DE69526704T2 - Mit modifizierten Polysiloxan beschichtete anorganische Teilchen - Google Patents

Mit modifizierten Polysiloxan beschichtete anorganische Teilchen

Info

Publication number
DE69526704T2
DE69526704T2 DE69526704T DE69526704T DE69526704T2 DE 69526704 T2 DE69526704 T2 DE 69526704T2 DE 69526704 T DE69526704 T DE 69526704T DE 69526704 T DE69526704 T DE 69526704T DE 69526704 T2 DE69526704 T2 DE 69526704T2
Authority
DE
Germany
Prior art keywords
inorganic particles
particles coated
modified polysiloxane
polysiloxane
modified
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69526704T
Other languages
English (en)
Other versions
DE69526704D1 (de
Inventor
Kazuyuki Hayashi
Hiroko Morii
Mineko Sakoda
Minoru Ohsugi
Mamoru Kamigaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toda Kogyo Corp
Original Assignee
Toda Kogyo Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toda Kogyo Corp filed Critical Toda Kogyo Corp
Publication of DE69526704D1 publication Critical patent/DE69526704D1/de
Application granted granted Critical
Publication of DE69526704T2 publication Critical patent/DE69526704T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/68—Particle size between 100-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12—Treatment with organosilicon compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62—Record carriers characterised by the selection of the material
    • G11B5/68—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent
    • G11B5/70—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer
    • G11B5/712—Record carriers characterised by the selection of the material comprising one or more layers of magnetisable material homogeneously mixed with a bonding agent on a base layer characterised by the surface treatment or coating of magnetic particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/38—Particle morphology extending in three dimensions cube-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/41—Particle morphology extending in three dimensions octahedron-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/42—(bi)pyramid-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • C01P2006/82—Compositional purity water content
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2998—Coated including synthetic resin or polymer
DE69526704T 1994-09-01 1995-09-01 Mit modifizierten Polysiloxan beschichtete anorganische Teilchen Expired - Fee Related DE69526704T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23217794 1994-09-01

Publications (2)

Publication Number Publication Date
DE69526704D1 DE69526704D1 (de) 2002-06-20
DE69526704T2 true DE69526704T2 (de) 2002-11-21

Family

ID=16935219

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69526704T Expired - Fee Related DE69526704T2 (de) 1994-09-01 1995-09-01 Mit modifizierten Polysiloxan beschichtete anorganische Teilchen

Country Status (3)

Country Link
US (1) US5686012A (de)
EP (1) EP0699721B1 (de)
DE (1) DE69526704T2 (de)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3397228B2 (ja) * 1997-03-06 2003-04-14 戸田工業株式会社 顔料粒子粉末及びその製造法並びに該顔料粒子粉末を用いた水系塗料
US6225434B1 (en) 1997-08-01 2001-05-01 Ppg Industries Ohio, Inc. Film-forming compositions having improved scratch resistance
US6420030B1 (en) 1997-10-31 2002-07-16 Toda Kogyo Corporation Black iron-based composite particles, process for producing the same, paint and rubber or resin composition containing the same
GB2331717B (en) * 1997-11-26 1999-12-22 Ranier Ltd Reticulated coatings
US6024789A (en) * 1998-05-07 2000-02-15 Videojet Systems International, Inc. Method of preparing iron-containing pigment with enhanced dispersibility in both polar and nonpolar solvents
US6248225B1 (en) 1998-05-26 2001-06-19 Ppg Industries Ohio, Inc. Process for forming a two-coat electrodeposited composite coating the composite coating and chip resistant electrodeposited coating composition
US6423425B1 (en) 1998-05-26 2002-07-23 Ppg Industries Ohio, Inc. Article having a chip-resistant electrodeposited coating and a process for forming an electrodeposited coating
US6531211B1 (en) * 1998-08-28 2003-03-11 Toda Kogyo Corporation Black plate-shaped ferrite composite particles with magnet oplumbite structure and magnetic recording medium using the same
EP0982715A1 (de) * 1998-08-28 2000-03-01 Toda Kogyo Corp. Schwarze plättchenförmige Kompositteilchen vom Magnetoplumbittyp und diese enthaltendes magnetisches Aufzeichnungsmedium
US6133360A (en) * 1998-10-23 2000-10-17 General Electric Company Polycarbonate resin blends containing titanium dioxide
US6458453B1 (en) * 1999-04-30 2002-10-01 Toda Kogyo Corporation Magnetic recording medium
EP1063639A1 (de) * 1999-06-24 2000-12-27 Toda Kogyo Corporation Magnetische Kompositteilchen,Verfahren zur Herstellung und diese enthaltendes magnetisches Aufzeichnungsmedium
DE60022765T2 (de) 1999-07-30 2006-06-29 Ppg Industries Ohio, Inc. Beschichtungszusammensetzungen mit verbesserter kratzfestigkeit und beschichtete oberflächen
US6623791B2 (en) 1999-07-30 2003-09-23 Ppg Industries Ohio, Inc. Coating compositions having improved adhesion, coated substrates and methods related thereto
JP2003506518A (ja) 1999-07-30 2003-02-18 ピーピージー インダストリーズ オハイオ， インコーポレイテッド 改良ひっかき抵抗性を有するコーティング組成物、コート基材及びそれに関連する方法
AU771282B2 (en) 1999-07-30 2004-03-18 Ppg Industries Ohio, Inc. Coating compositions having improved scratch resistance, coated substrates and methods related thereto
US6610777B1 (en) 1999-07-30 2003-08-26 Ppg Industries Ohio, Inc. Flexible coating compositions having improved scratch resistance, coated substrates and methods related thereto
US6440561B2 (en) * 1999-12-10 2002-08-27 Toda Kogyo Corporation Iron oxide hydroxide composite particles, pigment, paint and resin composition
EP1134733A1 (de) * 2000-03-16 2001-09-19 Toda Kogyo Corporation Magnetischer Aufzeichnungsträger mit Rückschicht die überzogene Hämatitteilchen enthält
US6635341B1 (en) 2000-07-31 2003-10-21 Ppg Industries Ohio, Inc. Coating compositions comprising silyl blocked components, coating, coated substrates and methods related thereto
US7022752B2 (en) 2000-09-01 2006-04-04 Toda Kogyo Corporation Composite particles, process for producing the same, and pigment, paint and resin composition using the same
JP4540921B2 (ja) * 2001-06-05 2010-09-08 戸田工業株式会社 インクジェット用インクの着色材及びインクジェット用インク並びに水性顔料分散体、有機無機複合粒子粉末
DE10047622A1 (de) * 2000-09-26 2002-04-11 Basf Ag Verfahren zur Herstellung von polymerumhüllten Pigmentteilchen durch Präzipitation
JP2002188021A (ja) * 2000-12-19 2002-07-05 Toda Kogyo Corp 黒色複合酸化鉄顔料並びに該黒色複合酸化鉄顔料を用いた塗料及び樹脂組成物
JP2002327202A (ja) * 2001-04-27 2002-11-15 Toda Kogyo Corp 鉄を主成分とする複合金属磁性粒子粉末及びその製造法並びに磁気記録媒体
US6916368B2 (en) * 2002-02-20 2005-07-12 Ppg Industries Ohio, Inc. Curable film-forming composition exhibiting improved scratch resistance
US6679943B1 (en) * 2002-05-01 2004-01-20 Basf Corporation Coating containing adhesion promoting additive
US6790904B2 (en) * 2002-06-03 2004-09-14 Ppg Industries Ohio, Inc. Liquid coating of film-forming resin and particles chemically modified to lower surface tension
US7141618B2 (en) * 2002-06-03 2006-11-28 Ppg Industries Ohio, Inc. Coating compositions with modified particles and methods of using the same
JP3979922B2 (ja) * 2002-11-08 2007-09-19 信越化学工業株式会社 親水化処理粉体及びこれらを含有する組成物
JP3872024B2 (ja) * 2003-02-07 2007-01-24 パウダーテック株式会社 キャリア芯材、被覆キャリア、電子写真用二成分系現像剤および画像形成方法
US7749570B2 (en) * 2006-12-20 2010-07-06 General Electric Company Method for depositing a platinum-group-containing layer on a substrate
CN102926187B (zh) * 2012-10-18 2014-08-06 西安工程大学 一种磁性纳米三氧化二铁改性涤纶织物的方法
DE102013226798A1 (de) * 2013-12-20 2015-06-25 Evonik Industries Ag Oberflächenbehandlung von Partikeln und deren Verwendung
WO2015105189A1 (ja) * 2014-01-10 2015-07-16 旭化成ケミカルズ株式会社 水性複合粒子分散体
CN112143269B (zh) * 2020-09-07 2022-07-12 中国石油大学胜利学院 一种水性无机富锌涂料及其制备方法

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US3849152A (en) * 1972-11-06 1974-11-19 Ferro Corp Polysiloxane encapsulation of pigments
DE2927379A1 (de) * 1979-07-06 1981-01-08 Bayer Ag Feinteilige festkoerper, ihre herstellung und verwendung
DE3334598A1 (de) * 1983-09-24 1985-04-18 Merck Patent Gmbh Witterungsbestaendige perlglanzpigmente
JPS6225753A (ja) * 1985-07-26 1987-02-03 Mitsubishi Paper Mills Ltd 写真用樹脂被覆紙
JPH02275814A (ja) * 1989-04-18 1990-11-09 Nippon Chem Ind Co Ltd 化粧料
JP2673582B2 (ja) * 1989-07-21 1997-11-05 キヤノン株式会社 現像剤
FR2656318B1 (fr) * 1989-12-27 1994-02-04 Rhone Poulenc Chimie Microspheres "core-shell" magnetisables a base d'organopolysiloxane reticule, leur procede de preparation et leur application en biologie.
DE4140794C1 (de) * 1991-12-11 1993-03-11 Th. Goldschmidt Ag, 4300 Essen, De
DE4207832C1 (en) * 1992-03-12 1993-03-11 Th. Goldschmidt Ag, 4300 Essen, De Impregnation of hot mineral fibres - with organo:siloxane with methyl and long chain alkyl, ether and/or reactive gps., for mfr. of insulation sheet without mineral oil
JP3122780B2 (ja) * 1993-02-26 2001-01-09 ぺんてる株式会社 ボールペン用インキ組成物

Also Published As

Publication number Publication date
US5686012A (en) 1997-11-11
EP0699721A3 (de) 1997-01-02
DE69526704D1 (de) 2002-06-20
EP0699721B1 (de) 2002-05-15
EP0699721A2 (de) 1996-03-06

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