DE69808712D1 - Gegen Kohlenmonoxid unempfindlicher Katalysator und Elektrode für Brennstoffzellen - Google Patents

Gegen Kohlenmonoxid unempfindlicher Katalysator und Elektrode für Brennstoffzellen

Info

Publication number
DE69808712D1
DE69808712D1 DE69808712T DE69808712T DE69808712D1 DE 69808712 D1 DE69808712 D1 DE 69808712D1 DE 69808712 T DE69808712 T DE 69808712T DE 69808712 T DE69808712 T DE 69808712T DE 69808712 D1 DE69808712 D1 DE 69808712D1
Authority
DE
Germany
Prior art keywords
electrode
carbon monoxide
fuel cells
insensitive catalyst
insensitive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69808712T
Other languages
English (en)
Other versions
DE69808712T2 (de
Inventor
Elise Marucchi-Soos
Richard James Bellows
David Terence Buckley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
ExxonMobil Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Research and Engineering Co filed Critical ExxonMobil Research and Engineering Co
Publication of DE69808712D1 publication Critical patent/DE69808712D1/de
Application granted granted Critical
Publication of DE69808712T2 publication Critical patent/DE69808712T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
DE69808712T 1997-08-15 1998-08-13 Gegen Kohlenmonoxid unempfindlicher Katalysator und Elektrode für Brennstoffzellen Expired - Fee Related DE69808712T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/912,878 US5922488A (en) 1997-08-15 1997-08-15 Co-tolerant fuel cell electrode

Publications (2)

Publication Number Publication Date
DE69808712D1 true DE69808712D1 (de) 2002-11-21
DE69808712T2 DE69808712T2 (de) 2003-07-10

Family

ID=25432615

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69808712T Expired - Fee Related DE69808712T2 (de) 1997-08-15 1998-08-13 Gegen Kohlenmonoxid unempfindlicher Katalysator und Elektrode für Brennstoffzellen

Country Status (5)

Country Link
US (1) US5922488A (de)
EP (1) EP0899805B1 (de)
JP (1) JPH11167926A (de)
CA (1) CA2241813A1 (de)
DE (1) DE69808712T2 (de)

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DE19756880A1 (de) * 1997-12-19 1999-07-01 Degussa Anodenkatalysator für Brennstoffzellen mit Polymerelektrolyt-Membranen
DE69900256T2 (de) * 1998-04-23 2002-06-27 N E Chemcat Corp Pt-Ru Elektrokatalysator auf Träger, sowie diesen enthaltende Elektrode, MEA und Festelektrolyt-Brennstoffzelle
US6232264B1 (en) * 1998-06-18 2001-05-15 Vanderbilt University Polymetallic precursors and compositions and methods for making supported polymetallic nanocomposites
US6482763B2 (en) * 1999-12-29 2002-11-19 3M Innovative Properties Company Suboxide fuel cell catalyst for enhanced reformate tolerance
JP2001216991A (ja) * 2000-02-02 2001-08-10 Toyota Motor Corp 燃料電池性能評価装置およびその評価方法、燃料電池用電極触媒の比表面積評価装置およびその評価方法、並びに燃料電池用電極触媒およびその製造方法
US6309769B1 (en) 2000-06-30 2001-10-30 Plug Power Inc. Carbon monoxide filter layer
US6656870B2 (en) * 2000-09-29 2003-12-02 Osram Sylvania Inc. Tungsten-containing fuel cell catalyst and method of making same
US7727927B2 (en) * 2000-09-29 2010-06-01 Global Tungsten & Powders Corp. Method of making tungsten-containing fuel cell catalysts
US20030086866A1 (en) * 2001-10-26 2003-05-08 Wangerow James R. Compact combined shift and selective methanation reactor for co control
US7067208B2 (en) * 2002-02-20 2006-06-27 Ion America Corporation Load matched power generation system including a solid oxide fuel cell and a heat pump and an optional turbine
CA2519957C (en) * 2003-03-26 2012-06-26 Osram Sylvania Inc. Tungsten-based electrocatalyst and fuel cell containing same
GB0411733D0 (en) 2004-05-26 2004-06-30 Johnson Matthey Plc Anode structure
US7736790B2 (en) * 2004-12-06 2010-06-15 Honda Motor Co., Ltd. Platinum and tungsten containing electrocatalysts
US7718309B2 (en) * 2004-12-06 2010-05-18 Honda Motor Co., Ltd. Platinum and tungsten containing electrocatalysts
US7435504B2 (en) * 2005-08-25 2008-10-14 Honda Motor Co., Ltd. Platinum, tungsten, and nickel or zirconium containing electrocatalysts
US7892299B2 (en) * 2005-09-15 2011-02-22 Headwaters Technology Innovation, Llc Methods of manufacturing fuel cell electrodes incorporating highly dispersed nanoparticle catalysts
US7968245B2 (en) * 2006-09-25 2011-06-28 Bloom Energy Corporation High utilization stack
WO2008048445A2 (en) 2006-10-18 2008-04-24 Bloom Energy Corporation Anode with remarkable stability under conditions of extreme fuel starvation
US10615444B2 (en) 2006-10-18 2020-04-07 Bloom Energy Corporation Anode with high redox stability
CA2677291C (en) * 2007-02-26 2016-10-11 Elcomax Gmbh Method for generating a catalyst layer
US20080261099A1 (en) * 2007-04-13 2008-10-23 Bloom Energy Corporation Heterogeneous ceramic composite SOFC electrolyte
US20080254336A1 (en) * 2007-04-13 2008-10-16 Bloom Energy Corporation Composite anode showing low performance loss with time
US20090081527A1 (en) * 2007-09-24 2009-03-26 Ping He Fuel cell system
CN101181679B (zh) * 2007-11-02 2012-09-05 中国科学院上海硅酸盐研究所 一种介孔c/wo3电催化剂及其制备方法
US9246184B1 (en) 2007-11-13 2016-01-26 Bloom Energy Corporation Electrolyte supported cell designed for longer life and higher power
CN105206847B (zh) 2007-11-13 2018-02-09 博隆能源股份有限公司 针对较长寿命和较高电力设计的电解质支撑型电池
FR2924443B1 (fr) * 2007-11-30 2011-08-26 Univ Paris Sud Cellule pour electrolyse de l'eau avec electrolyte solide contenant peu ou pas de metaux nobles
US20110033759A1 (en) * 2008-04-11 2011-02-10 Basf Se Method for operating a fuel cell
US9287571B2 (en) * 2008-07-23 2016-03-15 Bloom Energy Corporation Operation of fuel cell systems with reduced carbon formation and anode leading edge damage
US8617763B2 (en) * 2009-08-12 2013-12-31 Bloom Energy Corporation Internal reforming anode for solid oxide fuel cells
JP5323269B2 (ja) * 2010-01-26 2013-10-23 ブルーム エナジー コーポレーション 燃料電池の構成物、特に固形酸化物型燃料電池の電解質材料
WO2011097461A1 (en) * 2010-02-05 2011-08-11 The Board Of Regents For Oklahoma State University Colorimetric reagent for prevention of peroxide formation in solvents
US8440362B2 (en) 2010-09-24 2013-05-14 Bloom Energy Corporation Fuel cell mechanical components
RU2456079C1 (ru) * 2010-11-02 2012-07-20 Федеральное государственное бюджетное учреждение науки Институт высокотемпературной электрохимии Уральского отделения Российской Академии наук Способ получения наноигольчатых катализаторов окислительно-восстановительных процессов на основе оксидных вольфрамовых бронз
TWI408183B (zh) 2010-12-07 2013-09-11 Ind Tech Res Inst 隔熱材料及其製造方法
CN103055853B (zh) * 2011-10-20 2014-09-03 中国科学院大连化学物理研究所 一种以氧化硅分子筛为模板制备水电解析氧催化剂的方法
CN103157467B (zh) * 2011-12-14 2014-11-05 中国科学院大连化学物理研究所 一种Ru和/或Ir贵金属氧化物及其在析氧电催化的应用
CN103515620B (zh) * 2012-06-20 2015-09-30 江苏氢阳能源有限公司 一种电极材料、其应用、直接燃料电池、及电化学加氢电解槽
WO2014081716A1 (en) 2012-11-20 2014-05-30 Bloom Energy Corporation Doped scandia stabilized zirconia electrolyte compositions
US9755263B2 (en) 2013-03-15 2017-09-05 Bloom Energy Corporation Fuel cell mechanical components
RU2564095C1 (ru) * 2014-04-21 2015-09-27 Борис Иванович Подловченко Анод топливного элемента на основе молибденовых бронз и платины и способ его изготовления
US10651496B2 (en) 2015-03-06 2020-05-12 Bloom Energy Corporation Modular pad for a fuel cell system
US10347930B2 (en) 2015-03-24 2019-07-09 Bloom Energy Corporation Perimeter electrolyte reinforcement layer composition for solid oxide fuel cell electrolytes
WO2018081608A1 (en) * 2016-10-27 2018-05-03 The Regents Of The University Of California Fuel cell with dynamic response capability based on energy storage electrodes
CN107706364B (zh) * 2017-08-25 2020-10-13 宁波富理电池材料科技有限公司 一种正极材料前驱体及其制备方法以及一种正极材料
US10680251B2 (en) 2017-08-28 2020-06-09 Bloom Energy Corporation SOFC including redox-tolerant anode electrode and system including the same
CN108499562B (zh) * 2018-03-13 2020-04-24 中国科学院长春应用化学研究所 一种抗一氧化碳毒化的碳载铂-二氧化钨电催化剂及其制备方法
CN111834642B (zh) * 2019-04-15 2021-12-17 武汉氢阳能源有限公司 一种有机物电催化氧化催化剂及其制备方法和应用
CN110342578B (zh) * 2019-07-17 2021-10-01 中国科学院上海硅酸盐研究所 一种碱金属钨青铜粉体的制备方法
CN116711107A (zh) * 2020-09-28 2023-09-05 海易森汽车股份有限公司 具有使用复合催化剂的增强的一氧化碳耐受性催化剂层的燃料电池
CN113604843B (zh) * 2021-07-02 2023-04-21 北京化工大学 一种低负载量Pt/C催化剂氢气扩散阳极及其制备方法和应用
JP2023059693A (ja) * 2021-10-15 2023-04-27 株式会社キャタラー 水素燃料電池アノード用電極触媒

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JPH05208135A (ja) * 1991-02-23 1993-08-20 Tanaka Kikinzoku Kogyo Kk 負極用電極触媒
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Also Published As

Publication number Publication date
CA2241813A1 (en) 1999-02-15
EP0899805A1 (de) 1999-03-03
DE69808712T2 (de) 2003-07-10
EP0899805B1 (de) 2002-10-16
JPH11167926A (ja) 1999-06-22
US5922488A (en) 1999-07-13

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Legal Events

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8339 Ceased/non-payment of the annual fee