DE69735068D1 - Heterocyclische Metallocne und Polymerisationskatalysatoren - Google Patents
Heterocyclische Metallocne und PolymerisationskatalysatorenInfo
- Publication number
- DE69735068D1 DE69735068D1 DE69735068T DE69735068T DE69735068D1 DE 69735068 D1 DE69735068 D1 DE 69735068D1 DE 69735068 T DE69735068 T DE 69735068T DE 69735068 T DE69735068 T DE 69735068T DE 69735068 D1 DE69735068 D1 DE 69735068D1
- Authority
- DE
- Germany
- Prior art keywords
- polymerization catalysts
- heterocyclic metallocene
- metallocene
- heterocyclic
- catalysts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
- C07D333/62—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
- C07D333/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
- C07D333/70—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
- C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
- C07D495/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/05—Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96118369 | 1996-11-15 | ||
| EP96118369 | 1996-11-15 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69735068D1 true DE69735068D1 (de) | 2006-04-06 |
| DE69735068T2 DE69735068T2 (de) | 2006-08-24 |
Family
ID=8223400
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69721807T Expired - Lifetime DE69721807T2 (de) | 1996-11-15 | 1997-11-12 | Heterocyclische metallocene und polymerisationskatalysatoren |
| DE69735068T Expired - Lifetime DE69735068T2 (de) | 1996-11-15 | 1997-11-12 | Heterocyclische Metallocne und Polymerisationskatalysatoren |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69721807T Expired - Lifetime DE69721807T2 (de) | 1996-11-15 | 1997-11-12 | Heterocyclische metallocene und polymerisationskatalysatoren |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US7238818B2 (de) |
| EP (2) | EP0938491B1 (de) |
| KR (1) | KR100536794B1 (de) |
| CN (1) | CN1113890C (de) |
| AR (1) | AR009613A1 (de) |
| AU (1) | AU733813B2 (de) |
| BR (1) | BR9715006B1 (de) |
| CA (1) | CA2271861C (de) |
| DE (2) | DE69721807T2 (de) |
| ES (2) | ES2256662T3 (de) |
| HU (1) | HUP9904527A2 (de) |
| ID (1) | ID22443A (de) |
| IL (1) | IL129600A0 (de) |
| NO (1) | NO992352L (de) |
| PE (1) | PE52899A1 (de) |
| PL (1) | PL188107B1 (de) |
| RU (1) | RU2194708C2 (de) |
| TR (1) | TR199901635T2 (de) |
| TW (1) | TW394779B (de) |
| WO (1) | WO1998022486A1 (de) |
| ZA (1) | ZA9710211B (de) |
Families Citing this family (115)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69721807T2 (de) * | 1996-11-15 | 2004-03-04 | Basell Polyolefine Gmbh | Heterocyclische metallocene und polymerisationskatalysatoren |
| US6451938B1 (en) † | 1997-02-25 | 2002-09-17 | Exxon Mobil Chemical Patents Inc. | Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands |
| BR9807103A (pt) | 1997-11-12 | 2000-05-16 | Montell Technology Company Bv | Metalocenos,ligantes,catalizador e processo para a polimerizaçào de olefinas |
| US6403773B1 (en) | 1998-09-30 | 2002-06-11 | Exxon Mobil Chemical Patents Inc. | Cationic group 3 catalyst system |
| DE19903306A1 (de) * | 1999-01-28 | 2000-08-03 | Targor Gmbh | Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung |
| EP1074557A3 (de) * | 1999-07-31 | 2003-02-26 | Basell Polyolefine GmbH | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen |
| DE60003936T2 (de) | 1999-09-22 | 2004-05-13 | Basell Polyolefine Gmbh | Katalysatorsystem unf verfahren zur polymerisierung von olefine |
| ES2210015T3 (es) | 1999-11-04 | 2004-07-01 | Exxonmobil Chemical Patents Inc. | Espumas de copolimero de propileno y su uso. |
| US6444833B1 (en) * | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
| US6281306B1 (en) | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
| CN1333032C (zh) | 1999-12-22 | 2007-08-22 | 埃克森美孚化学专利公司 | 聚丙烯基粘合剂组合物 |
| DE19962910A1 (de) | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| DE19962814A1 (de) | 1999-12-23 | 2001-06-28 | Targor Gmbh | Neues Katalysatorsystem und dessen Verwendung |
| KR100723853B1 (ko) | 1999-12-28 | 2007-05-31 | 바셀 테크놀로지 캄파니 비이브이 | 헤테로시클릭 메탈로센 화합물, 및 올레핀 중합체 제조를위한 촉매계에서의 그의 용도 |
| WO2001048040A1 (en) * | 1999-12-28 | 2001-07-05 | Basell Technology Company B.V. | Process for the preparation of ethylene polymers |
| US6864333B2 (en) | 1999-12-28 | 2005-03-08 | Basel Polyolefine Gmbh | Process for the preparation of ethylene polymers |
| DE60109680T2 (de) * | 2000-01-18 | 2006-02-02 | Basell Polyolefine Gmbh | Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis |
| JP2003524013A (ja) | 2000-02-24 | 2003-08-12 | バセル テクノロジー カンパニー ビー．ブイ． | オレフィン重合用助触媒として有用な有機金属化合物 |
| US20040072975A1 (en) | 2000-03-17 | 2004-04-15 | Jorg Schottek | Salt-like chemical compound, its preparation and its use in catalyst systems for preparing polyolefins |
| GB0007002D0 (en) * | 2000-03-22 | 2000-05-10 | Borealis Polymers Oy | Catalysts |
| DE10025412A1 (de) | 2000-05-24 | 2001-11-29 | Basell Polypropylen Gmbh | Als Cokatalysator geeignete chemische Produkte, Verfahren zu ihrer Herstellung und ihre Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
| DE10028432A1 (de) | 2000-06-13 | 2001-12-20 | Basell Polyolefine Gmbh | Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation |
| WO2002051877A2 (en) | 2000-12-22 | 2002-07-04 | Basell Polyolefine Gmbh | Catalyst components for the polymerization of olefins |
| EP1355958A2 (de) | 2000-12-22 | 2003-10-29 | Basell Poliolefine Italia S.p.A. | Verfahren zur herstellung von porösen polymeren und dadurch erhältliche polymere |
| JP2004530689A (ja) | 2001-05-15 | 2004-10-07 | バセル ポリオレフィン ジーエムビーエイチ | シクロペンタジエン誘導体の合成 |
| EP1392705B1 (de) | 2001-05-21 | 2005-01-05 | Basell Polyolefine GmbH | Katalysatorsystem für die polymerisierung von olefinen |
| DE10126265A1 (de) | 2001-05-29 | 2002-12-05 | Basell Polyolefine Gmbh | Verfahren zur Abreicherung von anorganischen Nebenprodukten und organometallischen Nebenprodukten bei der Herstellung von Metallocenen sowie der wirtschaftlichen Rückgewinnung der eingesetzten Edukte |
| US7074864B2 (en) | 2001-06-12 | 2006-07-11 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| ATE519789T1 (de) | 2001-06-12 | 2011-08-15 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von buten-1 |
| EP1397371B1 (de) * | 2001-06-22 | 2006-03-22 | Basell Polyolefine GmbH | Metallocene, verwendung in katalysatoren für olefinpolymerisation |
| DE10145453A1 (de) | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
| ATE412016T1 (de) | 2001-09-14 | 2008-11-15 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von olefinen |
| US7022793B2 (en) | 2001-11-27 | 2006-04-04 | Basell Polyolefine Gmbh | Process for the treatment of polymer compositions |
| ATE334135T1 (de) | 2001-11-30 | 2006-08-15 | Basell Polyolefine Gmbh | Metallocene und verfahren zur herstellung von propylenpolymeren |
| RU2315069C2 (ru) * | 2002-06-26 | 2008-01-20 | Базелль Полиолефин Италия С.П.А. | Ударопрочная полиолефиновая композиция, способ ее получения и изделие, содержащее указанную композицию |
| RU2308470C2 (ru) * | 2002-06-26 | 2007-10-20 | Базелль Полиолефин Италия С.П.А. | Ударопрочные полиолефиновые композиции |
| JP2005538245A (ja) | 2002-07-15 | 2005-12-15 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 担体を有する触媒組成物の製造方法 |
| US7285513B2 (en) | 2002-07-15 | 2007-10-23 | Basell Polyolefine Gmbh | Preparation of catalyst systems |
| US20060089253A1 (en) * | 2002-08-13 | 2006-04-27 | Shahram Mihan | Monocyclopentadienyl complexes |
| JP2005536566A (ja) | 2002-08-22 | 2005-12-02 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | モノシクロペンタジエニル錯体 |
| JP2005538198A (ja) | 2002-09-06 | 2005-12-15 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| AU2003302033A1 (en) | 2002-10-15 | 2004-06-15 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| ATE461222T1 (de) | 2002-11-04 | 2010-04-15 | Basell Polyolefine Gmbh | Herstellung einer katalysatorzusammensetzung mit vetbesserter aktivität |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| DE60329523D1 (de) | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| DE10260095A1 (de) | 2002-12-19 | 2004-07-01 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von heterocyclischen Ketonen |
| CN101372521B (zh) | 2002-12-20 | 2011-09-07 | 巴塞尔聚烯烃有限公司 | 乙烯和α-烯烃的共聚物 |
| ATE399056T1 (de) | 2002-12-20 | 2008-07-15 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
| US7195806B2 (en) | 2003-01-17 | 2007-03-27 | Fina Technology, Inc. | High gloss polyethylene articles |
| US7834107B2 (en) | 2003-04-03 | 2010-11-16 | Basell Polyolefine Gmbh | Preparation of polyolefins having high molecular weights in the presence of an organic transition metal compound in a gas-phase fluidized-bed reactor |
| RU2335338C2 (ru) | 2003-04-17 | 2008-10-10 | Базелль Полиолефин Италия С.Р.Л. | Способ газофазной полимеризации олефинов |
| US7507782B2 (en) | 2003-05-21 | 2009-03-24 | Basell Polyolefine Gmbh | Transition-metal complexes with tridentate, nitrogen-containing ligands |
| KR101167877B1 (ko) | 2003-07-04 | 2012-07-23 | 바젤 폴리올레핀 게엠베하 | 올레핀 중합 방법 |
| DE10352139A1 (de) * | 2003-11-04 | 2005-06-09 | Basell Polyolefine Gmbh | Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem und Verfahren zur Herstellung von Polyolefinen |
| JP2007513990A (ja) | 2003-12-16 | 2007-05-31 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | モノシクロペンタジエニル錯体 |
| JP2007514685A (ja) | 2003-12-19 | 2007-06-07 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | モノシクロペンタジエニル錯体 |
| JP2007515533A (ja) | 2003-12-23 | 2007-06-14 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | オレフィン重合用の触媒組成物 |
| BRPI0418117B1 (pt) | 2003-12-23 | 2015-10-13 | Basell Polyolefine Gmbh | preparação de cocatalisadores suportados |
| US7335250B2 (en) | 2004-02-06 | 2008-02-26 | Ivoclar Vivadent Ag | Dental composites based on X-ray-opaque mixed oxides prepared by flame spraying |
| EP1564226A1 (de) | 2004-02-16 | 2005-08-17 | Stichting Dutch Polymer Institute | Katalysatorsystem auf Basis von Titanocene |
| US7977444B2 (en) | 2004-03-12 | 2011-07-12 | Basell Polyolefine Gmbh | Process for polymerizaing 1-hexene or higher alpha-olefins |
| EP1723184A1 (de) | 2004-03-12 | 2006-11-22 | Basell Polyolefine GmbH | Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen |
| US7799722B2 (en) | 2004-03-12 | 2010-09-21 | Basell Polyolefine Gmbh | Catalyst system for the polymerization of olefin |
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| DE102004039877A1 (de) | 2004-08-17 | 2006-02-23 | Basell Polyolefine Gmbh | Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6 |
| EP1655314A1 (de) | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Polymerisationsverfahren von 1-buten mit propen |
| CN101061142B (zh) | 2004-11-22 | 2012-04-18 | 巴塞尔聚烯烃股份有限公司 | 基于丙烯的三元共聚物 |
| JP2008523231A (ja) * | 2004-12-13 | 2008-07-03 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | ポリオレフィン繊維 |
| DE102004061618A1 (de) * | 2004-12-17 | 2006-06-22 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
| JP2008525651A (ja) * | 2004-12-23 | 2008-07-17 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 弾性を有する繊維 |
| KR100753477B1 (ko) * | 2005-01-31 | 2007-08-31 | 주식회사 엘지화학 | 혼합 담지 메탈로센 촉매, 그 제조방법 및 이를 이용하여제조된 폴리올레핀 및 그 제조 방법 |
| WO2006097500A1 (en) | 2005-03-18 | 2006-09-21 | Basell Polyolefine Gmbh | Metallocene compounds |
| US7799880B2 (en) | 2005-03-23 | 2010-09-21 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
| AU2006226366A1 (en) | 2005-03-23 | 2006-09-28 | Basell Polyolefine Gmbh | Process for the polymerizatio of olefins |
| DE102005014395A1 (de) | 2005-03-24 | 2006-09-28 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe |
| DE102005019395A1 (de) * | 2005-04-25 | 2006-10-26 | Basell Polyolefine Gmbh | Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators |
| DE102005019393A1 (de) | 2005-04-25 | 2006-10-26 | Basell Polyolefine Gmbh | Polyethylenformmassen für Spritzgussanwendungen |
| US7964679B2 (en) | 2005-05-03 | 2011-06-21 | Basell Poliolefine Italia S.R.L. | Process for the polymerization of alpha olefins |
| US7985799B2 (en) | 2005-05-11 | 2011-07-26 | Basell Poliolefine Italia S.R.L. | Polymerization process for preparing polyolefin blends |
| DE102005035477A1 (de) | 2005-07-26 | 2007-02-01 | Basell Polyolefine Gmbh | Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren |
| ATE451377T1 (de) * | 2005-09-19 | 2009-12-15 | Basell Polyolefine Gmbh | Synthese von cyclopentadiendithiophen-derivaten |
| BRPI0617253A2 (pt) * | 2005-10-14 | 2016-04-19 | Basell Polyolefine Gmbh | sistemas catalisadores híbridos suportados sobre halogeneto de magnésio |
| DE102005056775A1 (de) * | 2005-11-28 | 2007-05-31 | Basell Polyolefine Gmbh | Verfahren für den Katalysatorwechsel in einem Gasphasenwirbelschichtreaktor |
| US7868197B2 (en) | 2005-12-14 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization |
| ATE522550T1 (de) | 2007-12-19 | 2011-09-15 | Basell Polyolefine Gmbh | Ethylenterpolymere |
| US8378028B2 (en) * | 2008-02-29 | 2013-02-19 | Basell Poliolefine Italia, s.r.l. | Polyolefin compositions |
| EP2367854B1 (de) | 2008-12-17 | 2012-11-28 | Basell Polyolefine GmbH | Katalysatorsystem für die olefinpolymerisation und herstellung und verwendung davon |
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1997
- 1997-11-12 DE DE69721807T patent/DE69721807T2/de not_active Expired - Lifetime
- 1997-11-12 ZA ZA9710211A patent/ZA9710211B/xx unknown
- 1997-11-12 ES ES03075392T patent/ES2256662T3/es not_active Expired - Lifetime
- 1997-11-12 AU AU53216/98A patent/AU733813B2/en not_active Ceased
- 1997-11-12 EP EP97950179A patent/EP0938491B1/de not_active Expired - Lifetime
- 1997-11-12 KR KR10-1999-7004277A patent/KR100536794B1/ko not_active IP Right Cessation
- 1997-11-12 RU RU99112514/04A patent/RU2194708C2/ru not_active IP Right Cessation
- 1997-11-12 BR BRPI9715006-1A patent/BR9715006B1/pt not_active IP Right Cessation
- 1997-11-12 CN CN97181299A patent/CN1113890C/zh not_active Expired - Lifetime
- 1997-11-12 HU HU9904527A patent/HUP9904527A2/hu unknown
- 1997-11-12 ID IDW990456A patent/ID22443A/id unknown
- 1997-11-12 TR TR1999/01635T patent/TR199901635T2/xx unknown
- 1997-11-12 PL PL97333462A patent/PL188107B1/pl not_active IP Right Cessation
- 1997-11-12 DE DE69735068T patent/DE69735068T2/de not_active Expired - Lifetime
- 1997-11-12 IL IL12960097A patent/IL129600A0/xx unknown
- 1997-11-12 WO PCT/EP1997/006297 patent/WO1998022486A1/en active IP Right Grant
- 1997-11-12 ES ES97950179T patent/ES2197377T3/es not_active Expired - Lifetime
- 1997-11-12 EP EP03075392A patent/EP1327636B1/de not_active Expired - Lifetime
- 1997-11-12 CA CA002271861A patent/CA2271861C/en not_active Expired - Lifetime
- 1997-11-17 AR ARP970105366A patent/AR009613A1/es active IP Right Grant
- 1997-11-17 PE PE1997001036A patent/PE52899A1/es not_active Application Discontinuation
- 1997-11-28 TW TW086117931A patent/TW394779B/zh not_active IP Right Cessation
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1999
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