DE60139901D1 - Halogenierte elastomere zusammensetzungen mit verbesserter stabilität und grünfestigkeit - Google Patents
Halogenierte elastomere zusammensetzungen mit verbesserter stabilität und grünfestigkeitInfo
- Publication number
- DE60139901D1 DE60139901D1 DE60139901T DE60139901T DE60139901D1 DE 60139901 D1 DE60139901 D1 DE 60139901D1 DE 60139901 T DE60139901 T DE 60139901T DE 60139901 T DE60139901 T DE 60139901T DE 60139901 D1 DE60139901 D1 DE 60139901D1
- Authority
- DE
- Germany
- Prior art keywords
- sup
- sub
- rubber
- halogenated
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/283—Halogenated homo- or copolymers of iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/686,215 US6552108B1 (en) | 2000-10-11 | 2000-10-11 | Rubber blends having improved stability and green strength |
PCT/US2001/031431 WO2002031039A1 (en) | 2000-10-11 | 2001-10-09 | Halogenated elastomeric compositions having improved stability and green strength |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60139901D1 true DE60139901D1 (de) | 2009-10-22 |
Family
ID=24755410
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60139901T Expired - Lifetime DE60139901D1 (de) | 2000-10-11 | 2001-10-09 | Halogenierte elastomere zusammensetzungen mit verbesserter stabilität und grünfestigkeit |
Country Status (16)
Country | Link |
---|---|
US (2) | US6552108B1 (de) |
EP (1) | EP1353989B1 (de) |
JP (1) | JP4059765B2 (de) |
KR (1) | KR20040005835A (de) |
CN (1) | CN1247678C (de) |
AT (1) | ATE442412T1 (de) |
AU (1) | AU2001296712A1 (de) |
BR (1) | BR0114409A (de) |
CA (1) | CA2423206C (de) |
CZ (1) | CZ20031000A3 (de) |
DE (1) | DE60139901D1 (de) |
HU (1) | HUP0302689A2 (de) |
MX (1) | MXPA03003194A (de) |
PL (1) | PL365611A1 (de) |
RU (1) | RU2320687C2 (de) |
WO (1) | WO2002031039A1 (de) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6552108B1 (en) | 2000-10-11 | 2003-04-22 | Exxonmobil Chemical Patents Inc. | Rubber blends having improved stability and green strength |
CA2448615C (en) * | 2001-06-08 | 2012-05-22 | Exxonmobil Chemical Patents Inc. | Low permeability nanocomposites |
EP1599534B1 (de) * | 2003-03-06 | 2010-05-26 | ExxonMobil Chemical Patents Inc. | Thermoplastische elastomerzusammensetzung mit viskositätsverstärkten und vulkanisierten elastomerdispersionen |
CA2465301C (en) * | 2004-04-28 | 2012-02-07 | John Scott Parent | Process to produce silica-filled elastomeric compounds |
WO2007022619A1 (en) * | 2005-08-26 | 2007-03-01 | Lanxess Inc. | Peroxide curable rubber compound containing high multiolefin halobutyl ionomers |
KR20080039436A (ko) * | 2005-08-26 | 2008-05-07 | 란세스 인크. | 퍼옥시드 경화성 고 멀티올레핀 할로부틸 이오노머의 제조방법 |
CA2637854A1 (en) * | 2005-08-26 | 2007-03-01 | Lanxess Inc. | Peroxide curable rubber compound containing high multiolefin halobutyl ionomers |
CA2578583C (en) | 2006-03-14 | 2014-06-03 | Lanxess Inc. | Butyl ionomer having improved surface adhesion |
DE602007010347D1 (de) * | 2006-12-29 | 2010-12-16 | Bridgestone Americas Tire | Reifeninnenmantel |
KR100871991B1 (ko) * | 2007-09-27 | 2008-12-05 | 금호타이어 주식회사 | 타이어 트레드 고무조성물 |
WO2009057369A1 (ja) * | 2007-11-02 | 2009-05-07 | Sumitomo Rubber Industries, Ltd. | 空気入りタイヤ |
JP4291399B2 (ja) | 2007-11-02 | 2009-07-08 | 住友ゴム工業株式会社 | 空気入りタイヤ |
EP2209818B1 (de) * | 2007-11-14 | 2011-06-08 | ExxonMobil Chemical Patents Inc. | Triethylaminfunktionalisiertes elastomer bei barriereanwendungen |
US8026304B2 (en) * | 2008-07-14 | 2011-09-27 | Acushnet Company | Partially or fully neutralized butyl ionomers in golf ball layers |
CN101864129B (zh) * | 2010-07-21 | 2012-01-25 | 天津市天塑科技集团有限公司第四塑料制品厂 | 一种丁腈橡胶改性的聚氯乙烯土工膜 |
PL2603556T3 (pl) * | 2010-08-13 | 2017-08-31 | Arlanxeo Deutschland Gmbh | Lateks butylojonomerowy |
RU2570045C2 (ru) * | 2011-04-21 | 2015-12-10 | Дзе Йокогама Раббер Ко., Лтд. | Термопластическая эластомерная композиция |
US8673995B2 (en) | 2011-06-20 | 2014-03-18 | 3M Innovative Properties Company | Radiation curable poly(isobutylene) adhesive copolymers having pendent amine groups |
US20120322910A1 (en) * | 2011-06-20 | 2012-12-20 | Joon Chatterjee | Radiation curable poly(isobutylene) adhesive copolymers having pendent amine groups |
CN102850621B (zh) * | 2012-08-30 | 2014-05-07 | 苏州市德莱尔建材科技有限公司 | 一种抗车辙添加剂 |
CA2894389A1 (en) * | 2012-12-18 | 2014-06-26 | Lanxess Butyl Pte. Ltd. | Transparent peroxide curable butyl rubber |
RU2656050C2 (ru) * | 2012-12-18 | 2018-05-30 | Лэнксесс Бутил Пте. Лтд. | Бутилкаучук с повышенной непроницаемостью |
KR102229517B1 (ko) * | 2012-12-20 | 2021-03-18 | 란세스 부틸 피티이. 리미티드 | 펜던트 비닐 기를 포함하는 이오노머 및 그의 제조 방법 |
CN104903398A (zh) * | 2012-12-26 | 2015-09-09 | 普利司通美国轮胎运营有限责任公司 | 用于含抗降解剂的橡胶组合物的外观增强剂 |
EP2987828A1 (de) * | 2014-08-22 | 2016-02-24 | Lanxess Inc. | Butyl-Ionomer-Mischungen |
US10479845B2 (en) | 2014-09-30 | 2019-11-19 | Exxonmobil Chemical Patents Inc. | Process for preparing a halogenated elastomer with improved Mooney viscosity stability |
RU2563017C1 (ru) * | 2014-10-13 | 2015-09-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Волгоградский государственный технический университет" (ВолгГТУ) | Способ приготовления резиновой смеси на основе хлоропренового каучука |
RU2563018C1 (ru) * | 2014-10-13 | 2015-09-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Волгоградский государственный технический университет" (ВолгГТУ) | Способ приготовления резиновой смеси на основе хлоропренового каучука |
CN104592704B (zh) * | 2015-02-06 | 2016-08-24 | 苏州欢颜电气有限公司 | 电气工程用防潮绝缘材料 |
US10035383B2 (en) | 2015-08-13 | 2018-07-31 | The Goodyear Tire & Rubber Company | Pneumatic tire with post cure sealant layer |
CN106566095A (zh) * | 2016-10-28 | 2017-04-19 | 无锡市永兴金属软管有限公司 | 一种蒸气软管用丁基橡胶 |
US10889704B2 (en) | 2017-05-22 | 2021-01-12 | Exxonmobil Chemical Patents Inc. | Halogenated elastomers with Mooney viscosity stability and method for preparing same |
CN112135848B (zh) * | 2018-04-03 | 2023-08-29 | 埃克森美孚化学专利公司 | 具有烯属侧链取代基的基于异丁烯的聚合物及含有它的可固化组合物 |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
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FR65758E (de) | 1950-04-18 | 1956-03-12 | ||
US2732354A (en) | 1952-12-05 | 1956-01-24 | Chlorine derivatives of isoolefem-poly- | |
NL207586A (de) | 1955-05-31 | |||
US2964489A (en) | 1956-07-16 | 1960-12-13 | Exxon Research Engineering Co | Process of chlorinating butyl rubber and vulcanizing the chlorinated product |
US3011996A (en) | 1957-04-15 | 1961-12-05 | Exxon Research Engineering Co | Process of reacting a tertiary amine with a halogenated copolymer of an isoolefin monomer and a multiolefin monomer, and product thereof |
US3037954A (en) | 1958-12-15 | 1962-06-05 | Exxon Research Engineering Co | Process for preparing a vulcanized blend of crystalline polypropylene and chlorinated butyl rubber |
US3099644A (en) | 1959-10-06 | 1963-07-30 | Exxon Research Engineering Co | Continuous chlorination and bromination of butyl rubber |
US3943664A (en) | 1971-07-19 | 1976-03-16 | Pinkhus Ruvimovich Broide | Profile-grinding machine |
CA1030699A (en) | 1973-11-08 | 1978-05-02 | Polysar Limited | Halobutyl of improved green strength |
CA1019094A (en) | 1973-11-08 | 1977-10-11 | Ernest J. Buckler | Remoldable halobutyl rubbers |
CA1014296A (en) | 1973-11-08 | 1977-07-19 | Ernest J. Buckler | Amine modified polymers |
US4130535A (en) * | 1975-07-21 | 1978-12-19 | Monsanto Company | Thermoplastic vulcanizates of olefin rubber and polyolefin resin |
US4130534A (en) * | 1976-12-27 | 1978-12-19 | Monsanto Company | Elastoplastic compositions of butyl rubber and polyolefin resin |
US4130354A (en) | 1977-08-30 | 1978-12-19 | Xerox Corporation | Reproduction machine having duplex job recovery capabilities |
US4454304A (en) * | 1981-04-22 | 1984-06-12 | Copolymer Rubber & Chemical Corp. | Method and material for producing high green strength rubber compounds |
US4594390A (en) | 1982-08-23 | 1986-06-10 | Monsanto Company | Process for the preparation of thermoplastic elastomers |
US5177147A (en) | 1986-03-03 | 1993-01-05 | Advanced Elastomer Systems, Lp | Elastomer-plastic blends |
US5162445A (en) | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
US5654379A (en) | 1987-11-27 | 1997-08-05 | Exxon Chemicals Patent, Inc. | Process for selective bromination of para-alkylstyrene/isoolefin copolymers |
US6013727A (en) | 1988-05-27 | 2000-01-11 | Exxon Chemical Patents, Inc. | Thermoplastic blend containing engineering resin |
US5013793A (en) | 1990-07-26 | 1991-05-07 | Exxon Chemical Patents Inc. | Dynamically cured thermoplastic olefin polymers and process for producing the same |
US5021500A (en) | 1988-10-28 | 1991-06-04 | Exxon Chemical Company | Dynamically vulcanized alloys of crystalline polyolefin resin and halobutyl rubber material |
US5043392A (en) | 1989-04-19 | 1991-08-27 | Polysar Limited | Toughened thermoplastics |
US4921910A (en) | 1989-04-19 | 1990-05-01 | Polysar Limited | Toughened thermoplastics |
US5073597A (en) | 1989-05-26 | 1991-12-17 | Advanced Elastomer Systems, L. P. | Dynamically vulcanized alloys having two copolymers in the crosslinked phase and a crystalline matrix |
US5051477A (en) | 1990-05-04 | 1991-09-24 | Advanced Elastomer Systems, L. P. | Dynamically cured thermoplastic olefin polymers and process for producing the same |
US5333662A (en) | 1990-07-18 | 1994-08-02 | Exxon Chemical Patents Inc. | Tire innerliner composition |
US5660827A (en) * | 1992-03-05 | 1997-08-26 | Board Of Regents, The University Of Texas System | Antibodies that bind to endoglin |
WO1994010214A1 (en) | 1992-11-02 | 1994-05-11 | Exxon Chemical Patents Inc. | Polymeric phosphonium ionomers |
US5290886A (en) | 1993-04-20 | 1994-03-01 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved low temperature properties |
US5428099A (en) | 1993-05-19 | 1995-06-27 | Exxon Chemical Patents Inc. | Method to control carbon black distribution in elastomer blends |
US5597866A (en) | 1995-06-30 | 1997-01-28 | Exxon Chemical Patents Inc. | Propylene polymer compositions having improved impact strength |
US5910543A (en) | 1996-12-18 | 1999-06-08 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomer with polar and non-polar rubber components |
US6060563A (en) | 1997-05-23 | 2000-05-09 | Exxon Research And Engineering Co | Graft copolymers containing ionomer units |
US6552108B1 (en) | 2000-10-11 | 2003-04-22 | Exxonmobil Chemical Patents Inc. | Rubber blends having improved stability and green strength |
US7019058B2 (en) | 2000-10-11 | 2006-03-28 | Exxonmobil Chemical Patents, Inc. | Halogenated elastomeric compositions having enhanced viscosity |
DE60116368T2 (de) | 2000-10-11 | 2006-07-06 | Exxonmobil Chemical Patents Inc., Baytown | Thermoplastische zusammensetzungen aus halogenierten elastomeren |
-
2000
- 2000-10-11 US US09/686,215 patent/US6552108B1/en not_active Expired - Fee Related
-
2001
- 2001-10-09 US US10/398,302 patent/US6956075B2/en not_active Expired - Fee Related
- 2001-10-09 WO PCT/US2001/031431 patent/WO2002031039A1/en active Application Filing
- 2001-10-09 CA CA002423206A patent/CA2423206C/en not_active Expired - Fee Related
- 2001-10-09 AU AU2001296712A patent/AU2001296712A1/en not_active Abandoned
- 2001-10-09 CN CNB018171923A patent/CN1247678C/zh not_active Expired - Fee Related
- 2001-10-09 MX MXPA03003194A patent/MXPA03003194A/es not_active Application Discontinuation
- 2001-10-09 RU RU2003110956/04A patent/RU2320687C2/ru not_active IP Right Cessation
- 2001-10-09 CZ CZ20031000A patent/CZ20031000A3/cs unknown
- 2001-10-09 AT AT01977606T patent/ATE442412T1/de not_active IP Right Cessation
- 2001-10-09 JP JP2002534415A patent/JP4059765B2/ja not_active Expired - Fee Related
- 2001-10-09 BR BR0114409-0A patent/BR0114409A/pt not_active IP Right Cessation
- 2001-10-09 PL PL01365611A patent/PL365611A1/xx not_active Application Discontinuation
- 2001-10-09 EP EP01977606A patent/EP1353989B1/de not_active Expired - Lifetime
- 2001-10-09 DE DE60139901T patent/DE60139901D1/de not_active Expired - Lifetime
- 2001-10-09 KR KR10-2003-7005136A patent/KR20040005835A/ko not_active Application Discontinuation
- 2001-10-09 HU HU0302689A patent/HUP0302689A2/hu unknown
Also Published As
Publication number | Publication date |
---|---|
ATE442412T1 (de) | 2009-09-15 |
CA2423206C (en) | 2009-12-15 |
HUP0302689A2 (hu) | 2003-11-28 |
US20040097654A1 (en) | 2004-05-20 |
AU2001296712A1 (en) | 2002-04-22 |
EP1353989A4 (de) | 2004-05-26 |
RU2320687C2 (ru) | 2008-03-27 |
JP2004514744A (ja) | 2004-05-20 |
JP4059765B2 (ja) | 2008-03-12 |
WO2002031039A1 (en) | 2002-04-18 |
PL365611A1 (en) | 2005-01-10 |
CN1247678C (zh) | 2006-03-29 |
MXPA03003194A (es) | 2004-05-21 |
EP1353989A1 (de) | 2003-10-22 |
BR0114409A (pt) | 2003-12-30 |
US6956075B2 (en) | 2005-10-18 |
EP1353989B1 (de) | 2009-09-09 |
KR20040005835A (ko) | 2004-01-16 |
CN1469897A (zh) | 2004-01-21 |
CA2423206A1 (en) | 2002-04-18 |
CZ20031000A3 (cs) | 2003-11-12 |
US6552108B1 (en) | 2003-04-22 |
RU2003110956A (ru) | 2005-01-27 |
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