EP1719108B1 - Electro-optic display with electro-optic layer adhered to the backplane - Google Patents

Electro-optic display with electro-optic layer adhered to the backplane Download PDF

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Publication number
EP1719108B1
EP1719108B1 EP05724082A EP05724082A EP1719108B1 EP 1719108 B1 EP1719108 B1 EP 1719108B1 EP 05724082 A EP05724082 A EP 05724082A EP 05724082 A EP05724082 A EP 05724082A EP 1719108 B1 EP1719108 B1 EP 1719108B1
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Prior art keywords
electro
optic
display
backplane
adhesive
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EP05724082A
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German (de)
French (fr)
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EP1719108A4 (en
EP1719108A2 (en
Inventor
Gregg M. Duthaler
Guy M. Danner
Jason C. Pinto
Justin J. Abramson
David D. Miller
John Atkinson
Alain Bouchard
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E Ink Corp
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E Ink Corp
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B26/00Optical devices or arrangements for the control of light using movable or deformable optical elements
    • G02B26/02Optical devices or arrangements for the control of light using movable or deformable optical elements for controlling the intensity of light
    • G02B26/026Optical devices or arrangements for the control of light using movable or deformable optical elements for controlling the intensity of light based on the rotation of particles under the influence of an external field, e.g. gyricons, twisting ball displays
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/166Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect
    • G02F1/167Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect by electrophoresis
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1334Constructional arrangements; Manufacturing methods based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/1506Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect caused by electrodeposition, e.g. electrolytic deposition of an inorganic material on or close to an electrode
    • G02F1/1508Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect caused by electrodeposition, e.g. electrolytic deposition of an inorganic material on or close to an electrode using a solid electrolyte
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/1675Constructional details
    • G02F1/16757Microcapsules
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/133707Structures for producing distorted electric fields, e.g. bumps, protrusions, recesses, slits in pixel electrodes
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F2202/00Materials and properties
    • G02F2202/28Adhesive materials or arrangements

Definitions

  • This invention relates to electro-optic displays. More specifically, in one aspect this invention relates to electro-optic displays incorporating a backplane provided with areas of low dielectric constant and/or high resistivity between adjacent pixels, which are designed to eliminate non-imaging areas between adjacent pixels caused by low resolution processes used to produce backplanes.
  • Electro-optic displays comprise a layer of electro-optic material, a term which is used herein in its conventional meaning in the imaging art to refer to a material having first and second display states differing in at least one optical property, the material being changed from its first to its second display state by application of an electric field to the material.
  • the optical property is typically color perceptible to the human eye, it may be another optical property, such as optical transmission, reflectance, luminescence or, in the case of displays intended for machine reading, pseudo-color in the sense of a change in reflectance of electromagnetic wavelengths outside the visible range.
  • the electro-optic displays of the present invention typically contain an electro-optic material which is a solid in the sense that the electro-optic material has solid external surfaces, although the material may, and often does, have internal liquid or gas-filled spaces, and to methods for assembling displays using such an electro-optic material.
  • Such displays using solid electro-optic materials may hereinafter for convenience be referred to as "solid electro-optic displays”.
  • solid electro-optic displays includes rotating bichromal member displays (see below), gas-based electrophoretic displays, encapsulated electrophoretic displays, microcell electrophoretic displays and encapsulated liquid crystal displays.
  • bistable and “bistability” are used herein in their conventional meaning in the art to refer to displays comprising display elements having first and second display states differing in at least one optical property, and such that after any given element has been driven, by means of an addressing pulse of finite duration, to assume either its first or second display state, after the addressing pulse has terminated, that state will persist for at least several times, for example at least four times, the minimum duration of the addressing pulse required to change the state of the display element.
  • some particle-based electrophoretic displays capable of gray scale are stable not only in their extreme black and white states but also in their intermediate gray states, and the same is true of some other types of electro-optic displays. This type of display is properly called “multi-stable” rather than bistable, although for convenience the term “bistable” may be used herein to cover both bistable and multi-stable displays.
  • electro-optic displays are known.
  • One type of electro-optic display is a rotating bichromal member type as described, for example, in U.S. Patents Nos. 5,808,783 ; 5,777,782 ; 5,760,761 ; 6,054,071 6,055,091 ; 6,097,531 ; 6,128,124 ; 6,137,467 ; and 6,147,791 (although this type of display is often referred to as a "rotating bichromal ball" display, the term "rotating bichromal member" is preferred as more accurate since in some of the patents mentioned above the rotating members are not spherical).
  • Such a display uses a large number of small bodies (typically spherical or cylindrical) which have two or more sections with differing optical characteristics, and an internal dipole. These bodies are suspended within liquid-filled vacuoles within a matrix, the vacuoles being filled with liquid so that the bodies are free to rotate. The appearance of the display is changed by applying an electric field thereto, thus rotating the bodies to various positions and varying which of the sections of the bodies is seen through a viewing surface.
  • This type of electro-optic medium is typically bistable.
  • electro-optic display uses an electrochromic medium, for example an electrochromic medium in the form of a nanochromic film comprising an electrode formed at least in part from a semi-conducting metal oxide and a plurality of dye molecules capable of reversible color change attached to the electrode; see, for example O'Regan, B., et al., Nature 1991, 353, 737 ; and Wood, D., Information Display, 18(3), 24 (March 2002 ). See also Bach, U., et al., Adv. Mater., 2002, 14(11), 845 . Nanochromic films of this type are also described, for example, in U.S. Patent No. 6,301,038 , International Application Publication No. WO 01/27690 , and in U.S. Patent Application 2003/0214695 . This type of medium is also typically bistable.
  • an electrochromic medium for example an electrochromic medium in the form of a nanochromic film comprising an electrode formed at least in part from a semi-conducting metal
  • Electrophoretic display Another type of electro-optic display, which has been the subject of intense research and development for a number of years, is the particle-based electrophoretic display, in which a plurality of charged particles move through a suspending fluid under the influence of an electric field.
  • Electrophoretic displays can have attributes of good brightness and contrast, wide viewing angles, state bistability, and low power consumption when compared with liquid crystal displays. Nevertheless, problems with the long-term image quality of these displays have prevented their widespread usage. For example, particles that make up electrophoretic displays tend to settle, resulting in inadequate service-life for these displays.
  • electrophoretic media require the presence of a suspending fluid.
  • this suspending fluid is a liquid, but electrophoretic media can be produced using gaseous suspending fluids; see, for example, Kitamura, T., et al., "Electrical toner movement for electronic paper-like display", IDW Japan, 2001, Paper HCSI-1 , and Yamaguchi, Y., et al., "Toner display using insulative particles charged triboelectrically", IDW Japan, 2001, Paper AMD4-4 ).
  • Such gas-based electrophoretic media appear to be susceptible to the same types of problems due to particle settling as liquid-based electrophoretic media, when the media are used in an orientation which permits such settling, for example in a sign where the medium is disposed in a vertical plane. Indeed, particle settling appears to be a more serious problem in gas-based electrophoretic media than in liquid-based ones, since the lower viscosity of gaseous suspending fluids as compared with liquid ones allows more rapid settling of the electrophoretic particles.
  • encapsulated electrophoretic media comprise numerous small capsules, each of which itself comprises an internal phase containing electrophoretically-mobile particles suspended in a liquid suspending medium, and a capsule wall surrounding the internal phase.
  • the capsules are themselves held within a polymeric binder to form a coherent layer positioned between two electrodes.
  • Encapsulated media of this type are described, for example, in U.S. Patents Nos.
  • WO 99/67678 WO 00/05704 ; WO 00/38000 ; WO 00/38001 ; WO00/36560 ; WO 00/67110 ; WO 00/67327 ; WO 01/07961 ; WO 01/08241 ; WO 03/107,315 ; WO 2004/023195 ; WO 2004/049045 ; WO 2004/059378 ; WO 2004/088002 ; WO 2004/088395 ; WO 2004/090857 ; and WO 2004/099862 .
  • the walls surrounding the discrete microcapsules in an encapsulated electrophoretic medium could be replaced by a continuous phase, thus producing a so-called polymer-dispersed electrophoretic display, in which the electrophoretic medium comprises a plurality of discrete droplets of an electrophoretic fluid and a continuous phase of a polymeric material, and that the discrete droplets of electrophoretic fluid within such a polymer-dispersed electrophoretic display may be regarded as capsules or microcapsules even though no discrete capsule membrane is associated with each individual droplet; see for example, the aforementioned 2002/0131147. Accordingly, for purposes of the present application, such polymer-dispersed electrophoretic media are regarded as sub-species of encapsulated electrophoretic media.
  • microcell electrophoretic display A related type of electrophoretic display is a so-called "microcell electrophoretic display".
  • the charged particles and the suspending fluid are not encapsulated within microcapsules but instead are retained within a plurality of cavities formed within a carrier medium, typically a polymeric film.
  • a carrier medium typically a polymeric film.
  • electro-optic display is an electro-wetting display developed by Philips and described in an article in the September 25, 2003 issue of the Journal “Nature” and entitled “Performing Pixels: Moving Images on Electronic Paper “. It is shown in copending U.S. Application Serial No. 10/711,802, filed October 6, 2004 , that such electro-wetting displays can be made bistable
  • electro-optic materials for example, polymer-dispersed liquid crystal, may also be used in the displays of the present invention.
  • electrophoretic media are often opaque (since, for example, in many electrophoretic media, the particles substantially block transmission of visible light through the display) and operate in a reflective mode
  • many electrophoretic displays can be made to operate in a so-called "shutter mode" in which one display state is substantially opaque and one is light-transmissive. See, for example, the aforementioned U.S. Patents Nos. 6,130,774 and 6,172,798 , and U.S. Patents Nos. 5,872,552 ; 6,144,361 ; 6,271,823 ; 6,225,971 ; and 6,184,856 .
  • Dielectrophoretic displays which are similar to electrophoretic displays but rely upon variations in electric field strength, can operate in a similar mode; see U.S. Patent No. 4,418,346 .
  • Other types of electro-optic displays may also be capable of operating in shutter mode.
  • An encapsulated or microcell electrophoretic display typically does not suffer from the clustering and settling failure mode of traditional electrophoretic devices and provides further advantages, such as the ability to print or coat the display on a wide variety of flexible and rigid substrates.
  • printing is intended to include all forms of printing and coating, including, but without limitation: pre-metered coatings such as patch die coating, slot or extrusion coating, slide or cascade coating, curtain coating; roll coating such as knife over roll coating, forward and reverse roll coating; gravure coating; dip coating; spray coating; meniscus coating; spin coating; brush coating; air knife coating; silk screen printing processes; electrostatic printing processes; thermal printing processes; ink jet printing processes; electrophoretic deposition; and other similar techniques.
  • pre-metered coatings such as patch die coating, slot or extrusion coating, slide or cascade coating, curtain coating
  • roll coating such as knife over roll coating, forward and reverse roll coating
  • gravure coating dip coating
  • spray coating meniscus coating
  • spin coating spin coating
  • brush coating air knife coating
  • silk screen printing processes
  • an electro-optic display normally comprises at least two other layers disposed on opposed sides of the electro-optic material, one of these two layers being an electrode layer.
  • both the layers are electrode layers, and one or both of the electrode layers are patterned to define the pixels of the display.
  • one electrode layer may be patterned into elongate row electrodes and the other into elongate column electrodes running at right angles to the row electrodes, the pixels being defined by the intersections of the row and column electrodes.
  • one electrode layer has the form of a single continuous electrode and the other electrode layer is patterned into a matrix of pixel electrodes, each of which defines one pixel of the display.
  • electro-optic display which is intended for use with a stylus, print head or similar movable electrode separate from the display
  • only one of the layers adjacent the electro-optic layer comprises an electrode, the layer on the opposed side of the electro-optic layer typically being a protective layer intended to prevent the movable electrode damaging the electro-optic layer.
  • the manufacture of a three-layer electro-optic display normally involves at least one lamination operation.
  • a process for manufacturing an encapsulated electrophoretic display in which an encapsulated electrophoretic medium comprising capsules in a binder is coated on to a flexible substrate comprising indium-tin-oxide or a similar conductive coating (which acts as an one electrode of the final display) on a plastic film, the capsules/binder coating being dried to form a coherent layer of the electrophoretic medium firmly adhered to the substrate.
  • a backplane containing an array of pixel electrodes and an appropriate arrangement of conductors to connect the pixel electrodes to drive circuitry, is prepared.
  • the substrate having the capsule/binder layer thereon is laminated to the backplane using a lamination adhesive.
  • a lamination adhesive A very similar process can be used to prepare an electrophoretic display useable with a stylus or similar movable electrode by replacing the backplane with a simple protective layer, such as a plastic film, over which the stylus or other movable electrode can slide.
  • the backplane is itself flexible and is prepared by printing the pixel electrodes and conductors on a plastic film or other flexible substrate.
  • the obvious lamination technique for mass production of displays by this process is roll lamination using a lamination adhesive. Similar manufacturing techniques can be used with other types of electro-optic displays.
  • a microcell electrophoretic medium or a rotating bichromal member medium may be laminated to a backplane in substantially the same manner as an encapsulated electrophoretic medium.
  • the lamination of the substrate carrying the electro-optic layer to the backplane may advantageously be carried out by vacuum lamination.
  • Vacuum lamination is effective in expelling air from between the two materials being laminated, thus avoiding unwanted air bubbles in the final display; such air bubbles may introduce undesirable artifacts in the images produced on the display.
  • vacuum lamination of the two parts of an electro-optic display in this manner imposes stringent requirements upon the lamination adhesive used, especially in the case of a display using an encapsulated electrophoretic medium.
  • the lamination adhesive must have sufficient adhesive strength to bind the electro-optic layer to the layer (typically an electrode layer) to which it is to be laminated, and in the case of an encapsulated electrophoretic medium, the adhesive must also have sufficient adhesive strength to mechanically hold the capsules together. If the electro-optic display is to be of a flexible type (and one of the important advantages of rotating bichromal member and encapsulated electrophoretic displays is that they can be made flexible), the adhesive must have sufficient flexibility not to introduce defects into the display when the display is flexed.
  • the lamination adhesive must have adequate flow properties at the lamination temperature to ensure high quality lamination, and in this regard, the demands of laminating encapsulated electrophoretic and some other types of electro-optic media are unusually difficult; the lamination has be conducted at a temperature of not more than about 110°C since the medium cannot be exposed to substantially higher temperatures without damage, but the flow of the adhesive must cope with the relatively uneven surface of the capsule-containing layer, the surface of which is rendered irregular by the underlying capsules.
  • the lamination temperature should indeed be kept as low as possible, and room temperature lamination would be ideal, but no commercial adhesive has been found which permits such room temperature lamination.
  • the lamination adhesive must be chemically compatible with all the other materials in the display. Solvent-based lamination adhesives should be avoided; it has been found (although this does not appear to have been described in the literature), that any solvent left behind in the adhesive after lamination has a strong tendency to introduce undesirable contaminants into the electro-optic medium.
  • a lamination adhesive used in an electro-optic display must meet certain electrical criteria, and this introduces considerable problems in the selection of the lamination adhesive.
  • Commercial manufacturers of lamination adhesives naturally devote considerable effort to ensuring that properties, such as strength of adhesion and lamination temperatures, of such adhesives are adjusted so that the adhesives perform well in their major applications, which typically involve laminating polymeric and similar films.
  • the electrical properties of the lamination adhesive are not relevant, and consequently the commercial manufacturers pay no heed to such electrical properties.
  • the electrical properties of the adhesive become crucial.
  • the volume resistivity of the lamination adhesive becomes important, since the voltage drop across the electro-optic medium is essentially equal to the voltage drop across the electrodes, minus the voltage drop across the lamination adhesive. If the resistivity of the adhesive layer is too high, a substantial voltage drop will occur within the adhesive layer, requiring an increase in voltage across the electrodes. Increasing the voltage across the electrodes in this manner is undesirable, since it increases the power consumption of the display, and may require the use of more complex and expensive control circuitry to handle the increased voltage involved.
  • the volume resistivity of the adhesive layer should not be too low, or lateral conduction of electric current through the continuous adhesive layer may cause undesirable crosstalk between adjacent electrodes.
  • a lamination adhesive layer having a uniform thickness of 10-50 ⁇ m and a conductivity of the order of 10 -10 to 10 -9 S/cm has been used in electro-optic displays.
  • This conductivity range was chosen based upon electrical models for display performance, the known conductivities of various electro-optic materials and the pixel sizes typically used in such displays.
  • This target conductivity range actually represents a compromise.
  • More conductive lamination adhesives are desirable because higher conductivity means the electro-optic material layer sees a larger voltage gradient.
  • charge supplied to a pixel is leaked to neighboring pixels; this decreases the voltage gradient across the ink and counteracts the effect of increasing the lamination adhesive conductivity.
  • this lateral charge leakage may cause a change in the optical state of neighboring pixels. It is desirable that the lamination adhesive be designed to provide good lateral voltage holding capability and that the gradient in voltage across the ink layer be maximized; therefore, development performance requirements for high resolution (100 to 200 lines per inch, 4 to 8 lines per mm) active-matrix displays require that isotropically conductive adhesives have conductivities in the range specified above.
  • the right-hand pixel is Figure 1A has applied thereto a driving voltage which turns the electro-optic medium to its black display state, the resultant black area, designated D2, is substantially larger than pixel 2 itself.
  • D2 the resultant black area
  • a central area between pixels 1 and 2 will turn black whenever the driving voltage is applied to either pixel 1 or pixel 2.
  • Such pixel blooming is undesirable, since it adversely affects the quality of the displayed image.
  • Pixel blooming can be reduced by reducing the thickness of the adhesive layer, but an adhesive layer which is too thin may give rise to other problems.
  • an adhesive layer which is deposited over a layer of capsules forming an encapsulated electrophoretic medium may serve not only to laminate the capsules to a backplane, but also to planarize the uneven surface of the layer of capsules.
  • An adhesive layer which is too thin may fail to provide sufficient adhesion and may also fail to planarize the capsule layer.
  • the aforementioned 2004/0252360 describes an electro-optic display using an anisotropic lamination adhesive having a higher electrical conductivity in a direction perpendicular to the layer of lamination adhesive than in the plane of this layer.
  • One aspect of the present invention relates to an alternative modification of an adhesive layer which provides advantages similar to those provided by the use of an anisotropic lamination adhesive without requiring the formation of such an adhesive. This aspect of the present invention also reduces pixel blooming.
  • This invention provides an electro-optic display comprising a backplane having a plurality of pixel electrodes; an adhesive layer disposed adjacent the backplane; and a solid layer of an electro-optic medium adjacent the adhesive layer on the opposed side thereof from the backplane.
  • the adhesive layer comprises a plurality of pixel regions disposed adjacent the pixel electrodes of the backplane and formed of a first adhesive material, and at least one inter-pixel region disposed adjacent to a gap between neighbouring pixel electrodes of the backplane and formed in part of a second material, which second material can be adhesive or non-adhesive, the second material having at least one of a lower dielectric constant and a higher volume resistivity than the first adhesive material.
  • the backplane of the electro-optic display may hereinafter be called the "ribbed backplane" of the invention.
  • the part of the inter-pixel region formed of the second material has the form of a rib.
  • the second material may have a dielectric constant less than about 3, and/or volume resistivity greater than about 10 12 ohm cm.
  • the rib may have an aspect ratio (the height of the rib divided by its width) of at least about 0.5, desirably at least about 1.0 and preferably at least about 2.0.
  • the rib or ribs may not extend completely through the adhesive layer so that the end of the or each rib remote from the backplane is covered by adhesive material.
  • the electro-optic display of the invention may make use of any of the types of bistable electro-optic media discussed above.
  • the display may comprise an electrophoretic electro-optic medium comprising a plurality of electrically charged particles in a suspending fluid and capable of moving through the suspending fluid on application of an electric field to the suspending fluid.
  • the suspending fluid may be gaseous or liquid.
  • the electrophoretic medium may be encapsulated, i.e., the charged particles and the suspending fluid may be confined within a plurality of capsules or microcells.
  • the first method may also be used with a display comprising a rotating bichromal member or electrochromic medium.
  • Figure 1A of the accompanying drawings illustrates the equipotential lines produced when a driving voltage is applied to two adjacent pixels of a prior art electro-optic display.
  • Figure 1B is a view similar to that of Figure 1A but showing the equipotential lines produced when a driving voltage is applied to two adjacent pixels of an electro-optic display of the present invention incorporating a ribbed backplane.
  • Figure 2 is a schematic side elevation of a small section of an encapsulated electrophoretic display of the present invention incorporating a ribbed backplane.
  • this invention provides an electro-optic display comprising a backplane having a plurality of pixel electrodes, an adhesive layer disposed adjacent the backplane, and a layer of a solid electro-optic medium adjacent the adhesive layer on the opposed side thereof from the backplane.
  • the adhesive layer comprises a plurality of pixel regions disposed adjacent the pixel electrodes of the backplane, and at least one inter-pixel region disposed adjacent to a gap between two neighbouring pixels of the backplane. A part of the at least one inter-pixel region has at least one of a lower dielectric constant and a higher volume resistivity than the pixel regions of the adhesive layer.
  • the lower dielectric constant and/or higher volume resistivity of the inter-pixel region of the adhesive layer could be produced by treatment of an originally essentially homogeneous adhesive layer.
  • the adhesive layer could be radiation cured in an imagewise manner to produce inter-pixel regions having higher volume resistivity than the pixel regions of the adhesive layer.
  • the inter-pixel regions be formed by bodies (ribs) which are separate from the remainder of the adhesive layer.
  • the aspect ratio (height/width) of the ribs is desirably greater than about 0.5, preferably greater than about 1.0, and most desirably greater than about 2.0.
  • the ribs will have a width of the order of 1-20 ⁇ m.
  • the ribs may have a variety of cross sections, including square, rectangular, trapezoidal, half-round, etc., depending on the process used to form them and the specific display in which they are used.
  • the ribs may be manufactured using photolithographic methods, printing techniques, or other processes known to those skilled in the art.
  • it may also be possible to fabricate a set of ribs for a backplane as a separate object for example, by punching, die cutting or molding a web of material and then cutting the web to produce sets of ribs for individual displays) and then laminating or adhering the set of ribs to the backplane.
  • the ribs function by reducing the tendency for the equipotential lines to spread out into a blooming pattern. More specifically, the ribs prevent the blooming of the equipotential lines within that portion of the thickness of the adhesive layer lying between the backplane and the upper edges (as illustrated in Figure 1B ) of the ribs, so that overall the blooming of the pixels is reduced and the areas D3 and D4 produced by pixels 3 and 4 are smaller that the corresponding areas D1 and D2 shown in Figure 1A . Also, of course, the overlap between areas D3 and D4 is substantially smaller than that between D1 and D2.
  • FIG. 2 is a schematic side elevation of a small section of an encapsulated electrophoretic display of the present invention incorporating a ribbed backplane.
  • This display (generally designated 200) comprises a backplane 202 having pixel electrodes 204 and 206, an adhesive layer 208, an encapsulated electrophoretic layer 210, a common front electrode 212 and a transparent front substrate 214, which forms a viewing surface through which an observer views the display 200.
  • the display 200 further comprises ribs 216, only one of which is shown in Figure 2 .
  • the ribs 216 are of rectangular cross-section and do not extend completely though the thickness of the adhesive layer 208, so that they do not contact the capsules of the electrophoretic layer 210 being separated therefrom by part of the thickness of the adhesive layer 208.
  • the adhesive layer is approximately 15 ⁇ m thick
  • the ribs 216 may be approximately 6 ⁇ m tall, thus reducing field spreading and blooming to that observed with a 9 ⁇ m adhesive layer.
  • ribs in accordance with the present invention allows the use of a thicker or more conductive adhesive layer that would otherwise be possible without sacrificing resolution through blooming effects.
  • the more conductive adhesive reduces the voltage drop within the adhesive layer, thus increasing the voltage drop across the electro-optic medium itself, and thus increasing the switching speed of the medium.
  • the ribbed backplanes of the present invention may be especially useful in high resolution displays in which the individual pixels are small, since blooming is largely a function of the thickness of the layers lying between the electrodes, and since it is not normally possible to reduce the thickness of these layers as the size of the pixels is reduced, blooming becomes a greater problem with smaller pixels, in the sense that the area affected by blooming becomes larger relative to the size of the individual pixels. Blooming is a particular problem in high resolution color displays. where pixels of differing colors lie closely adjacent each other. Consider for example a red/green/blue color display in which the pixels are arranged in rows of the same color, so that, for example, a red pixel is flanked by blue and green pixels in adjacent rows.
  • the red pixels are set to display red while the green and blue pixels are set to display black. If blooming occurs at the red pixel, part of the adjacent green and blue pixels will display green and blue respectively, thus rendering the desired red color less saturated. The smaller the pixels of such a display, the greater is the effect of a given amount of blooming.
  • ribbed backplanes may be especially useful in color displays.
  • Such color displays may be of any of the types of electro-optic displays known in the art, and in particular may be of any of the types described in the aforementioned 2004/0263947.
  • the displays described in this published application include:
  • Ribbed backplanes are also useful in preventing "creep" in flexible displays, for example displays in which the backplane (and any front substrate present) is formed from a flexible polymeric film, flexible metal foil or similar flexible material.
  • the adhesive layer used to secure the backplane to the electro-optic medium and other layers of the display tends to undergo fluid flow, with the result that the electro-optic medium moves slightly relative to the backplane.
  • the display is a color display in which a color filter array is disposed on the opposed side of the electro-optic medium from the backplane, since in such a display the various color stripes or other units of the color filter array need to aligned with the pixel electrodes or serious color distortion may occur in the displayed image.
  • a display in which two adjacent pixel electrodes are aligned with red and blue color filter elements. If the color filter array creeps relative to the backplane such that the pixel electrode originally aligned with the red element is now aligned with half the red element and half the blue element, it will readily be apparent that the colors of the displayed image will differ substantially from that intended.

Abstract

A backplane for an electro-optic display comprises a plurality of pixel electrodes, and an adhesive layer disposed adjacent the backplane, the adhesive layer comprising a plurality of pixel regions disposed adjacent the pixel electrodes of the backplane, and at least one inter-pixel region disposed between two pixels of the backplane, the at least one inter-pixel region having at least one of a lower dielectric constant and a higher volume resistivity than the pixel regions of the adhesive layer.

Description

  • This application is related to copending U.S. Application Publication No. 2004/0252360 and U.S. Patent No. 6,831,769 . This application is also related to (a) U.S. Application Publication No. 2003/0112491 ); (b) U.S. Patent No. 6,727,881 ; (c) U.S. Patent No. 6,124,851 ; (d) International Application No. PCT/US96/12000 ; (e) U.S. Patent No. 6,120,588 ; (f) U.S. Patent No. 6,657,772 ; (g) U.S. Application Publication No. 2004/0027327 ; (h) U.S. Application Publication No. 2004/0155857 ; (i) U.S. Patent 6,312,304 ; (j) U.S. Application Publication No. 2004/0263947 ; and (k) U.S Application Publication No. 2002/0180688 . The reader is referred to all the aforementioned patents and applications for background information concerning this invention.
  • This invention relates to electro-optic displays. More specifically, in one aspect this invention relates to electro-optic displays incorporating a backplane provided with areas of low dielectric constant and/or high resistivity between adjacent pixels, which are designed to eliminate non-imaging areas between adjacent pixels caused by low resolution processes used to produce backplanes.
  • Electro-optic displays comprise a layer of electro-optic material, a term which is used herein in its conventional meaning in the imaging art to refer to a material having first and second display states differing in at least one optical property, the material being changed from its first to its second display state by application of an electric field to the material. Although the optical property is typically color perceptible to the human eye, it may be another optical property, such as optical transmission, reflectance, luminescence or, in the case of displays intended for machine reading, pseudo-color in the sense of a change in reflectance of electromagnetic wavelengths outside the visible range.
  • The electro-optic displays of the present invention typically contain an electro-optic material which is a solid in the sense that the electro-optic material has solid external surfaces, although the material may, and often does, have internal liquid or gas-filled spaces, and to methods for assembling displays using such an electro-optic material. Such displays using solid electro-optic materials may hereinafter for convenience be referred to as "solid electro-optic displays". Thus, the term "solid electro-optic displays" includes rotating bichromal member displays (see below), gas-based electrophoretic displays, encapsulated electrophoretic displays, microcell electrophoretic displays and encapsulated liquid crystal displays.
  • The terms "bistable" and "bistability" are used herein in their conventional meaning in the art to refer to displays comprising display elements having first and second display states differing in at least one optical property, and such that after any given element has been driven, by means of an addressing pulse of finite duration, to assume either its first or second display state, after the addressing pulse has terminated, that state will persist for at least several times, for example at least four times, the minimum duration of the addressing pulse required to change the state of the display element. It is shown in published U.S. Patent Application No. 2002/0180687 that some particle-based electrophoretic displays capable of gray scale are stable not only in their extreme black and white states but also in their intermediate gray states, and the same is true of some other types of electro-optic displays. This type of display is properly called "multi-stable" rather than bistable, although for convenience the term "bistable" may be used herein to cover both bistable and multi-stable displays.
  • Several types of electro-optic displays are known. One type of electro-optic display is a rotating bichromal member type as described, for example, in U.S. Patents Nos. 5,808,783 ; 5,777,782 ; 5,760,761 ; 6,054,071 6,055,091 ; 6,097,531 ; 6,128,124 ; 6,137,467 ; and 6,147,791 (although this type of display is often referred to as a "rotating bichromal ball" display, the term "rotating bichromal member" is preferred as more accurate since in some of the patents mentioned above the rotating members are not spherical). Such a display uses a large number of small bodies (typically spherical or cylindrical) which have two or more sections with differing optical characteristics, and an internal dipole. These bodies are suspended within liquid-filled vacuoles within a matrix, the vacuoles being filled with liquid so that the bodies are free to rotate. The appearance of the display is changed by applying an electric field thereto, thus rotating the bodies to various positions and varying which of the sections of the bodies is seen through a viewing surface. This type of electro-optic medium is typically bistable.
  • Another type of electro-optic display uses an electrochromic medium, for example an electrochromic medium in the form of a nanochromic film comprising an electrode formed at least in part from a semi-conducting metal oxide and a plurality of dye molecules capable of reversible color change attached to the electrode; see, for example O'Regan, B., et al., Nature 1991, 353, 737; and Wood, D., Information Display, 18(3), 24 (March 2002). See also Bach, U., et al., Adv. Mater., 2002, 14(11), 845. Nanochromic films of this type are also described, for example, in U.S. Patent No. 6,301,038 , International Application Publication No. WO 01/27690 , and in U.S. Patent Application 2003/0214695 . This type of medium is also typically bistable.
  • Another type of electro-optic display, which has been the subject of intense research and development for a number of years, is the particle-based electrophoretic display, in which a plurality of charged particles move through a suspending fluid under the influence of an electric field. Electrophoretic displays can have attributes of good brightness and contrast, wide viewing angles, state bistability, and low power consumption when compared with liquid crystal displays. Nevertheless, problems with the long-term image quality of these displays have prevented their widespread usage. For example, particles that make up electrophoretic displays tend to settle, resulting in inadequate service-life for these displays.
  • As noted above, electrophoretic media require the presence of a suspending fluid. In most prior art electrophoretic media, this suspending fluid is a liquid, but electrophoretic media can be produced using gaseous suspending fluids; see, for example, Kitamura, T., et al., "Electrical toner movement for electronic paper-like display", IDW Japan, 2001, Paper HCSI-1, and Yamaguchi, Y., et al., "Toner display using insulative particles charged triboelectrically", IDW Japan, 2001, Paper AMD4-4). See also European Patent Applications 1,429,178 ; 1,462,847 ; 1,482,354 ; and 1,484,625 ; and International Applications WO 2004/090626 ; WO 2004/079442 ; WO 2004/077140 ; WO 2004/059379 ; WO 2004/055586 ; WO 2004/008239 ; WO 2004/006006 ; WO 2004/001498 ; WO 03/091799 ; and WO 03/088495 . Such gas-based electrophoretic media appear to be susceptible to the same types of problems due to particle settling as liquid-based electrophoretic media, when the media are used in an orientation which permits such settling, for example in a sign where the medium is disposed in a vertical plane. Indeed, particle settling appears to be a more serious problem in gas-based electrophoretic media than in liquid-based ones, since the lower viscosity of gaseous suspending fluids as compared with liquid ones allows more rapid settling of the electrophoretic particles.
  • Numerous patents and applications assigned to or in the names of the Massachusetts Institute of Technology (MIT) and E Ink Corporation have recently been published describing encapsulated electrophoretic media. Such encapsulated media comprise numerous small capsules, each of which itself comprises an internal phase containing electrophoretically-mobile particles suspended in a liquid suspending medium, and a capsule wall surrounding the internal phase. Typically, the capsules are themselves held within a polymeric binder to form a coherent layer positioned between two electrodes. Encapsulated media of this type are described, for example, in U.S. Patents Nos. 5,930,026 ; 5,961,804 ; 6,017,584 ; 6,067,185 ; 6,118,426 ; 6,120,588 ; 6,120,839 ; 6,124,851 ; 6,130,773 ; 6,130,774 ; 6,172,798 ; 6,177,921 ; 6,232,950 ; 6,249,271 ; 6,252,564 ; 6,262,706 ; 6,262,833 ; 6,300,932 ; 6,312,304 ; 6,312,971 ; 6,323,989 ; 6,327,072 ; 6,376,828 ; 6,377,387 ; 6,392,785 ; 6,392,786 ; 6,413,790 ; 6,422,687 ; 6,445,374 ; 6,445,489 ; 6,459,418 ; 6,473,072 ; 6,480,182 ; 6,498,114 ; 6,504,524 ; 6,506,438 ; 6,512,354 ; 6,515,649 ; 6,518,949 ; 6,521,489 ; 6,531,997 ; 6,535,197 ; 6,538,801 ; 6,545,291 ; 6,580,545 ; 6,639,578 ; 6,652,075 ; 6,657,772 ; 6,664,944 ; 6,680,725 ; 6,683,333 ; 6,704,133 ; 6,710,540 ; 6,721,083 ; 6,727,881 ; 6,738,050 ; 6,750,473 ; 6,753,999 ; 6,816,147 ; 6,819,471 ; 6,822,782 ; 6,825,068 ; 6,825,829 ; 6,825,970 ; 6,831,769 ; 6,839,158 ; 6,842,279 ; 6,842,657 ; and 6,842,167 ; and U.S. Patent Applications Publication Nos. 2002/0060321 ; 2002/0060321 ; 2002/0063661 ; 2002/0090980 ; 2002/0113770 ; 2002/0130832 ; 2002/0131147 ; 2002/0171910 ; 2002/0180687 ; 2002/0180688 ; 2003/0011560 ; 2003/0020844 ; 2003/0025855 ; 2003/0102858 ; 2003/0132908 ; 2003/0137521 ; 2003/0151702 ; 2003/0214695 ; 2003/0214697 ; 2003/0222315 ; 2004/0012839 ; 2004/0014265 ; 2004/0027327 ; 2004/0075634 ; 2004/0094422 ; 2004/0105036 ; 2004/0112750 ; 2004/0119681 ; and 2004/0196215 ; 2004/0226820 ; 2004/0233509 ; 2004/0239614 ; 2004/0252360 ; 2004/0257635 ; 2004/0263947 ; 2005/0000813 ; 2005/0001812 ; 2005/0007336 ; 2005/0007653 ; 2005/0012980 ; 2005/0017944 ; 2005/0018273 ; and 2005/0024353 ; and International Applications Publication Nos. WO 99/67678 ; WO 00/05704 ; WO 00/38000 ; WO 00/38001 ; WO00/36560 ; WO 00/67110 ; WO 00/67327 ; WO 01/07961 ; WO 01/08241 ; WO 03/107,315 ; WO 2004/023195 ; WO 2004/049045 ; WO 2004/059378 ; WO 2004/088002 ; WO 2004/088395 ; WO 2004/090857 ; and WO 2004/099862 .
  • Many of the aforementioned patents and applications recognize that the walls surrounding the discrete microcapsules in an encapsulated electrophoretic medium could be replaced by a continuous phase, thus producing a so-called polymer-dispersed electrophoretic display, in which the electrophoretic medium comprises a plurality of discrete droplets of an electrophoretic fluid and a continuous phase of a polymeric material, and that the discrete droplets of electrophoretic fluid within such a polymer-dispersed electrophoretic display may be regarded as capsules or microcapsules even though no discrete capsule membrane is associated with each individual droplet; see for example, the aforementioned 2002/0131147. Accordingly, for purposes of the present application, such polymer-dispersed electrophoretic media are regarded as sub-species of encapsulated electrophoretic media.
  • A related type of electrophoretic display is a so-called "microcell electrophoretic display". In a microcell electrophoretic display, the charged particles and the suspending fluid are not encapsulated within microcapsules but instead are retained within a plurality of cavities formed within a carrier medium, typically a polymeric film. See, for example, International Application Publication No. WO 02/01281 , and published US Application No. 2002/0075556 , both assigned to Sipix Imaging, Inc.
  • Another type of electro-optic display is an electro-wetting display developed by Philips and described in an article in the September 25, 2003 issue of the Journal "Nature" and entitled "Performing Pixels: Moving Images on Electronic Paper". It is shown in copending U.S. Application Serial No. 10/711,802, filed October 6, 2004 , that such electro-wetting displays can be made bistable
  • Other types of electro-optic materials, for example, polymer-dispersed liquid crystal, may also be used in the displays of the present invention.
  • Although electrophoretic media are often opaque (since, for example, in many electrophoretic media, the particles substantially block transmission of visible light through the display) and operate in a reflective mode, many electrophoretic displays can be made to operate in a so-called "shutter mode" in which one display state is substantially opaque and one is light-transmissive. See, for example, the aforementioned U.S. Patents Nos. 6,130,774 and 6,172,798 , and U.S. Patents Nos. 5,872,552 ; 6,144,361 ; 6,271,823 ; 6,225,971 ; and 6,184,856 . Dielectrophoretic displays, which are similar to electrophoretic displays but rely upon variations in electric field strength, can operate in a similar mode; see U.S. Patent No. 4,418,346 . Other types of electro-optic displays may also be capable of operating in shutter mode.
  • An encapsulated or microcell electrophoretic display typically does not suffer from the clustering and settling failure mode of traditional electrophoretic devices and provides further advantages, such as the ability to print or coat the display on a wide variety of flexible and rigid substrates. (Use of the word "printing" is intended to include all forms of printing and coating, including, but without limitation: pre-metered coatings such as patch die coating, slot or extrusion coating, slide or cascade coating, curtain coating; roll coating such as knife over roll coating, forward and reverse roll coating; gravure coating; dip coating; spray coating; meniscus coating; spin coating; brush coating; air knife coating; silk screen printing processes; electrostatic printing processes; thermal printing processes; ink jet printing processes; electrophoretic deposition; and other similar techniques.) Thus, the resulting display can be flexible. Further, because the display medium can be printed (using a variety of methods), the display itself can be made inexpensively.
  • In addition to the layer of electro-optic material, an electro-optic display normally comprises at least two other layers disposed on opposed sides of the electro-optic material, one of these two layers being an electrode layer. In most such displays both the layers are electrode layers, and one or both of the electrode layers are patterned to define the pixels of the display. For example, one electrode layer may be patterned into elongate row electrodes and the other into elongate column electrodes running at right angles to the row electrodes, the pixels being defined by the intersections of the row and column electrodes. Alternatively, and more commonly, one electrode layer has the form of a single continuous electrode and the other electrode layer is patterned into a matrix of pixel electrodes, each of which defines one pixel of the display. In another type of electro-optic display, which is intended for use with a stylus, print head or similar movable electrode separate from the display, only one of the layers adjacent the electro-optic layer comprises an electrode, the layer on the opposed side of the electro-optic layer typically being a protective layer intended to prevent the movable electrode damaging the electro-optic layer.
  • The manufacture of a three-layer electro-optic display normally involves at least one lamination operation. For example, in several of the aforementioned MIT and E Ink patents and applications, there is described a process for manufacturing an encapsulated electrophoretic display in which an encapsulated electrophoretic medium comprising capsules in a binder is coated on to a flexible substrate comprising indium-tin-oxide or a similar conductive coating (which acts as an one electrode of the final display) on a plastic film, the capsules/binder coating being dried to form a coherent layer of the electrophoretic medium firmly adhered to the substrate. Separately, a backplane, containing an array of pixel electrodes and an appropriate arrangement of conductors to connect the pixel electrodes to drive circuitry, is prepared. To form the final display, the substrate having the capsule/binder layer thereon is laminated to the backplane using a lamination adhesive. (A very similar process can be used to prepare an electrophoretic display useable with a stylus or similar movable electrode by replacing the backplane with a simple protective layer, such as a plastic film, over which the stylus or other movable electrode can slide.) In one preferred form of such a process, the backplane is itself flexible and is prepared by printing the pixel electrodes and conductors on a plastic film or other flexible substrate. The obvious lamination technique for mass production of displays by this process is roll lamination using a lamination adhesive. Similar manufacturing techniques can be used with other types of electro-optic displays. For example, a microcell electrophoretic medium or a rotating bichromal member medium may be laminated to a backplane in substantially the same manner as an encapsulated electrophoretic medium.
  • In the processes described above, the lamination of the substrate carrying the electro-optic layer to the backplane may advantageously be carried out by vacuum lamination. Vacuum lamination is effective in expelling air from between the two materials being laminated, thus avoiding unwanted air bubbles in the final display; such air bubbles may introduce undesirable artifacts in the images produced on the display. However, vacuum lamination of the two parts of an electro-optic display in this manner imposes stringent requirements upon the lamination adhesive used, especially in the case of a display using an encapsulated electrophoretic medium. The lamination adhesive must have sufficient adhesive strength to bind the electro-optic layer to the layer (typically an electrode layer) to which it is to be laminated, and in the case of an encapsulated electrophoretic medium, the adhesive must also have sufficient adhesive strength to mechanically hold the capsules together. If the electro-optic display is to be of a flexible type (and one of the important advantages of rotating bichromal member and encapsulated electrophoretic displays is that they can be made flexible), the adhesive must have sufficient flexibility not to introduce defects into the display when the display is flexed. The lamination adhesive must have adequate flow properties at the lamination temperature to ensure high quality lamination, and in this regard, the demands of laminating encapsulated electrophoretic and some other types of electro-optic media are unusually difficult; the lamination has be conducted at a temperature of not more than about 110°C since the medium cannot be exposed to substantially higher temperatures without damage, but the flow of the adhesive must cope with the relatively uneven surface of the capsule-containing layer, the surface of which is rendered irregular by the underlying capsules. The lamination temperature should indeed be kept as low as possible, and room temperature lamination would be ideal, but no commercial adhesive has been found which permits such room temperature lamination. The lamination adhesive must be chemically compatible with all the other materials in the display. Solvent-based lamination adhesives should be avoided; it has been found (although this does not appear to have been described in the literature), that any solvent left behind in the adhesive after lamination has a strong tendency to introduce undesirable contaminants into the electro-optic medium.
  • As discussed in detail in the aforementioned U.S. Patent No. 6,831,769 , a lamination adhesive used in an electro-optic display must meet certain electrical criteria, and this introduces considerable problems in the selection of the lamination adhesive. Commercial manufacturers of lamination adhesives naturally devote considerable effort to ensuring that properties, such as strength of adhesion and lamination temperatures, of such adhesives are adjusted so that the adhesives perform well in their major applications, which typically involve laminating polymeric and similar films. However, in such applications, the electrical properties of the lamination adhesive are not relevant, and consequently the commercial manufacturers pay no heed to such electrical properties. Indeed, E Ink researchers have observed substantial variations (of up to several fold) in certain electrical properties between different batches of the same commercial lamination adhesive, presumably because the manufacturer was attempting to optimize non-electrical properties of the lamination adhesive (for example, resistance to bacterial growth) and was not at all concerned about resulting changes in electrical properties.
  • However, in electro-optic displays, in which the lamination adhesive is normally located between the electrodes which apply the electric field needed to change the electrical state of the electro-optic medium, the electrical properties of the adhesive become crucial. As will be apparent to electrical engineers, the volume resistivity of the lamination adhesive becomes important, since the voltage drop across the electro-optic medium is essentially equal to the voltage drop across the electrodes, minus the voltage drop across the lamination adhesive. If the resistivity of the adhesive layer is too high, a substantial voltage drop will occur within the adhesive layer, requiring an increase in voltage across the electrodes. Increasing the voltage across the electrodes in this manner is undesirable, since it increases the power consumption of the display, and may require the use of more complex and expensive control circuitry to handle the increased voltage involved. On the other hand, if the adhesive layer, which extends continuously across the display, is in contact with a matrix of electrodes, as in an active matrix display, the volume resistivity of the adhesive layer should not be too low, or lateral conduction of electric current through the continuous adhesive layer may cause undesirable crosstalk between adjacent electrodes.
  • In practice, a lamination adhesive layer having a uniform thickness of 10-50 µm and a conductivity of the order of 10-10 to 10-9 S/cm has been used in electro-optic displays. This conductivity range was chosen based upon electrical models for display performance, the known conductivities of various electro-optic materials and the pixel sizes typically used in such displays. This target conductivity range actually represents a compromise. More conductive lamination adhesives are desirable because higher conductivity means the electro-optic material layer sees a larger voltage gradient. However, as the conductivity of the lamination adhesive is increased at constant pixel resolution and storage capacitance, charge supplied to a pixel is leaked to neighboring pixels; this decreases the voltage gradient across the ink and counteracts the effect of increasing the lamination adhesive conductivity. In addition, as already mentioned this lateral charge leakage may cause a change in the optical state of neighboring pixels. It is desirable that the lamination adhesive be designed to provide good lateral voltage holding capability and that the gradient in voltage across the ink layer be maximized; therefore, development performance requirements for high resolution (100 to 200 lines per inch, 4 to 8 lines per mm) active-matrix displays require that isotropically conductive adhesives have conductivities in the range specified above.
  • There is another problem associated with the use of adhesives in electro-optic displays, namely pixel "blooming", that is to say the tendency for a pixel electrode to cause a change in the display state of the electro-optic medium over an area larger than that occupied by the pixel electrode itself. This blooming effect is illustrated schematically in Figure 1A of the accompanying drawings, which shows the equipotential lines caused by application of driving voltage to two adjacent pixel electrodes of an electro-optic display. As will be seen from Figure 1A, the equipotential lines spread outwardly as distance from the pixel electrode increases, and since the area within which a driving voltage applied to a pixel electrode causes a change in the display state of the electro-optic medium follows the equipotential lines, if (say) pixel 1, the left-hand pixel is Figure 1A has applied thereto a driving voltage which turns the electro-optic medium to its black display state (as seen by an observer viewing the medium from above in Figure 1A), the resultant black area, designated D1, is substantially larger than pixel 1 itself. Similarly, if pixel 2, the right-hand pixel is Figure 1A has applied thereto a driving voltage which turns the electro-optic medium to its black display state, the resultant black area, designated D2, is substantially larger than pixel 2 itself. A central area between pixels 1 and 2 will turn black whenever the driving voltage is applied to either pixel 1 or pixel 2. Such pixel blooming is undesirable, since it adversely affects the quality of the displayed image.
  • Pixel blooming can be reduced by reducing the thickness of the adhesive layer, but an adhesive layer which is too thin may give rise to other problems. For example, an adhesive layer which is deposited over a layer of capsules forming an encapsulated electrophoretic medium may serve not only to laminate the capsules to a backplane, but also to planarize the uneven surface of the layer of capsules. An adhesive layer which is too thin may fail to provide sufficient adhesion and may also fail to planarize the capsule layer. Hence, it is not desirable to reduce the thickness of the adhesive layer too far, and the thickness chosen may be a compromise between that needed to reduce pixel blooming and that required for planarization and good adhesion.
  • The aforementioned 2004/0252360 describes an electro-optic display using an anisotropic lamination adhesive having a higher electrical conductivity in a direction perpendicular to the layer of lamination adhesive than in the plane of this layer. One aspect of the present invention relates to an alternative modification of an adhesive layer which provides advantages similar to those provided by the use of an anisotropic lamination adhesive without requiring the formation of such an adhesive. This aspect of the present invention also reduces pixel blooming.
  • Although blooming has been described above as a problem in electro-optic displays, there are certain circumstances in which a controlled amount of blooming may actually be useful.
  • This invention provides an electro-optic display comprising a backplane having a plurality of pixel electrodes; an adhesive layer disposed adjacent the backplane; and a solid layer of an electro-optic medium adjacent the adhesive layer on the opposed side thereof from the backplane. The adhesive layer comprises a plurality of pixel regions disposed adjacent the pixel electrodes of the backplane and formed of a first adhesive material, and at least one inter-pixel region disposed adjacent to a gap between neighbouring pixel electrodes of the backplane and formed in part of a second material, which second material can be adhesive or non-adhesive, the second material having at least one of a lower dielectric constant and a higher volume resistivity than the first adhesive material.
  • For convenience, the backplane of the electro-optic display may hereinafter be called the "ribbed backplane" of the invention. In a preferred form of the display, the part of the inter-pixel region formed of the second material has the form of a rib. The second material may have a dielectric constant less than about 3, and/or volume resistivity greater than about 1012 ohm cm. The rib may have an aspect ratio (the height of the rib divided by its width) of at least about 0.5, desirably at least about 1.0 and preferably at least about 2.0. The rib or ribs may not extend completely through the adhesive layer so that the end of the or each rib remote from the backplane is covered by adhesive material.
  • The electro-optic display of the invention may make use of any of the types of bistable electro-optic media discussed above. Thus, for example, the display may comprise an electrophoretic electro-optic medium comprising a plurality of electrically charged particles in a suspending fluid and capable of moving through the suspending fluid on application of an electric field to the suspending fluid. The suspending fluid may be gaseous or liquid. The electrophoretic medium may be encapsulated, i.e., the charged particles and the suspending fluid may be confined within a plurality of capsules or microcells. The first method may also be used with a display comprising a rotating bichromal member or electrochromic medium.
  • As already mentioned, Figure 1A of the accompanying drawings illustrates the equipotential lines produced when a driving voltage is applied to two adjacent pixels of a prior art electro-optic display.
  • Figure 1B is a view similar to that of Figure 1A but showing the equipotential lines produced when a driving voltage is applied to two adjacent pixels of an electro-optic display of the present invention incorporating a ribbed backplane.
  • Figure 2 is a schematic side elevation of a small section of an encapsulated electrophoretic display of the present invention incorporating a ribbed backplane.
  • As already mentioned, this invention provides an electro-optic display comprising a backplane having a plurality of pixel electrodes, an adhesive layer disposed adjacent the backplane, and a layer of a solid electro-optic medium adjacent the adhesive layer on the opposed side thereof from the backplane. The adhesive layer comprises a plurality of pixel regions disposed adjacent the pixel electrodes of the backplane, and at least one inter-pixel region disposed adjacent to a gap between two neighbouring pixels of the backplane. A part of the at least one inter-pixel region has at least one of a lower dielectric constant and a higher volume resistivity than the pixel regions of the adhesive layer.
  • In theory, the lower dielectric constant and/or higher volume resistivity of the inter-pixel region of the adhesive layer could be produced by treatment of an originally essentially homogeneous adhesive layer. For example, the adhesive layer could be radiation cured in an imagewise manner to produce inter-pixel regions having higher volume resistivity than the pixel regions of the adhesive layer. However, at present it is preferred that the inter-pixel regions be formed by bodies (ribs) which are separate from the remainder of the adhesive layer. The ribs preferably have a very low dielectric constant (typically less than k=3) and are very good insulators (volume resistivity desirably greater than 1012 ohm. cm). The aspect ratio (height/width) of the ribs is desirably greater than about 0.5, preferably greater than about 1.0, and most desirably greater than about 2.0. Typically, the ribs will have a width of the order of 1-20 µm. Examples of commercially available low-k dielectric material include Nanoglass (Registered Trade Mark) E with k=2.2 (Honeywell Corporation, Sunnyvale California, United States of America), Black Diamond with k=3 (Applied Materials, Santa Clara, California, United States of America), nanoporous silica aerogels with 1.1<k<2.5 (Nanopore Inc., Albuquerque, New Mexico, United States of America), or other such materials known to those skilled in the art. The ribs may have a variety of cross sections, including square, rectangular, trapezoidal, half-round, etc., depending on the process used to form them and the specific display in which they are used. The ribs may be manufactured using photolithographic methods, printing techniques, or other processes known to those skilled in the art. Depending upon the size of the pixels involved, it may also be possible to fabricate a set of ribs for a backplane as a separate object (for example, by punching, die cutting or molding a web of material and then cutting the web to produce sets of ribs for individual displays) and then laminating or adhering the set of ribs to the backplane.
  • As shown in Figure 1B, the ribs (or other inter-pixel regions) function by reducing the tendency for the equipotential lines to spread out into a blooming pattern. More specifically, the ribs prevent the blooming of the equipotential lines within that portion of the thickness of the adhesive layer lying between the backplane and the upper edges (as illustrated in Figure 1B) of the ribs, so that overall the blooming of the pixels is reduced and the areas D3 and D4 produced by pixels 3 and 4 are smaller that the corresponding areas D1 and D2 shown in Figure 1A. Also, of course, the overlap between areas D3 and D4 is substantially smaller than that between D1 and D2.
  • Figure 2 is a schematic side elevation of a small section of an encapsulated electrophoretic display of the present invention incorporating a ribbed backplane. This display (generally designated 200) comprises a backplane 202 having pixel electrodes 204 and 206, an adhesive layer 208, an encapsulated electrophoretic layer 210, a common front electrode 212 and a transparent front substrate 214, which forms a viewing surface through which an observer views the display 200.
  • In accordance with the present invention, the display 200 further comprises ribs 216, only one of which is shown in Figure 2. The ribs 216 are of rectangular cross-section and do not extend completely though the thickness of the adhesive layer 208, so that they do not contact the capsules of the electrophoretic layer 210 being separated therefrom by part of the thickness of the adhesive layer 208. For example, if the adhesive layer is approximately 15 µm thick, the ribs 216 may be approximately 6 µm tall, thus reducing field spreading and blooming to that observed with a 9 µm adhesive layer.
  • The use of ribs in accordance with the present invention allows the use of a thicker or more conductive adhesive layer that would otherwise be possible without sacrificing resolution through blooming effects. The more conductive adhesive reduces the voltage drop within the adhesive layer, thus increasing the voltage drop across the electro-optic medium itself, and thus increasing the switching speed of the medium.
  • The ribbed backplanes of the present invention may be especially useful in high resolution displays in which the individual pixels are small, since blooming is largely a function of the thickness of the layers lying between the electrodes, and since it is not normally possible to reduce the thickness of these layers as the size of the pixels is reduced, blooming becomes a greater problem with smaller pixels, in the sense that the area affected by blooming becomes larger relative to the size of the individual pixels. Blooming is a particular problem in high resolution color displays. where pixels of differing colors lie closely adjacent each other. Consider for example a red/green/blue color display in which the pixels are arranged in rows of the same color, so that, for example, a red pixel is flanked by blue and green pixels in adjacent rows. If it is desired to display pure red, the red pixels are set to display red while the green and blue pixels are set to display black. If blooming occurs at the red pixel, part of the adjacent green and blue pixels will display green and blue respectively, thus rendering the desired red color less saturated. The smaller the pixels of such a display, the greater is the effect of a given amount of blooming.
  • For these reasons, ribbed backplanes may be especially useful in color displays. Such color displays may be of any of the types of electro-optic displays known in the art, and in particular may be of any of the types described in the aforementioned 2004/0263947. The displays described in this published application include:
    1. (a) A display comprising: a full-color pixel comprising a first addressable sub-pixel and a second sub-pixel independently addressable from the first sub-pixel, wherein each of the first sub-pixel and the second sub-pixel comprises electrophoretic particles and is capable of displaying three or more colors selected from the group consisting of white, black, red, green, blue, cyan, magenta and yellow when addressed (see especially Figure 1D and Paragraph [0087] of this published application);
    2. (b) Displays in which particles are moved laterally so as to cover or reveal a colored reflector or filter disposed on the opposed side of the particles from an observer (see especially Figures @a-2D and 3A-3E, and Paragraphs [0088] to [[0097]);
    3. (c) Displays generally similar to those mentioned in (b) above but having two different types of particles having differing colors, so that each pixel of the display can display (i) the color of the first type of particles; (ii) the color of the second type of particles; or (iii) the color of a reflector or filter disposed on the opposed side of the particles from an observer (see Figures 3F-3I, and Paragraphs [0098]-[0101]);
    4. (d) Displays generally to those mentioned in (c) above but in which a suspending fluid in which the particles are suspended is colored and the reflector or filter is omitted, so that the third colored state occurs when the color of the suspending fluid is visible to the observer (see Figure 3L of Paragraph [0103]); and
    5. (e) Displays having three different types of particles having differing colors (see Figures 3M, 5, 6A-6B, 7A-7D and 8A-8C and Paragraphs [0103] to [0113]).
  • Numerous other types of color displays can also of course be improved by use of ribbed backplanes.
  • Ribbed backplanes are also useful in preventing "creep" in flexible displays, for example displays in which the backplane (and any front substrate present) is formed from a flexible polymeric film, flexible metal foil or similar flexible material. When such displays are flexed, the adhesive layer used to secure the backplane to the electro-optic medium and other layers of the display tends to undergo fluid flow, with the result that the electro-optic medium moves slightly relative to the backplane. This can cause serious problems if, for example, the display is a color display in which a color filter array is disposed on the opposed side of the electro-optic medium from the backplane, since in such a display the various color stripes or other units of the color filter array need to aligned with the pixel electrodes or serious color distortion may occur in the displayed image. Consider for example a display in which two adjacent pixel electrodes are aligned with red and blue color filter elements. If the color filter array creeps relative to the backplane such that the pixel electrode originally aligned with the red element is now aligned with half the red element and half the blue element, it will readily be apparent that the colors of the displayed image will differ substantially from that intended.
  • By providing ribs within the adhesive layer in accordance with dependent claims 2-8 of the present invention, creep and blooming can be minimized or eliminated simultaneously.

Claims (12)

  1. An electro-optic display (200) comprising:
    a backplane (202) having a plurality of pixel electrodes (204,206);
    an adhesive layer (208) disposed adjacent the backplane (202); and
    a solid layer (210) of an electro-optic medium adjacent the adhesive layer (208) on the opposed side thereof from the backplane (202),
    wherein the adhesive layer (208) comprises a plurality of pixel regions disposed adjacent the pixel electrodes (204,206) of the backplane (202) and formed of a first adhesive material, and at least one inter-pixel region disposed adjacent to a gap between neighbouring pixel electrodes (204,206) of the backplane (202), characterized in that the inter-pixel region of the adhesive layer (208) is formed in part of a second material, which second material can be adhesive or non-adhesive, the second material having at least one of a lower dielectric constant and a higher volume resistivity than the first adhesive material.
  2. An electro-optic display (200) according to claim 1 wherein the part (216) of the inter-pixel region formed of the second material has the form of a rib (216).
  3. An electro-optic display (200) according to claim 2 wherein the second material has a dielectric constant less than 3.
  4. An electro-optic display (200) according to claim 2 wherein the second material has a volume resistivity greater than 1012 ohm cm.
  5. An electro-optic display (200) according to claim 2 wherein the at least one rib (215) has an aspect ratio of at least 0.5.
  6. An electro-optic display (200) according to claim 5 wherein the at least one rib (216) has an aspect ratio of at least 1.0.
  7. An electro-optic display (200) according to claim 6 wherein the at least one rib (216) has an aspect ratio of at least 2.0.
  8. An electro-optic display (200) according to claim 2 wherein the at least one rib (216) does not extend completely through the adhesive layer (208) so that the end of the at least one rib (216) remote from the backplane (202) is covered by the first adhesive material.
  9. An electro-optic display (200) according to claim 1 wherein the electro-optic medium comprises an electrophoretic medium comprising a plurality of electrically charged particles in a suspending fluid and capable of moving through the suspending fluid on application of an electric field to the suspending fluid.
  10. An electro-optic display (200) according to claim 9 wherein the suspending fluid is gaseous.
  11. An electro-optic display (200) according to claim 9 wherein the charged particles and the suspending fluid are confined within a plurality of capsules or microcells.
  12. An electro-optic display (200) according to claim 1 wherein the electro-optic medium comprises a rotating bichromal member or electrochromic medium.
EP05724082A 2004-02-27 2005-02-28 Electro-optic display with electro-optic layer adhered to the backplane Active EP1719108B1 (en)

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Families Citing this family (110)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7583251B2 (en) 1995-07-20 2009-09-01 E Ink Corporation Dielectrophoretic displays
US7411719B2 (en) 1995-07-20 2008-08-12 E Ink Corporation Electrophoretic medium and process for the production thereof
US7999787B2 (en) 1995-07-20 2011-08-16 E Ink Corporation Methods for driving electrophoretic displays using dielectrophoretic forces
US7848006B2 (en) 1995-07-20 2010-12-07 E Ink Corporation Electrophoretic displays with controlled amounts of pigment
US8040594B2 (en) 1997-08-28 2011-10-18 E Ink Corporation Multi-color electrophoretic displays
WO2000003291A1 (en) 1998-07-08 2000-01-20 E Ink Corporation Methods for achieving improved color in microencapsulated electrophoretic devices
US8115729B2 (en) 1999-05-03 2012-02-14 E Ink Corporation Electrophoretic display element with filler particles
AU2002250304A1 (en) 2001-03-13 2002-09-24 E Ink Corporation Apparatus for displaying drawings
US7679814B2 (en) 2001-04-02 2010-03-16 E Ink Corporation Materials for use in electrophoretic displays
US8390918B2 (en) 2001-04-02 2013-03-05 E Ink Corporation Electrophoretic displays with controlled amounts of pigment
US7535624B2 (en) 2001-07-09 2009-05-19 E Ink Corporation Electro-optic display and materials for use therein
US8558783B2 (en) * 2001-11-20 2013-10-15 E Ink Corporation Electro-optic displays with reduced remnant voltage
US9530363B2 (en) 2001-11-20 2016-12-27 E Ink Corporation Methods and apparatus for driving electro-optic displays
US8125501B2 (en) 2001-11-20 2012-02-28 E Ink Corporation Voltage modulated driver circuits for electro-optic displays
US7952557B2 (en) 2001-11-20 2011-05-31 E Ink Corporation Methods and apparatus for driving electro-optic displays
US8593396B2 (en) 2001-11-20 2013-11-26 E Ink Corporation Methods and apparatus for driving electro-optic displays
US7223672B2 (en) 2002-04-24 2007-05-29 E Ink Corporation Processes for forming backplanes for electro-optic displays
US8363299B2 (en) 2002-06-10 2013-01-29 E Ink Corporation Electro-optic displays, and processes for the production thereof
US8049947B2 (en) 2002-06-10 2011-11-01 E Ink Corporation Components and methods for use in electro-optic displays
US7649674B2 (en) 2002-06-10 2010-01-19 E Ink Corporation Electro-optic display with edge seal
US7843621B2 (en) 2002-06-10 2010-11-30 E Ink Corporation Components and testing methods for use in the production of electro-optic displays
US20080024482A1 (en) 2002-06-13 2008-01-31 E Ink Corporation Methods for driving electro-optic displays
US7839564B2 (en) 2002-09-03 2010-11-23 E Ink Corporation Components and methods for use in electro-optic displays
EP3056941B1 (en) 2002-09-03 2019-01-09 E Ink Corporation Electro-phoretic medium
US20130063333A1 (en) 2002-10-16 2013-03-14 E Ink Corporation Electrophoretic displays
US7910175B2 (en) 2003-03-25 2011-03-22 E Ink Corporation Processes for the production of electrophoretic displays
US10726798B2 (en) 2003-03-31 2020-07-28 E Ink Corporation Methods for operating electro-optic displays
US8174490B2 (en) 2003-06-30 2012-05-08 E Ink Corporation Methods for driving electrophoretic displays
US7672040B2 (en) 2003-11-05 2010-03-02 E Ink Corporation Electro-optic displays, and materials for use therein
US8177942B2 (en) 2003-11-05 2012-05-15 E Ink Corporation Electro-optic displays, and materials for use therein
US20110164301A1 (en) 2003-11-05 2011-07-07 E Ink Corporation Electro-optic displays, and materials for use therein
US11250794B2 (en) 2004-07-27 2022-02-15 E Ink Corporation Methods for driving electrophoretic displays using dielectrophoretic forces
US20080136774A1 (en) 2004-07-27 2008-06-12 E Ink Corporation Methods for driving electrophoretic displays using dielectrophoretic forces
US7230751B2 (en) * 2005-01-26 2007-06-12 E Ink Corporation Electrophoretic displays using gaseous fluids
WO2007002452A2 (en) 2005-06-23 2007-01-04 E Ink Corporation Edge seals and processes for electro-optic displays
KR20080015507A (en) 2005-10-18 2008-02-19 이 잉크 코포레이션 Components for electro-optic displays
US20080043318A1 (en) 2005-10-18 2008-02-21 E Ink Corporation Color electro-optic displays, and processes for the production thereof
TWI350793B (en) 2006-03-08 2011-10-21 E Ink Corp Methods for production of electro-optic displays
US8390301B2 (en) 2006-03-08 2013-03-05 E Ink Corporation Electro-optic displays, and materials and methods for production thereof
US7843624B2 (en) 2006-03-08 2010-11-30 E Ink Corporation Electro-optic displays, and materials and methods for production thereof
US8610988B2 (en) 2006-03-09 2013-12-17 E Ink Corporation Electro-optic display with edge seal
US7952790B2 (en) 2006-03-22 2011-05-31 E Ink Corporation Electro-optic media produced using ink jet printing
US7903319B2 (en) 2006-07-11 2011-03-08 E Ink Corporation Electrophoretic medium and display with improved image stability
US8018640B2 (en) 2006-07-13 2011-09-13 E Ink Corporation Particles for use in electrophoretic displays
US7986450B2 (en) 2006-09-22 2011-07-26 E Ink Corporation Electro-optic display and materials for use therein
US7477444B2 (en) 2006-09-22 2009-01-13 E Ink Corporation & Air Products And Chemical, Inc. Electro-optic display and materials for use therein
US7649666B2 (en) 2006-12-07 2010-01-19 E Ink Corporation Components and methods for use in electro-optic displays
EP2111562B1 (en) 2007-01-22 2018-09-19 E Ink Corporation Multi-layer sheet for use in electro-optic displays
US7688497B2 (en) * 2007-01-22 2010-03-30 E Ink Corporation Multi-layer sheet for use in electro-optic displays
US7826129B2 (en) 2007-03-06 2010-11-02 E Ink Corporation Materials for use in electrophoretic displays
CN101681211A (en) 2007-05-21 2010-03-24 伊英克公司 Methods for driving video electro-optic displays
US9199441B2 (en) 2007-06-28 2015-12-01 E Ink Corporation Processes for the production of electro-optic displays, and color filters for use therein
WO2009006248A1 (en) 2007-06-29 2009-01-08 E Ink Corporation Electro-optic displays, and materials and methods for production thereof
US8902153B2 (en) 2007-08-03 2014-12-02 E Ink Corporation Electro-optic displays, and processes for their production
JP5096072B2 (en) * 2007-08-21 2012-12-12 株式会社リコー Image display device
US20090122389A1 (en) 2007-11-14 2009-05-14 E Ink Corporation Electro-optic assemblies, and adhesives and binders for use therein
KR101237263B1 (en) 2008-03-21 2013-02-27 이 잉크 코포레이션 Electro-optic displays and color filters
CN102067200B (en) 2008-04-11 2013-11-13 伊英克公司 Methods for driving electro-optic displays
JP2010102293A (en) * 2008-09-26 2010-05-06 Toppan Printing Co Ltd Microcapsule-type electrophoretic display panel and method of manufacturing the same
US8234507B2 (en) 2009-01-13 2012-07-31 Metrologic Instruments, Inc. Electronic-ink display device employing a power switching mechanism automatically responsive to predefined states of device configuration
US8457013B2 (en) 2009-01-13 2013-06-04 Metrologic Instruments, Inc. Wireless dual-function network device dynamically switching and reconfiguring from a wireless network router state of operation into a wireless network coordinator state of operation in a wireless communication network
TWI484273B (en) 2009-02-09 2015-05-11 E Ink Corp Electrophoretic particles
US8098418B2 (en) 2009-03-03 2012-01-17 E. Ink Corporation Electro-optic displays, and color filters for use therein
CN105808008A (en) 2009-10-28 2016-07-27 伊英克公司 Electro-optic displays with touch sensors
US8654436B1 (en) 2009-10-30 2014-02-18 E Ink Corporation Particles for use in electrophoretic displays
JP5449617B2 (en) 2010-04-02 2014-03-19 イー インク コーポレイション Electrophoresis medium
TWI575487B (en) 2010-04-09 2017-03-21 電子墨水股份有限公司 Methods for driving electro-optic displays
TWI484275B (en) 2010-05-21 2015-05-11 E Ink Corp Electro-optic display, method for driving the same and microcavity electrophoretic display
KR20140015248A (en) * 2010-08-09 2014-02-06 휴렛-팩커드 디벨롭먼트 컴퍼니, 엘.피. System and method for tri-state electro-optical displays
JP5741122B2 (en) * 2011-03-28 2015-07-01 ソニー株式会社 Electrophoretic element, display device and electronic device
US20130125910A1 (en) 2011-11-18 2013-05-23 Avon Products, Inc. Use of Electrophoretic Microcapsules in a Cosmetic Composition
CN102654710B (en) * 2011-11-23 2014-12-17 京东方科技集团股份有限公司 Electronic paper display device and manufacturing method thereof
WO2013159093A1 (en) 2012-04-20 2013-10-24 E Ink Corporation Illumination systems for reflective displays
US11467466B2 (en) 2012-04-20 2022-10-11 E Ink Corporation Illumination systems for reflective displays
JP5500329B1 (en) * 2012-08-22 2014-05-21 凸版印刷株式会社 Electrophoretic display substrate, inspection method thereof, and electrophoretic display device
US9726957B2 (en) 2013-01-10 2017-08-08 E Ink Corporation Electro-optic display with controlled electrochemical reactions
US9715155B1 (en) 2013-01-10 2017-07-25 E Ink Corporation Electrode structures for electro-optic displays
CN109491173B (en) * 2014-01-17 2022-07-12 伊英克公司 Electro-optic display with dual phase electrode layers
US10317767B2 (en) 2014-02-07 2019-06-11 E Ink Corporation Electro-optic display backplane structure with drive components and pixel electrodes on opposed surfaces
KR20160119195A (en) 2014-02-07 2016-10-12 이 잉크 코포레이션 Electro-optic display backplane structures
US10446585B2 (en) * 2014-03-17 2019-10-15 E Ink Corporation Multi-layer expanding electrode structures for backplane assemblies
WO2016073914A1 (en) 2014-11-07 2016-05-12 E Ink Corporation Applications of electro-optic displays
US9835925B1 (en) 2015-01-08 2017-12-05 E Ink Corporation Electro-optic displays, and processes for the production thereof
US10997930B2 (en) 2015-05-27 2021-05-04 E Ink Corporation Methods and circuitry for driving display devices
JP6524271B2 (en) 2015-06-29 2019-06-05 イー インク コーポレイション Method for mechanical and electrical connection to display electrodes
WO2017210069A1 (en) 2016-05-31 2017-12-07 E Ink Corporation Backplanes for electro-optic displays
WO2018160546A1 (en) 2017-02-28 2018-09-07 E Ink Corporation Writeable electrophoretic displays including sensing circuits and styli configured to interact with sensing circuits
CN110383165B (en) 2017-03-28 2023-05-02 伊英克公司 Permeable back sheet for electro-optic displays
CN110622102B (en) 2017-05-19 2021-04-13 伊英克公司 Foldable electro-optic display including digitization and touch sensing
US10573257B2 (en) 2017-05-30 2020-02-25 E Ink Corporation Electro-optic displays
US11404013B2 (en) 2017-05-30 2022-08-02 E Ink Corporation Electro-optic displays with resistors for discharging remnant charges
EP3697535B1 (en) 2017-10-18 2023-04-26 Nuclera Nucleics Ltd Digital microfluidic devices including dual substrates with thin-film transistors and capacitive sensing
US10824042B1 (en) 2017-10-27 2020-11-03 E Ink Corporation Electro-optic display and composite materials having low thermal sensitivity for use therein
ES2931049T3 (en) 2017-11-03 2022-12-23 E Ink Corp Production processes of electro-optical display devices
EP3752883A4 (en) 2018-02-15 2021-11-10 E Ink Corporation Via placement for slim border electro-optic display backplanes with decreased capacitive coupling between t-wires and pixel electrodes
US11175561B1 (en) 2018-04-12 2021-11-16 E Ink Corporation Electrophoretic display media with network electrodes and methods of making and using the same
CN109143718A (en) * 2018-08-08 2019-01-04 广州奥翼电子科技股份有限公司 A kind of high definition electrophoresis type display
US11353759B2 (en) 2018-09-17 2022-06-07 Nuclera Nucleics Ltd. Backplanes with hexagonal and triangular electrodes
US11511096B2 (en) 2018-10-15 2022-11-29 E Ink Corporation Digital microfluidic delivery device
WO2020097462A1 (en) 2018-11-09 2020-05-14 E Ink Corporation Electro-optic displays
EP3894934A4 (en) 2018-12-13 2022-07-20 E Ink Corporation Illumination systems for reflective displays
TWI728631B (en) 2018-12-28 2021-05-21 美商電子墨水股份有限公司 Electro-optic displays
TWI734327B (en) 2018-12-30 2021-07-21 美商伊英克加利福尼亞有限責任公司 Method for driving an electro-optic display
KR20220112833A (en) 2020-02-07 2022-08-11 이 잉크 코포레이션 Electrophoretic display layer with thin film top electrode
WO2021247470A1 (en) 2020-06-03 2021-12-09 E Ink Corporation Foldable electrophoretic display module including non-conductive support plate
AU2022283264A1 (en) 2021-05-25 2023-10-12 E Ink Corporation Synchronized driving waveforms for four-particle electrophoretic displays
US11935495B2 (en) 2021-08-18 2024-03-19 E Ink Corporation Methods for driving electro-optic displays
TW202349091A (en) 2022-02-25 2023-12-16 美商電子墨水股份有限公司 Electro-optic displays with edge seal components and methods of making the same
US11830449B2 (en) 2022-03-01 2023-11-28 E Ink Corporation Electro-optic displays
WO2023211699A1 (en) 2022-04-27 2023-11-02 E Ink Corporation Electro-optic display stacks with segmented electrodes and methods of making the same

Family Cites Families (148)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2800457A (en) 1953-06-30 1957-07-23 Ncr Co Oil-containing microscopic capsules and method of making them
NL7005615A (en) 1969-04-23 1970-10-27
US3870517A (en) * 1969-10-18 1975-03-11 Matsushita Electric Ind Co Ltd Color image reproduction sheet employed in photoelectrophoretic imaging
US3668106A (en) * 1970-04-09 1972-06-06 Matsushita Electric Ind Co Ltd Electrophoretic display device
US3767392A (en) 1970-04-15 1973-10-23 Matsushita Electric Ind Co Ltd Electrophoretic light image reproduction process
US3792308A (en) * 1970-06-08 1974-02-12 Matsushita Electric Ind Co Ltd Electrophoretic display device of the luminescent type
JPS4917079B1 (en) 1970-12-21 1974-04-26
US4273672A (en) * 1971-08-23 1981-06-16 Champion International Corporation Microencapsulation process
US4001140A (en) * 1974-07-10 1977-01-04 Ncr Corporation Capsule manufacture
US4418346A (en) 1981-05-20 1983-11-29 Batchelder J Samuel Method and apparatus for providing a dielectrophoretic display of visual information
US4650288A (en) * 1983-07-07 1987-03-17 North American Philips Corporation Electrically conductive materials for devices
US4640583A (en) * 1983-07-22 1987-02-03 Kabushiki Kaisha Seiko Epson Display panel having an inner and an outer seal and process for the production thereof
US4742345A (en) * 1985-11-19 1988-05-03 Copytele, Inc. Electrophoretic display panel apparatus and methods therefor
US4690749A (en) 1985-12-16 1987-09-01 Universities Space Research Association Polymer-coated surfaces to control surface zeta potential
US4892607A (en) * 1986-12-04 1990-01-09 Copytele, Inc. Chip mounting techniques for display apparatus
US5502889A (en) 1988-06-10 1996-04-02 Sheldahl, Inc. Method for electrically and mechanically connecting at least two conductive layers
DE69034082T2 (en) * 1989-03-16 2004-04-01 Dai Nippon Printing Co., Ltd. Manufacturing and reproduction processes for filters, and processes for manufacturing photographic filter materials
US5302235A (en) 1989-05-01 1994-04-12 Copytele, Inc. Dual anode flat panel electrophoretic display apparatus
US5128226A (en) 1989-11-13 1992-07-07 Eastman Kodak Company Electrophotographic element containing barrier layer
FI91573C (en) * 1990-01-04 1994-07-11 Neste Oy Method for manufacturing electronic and electro-optical components and circuits
US5250938A (en) 1990-12-19 1993-10-05 Copytele, Inc. Electrophoretic display panel having enhanced operation
US5298833A (en) * 1992-06-22 1994-03-29 Copytele, Inc. Black electrophoretic particles for an electrophoretic image display
CA2162874A1 (en) 1993-05-21 1994-12-08 Wei-Hsin Hou Methods of preparing electrophoretic dispersions containing two types of particles with different colors and opposite charges
US5380362A (en) * 1993-07-16 1995-01-10 Copytele, Inc. Suspension for use in electrophoretic image display systems
US5411656A (en) * 1993-08-12 1995-05-02 Copytele, Inc. Gas absorption additives for electrophoretic suspensions
WO1995007527A1 (en) * 1993-09-09 1995-03-16 Copytele, Inc. Electrophoretic display panel with selective character addressability
US5403518A (en) * 1993-12-02 1995-04-04 Copytele, Inc. Formulations for improved electrophoretic display suspensions and related methods
US5699097A (en) 1994-04-22 1997-12-16 Kabushiki Kaisha Toshiba Display medium and method for display therewith
EP0760872A4 (en) 1994-05-26 1997-12-10 Copytele Inc Fluorinated dielectric suspensions for electrophoretic image displays and related methods
EP0767964B1 (en) * 1994-06-29 1998-10-21 Robert Bosch Gmbh Anisotropically conducting adhesive and process for its production
GB2292119B (en) 1994-08-10 1998-12-30 Chemitech Inc A process for producing a magnetic display sheet using microcapsules
US5745094A (en) * 1994-12-28 1998-04-28 International Business Machines Corporation Electrophoretic display
US6137467A (en) 1995-01-03 2000-10-24 Xerox Corporation Optically sensitive electric paper
US6710540B1 (en) * 1995-07-20 2004-03-23 E Ink Corporation Electrostatically-addressable electrophoretic display
US7079305B2 (en) * 2001-03-19 2006-07-18 E Ink Corporation Electrophoretic medium and process for the production thereof
US6262706B1 (en) 1995-07-20 2001-07-17 E Ink Corporation Retroreflective electrophoretic displays and materials for making the same
US6866760B2 (en) * 1998-08-27 2005-03-15 E Ink Corporation Electrophoretic medium and process for the production thereof
US6017584A (en) * 1995-07-20 2000-01-25 E Ink Corporation Multi-color electrophoretic displays and materials for making the same
US6118426A (en) 1995-07-20 2000-09-12 E Ink Corporation Transducers and indicators having printed displays
US6120839A (en) 1995-07-20 2000-09-19 E Ink Corporation Electro-osmotic displays and materials for making the same
US7071913B2 (en) * 1995-07-20 2006-07-04 E Ink Corporation Retroreflective electrophoretic displays and materials for making the same
US6459418B1 (en) 1995-07-20 2002-10-01 E Ink Corporation Displays combining active and non-active inks
US6120588A (en) 1996-07-19 2000-09-19 E Ink Corporation Electronically addressable microencapsulated ink and display thereof
US7106296B1 (en) 1995-07-20 2006-09-12 E Ink Corporation Electronic book with multiple page displays
US6124851A (en) * 1995-07-20 2000-09-26 E Ink Corporation Electronic book with multiple page displays
US6727881B1 (en) * 1995-07-20 2004-04-27 E Ink Corporation Encapsulated electrophoretic displays and methods and materials for making the same
US6515649B1 (en) * 1995-07-20 2003-02-04 E Ink Corporation Suspended particle displays and materials for making the same
US5686383A (en) 1995-08-22 1997-11-11 Eastman Kodak Company Method of making a color filter array by colorant transfer and lamination
US5760761A (en) * 1995-12-15 1998-06-02 Xerox Corporation Highlight color twisting ball display
US6055091A (en) * 1996-06-27 2000-04-25 Xerox Corporation Twisting-cylinder display
US5808783A (en) 1996-06-27 1998-09-15 Xerox Corporation High reflectance gyricon display
US6538801B2 (en) * 1996-07-19 2003-03-25 E Ink Corporation Electrophoretic displays using nanoparticles
US6323989B1 (en) 1996-07-19 2001-11-27 E Ink Corporation Electrophoretic displays using nanoparticles
US6721083B2 (en) * 1996-07-19 2004-04-13 E Ink Corporation Electrophoretic displays using nanoparticles
US5930026A (en) 1996-10-25 1999-07-27 Massachusetts Institute Of Technology Nonemissive displays and piezoelectric power supplies therefor
JPH10149118A (en) * 1996-11-21 1998-06-02 Nok Corp Electrophoresis display device
US5777782A (en) 1996-12-24 1998-07-07 Xerox Corporation Auxiliary optics for a twisting ball display
WO1998035267A1 (en) 1997-02-06 1998-08-13 University College Dublin Electrochromic system
US6980196B1 (en) 1997-03-18 2005-12-27 Massachusetts Institute Of Technology Printable electronic display
US5961804A (en) 1997-03-18 1999-10-05 Massachusetts Institute Of Technology Microencapsulated electrophoretic display
US6215920B1 (en) * 1997-06-10 2001-04-10 The University Of British Columbia Electrophoretic, high index and phase transition control of total internal reflection in high efficiency variable reflectivity image displays
DE69805300T2 (en) * 1997-06-12 2003-01-23 Papyron B V SUBSTRATE WITH DIRECT CONDUCTIVITY UPRIGHT TO ITS SURFACE, DEVICES WITH SUCH A SUBSTRATE AND METHOD FOR PRODUCING SUCH A SUBSTRATE
US6252564B1 (en) 1997-08-28 2001-06-26 E Ink Corporation Tiled displays
US6825829B1 (en) * 1997-08-28 2004-11-30 E Ink Corporation Adhesive backed displays
US6300932B1 (en) 1997-08-28 2001-10-09 E Ink Corporation Electrophoretic displays with luminescent particles and materials for making the same
US6232950B1 (en) * 1997-08-28 2001-05-15 E Ink Corporation Rear electrode structures for displays
US6067185A (en) * 1997-08-28 2000-05-23 E Ink Corporation Process for creating an encapsulated electrophoretic display
US6839158B2 (en) * 1997-08-28 2005-01-04 E Ink Corporation Encapsulated electrophoretic displays having a monolayer of capsules and materials and methods for making the same
US7002728B2 (en) * 1997-08-28 2006-02-21 E Ink Corporation Electrophoretic particles, and processes for the production thereof
US6177921B1 (en) * 1997-08-28 2001-01-23 E Ink Corporation Printable electrode structures for displays
US6054071A (en) * 1998-01-28 2000-04-25 Xerox Corporation Poled electrets for gyricon-based electric-paper displays
US6704133B2 (en) * 1998-03-18 2004-03-09 E-Ink Corporation Electro-optic display overlays and systems for addressing such displays
WO1999047970A1 (en) 1998-03-18 1999-09-23 E-Ink Corporation Electrophoretic displays and systems for addressing such displays
US7075502B1 (en) * 1998-04-10 2006-07-11 E Ink Corporation Full color reflective display with multichromatic sub-pixels
DE69918308T2 (en) * 1998-04-10 2004-10-21 E Ink Corp ELECTRONIC DISPLAY BASED ON ORGANIC FIELD EFFECT TRANSISTORS
JP2002513169A (en) * 1998-04-27 2002-05-08 イー−インク コーポレイション Microencapsulated electrophoretic display in shutter mode
WO1999059101A2 (en) * 1998-05-12 1999-11-18 E-Ink Corporation Microencapsulated electrophoretic electrostatically-addressed media for drawing device applications
US6241921B1 (en) 1998-05-15 2001-06-05 Massachusetts Institute Of Technology Heterogeneous display elements and methods for their fabrication
US6136128A (en) 1998-06-23 2000-10-24 Amerasia International Technology, Inc. Method of making an adhesive preform lid for electronic devices
US6428650B1 (en) 1998-06-23 2002-08-06 Amerasia International Technology, Inc. Cover for an optical device and method for making same
EP1095354B1 (en) * 1998-07-08 2002-11-27 E Ink Corporation Method and apparatus for sensing the state of an electrophoretic display
US20030102858A1 (en) * 1998-07-08 2003-06-05 E Ink Corporation Method and apparatus for determining properties of an electrophoretic display
USD485294S1 (en) * 1998-07-22 2004-01-13 E Ink Corporation Electrode structure for an electronic display
US7256766B2 (en) * 1998-08-27 2007-08-14 E Ink Corporation Electrophoretic display comprising optical biasing element
US6271823B1 (en) 1998-09-16 2001-08-07 International Business Machines Corporation Reflective electrophoretic display with laterally adjacent color cells using a reflective panel
US6184856B1 (en) * 1998-09-16 2001-02-06 International Business Machines Corporation Transmissive electrophoretic display with laterally adjacent color cells
US6144361A (en) 1998-09-16 2000-11-07 International Business Machines Corporation Transmissive electrophoretic display with vertical electrodes
US6225971B1 (en) * 1998-09-16 2001-05-01 International Business Machines Corporation Reflective electrophoretic display with laterally adjacent color cells using an absorbing panel
US6262833B1 (en) 1998-10-07 2001-07-17 E Ink Corporation Capsules for electrophoretic displays and methods for making the same
EP1118039B1 (en) * 1998-10-07 2003-02-05 E Ink Corporation Illumination system for nonemissive electronic displays
US6128124A (en) 1998-10-16 2000-10-03 Xerox Corporation Additive color electric paper without registration or alignment of individual elements
US6147791A (en) 1998-11-25 2000-11-14 Xerox Corporation Gyricon displays utilizing rotating elements and magnetic latching
US6097531A (en) 1998-11-25 2000-08-01 Xerox Corporation Method of making uniformly magnetized elements for a gyricon display
US6312304B1 (en) 1998-12-15 2001-11-06 E Ink Corporation Assembly of microencapsulated electronic displays
US6506438B2 (en) * 1998-12-15 2003-01-14 E Ink Corporation Method for printing of transistor arrays on plastic substrates
US6724519B1 (en) * 1998-12-21 2004-04-20 E-Ink Corporation Protective electrodes for electrophoretic displays
JP4582914B2 (en) * 1999-04-06 2010-11-17 イー インク コーポレイション Method for making droplets for use in capsule-based electromotive displays
US6344155B1 (en) * 1999-04-06 2002-02-05 Tomoegawa Paper Co., Ltd. Electrically conductive adhesive composition, electrically conductive adhesive sheet and use thereof
US6327072B1 (en) 1999-04-06 2001-12-04 E Ink Corporation Microcell electrophoretic displays
US6842657B1 (en) * 1999-04-09 2005-01-11 E Ink Corporation Reactive formation of dielectric layers and protection of organic layers in organic semiconductor device fabrication
US6498114B1 (en) 1999-04-09 2002-12-24 E Ink Corporation Method for forming a patterned semiconductor film
US7012600B2 (en) * 1999-04-30 2006-03-14 E Ink Corporation Methods for driving bistable electro-optic displays, and apparatus for use therein
US6531997B1 (en) * 1999-04-30 2003-03-11 E Ink Corporation Methods for addressing electrophoretic displays
US7119772B2 (en) * 1999-04-30 2006-10-10 E Ink Corporation Methods for driving bistable electro-optic displays, and apparatus for use therein
US6504524B1 (en) * 2000-03-08 2003-01-07 E Ink Corporation Addressing methods for displays having zero time-average field
US7038655B2 (en) * 1999-05-03 2006-05-02 E Ink Corporation Electrophoretic ink composed of particles with field dependent mobilities
US6693620B1 (en) * 1999-05-03 2004-02-17 E Ink Corporation Threshold addressing of electrophoretic displays
US7030412B1 (en) * 1999-05-05 2006-04-18 E Ink Corporation Minimally-patterned semiconductor devices for display applications
EP1192504B1 (en) * 1999-07-01 2011-03-16 E Ink Corporation Electrophoretic medium provided with spacers
DE60043441D1 (en) * 1999-07-21 2010-01-14 E Ink Corp PREFERRED METHOD, ELECTRIC LADDER RAILS FOR DELLEN
US6545291B1 (en) * 1999-08-31 2003-04-08 E Ink Corporation Transistor design for use in the construction of an electronically driven display
US6312971B1 (en) 1999-08-31 2001-11-06 E Ink Corporation Solvent annealing process for forming a thin semiconductor film with advantageous properties
JP3934420B2 (en) * 1999-10-11 2007-06-20 ユニバーシティ・カレッジ・ダブリン Electrochromic element
US6672921B1 (en) * 2000-03-03 2004-01-06 Sipix Imaging, Inc. Manufacturing process for electrophoretic display
CN1237623C (en) * 2000-04-18 2006-01-18 伊英克公司 Process for fabricating thin transistor
US20020060321A1 (en) * 2000-07-14 2002-05-23 Kazlas Peter T. Minimally- patterned, thin-film semiconductor devices for display applications
US6816147B2 (en) * 2000-08-17 2004-11-09 E Ink Corporation Bistable electro-optic display, and method for addressing same
AU2002230520A1 (en) * 2000-11-29 2002-06-11 E-Ink Corporation Addressing circuitry for large electronic displays
AU2002250304A1 (en) * 2001-03-13 2002-09-24 E Ink Corporation Apparatus for displaying drawings
JP4568477B2 (en) * 2001-04-02 2010-10-27 イー インク コーポレイション Electrophoretic media with improved image stability
US6870661B2 (en) * 2001-05-15 2005-03-22 E Ink Corporation Electrophoretic displays containing magnetic particles
EP1393122B1 (en) * 2001-05-15 2018-03-28 E Ink Corporation Electrophoretic particles
US7110163B2 (en) 2001-07-09 2006-09-19 E Ink Corporation Electro-optic display and lamination adhesive for use therein
WO2003007066A2 (en) * 2001-07-09 2003-01-23 E Ink Corporation Electro-optical display having a lamination adhesive layer
US6982178B2 (en) * 2002-06-10 2006-01-03 E Ink Corporation Components and methods for use in electro-optic displays
JP4027178B2 (en) * 2001-09-12 2007-12-26 キヤノン株式会社 Electrophoretic display device
WO2003027764A1 (en) * 2001-09-19 2003-04-03 Bridgestone Corporation Particles and device for displaying image
US7528822B2 (en) * 2001-11-20 2009-05-05 E Ink Corporation Methods for driving electro-optic displays
US7202847B2 (en) * 2002-06-28 2007-04-10 E Ink Corporation Voltage modulated driver circuits for electro-optic displays
US6865010B2 (en) * 2001-12-13 2005-03-08 E Ink Corporation Electrophoretic electronic displays with low-index films
JP2003186065A (en) * 2001-12-21 2003-07-03 Canon Inc Electrophoretic display device and its driving method
US6900851B2 (en) * 2002-02-08 2005-05-31 E Ink Corporation Electro-optic displays and optical systems for addressing such displays
JP4515035B2 (en) * 2002-03-14 2010-07-28 株式会社半導体エネルギー研究所 Display device and manufacturing method thereof
US6885146B2 (en) * 2002-03-14 2005-04-26 Semiconductor Energy Laboratory Co., Ltd. Display device comprising substrates, contrast medium and barrier layers between contrast medium and each of substrates
US7223672B2 (en) * 2002-04-24 2007-05-29 E Ink Corporation Processes for forming backplanes for electro-optic displays
US7190008B2 (en) * 2002-04-24 2007-03-13 E Ink Corporation Electro-optic displays, and components for use therein
US7110164B2 (en) * 2002-06-10 2006-09-19 E Ink Corporation Electro-optic displays, and processes for the production thereof
US6842279B2 (en) * 2002-06-27 2005-01-11 E Ink Corporation Illumination system for nonemissive electronic displays
US7312916B2 (en) * 2002-08-07 2007-12-25 E Ink Corporation Electrophoretic media containing specularly reflective particles
US6987603B2 (en) * 2003-01-31 2006-01-17 E Ink Corporation Construction of electrophoretic displays
JP4402358B2 (en) * 2003-03-05 2010-01-20 キヤノン株式会社 Color image display panel and driving method thereof
EP2273307B1 (en) * 2003-03-27 2012-08-22 E Ink Corporation Electrophoretic medium for an electrophoretic display
WO2004099862A2 (en) * 2003-05-02 2004-11-18 E Ink Corporation Electrophoretic displays
EP2698784B1 (en) * 2003-08-19 2017-11-01 E Ink Corporation Electro-optic display
WO2005029458A1 (en) * 2003-09-19 2005-03-31 E Ink Corporation Methods for reducing edge effects in electro-optic displays
US20050123767A1 (en) * 2003-12-08 2005-06-09 Xerox Corporation Pillow packaged for display media
US20060050028A1 (en) * 2004-04-13 2006-03-09 Pasch Nicholas F Method and apparatus for an improved micro electro-mechanical display backplane
US7359109B2 (en) * 2004-12-14 2008-04-15 Palo Alto Research Center Incorporated Rear-viewable reflective display

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HK1106055A1 (en) 2008-02-29
WO2005084280A3 (en) 2006-11-16
CN100474379C (en) 2009-04-01
CN1985295A (en) 2007-06-20
US7388572B2 (en) 2008-06-17
DE602005023274D1 (en) 2010-10-14
WO2005084280A2 (en) 2005-09-15
JP4783781B2 (en) 2011-09-28
EP1719108A2 (en) 2006-11-08
JP2007525712A (en) 2007-09-06
US20050190137A1 (en) 2005-09-01
ATE479921T1 (en) 2010-09-15
JP2011175285A (en) 2011-09-08

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