DE69314451T2 - Methode zur Herstellung eines absorbierenden Harzes - Google Patents
Methode zur Herstellung eines absorbierenden HarzesInfo
- Publication number
- DE69314451T2 DE69314451T2 DE69314451T DE69314451T DE69314451T2 DE 69314451 T2 DE69314451 T2 DE 69314451T2 DE 69314451 T DE69314451 T DE 69314451T DE 69314451 T DE69314451 T DE 69314451T DE 69314451 T2 DE69314451 T2 DE 69314451T2
- Authority
- DE
- Germany
- Prior art keywords
- making
- absorbent resin
- absorbent
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/243—Two or more independent types of crosslinking for one or more polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4336392A JP2675729B2 (ja) | 1992-12-16 | 1992-12-16 | 吸水性樹脂の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69314451D1 DE69314451D1 (de) | 1997-11-13 |
DE69314451T2 true DE69314451T2 (de) | 1998-05-20 |
Family
ID=18298665
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69314451T Expired - Lifetime DE69314451T2 (de) | 1992-12-16 | 1993-12-16 | Methode zur Herstellung eines absorbierenden Harzes |
Country Status (6)
Country | Link |
---|---|
US (1) | US5422405A (de) |
EP (1) | EP0605150B1 (de) |
JP (1) | JP2675729B2 (de) |
KR (1) | KR0137347B1 (de) |
DE (1) | DE69314451T2 (de) |
ES (1) | ES2106984T3 (de) |
Families Citing this family (85)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4333056C2 (de) * | 1993-09-29 | 1998-07-02 | Stockhausen Chem Fab Gmbh | Pulverförmige, wäßrige Flüssigkeiten absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung als Absorptionsmittel |
US5610208A (en) | 1994-02-17 | 1997-03-11 | Nippon Shokubai Co., Ltd. | Water-absorbent agent, method for production thereof, and water-absorbent composition |
US5830543A (en) | 1994-05-30 | 1998-11-03 | Nippon Shokubai Co., Ltd. | Gelling material for aqueous fluids |
US5624967A (en) | 1994-06-08 | 1997-04-29 | Nippon Shokubai Co., Ltd. | Water-absorbing resin and process for producing same |
JP2918808B2 (ja) * | 1994-06-13 | 1999-07-12 | 株式会社日本触媒 | 吸収体および吸収性物品 |
DE69524928T2 (de) * | 1994-06-13 | 2002-08-29 | Nippon Catalytic Chem Ind | Wasser-absorbent, verfahren zu dessen herstellung und den enthaltender absorbent-gegenstand |
GB9413605D0 (en) * | 1994-07-06 | 1994-08-24 | American Colloid Co | Method of increasing the size and absorption under load of super-absorbent fine particles by impregnation with an aqueous acrylic monomer solution |
CN1064974C (zh) * | 1994-08-12 | 2001-04-25 | 花王株式会社 | 生产改进的高吸收聚合物的方法 |
EP0780424B2 (de) † | 1995-07-07 | 2012-08-01 | Nippon Shokubai Co., Ltd. | Wasserabsorbierendes pulver und verfahren zur herstellung |
JP2000342963A (ja) * | 1995-09-01 | 2000-12-12 | Nippon Shokubai Co Ltd | 吸収剤組成物およびその製造方法、並びに、吸収剤組成物を含む吸収物品 |
JP3335843B2 (ja) * | 1995-09-01 | 2002-10-21 | 株式会社日本触媒 | 吸収剤組成物および吸収体、並びに、吸収体を含む吸収物品 |
US5804318A (en) * | 1995-10-26 | 1998-09-08 | Corvita Corporation | Lubricious hydrogel surface modification |
DE69737590T2 (de) * | 1996-08-07 | 2007-12-20 | Nippon Shokubai Co. Ltd. | Wasserabsorbierendes Produkt und Verfahren zu seiner Herstellung |
ID19116A (id) * | 1996-10-15 | 1998-06-18 | Nippon Catalytic Chem Ind | Bahan pengabsorpsi air dan proses produksinya |
US6228930B1 (en) | 1997-06-18 | 2001-05-08 | Nippon Shokubai Co., Ltd. | Water-absorbent resin granule-containing composition and production process for water-absorbent resin granule |
JPH11263850A (ja) * | 1997-12-02 | 1999-09-28 | Nippon Shokubai Co Ltd | 吸水剤およびその製造方法とその用途 |
US6254990B1 (en) * | 1998-02-18 | 2001-07-03 | Nippon Shokubai Co., Ltd. | Surface-crosslinking process for water-absorbent resin |
US6444744B1 (en) | 1998-03-11 | 2002-09-03 | Nippon Shokubai Co., Ltd. | Hydrophilic resin, absorbent article, and acrylic acid for polymerization |
US6103785A (en) * | 1998-03-26 | 2000-08-15 | Nippon Shokubai Co., Ltd. | Water-absorbing agent and its production process and use |
DE19909653A1 (de) * | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Pulverförmige, vernetzte, wässrige Flüssigkeiten sowie Blut absorbierende Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung |
EP1130045B2 (de) | 2000-02-29 | 2015-10-28 | Nippon Shokubai Co., Ltd. | Verfaren zur Herstellung eines wasserabsorbierenden Harzpulvers |
US6617489B2 (en) | 2000-05-09 | 2003-09-09 | Nippon Shokubai Co., Ltd. | Absorbent, absorbing product based thereon, and water-absorbing resin |
US6720389B2 (en) | 2000-09-20 | 2004-04-13 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and production process therefor |
US7595428B2 (en) * | 2000-11-22 | 2009-09-29 | Nippon Shokubai Co., Ltd. | Water-absorbing agent composition and method for production thereof, absorptive article and absorbing material |
US20030065296A1 (en) * | 2001-02-26 | 2003-04-03 | Kaiser Thomas A. | Absorbent material of water absorbent polymer, thermoplastic polymer, and water and method for making same |
WO2003051939A1 (en) | 2001-12-19 | 2003-06-26 | Nippon Shokubai Co.,Ltd. | Water-absorbent resin and production process therefor |
MXPA04005565A (es) * | 2002-06-06 | 2004-12-06 | Nippon Catalytic Chem Ind | Composicion de agente de absorcion de agua y metodo para la produccion de la misma y material de absorcion y articulo absorbente. |
JP3917052B2 (ja) * | 2002-10-16 | 2007-05-23 | 信和化工株式会社 | コポリマー、これを用いた吸着剤又は濃縮媒体、固相マイクロ抽出用注射針 |
US7193006B2 (en) | 2002-12-06 | 2007-03-20 | Nippon Shokubai Co., Ltd. | Process for continuous production of water-absorbent resin product |
CN100519663C (zh) | 2003-02-10 | 2009-07-29 | 株式会社日本触媒 | 以吸水树脂为主要成分的粒状吸水剂 |
US7169843B2 (en) | 2003-04-25 | 2007-01-30 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
DE10334286B4 (de) | 2003-07-25 | 2006-01-05 | Stockhausen Gmbh | Pulverförmige,wasserabsorbierende Polymere mit mittels thermoplastischen Klebstoffen gebundenen Feinteilchen, Verfahren zu deren Herstellung sowie diese beinhaltende chemische Produkte und Verbunde |
DE10334584A1 (de) * | 2003-07-28 | 2005-02-24 | Basf Ag | Verfahren zur Nachvernetzung von Hydrogelen mit bicyclischen Amidacetalen |
CN1274754C (zh) * | 2003-09-09 | 2006-09-13 | 青岛科技大学高分子科学与工程学院 | 遇水崩解型环境友好高分子共混材料及其制取方法 |
US7173086B2 (en) | 2003-10-31 | 2007-02-06 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
JP4926474B2 (ja) * | 2004-02-05 | 2012-05-09 | 株式会社日本触媒 | 粒子状吸水剤及びその製造方法並びに吸水性物品 |
EP1629854B1 (de) * | 2004-07-20 | 2010-10-13 | The Procter & Gamble Company | Oberflächlich vernetzte superabsorbierende Partikeln und Verfahren zu ihrer Herstellung |
US8080705B2 (en) * | 2004-07-28 | 2011-12-20 | The Procter & Gamble Company | Superabsorbent polymers comprising direct covalent bonds between polymer chain segments and method of making them |
CN101010364B (zh) * | 2004-09-02 | 2011-07-27 | 株式会社日本触媒 | 吸水性材料、用于表面交联的吸水性树脂的生产方法以及用于吸水性材料的评价方法 |
CN101076554B (zh) * | 2004-12-10 | 2012-05-02 | 株式会社日本触媒 | 改性吸水性树脂的生产方法 |
US20060128827A1 (en) * | 2004-12-10 | 2006-06-15 | The Procter & Gamble Company | Absorbent members comprising modified water absorbent resin for use in diapers |
CN101072817B (zh) * | 2004-12-10 | 2012-05-02 | 株式会社日本触媒 | 吸水性树脂的表面处理方法 |
EP1669394A1 (de) * | 2004-12-10 | 2006-06-14 | The Procter & Gamble Company | Superabsorbierende Polymerpartikel mit verbesserter Oberflächenvernetzung und hydrophiler Eigenschaft und Verfahren zur Herstellung |
TWI344469B (en) | 2005-04-07 | 2011-07-01 | Nippon Catalytic Chem Ind | Polyacrylic acid (salt) water-absorbent resin, production process thereof, and acrylic acid used in polymerization for production of water-absorbent resin |
US8481664B2 (en) | 2005-04-12 | 2013-07-09 | Nippon Shokubai Co., Ltd. | Particulate water absorbing agent including polyacrylic acid (polyacrylate) based water absorbing resin as a principal component, method for production thereof, water-absorbent core and absorbing article in which the particulate water absorbing agent is used |
JP2007077366A (ja) * | 2005-09-16 | 2007-03-29 | Procter & Gamble Co | 吸水剤の製法 |
TW200712065A (en) * | 2005-09-16 | 2007-04-01 | Nippon Catalytic Chem Ind | Method for production of water absorbing agent |
JP2007099845A (ja) * | 2005-09-30 | 2007-04-19 | Procter & Gamble Co | 水性液吸収剤およびその製法 |
US7812082B2 (en) * | 2005-12-12 | 2010-10-12 | Evonik Stockhausen, Llc | Thermoplastic coated superabsorbent polymer compositions |
TWI394789B (zh) | 2005-12-22 | 2013-05-01 | Nippon Catalytic Chem Ind | 吸水性樹脂組成物及其製造方法、吸收性物品 |
EP1837348B9 (de) | 2006-03-24 | 2020-01-08 | Nippon Shokubai Co.,Ltd. | Wasserabsorbierendes Harz und Verfahren zu seiner Herstellung |
EP2042521A1 (de) | 2006-03-29 | 2009-04-01 | Nippon Shokubai Co., Ltd. | Verfahren zur Herstellung von wasserabsorbierendem Polyacrylsäure (Salz)-Harz |
WO2007120561A2 (en) | 2006-04-10 | 2007-10-25 | The Procter & Gamble Company | An absorbent member comprising a modified water absorbent resin |
JP5478897B2 (ja) | 2007-01-24 | 2014-04-23 | 株式会社日本触媒 | 粒子状吸水性ポリマーおよびその製造方法 |
US9187579B2 (en) | 2007-02-05 | 2015-11-17 | Nippon Shokubai Co., Ltd. | Particle-shaped water absorbing agent and method for producing the same |
EP2121049B1 (de) | 2007-02-22 | 2016-03-30 | The Procter and Gamble Company | Verfahren zur oberflächenbehandlung eines partikelförmigen materials mithilfe elektromagnetischer strahlung |
CN101627086B (zh) * | 2007-03-01 | 2013-07-10 | 株式会社日本触媒 | 以吸水性树脂为主成分的粒状吸水剂 |
SA08290402B1 (ar) | 2007-07-04 | 2014-05-22 | نيبون شوكوباي كو. ، ليمتد | عامل دقائقي ماص للماء وطريقة لتصنيعه |
SA08290542B1 (ar) * | 2007-08-28 | 2012-11-14 | نيبون شوكوباي كو. ، ليمتد | طريقة لإنتاج راتنج ماص للماء |
SA08290556B1 (ar) * | 2007-09-07 | 2012-05-16 | نيبون شوكوباي كو. ، ليمتد | طريقة لربط راتنجات ممتصة للماء |
JP5448699B2 (ja) * | 2008-10-14 | 2014-03-19 | Sdpグローバル株式会社 | 吸収性樹脂粒子、この製造方法、これを含む吸収体及び吸収性物品 |
WO2010100936A1 (ja) | 2009-03-04 | 2010-09-10 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
JP5580812B2 (ja) | 2009-05-15 | 2014-08-27 | 株式会社日本触媒 | (メタ)アクリル酸の製造方法 |
BRPI1012135A2 (pt) | 2009-05-15 | 2016-03-29 | Nippon Catalytic Chem Ind | processo para produzir ácido (met) acrílico e sistema de cristalização |
US8586787B2 (en) | 2009-05-15 | 2013-11-19 | Nippon Shokubai Co., Ltd. | Process for producing (meth)acrylic acid |
EP2471844B1 (de) | 2009-08-27 | 2016-03-30 | Nippon Shokubai Co., Ltd. | Wasserabsorbierendes harz auf basis von polyacrylsäure(salz) und verfahren zu seiner herstellung |
JP5616346B2 (ja) | 2009-08-28 | 2014-10-29 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
CN105771945A (zh) | 2009-09-29 | 2016-07-20 | 株式会社日本触媒 | 颗粒状吸水剂及其制造方法 |
JP5731390B2 (ja) | 2009-09-30 | 2015-06-10 | 株式会社日本触媒 | ポリアクリル酸(塩)系吸水性樹脂およびその製造方法 |
CN102712763B (zh) | 2010-01-20 | 2014-07-30 | 株式会社日本触媒 | 吸水性树脂的制造方法 |
EP2527391B1 (de) | 2010-01-20 | 2023-08-09 | Nippon Shokubai Co., Ltd. | Verfahren zur herstellung eines wasserabsorbierenden harzes |
US9976001B2 (en) | 2010-02-10 | 2018-05-22 | Nippon Shokubai Co., Ltd. | Process for producing water-absorbing resin powder |
US8875415B2 (en) | 2010-03-08 | 2014-11-04 | Nippon Shokubai, Co., Ltd. | Method for drying granular water-containing gel-like cross-linked polymer |
JP5554268B2 (ja) * | 2010-03-11 | 2014-07-23 | 株式会社クラレ | 架橋性組成物、架橋物及びその製造方法、並びに多層構造体 |
US9272068B2 (en) | 2010-03-12 | 2016-03-01 | Nippon Shokubai Co., Ltd. | Process for producing water-absorbing resin |
WO2011115216A1 (ja) | 2010-03-17 | 2011-09-22 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
JP5806209B2 (ja) | 2010-04-26 | 2015-11-10 | 株式会社日本触媒 | ポリアクリル酸(塩)系吸水性樹脂及びその製造方法 |
EP2565212B1 (de) | 2010-04-26 | 2020-05-06 | Nippon Shokubai Co., Ltd. | Polyacrylatsäure(salz), wasserabsorbierendes harz auf basis von polyacrylatsäure(salz) und verfahren zu seiner herstellung |
JPWO2014021388A1 (ja) * | 2012-08-01 | 2016-07-21 | 株式会社日本触媒 | ポリアクリル酸(塩)系吸水性樹脂粉末を用いた吸水剤及びその製造方法 |
JP5766344B1 (ja) | 2014-07-11 | 2015-08-19 | 住友精化株式会社 | 吸水性樹脂及び吸収性物品 |
KR102011926B1 (ko) * | 2014-12-22 | 2019-08-20 | 주식회사 엘지화학 | 고흡수성 수지 및 이의 제조 방법 |
KR102162500B1 (ko) * | 2016-12-13 | 2020-10-06 | 주식회사 엘지화학 | 고흡수성 수지 및 이의 제조 방법 |
KR102094453B1 (ko) | 2016-12-23 | 2020-03-27 | 주식회사 엘지화학 | 고흡수성 수지 및 이의 제조 방법 |
KR102489568B1 (ko) * | 2017-11-07 | 2023-01-16 | 주식회사 엘지화학 | 고흡수성 수지 및 이의 제조 방법 |
JP6979487B1 (ja) * | 2020-07-13 | 2021-12-15 | 長瀬産業株式会社 | 吸水性樹脂架橋剤組成物 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4061846A (en) * | 1974-03-13 | 1977-12-06 | The Dow Chemical Company | Flexible water swellable crosslinked polyacrylate film |
JPS60163956A (ja) * | 1984-02-04 | 1985-08-26 | Arakawa Chem Ind Co Ltd | 吸水性樹脂の製法 |
CA1256640A (en) * | 1984-03-05 | 1989-06-27 | Harumasa Yamasaki | Absorptive material |
US4880868A (en) * | 1986-10-06 | 1989-11-14 | Arco Chemical Technology, Inc. | Extended shelf life water-absorbing composition which facilitates fiber formation |
JPS63118308A (ja) * | 1986-11-06 | 1988-05-23 | Nippon Synthetic Chem Ind Co Ltd:The | 高吸水性樹脂の製造法 |
EP0317106B1 (de) * | 1987-10-29 | 1993-02-17 | Nippon Shokubai Kagaku Kogyo Co., Ltd | Verfahren zur Oberflächenbehandlung eines Wasser absorbierenden Harzes |
KR910008293B1 (ko) * | 1988-05-13 | 1991-10-12 | 주식회사 럭키 | 흡수 속도가 우수한 고흡수성 수지의 제조방법 |
JPH02132103A (ja) * | 1988-11-11 | 1990-05-21 | Idemitsu Petrochem Co Ltd | ポリアクリル酸アルカリ金属塩の製造方法 |
JP3210009B2 (ja) * | 1990-04-02 | 2001-09-17 | ザ、プロクター、エンド、ギャンブル、カンパニー | 粒子間架橋凝集体を含む粒状吸収性高分子組成物 |
US5164459A (en) * | 1990-04-02 | 1992-11-17 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Method for treating the surface of an absorbent resin |
GB9107952D0 (en) * | 1991-04-15 | 1991-05-29 | Dow Rheinmuenster | Surface crosslinked and surfactant coated absorbent resin particles and method of preparation |
-
1992
- 1992-12-16 JP JP4336392A patent/JP2675729B2/ja not_active Expired - Fee Related
-
1993
- 1993-12-15 US US08/167,077 patent/US5422405A/en not_active Expired - Lifetime
- 1993-12-16 ES ES93310168T patent/ES2106984T3/es not_active Expired - Lifetime
- 1993-12-16 EP EP93310168A patent/EP0605150B1/de not_active Expired - Lifetime
- 1993-12-16 KR KR1019930027967A patent/KR0137347B1/ko not_active IP Right Cessation
- 1993-12-16 DE DE69314451T patent/DE69314451T2/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69314451D1 (de) | 1997-11-13 |
JP2675729B2 (ja) | 1997-11-12 |
ES2106984T3 (es) | 1997-11-16 |
US5422405A (en) | 1995-06-06 |
KR940014468A (ko) | 1994-07-18 |
EP0605150B1 (de) | 1997-10-08 |
KR0137347B1 (ko) | 1998-04-27 |
EP0605150A1 (de) | 1994-07-06 |
JPH06184320A (ja) | 1994-07-05 |
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