) | 异丁烯型单体交替共聚物的制造方法 | |
CN1087361A (zh) | 含有复合聚合物颗粒的涂料组合物 | |
CN1041839C (zh) | 可用于阴极电泳涂漆的可控制成膜的环氧涂料的混合物 | |
CN1069672C (zh) | 热固性粉末涂料、该涂料的涂覆方法以及采用这种涂料涂覆的物品 | |
CN1032478C (zh) | 着色的涂料组合物及其制备方法和用途 | |
CN1894299A (zh) | 无溶剂型聚氨酯系组合物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: PPG industrial coatings (Suzhou) Co., Ltd. Assignor: PPG Industries, Inc. Contract record no.: 2012990000290 Denomination of invention: Thermosetting compositions containing alternating copolymers of isobutylene type monomers Granted publication date: 20070214 License type: Common License Open date: 20050713 Record date: 20120504 |
|
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: PPG Ind Ohio Inc. Assignor: PPG Industries, Inc. Contract record no.: 2012990000336 Denomination of invention: Thermosetting compositions containing alternating copolymers of isobutylene type monomers Granted publication date: 20070214 License type: Common License Open date: 20050713 Record date: 20120521 |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070214 Termination date: 20150129 |
|
EXPY | Termination of patent right or utility model | ||
EC01 | Cancellation of recordation of patent licensing contract |
Assignee: PPG industrial coatings (Suzhou) Co., Ltd. Assignor: PPG Industries, Inc. Contract record no.: 2012990000290 Date of cancellation: 20170228 |
|
LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
EC01 | Cancellation of recordation of patent licensing contract | ||
EC01 | Cancellation of recordation of patent licensing contract |
Assignee: PPG Ind Ohio Inc. Assignor: PPG Industries, Inc. Contract record no.: 2012990000336 Date of cancellation: 20170320 |