EP2239248A3 - A selective synthesis of organophosphites - Google Patents

A selective synthesis of organophosphites Download PDF

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Publication number
EP2239248A3
EP2239248A3 EP20100170520 EP10170520A EP2239248A3 EP 2239248 A3 EP2239248 A3 EP 2239248A3 EP 20100170520 EP20100170520 EP 20100170520 EP 10170520 A EP10170520 A EP 10170520A EP 2239248 A3 EP2239248 A3 EP 2239248A3
Authority
EP
European Patent Office
Prior art keywords
selective synthesis
organophosphites
separately
triorganoamine
discontinuously
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP20100170520
Other languages
German (de)
French (fr)
Other versions
EP2239248A2 (en
EP2239248B1 (en
EP2239248B2 (en
Inventor
Joachim C. Ritter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Invista Technologies Sarl
Original Assignee
Invista Technologies SARL Switzerland
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Filing date
Publication date
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Application filed by Invista Technologies SARL Switzerland filed Critical Invista Technologies SARL Switzerland
Publication of EP2239248A2 publication Critical patent/EP2239248A2/en
Publication of EP2239248A3 publication Critical patent/EP2239248A3/en
Publication of EP2239248B1 publication Critical patent/EP2239248B1/en
Application granted granted Critical
Publication of EP2239248B2 publication Critical patent/EP2239248B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/146—Esters of phosphorous acids containing P-halide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/142—Esters of phosphorous acids with hydroxyalkyl compounds without further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/145—Esters of phosphorous acids with hydroxyaryl compounds

Abstract

Disclosed herein is a process for the selective synthesis of triorganophosphite intermediates, including mono- and di-phosphites, from phosphorus trihalides, alcohols and triorganoamines where the alcohol and the triorganoamine are added either (a) separately but concurrently and continuously, (b) separately, concurrently but discontinuously, or (c) separately, discontinuously and in alternating portions of triorganoamine and alcohol.
EP10170520.0A 2002-12-02 2003-12-02 A selective synthesis of organophosphites Expired - Lifetime EP2239248B2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US43042602P 2002-12-02 2002-12-02
US10/454,043 US20040106815A1 (en) 2002-12-02 2003-06-04 Selective synthesis of organophosphites
EP03787252A EP1567468B1 (en) 2002-12-02 2003-12-02 A selective synthesis of organophosphites
PCT/US2003/038367 WO2004050588A2 (en) 2002-12-02 2003-12-02 A selective synthesis of organophosphites

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP03787252.0 Division 2003-12-02
EP03787252A Division EP1567468B1 (en) 2002-12-02 2003-12-02 A selective synthesis of organophosphites

Publications (4)

Publication Number Publication Date
EP2239248A2 EP2239248A2 (en) 2010-10-13
EP2239248A3 true EP2239248A3 (en) 2010-12-29
EP2239248B1 EP2239248B1 (en) 2015-09-23
EP2239248B2 EP2239248B2 (en) 2021-06-09

Family

ID=32397248

Family Applications (3)

Application Number Title Priority Date Filing Date
EP03787252A Expired - Lifetime EP1567468B1 (en) 2002-12-02 2003-12-02 A selective synthesis of organophosphites
EP10170520.0A Expired - Lifetime EP2239248B2 (en) 2002-12-02 2003-12-02 A selective synthesis of organophosphites
EP10170500.2A Expired - Lifetime EP2243763B2 (en) 2002-12-02 2003-12-02 A selective synthesis of organophosphites

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP03787252A Expired - Lifetime EP1567468B1 (en) 2002-12-02 2003-12-02 A selective synthesis of organophosphites

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP10170500.2A Expired - Lifetime EP2243763B2 (en) 2002-12-02 2003-12-02 A selective synthesis of organophosphites

Country Status (10)

Country Link
US (1) US20040106815A1 (en)
EP (3) EP1567468B1 (en)
JP (1) JP2006508177A (en)
AT (1) ATE501998T1 (en)
AU (1) AU2003294564A1 (en)
CA (1) CA2508337C (en)
DE (1) DE60336419D1 (en)
ES (1) ES2526971T3 (en)
HK (1) HK1085194A1 (en)
WO (1) WO2004050588A2 (en)

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FR2849027B1 (en) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates PROCESS FOR THE SYNTHESIS OF COMPOUNDS COMPRISING NITRIL FUNCTIONS FROM ETHYLENE-UNSATURATED COMPOUNDS
FR2850966B1 (en) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates PROCESS FOR PRODUCING DINITRIL COMPOUNDS
FR2854892B1 (en) * 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates PROCESS FOR PRODUCING DINITRILES
FR2854891B1 (en) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates PROCESS FOR PREPARING DINITRILES
CA2644961A1 (en) * 2006-03-17 2007-09-27 Invista Technologies S.A.R.L. Method for the purification of triorganophosphites by treatment with a basic additive
EP2044092B1 (en) * 2006-07-12 2011-09-28 Basf Se Method for producing organic phosphorous compounds containing halogene
US7659422B2 (en) * 2006-07-14 2010-02-09 Invista North America S.A.R.L. Hydrocyanation process with reduced yield losses
US7709673B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7709674B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7919646B2 (en) * 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7880028B2 (en) * 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7977502B2 (en) * 2008-01-15 2011-07-12 Invista North America S.A R.L. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
EP2229353B1 (en) * 2008-01-15 2018-01-03 INVISTA Textiles (U.K.) Limited Hydrocyanation of pentenenitriles
WO2009120529A1 (en) * 2008-03-28 2009-10-01 Union Carbide Chemicals & Plastics Technology Llc (Formerly Union Carbide Chemicals & Plastics Technology Corporation) Slurry process for phosphoromonochloridite synthesis
JP2012514118A (en) 2008-12-29 2012-06-21 ダウ グローバル テクノロジーズ エルエルシー Catalyst composition and method comprising a phosphorus donor
US8609901B2 (en) 2009-04-21 2013-12-17 Invista North America S.A R.L. Highly selective process for producing organodiphosphites
WO2011014405A1 (en) * 2009-07-31 2011-02-03 Chemtura Corporation Liquid alkylated trisaryl phosphite compositions having two alkyl groups with different carbon number
EP2512673B1 (en) 2009-12-18 2016-09-28 Invista Technologies S.à.r.l. Nickel metal compositions and nickel complexes derived from basic nickel carbonates
JP5705986B2 (en) 2010-09-07 2015-04-22 インヴィスタ テクノロジーズ エスアエルエル Nickel composition for preparing nickel metal and nickel complex
EP2718013A2 (en) 2011-06-10 2014-04-16 Invista Technologies S.à.r.l. Nickel calcination and reduction process including a fluidizing bed reactor
JP2014522408A (en) 2011-06-10 2014-09-04 インヴィスタ テクノロジーズ エスアエルエル Improved metal-ligand catalyst formation
EP2771347B1 (en) 2011-10-26 2016-07-27 Invista Technologies S.à.r.l. Methods for producing organodiphosphites from phosphorochloridites characterized by measuring side-product levels to determine further additions
CN103739622A (en) * 2014-01-06 2014-04-23 重庆中平紫光科技发展有限公司 Method for synthesizing phosphorous acid triaryl ester by using two-step method
WO2019025001A1 (en) 2017-08-04 2019-02-07 Wacker Chemie Ag Silicone compositions that can be cross-linked by irradiation with uv light
WO2023228077A1 (en) 2022-05-23 2023-11-30 Inv Nylon Chemicals Americas, Llc Multidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2023228075A1 (en) 2022-05-23 2023-11-30 Inv Nylon Chemicals Americas, Llc Multidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2024028718A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Bidfntate phosphite ligands. catalytic compositions containing such ligands. and catalytic processes utilizing such catalytic compositions
WO2024028715A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Processes for producing nitriles and phosphorus-containing catalysts for use in such processes
WO2024028722A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2024028720A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2024028719A2 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Bidentate phosphite ligands, catalytic compositions containing such ligands, and catalytic processes utilizing such catalytic compositions
WO2024028716A1 (en) 2022-08-02 2024-02-08 Inv Nylon Chemicals Americas, Llc Processes for producing nitriles and phosphorus-containing catalysts for use in such processes

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GERRARD, W.; HERBST, H.: "Reactions in Alcohol-Phosphorus Tribromide Systems", J. CHEM. SOC, 1955, pages 277 - 278, XP009140272 *

Also Published As

Publication number Publication date
EP2239248A2 (en) 2010-10-13
EP1567468A2 (en) 2005-08-31
CA2508337C (en) 2013-01-29
WO2004050588A3 (en) 2004-09-23
EP2243763B1 (en) 2014-10-08
EP2239248B1 (en) 2015-09-23
ES2526971T3 (en) 2015-01-19
AU2003294564A8 (en) 2004-06-23
DE60336419D1 (en) 2011-04-28
HK1085194A1 (en) 2006-08-18
JP2006508177A (en) 2006-03-09
EP2243763A3 (en) 2010-12-29
EP2243763A2 (en) 2010-10-27
AU2003294564A1 (en) 2004-06-23
CA2508337A1 (en) 2004-06-17
US20040106815A1 (en) 2004-06-03
WO2004050588A2 (en) 2004-06-17
EP1567468A4 (en) 2008-01-23
EP2239248B2 (en) 2021-06-09
EP2243763B2 (en) 2022-07-06
EP1567468B1 (en) 2011-03-16
ATE501998T1 (en) 2011-04-15

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