DE69736847D1 - Herstellung von Laktamen aus aliphatischen Alpha,Omega-Dinitrilen - Google Patents
Herstellung von Laktamen aus aliphatischen Alpha,Omega-DinitrilenInfo
- Publication number
- DE69736847D1 DE69736847D1 DE69736847T DE69736847T DE69736847D1 DE 69736847 D1 DE69736847 D1 DE 69736847D1 DE 69736847 T DE69736847 T DE 69736847T DE 69736847 T DE69736847 T DE 69736847T DE 69736847 D1 DE69736847 D1 DE 69736847D1
- Authority
- DE
- Germany
- Prior art keywords
- dinitriles
- lactams
- omega
- production
- aliphatic alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
- C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D211/74—Oxygen atoms
- C07D211/76—Oxygen atoms attached in position 2 or 6
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/19—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and carboxyl groups, other than cyano groups, bound to the same saturated acyclic carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/23—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and carboxyl groups, other than cyano groups, bound to the same unsaturated acyclic carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
- C07D223/02—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings
- C07D223/06—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D223/08—Oxygen atoms
- C07D223/10—Oxygen atoms attached in position 2
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
- C12N1/20—Bacteria; Culture media therefor
- C12N1/205—Bacterial isolates
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/14—Hydrolases (3)
- C12N9/78—Hydrolases (3) acting on carbon to nitrogen bonds other than peptide bonds (3.5)
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/88—Lyases (4.)
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P13/00—Preparation of nitrogen-containing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P13/00—Preparation of nitrogen-containing organic compounds
- C12P13/002—Nitriles (-CN)
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P13/00—Preparation of nitrogen-containing organic compounds
- C12P13/02—Amides, e.g. chloramphenicol or polyamides; Imides or polyimides; Urethanes, i.e. compounds comprising N-C=O structural element or polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P17/00—Preparation of heterocyclic carbon compounds with only O, N, S, Se or Te as ring hetero atoms
- C12P17/10—Nitrogen as only ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12R—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES C12C - C12Q, RELATING TO MICROORGANISMS
- C12R2001/00—Microorganisms ; Processes using microorganisms
- C12R2001/01—Bacteria or Actinomycetales ; using bacteria or Actinomycetales
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US650073 | 1996-05-17 | ||
US08/650,073 US5858736A (en) | 1996-05-17 | 1996-05-17 | Preparation of lactams from aliphatic α,ω-dinitriles |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69736847D1 true DE69736847D1 (de) | 2006-11-30 |
DE69736847T2 DE69736847T2 (de) | 2007-04-12 |
Family
ID=24607336
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69729864T Expired - Fee Related DE69729864T2 (de) | 1996-05-17 | 1997-05-07 | Herstellung von laktamen aus aliphatischen alpha, omega-dinitrilen |
DE69736847T Expired - Lifetime DE69736847T2 (de) | 1996-05-17 | 1997-05-07 | Herstellung von Laktamen aus aliphatischen Alpha,Omega-Dinitrilen |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69729864T Expired - Fee Related DE69729864T2 (de) | 1996-05-17 | 1997-05-07 | Herstellung von laktamen aus aliphatischen alpha, omega-dinitrilen |
Country Status (8)
Country | Link |
---|---|
US (7) | US5858736A (de) |
EP (3) | EP1466971B1 (de) |
KR (2) | KR100552025B1 (de) |
CN (5) | CN1253554C (de) |
CA (1) | CA2254902A1 (de) |
DE (2) | DE69729864T2 (de) |
TW (1) | TW591014B (de) |
WO (1) | WO1997044318A1 (de) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10179183A (ja) * | 1996-12-20 | 1998-07-07 | Daicel Chem Ind Ltd | カルボン酸の製造方法 |
US20010047183A1 (en) * | 2000-04-05 | 2001-11-29 | Salvatore Privitera | Surgical device for the collection of soft tissue |
NL1011867C2 (nl) * | 1999-04-22 | 2000-10-24 | Dsm Nv | Werkwijze voor de bereiding van een lineair, onverzadigd C3 - C8 carbonzuur. |
US6368804B1 (en) * | 1999-07-12 | 2002-04-09 | E. I. Du Pont De Nemours & Company | Method for stabilizing nitrilase activity and preserving microbial cells |
US6551804B2 (en) * | 1999-07-12 | 2003-04-22 | E. I. Du Pont De Nemours And Company | Process for preparing 4-cyanopentanoic acid |
US6251646B1 (en) * | 1999-07-12 | 2001-06-26 | E. I. Du Pont De Nemours And Company | Method for stabilizing nitrilase activity and preserving microbial cells |
MY133839A (en) * | 2000-03-14 | 2007-11-30 | Shell Int Research | Process for the carbonylation of pentenenitrile |
WO2001075077A2 (en) * | 2000-03-31 | 2001-10-11 | E.I. Dupont De Nemours And Company | Isolation and expression of a gene for a nitrilase from acidovorax facilis 72w |
US6562603B2 (en) | 2000-08-04 | 2003-05-13 | E. I. Du Pont De Nemours And Company | 3-hydroxycarboxylic acid production and use in branched polymers |
US6455730B1 (en) * | 2000-08-04 | 2002-09-24 | E. I. Du Pont De Nemours & Company | Preparation of dicarboxylic acid monoesters from cyanocarboxylic acid esters |
EA200300426A1 (ru) | 2000-09-30 | 2004-04-29 | Норт Каролина Стейт Юниверсити | Способы получения парагидроксибензоата в бактериях |
US6416980B1 (en) | 2001-02-23 | 2002-07-09 | E. I. Du Pont De Nemours & Company | Method for producing glycolic acid from glycolonitrile using nitrilase |
FR2824823A1 (fr) * | 2001-05-21 | 2002-11-22 | Aventis Animal Nutrition Sa | Procede de preparation d'acides carboxyliques aliphatiques par hydrolyse enzymatique de composes nitriles aliphatiques |
EP1474147B1 (de) * | 2001-12-07 | 2010-05-05 | Vertex Pharmaceuticals Incorporated | Verbindungen auf pyrimidin-basis als gsk-3-hemmer |
US20040225116A1 (en) * | 2003-05-08 | 2004-11-11 | Payne Mark S. | Nucleic acid fragments encoding nitrile hydratase and amidase enzymes from comamonas testosteroni 5-MGAM-4D and recombinant organisms expressing those enzymes useful for the production of amides and acids |
US7198926B2 (en) * | 2003-05-08 | 2007-04-03 | E. I. Du Pont De Nemours And Company | Preparation of (E)- and (Z)-2-methyl-2-butenoic acids |
EP1639118A1 (de) * | 2003-06-19 | 2006-03-29 | Pfizer Products Inc. | Biokatalytische herstellung von 1-cyano-cyclohexanessigsäure |
UA82292C2 (uk) * | 2004-04-14 | 2008-03-25 | Пфайзер Продактс Инк. | Спосіб стереоселективного біоперетворення аліфатичних динітрилів в ціанокарбонові кислоти (варіанти) |
WO2006069129A1 (en) * | 2004-12-22 | 2006-06-29 | E.I. Dupont De Nemours And Company | Method for the production of glycolic acid from ammonium glycolate by direct deammoniation |
US7198927B2 (en) | 2004-12-22 | 2007-04-03 | E. I. Du Pont De Nemours And Company | Enzymatic production of glycolic acid |
US7445917B2 (en) * | 2004-12-22 | 2008-11-04 | E.I. Du Pont De Nemours And Company | Process for producing glycolic acid from formaldehyde and hydrogen cyanide |
MX2008003428A (es) * | 2005-09-15 | 2008-03-27 | Ucb Pharma Sa | Pirrolidin -2-onas sustituidas en la posicion 4 y sus usos. |
DE102006028817A1 (de) * | 2006-06-21 | 2007-12-27 | Evonik Degussa Gmbh | Aufarbeitung von Reaktionslösungen aus Ganzzell-Biotransformationen |
US20100267100A1 (en) * | 2007-03-21 | 2010-10-21 | Ling Hua | Enzymatic synthesis of optically pure beta-hydroxy carboxylic acids and their derivatives |
US20090004720A1 (en) * | 2007-06-26 | 2009-01-01 | Ling Hua | Smart Biocatalysts For Organic Synthesis |
US7871802B2 (en) * | 2007-10-31 | 2011-01-18 | E.I. Du Pont De Nemours And Company | Process for enzymatically converting glycolonitrile to glycolic acid |
US7741088B2 (en) * | 2007-10-31 | 2010-06-22 | E.I. Dupont De Nemours And Company | Immobilized microbial nitrilase for production of glycolic acid |
DE102007060705A1 (de) * | 2007-12-17 | 2009-06-18 | Evonik Degussa Gmbh | ω-Aminocarbonsäuren oder ihre Lactame, herstellende, rekombinante Zellen |
US9190785B1 (en) * | 2014-09-09 | 2015-11-17 | Gene Rogero | Versatile adapter having a main body with a plug, a receptacle and two different kinds of adapters |
JPWO2021100759A1 (de) * | 2019-11-19 | 2021-05-27 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1171323A (fr) * | 1955-08-04 | 1959-01-23 | Union Carbide & Carbon Corp | Procédé de fabrication de la 2-pyrrolidone |
FR1226354A (fr) * | 1958-06-06 | 1960-07-11 | Montedison Spa | Procédé pour la production de caprolactame à partir d'esters de l'acide 5-cyano-(3)-penténoïque |
US3288779A (en) * | 1962-08-22 | 1966-11-29 | American Cyanamid Co | 2-cyanovinyl esters of organic carboxylic acids |
US3658878A (en) * | 1965-12-20 | 1972-04-25 | Eastman Kodak Co | Ethylenically unsaturated cyano group containing compounds |
US3728375A (en) * | 1971-05-12 | 1973-04-17 | Eastman Kodak Co | Cyanoacrylate adhesive compositions |
DE2932456A1 (de) * | 1979-08-10 | 1981-02-26 | Chevron Res | Verfahren zur herstellung von 2-pyrrolidon |
US4329498A (en) * | 1979-09-11 | 1982-05-11 | Allied Corporation | Preparation of 6-aminocaproic acid via muconic acid mononitrile |
DE3403574A1 (de) * | 1984-02-02 | 1985-08-08 | Basf Ag, 6700 Ludwigshafen | Verfahren zur gewinnung von caprolactam aus (epsilon)-aminocapronsaeure |
CN85107055A (zh) * | 1984-10-01 | 1986-06-10 | 诺沃工业联合股票公司 | 酶促工艺方法 |
EP0178160B1 (de) * | 1984-10-09 | 1990-03-21 | Arley Holdings Plc | Photographischer Entwicklungstank |
US4625023A (en) * | 1985-09-03 | 1986-11-25 | Allied Corporation | Selective conversion of aliphatic and aromatic aminonitriles and/or dinitriles into lactams |
DE3602377A1 (de) * | 1986-01-28 | 1987-07-30 | Basf Ag | Verfahren zur herstellung von caprolactam |
JP3009421B2 (ja) * | 1990-02-28 | 2000-02-14 | 秀明 山田 | 有機酸の生物学的製造法 |
DE4033259A1 (de) * | 1990-10-19 | 1992-04-23 | Basf Ag | Verfahren zur herstellung von 2-pyrrolidinonen |
FR2694571B1 (fr) * | 1992-08-10 | 1994-11-04 | Rhone Poulenc Chimie | Polypeptides possédant une activité nitrilase, séquence d'ADN codant pour lesdits polypeptides, cassettes d'expression et micro-organismes hôtes permettant leur obtention. |
US5449780A (en) * | 1994-03-10 | 1995-09-12 | E. I. Du Pont De Nemours And Company | Process for the preparation of 1,3- and 1,5-dialkylpiperidone-2 |
JP3429095B2 (ja) * | 1994-05-27 | 2003-07-22 | ツイマー・アクチェンゲゼルシャフト | α,ω−ジニトリルに基づくポリアミドの製造方法 |
JP3163224B2 (ja) * | 1994-10-14 | 2001-05-08 | 三菱レイヨン株式会社 | 菌体または固定化菌体の懸濁液の保存方法 |
US5637767A (en) * | 1995-06-07 | 1997-06-10 | Warner-Lambert Company | Method of making (S)-3-(aminomethyl)-5-methylhexanoic acid |
-
1996
- 1996-05-17 US US08/650,073 patent/US5858736A/en not_active Expired - Lifetime
-
1997
- 1997-05-07 DE DE69729864T patent/DE69729864T2/de not_active Expired - Fee Related
- 1997-05-07 EP EP04076463A patent/EP1466971B1/de not_active Expired - Lifetime
- 1997-05-07 WO PCT/US1997/007796 patent/WO1997044318A1/en active IP Right Grant
- 1997-05-07 CN CNB2004100488914A patent/CN1253554C/zh not_active Expired - Lifetime
- 1997-05-07 EP EP04076478A patent/EP1449830A1/de not_active Withdrawn
- 1997-05-07 CA CA002254902A patent/CA2254902A1/en not_active Abandoned
- 1997-05-07 CN CNA2004100488933A patent/CN1554646A/zh active Pending
- 1997-05-07 CN CNB2004100488929A patent/CN1308443C/zh not_active Expired - Lifetime
- 1997-05-07 KR KR1020057007511A patent/KR100552025B1/ko not_active IP Right Cessation
- 1997-05-07 CN CNB971947023A patent/CN1227226C/zh not_active Expired - Fee Related
- 1997-05-07 CN CNA2004100488859A patent/CN1557945A/zh active Pending
- 1997-05-07 KR KR19980709248A patent/KR100522069B1/ko not_active IP Right Cessation
- 1997-05-07 EP EP97929676A patent/EP0901468B1/de not_active Expired - Lifetime
- 1997-05-07 DE DE69736847T patent/DE69736847T2/de not_active Expired - Lifetime
- 1997-08-13 US US08/910,260 patent/US5814508A/en not_active Expired - Lifetime
- 1997-09-11 TW TW086113201A patent/TW591014B/zh not_active IP Right Cessation
- 1997-12-10 US US08/987,938 patent/US6066490A/en not_active Expired - Lifetime
-
1998
- 1998-07-01 US US09/108,631 patent/US5936114A/en not_active Expired - Lifetime
- 1998-07-01 US US09/108,729 patent/US5922589A/en not_active Expired - Lifetime
- 1998-07-01 US US09/108,728 patent/US6077955A/en not_active Expired - Lifetime
- 1998-07-01 US US09/108,445 patent/US5908954A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
CN1554746A (zh) | 2004-12-15 |
CA2254902A1 (en) | 1997-11-27 |
KR100522069B1 (ko) | 2005-12-21 |
US6077955A (en) | 2000-06-20 |
KR100552025B1 (ko) | 2006-02-16 |
EP1466971A1 (de) | 2004-10-13 |
WO1997044318A1 (en) | 1997-11-27 |
EP1466971B1 (de) | 2006-10-18 |
US6066490A (en) | 2000-05-23 |
KR20000011091A (ko) | 2000-02-25 |
KR20050047140A (ko) | 2005-05-19 |
CN1557945A (zh) | 2004-12-29 |
US5936114A (en) | 1999-08-10 |
CN1253554C (zh) | 2006-04-26 |
US5908954A (en) | 1999-06-01 |
CN1554768A (zh) | 2004-12-15 |
EP0901468A1 (de) | 1999-03-17 |
US5858736A (en) | 1999-01-12 |
TW591014B (en) | 2004-06-11 |
CN1554646A (zh) | 2004-12-15 |
US5814508A (en) | 1998-09-29 |
DE69729864D1 (de) | 2004-08-19 |
CN1219167A (zh) | 1999-06-09 |
US5922589A (en) | 1999-07-13 |
CN1308443C (zh) | 2007-04-04 |
DE69729864T2 (de) | 2005-08-25 |
EP1449830A1 (de) | 2004-08-25 |
DE69736847T2 (de) | 2007-04-12 |
EP0901468B1 (de) | 2004-07-14 |
CN1227226C (zh) | 2005-11-16 |
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