DE69028509D1 - Katalysator und Prepolymer für Herstellung von Polyolefinen - Google Patents

Katalysator und Prepolymer für Herstellung von Polyolefinen

Info

Publication number
DE69028509D1
DE69028509D1 DE69028509T DE69028509T DE69028509D1 DE 69028509 D1 DE69028509 D1 DE 69028509D1 DE 69028509 T DE69028509 T DE 69028509T DE 69028509 T DE69028509 T DE 69028509T DE 69028509 D1 DE69028509 D1 DE 69028509D1
Authority
DE
Germany
Prior art keywords
catalyst
prepolymer
solid catalyst
copolymer
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69028509T
Other languages
English (en)
Other versions
DE69028509T2 (de
Inventor
Jean-Claude Andre Bailly
Philippe Bres
Christine Chabrand
Erick Daire
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of DE69028509D1 publication Critical patent/DE69028509D1/de
Application granted granted Critical
Publication of DE69028509T2 publication Critical patent/DE69028509T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69028509T 1989-12-22 1990-12-13 Katalysator und Prepolymer für Herstellung von Polyolefinen Expired - Fee Related DE69028509T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8917402A FR2656314B1 (fr) 1989-12-22 1989-12-22 Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.

Publications (2)

Publication Number Publication Date
DE69028509D1 true DE69028509D1 (de) 1996-10-17
DE69028509T2 DE69028509T2 (de) 1997-02-06

Family

ID=9389117

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69028509T Expired - Fee Related DE69028509T2 (de) 1989-12-22 1990-12-13 Katalysator und Prepolymer für Herstellung von Polyolefinen

Country Status (19)

Country Link
US (2) US5106804A (de)
EP (1) EP0436326B1 (de)
JP (1) JPH04211404A (de)
KR (1) KR910011913A (de)
CN (1) CN1053433A (de)
AT (1) ATE142651T1 (de)
AU (1) AU646004B2 (de)
CA (1) CA2032619A1 (de)
DE (1) DE69028509T2 (de)
ES (1) ES2091229T3 (de)
FI (1) FI906298A (de)
FR (1) FR2656314B1 (de)
HU (1) HU208981B (de)
MY (1) MY105298A (de)
NO (1) NO176571C (de)
PL (1) PL288414A1 (de)
PT (1) PT96343B (de)
SG (1) SG44346A1 (de)
ZA (1) ZA9010048B (de)

Families Citing this family (153)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6025448A (en) 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
FR2659336B1 (fr) * 1990-03-12 1993-05-07 Bp Chemicals Snc Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2659337B1 (fr) * 1990-03-12 1992-06-05 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
IT1240613B (it) * 1990-03-26 1993-12-17 Enichem Anic Spa Catalizzatore supportato per la polimerizzazione e la copolimerizzazione di composti olefinicamente insaturi, e procedimento di (co) polimerizzazione impiegante lo stesso
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
EP0578838A1 (de) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung
EP0609439B1 (de) * 1992-05-28 1996-11-27 Idemitsu Petrochemical Co., Ltd. Verfahren zur herstellung von polyolefin
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
WO1994025495A1 (en) * 1993-05-20 1994-11-10 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5397757A (en) * 1993-10-27 1995-03-14 Mobil Oil Corporation Cocatalysts for metallocene-based olefin polymerization catalyst systems
DE4337985A1 (de) * 1993-11-06 1995-05-11 Hoechst Ag Verfahren zur Herstellung eines Poly-1-olefins
FI95276C (fi) * 1993-12-03 1996-01-10 Borealis As Olefiinien polymerointikatalyytti ja menetelmä sen valmistamiseksi
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1269837B (it) * 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
US5498581A (en) 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US5468702A (en) * 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
US5712353A (en) * 1994-10-31 1998-01-27 Exxon Chemical Patents Inc. Gas phase polymerization process
TW369547B (en) * 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
US5585184A (en) * 1994-09-29 1996-12-17 Union Carbide Chemicals & Plastics Technology Corporation Colorable non-sticky resin core-shell particles
CN1044609C (zh) * 1994-11-07 1999-08-11 中国科学院化学研究所 乙烯聚合载体锆茂催化剂体系及其制法和用途
US5670589A (en) * 1995-02-08 1997-09-23 Phillips Petroleum Company Organoaluminoxy product, catalyst systems, preparation, and use
US6533988B2 (en) 1995-05-02 2003-03-18 Borealis Technology Oy Rotational moulding process of ethylene polymers or copolymers having a controlled particle size and morphology
FI105195B (fi) * 1995-05-02 2000-06-30 Borealis As Polyeteeni, jolla on hallittu partikkelikoko ja morfologia
US5705578A (en) * 1995-05-04 1998-01-06 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US6399533B2 (en) * 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
US5565395A (en) * 1995-05-26 1996-10-15 Albemarle Corporation Aluminoxanate compositions
CN1069100C (zh) * 1995-06-16 2001-08-01 中国石油化工集团公司北京化工研究院 一种复合型固体催化剂与其制法及用途
KR970015606A (ko) * 1995-09-01 1997-04-28 윤덕용 폴리올레핀 중합용 메탈로센 담지촉매의 제조방법
US5670682A (en) * 1995-10-19 1997-09-23 Albemarle Corporation Liquid clathrate aluminoxane compositions
US5922631A (en) * 1995-10-19 1999-07-13 Albemarle Corporation Liquid clathrate aluminoxane compositions as co-catalysts with transition metal catalyst compounds
KR19990087479A (ko) * 1996-03-04 1999-12-27 데니스 피. 산티니 성형 제품
US6864207B2 (en) * 1997-01-28 2005-03-08 Fina Technology, Inc. Ziegler-Natta catalyst for polyolefins
US6930071B2 (en) * 1997-01-28 2005-08-16 Fina Technology, Inc. Ziegler-natta catalyst for polyolefins
US5965477A (en) * 1997-02-21 1999-10-12 Council Of Scientific & Industrial Research Process for the preparation of supported metallocene catalyst
US6187882B1 (en) * 1997-02-21 2001-02-13 Council Of Scientific & Industrial Research Process for polymerization of olefins
US5962360A (en) * 1997-03-27 1999-10-05 Council Of Scientific And Industrial Research Process for the preparation of a magnesium halide supported metallocene catalyst
US5955554A (en) * 1997-03-27 1999-09-21 Council Of Scientific Industrial Research Process for polymerization and copolymerization of olefins
US6645506B1 (en) * 1997-04-18 2003-11-11 Ganeden Biotech, Inc. Topical compositions containing extracellular products of Pseudomonas lindbergii and Emu oil
US6268447B1 (en) 1998-12-18 2001-07-31 Univation Technologies, L.L.C. Olefin polymerization catalyst
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6635715B1 (en) * 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
WO2002083754A1 (en) 2001-04-12 2002-10-24 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
WO1999021898A1 (en) * 1997-10-28 1999-05-06 Exxon Chemical Patents Inc. Magnesium halide based metallocene catalyst system
US6551955B1 (en) 1997-12-08 2003-04-22 Albemarle Corporation Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use
US6677265B1 (en) 1997-12-08 2004-01-13 Albemarle Corporation Process of producing self-supported catalysts
JP2001525458A (ja) 1997-12-08 2001-12-11 アルベマール・コーポレーシヨン 生産性を向上させた触媒組成物
US6154501A (en) * 1998-02-04 2000-11-28 Friedman; Robert F. Method and apparatus for combining transponders on multiple satellites into virtual channels
US6165929A (en) * 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
US6107230A (en) * 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
BR9910611B1 (pt) * 1998-05-18 2009-05-05 processo para produção de uma composição de catalisador.
US6300271B1 (en) * 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
EP1098934A1 (de) * 1998-07-01 2001-05-16 Exxon Chemical Patents Inc. Elastische mischung mit kristallpolymeren und kristallisierbaren polymeren des propens
US7767203B2 (en) 1998-08-07 2010-08-03 Ganeden Biotech, Inc. Methods for the dietary management of irritable bowel syndrome and carbohydrate malabsorption
EP1719518A1 (de) 1998-08-07 2006-11-08 Ganeden Biotech, Inc. Zusammensetzung enthaltend Bacillus Coagulans zur Erhöhung der Löslichkeit von Mineralien
US6008394A (en) * 1998-08-07 1999-12-28 Arco Chemicals Technology, L.P. Sulfonyl catalysts and method of using the same
US6461607B1 (en) 1998-08-24 2002-10-08 Ganeden Biotech, Inc. Probiotic, lactic acid-producing bacteria and uses thereof
DE19843858A1 (de) * 1998-09-25 2000-04-06 Ticona Gmbh Verfahren zur Herstellung eines Polymers
DE19844167A1 (de) * 1998-09-25 2000-04-06 Ticona Gmbh Aktivkohlefilter
JP3322643B2 (ja) 1998-10-19 2002-09-09 丸善石油化学株式会社 オレフィン重合用固体触媒およびこれを用いたオレフィン系重合体の製造方法
ES2356612T3 (es) 1998-11-02 2011-04-11 Dow Global Technologies Inc. Interpolímeros de etileno/alfa-olefina/dieno reo-fluidificantes y su preparación .
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
KR100430979B1 (ko) 1999-02-04 2004-05-12 삼성아토피나주식회사 올레핀 중합용 킬레이트 촉매의 제조방법
US6545108B1 (en) 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
DE60014376T2 (de) * 1999-02-22 2005-02-24 Eastman Chemical Co., Kingsport Katalysatoren, die n-pyrrolylsubstituierte stickstoffdonoren enthalten
US6313236B1 (en) 1999-03-30 2001-11-06 Eastman Chemical Company Process for producing polyolefins
US6288181B1 (en) 1999-03-30 2001-09-11 Eastman Chemical Company Process for producing polyolefins
US6265037B1 (en) 1999-04-16 2001-07-24 Andersen Corporation Polyolefin wood fiber composite
KR100524293B1 (ko) 1999-05-27 2005-10-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100546499B1 (ko) * 1999-05-27 2006-01-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
US6417298B1 (en) * 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417301B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417299B1 (en) * 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6187879B1 (en) 1999-08-31 2001-02-13 Eastman Chemical Company Process for producing polyolefins
CN1367797A (zh) 1999-08-31 2002-09-04 伊斯曼化学公司 聚烯烃生产方法
US6849256B1 (en) * 1999-11-08 2005-02-01 Ganeden Biotech Incorporated Inhibition of pathogens by probiotic bacteria
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
DE19962129A1 (de) 1999-12-21 2001-06-28 Targor Gmbh Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
US20040127658A1 (en) * 2000-02-18 2004-07-01 Eastman Chemical Company Productivity catalysts and microstructure control
US6579823B2 (en) * 2000-02-18 2003-06-17 Eastman Chemical Company Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors
US7056996B2 (en) * 2000-02-18 2006-06-06 E. I. Du Pont De Nemours And Company Productivity catalysts and microstructure control
US6605677B2 (en) 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
DE10009247C1 (de) * 2000-02-28 2001-10-18 Schoeller Felix Jun Foto Schichtträger
KR100387734B1 (ko) * 2000-06-17 2003-06-18 삼성종합화학주식회사 올레핀 중합용 촉매 및 중합방법
GC0000293A (en) 2000-10-10 2006-11-01 Saudi Basic Ind Corp Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems
US6706891B2 (en) 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
KR100389477B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389476B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389475B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
KR100389962B1 (ko) * 2000-11-10 2003-07-02 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
CN1131246C (zh) * 2000-12-14 2003-12-17 中国石油化工股份有限公司 用于烯烃聚合或共聚合的催化剂组份及其催化剂和应用
KR100421551B1 (ko) * 2000-12-16 2004-03-09 삼성아토피나주식회사 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법
KR100421552B1 (ko) 2000-12-18 2004-03-09 삼성아토피나주식회사 올레핀 중합용 촉매 및 이를 이용한 중합 방법
WO2002051882A1 (en) * 2000-12-22 2002-07-04 Samsung General Chemicals Co., Ltd. Chelate catalyst for olefin polymerization and olefin polymerization method using the same
EP1265933B1 (de) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Katalysatorkomponente fur die polymerisation von olefinen
US7067576B2 (en) * 2000-12-22 2006-06-27 Samsung Atofina, Co., Ltd. Flame retardant polypropylene resin composition
EP1362079B1 (de) * 2000-12-22 2005-06-08 Samsung General Chemicals Co., Ltd. Polypropylenharzzusammensetzung mit verbesserter oberflächenhärte und kratzfestigkeit
US20040072936A1 (en) * 2000-12-22 2004-04-15 Sok-Won Kim Polyolefin resin composition
US6534609B2 (en) 2001-03-13 2003-03-18 Chevron Phillips Chemical Company Lp Method for making and using a metallocene catalyst system
KR100530794B1 (ko) * 2001-06-21 2005-11-23 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
US6927256B2 (en) * 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
EP1444276A1 (de) * 2001-11-06 2004-08-11 Dow Global Technologies, Inc. Isotaktische propylencopolymere, ihre herstellung und ihre verwendung
US7579407B2 (en) * 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US6992034B2 (en) * 2003-07-10 2006-01-31 Formosa Plastics Corporation, U.S.A. Catalyst component for olefin polymerization
US7155295B2 (en) * 2003-11-07 2006-12-26 Paracor Medical, Inc. Cardiac harness for treating congestive heart failure and for defibrillating and/or pacing/sensing
US7399895B2 (en) * 2004-03-16 2008-07-15 Union Carbide Chemicals & Plastics Aluminum phosphate-supported group 6 metal amide catalysts for oligomerization of ethylene
SG151301A1 (en) 2004-03-17 2009-04-30 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for ethylene multi- block copolymer formation
BRPI0508173B1 (pt) 2004-03-17 2016-03-15 Dow Global Technologies Inc copolímeros em multibloco, polímero, copolímero, um derivado funcional, mistura homogênea de polímero, processo para a preparação de um copolímero em multibloco contendo propileno e processo para preparar um copolímero em multibloco contendo 4-metil-1-penteno
AU2005224258B2 (en) 2004-03-17 2010-09-02 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene copolymer formation
EP1778738B1 (de) * 2004-08-09 2014-05-07 Dow Global Technologies LLC Geträgerte bis(hydroxyarylaryloxy)-katalysatoren zur herstellung von polymeren
EP1693388A1 (de) * 2005-02-21 2006-08-23 Innovene Europe Limited Polymerisationskatalysatoren
WO2006101596A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
EP2894176B1 (de) 2005-03-17 2022-06-01 Dow Global Technologies LLC Katalysatorzusammensetzung mit reversiblem Kettenübertragungsreagenz für die regio-irreguläre Multiblock-Copolymer-Synthese
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
US20090069171A1 (en) * 2005-05-12 2009-03-12 Japan Polypropylene Corporation Catalysts for olefin polymerization, process for production of the catalysts, and method for preservation thereof
BR122017016853B1 (pt) * 2005-09-15 2018-05-15 Dow Global Technologies Inc. Processo para a polimerização de um ou mais monômeros polimerizáveis por adição
CA2622720A1 (en) 2005-09-15 2007-03-29 Dow Global Technologies Inc. Catalytic olefin block copolymers via polymerizable shuttling agent
US8354484B2 (en) * 2006-05-17 2013-01-15 Dow Global Technologies, Llc High temperature solution polymerization process
LT2211626T (lt) 2007-08-29 2019-11-11 Ganeden Biotech Inc Kepiniai
ES2700855T3 (es) * 2007-10-16 2019-02-19 Ganeden Biotech Inc Composiciones bebibles
US8003741B2 (en) 2008-02-07 2011-08-23 Fina Technology, Inc. Ziegler-Natta catalyst
US7788209B2 (en) * 2008-05-05 2010-08-31 United Technologies Corporation Hybrid fault reasoning and guided troubleshooting system that uses case-based reasoning and model-based reasoning
US9622502B2 (en) 2008-10-16 2017-04-18 Ganeden Biotech, Inc. Probiotic Bacillus pasta compositions
ES2639364T3 (es) 2009-04-29 2017-10-26 Ganeden Biotech, Inc. Formulación de membrana celular bacteriana
ES2651292T3 (es) 2009-07-29 2018-01-25 Dow Global Technologies Llc Agentes de transferencia de cadena de doble o múltiple cabeza y su uso para la preparación de copolímeros de bloque
US9610723B2 (en) 2009-11-10 2017-04-04 Total Petrochemicals Research Feluy Bimodal polyethylene for injection stretch blow moulding applications
HUE056588T2 (hu) 2010-02-05 2022-02-28 Total Res & Technology Feluy Eljárás poliolefinek elõállítására
WO2012119948A1 (en) 2011-03-04 2012-09-13 Total Research & Technology Feluy Process for preparing polyolefin blends in a device for continuously physically melting and blending the blends
CN103502348B (zh) 2011-03-04 2016-02-03 道达尔研究技术弗吕公司 齐格勒-纳塔生产的聚乙烯共混物的制备方法
WO2012135499A1 (en) 2011-03-31 2012-10-04 Ganeden Biotech, Inc. Probiotic sports nutrition compositions
EP2709456A1 (de) 2011-05-20 2014-03-26 The Government of the United States of America as represented by the Secretary of the Department of Health and Human Services Paenibacillus-alvei-stamm ts-15 und seine anwendung zur kontrolle von pathogenen organismen
CN103958593A (zh) 2011-09-30 2014-07-30 道达尔研究技术弗吕公司 用于帽和封闭件的高密度聚乙烯
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
BR112016002478A2 (pt) 2013-08-12 2017-08-01 Total Res & Technology Feluy polietileno para aplicações de moldagem por injeção com estiramento e sopro
PL3074464T3 (pl) 2014-07-10 2017-09-29 Total Research & Technology Feluy Sposób wytwarzania kompozycji mającej wysoką odporność na pękanie pod wpływem czynników zewnętrznych z poużytkowego tworzywa sztucznego oraz wytwory wytworzone ze wspomnianej kompozycji
CA2874344C (en) 2014-12-15 2021-08-31 Nova Chemicals Corporation Spheroidal catalyst for olefin polymerization
CA2890606C (en) 2015-05-07 2022-07-19 Nova Chemicals Corporation Process for polymerization using dense and spherical ziegler-natta type catalyst
CN108026115B (zh) 2015-09-30 2021-11-09 陶氏环球技术有限责任公司 可用于链穿梭的多头或双头组合物及其制备方法
BR112019006150B1 (pt) 2016-09-30 2023-02-28 Dow Global Technologies Llc Composição e processo para preparar a composição
WO2018064553A1 (en) 2016-09-30 2018-04-05 Dow Global Technologies Llc Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
EP3519474A1 (de) 2016-09-30 2019-08-07 Dow Global Technologies LLC Verfahren zur herstellung von mehrfach- oder doppelkopfzusammensetzungen zur kettenübertragung
KR102648625B1 (ko) 2017-03-15 2024-03-19 다우 글로벌 테크놀로지스 엘엘씨 다중-블록 공중합체 형성을 위한 촉매 시스템
EP3596146B1 (de) 2017-03-15 2023-07-19 Dow Global Technologies LLC Katalysatorsystem für mehrblockcopolymerbildung
CN110582518B (zh) 2017-03-15 2022-08-09 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
US20200247936A1 (en) 2017-03-15 2020-08-06 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
SG11201908306TA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1348655A (en) * 1970-05-22 1974-03-20 Montedison Spa Catalysts for the polymerization of olefins
US4295991A (en) * 1978-09-26 1981-10-20 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
FR2529207A1 (fr) * 1982-06-24 1983-12-30 Bp Chimie Sa Procede pour la preparation de supports de catalyseurs pour la polymerisation des alpha-olefines et supports obtenus
DE3366573D1 (en) * 1982-06-24 1986-11-06 Bp Chimie Sa Process for the polymerization and copolymerization of alpha-olefins in a fluidized bed
FR2541683B1 (fr) * 1983-02-28 1986-05-09 Ato Chimie Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme
US4588703A (en) * 1984-07-18 1986-05-13 Phillips Petroleum Company Polyolefin polymerization process and catalyst
US4897455A (en) * 1985-06-21 1990-01-30 Exxon Chemical Patents Inc. Polymerization process
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
US4814314A (en) * 1986-09-26 1989-03-21 Mitsubishi Petrochemical Company Limited Catalyst for olefin polymerization
JPS63168408A (ja) * 1986-12-29 1988-07-12 Showa Denko Kk ポリオレフインの製造方法
JPH07110885B2 (ja) * 1987-06-30 1995-11-29 三井石油化学工業株式会社 オレフインの重合方法
US5026797A (en) * 1987-10-22 1991-06-25 Mitsubishi Petrochemical Co., Ltd. Process for producing ethylene copolymers
FR2628110B1 (fr) * 1988-03-03 1994-03-25 Bp Chimie Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation

Also Published As

Publication number Publication date
HU208981B (en) 1994-02-28
FI906298A0 (fi) 1990-12-20
ATE142651T1 (de) 1996-09-15
US5439995A (en) 1995-08-08
NO905439L (no) 1991-06-24
PT96343A (pt) 1991-09-30
AU6817390A (en) 1991-06-27
MY105298A (en) 1994-09-30
FR2656314B1 (fr) 1992-04-17
ES2091229T3 (es) 1996-11-01
PT96343B (pt) 1998-06-30
NO176571B (no) 1995-01-16
SG44346A1 (en) 1997-12-19
NO176571C (no) 1995-04-26
CA2032619A1 (en) 1991-06-23
NO905439D0 (no) 1990-12-17
US5106804A (en) 1992-04-21
KR910011913A (ko) 1991-08-07
HUT59698A (en) 1992-06-29
JPH04211404A (ja) 1992-08-03
EP0436326B1 (de) 1996-09-11
HU908438D0 (en) 1991-07-29
PL288414A1 (en) 1992-02-24
ZA9010048B (en) 1992-08-26
CN1053433A (zh) 1991-07-31
AU646004B2 (en) 1994-02-03
FI906298A (fi) 1991-06-23
FR2656314A1 (fr) 1991-06-28
DE69028509T2 (de) 1997-02-06
EP0436326A1 (de) 1991-07-10

Similar Documents

Publication Publication Date Title
DE69028509D1 (de) Katalysator und Prepolymer für Herstellung von Polyolefinen
DE69028503D1 (de) Katalysator und Prepolymer für Polyolefinherstellung
DE69123164D1 (de) Katalysator und Prepolymere für die Polymerisation von Olefin und daraus erhältliches Ethylen(co)polymer

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee