EP0141470A3 - Manganese adjuncts, their preparation and use - Google Patents

Manganese adjuncts, their preparation and use Download PDF

Info

Publication number
EP0141470A3
EP0141470A3 EP84201578A EP84201578A EP0141470A3 EP 0141470 A3 EP0141470 A3 EP 0141470A3 EP 84201578 A EP84201578 A EP 84201578A EP 84201578 A EP84201578 A EP 84201578A EP 0141470 A3 EP0141470 A3 EP 0141470A3
Authority
EP
European Patent Office
Prior art keywords
manganese
water
compound
adjunct
sub
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84201578A
Other versions
EP0141470A2 (en
EP0141470B1 (en
Inventor
Timothy David Finch
Raymond John Wilde
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Priority to AT84201578T priority Critical patent/ATE62929T1/en
Publication of EP0141470A2 publication Critical patent/EP0141470A2/en
Publication of EP0141470A3 publication Critical patent/EP0141470A3/en
Application granted granted Critical
Publication of EP0141470B1 publication Critical patent/EP0141470B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes

Abstract

A stable manganese adjunct for use as a bleach catalyst is obtained by having a manganese (II) cation bound to a "ligand" forming either a true complex compound, a water-insoluble salt compound, or an ion-binding compound by adsorption, which compound is then protectively enclosed in a matrix of water-soluble or water-dispersible material.The adjunct is particularly suitable for incorporation in fabric-washing powder compositions containing a peroxide bleach without causing instability to the composition and brown discolouration due to Mn0<sub>2</sub> formation.
EP84201578A 1983-11-08 1984-11-02 Manganese adjuncts, their preparation and use Expired - Lifetime EP0141470B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT84201578T ATE62929T1 (en) 1983-11-08 1984-11-02 MANGANESE SUPPLEMENTS, THEIR PREPARATION AND USE.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB838329762A GB8329762D0 (en) 1983-11-08 1983-11-08 Manganese adjuncts
GB8329762 1983-11-08

Publications (3)

Publication Number Publication Date
EP0141470A2 EP0141470A2 (en) 1985-05-15
EP0141470A3 true EP0141470A3 (en) 1988-09-14
EP0141470B1 EP0141470B1 (en) 1991-04-24

Family

ID=10551418

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84201578A Expired - Lifetime EP0141470B1 (en) 1983-11-08 1984-11-02 Manganese adjuncts, their preparation and use

Country Status (18)

Country Link
US (1) US4626373A (en)
EP (1) EP0141470B1 (en)
JP (1) JPS60115700A (en)
AT (1) ATE62929T1 (en)
AU (1) AU549623B2 (en)
BR (1) BR8405679A (en)
CA (1) CA1234382A (en)
DE (1) DE3484498D1 (en)
DK (1) DK530284A (en)
ES (1) ES537422A0 (en)
FI (1) FI844337L (en)
GB (2) GB8329762D0 (en)
GR (1) GR80857B (en)
IN (1) IN159938B (en)
NO (1) NO844414L (en)
PH (1) PH21422A (en)
PT (1) PT79465B (en)
ZA (1) ZA848703B (en)

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GB8329761D0 (en) * 1983-11-08 1983-12-14 Unilever Plc Metal adjuncts
GB8502032D0 (en) * 1985-01-28 1985-02-27 Unilever Plc Detergent powder
US4711748A (en) * 1985-12-06 1987-12-08 Lever Brothers Company Preparation of bleach catalyst aggregates of manganese cation impregnated aluminosilicates by high velocity granulation
US4728455A (en) * 1986-03-07 1988-03-01 Lever Brothers Company Detergent bleach compositions, bleaching agents and bleach activators
GB8619153D0 (en) * 1986-08-06 1986-09-17 Unilever Plc Fabric conditioning composition
GB8619152D0 (en) * 1986-08-06 1986-09-17 Unilever Plc Conditioning fabrics
US4731196A (en) * 1986-10-28 1988-03-15 Ethyl Corporation Process for making bleach activator
US5141664A (en) * 1987-12-30 1992-08-25 Lever Brothers Company, A Division Of Conopco, Inc. Clear detergent gel compositions having opaque particles dispersed therein
US5215543A (en) * 1988-12-28 1993-06-01 Elf Atochem North America, Inc. Method for bleaching and abrading fabrics
US5021187A (en) * 1989-04-04 1991-06-04 Lever Brothers Company, Division Of Conopco, Inc. Copper diamine complexes and their use as bleach activating catalysts
ES2016465A6 (en) * 1989-06-14 1990-11-01 Camp Jabones Textile bleaching compositions effective at low temperatures.
GB9003741D0 (en) * 1990-02-19 1990-04-18 Unilever Plc Bleach activation
GB9118242D0 (en) * 1991-08-23 1991-10-09 Unilever Plc Machine dishwashing composition
GB9124581D0 (en) * 1991-11-20 1992-01-08 Unilever Plc Bleach catalyst composition,manufacture and use thereof in detergent and/or bleach compositions
US5153161A (en) * 1991-11-26 1992-10-06 Lever Brothers Company, Division Of Conopco, Inc. Synthesis of manganese oxidation catalyst
CA2085642A1 (en) * 1991-12-20 1993-06-21 Ronald Hage Bleach activation
US5280117A (en) * 1992-09-09 1994-01-18 Lever Brothers Company, A Division Of Conopco, Inc. Process for the preparation of manganese bleach catalyst
GB9305598D0 (en) * 1993-03-18 1993-05-05 Unilever Plc Bleach catalyst composition
US5413733A (en) * 1993-07-26 1995-05-09 Lever Brothers Company, Division Of Conopco, Inc. Amidooxy peroxycarboxylic acids and sulfonimine complex catalysts
US5429769A (en) * 1993-07-26 1995-07-04 Lever Brothers Company, Division Of Conopco, Inc. Peroxycarboxylic acids and manganese complex catalysts
GB9318295D0 (en) * 1993-09-03 1993-10-20 Unilever Plc Bleach catalyst composition
US5686014A (en) * 1994-04-07 1997-11-11 The Procter & Gamble Company Bleach compositions comprising manganese-containing bleach catalysts
DE69504489T2 (en) * 1994-04-07 1999-05-20 Procter & Gamble BLEACHING AGENTS CONTAINING METAL BLEACHING CATALYSTS AND ANTIOXIDANTS
AU2524495A (en) * 1994-05-09 1995-11-29 Unilever Plc Bleach catalyst composition
US5560748A (en) * 1994-06-10 1996-10-01 The Procter & Gamble Company Detergent compositions comprising large pore size redox catalysts
GB2294268A (en) 1994-07-07 1996-04-24 Procter & Gamble Bleaching composition for dishwasher use
US5720897A (en) * 1995-01-25 1998-02-24 University Of Florida Transition metal bleach activators for bleaching agents and detergent-bleach compositions
US5968881A (en) * 1995-02-02 1999-10-19 The Procter & Gamble Company Phosphate built automatic dishwashing compositions comprising catalysts
DE69608541T2 (en) * 1995-02-02 2001-01-18 Procter & Gamble MACHINE DISHWASHER COMPOSITIONS WITH COBALT CHELATE CATALYSTS
ATE209245T1 (en) * 1995-02-02 2001-12-15 Procter & Gamble METHOD FOR REMOVAL OF TEA STAINS IN DISHWASHERS HAVING COMPOSITIONS CONTAINING COBALT (III) CATALYST
ATE203051T1 (en) * 1995-06-16 2001-07-15 Procter & Gamble MACHINE DISHWASHING DETERGENT CONTAINING COBALT CATALYSTS
BR9609384A (en) * 1995-06-16 1999-05-18 Procter & Gamble Bleaching compositions comprising cobalt catalysts
US5703034A (en) * 1995-10-30 1997-12-30 The Procter & Gamble Company Bleach catalyst particles
EP0778342A1 (en) 1995-12-06 1997-06-11 The Procter & Gamble Company Detergent compositions
DE19721886A1 (en) 1997-05-26 1998-12-03 Henkel Kgaa Bleaching system
HUP0101233A2 (en) 1997-11-21 2001-08-28 The Procter & Gamble Co. Product applicator
GB0004988D0 (en) * 2000-03-01 2000-04-19 Unilever Plc Composition and method for bleaching a substrate
CA2483393A1 (en) 2002-05-02 2003-11-13 The Procter & Gamble Company Detergent compositions and components thereof
EP1590426B1 (en) 2003-02-03 2014-01-08 Unilever PLC Laundry cleansing and conditioning compositions
ES2312089T3 (en) * 2005-07-08 2009-02-16 Unilever N.V. COMPOSITIONS FOR DISHWASHING MACHINES AND ITS USE.
US20070138674A1 (en) 2005-12-15 2007-06-21 Theodore James Anastasiou Encapsulated active material with reduced formaldehyde potential
GB0718777D0 (en) 2007-09-26 2007-11-07 Reckitt Benckiser Nv Composition
DE102008038376A1 (en) 2008-08-19 2010-02-25 Clariant International Ltd. Process for the preparation of 3,7-diazabicyclo [3.3.1] nonane compounds
DE102008045207A1 (en) 2008-08-30 2010-03-04 Clariant International Limited Bleach catalyst mixtures consisting of manganese salts and oxalic acid or salts thereof
DE102008045215A1 (en) 2008-08-30 2010-03-04 Clariant International Ltd. Use of manganese oxalates as bleaching catalysts
DE102008064009A1 (en) 2008-12-19 2010-06-24 Clariant International Ltd. Process for the preparation of 3,7-diaza-bicyclo [3.3.1] nonane-metal complexes
EP2441820A1 (en) * 2010-10-14 2012-04-18 Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House Laundry detergent particles
GB201021541D0 (en) * 2010-12-21 2011-02-02 Reckitt Benckiser Nv Bleach catalyst particle
FR2985274B1 (en) 2012-01-04 2021-01-08 Procter & Gamble FIBROUS STRUCTURES INCLUDING PARTICLES AND THEIR MANUFACTURING PROCESS
US10837949B1 (en) * 2012-03-22 2020-11-17 Piers Richard Warburton Peracetic acid sensor with filter to remove hydrogen peroxide
US10196592B2 (en) 2014-06-13 2019-02-05 Ecolab Usa Inc. Enhanced catalyst stability for alkaline detergent formulations
US9624119B2 (en) 2014-06-13 2017-04-18 Ecolab Usa Inc. Enhanced catalyst stability in activated peroxygen and/or alkaline detergent formulations
EP3075832B1 (en) 2015-03-30 2021-04-14 Dalli-Werke GmbH & Co. KG Manganese-amino acid compounds in cleaning compositions
ES2727144T3 (en) * 2016-01-06 2019-10-14 Dalli Werke Gmbh & Co Kg Coated Whitening Catalyst
PL3535370T3 (en) 2016-11-01 2020-12-28 The Procter & Gamble Company Methods of using leuco colorants as bluing agents in laundry care compositions
JP6790257B2 (en) 2016-11-01 2020-11-25 ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ Leuco colorants as bluish agents in laundry care compositions, their packaging, kits and methods
US11697904B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
US11697905B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles that exhibit consumer acceptable article in-use properties
CN115742472A (en) 2017-01-27 2023-03-07 宝洁公司 Active agent-containing articles exhibiting consumer acceptable article application characteristics
US11697906B2 (en) 2017-01-27 2023-07-11 The Procter & Gamble Company Active agent-containing articles and product-shipping assemblies for containing the same
EP3444328A1 (en) 2017-08-18 2019-02-20 The Procter & Gamble Company Cleaning agent
US11225631B2 (en) 2018-03-19 2022-01-18 Ecolab Usa Inc. Acidic liquid detergent compositions containing bleach catalyst and free of anionic surfactant
US20200190433A1 (en) 2018-12-14 2020-06-18 The Procter & Gamble Company Foaming Fibrous Structures Comprising Particles and Methods for Making Same
ES2724992B2 (en) 2019-05-16 2020-03-17 Sanchez Sandra Herrero Detergent for washing sportswear and its manufacturing procedure
US11485934B2 (en) 2019-08-02 2022-11-01 The Procter & Gamble Company Foaming compositions for producing a stable foam and methods for making same

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3532634A (en) * 1966-03-01 1970-10-06 United States Borax Chem Bleaching compositions and methods
EP0072166A1 (en) * 1981-08-08 1983-02-16 THE PROCTER &amp; GAMBLE COMPANY Bleach catalyst compositons, use thereof in laundry bleaching and detergent compositions, and process of bleaching therewith
EP0082563A2 (en) * 1981-12-23 1983-06-29 Unilever N.V. Bleach compositions

Family Cites Families (9)

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NL276367A (en) * 1961-03-24
US3156654A (en) * 1961-06-19 1964-11-10 Shell Oil Co Bleaching
GB1120944A (en) * 1964-07-24 1968-07-24 Unilever Ltd Catalysts
US3372125A (en) * 1965-11-15 1968-03-05 Peter Strong & Company Inc Denture cleanser
GB1565807A (en) * 1975-12-18 1980-04-23 Uilever Ltd Process and compositions for cleaning fabrics
DE2902236A1 (en) * 1978-01-25 1979-07-26 Kao Corp BLEACHING AGENT
EP0025608A2 (en) * 1979-09-18 1981-03-25 Süd-Chemie Ag Catalyst for the controlled decomposition of peroxide compounds, its preparation and use; washing or bleaching agent and process for producing a washing or bleaching agent that contains peroxide compounds
US4417994A (en) * 1981-01-24 1983-11-29 The Procter & Gamble Company Particulate detergent additive compositions
US4536183A (en) * 1984-04-09 1985-08-20 Lever Brothers Company Manganese bleach activators

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3532634A (en) * 1966-03-01 1970-10-06 United States Borax Chem Bleaching compositions and methods
EP0072166A1 (en) * 1981-08-08 1983-02-16 THE PROCTER &amp; GAMBLE COMPANY Bleach catalyst compositons, use thereof in laundry bleaching and detergent compositions, and process of bleaching therewith
EP0082563A2 (en) * 1981-12-23 1983-06-29 Unilever N.V. Bleach compositions

Also Published As

Publication number Publication date
IN159938B (en) 1987-06-13
AU3499084A (en) 1985-05-16
CA1234382A (en) 1988-03-22
ATE62929T1 (en) 1991-05-15
GB2149316A (en) 1985-06-12
FI844337L (en) 1985-05-09
JPS60115700A (en) 1985-06-22
ES8600382A1 (en) 1985-09-16
BR8405679A (en) 1985-09-10
ES537422A0 (en) 1985-09-16
GB8329762D0 (en) 1983-12-14
PT79465A (en) 1984-12-01
PT79465B (en) 1986-12-11
GB2149316B (en) 1988-04-27
DK530284A (en) 1985-05-09
AU549623B2 (en) 1986-02-06
FI844337A0 (en) 1984-11-06
EP0141470A2 (en) 1985-05-15
EP0141470B1 (en) 1991-04-24
PH21422A (en) 1987-10-15
GR80857B (en) 1985-02-07
GB8428022D0 (en) 1984-12-12
DK530284D0 (en) 1984-11-07
DE3484498D1 (en) 1991-05-29
NO844414L (en) 1985-05-09
US4626373A (en) 1986-12-02
ZA848703B (en) 1986-07-30

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