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Publication numberUS1422204 A
Publication typeGrant
Publication dateJul 11, 1922
Filing dateDec 19, 1919
Priority dateDec 19, 1919
Publication numberUS 1422204 A, US 1422204A, US-A-1422204, US1422204 A, US1422204A
InventorsBrown Thomas E, Hoover Wilson W
Original AssigneeBrown Thomas E, Hoover Wilson W
Export CitationBiBTeX, EndNote, RefMan
External Links: USPTO, USPTO Assignment, Espacenet
Method for working oil shales
US 1422204 A
Abstract  available in
Images(1)
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Claims  available in
Description  (OCR text may contain errors)

W. W. HOOVER AND T. E. BROWN.

METHOD FOR WORKING OIL SHALES.

APPLICATION FILED DEC. 19, 1919.

1,422,204;, Patented July 111, 1922.

lNVENTORS Willsm'n W Hoover. B'Yfhqmaa E. Brown,

W LU. 1W.

ATTORNEY structure as 'to be impermeable to the circu- ,umao sra'ras PATENT OFFICE.

WILSON W. HOOVER AND THOMAS E. BROWN, OF NEW YORK, N. Y.

METHOD FOR WORKING OIL SEALES.

To all whom it may concern:

Be it known that we, WILsON W. Hoovnn and THOMAS E. BROWN, cltizens of the United States, and residents of the borough of Manhattan, in the city, county, and State of New York, have invented a certain new and useful Method for Working Oil Shales, of which the following is a specification.

Our invention relates more particularly to that class in which a sub-surface zone, permeable to aheating medium, is produced in a normally impermeable oil shale formation, access to which is gained by drilled wells and the bituminous content treated 1n situ, with a heating medium and products recovered through such wells.

In the present state of the art, the oil shale is quarried, mined, or isolated columns are exposed and enclosed for treatment, the material excavated in the process be ng subjected to surface distillation.

Oil shale is recognized by accepted anthorities as containing a great mass of partly bituminized vegetable matter which can be converted into oil by heat. The 011 thus derived is commercially recognized as petroleum and its products as petroleum products, their chemical composition being substantially the same.

Among other objects of our invention is to gain access to a sub-surface deposit of oil shale by drilling a series or group of contiguous wells of limited diameter in such proximity to each other as to enable the ,pro-

duction in such deposit of a zone of fracture of a determinate area, through the medium of explosives introduced in such deposit through such wells, which zone shall thus be rendered permeable to a heating medium, also introduced therein through one or more of such wells and by the circulation of a heating medium therein to produce suitable temperatures for the treatment of the bituminous content of such zone, to effect the distillation, either collectively or selectively of the more volatile constituents of such content, the liquefaction of the heavier constituents and the recovery of the products through other wells of the group.

We will first describe our method:

Oil shale is normally of such a compact lation of a heating medium for the treatment of the material in situ, it is therefore necessary, in order to permit of such treatment Specification of Letters Patent. Patented J l 11 Application filed December 19, 1919. Serial No. 346,069.

of a sub-surface deposit, to first fracture the formation withln the proposed zone of operation, sufliciently-to permit of the free circulation, throughout such zone, of the vapor extensive with the area of the zone of fracture thus produced and such fractures by their number and extent shall be adapted to permit of the free circulation throughout the zone of the heating medium and of its exhaustion through any other member of the group. The zone of fracture thus produced is limited and defined, on all sides, solely by the lines of fracture segregating it from the unfractured formation. The distance intervening between the respective members of a group of wells, will necessarily vary with the special characteristics of the formation involved, with the natureand amount of the explosive charges exploded within the zone of fracture and with other local conditions and where the latter are novel, must be determined by experiment. The individual wells of a group are drilled to an increasing depth from the inlet well to the outlet well for liquid products, to effect the drainage from the latter. Where the formation permits, the wells which are not required for treating material and recovering products need not be cased. The area of the zone of fracture thus to be produced, may be varied in area and thickness, or vertical section with the richness and thickness of the workable deposit and may be produced at any depth below the surface sufficient to resist the pressures maintained in working the deposit. Two or more such zones may be produced within the same area,

at different depths. When the necessary number of wells have been drilled, explosive charges are introduced into the zone through the respective wells of the group and are exploded therein as required, to produce a system of intercommunicating fractures throughout the zone, such as hereinbefore described. After the ground has been sufficiently fractured. all wells not required for treatment of material and recovery of products are then securely sealed in any suitablemanner, as with cement, so that they will successfully resist the pressures which may be maintained in the treatment of the material in the zone. provided with exhaust pipes, under valvular control; these pipes have connections, where steam is employed as a medium, to receive pressure gauges, and where a gas is employed, they are provided with temperature indicating devices. so that local pressure and temperature at each well may be observed.

In the drawing we show the source for generating the heating medium as a steam boiler and we preferably use steam as the heating medium, but we do not confine ourselves to any specific gas or vapor, but include within the purview of our invention any suitable gas or vapor, including furnace gases, which local conditions may render it profitable or expedient to employ as a heating medium. In the event a gas be used instead of a vapor, then in addition to pressure gauges, with which the boilers are equipped, it becomes necessary to also employ temperature indicating devices as well, in order to govern and control the pressure and temperature of the heating medium supply and of the zone of fracture. Such supply is always under valvular control both at the source and at the inlet well. The outlets for both vaporized and liquid products are also under valvular control in the field as well as at the condenser and tanks.

By the means thus employed the'local pressure and temperature in the zone may not only be observed, but can be absolutely governed and controlled and may be varied, or maintained at any given point, as desired, in order to carry on any of the respective operations, or to vary the same, herein described, to produce any of the results specified or claimed herein.

These operations include, but are not limited, to the conversion of the bituminous material into shale oil, or petroleum, the selective distillation of any of the more volatile constituents of such material, the progressive distillation of all, or a group of such constituents, in the order of their volatili'zation, the liquefaction of the heavier constituents and any other operation involved in the treatment of the material in situ, as may be profitable and practicable, which may be desired or developed by progress in this branch of the art.

The distillates produced by the treatment of the material are delivered, through a valve controlled pipe system connected with the exhaust well, to a suitable condensing apparatus, where the distillates may be sepa- Each well is preferably rated from any foreign vapors or gases, recovered and stored for market or further treatment as the case may be.

The liquid products are pumped .or blown from the pool at the outlet well and conveyed through a valve controlled pipe system connecting such well with suitable tanks and there recovered and stored.

We will now describe our apparatus which we preferably employ in the practice of our invention and which is shown in the drawing and adapted therefor, but we do not limit the practice of our method to the use of 'said apparatus, or the arrangement here shown, as any form of apparatus adapted therefor may be used in the practice thereof.

In the drawing similar reference characters indicate identical parts.

Referring to the drawing:

Fig. 1 is a perspective and sectional view showing the sub-surface material under treatment, and the surface plant and wells.

Fig. 2 is a section ofthe top of a well showing the installation of the exhaust pipe and pressure gauge, and method of sealing.

Referring to Fig. 1 F, is the fractured sub-surface zone of oil shale under treatment, B, the overlying unfractured rock and C, the surface material, A, A, A A A are wells suitably spaced and forming a group covering the area of the zone under treatment. Only the tops of the wells not in section are indicated.

Any well such as A may be used for the supply of a heating medium and any well such as A for the exhaustion of the gases and distillates and any well such as A", for the extraction of the liquids produced by the heating medium.

After the zone of treatment has been properly fractured and rendered permeable as herein described, the tops of the wells A, are provided with exhaust pipes 24, and valves 25, arranged for the reception of pressure gauges 22, and are sealed with cement 23, or other material suited to withstand internal pressure as shown on a larger scale in big. 2.

The surface plant consists preferably of a battery of boilers 1, a liquid receiving tank 2, a condensate receiving tank 3, a condensing apparatus 4, and agas receiver 5, all of which may be duplicated or multiplied in number as desired.

Boilers 1, are connected to well A by pipe 6, with controlling Valves 7, 8 and 9 and pressure gauges 10 and 11, and tank 2 is connected to well A by pipe 12, said pipe being extended down to or near the bottom of said.

with interior coils through which a cooling liquid is circulated, is provided with pipe and valve 18, by which the condensates may be drawn oif into tank 3, and with pipe and valve 19, by which the non-condensable or fixed gases may be carried to gas receiver 5, from which said gases may be carried by pipe 20, to the furnace of boilers 1, and used extraction well A which preferably should be somewhat deeper than the others to form a sump 21.

After the wells are drilled explosives are lowered into them and exploded in any usual manner. Preferably each well is exploded separately and successive charges are preferably exploded at various levels in each well, but the number and amount of the charges and the manner of their explosion may be varied to suit local conditions, such as the depth and nature of the particular rock to be treated and the nature and propertiesof the overlying materials, in order to produce intercommunicating cracks and fissures and render the zone permeable to the heating medium and avoid cracking and fissuring of and causing leakage to the surface through the superincumbent strata.

After the wells have been exploded and the zone rendered permeable, the surface plant having been installed, the pipe connections hereinbefore described are made and the tops of all the wells are sealed.

Steam from the boilers 1, under governed control by means of valves 7, 8 and 9 and gauges 10 and 11 is admitted to well A, passes down said well and permeates the fractured zone through the intercommunieating fissures produced by explosion as before described, and gradually raises the fractured shale rock to the desired temperature.

During the heating up period the waterfrom the condensation of steam may be removed from well A through pipe 12, by pumping until a sufiicient. pressure is reached toforce said water to the surface.

When the desired temperature and corresponding pressure is reached the lighter constituents of the shale rock which volatilize are exhausted through well A pass by the pipe 15, controlled by valves 16 and 17 to condenser 4,'from which the condensates are delivered to tank 3, and the fixed gases which will not condense are delivered to receiver 5.

The liquid roducts which are melted out of the sha e rock accumulate in sump 21, and are forced up through pipe 12, by I the internal pressure, and may be discharged into tank 2, at will and the flow controlled by means of valves 13 and 14.

The liquid accumulated in tanks 2 and 3, may be separated therein by ravity. Any water of condensation may e drawn off from the bottom of said tanks and the accumulated oils may be conveyed away in any suitable manner and subjected to any other refining desired.

The exhaust pipes 24, and valves 25, are very useful in determining the conditions in various portions of the zone. The pressure may be determined by the gauges 22, and samples of the gases may be taken out and analyzed and thus the conditions of pressure and temperature and the degree of permeability in various parts of the zone ma be determined.

ymeans of the steam and outlet valves and gauges shown the temperature and pressure in the zone under treatment are under governed control and may be maintained at any point desired or may be grad ually varied to produce fractional distillation in situ, as before described.

Having thus specified, shown and described t e same, we claim as novel and our invention:

The hereinbefore described method of working oil shales which consists in gaining access to a determinate zone of any desired area, in a sub-surface deposit of oil shale, by drilling a group of contiguous wells, suitable in number, proximity and same permeable to a heating medium, in

introducing a heating medium into the zone of fracture through a member of the group of wells, all wells not required for the treatment of material and recovery of products bein first securely sealed, in circulating heating medium through said zone, in treating the bituminous material therewith, in thereby converting such material into oil and in recovering the products through other members of the roup.

- WILSO W. HOOVER.

THOMAS BROWN.

Referenced by
Citing PatentFiling datePublication dateApplicantTitle
US2630306 *Jan 3, 1952Mar 3, 1953Socony Vacuum Oil Co IncSubterranean retorting of shales
US2630307 *Dec 9, 1948Mar 3, 1953Carbonic Products IncMethod of recovering oil from oil shale
US2634961 *Jun 24, 1947Apr 14, 1953Svensk Skifferolje AktiebolageMethod of electrothermal production of shale oil
US2695163 *Dec 9, 1950Nov 23, 1954Stanolind Oil & Gas CoMethod for gasification of subterranean carbonaceous deposits
US2725939 *Jun 19, 1953Dec 6, 1955Carl BelserApparatus for producing oil from oil shale in situ
US2734578 *Feb 14, 1952Feb 14, 1956 Walter
US2780449 *Dec 26, 1952Feb 5, 1957Sinclair Oil & Gas CoThermal process for in-situ decomposition of oil shale
US2780450 *May 20, 1952Feb 5, 1957Svenska Skifferolje AktiebolagMethod of recovering oil and gases from non-consolidated bituminous geological formations by a heating treatment in situ
US2881838 *Oct 26, 1953Apr 14, 1959Pan American Petroleum CorpHeavy oil recovery
US2906337 *Aug 16, 1957Sep 29, 1959Pure Oil CoMethod of recovering bitumen
US2910123 *Aug 20, 1956Oct 27, 1959Pan American Petroleum CorpMethod of recovering petroleum
US2917296 *Mar 8, 1957Dec 15, 1959Phillips Petroleum CoRecovery of hydrocarbon from oil shale adjoining a permeable oilbearing stratum
US2939688 *Oct 5, 1955Jun 7, 1960Sinclair Oil & Gas CompanyOpening fissures in low-permeability strata
US2962095 *Mar 6, 1957Nov 29, 1960Pan American Petroleum CorpUnderground combustion process for oil recovery
US2969226 *Jan 19, 1959Jan 24, 1961Pyrochem CorpPendant parting petro pyrolysis process
US3010707 *Jul 20, 1959Nov 28, 1961Phillips Petroleum CoRecovery of resins and hydrocarbons from resinous type coals
US3113620 *Jul 6, 1959Dec 10, 1963Exxon Research Engineering CoProcess for producing viscous oil
US3139928 *May 24, 1960Jul 7, 1964Shell Oil CoThermal process for in situ decomposition of oil shale
US3205942 *Feb 7, 1963Sep 14, 1965Socony Mobil Oil Co IncMethod for recovery of hydrocarbons by in situ heating of oil shale
US3223158 *Dec 10, 1962Dec 14, 1965Socony Mobil Oil Co IncIn situ retorting of oil shale
US3241611 *Apr 10, 1963Mar 22, 1966Equity Oil CompanyRecovery of petroleum products from oil shale
US3273640 *Dec 13, 1963Sep 20, 1966Pyrochem CorpPressure pulsing perpendicular permeability process for winning stabilized primary volatiles from oil shale in situ
US3279540 *Dec 3, 1962Oct 18, 1966Deutsche Erdoel AgProcess for the exploitation of bitumenscontaining strata by underground preparation and gasification
US3285335 *Dec 11, 1963Nov 15, 1966Exxon Research Engineering CoIn situ pyrolysis of oil shale formations
US3303881 *Nov 22, 1963Feb 14, 1967Nuclear Proc CorpUnderground nuclear detonations for treatment and production of hydrocarbons in situ
US3342257 *Dec 30, 1963Sep 19, 1967Standard Oil CoIn situ retorting of oil shale using nuclear energy
US3352355 *Jun 23, 1965Nov 14, 1967Dow Chemical CoMethod of recovery of hydrocarbons from solid hydrocarbonaceous formations
US3358756 *Mar 12, 1965Dec 19, 1967Shell Oil CoMethod for in situ recovery of solid or semi-solid petroleum deposits
US3474863 *Jul 28, 1967Oct 28, 1969Shell Oil CoShale oil extraction process
US3480082 *Sep 25, 1967Nov 25, 1969Continental Oil CoIn situ retorting of oil shale using co2 as heat carrier
US3516495 *Nov 29, 1967Jun 23, 1970Exxon Research Engineering CoRecovery of shale oil
US3578080 *Jun 10, 1968May 11, 1971Shell Oil CoMethod of producing shale oil from an oil shale formation
US3593788 *Sep 5, 1967Jul 20, 1971Phillips Petroleum CoCrushing oil shale with nuclear explosives
US3730274 *Dec 30, 1971May 1, 1973Cities Service Oil CoMethod of offset explosive stimulation
US3844349 *Jan 26, 1973Oct 29, 1974Mobil Oil CorpPetroleum production by steam injection
US3918521 *Jun 24, 1974Nov 11, 1975Mobil Oil CorpPetroleum production by steam injection
US3938592 *Nov 12, 1973Feb 17, 1976Ivan Timofeevich AladievRock-exploitation method based on thermodynamic cycles utilizing in-situ energy source
US4344485 *Jun 25, 1980Aug 17, 1982Exxon Production Research CompanyMethod for continuously producing viscous hydrocarbons by gravity drainage while injecting heated fluids
US4407367 *Oct 14, 1980Oct 4, 1983Hri, Inc.Method for in situ recovery of heavy crude oils and tars by hydrocarbon vapor injection
US4487260 *Mar 1, 1984Dec 11, 1984Texaco Inc.In situ production of hydrocarbons including shale oil
US7441603Jul 30, 2004Oct 28, 2008Exxonmobil Upstream Research CompanyHydrocarbon recovery from impermeable oil shales
US7516785Oct 10, 2007Apr 14, 2009Exxonmobil Upstream Research CompanyMethod of developing subsurface freeze zone
US7516787Oct 10, 2007Apr 14, 2009Exxonmobil Upstream Research CompanyMethod of developing a subsurface freeze zone using formation fractures
US7631691Jan 25, 2008Dec 15, 2009Exxonmobil Upstream Research CompanyMethods of treating a subterranean formation to convert organic matter into producible hydrocarbons
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US7669657Oct 10, 2007Mar 2, 2010Exxonmobil Upstream Research CompanyEnhanced shale oil production by in situ heating using hydraulically fractured producing wells
US7857056Oct 15, 2008Dec 28, 2010Exxonmobil Upstream Research CompanyHydrocarbon recovery from impermeable oil shales using sets of fluid-heated fractures
US7980312 *Jul 19, 2011Hill Gilman AIntegrated in situ retorting and refining of oil shale
US8082995Nov 14, 2008Dec 27, 2011Exxonmobil Upstream Research CompanyOptimization of untreated oil shale geometry to control subsidence
US8087460Mar 7, 2008Jan 3, 2012Exxonmobil Upstream Research CompanyGranular electrical connections for in situ formation heating
US8104537Dec 15, 2009Jan 31, 2012Exxonmobil Upstream Research CompanyMethod of developing subsurface freeze zone
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US8146664May 21, 2008Apr 3, 2012Exxonmobil Upstream Research CompanyUtilization of low BTU gas generated during in situ heating of organic-rich rock
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US8230929Mar 17, 2009Jul 31, 2012Exxonmobil Upstream Research CompanyMethods of producing hydrocarbons for substantially constant composition gas generation
US8261823Sep 11, 2012Hill Gilman AIntegrated in situ retorting and refining of oil shale
US8540020Apr 21, 2010Sep 24, 2013Exxonmobil Upstream Research CompanyConverting organic matter from a subterranean formation into producible hydrocarbons by controlling production operations based on availability of one or more production resources
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US9085972Aug 6, 2012Jul 21, 2015Gilman A. HillIntegrated in situ retorting and refining of heavy-oil and tar sand deposits
DE1245290B *Jan 19, 1966Jul 27, 1967Equity Oil CompanyVerfahren zur Gewinnung von Erdoel aus OElschiefer
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Classifications
U.S. Classification166/271, 166/272.3, 235/91.00R, 102/313, 166/299, 175/2, 166/245
International ClassificationE21B43/16, E21B43/24
Cooperative ClassificationE21B43/24
European ClassificationE21B43/24