DE68920043T2 - Verfahren zur selektiven diisopropylierung von naphthylverbindungen unter verwendung von formselektiven, sauren, kristallinen molekularsiebkatalysatoren. - Google Patents

Verfahren zur selektiven diisopropylierung von naphthylverbindungen unter verwendung von formselektiven, sauren, kristallinen molekularsiebkatalysatoren.

Info

Publication number
DE68920043T2
DE68920043T2 DE68920043T DE68920043T DE68920043T2 DE 68920043 T2 DE68920043 T2 DE 68920043T2 DE 68920043 T DE68920043 T DE 68920043T DE 68920043 T DE68920043 T DE 68920043T DE 68920043 T2 DE68920043 T2 DE 68920043T2
Authority
DE
Germany
Prior art keywords
diisopropylation
selectives
selective
acids
molecular screen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE68920043T
Other languages
English (en)
Other versions
DE68920043D1 (de
Inventor
Jere Fellmann
Robert Saxton
Paul Wentrcek
Eric Derouane
Pascale Massiani
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koch Chemical Co
Original Assignee
Catalytica Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Catalytica Inc filed Critical Catalytica Inc
Publication of DE68920043D1 publication Critical patent/DE68920043D1/de
Application granted granted Critical
Publication of DE68920043T2 publication Critical patent/DE68920043T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/20—Polycyclic condensed hydrocarbons
    • C07C15/24—Polycyclic condensed hydrocarbons containing two rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/68—Catalytic processes with halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/14—After treatment, characterised by the effect to be obtained to alter the inside of the molecular sieve channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/34—Reaction with organic or organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
DE68920043T 1988-10-05 1989-10-05 Verfahren zur selektiven diisopropylierung von naphthylverbindungen unter verwendung von formselektiven, sauren, kristallinen molekularsiebkatalysatoren. Expired - Fee Related DE68920043T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/254,284 US5003122A (en) 1988-10-05 1988-10-05 Process for selective diisopropylation of naphthyl compounds using shape selective acidic crystalline molecular sieve catalysts
PCT/US1989/004485 WO1990003961A1 (en) 1988-10-05 1989-10-05 Process for selective diisopropylation of naphthyl compounds using shape selective acidic crystalline molecular sieve catalysts

Publications (2)

Publication Number Publication Date
DE68920043D1 DE68920043D1 (de) 1995-01-26
DE68920043T2 true DE68920043T2 (de) 1995-05-04

Family

ID=22963676

Family Applications (1)

Application Number Title Priority Date Filing Date
DE68920043T Expired - Fee Related DE68920043T2 (de) 1988-10-05 1989-10-05 Verfahren zur selektiven diisopropylierung von naphthylverbindungen unter verwendung von formselektiven, sauren, kristallinen molekularsiebkatalysatoren.

Country Status (8)

Country Link
US (1) US5003122A (de)
EP (1) EP0437517B1 (de)
JP (1) JP2656641B2 (de)
KR (1) KR920700177A (de)
AU (1) AU4408689A (de)
CA (1) CA1327611C (de)
DE (1) DE68920043T2 (de)
WO (1) WO1990003961A1 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5175135A (en) * 1987-11-23 1992-12-29 The Dow Chemical Company Alkylation of aromatic compounds to alkylates enriched in the linear substituted isomers
US5198595A (en) * 1987-11-23 1993-03-30 The Dow Chemical Company Alkylation of aromatic compounds
JPH02295936A (ja) * 1989-05-10 1990-12-06 Agency Of Ind Science & Technol ２，６―ジアルキルナフタレンの製造方法
US5268523A (en) * 1989-07-24 1993-12-07 Catalytica, Inc. Selective sorption of dialkylated multinuclear aromatic compounds
JP2546545B2 (ja) * 1990-02-02 1996-10-23 株式会社日本触媒 アルキルナフタレン類の製造方法
JPH0441446A (ja) * 1990-06-06 1992-02-12 Mitsubishi Materials Corp ジアルキルナフタレンの製造方法及びその触媒
CA2093511C (en) * 1991-08-08 1999-09-21 Koji Sumitani Process for producing dialkylnaphthalene
ATE166638T1 (de) * 1991-08-21 1998-06-15 Solutia Europ Nv Sa Katalytischer prozess zur selektiven alkylierung polyzyklischer, aromatischer verbindungen
JPH05221885A (ja) * 1992-02-13 1993-08-31 Nkk Corp アルキルベンゼン中に共存するアルキルテトラリンの除去方法
ES2197499T3 (es) * 1997-08-18 2004-01-01 Exxonmobil Chemical Patents Inc. Procedimiento para alquilar un compuesto aromatico con una corriente diluida que comprende propileno y etileno.
US6018086A (en) 1997-10-10 2000-01-25 Kabushiki Kaisha Kobe Seiko Sho Process for preparing 2,6-dialkylnaphthalene
IT1300061B1 (it) * 1998-04-17 2000-04-19 Eniricerche S P A Ora Enitecno Processo per preparare 2,6-dimetilnaftalene
CN105218290A (zh) * 2014-07-03 2016-01-06 中国石油化工股份有限公司 萘和多异丙苯液相烷基转移反应制备二异丙基萘的方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3251897A (en) * 1962-12-20 1966-05-17 Socony Mobil Oil Co Inc Alkylation of aromatic compounds in the presence of an alumino-silicate catalyst
US3504046A (en) * 1968-04-26 1970-03-31 American Cyanamid Co Alkylation of naphthalene with propylene in the presence of phosphoric acid catalyst
US3631120A (en) * 1969-06-13 1971-12-28 Exxon Research Engineering Co Alkylation of aromatic hydrocarbons
US3637884A (en) * 1970-05-08 1972-01-25 Universal Oil Prod Co Hf alkylation of naphthalene
JPS579222B2 (de) * 1973-05-25 1982-02-20
JPS5011379A (de) * 1973-05-30 1975-02-05
US4064068A (en) * 1975-07-30 1977-12-20 Sun Oil Company Of Pennsylvania Preparation of isopropylnaphthalene mixture
US4026959A (en) * 1976-05-07 1977-05-31 American Cyanamid Company Low temperature isomerization process for isopropylnaphthalene (100 percent sieve catalyst)
CA1135286A (en) * 1978-12-14 1982-11-09 Mobil Oil Corporation Alkylation of aromatic hydrocarbons
US4288646A (en) * 1979-10-05 1981-09-08 Pcuk Produits Chimiques Ugine Kuhlmann Regioselective preparation of β-isopropylnaphthalene over superacidic solid or supported perfluorinated sulfonic acid catalysts
US4413544A (en) * 1982-01-18 1983-11-08 The Marmon Group, Inc. Single channel string ensemble sound system for an electronic musical instrument
EP0086543B1 (de) * 1982-02-17 1986-05-07 Stamicarbon B.V. Kristalline Silikatkatalysatoren mit entaktivierter Aussenoberfläche und Verfahren zu deren Entaktivierung
US4415544A (en) * 1982-05-27 1983-11-15 Mobil Oil Corporation Modification of catalytic activity of porous zeolites
US4440871A (en) * 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4567029A (en) * 1983-07-15 1986-01-28 Union Carbide Corporation Crystalline metal aluminophosphates
DE3681493D1 (de) * 1985-04-22 1991-10-24 Ici Plc Alkylierungsverfahren.
JPS62226931A (ja) * 1986-03-29 1987-10-05 Nippon Steel Chem Co Ltd ２．６−ジイソプロピルナフタレンの製造方法
JPH064546B2 (ja) * 1986-07-08 1994-01-19 東ソー株式会社 モノ及び／又はジアルキルナフタレンの製造方法
DE3703291A1 (de) * 1987-02-04 1988-08-18 Ruetgerswerke Ag Verfahren zur herstellung von 2,6-dialkylnaphthalin
JPH0764760B2 (ja) * 1987-03-13 1995-07-12 呉羽化学工業株式会社 ビフェニルのパラ選択的アルキル化方法
US4891448A (en) * 1987-11-23 1990-01-02 The Dow Chemical Company Alkylation of polycyclic aromatic compounds to alkylates enriched in the para-substituted isomers
JPS63288582A (ja) * 1988-03-29 1988-11-25 Minolta Camera Co Ltd イメージセンサ

Also Published As

Publication number Publication date
US5003122A (en) 1991-03-26
KR920700177A (ko) 1992-02-19
WO1990003961A1 (en) 1990-04-19
DE68920043D1 (de) 1995-01-26
AU4408689A (en) 1990-05-01
EP0437517A1 (de) 1991-07-24
JP2656641B2 (ja) 1997-09-24
EP0437517A4 (en) 1991-11-06
EP0437517B1 (de) 1994-12-14
CA1327611C (en) 1994-03-08
JPH04500808A (ja) 1992-02-13

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: KOCH CHEMICAL CO., CORPUS CHRISTI, US

8328 Change in the person/name/address of the agent

Free format text: EISENFUEHR, SPEISER & PARTNER, 28195 BREMEN

8339 Ceased/non-payment of the annual fee