DE69605952D1 - Spinel-Lithium-Manganoxid-Material, Verfahren zu seiner Herstellung und seine Verwendung - Google Patents

Spinel-Lithium-Manganoxid-Material, Verfahren zu seiner Herstellung und seine Verwendung

Info

Publication number
DE69605952D1
DE69605952D1 DE69605952T DE69605952T DE69605952D1 DE 69605952 D1 DE69605952 D1 DE 69605952D1 DE 69605952 T DE69605952 T DE 69605952T DE 69605952 T DE69605952 T DE 69605952T DE 69605952 D1 DE69605952 D1 DE 69605952D1
Authority
DE
Germany
Prior art keywords
production
manganese oxide
oxide material
lithium manganese
spinel lithium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69605952T
Other languages
English (en)
Other versions
DE69605952T2 (de
Inventor
Eiichi Iwata
Ken-Ichi Takahashi
Setsuo Yoshida
Masaki Okada
Masanori Sawano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Tosoh Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tosoh Corp filed Critical Tosoh Corp
Publication of DE69605952D1 publication Critical patent/DE69605952D1/de
Application granted granted Critical
Publication of DE69605952T2 publication Critical patent/DE69605952T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/12Manganates manganites or permanganates
    • C01G45/1221Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1242Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [Mn2O4]-, e.g. LiMn2O4, Li[MxMn2-x]O4
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/12Manganates manganites or permanganates
    • C01G45/1221Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1292Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [Mn5O12]n-
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/30Three-dimensional structures
    • C01P2002/32Three-dimensional structures spinel-type (AB2O4)
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/11Powder tap density
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
DE69605952T 1995-02-23 1996-02-22 Spinel-Lithium-Manganoxid-Material, Verfahren zu seiner Herstellung und seine Verwendung Expired - Lifetime DE69605952T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP3534695 1995-02-23
JP3534595 1995-02-23
JP20270595 1995-07-18

Publications (2)

Publication Number Publication Date
DE69605952D1 true DE69605952D1 (de) 2000-02-10
DE69605952T2 DE69605952T2 (de) 2000-07-20

Family

ID=27288733

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69605952T Expired - Lifetime DE69605952T2 (de) 1995-02-23 1996-02-22 Spinel-Lithium-Manganoxid-Material, Verfahren zu seiner Herstellung und seine Verwendung

Country Status (3)

Country Link
US (1) US5807646A (de)
EP (1) EP0728701B1 (de)
DE (1) DE69605952T2 (de)

Families Citing this family (44)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE195495T1 (de) * 1996-04-05 2000-09-15 Fmc Corp Verfahren zur herstellung von li(1+x)mn(2- x)0(4+y)-spinelleinlagerungsverbindungen
JP3221352B2 (ja) * 1996-06-17 2001-10-22 株式会社村田製作所 スピネル型リチウムマンガン複合酸化物の製造方法
JP3047827B2 (ja) * 1996-07-16 2000-06-05 株式会社村田製作所 リチウム二次電池
US6270926B1 (en) * 1996-07-16 2001-08-07 Murata Manufacturing Co., Ltd. Lithium secondary battery
US6083646A (en) * 1996-08-29 2000-07-04 Sony Corporation Non-aqueous electrolyte secondary battery and method for producing cathode material
US6071489A (en) * 1996-12-05 2000-06-06 Samsung Display Device Co., Ltd. Methods of preparing cathode active materials for lithium secondary battery
CA2240805C (en) 1997-06-19 2005-07-26 Tosoh Corporation Spinel-type lithium-manganese oxide containing heteroelements, preparation process and use thereof
KR100378005B1 (ko) * 1997-06-30 2003-06-12 삼성에스디아이 주식회사 고용량및안정성의리튬이온용양극활물질및그제조방법
US6749648B1 (en) 2000-06-19 2004-06-15 Nanagram Corporation Lithium metal oxides
US6482374B1 (en) * 1999-06-16 2002-11-19 Nanogram Corporation Methods for producing lithium metal oxide particles
US6607706B1 (en) 1998-11-09 2003-08-19 Nanogram Corporation Composite metal oxide particles
US6506493B1 (en) 1998-11-09 2003-01-14 Nanogram Corporation Metal oxide particles
US6071646A (en) * 1997-08-26 2000-06-06 Kyushu Ceramics Industry Co., Ltd. Spinel compounds as cathodes for lithium materials
JPH11180717A (ja) * 1997-12-22 1999-07-06 Ishihara Sangyo Kaisha Ltd マンガン酸リチウム及びその製造方法ならびにそれを用いてなるリチウム電池
AU3203899A (en) * 1998-03-24 1999-10-18 Board Of Regents, The University Of Texas System Low temperature synthesis of Li4Mn5O12 cathodes for lithium batteries
AU5466699A (en) * 1998-08-13 2000-03-06 E.I. Du Pont De Nemours And Company Method for producing lithium manganese oxide intercalation compounds and compounds produced thereby
JP3526223B2 (ja) * 1998-09-17 2004-05-10 日本碍子株式会社 リチウム二次電池
US6267943B1 (en) * 1998-10-15 2001-07-31 Fmc Corporation Lithium manganese oxide spinel compound and method of preparing same
US6428766B1 (en) 1998-10-27 2002-08-06 Toda Kogyo Corporation Manganese oxide, lithium manganese complex oxide and cobalt-coated lithium manganese complex oxide, and preparation processes thereof
US6136287A (en) * 1998-11-09 2000-10-24 Nanogram Corporation Lithium manganese oxides and batteries
WO2000027754A1 (en) * 1998-11-09 2000-05-18 Nanogram Corporation Metal oxide particles
JP3652539B2 (ja) * 1999-02-05 2005-05-25 日本碍子株式会社 リチウム二次電池の製造方法
CA2298095C (en) 1999-02-05 2005-03-01 Ngk Insulators, Ltd. Lithium secondary battery
EP1049187A3 (de) * 1999-04-27 2004-04-28 Hitachi, Ltd. Lithium-Sekundärbatterie
JP2000331682A (ja) * 1999-05-21 2000-11-30 Mitsui Mining & Smelting Co Ltd リチウム二次電池用正極材料及びこれを用いた電池
JP4453122B2 (ja) * 1999-06-23 2010-04-21 パナソニック株式会社 非水電解質二次電池
DE19935090A1 (de) * 1999-07-27 2001-02-08 Emtec Magnetics Gmbh Lithiumoxid enthaltende Lithiuminterkalationsverbindungen
JP3670895B2 (ja) * 1999-08-04 2005-07-13 三洋電機株式会社 リチウム二次電池
EP1089365B1 (de) * 1999-10-01 2016-07-20 Tosoh Corporation Lithium-Mangan-Oxid und Verfahren zu seiner Herstellung und es verwendende Sekundärzelle.
WO2001035473A1 (en) 1999-11-08 2001-05-17 Nanogram Corporation Electrodes including particles of specific sizes
US6673491B2 (en) * 2000-01-21 2004-01-06 Showa Denko Kabushiki Kaisha Cathode electroactive material, production method therefor, and nonaqueous secondary cell using the same
US6686090B2 (en) * 2000-03-15 2004-02-03 Kabushiki Kaisha Toshiba Battery with a nonaqueous electrolyte and a negative electrode having a negative electrode active material occluding and releasing an active material
MXPA01004028A (es) 2000-04-25 2003-08-20 Sony Corp Material activo de electrodo positivo y celda de electrolito no acuoso.
US6699618B2 (en) * 2000-04-26 2004-03-02 Showa Denko K.K. Cathode electroactive material, production method therefor and secondary cell
US6844977B2 (en) * 2001-01-26 2005-01-18 Ciena Corporation Multi-channel optical filter
KR100498442B1 (ko) * 2001-05-23 2005-07-01 삼성전자주식회사 광 마스크 세트 및 그의 제조 방법
US6759167B2 (en) * 2001-11-19 2004-07-06 The Gillette Company Primary lithium electrochemical cell
US6783893B2 (en) * 2001-11-19 2004-08-31 The Gillette Company Alkaline battery
JP2006202724A (ja) * 2004-12-21 2006-08-03 Nissan Motor Co Ltd 非水電解質二次電池用正極及びその製造方法
CN103717536B (zh) 2011-06-02 2017-02-15 康奈尔大学 氧化锰纳米粒子、方法和应用
JP2013093316A (ja) * 2011-10-04 2013-05-16 Semiconductor Energy Lab Co Ltd 二次粒子の作製方法と蓄電装置の電極の作製方法
EP2835353B1 (de) * 2012-04-05 2022-05-04 Tosoh Corporation Metallhaltige trimangantetraoxidverbundpartikel und verfahren zur herstellung davon
KR102195186B1 (ko) * 2019-02-18 2020-12-28 주식회사 에스엠랩 양극활물질, 이의 제조방법 및 이를 포함하는 양극을 포함한 리튬이차전지
JP7082096B2 (ja) 2019-08-20 2022-06-07 本田技研工業株式会社 リチウムイオン二次電池用電極、およびリチウムイオン二次電池

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0821431B2 (ja) * 1986-10-29 1996-03-04 ソニー株式会社 有機電解質二次電池
JP2550990B2 (ja) * 1987-05-01 1996-11-06 ソニー株式会社 非水電解液電池
GB2196785B (en) * 1986-10-29 1990-05-23 Sony Corp Organic electrolyte secondary cell
JPH0746607B2 (ja) * 1987-01-29 1995-05-17 三洋電機株式会社 非水系二次電池
US4959282A (en) * 1988-07-11 1990-09-25 Moli Energy Limited Cathode active materials, methods of making same and electrochemical cells incorporating the same
JPH0824043B2 (ja) * 1988-11-17 1996-03-06 松下電器産業株式会社 非水電解質二次電池とその正極活物質の製造法
JPH02270268A (ja) * 1989-04-11 1990-11-05 Matsushita Electric Ind Co Ltd 非水電解質二次電池
JPH02270269A (ja) * 1989-04-11 1990-11-05 Matsushita Electric Ind Co Ltd 非水電解質二次電池
JPH034445A (ja) * 1989-05-31 1991-01-10 Toshiba Battery Co Ltd 非水溶媒二次電池
JPH0367464A (ja) * 1989-08-04 1991-03-22 Matsushita Electric Ind Co Ltd 有機電解質リチウム二次電池及びリチウムとマンガンとの複合酸化物の製造法
CA2022898C (en) * 1989-08-15 1995-06-20 Nobuhiro Furukawa Non-aqueous secondary cell
JP2797528B2 (ja) * 1989-10-06 1998-09-17 松下電器産業株式会社 リチウム二次電池用正極活物質の製造方法
JP3135545B2 (ja) * 1990-01-23 2001-02-19 日立マクセル株式会社 リチウム二次電池およびその製造方法
JP3057755B2 (ja) * 1990-11-28 2000-07-04 東ソー株式会社 リチウムマンガン複合酸化物の製造方法及びその用途
ZA936168B (en) * 1992-08-28 1994-03-22 Technology Finance Corp Electrochemical cell
US5425932A (en) * 1993-05-19 1995-06-20 Bell Communications Research, Inc. Method for synthesis of high capacity Lix Mn2 O4 secondary battery electrode compounds
DE4327760A1 (de) * 1993-08-18 1995-02-23 Varta Batterie Verfahren zur Herstellung einer positiven Elektrode für Lithium-Sekundärbatterien
FR2721308B1 (fr) * 1994-06-21 1996-10-11 Commissariat Energie Atomique Composés d'insertion à base d'oxyde de manganèse, utilisables comme électrode positive dans un accumulateur au lithium.

Also Published As

Publication number Publication date
EP0728701B1 (de) 2000-01-05
US5807646A (en) 1998-09-15
EP0728701A1 (de) 1996-08-28
DE69605952T2 (de) 2000-07-20

Similar Documents

Publication Publication Date Title
DE69605952T2 (de) Spinel-Lithium-Manganoxid-Material, Verfahren zu seiner Herstellung und seine Verwendung
DE69801714T2 (de) Heteroelemente enthaltende Spinel-Lithium-Manganoxid-Material, Verfahren zu seiner Herstellung und seine Verwendung
DE69500288D1 (de) Poröser Film, Verfahren zu seiner Herstellung und seine Verwendung
DE59508149D1 (de) Aerogelhaltiges verbundmaterial, verfahren zu seiner herstellung sowie seine verwendung
DE69722988D1 (de) Lithiumnickelverbundoxid, Verfahren zu seiner Herstellung und seine Verwendung
DE59208738D1 (de) Poröses Honeycomb-Material, Verfahren zu seiner Herstellung und seine Verwendung
ATE279251T1 (de) Stickoxid-speichermaterial und daraus hergestellter stickoxid-speicherkatalysator, verfahren zu dessen herstellung und seine verwendung
DE69704327D1 (de) Lithium Nickel Kupfer Mischoxid und Verfahren zu seiner Herstellung und seine Verwendung
DE59608388D1 (de) Verstärktes formteil, verfahren zu seiner herstellung und seine verwendung
DE59800437D1 (de) Dispersionsverfestigter Platin-Werkstoff, Verfahren zu seiner Herstellung und seine Verwendung
DE69411632T2 (de) Filtermaterial und Verfahren zu seiner Herstellung
DE69713988T2 (de) Silberoxid zur Verwendung in Zelle und Verfahren zu seiner Herstellung
DE69409886T2 (de) Katalytischer Konverter - metallische Folie und seine Anwendung, und Verfahren zu seiner Herstellung
DE69116599D1 (de) Polyisocyanatoisocyanurat, Verfahren zu seiner Herstellung und seine Verwendung
DE69417432T2 (de) Retroreflektierendes blattmaterial,verfahren zu seiner herstellung und verwendung
DE60007280D1 (de) Bildempfangsmaterial und verfahren zu ihrer herstellung und verwendung
DE69533082D1 (de) Ionenleitender Polymerelektrolyt, Verfahren zur Herstellung des Elektrolyts und seine Verwendung in Kondensatoren
DE19880237D2 (de) Deformationselement, Verfahren zu seiner Herstellung und seine Verwendung
DE69613323D1 (de) Gleitwerkstoff und Verfahren zu seiner Herstellung
DE69622456T2 (de) Aufzeichnungsmaterial und Verfahren zu seiner Herstellung
DE58903740D1 (de) Pulverfoermiger dentalwerkstoff, verfahren zu seiner herstellung und seine verwendung.
DE59506347D1 (de) Zirkondioxidpulver, Verfahren zu seiner Herstellung und Verwendung
DE69709601D1 (de) Lithiumeisenoxyd, Verfahren zu seiner Herstellung und Lithiumbatterie unter Verwendung desselben
DE3689511D1 (de) Ionomermodifiziertes Polyethylen, Verfahren zu seiner Herstellung und seine Verwendung als Folienmaterial.
DE69201431D1 (de) Zinkoxidkristall und Verfahren zu seiner Herstellung.

Legal Events

Date Code Title Description
8364 No opposition during term of opposition